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基于电射流打印的Ti_(3)C_(2)MXene基柔性气体传感器的制备及其性能研究
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作者 王云帆 孙蕾 +3 位作者 王春静 张鹏亚 焦泽霖 张文磊 《化工新型材料》 北大核心 2026年第1期151-155,160,共6页
传统气体传感器加载敏感材料多采用电极表面直接滴涂方式,该方法存在材料加载量难以精确控制、重复性差等问题。为解决上述问题开发了基于电射流打印制备柔性气体传感器的新方法,自主搭建了低成本电射流打印装置,配制了以Ti_(3)C_(2)MX... 传统气体传感器加载敏感材料多采用电极表面直接滴涂方式,该方法存在材料加载量难以精确控制、重复性差等问题。为解决上述问题开发了基于电射流打印制备柔性气体传感器的新方法,自主搭建了低成本电射流打印装置,配制了以Ti_(3)C_(2)MXene材料为基础的功能墨水,讨论了打印条件对Ti_(3)C_(2)MXene基功能墨水打印图形尺寸的影响。在Ti_(3)C_(2)MXene功能墨水中加入气敏材料In_(2)O_(3),在聚对苯二甲酸乙二醇酯柔性叉指电极上通过电射流打印制备了柔性气体传感器并测试了其灵敏度。结果表明:采用0.3%Ti_(3)C_(2)MXene/7%PEO(聚氧化乙烯)溶液作为电射流打印的功能墨水,可以保证在开启电压较小的同时形成分辨率较高的图形;在施加电压2500V,打印距离1mm,注射泵流速300nL/min,基板移动速度300mm/min的锥射流打印条件下,沉积的图形规整有序、直径均匀,尺寸为(2.56±0.32)μm;柔性气体传感器灵敏度较高。 展开更多
关键词 Ti_(3)C_(2)mxene 功能墨水 电射流打印 可控加载 气体传感器
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MXene基材料修复骨缺损的临床应用与前景
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作者 王亮 张鑫 +1 位作者 何维 王剑 《中国组织工程研究》 北大核心 2026年第20期5282-5294,共13页
背景:近年来,MXene及其衍生物因良好的生物相容性、生物可降解性、高光热转换能力以及内在的抗菌和成骨能力等特性,在骨缺损修复领域展现出较大的应用前景。目的:阐述MXene的生物医学特性,总结MXene基材料在修复骨缺损方面的研究应用进... 背景:近年来,MXene及其衍生物因良好的生物相容性、生物可降解性、高光热转换能力以及内在的抗菌和成骨能力等特性,在骨缺损修复领域展现出较大的应用前景。目的:阐述MXene的生物医学特性,总结MXene基材料在修复骨缺损方面的研究应用进展。方法:在PubMed、Web of Science、中国知网和万方数据库中检索2005-2025年发表的文献,英文检索词为“MXene,Bone defect,Bone repair,Bone Regeneration,Bone tissue engineering”,中文检索词为“MXene,骨缺损,骨修复,骨再生,骨组织工程”,经逐层筛选后最终纳入97篇文献进行综述。结果与结论:MXene具有良好的生物相容性、抗菌性、抗氧化和免疫调节性、光热性能和导电性能,将MXene引入骨组织工程支架的制备中可以赋予支架抗感染功能、免疫调节功能、增强的机械性能和促成骨能力。MXene作为引导骨再生膜材料有较大的应用潜力。MXene材料因具备优异的生物活性和抗菌性能是构建高性能植入物涂层的理想选择。MXene基3D打印墨水的成功制备为构建复杂结构的骨支架奠定了基础,MXene的优异性能赋予3D打印支架多重功能,使其在骨缺损修复中具备更广泛的应用前景。 展开更多
关键词 mxene 骨缺损 骨组织工程 骨修复 骨再生 骨缺损修复
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Bi_(2)O_(3)@MXene/碳毡的制备及电化学和电池性能
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作者 秦野 赵海东 王晶 《精细化工》 北大核心 2026年第1期116-124,共9页
为提升碳毡(CF)作为钒电池负极的电化学反应活性,将Ti_(3)AlC_(2)经氢氟酸刻蚀制备了MXene(Ti_(3)C_(2)T_(x));然后,通过溶剂热法在MXene层间和表面生长Bi_(2)O_(3)颗粒制备了Bi_(2)O_(3)@MXene;最后,采用浸渍拉伸法将其负载碳毡,制备了... 为提升碳毡(CF)作为钒电池负极的电化学反应活性,将Ti_(3)AlC_(2)经氢氟酸刻蚀制备了MXene(Ti_(3)C_(2)T_(x));然后,通过溶剂热法在MXene层间和表面生长Bi_(2)O_(3)颗粒制备了Bi_(2)O_(3)@MXene;最后,采用浸渍拉伸法将其负载碳毡,制备了Bi_(2)O_(3)@MXene/碳毡。采用XRD、SEM、XPS、BET、接触角测试仪对Bi_(2)O_(3)@MXene/碳毡进行了表征,通过电化学工作站和三电极体系对Bi_(2)O_(3)@MXene/碳毡的电化学性能进行了测试。评价了以碳毡为正极、Bi_(2)O_(3)@MXene/碳毡为负极组装的不对称钒电池(BMC-C电池)的充放电性能。结果表明,Bi_(2)O_(3)@MXene/碳毡的比表面积(4.93 m^(2)/g)比碳毡提升了63.7%,电解液的接触角(85.7°)比碳毡减小了44.7°。在400 mA/cm^(2)电流密度下,BMC-C电池能量效率达到了71.2%,在200 mA/cm^(2)的电流密度下连续充放电500圈循环后,其能量效率能够稳定在81%。BMC-C电池优异的性能主要归因于生长在MXene层间和表面的Bi_(2)O_(3)颗粒改善了电极的亲水性和比表面积,增加了反应活性位点,而层间的Bi_(2)O_(3)颗粒抑制了MXene结构的堆叠。 展开更多
关键词 钒电池 碳毡 负极 mxene 溶剂热法 功能材料
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MXene基复合材料在航空领域应用的研究进展
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作者 王士军 杨明 王雯嘉 《材料导报》 北大核心 2026年第1期27-35,共9页
作为一种新兴的二维纳米材料,MXene凭借其独特的理化特性,如高导电性、大比表面积、优异的亲水性和活性表面等,近年来被逐步应用于航空领域。本文首先介绍了MXene的主要制备方法,如氢氟酸刻蚀法、原位生成氢氟酸刻蚀法、熔融盐刻蚀法、... 作为一种新兴的二维纳米材料,MXene凭借其独特的理化特性,如高导电性、大比表面积、优异的亲水性和活性表面等,近年来被逐步应用于航空领域。本文首先介绍了MXene的主要制备方法,如氢氟酸刻蚀法、原位生成氢氟酸刻蚀法、熔融盐刻蚀法、电化学刻蚀法、碱刻蚀法等。其次,总结分析了MXene及其复合材料在航空领域用作电磁屏蔽材料、吸波材料、防/除冰材料、防雷击材料和传感材料等方面的研究成果。最后,对MXene在航空领域未来的发展方向和面临的主要挑战进行了展望。 展开更多
关键词 mxene 航空材料 纳米材料 制备方法
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MXene柔性电子传感器的优势及在糖尿病足创面监测中的应用
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作者 潘之怡 黄嘉雯 +1 位作者 薛文君 徐建达 《中国组织工程研究》 北大核心 2026年第8期2023-2032,共10页
背景:MXene材料具有良好的抗菌性、导电性、光热转换活性及生物相容性,可用于制备柔性电子传感器,在实时监测糖尿病足创面领域具有巨大的应用潜能。目的:综述基于MXene柔性电子传感器的优势及在糖尿病足创面监测中的应用现状与未来发展... 背景:MXene材料具有良好的抗菌性、导电性、光热转换活性及生物相容性,可用于制备柔性电子传感器,在实时监测糖尿病足创面领域具有巨大的应用潜能。目的:综述基于MXene柔性电子传感器的优势及在糖尿病足创面监测中的应用现状与未来发展前景。方法:检索PubMed数据库、Web of Science数据库、中国知网、万方数据库中已发表的相关文献,以“MXene,柔性电子传感器,糖尿病足,创面监测”为中文检索词,以“MXene,flexible electronic sensor,diabetic foot,wound detection”为英文检索词,最终纳入55篇文章进行综述分析。结果与结论:对于与创面预后息息相关的pH值、温度、尿酸、血糖、超氧化物阴离子、过氧化氢等生理参数,MXene柔性电子传感器呈现出实时监测能力,具有广阔的发展前景。根据MXene材料的固有特性,通过对传统柔性传感器进行创造性的表面改性,不仅能够赋予传感器良好的抗菌能力,还可提升传感器的综合性能,通过增强对病理信号变化的敏感度展现出更高的氧化还原电流响应,实现精确、稳定的动态监测。尽管MXene柔性电子传感器在糖尿病足创面监测中取得了较大进展,但目前大多数研究仍处于初始阶段,长期生物安全性及系统性验证有待深入研究。 展开更多
关键词 mxene 柔性电子传感器 生物传感器 糖尿病足 糖尿病 创面监测
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Correction:Self-Assembly of Binderless MXene Aerogel for Multiple-Scenario and Responsive Phase Change Composites with Ultrahigh Thermal Energy Storage Density and Exceptional Electromagnetic Interference Shielding
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作者 Chuanbiao Zhu Yurong Hao +8 位作者 Hao Wu Mengni Chen Bingqing Quan Shuang Liu Xinpeng Hu Shilong Liu Qinghong Ji Xiang Lu Jinping Qu 《Nano-Micro Letters》 2025年第5期256-262,共7页
Correction to:Nano-Micro Lett.(2024)16:57 https://doi.org/10.1007/s40820-023-01288-y.Following publication of the original article[1],the authors reported that the order of the images in Figs.5 and 6 were reversed,the... Correction to:Nano-Micro Lett.(2024)16:57 https://doi.org/10.1007/s40820-023-01288-y.Following publication of the original article[1],the authors reported that the order of the images in Figs.5 and 6 were reversed,the positions of the images needed to be exchanged.Another mistake is that the author inadvertently copied the same image in Fig.2(f)with Fig.2(e).The correct Figs.2,5 and 6 have been provided in this correction.The original article[1]has been updated。 展开更多
关键词 mxene reversed MISTAKE
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二维MXene膜在分离与净化领域的应用研究进展
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作者 赵兴雷 叶舣 +4 位作者 宁晨君 刘龙杰 范文琦 孙伟 薛明 《低碳化学与化工》 北大核心 2026年第1期87-97,共11页
MXene作为新型二维过渡金属碳化物/氮化物材料,凭借其独特的结构和丰富的表面官能团,在分离与净化领域展现出优异性能。结合有关理论及实验研究成果,介绍了MXene膜的后处理稳定性、电学性能和机械性能等物理化学特性,综述了MXene膜在气... MXene作为新型二维过渡金属碳化物/氮化物材料,凭借其独特的结构和丰富的表面官能团,在分离与净化领域展现出优异性能。结合有关理论及实验研究成果,介绍了MXene膜的后处理稳定性、电学性能和机械性能等物理化学特性,综述了MXene膜在气体分离与捕集、离子筛分、水体净化和有机溶剂纯化等领域的应用研究进展。尽管MXene膜在分离与净化领域展现出较大应用潜力,但仍面临稳定性、层间距调控、溶胀、界面兼容性、成本,以及环境安全等方面的挑战。未来研究需整合表面改性、结构设计和工艺优化等策略,同时探索低成本制备技术,并加强环境安全评估,促进MXene膜在更广泛领域的应用。 展开更多
关键词 膜分离 二维mxene 气体分离 离子筛分 水体净化 有机溶剂纯化
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Peak current reduction in presence of RF phase modulationin the dual RF system
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作者 Jiang Bocheng Zhang Yao Tsai Cheng-Ying 《强激光与粒子束》 北大核心 2026年第1期160-165,共6页
[Background]High harmonic cavities are widely used in electron storage rings to lengthen thebunch,lower the bunch peak current,thereby reducing the IBS effect,enhancing the Touschek lifetime,as well asproviding Landau... [Background]High harmonic cavities are widely used in electron storage rings to lengthen thebunch,lower the bunch peak current,thereby reducing the IBS effect,enhancing the Touschek lifetime,as well asproviding Landau damping,which is particularly important for storage rings operating with ultra-low emittance or atlow beam energy.[Purpose]To further increase the bunch length without additional hardware costs,the phasemodulation in a dual-RF system is considered.[Methods]In this paper,turn-by-turn simulations incorporating randomsynchrotron radiation excitation are conducted,and a brief analysis is presented to explain the bunch lengtheningmechanism.[Results]Simulation results reveal that the peak current can be further reduced,thereby mitigating IBSeffects and enhancing the Touschek lifetime.Although the energy spread increases,which tends to reduce thebrightness of higher-harmonic radiation from the undulator,the brightness of the fundamental harmonic can,in fact,beimproved. 展开更多
关键词 dual high-frequency system phase modulation beam bunch stretching intra-beam scattering
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Effect of Addition of Er-TiB_(2)Dual-Phase Nanoparticles on Strength-Ductility of Al-Mn-Mg-Sc-Zr Alloy Prepared by Laser Powder Bed Fusion
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作者 Li Suli Zhang Yanze +5 位作者 Yang Mengjia Zhang Longbo Xie Qidong Yang Laixia MaoFeng Chen Zhen 《稀有金属材料与工程》 北大核心 2026年第1期9-17,共9页
A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5w... A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5wt%Er-1wt%TiB_(2)/Al-Mn-Mg-Sc-Zr nanocomposite were prepared using vacuum homogenization technique,and the density of samples prepared through the LPBF process reached 99.8%.The strengthening and toughening mechanisms of Er-TiB_(2)were investigated.The results show that Al_(3)Er diffraction peaks are detected by X-ray diffraction analysis,and texture strength decreases according to electron backscatter diffraction results.The added Er and TiB_(2)nano-reinforcing phases act as heterogeneous nucleation sites during the LPBF forming process,hindering grain growth and effectively refining the grains.After incorporating the Er-TiB_(2)dual-phase nano-reinforcing phases,the tensile strength and elongation at break of the LPBF-deposited samples reach 550 MPa and 18.7%,which are 13.4%and 26.4%higher than those of the matrix material,respectively. 展开更多
关键词 Al-Mn-Mg-Sc-Zr alloy laser powder bed fusion nano-reinforcing phase synergistic enhancement
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CTA联合PHASES评分对颅内动脉瘤破裂出血预后的价值分析
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作者 张杰 鲁东 吕维富 《影像研究与医学应用》 2026年第2期17-21,共5页
目的:探讨头颈部CT血管造影(CTA)联合PHASES评分对颅内动脉瘤破裂导致动脉瘤性蛛网膜下腔出血(aSAH)预后的价值。方法:回顾性分析2022年1月—2024年10月在亳州市中医院接受诊疗的67例aSAH患者病例资料。根据格拉斯哥预后评分,将患者分... 目的:探讨头颈部CT血管造影(CTA)联合PHASES评分对颅内动脉瘤破裂导致动脉瘤性蛛网膜下腔出血(aSAH)预后的价值。方法:回顾性分析2022年1月—2024年10月在亳州市中医院接受诊疗的67例aSAH患者病例资料。根据格拉斯哥预后评分,将患者分为预后良好组(n=37)和预后不良组(n=30)。采用单因素及多因素Logistic回归分析比较组间临床、影像及PHASES评分,筛选aSAH患者预后的独立预测因素并构建回归模型。绘制受试者工作特征(ROC)曲线,评估各单一独立预测因素及回归模型预测aSAH患者预后的效能。结果:预后不良组患者Hunt-Hess分级Ⅳ~Ⅴ级的占比、AR值、SR值、入射夹角和PHASES评分均高于预后良好组,发病至治疗时间>3 d的占比高于预后良好组,差异有统计学意义(P<0.05)。多因素Logistic回归分析结果显示,Hunt-Hess分级、入射夹角和PHASES评分为aSAH患者不良结局的影响因素(P<0.05),其曲线下面积(AUC)分别为0.613、0.658、0.761;以三者联合构建的回归模型预测患者预后的诊断灵敏度为0.733,特异度为0.919,AUC为0.898。结论:CTA联合PHASES评分能够有效提升对aSAH患者预后的预测效能,有助于临床进行预后判断。 展开更多
关键词 颅内动脉瘤 破裂出血 CT血管造影 phaseS评分 预后价值
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Two-Dimensional MXene-Based Advanced Sensors for Neuromorphic Computing Intelligent Application
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作者 Lin Lu Bo Sun +2 位作者 Zheng Wang Jialin Meng Tianyu Wang 《Nano-Micro Letters》 2026年第2期664-691,共28页
As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and el... As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies. 展开更多
关键词 TWO-DIMENSIONAL mxenes SENSOR Neuromorphic computing Multimodal intelligent system Wearable electronics
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MXene-Based Wearable Contact Lenses: Integrating Smart Technology into Vision Care
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作者 Arezoo Khosravi Atefeh Zarepour +1 位作者 Ali Zarrabi Siavash Iravani 《Nano-Micro Letters》 2026年第1期490-508,共19页
MXene-based smart contact lenses demonstrate a cutting-edge advancement in wearable ophthalmic technology,combining real-time biosensing,therapeutic capabilities,and user comfort in a single platform.These devices tak... MXene-based smart contact lenses demonstrate a cutting-edge advancement in wearable ophthalmic technology,combining real-time biosensing,therapeutic capabilities,and user comfort in a single platform.These devices take the advantage of the exceptional electrical conductivity,mechanical flexibility,and biocompatibility of two-dimensional MXenes to enable noninvasive,tear-based monitoring of key physiological markers such as intraocular pressure and glucose levels.Recent developments focus on the integration of transparent MXene films into the conventional lens materials,allowing multifunctional performance including photothermal therapy,antimicrobial and anti-inflammation protection,and dehydration resistance.These innovations offer promising strategies for ocular disease management and eye protection.In addition to their multifunctionality,improvements in MXene synthesis and device engineering have enhanced the stability,transparency,and wearability of these lenses.Despite these advances,challenges remain in long-term biostability,scalable production,and integration with wireless communication systems.This review summarizes the current progress,key challenges,and future directions of MXene-based smart contact lenses,highlighting their transformative potential in next-generation digital healthcare and ophthalmic care. 展开更多
关键词 mxenes Wearable contact lenses Intraocular lenses Drug delivery Wearable electronics
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Tellurium-Terminated MXene Synthesis via One-Step Tellurium Etching
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作者 Guoliang Ma Zongbin Luo +3 位作者 Hui Shao Yanbin Shen Zifeng Lin Patrice Simon 《Nano-Micro Letters》 2026年第1期738-749,共12页
With the rapid development of twodimensional MXene materials,numerous preparation strategies have been proposed to enhance synthesis efficiency,mitigate environmental impact,and enable scalability for large-scale prod... With the rapid development of twodimensional MXene materials,numerous preparation strategies have been proposed to enhance synthesis efficiency,mitigate environmental impact,and enable scalability for large-scale production.The compound etching approach,which relies on cationic oxidation of the A element of MAX phase precursors while anions typically adsorb onto MXene surfaces as functional groups,remains the main prevalent strategy.By contrast,synthesis methodologies utilizing elemental etching agents have been rarely reported.Here,we report a new elemental tellurium(Te)-based etching strategy for the preparation of MXene materials with tunable surface chemistry.By selectively removing the A-site element in MAX phases using Te,our approach avoids the use of toxic fluoride reagents and achieves tellurium-terminated surface groups that significantly enhance sodium storage performance.Experimental results show that Te-etched MXene delivers substantially higher capacities(exceeding 50%improvement over conventionally etched MXene)with superior rate capability,retaining high capacity at large current densities and demonstrating over 90%capacity retention after 1000 cycles.This innovative synthetic strategy provides new insight into controllable MXene preparation and performance optimization,while the as-obtained materials hold promises for high-performance sodium-ion batteries and other energy storage systems. 展开更多
关键词 Te-terminated mxene Elemental tellurium etching Sodium-ion storage High-rate performance
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Multifunctional MXene for Thermal Management in Perovskite Solar Cells
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作者 Zhongquan Wan Runmin Wei +5 位作者 Yuanxi Wang Huaibiao Zeng Haomiao Yin Muhammad Azam Junsheng Luo Chunyang Jia 《Nano-Micro Letters》 2026年第1期458-473,共16页
Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bot... Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bottleneck,severely affecting device stability and long-term operational performance.Herein,we present a multifunctional strategy by incorporating highly thermally conductive Ti_(3)C_(2)T_(X) MXene nanosheets into the perovskite layer to simultaneously enhance thermal management and optoelectronic properties.The Ti_(3)C_(2)T_(X) nanosheets,embedded at perovskite grain boundaries,construct efficient thermal conduction pathways,significantly improving the thermal conductivity and diffusivity of the film.This leads to a notable reduction in the device’s steady-state operating temperature from 42.96 to 39.97 under 100 mW cm^(−2) illumination,thereby alleviating heat-induced performance degradation.Beyond thermal regulation,Ti_(3)C_(2)T_(X),with high conductivity and negatively charged surface terminations,also serves as an effective defect passivation agent,reducing trap-assisted recombination,while simultaneously facilitating charge extraction and transport by optimizing interfacial energy alignment.As a result,the Ti_(3)C_(2)T_(X)-modified PSC achieve a champion PCE of 25.13%and exhibit outstanding thermal stability,retaining 80%of the initial PCE after 500 h of thermal aging at 85 and 30±5%relative humidity.(In contrast,control PSC retain only 58%after 200 h.)Moreover,under continuous maximum power point tracking in N2 atmosphere,Ti_(3)C_(2)T_(X)-modified PSC retained 70%of the initial PCE after 500 h,whereas the control PSC drop sharply to 20%.These findings highlight the synergistic role of Ti_(3)C_(2)T_(X) in thermal management and optoelectronic performance,paving the way for the development of high-efficiency and heat-resistant perovskite photovoltaics. 展开更多
关键词 Perovskite solar cells Heat accumulation Thermal management Multifunctional mxene Defect passivation
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Illusion Optics via Phase-Gradient Metasurfaces
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作者 haoyao Pan Jinpeng Yang Yadong Xu 《Chinese Physics Letters》 2026年第1期31-36,共6页
Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with pha... Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with phase gradient modulation can be used to achieve illusion optics,featuring the advantages of simple geometric structure and feasible implementation compared with the well-known transformation optics method.The underlying mechanism is the anomalous diffraction law caused by the phase gradient,which provides a theoretical basis for freely manipulating the propagation path of light.By considering a specific example,we will demonstrate that the phase gradient can transform spatial coordinates in real space into illusion space,thereby converting a plane in real space into a curved surface structure in illusion space to achieve the illusion effect.This approach provides a viable alternative to transformation optics for designing illusion devices. 展开更多
关键词 transformation optics anomalous diffraction law illusion opticsfeaturing flexible light manipulationwith illusion optics anomalous diffraction phase gradient modulation phase gradient metasurfaces
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Flexible Monolithic 3D-Integrated Self-Powered Tactile Sensing Array Based on Holey MXene Paste
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作者 Mengjie Wang Chen Chen +9 位作者 Yuhang Zhang Yanan Ma Li Xu Dan‑Dan Wu Bowen Gao Aoyun Song Li Wen Yongfa Cheng Siliang Wang Yang Yue 《Nano-Micro Letters》 2026年第2期772-785,共14页
Flexible electronics face critical challenges in achieving monolithic three-dimensional(3D)integration,including material compatibility,structural stability,and scalable fabrication methods.Inspired by the tactile sen... Flexible electronics face critical challenges in achieving monolithic three-dimensional(3D)integration,including material compatibility,structural stability,and scalable fabrication methods.Inspired by the tactile sensing mechanism of the human skin,we have developed a flexible monolithic 3D-integrated tactile sensing system based on a holey MXene paste,where each vertical one-body unit simultaneously functions as a microsupercapacitor and pressure sensor.The in-plane mesopores of MXene significantly improve ion accessibility,mitigate the self-stacking of nanosheets,and allow the holey MXene to multifunctionally act as a sensing material,an active electrode,and a conductive interconnect,thus drastically reducing the interface mismatch and enhancing the mechanical robustness.Furthermore,we fabricate a large-scale device using a blade-coating and stamping method,which demonstrates excellent mechanical flexibility,low-power consumption,rapid response,and stable long-term operation.As a proof-of-concept application,we integrate our sensing array into a smart access control system,leveraging deep learning to accurately identify users based on their unique pressing behaviors.This study provides a promising approach for designing highly integrated,intelligent,and flexible electronic systems for advanced human-computer interactions and personalized electronics. 展开更多
关键词 Holey mxene Microsupercapacitor Tactile sensor Monolithic 3D integration Deep learning algorithm
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Quantitative analysis on T1 phase precipitation behaviors and mechanicalproperties of 2195 Al−Li alloy after cryogenic deformation and aging
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作者 Meng-jia YAO Hua-bo ZHOU +1 位作者 Rui-qian WANG Wei LIU 《Transactions of Nonferrous Metals Society of China》 2026年第1期25-42,共18页
The water-quenched(WQ)2195 Al−Li alloy was subjected to stretching at different temperatures,from room temperature(RT)to−196℃(CT),to investigate the effect of cryogenic deformation on the aging precipitation behavior... The water-quenched(WQ)2195 Al−Li alloy was subjected to stretching at different temperatures,from room temperature(RT)to−196℃(CT),to investigate the effect of cryogenic deformation on the aging precipitation behaviors and mechanical properties.The precipitation kinetics of the T1 phase and the microstructures in peak aging state were investigated through the differential scanning calorimetric(DSC)tests and electron microscopy observation.The results show that−196℃deformation produces a high dislocation density,which promotes the precipitation of the T1 phase and refines its sizes significantly.In addition,the grain boundary precipitates(GBPs)of−196℃-stretched samples are suppressed considerably due to the high dislocation density in the grain interiors,which increases the ductility.In comparison,the strength remains nearly constant.Thus,it is indicated that cryogenic forming has the potential to provide the shape and property control for the manufacture of critical components of aluminum alloys. 展开更多
关键词 Al−Li alloy cryogenic stretching T1 phase precipitation kinetics grain boundary precipitates
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Occurrence of beryllium and its microscale interactions with coexisting phases in beryllium-containing sludge
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作者 Xiaobo Min Lin Yu +6 位作者 Yong Ke Yunyan Wang Wenming Zeng Hui Xu Yun Li Cong Peng Zhumei Sun 《Journal of Environmental Sciences》 2026年第1期383-390,共8页
Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the o... Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the occurrence of Be in BCS is unclear,which seriously hinders the development of pollution control technologies.In order to enhance the understanding of BCS,the occurrence of Be and the microscale interactions with coexisting phases were investigated for the first time.It was found that CaSO_(4)·2H_(2)O and amorphous SiO_(2) are the primary phases of BCS.The simulated experiments of purified materials showed that Be interacted with CaSO_(4)·2H_(2)O and amorphous SiO_(2).Be can enter into the lattice of CaSO_(4)·2H_(2)O mainly as free Be2+.Amorphous SiO_(2) can adsorb Be2+particularly at a pH range of 3–5.The dissolution behavior experiment of BCS shows that about 52%of the Be is readily extracted under acidic conditions,which refers to the Be of independent occurrence.In contrast,the remaining 48%of Be can be extracted only after the CaSO_(4)·2H_(2)O has completely dissolved.Hence,CaSO_(4)·2H_(2)O is identified as the key occurrence phase which determines the highly efficient dissolution of Be.As a result,this study enhances the understanding of BCS and lays the foundation for the development of Be separation technologies. 展开更多
关键词 Beryllium-containing sludge(BCS) Occurrence phase CaSO_(4)·2H_(2)O Amorphous SiO_(2) Microscale interactions
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Ti_(3)C_(2)-MXene/CuS/PVDF复合光热膜的制备及太阳能驱动界面水蒸发性能 被引量:1
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作者 姜艳丽 徐云松 +4 位作者 王建康 李伟豪 宋英 汪新智 姚忠平 《高等学校化学学报》 北大核心 2025年第4期143-154,共12页
采用化学刻蚀-溶剂热法合成了Ti_(3)C_(2)-MXene/CuS复合材料,再通过真空抽滤将该复合材料负载到聚偏二氟乙烯(PVDF)膜上,构筑了Ti_(3)C_(2)-MXene/CuS/PVDF复合光热膜,并研究了其界面水蒸发性能.X射线衍射(XRD)和扫描电子显微镜(SEM)... 采用化学刻蚀-溶剂热法合成了Ti_(3)C_(2)-MXene/CuS复合材料,再通过真空抽滤将该复合材料负载到聚偏二氟乙烯(PVDF)膜上,构筑了Ti_(3)C_(2)-MXene/CuS/PVDF复合光热膜,并研究了其界面水蒸发性能.X射线衍射(XRD)和扫描电子显微镜(SEM)表征结果显示,CuS纳米颗粒将Ti_(3)C_(2)-MXene包裹并填满片层间隙.界面水蒸发性能测试结果表明,在180℃反应9 h所得材料的性能最佳,在1 kW/m2光照强度下,其界面水蒸发速率和蒸发效率分别为1.92 kg·m^(-2)·h^(-1)和110.4%.此外,复合光热膜具有较好的海水脱盐效果及良好的循环稳定性.紫外-可见漫反射光谱(DRS)与光热转换实验结果表明,Ti_(3)C_(2)-MXene与CuS的复合提高了其光吸收能力与光热转换效率,二者的协同效应显著提升了材料的光热转换和界面水蒸发性能.本工作可为低成本、高性能光热转换材料的开发提供借鉴. 展开更多
关键词 界面水蒸发 光热转换 Ti_(3)C_(2)-mxene CUS
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硫功能化M_(2)N型MXene的钠离子多层吸附性能增强机制
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作者 曹宇 杜心宇 +4 位作者 高昂 梁康 蔡永茂 逄金波 周静 《化工学报》 北大核心 2025年第12期6729-6738,共10页
基于密度泛函理论(DFT),系统探究了硫(S)功能化对M_(2)N型MXene(M=Sc、Ti、V、Zr、Nb)结构稳定性、电子性质及储钠性能的影响。结果表明,硫功能化通过诱导电荷重分布并增强钠离子的吸附强度,显著提升了多层吸附能力。其中,Sc_(2)NS_(2)... 基于密度泛函理论(DFT),系统探究了硫(S)功能化对M_(2)N型MXene(M=Sc、Ti、V、Zr、Nb)结构稳定性、电子性质及储钠性能的影响。结果表明,硫功能化通过诱导电荷重分布并增强钠离子的吸附强度,显著提升了多层吸附能力。其中,Sc_(2)NS_(2)和Zr_(2)NS_(2)的理论容量分别达到968 mAh/g和617 mAh/g,远高于未功能化的Sc_(2)N(理论容量为515 mAh/g)及传统硬碳材料(理论容量为300~400 mAh/g)。硫功能化后的M_(2)NS_(2)材料的迁移能垒(如Sc_(2)NS_(2)为0.168 eV,Zr_(2)NS_(2)为0.165 eV)显著低于硬碳的迁移能垒(0.25 eV)。差分电荷密度与电子局域函数(electron localization function,ELF)分析表明,硫的引入增强了钠离子与材料表面的电荷转移及局域化电子相互作用,为多层吸附提供了更多活性位点。该研究为高容量、快充放钠电负极的设计提供了理论依据,凸显了硫功能化M_(2)N型MXene在储能领域的应用潜力。 展开更多
关键词 钠离子电池 mxene 硫功能化 密度泛函理论 理论容量 纳米材料 模拟 动力学
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