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Magnéli相亚氧化钛陶瓷的制备及其应用研究进展
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作者 刘会军 肖浩宇 +2 位作者 乔永莲 杨凌旭 曾潮流 《材料研究与应用》 CAS 2024年第1期37-50,共14页
Magnéli相亚氧化钛是一系列非化学计量比氧化钛的统称,主要包括Ti_(4)O_(7)、Ti_(5)O_(9)、Ti_(6)O_(11)和Ti_(8)O_(15)等相,其中以Ti_(4)O_(7)的导电性最好,其理论电导率可达1500 S·cm^(-1),约为石墨的二倍。此外,Magné... Magnéli相亚氧化钛是一系列非化学计量比氧化钛的统称,主要包括Ti_(4)O_(7)、Ti_(5)O_(9)、Ti_(6)O_(11)和Ti_(8)O_(15)等相,其中以Ti_(4)O_(7)的导电性最好,其理论电导率可达1500 S·cm^(-1),约为石墨的二倍。此外,Magnéli相亚氧化钛在强酸、强碱环境中均表现出极强的耐蚀性能,并且能够在水溶液中保持3.0 V以上的稳定电位窗口。Magnéli相亚氧化钛优异的性能使其在化学电源如铅蓄电池、液流电池、锂硫电池、可再生燃料电池,电解水的催化剂载体,热电及光电材料,光催化制氢以及电催化氧化降解有机污染物等领域中展现出良好的应用前景。目前,科研人员已经开发出一系列制备亚氧化钛的方法。但是在高纯度、单相、纳米或亚微米尺度亚氧化钛粉体,大尺寸的一体式亚氧化钛电极和金属基亚氧化钛涂层电极的规模化生产和应用中依然存在许多问题,限制了亚氧化钛系列产品在上述领域中的广泛应用。基于Magnéli相亚氧化钛陶瓷的固有特性,重点介绍了亚氧化钛粉体、一体式电极和涂层电极的制备方法及应用现状,同时对亚氧化钛相关材料的应用前景进行了简要概述,为科研院所及相关企业提供了参考依据、研究思路和解决办法。 展开更多
关键词 magnéli相 亚氧化钛 Ti_(4)O_(7) 纳米粉体 亚微米粉体 一体式电极 靶材 涂层电极
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Insight from Lithostructural and Aeromagnetic Data from the Léo Square Degree, Central-Western Burkina Faso
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作者 Adama Ouédraogo Yaméogo Pascal Ouiya +4 位作者 Gounwendmanaghré Hubert Zongo Omar Akonyiré Abraham Seydoux Traoré Saga Sawadogo Séta Naba 《Open Journal of Geology》 CAS 2024年第1期19-28,共10页
This study, carried out in the Léo square degree (west-central Burkina Faso) in the Palaeoproterozoic domain of the Man/Léo ridge, aims to define the shapes and positions of granitic plutons and the organisa... This study, carried out in the Léo square degree (west-central Burkina Faso) in the Palaeoproterozoic domain of the Man/Léo ridge, aims to define the shapes and positions of granitic plutons and the organisation of deformation structures using aeromagnetic data. These data have shown that there are small sub-circular granitic bodies to the north of the granitic masses in this region, and a large sub-circular granitic body to the south, around which are other smaller granitic bodies. The lineament map shows that the deformation structures are organised along three main directions and largely form these sub-circular plutonic bodies. We suggest that the granitic plutons are coalescent, pending identification of the internal structures of these granites to further refine the geodynamic model. 展开更多
关键词 Burkina Faso LINEAMENTS Belts Rocks Leo’s Leaf Granitoïd Airbornes magnétics
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铝热还原TiO2制备Magnéli相低价钛氧化物工艺及过程机制研究 被引量:6
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作者 李军 鲁雄刚 +3 位作者 杨绍利 吴恩辉 侯静 李重河 《稀有金属》 EI CAS CSCD 北大核心 2018年第6期627-633,共7页
Magnéli相(TinO2n-1)(4〈n〈10)低价钛氧化物材料具有导电性好、可见光响应强、耐磨、优异的耐腐蚀性能等,被广泛应用于制备电池、惰性电极及光催化降解材料。在空气气氛下利用铝还原锐钛矿相TiO2制备Magnéli相低价钛氧... Magnéli相(TinO2n-1)(4〈n〈10)低价钛氧化物材料具有导电性好、可见光响应强、耐磨、优异的耐腐蚀性能等,被广泛应用于制备电池、惰性电极及光催化降解材料。在空气气氛下利用铝还原锐钛矿相TiO2制备Magnéli相低价钛氧化物材料,研究了不同焙烧温度、焙烧时间和配铝量等工艺参数对制备黑色Magnéli相低价钛氧化物复合材料相变过程的影响,并采用X射线衍射(XRD)、拉曼光谱(Raman)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)等分析手段对制备出的Magnéli相低价氧化物复合材料的物相组成变化及微观组织形貌进行表征,结果表明:不同焙烧温度和焙烧时间下制备的样品主要物相为Ti9O17,Ti8O15,Ti7O13,Ti4O7,随着焙烧温度的升高和焙烧时间的延长,还原程度不断加深,TinO2n-1中的n值不断降低。制备的Magnéli相低价氧化物材料呈颗粒状,粒径200~400 nm左右。通过稀盐酸浸出,可以将Magnéli相材料中过剩的铝除去得到较为纯净的Magnéli相TinO2n-1材料。 展开更多
关键词 铝热还原 TinO2n-1 magnéli相
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Magnéli相Ti_4O_7的制备及在燃料电池中的应用 被引量:3
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作者 姚传好 李钒 李翔 《材料导报》 EI CAS CSCD 北大核心 2011年第13期40-43,共4页
综述了制备Magnéli相Ti4O7的H2还原TiO2、C还原TiO2和机械活化Ti和TiO2及两步法合成等4种方法的研究现状及其优缺点,以及研究Magnéli相Ti4O7在燃料电池中的应用现状。展望了软化学法合成高比表面积的Ti4O7材料作为燃料电池催... 综述了制备Magnéli相Ti4O7的H2还原TiO2、C还原TiO2和机械活化Ti和TiO2及两步法合成等4种方法的研究现状及其优缺点,以及研究Magnéli相Ti4O7在燃料电池中的应用现状。展望了软化学法合成高比表面积的Ti4O7材料作为燃料电池催化剂载体材料的发展趋势。 展开更多
关键词 magnéli相Ti4O7 催化剂载体 燃料电池
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Magnéli相亚氧化钛的制备及其应用 被引量:9
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作者 张浩 曹高萍 +1 位作者 徐斌 杨裕生 《电池工业》 CAS 2011年第6期363-366,共4页
Magnéli相亚氧化钛材料是一类分子式为TinO2n-1(3<n<10)的导电化合物,该类化合物是于20世纪50年代通过XRD技术发现。对这些钛氧化物的制备及其物化性质进行介绍;着重介绍它们在铅蓄电池、液流电池和燃料电池等化学电源电极... Magnéli相亚氧化钛材料是一类分子式为TinO2n-1(3<n<10)的导电化合物,该类化合物是于20世纪50年代通过XRD技术发现。对这些钛氧化物的制备及其物化性质进行介绍;着重介绍它们在铅蓄电池、液流电池和燃料电池等化学电源电极材料方面的应用进展。 展开更多
关键词 magnéli相亚氧化钛 电极材料 铅蓄电池 液流电池 燃料电池
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铝热还原法制备Magnéli相亚氧化钛及其可见光光催化活性研究 被引量:1
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作者 李军 吴恩辉 +4 位作者 侯静 黄平 蒋燕 徐众 刘黔蜀 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2020年第7期2281-2288,共8页
采用铝热还原-盐酸酸洗工艺成功制备了Magnéli相亚氧化钛,通过XRD,SEM,UV-Vis DRS和XPS等手段进行表征。结果表明:在焙烧温度950℃,焙烧时间20 min,Al/TiO2=0.2时,成功制备以Ti4O7为主要物相的Magnéli相亚氧化钛材料,其粒径为... 采用铝热还原-盐酸酸洗工艺成功制备了Magnéli相亚氧化钛,通过XRD,SEM,UV-Vis DRS和XPS等手段进行表征。结果表明:在焙烧温度950℃,焙烧时间20 min,Al/TiO2=0.2时,成功制备以Ti4O7为主要物相的Magnéli相亚氧化钛材料,其粒径为400~600 nm,样品表面形成了大量的氧空位,表现出很强的紫外和可见光吸收性能。在可见光条件下光照130 min时,950℃焙烧20、25和35 min条件下制备并酸洗后的Magnéli相亚氧化钛降解亚甲基蓝的效率分别达到37%、43%和62%。 展开更多
关键词 铝热还原 magnéli相 光催化降解
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Miniature quad-channel spin-exchange relaxation-free magnetometer for magnetoencephalography 被引量:9
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作者 Jian-Jun Li Peng-Cheng Du +3 位作者 Ji-Qing Fu Xu-Tong Wang Qing Zhou Ru-Quan Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第4期145-149,共5页
A miniature quad-channel optically pumped atomic magnetometer(OPM) has been developed based on the spinexchange relaxation-free(SERF) mechanism. With a vapor cell of size 8 mm×8 mm×8 mm, we have incorporated... A miniature quad-channel optically pumped atomic magnetometer(OPM) has been developed based on the spinexchange relaxation-free(SERF) mechanism. With a vapor cell of size 8 mm×8 mm×8 mm, we have incorporated four SERF magnetometer channels, which provides sufficient spatial resolution for magnetoencephalography(MEG). The four channels share the same laser beam for the best cancellation of common mode noise due to laser fluctuations. With gradient measurement, the sensitivities of the four sensors are better than 6 fT/Hz^(1/2), which is also good enough for MEG measurement. The vapor cell is heated to 160℃ by a novel nonmagnetic current-heating structure. Our sensor with high spatial resolution and compact size is particularly suitable for MEG systems. 展开更多
关键词 multi-channel SPIN-EXCHANGE relaxation-free optically PUMPED atomic magnETOMETER magne-toencephalography
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Magnéli相亚氧化钛材料的制备及其可见光光催化性能
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作者 李军 吴恩辉 +4 位作者 侯静 黄平 徐众 蒋燕 刘黔蜀 《材料科学与工程学报》 CAS CSCD 北大核心 2021年第6期922-928,共7页
以金红石型钛白粉为原料,采用铝还原-盐酸酸洗工艺常压下制备了Magnéli相亚氧化钛材料。采用包括X射线衍射(XRD)仪等多种表征方法测定了制备样品的物相组成、形貌、化学价态及光谱吸收性能,并测试了可见光下样品降解甲基蓝的光催... 以金红石型钛白粉为原料,采用铝还原-盐酸酸洗工艺常压下制备了Magnéli相亚氧化钛材料。采用包括X射线衍射(XRD)仪等多种表征方法测定了制备样品的物相组成、形貌、化学价态及光谱吸收性能,并测试了可见光下样品降解甲基蓝的光催化活性。研究结果表明:950℃焙烧15~30min条件下制备的Magnéli相亚氧化钛材料主要为Ti_(4)O_(7)和Ti5O9的混合相,采用盐酸酸洗可以有效去除样品中的Al,但含有不溶于酸的α-Al_(2)O_(3)。该工艺制备的Magnéli相亚氧化钛颗粒尺寸为100~200nm,没有存在明显的团聚烧结长大现象,具有良好的可见光和近红外光吸收性能以及在可见光条件下具有较好的光催化能力。 展开更多
关键词 钛白粉 铝热还原 盐酸酸洗 magnéli 光催化
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Crystallization Behavior of High Purity Fused Magnesia 被引量:2
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作者 LI Xuejun GAO Zhenxin +2 位作者 YAN Guanghui ZHANG Wei FU Qiuhua 《China's Refractories》 CAS 2017年第2期1-6,共6页
The chemical composition and microstructure of Tibetan microcrystalline magnesite were studied by means of XRF,XRD and FESEM. It is found that the microcrystalline magnesite has uniformly distributed grains,mostly in ... The chemical composition and microstructure of Tibetan microcrystalline magnesite were studied by means of XRF,XRD and FESEM. It is found that the microcrystalline magnesite has uniformly distributed grains,mostly in the range of 2-4 μm,and the MgO content is47. 80%. In fused magnesia,the druses are colorless transparent periclase megacrysts without impurity,while the crust sand is white,with a high MgO content up to97%-99%. The periclase crystals are big,appearing as faced and step-growth morphology. Massive secondary long columnar periclase is crystallized. 展开更多
关键词 microcrystalline magnesite fused magne-sia crust sand long columnar periclase crystals
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The magnetization reversal behaviour for SmCo_(6.8)Zr_(0.2) and SmCo_(6.8)Zr_(0.2)/α-(Fe,Co) nanocrystalline magnets at low temperature
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作者 刘壮 陈仁杰 +1 位作者 李东 闫阿儒 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第6期528-533,共6页
This paper reports that the SmCo6.8Zr0.2 nanocrystalline permanent magnets and SmCo6.8Zr0.2/a-(Fe,Co) nanocomposite permanent magnets are successfully produced by mechanical alloying and subsequently annealing at 70... This paper reports that the SmCo6.8Zr0.2 nanocrystalline permanent magnets and SmCo6.8Zr0.2/a-(Fe,Co) nanocomposite permanent magnets are successfully produced by mechanical alloying and subsequently annealing at 700℃ for 10 minutes. The x-ray diffraction results show that the phase structure of SmCo6.8Zr0.2 nanocrystalline permanent magnets is composed of SmCo7 phase and SmCo6.8Zr0.2/a-(Fe,Co) nanocomposite permanent magnets is composed of SmCo7 and a-(Fe,Co) phases. The mechanism of magnetization reversal is mainly controlled by inhomogeneous domain wall pinning in SmCo6.8Zr0.2 and SmCo6.8Zr0.2/a-(Fe,Co) magnets. The inter-grain exchange interaction at low temperature is investigated, which shows that the inter-grain exchange interaction of SmCo6.8Zr0.2/a-(Fe,Co) magnets increases greatly by the decrease of the measured temperature. According to Amirr-H/Hcj, Amrev-H/Hcj and Xirr-H/Hcj curves at room temperature and 100 K, the changes of irreversible and reversible magnetization behaviours of SmCo6.8Zr0.2 and SmCo6.8Zr0.2/a-(Fe,Co) magnets with the decreasing temperature are analysed in detail. The magnetic viscosity and the activation volume of SmCo6.8Zr0.2 and SmCo6.8Zr0.2/a-(Fe,Co) magnets at different temperatures are also studied. 展开更多
关键词 nanocrystalline magnets coercivity mechanism inter-grain exchange coupling magne- tization reversal behaviour
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Ti-O Magnéli相氧化物的性质、制备与应用研究进展 被引量:1
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作者 霍玲玲 乔丹 +2 位作者 王义智 李钒 黄一兵 《材料导报》 EI CAS CSCD 北大核心 2017年第11期29-37,58,共10页
Ti-O Magnéli相氧化物因具有特殊的结构和性质自发现以来就备受关注。Ti-O Magnéli相氧化物优良的电子导电性、稳定性以及耐腐蚀性使得其在电化学领域应用广泛。综述了Ti-O Magnéli相氧化物的组成、结构、性质及其主要... Ti-O Magnéli相氧化物因具有特殊的结构和性质自发现以来就备受关注。Ti-O Magnéli相氧化物优良的电子导电性、稳定性以及耐腐蚀性使得其在电化学领域应用广泛。综述了Ti-O Magnéli相氧化物的组成、结构、性质及其主要的制备方法,并总结归纳了该材料的主要应用。提供了Ti-O Magnéli相氧化物未来合成与应用研究的方向。 展开更多
关键词 Ti-O magnéli相 电子导电氧化物 材料制备 电极特性
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Magnéli相亚氧化钛的制备和应用研究进展 被引量:2
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作者 孟令岽 李国明 陈珊 《装备环境工程》 CAS 2017年第12期77-82,共6页
介绍了当前制备亚氧化钛的几种常见方法,以及亚氧化钛材料的应用现状,并对亚氧化钛材料的前景进行了简要分析。虽然当前该种材料在制备上存在一些问题,但经过相应改进后该材料能够实现大规模合成,展现出更大的应用价值。
关键词 magné1i相亚氧化钛 TL4O7
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Role of magnetic resonance imaging in the detection and characterization of solid pancreatic nodules: An update 被引量:10
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作者 Najwa Al Ansari Miguel Ramalho +3 位作者 Richard C Semelka Valeria Buonocore Silvia Gigli Francesca Maccioni 《World Journal of Radiology》 CAS 2015年第11期361-374,共14页
Pancreatic ductal adenocarcinoma is the most common malignant tumor of the pancreas. The remaining pancreatic tumors are a diverse group of pancreatic neoplasms that comprises cystic pancreatic neoplasms, endocrine tu... Pancreatic ductal adenocarcinoma is the most common malignant tumor of the pancreas. The remaining pancreatic tumors are a diverse group of pancreatic neoplasms that comprises cystic pancreatic neoplasms, endocrine tumors and other uncommon pancreatic tumors. Due to the excellent soft tissue contrast resolution, magnetic resonance imaging(MRI) is frequently able to readily separate cystic from noncystic tumors. Cystic tumors are often easy to diagnose with MRI; however, noncystic non-adenocarcinoma tumors may show a wide spectrum of imaging features, which can potentially mimic ductal adenocarcinoma. MRI is a reliable technique for the characterization of pancreatic lesions. The implementation of novel motionresistant pulse sequences and respiratory gating techniques, as well as the recognized benefits of MR cholangiopancreatography, make MRI a very accurate examination for the evaluation of pancreatic masses. MRI has the distinctive ability of non-invasive assessment of the pancreatic ducts, pancreatic parenchyma, neighbouring soft tissues, and vascular network in one examination. MRI can identify different characteristics of various solid pancreatic lesions, potentially allowing the differentiation of adenocarcinoma from other benign and malignant entities. In this review we describe the MRI protocols and MRI characteristics of various solid pancreatic lesions. Recognition of these characteristics may establish the right diagnosis or at least narrow the differential diagnosis, thus avoiding unnecessary tests or procedures and permitting better management. 展开更多
关键词 PANCREATIC NODULES MALIGNANT LYMPHOMA BENIGN magne
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空气气氛下碳热还原筛分法制备Magnéli相Ti_(n)O_(2n-1)
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作者 侯静 杨培志 +2 位作者 郑勤红 吴恩辉 李军 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2021年第11期3824-3827,共4页
介绍了一种在空气气氛中通过碳热还原筛分法制备Magnéli相(Ti_(n)O_(2n−1),4<n<10)低价钛氧化物的方法,研究了还原温度和还原时间对还原产物的物相、电阻率的影响。结果表明,提高还原温度和延长还原时间有利于将TiO_(2)还原... 介绍了一种在空气气氛中通过碳热还原筛分法制备Magnéli相(Ti_(n)O_(2n−1),4<n<10)低价钛氧化物的方法,研究了还原温度和还原时间对还原产物的物相、电阻率的影响。结果表明,提高还原温度和延长还原时间有利于将TiO_(2)还原为Magnéli相Ti_(n)O_(2n−1)。将Magnéli相Ti_(n)O_(2n−1)(n=4,5)粉末在1350℃下干燥20 min,通过扫描电子显微镜观察,其粒径为0.5~8μm。在还原温度为1350℃时,还原产物的电阻率随还原时间的延长而显著降低。在1350℃下还原50 min的产物的电阻率最小,为79.3Ω‧cm,其物相组成几乎全部为Ti_(3)O_(5)。 展开更多
关键词 碳热还原 筛分 magnéli相Ti_(n)O_(2n-1)电阻率 TiO_(2) 相变
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Magnéli相亚氧化钛电极的制备及应用 被引量:3
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作者 谭向东 邢心语 +3 位作者 王雪清 马传军 郭宏山 李宝忠 《现代化工》 CAS CSCD 北大核心 2023年第6期107-111,共5页
简要阐述了常规电催化氧化阳极材料及电催化氧化机理,归纳总结了Magnéli相亚氧化钛电极的性质及不同制备手段的优缺点。对近年来国内外Magnéli相亚氧化钛电极在电催化氧化处理新污染物废水的应用进行了综述,并从电极制备及性... 简要阐述了常规电催化氧化阳极材料及电催化氧化机理,归纳总结了Magnéli相亚氧化钛电极的性质及不同制备手段的优缺点。对近年来国内外Magnéli相亚氧化钛电极在电催化氧化处理新污染物废水的应用进行了综述,并从电极制备及性质上进行了分析,对Magnéli相亚氧化钛电极的应用前景和发展方向进行了展望。 展开更多
关键词 电催化氧化 阳极 magnéli相 亚氧化钛电极 新污染物
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Screening on Chemicals for Preventing Mycogone peniciosa Magn in Agaricus bisporus 被引量:1
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作者 Fan Jianqi Wang Haiping +1 位作者 Xiong Ying He Wenhui 《Plant Diseases and Pests》 CAS 2013年第2期12-14,21,共4页
[ Objective ] The aim was to screen out chemicals with good control effect against Mycogone peniciosa Magn in Agaricus bisporus. [ Method ] M. peniciosa ofA. b/sporus was taken as the detection bacteria, and nine kind... [ Objective ] The aim was to screen out chemicals with good control effect against Mycogone peniciosa Magn in Agaricus bisporus. [ Method ] M. peniciosa ofA. b/sporus was taken as the detection bacteria, and nine kinds of chemicals were conducted plate efficacy test in the laboratory. Mushroom house validation was carried out for the screened chemicals with strong inhibition to M. peniciosa. [ Result] Nine kinds of chemicals had obvious difference in control effects on M. peniciosa and effects on growth ofA. bisporus; 2 400 and 3 200 times dilution of 78% Boer MZ WP and 2 400 times dilution of 69% Fulishuang WP after casing material processing had good control effects on M. peniciosa and had no apparent adverse effects on mycelial growth and fruiting development of A. bisporus. [ Conclusion] The 2 400 and 3 200 times dilution of 78% Boer MZ WP and 2 400 times dilution of 69% Fulishuang WP are worth popularizing. 展开更多
关键词 Agaricus bisporus Mycogone peniciosa magn CHEMICALS SCREENING
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Magneli phase titanium sub-oxide conductive ceramic Ti_nO_(2n-1) as support for electrocatalyst toward oxygen reduction reaction with high activity and stability 被引量:3
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作者 伍秋美 阮建明 +1 位作者 周忠诚 桑商斌 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第4期1212-1219,共8页
Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-... Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-reduction method. The electrochemical stability of Tin O2n-1 was investigated and the results show almost no change in the redox region after oxidation for 20 h at 1.2 V(vs NHE) in 0.5 mol/L H2SO4 aqueous solution. The catalytic activity and stability of the Pt/Tin O2n-1 toward the oxygen reduction reaction(ORR) in 0.5 mol/L H2SO4 solution were investigated through the accelerated aging tests(AAT), and the morphology of the catalysts before and after the AAT was observed by transmission electron microscopy. At the potential of 0.55 V(vs SCE), the specific kinetic current density of the ORR on the Pt/Tin O2n-1 is about 1.5 times that of the Pt/C. The LSV curves for the Pt/C shift negatively obviously with the half-wave potential shifting about 0.02 V after 8000 cycles AAT, while no obvious change takes place for the LSV curves for the Pt/Tin O2n-1. The Pt particles supported on the carbon aggregate obviously, while the morphology of the Pt supported on Tin O2n-1 remains almost unchanged, which contributes to the electrochemical surface area loss of Pt/C being about 2times that of the Pt/Tin O2n-1. The superior catalytic stability of Pt/Tin O2n-1 toward the ORR could be attributed to the excellent stability of the Tin O2n-1 and the electronic interaction between the metals and the support. 展开更多
关键词 magneli phase TinO2n-1 support oxygen reduction reaction stability
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络合态金属铜在大型水蚤(Daphnia magna)体内的生物积累及生物毒性 被引量:2
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作者 史志伟 范文宏 +1 位作者 曾小岚 段勇 《环境化学》 CAS CSCD 北大核心 2010年第1期53-57,共5页
以人工稀释水作为背景水样,通过实验室暴露和化学平衡软件的辅助分析,研究了4种有机络合剂(草酸、酒石酸、EDTA和腐殖酸)对大型水蚤(Daphniamagna)体内铜的生物积累(BBD)以及生物毒性的影响.结果表明,有机络合剂的存在降低了大型水蚤体... 以人工稀释水作为背景水样,通过实验室暴露和化学平衡软件的辅助分析,研究了4种有机络合剂(草酸、酒石酸、EDTA和腐殖酸)对大型水蚤(Daphniamagna)体内铜的生物积累(BBD)以及生物毒性的影响.结果表明,有机络合剂的存在降低了大型水蚤体内生物积累量和金属硫蛋白(MT)含量,明显降低了水体中金属Cu的毒性,4种不同有机络合剂所产生的效果大体相同;有机络合态的铜也能为大型水蚤所吸收和利用,在相同浓度条件下大型水蚤对腐殖酸络合态铜的利用大于EDTA络合态铜. 展开更多
关键词 大型水蚤 络合态铜 生物积累 生物毒性 生物可利用性
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Diagnosing coronary microvascular dysfunction in patients with non-obstructive coronary artery disease by stress cardiac magnetic resonance
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作者 Pengyu Zhou Xiuyu Chen Shihua Zhao 《Chinese Medical Journal》 2025年第5期601-603,共3页
To the Editor:More than half of the patients undergoing invasive coronary angiography for angina or signs of myocardial ischemia present with non-obstructive coronary arteries(NOCA,<50%diameter reduction or fractio... To the Editor:More than half of the patients undergoing invasive coronary angiography for angina or signs of myocardial ischemia present with non-obstructive coronary arteries(NOCA,<50%diameter reduction or fractional flow reserve>0.80).[1]Coronary microvascular dysfunction(CMD)is a significant pathophysiological factor in these patients and is linked to adverse outcomes.[2]Although coronary reactivity testing(CRT)remains the gold standard for diagnosing CMD,it is both invasive and costly.Stress cardiac magnetic resonance(CMR)is a non-invasive and promising alternative,providing essential perfusion parameters such as myocardial perfusion reserve index(MPRI)and myocardial perfusion reserve(MPR)to diagnose CMD.Thus,based on current literature,there is robust evidence supporting the effectiveness of stress CMR in diagnosing CMD in patients with NOCA,as defined by CRT. 展开更多
关键词 myocardial perfusion reserve index coronary reactivity testing crt remains coronary microvascular dysfunction invasive coronary angiography myocardial ischemia microvascular dysfunction cmd cardiac magne stress cardiac magnetic resonance
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Mo含量对CrAlMoN涂层微观结构、力学性能及摩擦学性能的影响 被引量:1
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作者 毕健浩男 张艳 +4 位作者 王振玉 周晟昊 刘永跃 张小岩 汪爱英 《金属学报》 北大核心 2025年第9期1413-1424,共12页
CrAlN涂层因具有硬度高、热稳定性和抗氧化性能良好等特点,在模具防护方向备受关注。然而,在铝合金压铸和热冲压模具严苛工况下,涂层的摩擦系数高、抗冲击韧性差,从而严重限制了其应用。本工作基于多元合金设计与高通量制备思路,采用受... CrAlN涂层因具有硬度高、热稳定性和抗氧化性能良好等特点,在模具防护方向备受关注。然而,在铝合金压铸和热冲压模具严苛工况下,涂层的摩擦系数高、抗冲击韧性差,从而严重限制了其应用。本工作基于多元合金设计与高通量制备思路,采用受控阴极真空电弧复合技术在H13钢材基底表面制备了CrAlMoN涂层,研究了Mo含量对涂层的微观结构、力学性能和摩擦学性能的影响。利用XRD、SEM、EDS和SEM表征了涂层的相结构、表/截面形貌及元素分布,利用划痕仪和纳米压痕仪分析了涂层的硬度、膜基结合力和韧性等力学性能,利用摩擦试验机研究了涂层在大气环境下的摩擦学性能。结果表明,当Mo的原子分数从0.72%增加到19.47%时,掺杂Mo主要以固溶形式存在于(Cr,Al)N晶体结构中且伴有少量Mo_(2)N相生成。其中,当Mo含量为2.55%时,涂层的硬度和弹性模量最高,分别为(38.7±1.3)和(580.9±11.1)GPa,且涂层抗裂纹产生及扩展能力强,呈现高强韧特征。由于Mo掺杂利于生成Magnéli相氧化物MoO_(3),涂层耐摩擦性能优异,摩擦系数和磨损率分别在0.32~0.51和(5.90~10.88)×10^(-7)mm^(3)/(N·m)之间。当Mo含量达到19.47%时,涂层的摩擦系数最低(0.31),磨损率为5.90×10^(-7)mm^(3)/(N·m)。微结构分析表明,涂层磨损失效主要源于磨粒磨损、氧化磨损与局域点状剥落。 展开更多
关键词 CrAlMoN固溶涂层 高通量制备 高强韧 magnéli润滑相 耐磨损性能
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