Electrochemical liquid lithium extraction technology has attracted much attention because of its high selectivity,good efficiency,and eco-friendliness.However,the low energy density per unit area and poor stability of...Electrochemical liquid lithium extraction technology has attracted much attention because of its high selectivity,good efficiency,and eco-friendliness.However,the low energy density per unit area and poor stability of traditional thin film electrodes(F-LMO),as well as manganese dissolution loss induced by the Jahn-Teller distortion of LiMn_(2)O_(4),hinder their industrial scalability.Herein,a durable and high-efficiency multistage porous LiMn_(2)O_(4) thick electrode was prepared sustainably by 3D printing technology(3DPLMO)for enhancing lithium recovery from salt lake brine.The multistage porous structure reduced the mass transfer resistance and shortened the ion diffusion path,which was conducive to accelerating the diffusion rate of Li+.Simultaneously,the three-dimensional conductive networks composed of reduced graphene oxide(r GO)and carbon nanotubes(CNT)synergized with the multistage pores effectively weakened the polarization phenomenon of the electrode and improved the stability of 3DP-LMO.The3DP-LMO exhibited a 5.5-fold higher extraction capacity per unit area and the Mn dissolution loss rate was only 1/15 compared with the F-LMO.Notably,the capacity retention rate of 3DP-LMO was 87.6%,significantly better than that of F-LMO(66.3%).Based on the quasi-in situ X-ray Diffraction results,the mechanism of lithium intercalation and deintercalation in 3DP-LMO was elucidated.Furthermore,lithium extraction parameters were optimized using response surface method-center composite design(RSM-CCD),resulting in an increase in lithium extraction capacity to 15.66 mg g^(-1)and a reduction in energy consumption to only 12.33 Wh mol^(-1).The results show that 3DP-LMO has significantly improved lithium extraction performance and stability,and has considerable prospects in practical application.展开更多
After coal seam mining,the overlying rock strata above the goaf are subjected to long-term stress and eventually undergo failure.Under mining-induced disturbances,the strata develop fractures at various angles,which s...After coal seam mining,the overlying rock strata above the goaf are subjected to long-term stress and eventually undergo failure.Under mining-induced disturbances,the strata develop fractures at various angles,which significantly influence failure modes and the morphology of gas flow channels.This study employed multistage loading experiments,numerical simulations,three-dimensional reconstruction,and image recognition to investigate the fragmentation process of rocks with different initial fracture angles under multistage loading.The results show that variations in the initial fracture angle affect the transmission of contact forces among rock particles.As the angle increases,the transmission pattern shifts from a uniform distribution to one extending along the direction of the fracture.Rocks with small initial fracture angles tend to experience tensile-dominated failure,with most of the material subjected to longitudinal loading,resulting in reduced strength.Fractures propagate from the central region of the initial fracture,producing a complex internal fracture network.The proportion of fracture channels varies considerably across regions,creating multiple zones of velocity variation in the gas flow.In contrast,rocks with large initial fracture angles are more susceptible to shear failure,with the primary load-bearing zones aligned along the inclined fracture direction.As a result,the influence on surrounding regions is limited,improving the rock's load-bearing capacity under multistage loading.In these cases,the distribution and proportion of fracture channels become more uniform,promoting more stable gas flow within the channels.Overall,these findings provide theoretical insights into how initial fracture angles govern rock failure patterns and gas flow characteristics.展开更多
Hydrogen,as a zero-carbon secondary energy carrier,provides a unified pathway for low-carbon energy transformation.In electro–hydrogen coupling systems(EHCSs),surplus renewable power is stored via water electrolysis ...Hydrogen,as a zero-carbon secondary energy carrier,provides a unified pathway for low-carbon energy transformation.In electro–hydrogen coupling systems(EHCSs),surplus renewable power is stored via water electrolysis and later reconverted to electricity using fuel cells or gas turbines,enhancing the system’s flexibility and reliability in support of deep decarbonization.This study constructs an electricity–hydrogen energy-recycling model based on a coupling relationship considering the bidirectional conversion between electricity and hydrogen.A multistage carbon-emission-reduction indicator constraint is also established.Additionally,the green-certificate and carbon trading markets are introduced to optimize equipment investment and operation costs while achieving carbon-emission reduction.A case study reveals that the proposed EHCS planning model effectively allocates carbon emissions across different system stages,while mitigating economic repercussions,thus ensuring closer alignment with China’s emission-reduction policies.Incorporating diverse market mechanisms significantly enhances the system’s economy and decision-making flexibility,particularly in addressing future challenges in the energy market.展开更多
The leaching process of magnesiothermic self-propagating product generated during the multistage deep reduction process was investigated.The influence of magnesiothermic self-propagating product particle size,HCl solu...The leaching process of magnesiothermic self-propagating product generated during the multistage deep reduction process was investigated.The influence of magnesiothermic self-propagating product particle size,HCl solution concentration,and leaching solution temperature on the leaching behavior of elements Al and V was investigated.Results demonstrate that the leaching rate of Al and V is increased with the rise in leaching solution temperature,the increase in HCl solution concentration,and the enlargement of magnesiothermic self-propagating product particle size.The leaching processes of Al and V are consistent with the chemical reaction control model.When the magnesiothermic self-propagation product with D_(50) of 59.4μm is selected as the raw material,the leaching temperature is 40℃,and 1 mol/L HCl solution is employed,after leaching for 180 min,the leaching rates of Al and V are 24.8%and 12.6%,respectively.The acid-leached product exhibits a porous structure with a specific surface area of 3.5633 m^(2)/g.展开更多
This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its co...This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its control on paleogeomorphology and large-sale shoals based on analysis of outcrops,loggings and seismic data.The results show that the Maokou Formation comprises two third-order sequences,six fourth-order sequences(SSQ1-SSQ6),and four distinct slope-break zones developing progressively from north to south.Slope-break zones I-III in the northern basin,controlled by synsedimentary extensional faults,exhibited a NE-trending linear distribution with gradual southeastward migration.In contrast,slope-break zone IV in the southern basin displayed an arcuate distribution along the Emeishan Large Igneous Province(ELIP).The evolutions of these multistage slope-break zones governed the Mid-Permian paleogeomorphy in the Sichuan Basin transformations from a giant,north-dipping gentle slope(higher in the southwest than in the northeast)in the early-stage(SSQ1-SSQ2)to a platform(south)-basin(north)pattern in the middle-stage(SSQ3-SSQ5).Ultimately,a further depression zone developed in the southwestern basin during the late-stage(SSQ6),forming a paleo-uplift bounded by two depressions.The developments of the Mid-Permian paleogeomorphic configuration reflected the combined control by the rapid subduction of the Mianlüe Ocean and the episodic eruptions of the Emeishan mantle plume(or hot spots),which jointly facilitated the formation of extensive high-energy shoal facies belts along slope-break zones and around paleo-volcanic uplifts.展开更多
The current portfolio model for property-liability insurance company is only single period that can not meet the practical demands of portfolio management, and the purpose of this paper is to develop a multiperiod mod...The current portfolio model for property-liability insurance company is only single period that can not meet the practical demands of portfolio management, and the purpose of this paper is to develop a multiperiod model for its portfolio problem. The model is a multistage stochastic programming which considers transaction costs, cash flow between time periods, and the matching of asset and liability; it does not depend on the assumption for normality of return distribution. Additionally, an investment constraint is added. The numerical example manifests that the multiperiod model can more effectively assist the property-liability insurer to determine the optimal composition of insurance and investment portfolio and outperforms the single period one.展开更多
常规机载气象雷达采用脉冲对法估计谱宽实现湍流检测,当信噪比较低时脉冲对法的谱宽估计误差大。晴空湍流(clear air turbulence,CAT)含水量较少,雷达回波信噪比很低,因此常规机载气象雷达无法检测CAT。为提高低信噪比下机载气象雷达回...常规机载气象雷达采用脉冲对法估计谱宽实现湍流检测,当信噪比较低时脉冲对法的谱宽估计误差大。晴空湍流(clear air turbulence,CAT)含水量较少,雷达回波信噪比很低,因此常规机载气象雷达无法检测CAT。为提高低信噪比下机载气象雷达回波谱宽估计性能,提出了一种基于降秩多级维纳滤波器(Reduced-Rank Multistage Wiener Filter,RR-MWF)的回波谱矩估计方法。该方法在机载气象雷达引入空时体制的基础上,利用空时域联合处理对湍流回波进行处理,通过空时积累改善信噪比。在最小均方误差准则下,构造了适用于分布式气象目标的自适应RR-MWF权矢量和代价函数,估计回波谱矩。仿真实验表明,提出的RR-MWF估计器在信噪比低于10 dB时明显优于常规的脉冲对法,可用于CAT检测。展开更多
基金supported by the National Key R&D Program of China(No.2022YFE0208300)the National Natural Science Foundation of China(No.22278426)+2 种基金the China National Funds for Distinguished Young Scientists(No.22425808)the China Postdoctoral Science Foundation(No.2025M771155)the Science Foundation of China University of Petroleum,Beijing(Nos.2462024XKBH001,2462022YJRC003,2462022YJRC002,2462025BJRC002)。
文摘Electrochemical liquid lithium extraction technology has attracted much attention because of its high selectivity,good efficiency,and eco-friendliness.However,the low energy density per unit area and poor stability of traditional thin film electrodes(F-LMO),as well as manganese dissolution loss induced by the Jahn-Teller distortion of LiMn_(2)O_(4),hinder their industrial scalability.Herein,a durable and high-efficiency multistage porous LiMn_(2)O_(4) thick electrode was prepared sustainably by 3D printing technology(3DPLMO)for enhancing lithium recovery from salt lake brine.The multistage porous structure reduced the mass transfer resistance and shortened the ion diffusion path,which was conducive to accelerating the diffusion rate of Li+.Simultaneously,the three-dimensional conductive networks composed of reduced graphene oxide(r GO)and carbon nanotubes(CNT)synergized with the multistage pores effectively weakened the polarization phenomenon of the electrode and improved the stability of 3DP-LMO.The3DP-LMO exhibited a 5.5-fold higher extraction capacity per unit area and the Mn dissolution loss rate was only 1/15 compared with the F-LMO.Notably,the capacity retention rate of 3DP-LMO was 87.6%,significantly better than that of F-LMO(66.3%).Based on the quasi-in situ X-ray Diffraction results,the mechanism of lithium intercalation and deintercalation in 3DP-LMO was elucidated.Furthermore,lithium extraction parameters were optimized using response surface method-center composite design(RSM-CCD),resulting in an increase in lithium extraction capacity to 15.66 mg g^(-1)and a reduction in energy consumption to only 12.33 Wh mol^(-1).The results show that 3DP-LMO has significantly improved lithium extraction performance and stability,and has considerable prospects in practical application.
基金supported by the National Natural Science Foundation of China(Grant No.52522405)Key R&D Project of Sichuan Province of China(Regional Innovation Coop-eration)(Grant No.2025YFHZ0314).
文摘After coal seam mining,the overlying rock strata above the goaf are subjected to long-term stress and eventually undergo failure.Under mining-induced disturbances,the strata develop fractures at various angles,which significantly influence failure modes and the morphology of gas flow channels.This study employed multistage loading experiments,numerical simulations,three-dimensional reconstruction,and image recognition to investigate the fragmentation process of rocks with different initial fracture angles under multistage loading.The results show that variations in the initial fracture angle affect the transmission of contact forces among rock particles.As the angle increases,the transmission pattern shifts from a uniform distribution to one extending along the direction of the fracture.Rocks with small initial fracture angles tend to experience tensile-dominated failure,with most of the material subjected to longitudinal loading,resulting in reduced strength.Fractures propagate from the central region of the initial fracture,producing a complex internal fracture network.The proportion of fracture channels varies considerably across regions,creating multiple zones of velocity variation in the gas flow.In contrast,rocks with large initial fracture angles are more susceptible to shear failure,with the primary load-bearing zones aligned along the inclined fracture direction.As a result,the influence on surrounding regions is limited,improving the rock's load-bearing capacity under multistage loading.In these cases,the distribution and proportion of fracture channels become more uniform,promoting more stable gas flow within the channels.Overall,these findings provide theoretical insights into how initial fracture angles govern rock failure patterns and gas flow characteristics.
基金supported by State Grid Jiangsu Electric Power Co.,Ltd.Technology Project(Research on Planning and Operation Technology of Electric–Hydrogen Coupling System Driven by the Electric–Carbon–Green Certificate Market):J2024005.
文摘Hydrogen,as a zero-carbon secondary energy carrier,provides a unified pathway for low-carbon energy transformation.In electro–hydrogen coupling systems(EHCSs),surplus renewable power is stored via water electrolysis and later reconverted to electricity using fuel cells or gas turbines,enhancing the system’s flexibility and reliability in support of deep decarbonization.This study constructs an electricity–hydrogen energy-recycling model based on a coupling relationship considering the bidirectional conversion between electricity and hydrogen.A multistage carbon-emission-reduction indicator constraint is also established.Additionally,the green-certificate and carbon trading markets are introduced to optimize equipment investment and operation costs while achieving carbon-emission reduction.A case study reveals that the proposed EHCS planning model effectively allocates carbon emissions across different system stages,while mitigating economic repercussions,thus ensuring closer alignment with China’s emission-reduction policies.Incorporating diverse market mechanisms significantly enhances the system’s economy and decision-making flexibility,particularly in addressing future challenges in the energy market.
基金Scientific and Technological Project of Nanyang(23KJGG017)Key Specialized Research&Development and Promotion Project(Scientific and Technological Project)of Henan Province(232102221022)+1 种基金College Students and Technology Innovation Fund Project of Nanyang Institute of Technology(2023139)Project of Doctoral Scientific Research Startup Fund of Nanyang Institute of Technology(NGBJ-2023-25)。
文摘The leaching process of magnesiothermic self-propagating product generated during the multistage deep reduction process was investigated.The influence of magnesiothermic self-propagating product particle size,HCl solution concentration,and leaching solution temperature on the leaching behavior of elements Al and V was investigated.Results demonstrate that the leaching rate of Al and V is increased with the rise in leaching solution temperature,the increase in HCl solution concentration,and the enlargement of magnesiothermic self-propagating product particle size.The leaching processes of Al and V are consistent with the chemical reaction control model.When the magnesiothermic self-propagation product with D_(50) of 59.4μm is selected as the raw material,the leaching temperature is 40℃,and 1 mol/L HCl solution is employed,after leaching for 180 min,the leaching rates of Al and V are 24.8%and 12.6%,respectively.The acid-leached product exhibits a porous structure with a specific surface area of 3.5633 m^(2)/g.
基金Supported by the Key projects of the PetroChina Joint Fund Under the National Natural Science Foundation of China(U23B20154,92255302)Science and Technology Cooperation Project of the Innovation Consortium between PetroChina and Southwest Petroleum University(2020CX010000)Open Fund of the Key Laboratory of Carbonate Reservoirs,China National Petroleum Corporation(RIPED-2024-JS-1804).
文摘This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its control on paleogeomorphology and large-sale shoals based on analysis of outcrops,loggings and seismic data.The results show that the Maokou Formation comprises two third-order sequences,six fourth-order sequences(SSQ1-SSQ6),and four distinct slope-break zones developing progressively from north to south.Slope-break zones I-III in the northern basin,controlled by synsedimentary extensional faults,exhibited a NE-trending linear distribution with gradual southeastward migration.In contrast,slope-break zone IV in the southern basin displayed an arcuate distribution along the Emeishan Large Igneous Province(ELIP).The evolutions of these multistage slope-break zones governed the Mid-Permian paleogeomorphy in the Sichuan Basin transformations from a giant,north-dipping gentle slope(higher in the southwest than in the northeast)in the early-stage(SSQ1-SSQ2)to a platform(south)-basin(north)pattern in the middle-stage(SSQ3-SSQ5).Ultimately,a further depression zone developed in the southwestern basin during the late-stage(SSQ6),forming a paleo-uplift bounded by two depressions.The developments of the Mid-Permian paleogeomorphic configuration reflected the combined control by the rapid subduction of the Mianlüe Ocean and the episodic eruptions of the Emeishan mantle plume(or hot spots),which jointly facilitated the formation of extensive high-energy shoal facies belts along slope-break zones and around paleo-volcanic uplifts.
文摘The current portfolio model for property-liability insurance company is only single period that can not meet the practical demands of portfolio management, and the purpose of this paper is to develop a multiperiod model for its portfolio problem. The model is a multistage stochastic programming which considers transaction costs, cash flow between time periods, and the matching of asset and liability; it does not depend on the assumption for normality of return distribution. Additionally, an investment constraint is added. The numerical example manifests that the multiperiod model can more effectively assist the property-liability insurer to determine the optimal composition of insurance and investment portfolio and outperforms the single period one.
文摘常规机载气象雷达采用脉冲对法估计谱宽实现湍流检测,当信噪比较低时脉冲对法的谱宽估计误差大。晴空湍流(clear air turbulence,CAT)含水量较少,雷达回波信噪比很低,因此常规机载气象雷达无法检测CAT。为提高低信噪比下机载气象雷达回波谱宽估计性能,提出了一种基于降秩多级维纳滤波器(Reduced-Rank Multistage Wiener Filter,RR-MWF)的回波谱矩估计方法。该方法在机载气象雷达引入空时体制的基础上,利用空时域联合处理对湍流回波进行处理,通过空时积累改善信噪比。在最小均方误差准则下,构造了适用于分布式气象目标的自适应RR-MWF权矢量和代价函数,估计回波谱矩。仿真实验表明,提出的RR-MWF估计器在信噪比低于10 dB时明显优于常规的脉冲对法,可用于CAT检测。
