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Alpha-decay properties of nuclei around neutron magic numbers
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作者 Ming Li Chu-Xin Chen +3 位作者 Lan-Fang Xiao Yi Zhang Song Luo Xiao-Hua Li 《Nuclear Science and Techniques》 2025年第1期140-149,共10页
By combining experimental α-decay energies and half-lives, the α-particle preformation factor for nuclei around neutron magic numbers N of 126, 152, and 162 were extracted using the two-potential approach. The nucle... By combining experimental α-decay energies and half-lives, the α-particle preformation factor for nuclei around neutron magic numbers N of 126, 152, and 162 were extracted using the two-potential approach. The nuclei around the shell closure were more tightly bound than adjacent nuclei. Additionally, based on the WS4 mass model (Wang et al., Phys. Lett.B 734, 215 (2014)), we extended the two-potential approach to predict the α-decay half-lives of nuclei around N values of178 and 184 with Z of 119 and 120. We believe that our findings will serve as guidelines for future experimental studies. 展开更多
关键词 adecay Preformation factor Neutron magic number Heavy and superheavy nuclei
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基于WAT Analyzer软件的阈值电压计算及magic number测定
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作者 吴振华 刘鉴常 +1 位作者 付宇卓 俞晓华 《实验室研究与探索》 CAS 北大核心 2009年第9期33-35,87,共4页
阈值电压是半导体晶圆测试的一个重要指标,它和半导器件参数等许多方面有紧密的联系,magic number(N)是一个基于线度计算阈值电压经验公式的关键值。基于自主研发的WAT Analyzer软件对相关实测数据处理,对比根据实测数据用跨导法计算阈... 阈值电压是半导体晶圆测试的一个重要指标,它和半导器件参数等许多方面有紧密的联系,magic number(N)是一个基于线度计算阈值电压经验公式的关键值。基于自主研发的WAT Analyzer软件对相关实测数据处理,对比根据实测数据用跨导法计算阈值电压的结果,经统计分析提出了一个N的新值。通过实测数据进行检验,验证了N值的有效性。 展开更多
关键词 晶圆 WAT 阈值电压 magicnumber
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A Suggestion Complementing the Magic Numbers Interpretation of the Nuclear Fission Phenomena
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作者 Faustino Menegus 《World Journal of Nuclear Science and Technology》 2018年第1期11-22,共12页
Ideas, solely related on the nuclear shell model, fail to give an interpretation of the experimental central role of 54Xe in the asymmetric fission of actinides. The same is true for the &beta;-delayed fission of ... Ideas, solely related on the nuclear shell model, fail to give an interpretation of the experimental central role of 54Xe in the asymmetric fission of actinides. The same is true for the &beta;-delayed fission of 180Tl to 80Kr and 100Ru. The representation of the natural isotopes, in the Z-Neutron Excess plane, suggests the importance of the of the Neutron Excess evolution mode in the fragments of the asymmetric actinide fission and in the fragments of the &beta;-delayed fission of 180Tl. The evolution mode of the Neutron Excess, hinged at Kr and Xe, is directed by the 50 and 82 neutron magic numbers. The present isotope representation offers a frame for the interpretation of the post fission evaporation of neutrons, higher for the AL compared to the AH fragments, a tenet in nuclear fission. Further enlightened is the functional meaning of the 50 proton magic number, marking the start of the yield rise of the AH fragments in actinide fission. 展开更多
关键词 Nuclear Structure Neutron EXCESS magic numberS Isotons Binding Energy Kr XE ACTINIDES
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Direct mass measurements of neutron-rich ^(86)Kr projectile fragments and the persistence of neutron magic number N=32 in Sc isotopes 被引量:3
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作者 徐星 王猛 +31 位作者 张玉虎 徐瑚珊 帅鹏 涂小林 Yuri A.Litvinov 周小红 孙保华 原有进 夏佳文 杨建成 Klaus Blaum 陈瑞九 陈相成 付超义 葛壮 胡正国 黄文嘉 刘大委 蓝乙华 马新文 毛瑞士 T.Uesaka 肖国青 邢元明 T.Yamaguchi Y.Yamaguchi 曾奇 颜鑫亮 赵红卫 赵铁成 章卫 詹文龙 《Chinese Physics C》 SCIE CAS CSCD 2015年第10期24-28,共5页
In this paper, we present direct mass measurements of neutron-rich S6Kr projectile fragments conducted at the HIRFL-CSR facility in Lanzhou by employing the Isochronous Mass Spectrometry (IMS) method. The new mass e... In this paper, we present direct mass measurements of neutron-rich S6Kr projectile fragments conducted at the HIRFL-CSR facility in Lanzhou by employing the Isochronous Mass Spectrometry (IMS) method. The new mass excesses of ^52-54Sc nuclides are determined to be -40492(82), -38928(114), -34654(540) keV, which show a significant increase of binding energy compared to the reported ones in the Atomic Mass Evaluation 2012 (AME12). In particular, ^53Sc and ^54sc are more bound by 0.8 MeV and 1.0 MeV, respectively. The behavior of the two neutron separation energy with neutron numbers indicates a strong sub-shell closure at neutron number N=32 in Sc isotopes. 展开更多
关键词 isochronous mass spectrometry exotic nuclei mass excess new magic number
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Islands of stability and quasi-magic numbers for super- and ultra-heavy nuclei 被引量:1
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作者 M.Ismail A.Y.Ellithi +1 位作者 A.Adel Hisham Anwer 《Chinese Physics C》 SCIE CAS CSCD 2016年第12期69-90,共22页
In the framework of Strutinsky's approach, we calculated the shell and the residual pairing correction energies for 5569 even-even nuclei in the range 72 ≤ Z ≤ 282 and 96≤N ≤ 540. Quasi-magic numbers and deformed... In the framework of Strutinsky's approach, we calculated the shell and the residual pairing correction energies for 5569 even-even nuclei in the range 72 ≤ Z ≤ 282 and 96≤N ≤ 540. Quasi-magic numbers and deformed islands of stability that reside in a range defined by Green's formula and the two-neutrons drip line are introduced. We present 36 quasi-magic proton and 53 quasi-magic neutron magic numbers that contribute to the formation of 133 deformed islands of stability along the N-Z space. The quasi-magic proton and neutron magic numbers volatile as the mass number increases and other magic numbers take over. Consequently, the deformed islands of stability fail to exhibit a pattern along the search space covered. 展开更多
关键词 deformed nuclei islands of stability magic numbers
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Metallic Softness Influence on Magic Numbers of Clusters
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作者 Liu Hao-yang Zou Xian-wu +1 位作者 Ren Da-zhi Jin Zhun-zhi 《Wuhan University Journal of Natural Sciences》 EI CAS 2000年第3期301-306,共6页
The metallic softness parameterαr 0 determines the structure of the cluster and governs the rule of magic numbers. Using molecular dynamic method, the stable structures and magic numbers are determined for the cluste... The metallic softness parameterαr 0 determines the structure of the cluster and governs the rule of magic numbers. Using molecular dynamic method, the stable structures and magic numbers are determined for the clusters consisting of 13 up to 147 atoms in medium range Morse potentials, which is suitable for most of metals. As the number of atoms constituting the cluster increases, the stable structures undergo transition from face-centered (FC) to edge-centered (EC) structures. The magic number take ones of FC series before transition and take ones of EC series after that. The transition point from FC to EC structures depends on the value of softness parameter. 展开更多
关键词 CLUSTER magic number SOFTNESS
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Formation of Al^(+)(C_(6)H_(6))_(13):The Origin of Magic Number in Metal-Benzene Clusters Determined by the Nature of the Core
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作者 Hanyu Zhang Arthur C.Reber +5 位作者 Lijun Geng Daniel Rabayda Haiming Wu Zhixun Luo Jiannian Yao Shiv N.Khanna 《CCS Chemistry》 CAS 2019年第5期571-581,共11页
The identification of highly abundant,“magic”spe-cies in the mass spectra of clusters have proven to be valuable in nanoscience,leading to the discovery of new stable species such as fullerenes and the elec-tronic s... The identification of highly abundant,“magic”spe-cies in the mass spectra of clusters have proven to be valuable in nanoscience,leading to the discovery of new stable species such as fullerenes and the elec-tronic shell structures of metallic clusters. 展开更多
关键词 magic number benzene cluster noncova-lent interaction Al^(+)(C_(6)H_(6))_(13)
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Size distributions and magic number characteristics of cluster configurations formed during solidification processes of liquid metal Al 被引量:2
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作者 LIU Rangsu1, LIU Fengxiang1, DONG Kejun1, ZHENG Caixing1, LIU Hairong2, PENG Ping2 & LI Jiyong3 1. Department of Physics, Hunan University, Changsha 410082, China 2. Department of Material Science and Engineering, Hunan University, Changsha 410082, China 3. Department of Chemistry, Hunan University, Changsha 410082, China 《Science China(Technological Sciences)》 SCIE EI CAS 2006年第2期172-187,共16页
A molecular dynamics simulation study has been performed for a large systemconsisting of 100000 liquid metal Al atoms to investigate the formation and magic numbercharacteristics of the cluster configurations formed d... A molecular dynamics simulation study has been performed for a large systemconsisting of 100000 liquid metal Al atoms to investigate the formation and magic numbercharacteristics of the cluster configurations formed during the rapid solidification processes. Thecluster-type index method (CTIM) has been adopted to describe various types of clusterconfigurations. The results indicate that the icosahedral clusters (12 0 12 0) and theircombinations play the most important role in the rnicrostructure transitions during solidificationprocesses; for the cluster configurations of different levels formed by various combinations withdiffering numbers of basic clusters, their size distributions possess obvious magic number sequencewhich is in turn as 13(13), 19(21), 26-28(27), 32-33(32), 39-40, 43-44, 48..., (those in bracket arethe corresponding value in liquid state); the magic numbers correspond to the peak value positionsof the cluster numbers for corresponding level formed with various combinations by 1, 2, 3, 4, 5, 6,7, ...basic clusters, respectively. This magic number sequence is in good agreement with theexperimental results obtained by Harris et al. At the same time, this simulation study also gives ascientific and reasonable explanation to these experimental results. 展开更多
关键词 liquid metal SOLIDIFICATION processes CLUSTER configuration magic numbers computer simulation.
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Optical-Focused Fresnel Lens for Generating Electricity Output Using Multiple Layers of Heated Disks with Water as a Medium
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作者 Hung-Te Henry Su Po-Han Lee 《Journal of Environmental Science and Engineering(B)》 2025年第2期76-80,共5页
Concentrated solar thermal power generation has been experimentally tested in advanced countries for a period of time.This paper demonstrates how this technology can be improved by using water molecules as a medium to... Concentrated solar thermal power generation has been experimentally tested in advanced countries for a period of time.This paper demonstrates how this technology can be improved by using water molecules as a medium to drive traditional generator sets for energy conversion,thereby simultaneously improving the energy conversion rate.Additionally,a novel contribution is made by incorporating a magic number 4 to enhance the focusing efficiency of Fresnel lenses,which drives improvements in power generation output and QE(Quantum Efficiency). 展开更多
关键词 Energy conversion rate Fresnel lens generator sets solar power volume factors magic number 4 QE
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Properties of the drip-line nucleus and mass relation of mirror nuclei
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作者 Meng-Ting Wan Li Ou +1 位作者 Min Liu Ning Wang 《Nuclear Science and Techniques》 2025年第2期112-122,共11页
The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb e... The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb energy heightened by an aug-mented charge could not be mitigated completely by symmetry energy because of isospin asymmetry saturation but is resisted complementally by strong nuclear deformation.The positions of saltation for the difference in proton numbers between two neighboring nuclei at the neutron drip line,and the isospin asymmetry of the neutron drip-line nucleus as a function of the neutron number distinctly correspond to the known magic numbers,which can serve as a reference to verify the undeter-mined neutron magic number.Through fitting of the binding energy difference between mirror nuclei(BEDbMN),a set of Coulomb energy coefficients with greater accuracy is obtained.A high-precision description of the BEDbMN is useful for accurately determining the experimentally unknown mass of the nucleus close to the proton drip line if the mass of its mirror nucleus is measured experimentally. 展开更多
关键词 Nuclear mass formula Drip-line nucleus magic number Mirror nuclei Coulomb energy
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Nuclear deformation effects on α‑decay half‑lives with empirical formula and machine learning
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作者 Hong‑Qiang You Xiao‑Tao He +4 位作者 Ren‑Hang Wu Shuang‑Shuang Zhang Jing‑Jing Li Qing‑Hua He Hai‑Qian Zhang 《Nuclear Science and Techniques》 2025年第10期145-158,共14页
An improved formula considering the deformation effect for the α-decay half-lives is proposed based on WKB barrier penetrability.Using the quadrupole deformation values of the daughter nuclei obtained from the WS4 an... An improved formula considering the deformation effect for the α-decay half-lives is proposed based on WKB barrier penetrability.Using the quadrupole deformation values of the daughter nuclei obtained from the WS4 and FRDM models in the improved formula,the root mean square deviation(RMSD)between the calculated results and experimental data decreased from 0.456 to 0.413 and 0.415,respectively.Although the improved formula did not significantly reduce the overall RMSD,it produced results that better matched the experimental values for nuclei with larger deformations.Additionally,eXtreme Gradient Boosting(XGBoost)models were employed to further reduce the deviations between the calculated α-decay half-lives and experimental data,with the corresponding RMSDs decreasing from 0.413 to 0.295 and from 0.415 to 0.302,respectively.Furthermore,the improved empirical formula and XGBoost models were used to predict the α-decay half-lives of nuclei with Z=117,118,119,and 120.The results suggest that N=184 is the magic number. 展开更多
关键词 Α-DECAY Nuclear deformation effects magic numbers Superheavy nuclei
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基于MLP神经网络优化改进的BW模型 被引量:4
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作者 陈存宇 陈爱喜 +1 位作者 戚晓秋 王韩奎 《物理学报》 北大核心 2025年第1期114-124,共11页
神经网络具有强大的建模能力和对大规模数据的适应性,在拟合核质量模型参数方面表现出显著效果.本研究旨在探索神经网络拟合核质量模型参数的问题:采用多层感知机(multilayer perceptron,MLP)神经网络结构,评估不同参数下Adam优化器的... 神经网络具有强大的建模能力和对大规模数据的适应性,在拟合核质量模型参数方面表现出显著效果.本研究旨在探索神经网络拟合核质量模型参数的问题:采用多层感知机(multilayer perceptron,MLP)神经网络结构,评估不同参数下Adam优化器的训练效果,训练出准确的模型参数.研究发现,基于AME2020数据,更新系数后的BW2核质量模型在双幻数以及重核区域的均方根误差降低明显;BW3模型重新拟合后的全局均方根误差为1.63 MeV,较之前1.86 MeV有所降低.结果表明,该方法能够有效地拟合模型参数,并具有良好的拟合性能和泛化能力.这项研究为BW系列核质量模型的系数提供了新的拟合方法,也为其他核质量寻求最佳拟合参数提供了有益的参考. 展开更多
关键词 核质量模型 幻数 MLP神经网络 Adam优化器
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中等质量核形状共存与壳效应研究
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作者 刘冬 郭建友 《物理学报》 北大核心 2025年第11期165-172,共8页
对原子核形状共存和壳效应的研究有助于人们深入理解原子核内部结构.物理学家们在Zn,Ge,Se,Kr的同位素研究中,发现了显著的形状共存现象与刚性三轴性特征.为了深入探究形状共存现象及其对原子核基态性质的影响,我们采用相对论Hartree-Bo... 对原子核形状共存和壳效应的研究有助于人们深入理解原子核内部结构.物理学家们在Zn,Ge,Se,Kr的同位素研究中,发现了显著的形状共存现象与刚性三轴性特征.为了深入探究形状共存现象及其对原子核基态性质的影响,我们采用相对论Hartree-Bogoliubov理论中密度依赖的介子交换模型,对N=32—42的偶偶核Zn,Ge,Se,Kr同位素的基态性质进行了系统研究,获得的势能面清晰地展现了这些同位素存在形状共存和三轴性特征.计算获得了原子核的基态能量、形变参数、双中子分离能、中子半径、质子半径和电荷半径,结果都支持N=40为新幻数,部分结果也支持N=32,34为新幻数.尤其,三轴形变在其中扮演着重要角色.进一步,我们探讨了壳效应与形状共存现象之间可能存在的关联及其对原子核基态性质的影响,并分析了这些变化的物理机制. 展开更多
关键词 形状共存 壳效应 新幻数
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核素丰度的统计规律
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作者 隆寅 彭金松 《科学技术创新》 2024年第21期59-62,共4页
核素丰度是指核素在自然界中含量的丰富程度,其大小是核素稳定性的一个重要标志。本文从国际原子能机构核数据中心Nudat3.0库中收集了287个核素的丰度实验数据,进行统计分析,发现当核子数为幻数时,稳定核素的数目大多都比邻近元素多,而... 核素丰度是指核素在自然界中含量的丰富程度,其大小是核素稳定性的一个重要标志。本文从国际原子能机构核数据中心Nudat3.0库中收集了287个核素的丰度实验数据,进行统计分析,发现当核子数为幻数时,稳定核素的数目大多都比邻近元素多,而且幻数核的丰度普遍都比较高,说明了幻数核的稳定性高。 展开更多
关键词 核素 丰度 幻数
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原子核氘核结合能与幻数关联的统计规律
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作者 隆寅 《大众科学》 2024年第13期100-102,共3页
原子核结合能的大小是原子核稳定性的标志之一。根据国际原子能机构(IAEA)发布的原子质量评估(AME)中的原子质量数据,计算了原子核的结合能和原子核氘核的结合能,发现核子数A较大的原子核结合能也越大。当核子数为20、28、50、82、126... 原子核结合能的大小是原子核稳定性的标志之一。根据国际原子能机构(IAEA)发布的原子质量评估(AME)中的原子质量数据,计算了原子核的结合能和原子核氘核的结合能,发现核子数A较大的原子核结合能也越大。当核子数为20、28、50、82、126这些幻数时,原子核氘核结合能比附近核素的结合能都大,从而证实了幻数的存在。 展开更多
关键词 原子核 氘核结合能 原子 质量
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液态金属Al凝固过程中的团簇结构与幻数特性 被引量:8
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作者 刘让苏 刘凤翔 +4 位作者 董科军 郑采星 刘海蓉 彭平 李基永 《物理化学学报》 SCIE CAS CSCD 北大核心 2004年第9期1093-1098,共6页
采用分子动力学方法,对含有100000个Al原子的液态金属系统在凝固过程中团簇结构的形成特性进行了模拟研究,并采用原子团类型指数法(CTIM)来描述各种类型的团簇结构组态.研究结果显示:在液态金属Al的凝固过程中,只有与1551键型相关的二... 采用分子动力学方法,对含有100000个Al原子的液态金属系统在凝固过程中团簇结构的形成特性进行了模拟研究,并采用原子团类型指数法(CTIM)来描述各种类型的团簇结构组态.研究结果显示:在液态金属Al的凝固过程中,只有与1551键型相关的二十面体原子团(120120)及其组合形成的各种团簇结构,对微结构的演变起着关键的、决定性的作用;由不同数目、不同类型基本原子团组成的各种层次的团簇结构,都在一定的原子数区段内呈现出峰值,即幻数点;系统的幻数序列为:13(13),19(21),25~28(27),31~33(29~30),37、39,…(括号内为液态时对应的幻数值),与Harris等人的实验结果甚为相符.本模拟研究所用的团簇结构按层次区段来研究幻数序列的方法,可为实验结果提供更为合理的模型解释. 展开更多
关键词 液态金属 铝凝固 团簇结构 幻数特性 分子动力学 计算机模拟
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硅氧团簇(SiO_2)_nO_2H_4的密度泛函理论研究 被引量:6
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作者 徐灿 朱莉芳 +1 位作者 高晨阳 曹娟 《物理化学学报》 SCIE CAS CSCD 北大核心 2006年第2期152-155,共4页
提出硅氧团簇(SiO2)nO2H4的两种新构型:基于笼状结构和环状结构的构型,并与链状构型相比较,用密度泛函理论的B3LYP方法在6-31G(d)基组水平上计算了三种构型n=2~22(n取偶数)的几何结构、平均结合能、能隙以及能量的二次差分.分析计算结... 提出硅氧团簇(SiO2)nO2H4的两种新构型:基于笼状结构和环状结构的构型,并与链状构型相比较,用密度泛函理论的B3LYP方法在6-31G(d)基组水平上计算了三种构型n=2~22(n取偶数)的几何结构、平均结合能、能隙以及能量的二次差分.分析计算结果发现,笼状构型不但在n=4和8处存在幻数团簇(实验上已经观察到),而且预测在n=14处也存在类似的幻数团簇;此外,与(SiO2)n团簇不同的是,(SiO2)nO2H4团簇的环状构型的稳定性从n=4开始大于链状构型,意味着水的加成对硅氧团簇的稳定性有着重要的影响. 展开更多
关键词 团簇 幻数 密度泛函理论 结构 机理
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乙醇-水分子团簇C_2H_5OH(H_2O)_n(n=1-9)稳定结构的量子化学研究 被引量:11
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作者 韩光占 张超 +1 位作者 高吉刚 钱萍 《物理化学学报》 SCIE CAS CSCD 北大核心 2011年第6期1361-1371,共11页
采用密度泛函理论B3LYP方法,在B3LYP/6-311++G(2d,2p)//B3LYP/6-311++G(d,p)基组水平上对乙醇-水分子团簇(C2H5OH(H2O)n(n=1-9))的各种性质进行研究,如:优化的几何构型、结构参数、氢键、结合能、平均氢键强度、自然键轨道(NBO)电荷分... 采用密度泛函理论B3LYP方法,在B3LYP/6-311++G(2d,2p)//B3LYP/6-311++G(d,p)基组水平上对乙醇-水分子团簇(C2H5OH(H2O)n(n=1-9))的各种性质进行研究,如:优化的几何构型、结构参数、氢键、结合能、平均氢键强度、自然键轨道(NBO)电荷分布、团簇的生长规律等.结果表明,从二维(2-D)环状结构到三维(3-D)笼状结构的过渡出现在n=5的乙醇-水分子团簇中.此外,利用团簇结合能的二阶差分、形成能、能隙等性质,发现在n=6时乙醇-水分子团簇的最低能量结构稳定性较好,可能为幻数结构.最后,为了进一步探讨氢键本质,将C2H5OH(H2O)n(n=2-9)最低能量结构的各种性质与纯水分子团簇(H2O)n(n=3-10)比较,结果表明前者与后者中的水分子之间氢键相似. 展开更多
关键词 密度泛函理论 乙醇-水分子团簇 氢键 幻数
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THF/H_2O二元团簇中“幻数”现象研究 被引量:3
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作者 石土金 王栩 +4 位作者 杨达林 朱起鹤 盛六四 武国华 张允武 《化学学报》 SCIE CAS CSCD 北大核心 2000年第9期1107-1111,共5页
利用分子束、同步辐射光源和飞行时间质谱研究了THF/H_2O二元团簇体系,观察到一系列组成为(THF)_n·(H_2O)_mH^+(n=2~5,m=0~n-1)离子峰,其中(THF)_n(H_2O)_(n-2)H^+(n=2~5)离子峰强为“幻数”峰.运用从头算(ab initio)分子轨道法... 利用分子束、同步辐射光源和飞行时间质谱研究了THF/H_2O二元团簇体系,观察到一系列组成为(THF)_n·(H_2O)_mH^+(n=2~5,m=0~n-1)离子峰,其中(THF)_n(H_2O)_(n-2)H^+(n=2~5)离子峰强为“幻数”峰.运用从头算(ab initio)分子轨道法,在HF/3-21G基组水平上对(THF)_n(H_2O)_(n-2)H^+(n=2~4)团簇几何构型进行了优化,计算结果表明团簇离子(THF)_n(H_2O)_(n-2)H^+具有较大的稳定性,解释了实验中观察到的“幻数”现象. 展开更多
关键词 同步辐射光源 四氢呋喃 “幻数” 二元团簇
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乙醇/水混合团簇的多光子电离质谱研究 被引量:4
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作者 姜素蓉 张树东 +2 位作者 孔祥和 许明坤 蔡廷栋 《激光杂志》 CAS CSCD 北大核心 2007年第1期29-30,共2页
利用激光器(输出波长355nm)激发乙醇和水二元混合团簇中的离子-分子反应,运用飞行时间质谱技术检测反应后生成的团簇离子。实验观测到多个序列的质子化团簇离子:(C2H5OH)nH+和(C2H5OH)n(H2O)mH+(n=1-12,m=1-4),其产生是通过团簇内的质... 利用激光器(输出波长355nm)激发乙醇和水二元混合团簇中的离子-分子反应,运用飞行时间质谱技术检测反应后生成的团簇离子。实验观测到多个序列的质子化团簇离子:(C2H5OH)nH+和(C2H5OH)n(H2O)mH+(n=1-12,m=1-4),其产生是通过团簇内的质子转移反应。通过对团簇离子的峰强度同乙醇数目n和水分子数目m的关系的研究发现,团簇离子(C2H5OH)8(H2O)H+是幻数结构。 展开更多
关键词 氢键团簇 质子化团簇离子 质子转移 信号强度 幻数
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