Phosphorus (P) is an essential nutrient element that is critical for plant growth and ecosystem functionality.The soil P cycle plays multiple roles,such as sustaining plant growth and productivity,regulating nutrient ...Phosphorus (P) is an essential nutrient element that is critical for plant growth and ecosystem functionality.The soil P cycle plays multiple roles,such as sustaining plant growth and productivity,regulating nutrient balance within ecosystems,and enhancing ecosystem adaptability and resilience.This cycle is influenced by factors such as the restoration approach and microbial community dynamics.However,the extent to which the restoration approach alters the P cycle in karst ecosystems and the underlying microbial mechanisms remain poorly understood.The P-cycle multifunctionality index (P-cycle MFI) serves as a comprehensive indicator for evaluating soil P cycle function,and it provides insights into changes in the P cycle between different restoration approaches.To investigate the shifts in soil P-cycle MFI and microbial mechanisms between different restoration approaches,we analyzed soil available P (AP),total P (TP),microbial biomass P (MBP),and the activities of acid phosphatase (ACP) and alkaline phosphatase (ALP).These data were used to calculate the P-cycle MFI by averaging the Z-scores between two restoration approaches(artificial restoration of forest (AF) and natural restoration of forest (NF)) and a control (cropland,CP) at six subtropical karst ecosystem sites in China.We also determined the soil organic carbon (SOC),exchangeable calcium (Ca) and magnesium (Mg),pH,bulk density (BD),microbial biomass C (MBC),and microbial biomass nitrogen (MBN),as well as the community structure,relative abundance,diversity indices,and co-occurrence networks of phoD-harboring bacteria.The results showed that the community structure of phoD-harboring bacteria varied significantly among AF,NF,and CP and across different temperature gradients.These bacteria exhibited increasing complexity and tightness in co-occurrence networks from CP to AF and then to NF,along with the ACP and ALP activities,but not the TP and AP contents.The P-cycle MFI values were significantly higher in NF compared to AF and CP,and the variation was significantly explained by restoration approach,temperature,MBC,MBN,SOC,exchangeable Ca,BD,community structure of phoD-harboring bacteria,and exchangeable Mg.Furthermore,natural restoration had a more substantial impact on the P-cycle MFI than temperature by enhancing SOC,microbial biomass,the complexity and co-occurrence network tightness of the phoD-harboring bacterial community structure,and ACP and ALP activities,but it reduced soil BD.The rare genera of phoD-harboring bacteria significantly influenced the variation of soil P-cycle MFI compared to the dominant genera.This study highlights the importance of rare genera of phoD-harboring bacteria in driving soil P-cycle multifunctionality in karst ecosystems,with natural restoration being more effective than artificial methods for enhancing soil organic matter and microbial community complexity.展开更多
Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bot...Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bottleneck,severely affecting device stability and long-term operational performance.Herein,we present a multifunctional strategy by incorporating highly thermally conductive Ti_(3)C_(2)T_(X) MXene nanosheets into the perovskite layer to simultaneously enhance thermal management and optoelectronic properties.The Ti_(3)C_(2)T_(X) nanosheets,embedded at perovskite grain boundaries,construct efficient thermal conduction pathways,significantly improving the thermal conductivity and diffusivity of the film.This leads to a notable reduction in the device’s steady-state operating temperature from 42.96 to 39.97 under 100 mW cm^(−2) illumination,thereby alleviating heat-induced performance degradation.Beyond thermal regulation,Ti_(3)C_(2)T_(X),with high conductivity and negatively charged surface terminations,also serves as an effective defect passivation agent,reducing trap-assisted recombination,while simultaneously facilitating charge extraction and transport by optimizing interfacial energy alignment.As a result,the Ti_(3)C_(2)T_(X)-modified PSC achieve a champion PCE of 25.13%and exhibit outstanding thermal stability,retaining 80%of the initial PCE after 500 h of thermal aging at 85 and 30±5%relative humidity.(In contrast,control PSC retain only 58%after 200 h.)Moreover,under continuous maximum power point tracking in N2 atmosphere,Ti_(3)C_(2)T_(X)-modified PSC retained 70%of the initial PCE after 500 h,whereas the control PSC drop sharply to 20%.These findings highlight the synergistic role of Ti_(3)C_(2)T_(X) in thermal management and optoelectronic performance,paving the way for the development of high-efficiency and heat-resistant perovskite photovoltaics.展开更多
The development of multifunctional intelligent textiles has become an important innovation direction in the field of textile engineering, under the dual demands of intelligent health monitoring and environmental prote...The development of multifunctional intelligent textiles has become an important innovation direction in the field of textile engineering, under the dual demands of intelligent health monitoring and environmental protection. Although singlefunctional textiles with antibacterial, photochromic, and strain-sensing properties have been developed, they are unable to meet the demand for multifunctional textiles. In this respect, this study developed a poly(lactic acid) and poly(3-hydroxybutyrate)/thermoplastic polyurethane/carbon black nanoparticle composite nanofiber yarn(PPTCY) with a hollow-core-sheath structure using a simple conjugate electrospinning technology. PPTCY possessed excellent mechanical strength and could be effectively woven. More importantly, it not only enabled real-time visual monitoring of ultraviolet(UV) intensity in the environment but also possessed excellent antibacterial properties and strain-sensing performance. Its ΔE value was up to 58.24, and its antibacterial rates against Escherichia coli and Staphylococcus aureus were both 99.99%. This fabric had excellent strainsensing performance, high linearity, and durability under both pressure and stretching deformations. This research provides favorable technical support for the application of intelligent textiles in the field of UV protection and traffic safety.展开更多
Rapid regional population shifts and spatial polarization have heightened pressure on cultivated land—a critical resource demanding urgent attention amid ongoing urban-rural transition.This study selects Jiangsu prov...Rapid regional population shifts and spatial polarization have heightened pressure on cultivated land—a critical resource demanding urgent attention amid ongoing urban-rural transition.This study selects Jiangsu province,a national leader in both economic and agricultural development,as a case area to construct a multidimensional framework for assessing the recessive morphological characteristics of multifunctional cultivated land use.We examine temporal dynamics,spatial heterogeneity,and propose an integrated zoning strategy based on empirical analysis.The results reveal that:(1)The recessive morphology index shows a consistent upward trend,with structural breaks in 2007 and 2013,and a spatial shift from“higher in the east and lower in the west”to“higher in the south and lower in the north.”(2)Coordination among sub-dimensions of the index has steadily improved.(3)The index is expected to continue rising in the next decade,though at a slower pace.(4)To promote coordinated multidimensional land-use development,we recommend a policy framework that reinforces existing strengths,addresses weaknesses,and adapts zoning schemes to current spatial conditions.This research offers new insights into multifunctional cultivated land systems and underscores their role in enhancing human well-being,securing food supply,and supporting sustainable urban-rural integration.展开更多
Urban forests are highly multifunctional and provide numerous ecological functions.Plant functional traits individually or jointly influence the ecological multifunctionality of tree species(TS-EMF)and can also modify...Urban forests are highly multifunctional and provide numerous ecological functions.Plant functional traits individually or jointly influence the ecological multifunctionality of tree species(TS-EMF)and can also modify TSEMF in response to environmental changes.However,there has been limited exploration of multitrait combinations for predicting TS-EMF across seasons and of trait thresholds that enhance TS-EMF.Here,for 10 dominant tree species in urban forests of Northeast China,14 traits were measured and four aboveground and three belowground ecological functions assessed in three seasons.Ecological functions and TS-EMF differed significantly throughout the seasons(P<0.05).Synergistic relationships were found between carbon sequestration and oxygen release,between cooling and humidification,and between organic carbon accumulation and nutrient cycling.Notably,aboveground multifunctionality played a leading role in TS-EMF.With seasonal changes,resource allocation shifted toward traits related to resource acquisition rather than conservation to maintain TS-EMF.The combination of traits that predicted TS-EMF varied by type,accounting for up to 66.45%of the variation.TS-EMF was primarily driven by leaf structure in spring and by nutrient accumulation in autumn.Leaf carbon content(LCC)consistently served as a stabilizing factor for predicting TS-EMF across seasons.At 36.5-36.8 mg g^(-1),LCC had its optimal effect on TS-EMF.Other traits in combination that positively influence total TS-EMF include leaf nitrogen content(3.43-3.45 mg g^(-1)),leaf phosphorus content(0.80-0.83 mg g^(-1)),and leaf area(65.86-68.43 cm^(2)).Within these specified trait thresholds,Morus alba and Quercus mongolica were identified as key species.These findings suggest that the trade-off between various ecological functions can be managed by altering plant traits across seasons.This approach could provide a theoretical foundation for enhancing the TS-EMF of urban forests through trait-based management,offering practical guidance for selecting tree species.展开更多
Polymer nanocomposite coatings(PNCCs)are unprecedented generation of coatings engineered for displaying inexpensive and brilliant functional surface coatings with eminent corrosion guard,mechanical resistance,antimicr...Polymer nanocomposite coatings(PNCCs)are unprecedented generation of coatings engineered for displaying inexpensive and brilliant functional surface coatings with eminent corrosion guard,mechanical resistance,antimicrobial,chemical durability,electrical insulation,and UV aging features.Due to their widely anticipation in petroleum,applications in building,conveyance,aerospace,electronics,automobiles and energy,these multi-functional coatings have a tremendous leverage in human life,all technological and scientific subjects.Numerous applications have been made for multilateral polymers like polyurethane(PU),epoxy(EP),polyaniline(PANI)conductive polymer,polypyrrole(PPy),and etc,on various metallic surfaces especially,carbon steel substrate owing to their excellent resistance properties.Practically,nanomaterials can possess potential in the all-interdisciplinary domains of materials science and engineering,chemical and physical sciences,biological and health sciences.As known,the designed polymer nanocomposite coating paradigm is fundamentally constituted from polymer or resin as a vehicle and inorganic nanofillers(nanoparticles and nanocomposites).Some commercialized and excessively employed nanocontainers in polymer nanocomposite coating formulations,like ZnO,TiO_(2),carbon nanotubes(CNTs),clay,SiO_(2),Al_(2)O_(3),graphene,GO,CeO_(2),ZrO_(2),FeTiO_(3),etc were discussed.The current review covered the chemistry and potential applications of the largest utilized multifunctional polymer nanocomposite coatings such as EP,PU and other considerable PNCCs.Lately,a titanic attention was made for epoxy nanocomposites because of their distinct physicochemical characteristics,which result from the combined qualities of the nanoparticles and polymer material unity.In addition,the author incorporated some of his scientific contributions in this area represented in construction of innovative functional polymer nanocomposites for a variety of uses with high economic,industrial impacts and future orientation.Furthermore,some newly published applications of polymer nanocomposite coatings were incorporated and discussed.展开更多
Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication,...Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic equipment.In this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.展开更多
Soil microbial communities are key factors in maintaining ecosystem multifunctionality(EMF).However,the distribution patterns of bacterial diversity and how the different bacterial taxa and their diversity dimensions ...Soil microbial communities are key factors in maintaining ecosystem multifunctionality(EMF).However,the distribution patterns of bacterial diversity and how the different bacterial taxa and their diversity dimensions affect EMF remain largely unknown.Here,we investigated variation in three measures of diversity(alpha diversity,community composition and network complexity)among rare,intermediate,and abundant taxa across a latitudinal gradient spanning five forest plots in Yunnan Province,China and examined their contributions on EMF.We aimed to characterize the diversity distributions of bacterial groups across latitudes and to assess the differences in the mechanisms underlying their contributions to EMF.We found that multifaceted diversity(i.e.,diversity assessed by the three different metrics)of rare,intermediate,and abundant bacteria generally decreased with increasing latitude.More importantly,we found that rare bacterial taxa tended to be more diverse,but they contributed less to EMF than intermediate or abundant bacteria.Among the three dimensions of diversity we assessed,only community composition significantly affected EMF across all locations,while alpha diversity had a negative effect,and network complexity showed no significant impact.Our study further emphasizes the importance of intermediate and abundant bacterial taxa as well as community composition to EMF and provides a theoretical basis for investigating the mechanisms by which belowground microorganisms drive EMF along a latitudinal gradient.展开更多
Separator modification is an effective approach to suppress dendrite growth to realize high-energy sodium metal batteries(SMBs)in practical applications,however,its success is mainly subject to surface modification.He...Separator modification is an effective approach to suppress dendrite growth to realize high-energy sodium metal batteries(SMBs)in practical applications,however,its success is mainly subject to surface modification.Herein,a separator with multifunctional layers composed of N-doped mesoporous hollow carbon spheres(HCS)as the inner layer and sodium fluoride(NaF)as the outer layer on commercial polypropylene separator(PP)is proposed(PP@HCS-NaF)to achieve stable cycling in SMB.At the molecular level,the inner HCS layer with a high content of pyrrolic-N induces the uniform Na^(+)flux as a potential Na^(+)redistributor for homogenous deposition,whereas its hollow mesoporous structure offers nanoporous buffers and ion channels to regulate Na^(+)ion distribution and uniform deposition.The outer layer(NaF)constructs the NaF-enriched robust solid electrolyte interphase layer,significantly lowering the Na^(+)ions diffusion barrier.Benefiting from these merits,higher electrochemical performances are achieved with multifunctional double-layered PP@HCS-NaF separators compared with single-layered separators(i.e.PP@HCS or PP@NaF)in SMBs.The Na‖Cu half-cell with PP@HCS-NaF offers stable cycling(280 cycles)with a high CE(99.6%),and Na‖Na symmetric cells demonstrate extended lifespans for over 6000 h at 1 mA cm^(-2)with a progressively stable overpotential of 9 mV.Remarkably,in Na‖NVP full-cells,the PP@HCS-NaF separator grants a stable capacity of~81 mA h g^(-1)after 3500 cycles at 1 C and an impressive rate capability performance(~70 mA h g^(-1)at 15 C).展开更多
Herein,a novel Janus-structured multifunctional membrane with integrated electromagnetic interference(EMI)shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation and vacuum...Herein,a novel Janus-structured multifunctional membrane with integrated electromagnetic interference(EMI)shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation and vacuum-assisted filtration.Interestingly,within the polytetrafluoroethylene(PTFE)-carbon nanotube(CNT)-Fe_(3)O_(4)layer(FCFe),CNT nanofibers interweave with PTFE fibers to form a stable“silk-like”structure that effectively captures Fe_(3)O_(4)particles.By incorporating a highly conductive MXene layer,the FCFe/MXene(FCFe/M)membrane exhibits excellent electrical/thermal conductivity,mechanical properties,and flame retardancy.Impressively,benefiting from the rational regulation of component proportions and the design of a Janus structure,the FCFe/M membrane with a thickness of only 84.9μm delivers outstanding EMI shielding effectiveness of 44.56 dB in the X-band,with a normalized specific SE reaching 10,421.3 dB cm^(2)g^(-1),which is attributed to the“absorption-reflection-reabsorption”mechanism.Furthermore,the membrane demonstrates low-voltage-driven Joule heating and fast-response photothermal performance.Under the stimulation of a 3 V voltage and an optical power density of 320 mW cm^(-2),the surface temperatures of the FCFe/M membranes can reach up to 140.4 and 145.7℃,respectively.In brief,the FCFe/M membrane with anti-electromagnetic radiation and temperature regulation is an attractive candidate for the next generation of wearable electronics,EMI compatibility,visual heating,thermotherapy,and military and aerospace applications.展开更多
Aqueous zinc-ion batteries(AZIBs)have garnered extensive attention as the promising energy storage technology owing to their high safety,cost-effectiveness,and environmental friendliness.Nevertheless,their practical a...Aqueous zinc-ion batteries(AZIBs)have garnered extensive attention as the promising energy storage technology owing to their high safety,cost-effectiveness,and environmental friendliness.Nevertheless,their practical application is hindered by critical challenges,including Hydrogen evolution reactions(HER)and non-uniform Zn deposition,which compromise electrochemical performance and cycling stability.Herein,we propose a multifunctional hybrid electrolyte additive consisting of vanillin and Dimethyl sulfoxide,designed to weaken the interaction between Zn^(2+)and H_(2)O molecules,effectively modulating the solvation shell structure.In situ optical microscopy shows the hybrid additive significantly suppresses HER and promotes Zn^(2+)deposition on the(002)plane,inhibiting dendritic growth.The Zn||Zn symmetric cells with hybrid additive exhibit exceptional cycling stability,achieving over 4000 h at 1.0 mA cm^(-2)/1.0 m A h cm^(-2).The research on hybrid additives presents significant potential for exploration,offering a promising approach to the development of durable AZIBs.展开更多
Hydrogel-based flexible sensors are emerging as ideal candidates for wearable devices and soft robotics.However,most current hydrogels possess limited physicochemical properties,which hinder their practical applicatio...Hydrogel-based flexible sensors are emerging as ideal candidates for wearable devices and soft robotics.However,most current hydrogels possess limited physicochemical properties,which hinder their practical application in long-term and complex scenarios.Herein,inspired by the unique structure of the barnacle,we design multifunctional poly(DMAPA-co-PHEA)hydrogels(CP hydrogels)by employing multiple physical crosslinks in the presence of Ag nanoparticles and NaCl additives.Owing to the synergistic effect of cation-πinteractions,hydrophobic interactions,and ionic bonds,the CP hydrogels exhibit high stretchability(strain up to 1430%),strong adhesion(22.8 kPa),satisfactory antibacterial activity,stable anti-icing ability(<20 kPa after 20 icing-deicing cycles),and high electrical conductivity(18.5 mS/cm).Additionally,the CP hydrogels show fast and sensitive responsiveness and cycling stability and can attach directly to human skin to accurately detect both human motions and tiny physiological signals as a flexible wearable sensor.Collectively,this work significantly contributes a straightforward and efficient design strategy for the development of multifunctional hydrogels,broadening their application scenarios.展开更多
All maritime industries are plagued by marine biofouling pollution,which causes large economic and environmental costs.Therefore,there is an urgent need for ecofriendly alternatives that can effectively reduce the neg...All maritime industries are plagued by marine biofouling pollution,which causes large economic and environmental costs.Therefore,there is an urgent need for ecofriendly alternatives that can effectively reduce the negative consequences of biofouling pollution.This study aimed to produce novel capsaicin-inspired amide derivatives(CIADs)with multifunctional antifouling features by introducing amide compounds to aromatic compounds via a Friedel-Crafts alkylation reaction.The structure of the CIADs was characterized using FTIR,1H NMR,13C NMR,and HRMS,and the comprehensive antifouling capacity was determined by thermal stability,anti-ultraviolet,antibacterial,anti-algal,and marine field experiments.CIADs showed good thermal stability and did not show obvious weight loss before 226°C.2,4-dihydroxy-3,5-diphenylimidemet-hylbenzophenone(DDB)had an excellent ultraviolet absorption effect,which was even better than that of 2-hydroxy-4-(octyloxy)benzophenone.The antibacterial and anti-algal rates of N-(2,4-dimethyl-3-chloro-5-benzamide-methyl-6-hydroxybenzyl)benzamide(NDCBHB)were more than 99.5%and 64.0%,respectively,and the surface of antifouling coating with NDCBHB(NDCBHB-AC)was covered with only a small amount of sludge and biofilm,its antifouling effect was better than that of chlorothalonil.The above work provides a reference for preparing green and multifunctional antifouling agents.展开更多
The growing demand for microwave absorbing materials to mitigate electromagnetic pollution has driven the exploration of efficient design strategies.However,traditional experimental approaches for optimizing multicomp...The growing demand for microwave absorbing materials to mitigate electromagnetic pollution has driven the exploration of efficient design strategies.However,traditional experimental approaches for optimizing multicomponent and multilayer structures are time-consuming.To rapidly predict and optimize the electromagnetic parameters of microwave absorbing materials,a machine learning-assisted design framework has been proposed.A series of graphene/SiO_(2)(GS)and graphene/BaTiO_(3)(GB)aerogels were prepared by electrospinning technology,and their electromagnetic parameter datasets were used to train a machine learning model.The model achieved a maximum prediction accuracy of 97.3%,significantly accelerating the design process.By integrating the predicted parameters into simulation software,gradient impedance structures were rapidly designed,yielding multifunctional aerogels with an ultrawideband absorption range of 3.26–17.30 GHz at a thickness of 20 mm.Compared with conventional methods,this machine learning strategy reduces the research cycle to mere weeks,enabling the fast and efficient design of high-performance absorbing materials.Additionally,the aerogel demonstrated excellent thermal insulation and soundproofing capabilities,underscoring its multifunctionality.This study demonstrates the potential of machine learning in accelerating the development of next-generation microwave absorbing materials.展开更多
Sodium-ion-based electrochromic device(SECD)has been identified as an appealing cost-effective alternative of lithium-based counterparts,only if it can address the challenges in association with the inadequate electro...Sodium-ion-based electrochromic device(SECD)has been identified as an appealing cost-effective alternative of lithium-based counterparts,only if it can address the challenges in association with the inadequate electrochromic performance.In this regard,the quantized strategy is a particularly promising approach owing to the large surface-to-volume ratio and high reaction activity.However,quantum dots inevitably suffer from volume changes and undesired aggregation during electrochemical cycling.Herein,bioinspired from the robust connection of alveoli in lung,we propose a stable electrode,where WO_(3) quantum dots(WQDs)are robustly anchored on Ti_(3)C_(2) MXene through the strong chemical bonds of W-O-Ti.Theoretical results reveal the fundamental mechanism of the volume changes within WQDs and the dynamic diffusion process of sodium ions.The WQD@MXene electrodes exhibit a nearly twofold enhancement in cycling performance(1000 vs 500 cycles),coloration speed(3.2 vs 6.0 s),and areal capacity(87.5 vs 43.9 mAhm^(-2) at 0.1 mA cm^(-2)),compared to those of the pristine WQD electrode.As a proof-of-concept demonstration,a smart house system integrated with SECDs demonstrates a“3-in-1”device,enabling a combination of energy-saving,energy storage,and display functionalities.The present work significantly advances the versatile applications of cost-effective electrochromic electronics in interdisciplinary.展开更多
The proliferation of advanced electronics and devices has led to significant electromagnetic interference and pollution,resulting in heightened interest in electromagnetic interference(EMI)shielding materials in recen...The proliferation of advanced electronics and devices has led to significant electromagnetic interference and pollution,resulting in heightened interest in electromagnetic interference(EMI)shielding materials in recent years.Carbon foam,as a typical porous carbonaceous material,demonstrates significant potential as an innovative EMI shielding material owing to its lightweight nature,exceptional porosity,flexibility,favorable processability,and environmental sustainability.Nonetheless,the configuration of carbon atoms within the carbon foam is significantly disordered,leading to its intrinsic conductivity being comparatively low.Consequently,its shielding efficacy cannot meet the standards required for commercial EMI materials.Herein,we propose a hierarchical engineering strategy to construct a carbon foam composite with high shielding efficacy.Specifically,the FeCo nanoparticles and carbon layer are concurrently integrated into the carbon foam matrix to modulate its magnetic characteristics and conductivity.The results demonstrate that the carbon-coated FeCo/carbon foam composite achieves a shielding effectiveness(SE)of 24 dB in the X-band,signifying a 240% improvement compared to the pristine carbon foam.Simultaneously,the composite also exhibits superior multifunctionalities involving flexibility,Joule heating,and hydrophobicity.This study provides a facile and effective routine to regulate the shielding efficacy of EMI shielding materials.展开更多
To facilitate real-time monitoring and recording of humidity in the environment and to satisfy the requirement for strain performance in certain applications(such as wearable devices),this paper proposes an in-situ me...To facilitate real-time monitoring and recording of humidity in the environment and to satisfy the requirement for strain performance in certain applications(such as wearable devices),this paper proposes an in-situ method for synthesising Au nanoparticles on ZIF-67.In this study,an Au@ZIF-67 composite humidity-sensitive material was combined with flexible polyethylene terephthalate interdigitated electrodes to create an Au@ZIF-67 flexible humidity sensor.The prepared samples were characterised using X-ray diffraction,X-ray photoelectron spectroscopy,and transmission electron microscopy.The humidity-sensitive properties of the sensor were investigated,and its monitoring capabilities in applications involving respiration,gestures,skin,and baby diapers were tested.The experimental results indicate that compared with a pure ZIF-67 humidity sensor,the Au@ZIF-67(0.1Au@Z)flexible humidity sensor exhibits a 158.07%decrease in baseline resistance and a 51.66%increase in sensitivity to 95%relative humidity,and the hysteresis,response time,and recovery time are significantly reduced.Furthermore,the sensor exhibits excellent characteristics such as high resolution,repeatability,and stability.The obtained results regarding the material properties,humidity sensitivity,and practical application of non-contact humidity monitoring demonstrate that the prepared sensors exhibit excellent and comprehensive performance,indicating their broad prospects in wearable medical devices,wireless Internet of Things,humidity detection in complex environments,and intelligent integrated systems.展开更多
The traditional inflexible electromagnetic interference(EMI)shielding materials have poor adaptability to wearable and portable flexible electronic devices due to their shortcomings such as brittleness and difficulty ...The traditional inflexible electromagnetic interference(EMI)shielding materials have poor adaptability to wearable and portable flexible electronic devices due to their shortcomings such as brittleness and difficulty in machinability.As an optimized alternative,the conductive polymer composites(CPCs)constructed by integrating MXene and polymer have become one of the most promising EMI shielding materials.To cope with the more harsh application conditions,the processing-structure-property relationship of MXene/polymer EMI shielding composites urgently needs to be clarified.In this review,the EMI shielding mechanism and theory of CPCs are first outlined.Then,the recent advances in processing strategies for MXene/polymer EMI shielding composites with different structures are comprehensively summarized,including layered structure,segregated structure,and porous structure.Next,the multifunctionality of MXene/polymer EMI shielding composites in hydrophobicity,flame retardancy,thermal conductivity,infrared thermal camouflage,electrothermal conversion,photothermal conversion,and sensing function,is systematically introduced.Finally,the prospects and challenges for the future development and application of multifunctional MXene/polymer EMI shielding composites are discussed.This review aims to put forward effective guidance for fabricating intelligent,adaptable,and integrated MXene/polymer EMI shielding composites,thus promoting the upgrading of advanced MXene-based CPCs.展开更多
In recent years,soil acidification has been expanding in many areas of Asia due to increasing reactive nitrogen inputs and industrial activities,which may seriously affect the performance of various ecosystem function...In recent years,soil acidification has been expanding in many areas of Asia due to increasing reactive nitrogen inputs and industrial activities,which may seriously affect the performance of various ecosystem functions.However,the underlying patterns and processes of ecosystem multifunctionality(EMF)are largely unknown at different levels of pH,limiting our understanding of how EMF respond to drivers.This study aims to explore threshold of pH on changes in EMF and differences in the drivers for the changes in EMF on either side of each of the determined pH thresholds.We collected nutrient and environmental databases for raster-level sampling data,totaling 4,000 sampling points.Averaging and cluster-multiple-threshold approach were used to calculate EMF,then quadratic and generalized additive models and Mann-Whitney U were used to determine and test the pH thresholds for changes in EMF,structural equation modellings and variance partitioning analysis were used to explore the main drivers on changes in EMF.The pH threshold for EMF changes in Chinese terrestrial ecosystems is 6.0.When pH<6.0,climate was consistently more important in controlling the variation of EMF than other variables;when pH≥6.0,soil was consistently more important in controlling the variation of EMF than other variables.Specifically,when pH<6.0,mean annual temperature was the main factor in regulating the EMF variation;when pH≥6.0,soil moisture was the main factor in regulating the EMF variation.Our study provides important scientific value for the mechanism of maintaining EMF under global change.For example,with further increases in global nitrogen deposition,leading to increased soil acidification,there are different impacts on EMF in different regions.It may lead to a decrease in EMF in acidic soils and an increase in EMF in alkaline soils.This suggests different management strategies for different regions to maintain EMF stability in the context of future global changes.In the future,more attention should be paid to the biological mechanisms regulating EMF.展开更多
An all-solid-state ion-selective electrode(ISE)for the detection of potassium ions in complex media was developed based on functional peptides with both antibacterial and antifouling properties.While exhibiting unique...An all-solid-state ion-selective electrode(ISE)for the detection of potassium ions in complex media was developed based on functional peptides with both antibacterial and antifouling properties.While exhibiting unique antifouling property,the ISE capitalized on the high surface area of the conductive metalorganic framework(MOF)solid transducer layer to facilitate rapid ion-electron transfer,consequently improving the electrode stability.For a short period,the application of a±1 n A current to the ISE resulted in a slight potential drift of 2.5μV/s,while for a long-term stability test,the ISE maintained a stable Nernstian response slope over 8 days.The antifouling and antibacterial peptide effectively eradicated bacteria from the electrode surface while inhibited the adhesion of bacteria and other biological organisms.Both theoretical calculations and experimental results indicated that the incorporation of peptides in the sensing membrane did not compromise the detection performance of the ISE.The prepared antifouling potassium ion-selective electrode exhibited a Nernstian response range spanning from 1.0×10^(–8)mol/L to 1.0×10–3mol/L,with a detection limit of 2.51 nmol/L.Crucially,the prepared solid-contact ISE maintained excellent antifouling and sensing capabilities in actual seawater and human urine,indicating a promising feasibility of this strategy for constructing ISEs suitable for practical application in complex systems.展开更多
基金supported by the National Key Research and Development Program of China (2022YFF1300705)the Key Research and Development Project of Guangxi,China (Guike AB24010051)+1 种基金the National Natural Science Foundation of China (42261011,32271730 and U20A2011)the Central Public Welfare Research Institutes,Chinese Academy of Geological Sciences (2023020)。
文摘Phosphorus (P) is an essential nutrient element that is critical for plant growth and ecosystem functionality.The soil P cycle plays multiple roles,such as sustaining plant growth and productivity,regulating nutrient balance within ecosystems,and enhancing ecosystem adaptability and resilience.This cycle is influenced by factors such as the restoration approach and microbial community dynamics.However,the extent to which the restoration approach alters the P cycle in karst ecosystems and the underlying microbial mechanisms remain poorly understood.The P-cycle multifunctionality index (P-cycle MFI) serves as a comprehensive indicator for evaluating soil P cycle function,and it provides insights into changes in the P cycle between different restoration approaches.To investigate the shifts in soil P-cycle MFI and microbial mechanisms between different restoration approaches,we analyzed soil available P (AP),total P (TP),microbial biomass P (MBP),and the activities of acid phosphatase (ACP) and alkaline phosphatase (ALP).These data were used to calculate the P-cycle MFI by averaging the Z-scores between two restoration approaches(artificial restoration of forest (AF) and natural restoration of forest (NF)) and a control (cropland,CP) at six subtropical karst ecosystem sites in China.We also determined the soil organic carbon (SOC),exchangeable calcium (Ca) and magnesium (Mg),pH,bulk density (BD),microbial biomass C (MBC),and microbial biomass nitrogen (MBN),as well as the community structure,relative abundance,diversity indices,and co-occurrence networks of phoD-harboring bacteria.The results showed that the community structure of phoD-harboring bacteria varied significantly among AF,NF,and CP and across different temperature gradients.These bacteria exhibited increasing complexity and tightness in co-occurrence networks from CP to AF and then to NF,along with the ACP and ALP activities,but not the TP and AP contents.The P-cycle MFI values were significantly higher in NF compared to AF and CP,and the variation was significantly explained by restoration approach,temperature,MBC,MBN,SOC,exchangeable Ca,BD,community structure of phoD-harboring bacteria,and exchangeable Mg.Furthermore,natural restoration had a more substantial impact on the P-cycle MFI than temperature by enhancing SOC,microbial biomass,the complexity and co-occurrence network tightness of the phoD-harboring bacterial community structure,and ACP and ALP activities,but it reduced soil BD.The rare genera of phoD-harboring bacteria significantly influenced the variation of soil P-cycle MFI compared to the dominant genera.This study highlights the importance of rare genera of phoD-harboring bacteria in driving soil P-cycle multifunctionality in karst ecosystems,with natural restoration being more effective than artificial methods for enhancing soil organic matter and microbial community complexity.
基金the National Natural Science Foundation of China(Nos.62374029,22175029,62474033,and W2433038)the Young Elite Scientists Sponsorship Program by CAST(No.YESS20220550)+2 种基金the Sichuan Science and Technology Program(No.2024NSFSC0250)the Natural Science Foundation of Shenzhen Innovation Committee(JCYJ20210324135614040)the Fundamental Research Funds for the Central Universities of China(No.ZYGX2022J032).
文摘Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bottleneck,severely affecting device stability and long-term operational performance.Herein,we present a multifunctional strategy by incorporating highly thermally conductive Ti_(3)C_(2)T_(X) MXene nanosheets into the perovskite layer to simultaneously enhance thermal management and optoelectronic properties.The Ti_(3)C_(2)T_(X) nanosheets,embedded at perovskite grain boundaries,construct efficient thermal conduction pathways,significantly improving the thermal conductivity and diffusivity of the film.This leads to a notable reduction in the device’s steady-state operating temperature from 42.96 to 39.97 under 100 mW cm^(−2) illumination,thereby alleviating heat-induced performance degradation.Beyond thermal regulation,Ti_(3)C_(2)T_(X),with high conductivity and negatively charged surface terminations,also serves as an effective defect passivation agent,reducing trap-assisted recombination,while simultaneously facilitating charge extraction and transport by optimizing interfacial energy alignment.As a result,the Ti_(3)C_(2)T_(X)-modified PSC achieve a champion PCE of 25.13%and exhibit outstanding thermal stability,retaining 80%of the initial PCE after 500 h of thermal aging at 85 and 30±5%relative humidity.(In contrast,control PSC retain only 58%after 200 h.)Moreover,under continuous maximum power point tracking in N2 atmosphere,Ti_(3)C_(2)T_(X)-modified PSC retained 70%of the initial PCE after 500 h,whereas the control PSC drop sharply to 20%.These findings highlight the synergistic role of Ti_(3)C_(2)T_(X) in thermal management and optoelectronic performance,paving the way for the development of high-efficiency and heat-resistant perovskite photovoltaics.
基金supported by the Science and Technology Guidance Project of China National Textile and Apparel Council (Grant No.2024033)the Jiangsu Provincial Key Research and Development Program (Grant No.BE2019045)。
文摘The development of multifunctional intelligent textiles has become an important innovation direction in the field of textile engineering, under the dual demands of intelligent health monitoring and environmental protection. Although singlefunctional textiles with antibacterial, photochromic, and strain-sensing properties have been developed, they are unable to meet the demand for multifunctional textiles. In this respect, this study developed a poly(lactic acid) and poly(3-hydroxybutyrate)/thermoplastic polyurethane/carbon black nanoparticle composite nanofiber yarn(PPTCY) with a hollow-core-sheath structure using a simple conjugate electrospinning technology. PPTCY possessed excellent mechanical strength and could be effectively woven. More importantly, it not only enabled real-time visual monitoring of ultraviolet(UV) intensity in the environment but also possessed excellent antibacterial properties and strain-sensing performance. Its ΔE value was up to 58.24, and its antibacterial rates against Escherichia coli and Staphylococcus aureus were both 99.99%. This fabric had excellent strainsensing performance, high linearity, and durability under both pressure and stretching deformations. This research provides favorable technical support for the application of intelligent textiles in the field of UV protection and traffic safety.
基金National Natural Science Foundation of China,No.42101252。
文摘Rapid regional population shifts and spatial polarization have heightened pressure on cultivated land—a critical resource demanding urgent attention amid ongoing urban-rural transition.This study selects Jiangsu province,a national leader in both economic and agricultural development,as a case area to construct a multidimensional framework for assessing the recessive morphological characteristics of multifunctional cultivated land use.We examine temporal dynamics,spatial heterogeneity,and propose an integrated zoning strategy based on empirical analysis.The results reveal that:(1)The recessive morphology index shows a consistent upward trend,with structural breaks in 2007 and 2013,and a spatial shift from“higher in the east and lower in the west”to“higher in the south and lower in the north.”(2)Coordination among sub-dimensions of the index has steadily improved.(3)The index is expected to continue rising in the next decade,though at a slower pace.(4)To promote coordinated multidimensional land-use development,we recommend a policy framework that reinforces existing strengths,addresses weaknesses,and adapts zoning schemes to current spatial conditions.This research offers new insights into multifunctional cultivated land systems and underscores their role in enhancing human well-being,securing food supply,and supporting sustainable urban-rural integration.
基金supported by the National Natural Science Foundation(32130068,32271634,and 32071597)CAS Key Laboratory of Forest Ecology and Silviculture,Institute of Applied Ecology,Chinese Academy of Sciences(KLFES-2025)。
文摘Urban forests are highly multifunctional and provide numerous ecological functions.Plant functional traits individually or jointly influence the ecological multifunctionality of tree species(TS-EMF)and can also modify TSEMF in response to environmental changes.However,there has been limited exploration of multitrait combinations for predicting TS-EMF across seasons and of trait thresholds that enhance TS-EMF.Here,for 10 dominant tree species in urban forests of Northeast China,14 traits were measured and four aboveground and three belowground ecological functions assessed in three seasons.Ecological functions and TS-EMF differed significantly throughout the seasons(P<0.05).Synergistic relationships were found between carbon sequestration and oxygen release,between cooling and humidification,and between organic carbon accumulation and nutrient cycling.Notably,aboveground multifunctionality played a leading role in TS-EMF.With seasonal changes,resource allocation shifted toward traits related to resource acquisition rather than conservation to maintain TS-EMF.The combination of traits that predicted TS-EMF varied by type,accounting for up to 66.45%of the variation.TS-EMF was primarily driven by leaf structure in spring and by nutrient accumulation in autumn.Leaf carbon content(LCC)consistently served as a stabilizing factor for predicting TS-EMF across seasons.At 36.5-36.8 mg g^(-1),LCC had its optimal effect on TS-EMF.Other traits in combination that positively influence total TS-EMF include leaf nitrogen content(3.43-3.45 mg g^(-1)),leaf phosphorus content(0.80-0.83 mg g^(-1)),and leaf area(65.86-68.43 cm^(2)).Within these specified trait thresholds,Morus alba and Quercus mongolica were identified as key species.These findings suggest that the trade-off between various ecological functions can be managed by altering plant traits across seasons.This approach could provide a theoretical foundation for enhancing the TS-EMF of urban forests through trait-based management,offering practical guidance for selecting tree species.
文摘Polymer nanocomposite coatings(PNCCs)are unprecedented generation of coatings engineered for displaying inexpensive and brilliant functional surface coatings with eminent corrosion guard,mechanical resistance,antimicrobial,chemical durability,electrical insulation,and UV aging features.Due to their widely anticipation in petroleum,applications in building,conveyance,aerospace,electronics,automobiles and energy,these multi-functional coatings have a tremendous leverage in human life,all technological and scientific subjects.Numerous applications have been made for multilateral polymers like polyurethane(PU),epoxy(EP),polyaniline(PANI)conductive polymer,polypyrrole(PPy),and etc,on various metallic surfaces especially,carbon steel substrate owing to their excellent resistance properties.Practically,nanomaterials can possess potential in the all-interdisciplinary domains of materials science and engineering,chemical and physical sciences,biological and health sciences.As known,the designed polymer nanocomposite coating paradigm is fundamentally constituted from polymer or resin as a vehicle and inorganic nanofillers(nanoparticles and nanocomposites).Some commercialized and excessively employed nanocontainers in polymer nanocomposite coating formulations,like ZnO,TiO_(2),carbon nanotubes(CNTs),clay,SiO_(2),Al_(2)O_(3),graphene,GO,CeO_(2),ZrO_(2),FeTiO_(3),etc were discussed.The current review covered the chemistry and potential applications of the largest utilized multifunctional polymer nanocomposite coatings such as EP,PU and other considerable PNCCs.Lately,a titanic attention was made for epoxy nanocomposites because of their distinct physicochemical characteristics,which result from the combined qualities of the nanoparticles and polymer material unity.In addition,the author incorporated some of his scientific contributions in this area represented in construction of innovative functional polymer nanocomposites for a variety of uses with high economic,industrial impacts and future orientation.Furthermore,some newly published applications of polymer nanocomposite coatings were incorporated and discussed.
基金supported by the Fundamental Research Funds for the Central Universities and Heilongjiang Provincial Natural Science Foundation of China(Grant No.YQ2020E009).
文摘Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic equipment.In this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.
基金supported by the Fundamental Research Funds of Chinese Academy of Forestry(Nos.CAFYBB2022SY037,CAFYBB2021ZA002 and CAFYBB2022QC002)the Basic Research Foundation of Yunnan Province(Grant No.202201AT070264).
文摘Soil microbial communities are key factors in maintaining ecosystem multifunctionality(EMF).However,the distribution patterns of bacterial diversity and how the different bacterial taxa and their diversity dimensions affect EMF remain largely unknown.Here,we investigated variation in three measures of diversity(alpha diversity,community composition and network complexity)among rare,intermediate,and abundant taxa across a latitudinal gradient spanning five forest plots in Yunnan Province,China and examined their contributions on EMF.We aimed to characterize the diversity distributions of bacterial groups across latitudes and to assess the differences in the mechanisms underlying their contributions to EMF.We found that multifaceted diversity(i.e.,diversity assessed by the three different metrics)of rare,intermediate,and abundant bacteria generally decreased with increasing latitude.More importantly,we found that rare bacterial taxa tended to be more diverse,but they contributed less to EMF than intermediate or abundant bacteria.Among the three dimensions of diversity we assessed,only community composition significantly affected EMF across all locations,while alpha diversity had a negative effect,and network complexity showed no significant impact.Our study further emphasizes the importance of intermediate and abundant bacterial taxa as well as community composition to EMF and provides a theoretical basis for investigating the mechanisms by which belowground microorganisms drive EMF along a latitudinal gradient.
基金supported by the National Natural Science Foundation of China(Grant Number 22350410379)Zhejiang Provincial Natural Science Foundation of China(LZ23B030003)+1 种基金the Fundamental Research Funds for the Central Universities(226-202400075)Ten Thousand Talent Program of Zhejiang Province.
文摘Separator modification is an effective approach to suppress dendrite growth to realize high-energy sodium metal batteries(SMBs)in practical applications,however,its success is mainly subject to surface modification.Herein,a separator with multifunctional layers composed of N-doped mesoporous hollow carbon spheres(HCS)as the inner layer and sodium fluoride(NaF)as the outer layer on commercial polypropylene separator(PP)is proposed(PP@HCS-NaF)to achieve stable cycling in SMB.At the molecular level,the inner HCS layer with a high content of pyrrolic-N induces the uniform Na^(+)flux as a potential Na^(+)redistributor for homogenous deposition,whereas its hollow mesoporous structure offers nanoporous buffers and ion channels to regulate Na^(+)ion distribution and uniform deposition.The outer layer(NaF)constructs the NaF-enriched robust solid electrolyte interphase layer,significantly lowering the Na^(+)ions diffusion barrier.Benefiting from these merits,higher electrochemical performances are achieved with multifunctional double-layered PP@HCS-NaF separators compared with single-layered separators(i.e.PP@HCS or PP@NaF)in SMBs.The Na‖Cu half-cell with PP@HCS-NaF offers stable cycling(280 cycles)with a high CE(99.6%),and Na‖Na symmetric cells demonstrate extended lifespans for over 6000 h at 1 mA cm^(-2)with a progressively stable overpotential of 9 mV.Remarkably,in Na‖NVP full-cells,the PP@HCS-NaF separator grants a stable capacity of~81 mA h g^(-1)after 3500 cycles at 1 C and an impressive rate capability performance(~70 mA h g^(-1)at 15 C).
基金support from the National Natural Science Foundation of China(NSFC,Grant No.52175341)Shandong Provincial Natural Science Foundation(Grant No.ZR2022JQ24)Funding Project of Jinan City’s New Twenty Items for Colleges and Universities(Grant No.202333038).
文摘Herein,a novel Janus-structured multifunctional membrane with integrated electromagnetic interference(EMI)shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation and vacuum-assisted filtration.Interestingly,within the polytetrafluoroethylene(PTFE)-carbon nanotube(CNT)-Fe_(3)O_(4)layer(FCFe),CNT nanofibers interweave with PTFE fibers to form a stable“silk-like”structure that effectively captures Fe_(3)O_(4)particles.By incorporating a highly conductive MXene layer,the FCFe/MXene(FCFe/M)membrane exhibits excellent electrical/thermal conductivity,mechanical properties,and flame retardancy.Impressively,benefiting from the rational regulation of component proportions and the design of a Janus structure,the FCFe/M membrane with a thickness of only 84.9μm delivers outstanding EMI shielding effectiveness of 44.56 dB in the X-band,with a normalized specific SE reaching 10,421.3 dB cm^(2)g^(-1),which is attributed to the“absorption-reflection-reabsorption”mechanism.Furthermore,the membrane demonstrates low-voltage-driven Joule heating and fast-response photothermal performance.Under the stimulation of a 3 V voltage and an optical power density of 320 mW cm^(-2),the surface temperatures of the FCFe/M membranes can reach up to 140.4 and 145.7℃,respectively.In brief,the FCFe/M membrane with anti-electromagnetic radiation and temperature regulation is an attractive candidate for the next generation of wearable electronics,EMI compatibility,visual heating,thermotherapy,and military and aerospace applications.
基金supported by the National Natural Science Foundation of China(52402247)the Innovative Funds Plan of Henan University of Technology(2020ZKCJ07)+1 种基金the Cultivation Project of Tuoxin Team in Henan University of Technology(2024TXTD14)the Doctoral Fund of Henan University of Technology(31401577)。
文摘Aqueous zinc-ion batteries(AZIBs)have garnered extensive attention as the promising energy storage technology owing to their high safety,cost-effectiveness,and environmental friendliness.Nevertheless,their practical application is hindered by critical challenges,including Hydrogen evolution reactions(HER)and non-uniform Zn deposition,which compromise electrochemical performance and cycling stability.Herein,we propose a multifunctional hybrid electrolyte additive consisting of vanillin and Dimethyl sulfoxide,designed to weaken the interaction between Zn^(2+)and H_(2)O molecules,effectively modulating the solvation shell structure.In situ optical microscopy shows the hybrid additive significantly suppresses HER and promotes Zn^(2+)deposition on the(002)plane,inhibiting dendritic growth.The Zn||Zn symmetric cells with hybrid additive exhibit exceptional cycling stability,achieving over 4000 h at 1.0 mA cm^(-2)/1.0 m A h cm^(-2).The research on hybrid additives presents significant potential for exploration,offering a promising approach to the development of durable AZIBs.
基金financial support from the Guangdong Basic and Applied Basic Research Foundation(No.2023A1515012218)Macao Science and Technology Development Fund(Nos.FDCT 0009/2020/AMJ,0027/2023/RIB1)+1 种基金National Natural Science Foundation of China(No.32301104)Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.23ptpy165).
文摘Hydrogel-based flexible sensors are emerging as ideal candidates for wearable devices and soft robotics.However,most current hydrogels possess limited physicochemical properties,which hinder their practical application in long-term and complex scenarios.Herein,inspired by the unique structure of the barnacle,we design multifunctional poly(DMAPA-co-PHEA)hydrogels(CP hydrogels)by employing multiple physical crosslinks in the presence of Ag nanoparticles and NaCl additives.Owing to the synergistic effect of cation-πinteractions,hydrophobic interactions,and ionic bonds,the CP hydrogels exhibit high stretchability(strain up to 1430%),strong adhesion(22.8 kPa),satisfactory antibacterial activity,stable anti-icing ability(<20 kPa after 20 icing-deicing cycles),and high electrical conductivity(18.5 mS/cm).Additionally,the CP hydrogels show fast and sensitive responsiveness and cycling stability and can attach directly to human skin to accurately detect both human motions and tiny physiological signals as a flexible wearable sensor.Collectively,this work significantly contributes a straightforward and efficient design strategy for the development of multifunctional hydrogels,broadening their application scenarios.
基金supported by the Scientific Research Project funded by the Qingdao Postdoctoral Science Foundation(No.QDBSH20230102075)the China Postdoctoral Science Foundation(No.2023M733337)the National Natural Science Foundation of China(No.U2141251).
文摘All maritime industries are plagued by marine biofouling pollution,which causes large economic and environmental costs.Therefore,there is an urgent need for ecofriendly alternatives that can effectively reduce the negative consequences of biofouling pollution.This study aimed to produce novel capsaicin-inspired amide derivatives(CIADs)with multifunctional antifouling features by introducing amide compounds to aromatic compounds via a Friedel-Crafts alkylation reaction.The structure of the CIADs was characterized using FTIR,1H NMR,13C NMR,and HRMS,and the comprehensive antifouling capacity was determined by thermal stability,anti-ultraviolet,antibacterial,anti-algal,and marine field experiments.CIADs showed good thermal stability and did not show obvious weight loss before 226°C.2,4-dihydroxy-3,5-diphenylimidemet-hylbenzophenone(DDB)had an excellent ultraviolet absorption effect,which was even better than that of 2-hydroxy-4-(octyloxy)benzophenone.The antibacterial and anti-algal rates of N-(2,4-dimethyl-3-chloro-5-benzamide-methyl-6-hydroxybenzyl)benzamide(NDCBHB)were more than 99.5%and 64.0%,respectively,and the surface of antifouling coating with NDCBHB(NDCBHB-AC)was covered with only a small amount of sludge and biofilm,its antifouling effect was better than that of chlorothalonil.The above work provides a reference for preparing green and multifunctional antifouling agents.
基金financially supported by the Key R&D Program of Zhejiang(No.2024SSYS0086)the National Natural Science Foundation of China(No.52302035).
文摘The growing demand for microwave absorbing materials to mitigate electromagnetic pollution has driven the exploration of efficient design strategies.However,traditional experimental approaches for optimizing multicomponent and multilayer structures are time-consuming.To rapidly predict and optimize the electromagnetic parameters of microwave absorbing materials,a machine learning-assisted design framework has been proposed.A series of graphene/SiO_(2)(GS)and graphene/BaTiO_(3)(GB)aerogels were prepared by electrospinning technology,and their electromagnetic parameter datasets were used to train a machine learning model.The model achieved a maximum prediction accuracy of 97.3%,significantly accelerating the design process.By integrating the predicted parameters into simulation software,gradient impedance structures were rapidly designed,yielding multifunctional aerogels with an ultrawideband absorption range of 3.26–17.30 GHz at a thickness of 20 mm.Compared with conventional methods,this machine learning strategy reduces the research cycle to mere weeks,enabling the fast and efficient design of high-performance absorbing materials.Additionally,the aerogel demonstrated excellent thermal insulation and soundproofing capabilities,underscoring its multifunctionality.This study demonstrates the potential of machine learning in accelerating the development of next-generation microwave absorbing materials.
基金supported by the Singapore National Research Foundation(NRFCRP26-2021-0003,NRF),for research conducted at the National University of Singaporethe support by the ARTIC(ADT-RP2-Low Loss and Tunable Ferroelectrics for Sub-6G Applications).
文摘Sodium-ion-based electrochromic device(SECD)has been identified as an appealing cost-effective alternative of lithium-based counterparts,only if it can address the challenges in association with the inadequate electrochromic performance.In this regard,the quantized strategy is a particularly promising approach owing to the large surface-to-volume ratio and high reaction activity.However,quantum dots inevitably suffer from volume changes and undesired aggregation during electrochemical cycling.Herein,bioinspired from the robust connection of alveoli in lung,we propose a stable electrode,where WO_(3) quantum dots(WQDs)are robustly anchored on Ti_(3)C_(2) MXene through the strong chemical bonds of W-O-Ti.Theoretical results reveal the fundamental mechanism of the volume changes within WQDs and the dynamic diffusion process of sodium ions.The WQD@MXene electrodes exhibit a nearly twofold enhancement in cycling performance(1000 vs 500 cycles),coloration speed(3.2 vs 6.0 s),and areal capacity(87.5 vs 43.9 mAhm^(-2) at 0.1 mA cm^(-2)),compared to those of the pristine WQD electrode.As a proof-of-concept demonstration,a smart house system integrated with SECDs demonstrates a“3-in-1”device,enabling a combination of energy-saving,energy storage,and display functionalities.The present work significantly advances the versatile applications of cost-effective electrochromic electronics in interdisciplinary.
基金the financial support from the project funded by the Education Department of Shaanxi Provincial Government(No.23JP116)the Natural Science Fund of Shaanxi Province(No.2024JC-YBMS-396)+1 种基金the National Natural Science Foundation of China(Nos.52171191 and 52371198)the Constructing National Independent Innovation Demonstration Zones(XM2024XTGXQ05).
文摘The proliferation of advanced electronics and devices has led to significant electromagnetic interference and pollution,resulting in heightened interest in electromagnetic interference(EMI)shielding materials in recent years.Carbon foam,as a typical porous carbonaceous material,demonstrates significant potential as an innovative EMI shielding material owing to its lightweight nature,exceptional porosity,flexibility,favorable processability,and environmental sustainability.Nonetheless,the configuration of carbon atoms within the carbon foam is significantly disordered,leading to its intrinsic conductivity being comparatively low.Consequently,its shielding efficacy cannot meet the standards required for commercial EMI materials.Herein,we propose a hierarchical engineering strategy to construct a carbon foam composite with high shielding efficacy.Specifically,the FeCo nanoparticles and carbon layer are concurrently integrated into the carbon foam matrix to modulate its magnetic characteristics and conductivity.The results demonstrate that the carbon-coated FeCo/carbon foam composite achieves a shielding effectiveness(SE)of 24 dB in the X-band,signifying a 240% improvement compared to the pristine carbon foam.Simultaneously,the composite also exhibits superior multifunctionalities involving flexibility,Joule heating,and hydrophobicity.This study provides a facile and effective routine to regulate the shielding efficacy of EMI shielding materials.
基金supported by the Natural Science Project of Zhengzhou Science and Technology Bureau(No.21ZZXTCX12)the Key Research and Development Program of Henan Province(No.221111220300)+1 种基金the Key Program of the National Natural Science Foundation of China(No.62333013)the Youth Backbone Teacher Training Program of Henan University of Technology(No.21420154).
文摘To facilitate real-time monitoring and recording of humidity in the environment and to satisfy the requirement for strain performance in certain applications(such as wearable devices),this paper proposes an in-situ method for synthesising Au nanoparticles on ZIF-67.In this study,an Au@ZIF-67 composite humidity-sensitive material was combined with flexible polyethylene terephthalate interdigitated electrodes to create an Au@ZIF-67 flexible humidity sensor.The prepared samples were characterised using X-ray diffraction,X-ray photoelectron spectroscopy,and transmission electron microscopy.The humidity-sensitive properties of the sensor were investigated,and its monitoring capabilities in applications involving respiration,gestures,skin,and baby diapers were tested.The experimental results indicate that compared with a pure ZIF-67 humidity sensor,the Au@ZIF-67(0.1Au@Z)flexible humidity sensor exhibits a 158.07%decrease in baseline resistance and a 51.66%increase in sensitivity to 95%relative humidity,and the hysteresis,response time,and recovery time are significantly reduced.Furthermore,the sensor exhibits excellent characteristics such as high resolution,repeatability,and stability.The obtained results regarding the material properties,humidity sensitivity,and practical application of non-contact humidity monitoring demonstrate that the prepared sensors exhibit excellent and comprehensive performance,indicating their broad prospects in wearable medical devices,wireless Internet of Things,humidity detection in complex environments,and intelligent integrated systems.
基金financially supported by the National Natural Science Foundation of China(No.52436003)the Science and Technology Program of Guangzhou(No.2024A04J3710).
文摘The traditional inflexible electromagnetic interference(EMI)shielding materials have poor adaptability to wearable and portable flexible electronic devices due to their shortcomings such as brittleness and difficulty in machinability.As an optimized alternative,the conductive polymer composites(CPCs)constructed by integrating MXene and polymer have become one of the most promising EMI shielding materials.To cope with the more harsh application conditions,the processing-structure-property relationship of MXene/polymer EMI shielding composites urgently needs to be clarified.In this review,the EMI shielding mechanism and theory of CPCs are first outlined.Then,the recent advances in processing strategies for MXene/polymer EMI shielding composites with different structures are comprehensively summarized,including layered structure,segregated structure,and porous structure.Next,the multifunctionality of MXene/polymer EMI shielding composites in hydrophobicity,flame retardancy,thermal conductivity,infrared thermal camouflage,electrothermal conversion,photothermal conversion,and sensing function,is systematically introduced.Finally,the prospects and challenges for the future development and application of multifunctional MXene/polymer EMI shielding composites are discussed.This review aims to put forward effective guidance for fabricating intelligent,adaptable,and integrated MXene/polymer EMI shielding composites,thus promoting the upgrading of advanced MXene-based CPCs.
基金This work was supported by the Tianshan Programme of Excellence(2022TSYCCX0001)the National Key Program for Basic Research and Development(973 Program)(2012CB417101)。
文摘In recent years,soil acidification has been expanding in many areas of Asia due to increasing reactive nitrogen inputs and industrial activities,which may seriously affect the performance of various ecosystem functions.However,the underlying patterns and processes of ecosystem multifunctionality(EMF)are largely unknown at different levels of pH,limiting our understanding of how EMF respond to drivers.This study aims to explore threshold of pH on changes in EMF and differences in the drivers for the changes in EMF on either side of each of the determined pH thresholds.We collected nutrient and environmental databases for raster-level sampling data,totaling 4,000 sampling points.Averaging and cluster-multiple-threshold approach were used to calculate EMF,then quadratic and generalized additive models and Mann-Whitney U were used to determine and test the pH thresholds for changes in EMF,structural equation modellings and variance partitioning analysis were used to explore the main drivers on changes in EMF.The pH threshold for EMF changes in Chinese terrestrial ecosystems is 6.0.When pH<6.0,climate was consistently more important in controlling the variation of EMF than other variables;when pH≥6.0,soil was consistently more important in controlling the variation of EMF than other variables.Specifically,when pH<6.0,mean annual temperature was the main factor in regulating the EMF variation;when pH≥6.0,soil moisture was the main factor in regulating the EMF variation.Our study provides important scientific value for the mechanism of maintaining EMF under global change.For example,with further increases in global nitrogen deposition,leading to increased soil acidification,there are different impacts on EMF in different regions.It may lead to a decrease in EMF in acidic soils and an increase in EMF in alkaline soils.This suggests different management strategies for different regions to maintain EMF stability in the context of future global changes.In the future,more attention should be paid to the biological mechanisms regulating EMF.
基金supported by the National Natural Science Foundation of China(Nos.22174082,22374085)the Key Research and Development Program of Shandong Province(No.2021ZDSYS30)Qingdao Postdoctoral Innovation Project Funding(No.QDBSH20220201038)。
文摘An all-solid-state ion-selective electrode(ISE)for the detection of potassium ions in complex media was developed based on functional peptides with both antibacterial and antifouling properties.While exhibiting unique antifouling property,the ISE capitalized on the high surface area of the conductive metalorganic framework(MOF)solid transducer layer to facilitate rapid ion-electron transfer,consequently improving the electrode stability.For a short period,the application of a±1 n A current to the ISE resulted in a slight potential drift of 2.5μV/s,while for a long-term stability test,the ISE maintained a stable Nernstian response slope over 8 days.The antifouling and antibacterial peptide effectively eradicated bacteria from the electrode surface while inhibited the adhesion of bacteria and other biological organisms.Both theoretical calculations and experimental results indicated that the incorporation of peptides in the sensing membrane did not compromise the detection performance of the ISE.The prepared antifouling potassium ion-selective electrode exhibited a Nernstian response range spanning from 1.0×10^(–8)mol/L to 1.0×10–3mol/L,with a detection limit of 2.51 nmol/L.Crucially,the prepared solid-contact ISE maintained excellent antifouling and sensing capabilities in actual seawater and human urine,indicating a promising feasibility of this strategy for constructing ISEs suitable for practical application in complex systems.
