Sintered(Ce,Nd)-Fe-B magnets with high cost performance were prepared by substituting of Ce for Nd with the dual-main phase method.The corrosion behaviors of dual-main phase sintered(CexNd1-x)30Fe69B1(x=0.15 wt%,0.3 w...Sintered(Ce,Nd)-Fe-B magnets with high cost performance were prepared by substituting of Ce for Nd with the dual-main phase method.The corrosion behaviors of dual-main phase sintered(CexNd1-x)30Fe69B1(x=0.15 wt%,0.3 wt%) magnets,which were named as Ce15 and Ce30,were studied in 3.5 wt% NaCl,6.6 wt% Na2 SO4 and 3.0 wt% NaOH aqueous solutions,respectively.The galvanic corrosion of Ce30 is stronger than that of Ce15.However,the mass loss value of Ce30 is smaller than Ce15 after free corrosion for 33 d in NaCl solution.In the other two solutions,all the results show that the corrosion resistance of Ce30 is better than that of Ce15.The scanning electron microscope results show that the crack and shedding of the magnetic phase of Ce30 is less than that of Ce15.Combined above,the abnormal corrosion behavior shows that Ce30 magnets perform better corrosion resistance than Ce15,and the degradation degree of magnetic phase mainly affects the corrosion resistance of magnets.展开更多
Double main phase process is applied to fabricate [(Pr, Nd)1 – xMMx]13.8FebalM1.5B5.9 (x = 0.5 and 0.7;M = Cu, Al, Co, and Nb) sintered magnets with high misch metal (MM) content. In comparison to the magnets by sing...Double main phase process is applied to fabricate [(Pr, Nd)1 – xMMx]13.8FebalM1.5B5.9 (x = 0.5 and 0.7;M = Cu, Al, Co, and Nb) sintered magnets with high misch metal (MM) content. In comparison to the magnets by single main phase process, the enhanced magnetic properties have been achieved. For magnets of x = 0.7, Hcj increases to 371.9 kA/m by 60.5%, and (BH)max is significantly enhanced to 253.3 kJ/m3 by 56.9%, compared with those of the single main phase magnets of the same nominal composition. In combination with minor loops and magnetic recoil curves, the property improvement of magnets with double main phase method is well explained. As a result, it is demonstrated that double main phase technology is an effective approach to improve the permanent magnetic properties of MM based sintered magnets.展开更多
It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of gr...It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.展开更多
This study demonstrates simultaneous enhancement of magnetic and mechanical properties in NdFeB magnets through Ti addition.The coercivity increases by 1.1 kOe without compromising remanence,while bending strength imp...This study demonstrates simultaneous enhancement of magnetic and mechanical properties in NdFeB magnets through Ti addition.The coercivity increases by 1.1 kOe without compromising remanence,while bending strength improves by 159.05%.Analytical results reveal that Ti predominantly combines with free B atoms to form TiB_(2)phases,which reduce the brittleness of grain boundary(GB)phase and impede dislocation motion.The superposition of stress fields around dislocations generates reactive forces that counteract external loads,thereby enhancing GB strength.Concurrently,B depletion in GB phases induces amorphous transformation,further enhancing boundary strength.A minor fraction of Ti incorporates into the main phase,enhancing covalent bond strength and forming a reinforced main phase.Additionally,Ti addition promotes grain refinement and increases GB density,significantly improving bending strength.The synergistic effects of heterogeneous phase formation,amorphous transformation,main phase reinforcement,and grain refinement collectively enable coordinated strengthening between the main phase and GBs.This multi-mechanism approach provides novel insights for mechanical property optimization in Nd FeB magnets.展开更多
This paper probes the determination of the main gas-generation phase of marine organic mattes using the kinetic method. The main gas-generation phase of marine organic matters was determined by coupling the gas genera...This paper probes the determination of the main gas-generation phase of marine organic mattes using the kinetic method. The main gas-generation phase of marine organic matters was determined by coupling the gas generation yields and rates in geological history computed by the acquired kinetic parameters of typical marine organic matters （reservoir oil, residual bitumen, lowmaturity kerogen and residual kerogen） in both China and abroad and maturity by the EasyRo（%） method. Here, the main gas-generation phase was determined as Ro%=1.4%-2.4% for type Ⅰ kerogen, Ro%=1.5-3.0% for low-maturity type Ⅱ kerogen, Ro%=1.4-2.8% for residual kerogen, Ro%=1.5-3.2% for residual bitumen and Ro%=1.6-3.2% for reservoir oil cracking. The influences on the main gas-generation phase from the openness of the simulated system and the ＂dead line＂ of natural gas generation are also discussed. The results indicate that the openness of simulation system has a definite influence on computing the main gas-generation phase. The main gas-generation phase of type Ⅱ kerogen is Ro%=1.4-3.1% in an open system, which is earlier than that in a closed system. According to our results, the ＂dead line＂ of natural gas generation is determined as Ro=3.5 % for type Ⅰ kerogen, Ro=4.4-4.5% for type Ⅱ kerogen and Ro=4.6% for marine oil. Preliminary applications are presented taking the southwestern Tarim Basin as an example.展开更多
The isotropic nanocrystalline[(PrNd)0.8MM0.2]29.8Fe68.7Al0.1Cu0.12Co0.88B magnets(MM:mischmetal)were prepared by single-main phase and double-main phase methods using spark plasma sintering(SPS).Melt-spinning method w...The isotropic nanocrystalline[(PrNd)0.8MM0.2]29.8Fe68.7Al0.1Cu0.12Co0.88B magnets(MM:mischmetal)were prepared by single-main phase and double-main phase methods using spark plasma sintering(SPS).Melt-spinning method was used to prepare initial powder and avoid component deviations caused by longtime ball milling.The magnetic properties of the magnet prepared by double-main phase method(called double-main phase magnet,DMP magnet)are remanence of Br=0.75 T,intrinsic coercivity of Hcj=909.83 kA·m-1,maximum magnetic energy product of(BH)max=95.48 kJ·m-3,which are better than those of the magnet prepared by single-main phase method(called singlemain phase magnet,SMP magnet).The diffraction peaks of the main phase of DMP magnet split in X-ray diffractometer(XRD)pattern,indicating that R2 Fe14B phases with different distributions of La/Ce elements exist in the magnet.This speculation is confirmed by transmission electron microscopy(TEM)observation.The La/Ce-rich main phase and La/Celean main phase are present in DMP magnets.The heterogeneity of rare earth elements suppresses the magnetic dilution effect in DMP magnet,and the magnetic properties are improved.Though the DMP magnet contains different main phases,it presents unitary Curie temperature(TC)of 577 K,which is higher than that of SMP magnet.This result suggests that the TC of the magnets can be promoted by double-main phase method and SPS.展开更多
Studying of operation balance in single-phase induction motors is an issue of interest due to the need for reducing the power consumption and increasing the motors’ life. The paper focuses on improving the motor perf...Studying of operation balance in single-phase induction motors is an issue of interest due to the need for reducing the power consumption and increasing the motors’ life. The paper focuses on improving the motor performance by balancing the stator phase operation for the most common-used connection diagrams of single-phase capacitor-run induction motors (SPCRIMs) and three-phase induction motors (TPIMs) operating from single-phase supply (SPS). Therefore, a mathematical model is used to balance the motor operation by varying the frequency supply voltage. Characteristics of balancing parameters are investigated, various methods of motor balancing are presented and comparisons were done among these balancing methods.展开更多
基金Project supported by the National Natural Science Foundation of China(51871063,51571064,51590882)。
文摘Sintered(Ce,Nd)-Fe-B magnets with high cost performance were prepared by substituting of Ce for Nd with the dual-main phase method.The corrosion behaviors of dual-main phase sintered(CexNd1-x)30Fe69B1(x=0.15 wt%,0.3 wt%) magnets,which were named as Ce15 and Ce30,were studied in 3.5 wt% NaCl,6.6 wt% Na2 SO4 and 3.0 wt% NaOH aqueous solutions,respectively.The galvanic corrosion of Ce30 is stronger than that of Ce15.However,the mass loss value of Ce30 is smaller than Ce15 after free corrosion for 33 d in NaCl solution.In the other two solutions,all the results show that the corrosion resistance of Ce30 is better than that of Ce15.The scanning electron microscope results show that the crack and shedding of the magnetic phase of Ce30 is less than that of Ce15.Combined above,the abnormal corrosion behavior shows that Ce30 magnets perform better corrosion resistance than Ce15,and the degradation degree of magnetic phase mainly affects the corrosion resistance of magnets.
基金Project supported by the National Natural Foundation of China(Grant Nos.51590880,11564030,and 51571126)the National Key Research Program of China(Grant No.2016YFB0700903)+3 种基金Fujian Institute of Innovation,Chinese Academy of Sciences(Grant No.FJCXY18040302)the Key Program of the Chinese Academy of Sciences(Grant No.KJZD-EW-M05-1)the Inner Mongolia Science and Technology Major Project of 2016,Chinathe Natural Science Foundation of Inner Mongolia,China(Grant Nos.2018LH05006 and 2018LH05011)。
文摘Double main phase process is applied to fabricate [(Pr, Nd)1 – xMMx]13.8FebalM1.5B5.9 (x = 0.5 and 0.7;M = Cu, Al, Co, and Nb) sintered magnets with high misch metal (MM) content. In comparison to the magnets by single main phase process, the enhanced magnetic properties have been achieved. For magnets of x = 0.7, Hcj increases to 371.9 kA/m by 60.5%, and (BH)max is significantly enhanced to 253.3 kJ/m3 by 56.9%, compared with those of the single main phase magnets of the same nominal composition. In combination with minor loops and magnetic recoil curves, the property improvement of magnets with double main phase method is well explained. As a result, it is demonstrated that double main phase technology is an effective approach to improve the permanent magnetic properties of MM based sintered magnets.
文摘It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.
基金financially supported by the National Natural Science Foundation of China(No.52361033)National Key Research and Development Program(No.2022YFB3505400)+6 种基金Ministry of Industry and Information Technology Heavy Rare Earth Special use of Sintered NdFeB Project(No.TC220H06J)Academic and Technical Leaders in Major Disciplines in Jiangxi Province(No.20225BCJ23007)Jiangxi Natural Science Foundation Youth Fund(No.20232BAB214011)the Young Elite Scientists Sponsorship Program by CAST(No.2022QNRC001)Research Projects of Ganjiang Innovation Academy,Chinese Academy of Sciences(No.E255J001)Science and Technology Major Project of Ganzhou(No.202101064871)Program for Excellent Young Talents(No.JXUSTQJYC2024003)
文摘This study demonstrates simultaneous enhancement of magnetic and mechanical properties in NdFeB magnets through Ti addition.The coercivity increases by 1.1 kOe without compromising remanence,while bending strength improves by 159.05%.Analytical results reveal that Ti predominantly combines with free B atoms to form TiB_(2)phases,which reduce the brittleness of grain boundary(GB)phase and impede dislocation motion.The superposition of stress fields around dislocations generates reactive forces that counteract external loads,thereby enhancing GB strength.Concurrently,B depletion in GB phases induces amorphous transformation,further enhancing boundary strength.A minor fraction of Ti incorporates into the main phase,enhancing covalent bond strength and forming a reinforced main phase.Additionally,Ti addition promotes grain refinement and increases GB density,significantly improving bending strength.The synergistic effects of heterogeneous phase formation,amorphous transformation,main phase reinforcement,and grain refinement collectively enable coordinated strengthening between the main phase and GBs.This multi-mechanism approach provides novel insights for mechanical property optimization in Nd FeB magnets.
文摘This paper probes the determination of the main gas-generation phase of marine organic mattes using the kinetic method. The main gas-generation phase of marine organic matters was determined by coupling the gas generation yields and rates in geological history computed by the acquired kinetic parameters of typical marine organic matters （reservoir oil, residual bitumen, lowmaturity kerogen and residual kerogen） in both China and abroad and maturity by the EasyRo（%） method. Here, the main gas-generation phase was determined as Ro%=1.4%-2.4% for type Ⅰ kerogen, Ro%=1.5-3.0% for low-maturity type Ⅱ kerogen, Ro%=1.4-2.8% for residual kerogen, Ro%=1.5-3.2% for residual bitumen and Ro%=1.6-3.2% for reservoir oil cracking. The influences on the main gas-generation phase from the openness of the simulated system and the ＂dead line＂ of natural gas generation are also discussed. The results indicate that the openness of simulation system has a definite influence on computing the main gas-generation phase. The main gas-generation phase of type Ⅱ kerogen is Ro%=1.4-3.1% in an open system, which is earlier than that in a closed system. According to our results, the ＂dead line＂ of natural gas generation is determined as Ro=3.5 % for type Ⅰ kerogen, Ro=4.4-4.5% for type Ⅱ kerogen and Ro=4.6% for marine oil. Preliminary applications are presented taking the southwestern Tarim Basin as an example.
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0700903)the National Natural Science Foundation of China(Nos.51571064 and 51571126).
文摘The isotropic nanocrystalline[(PrNd)0.8MM0.2]29.8Fe68.7Al0.1Cu0.12Co0.88B magnets(MM:mischmetal)were prepared by single-main phase and double-main phase methods using spark plasma sintering(SPS).Melt-spinning method was used to prepare initial powder and avoid component deviations caused by longtime ball milling.The magnetic properties of the magnet prepared by double-main phase method(called double-main phase magnet,DMP magnet)are remanence of Br=0.75 T,intrinsic coercivity of Hcj=909.83 kA·m-1,maximum magnetic energy product of(BH)max=95.48 kJ·m-3,which are better than those of the magnet prepared by single-main phase method(called singlemain phase magnet,SMP magnet).The diffraction peaks of the main phase of DMP magnet split in X-ray diffractometer(XRD)pattern,indicating that R2 Fe14B phases with different distributions of La/Ce elements exist in the magnet.This speculation is confirmed by transmission electron microscopy(TEM)observation.The La/Ce-rich main phase and La/Celean main phase are present in DMP magnets.The heterogeneity of rare earth elements suppresses the magnetic dilution effect in DMP magnet,and the magnetic properties are improved.Though the DMP magnet contains different main phases,it presents unitary Curie temperature(TC)of 577 K,which is higher than that of SMP magnet.This result suggests that the TC of the magnets can be promoted by double-main phase method and SPS.
文摘Studying of operation balance in single-phase induction motors is an issue of interest due to the need for reducing the power consumption and increasing the motors’ life. The paper focuses on improving the motor performance by balancing the stator phase operation for the most common-used connection diagrams of single-phase capacitor-run induction motors (SPCRIMs) and three-phase induction motors (TPIMs) operating from single-phase supply (SPS). Therefore, a mathematical model is used to balance the motor operation by varying the frequency supply voltage. Characteristics of balancing parameters are investigated, various methods of motor balancing are presented and comparisons were done among these balancing methods.
