Multiferroic tunnel junctions(MFTJs),which combine tunneling magnetoresistance(TMR)and electroresistance(TER)efects,have emerged as key candidates for data storage.Two-dimensional van der Waals(vdW)MFTJs,in particular...Multiferroic tunnel junctions(MFTJs),which combine tunneling magnetoresistance(TMR)and electroresistance(TER)efects,have emerged as key candidates for data storage.Two-dimensional van der Waals(vdW)MFTJs,in particular,are promising spintronic devices for the post-Moore era.However,these vdW MFTJs are typically based on multiferroics composed of ferromagnetic and ferroelectric materials or multilayer magnetic materials with sliding ferroelectricity,which increases device fabrication complexity.In this work,we design a vdW MFTJ using bilayer MoPtGe_(2)S_(6),a material with homologous multiferroicity in each monolayer,combined with symmetric PtTe_(2)electrodes.Using frst-principles calculations based on density functional theory and nonequilibrium Green's functions,we theoretically explore the spin-polarized electronic transport properties of this MFTJ.By controlling the ferroelectric and ferromagnetic polarization directions of bilayer MoPtGe_(2)S_(6),the MFTJ can exhibit six distinct non-volatile resistance states,with maximum TMR(137%)and TER(1943%)ratios.Under biaxial strain,TMR and TER can increase to 265%and 4210%,respectively.The TER ratio also increases to 2186%under a 0.1 V bias voltage.Remarkably,the MFTJ exhibits a pronounced spin-fltering and a signifcant negative diferential resistance efect.These fndings not only highlight the potential of monolayer multiferroic MoPtGe_(2)S_(6)for MFTJs but also ofer valuable theoretical insights for future experimental investigations.展开更多
Ferromagnetic materials play an important role in memory materials,but conventional control methods are often limited by issues such as high power consumption and volatility.Multiferroic heterostructures provide a pro...Ferromagnetic materials play an important role in memory materials,but conventional control methods are often limited by issues such as high power consumption and volatility.Multiferroic heterostructures provide a promising alternative to achieve low power consumption and nonvolatile electric control of magnetic properties.In this paper,a two-dimensional multiferroic van der Waals heterostructure OsCl_(2)/Sc_(2)CO_(2),which is composed of ferromagnetic monolayer OsCl_(2)and ferroelectric monolayer Sc_(2)CO_(2),is studied by first-principles density functional theory.The results show that by reversing the direction of the electric polarization of Sc_(2)CO_(2),OsCl_(2)can be transformed from a semiconductor to a half-metal,demonstrating a nonvolatile electrical manipulation of the heterostructure through ferroelectric polarization.The underlying physical mechanism is explained by band alignments and charge density differences.Furthermore,based on the heterostructure,we construct a multiferroic tunnel junction with a tunnel electroresistance ratio of 3.38×10^(14)%and a tunnel magnetoresistance ratio of 5.04×10^(6)%,allowing control of conduction states via instantaneous electric or magnetic fields.The findings provide a feasible strategy for designing advanced nanodevices based on the giant tunnel electroresistance and tunnel magnetoresistance effects.展开更多
This paper investigates the frictional adhesive contact of a rigid,electrically/magnetically conductive spherical indenter sliding past a multiferroic coating deposed onto a rigid substrate,based on the hybrid element...This paper investigates the frictional adhesive contact of a rigid,electrically/magnetically conductive spherical indenter sliding past a multiferroic coating deposed onto a rigid substrate,based on the hybrid element method.The adhesion behavior is described based on the Maugis-Dugdale model.The adhesion-driven conjugate gradient method is employed to calculate the distribution of unknown pressures,while the discrete convolution-fast Fourier transform is utilized to compute the deformations,surface electric and magnetic potentials as well as the subsurface stresses,electric displacements,and magnetic inductions.The goal of this study is to investigate the influences of adhesion parameter,friction coefficient,coating thickness,and surface electric and magnetic charge densities on contact behaviors,such as contact area and pressures,electric and magnetic potentials,and subsurface stresses.展开更多
The adhesion enhancing effect induced by electro-magnetic loading and the adhesion weakening effect resulting from interfacial shear stress have been observed and widely reported in open literature.However,the adhesio...The adhesion enhancing effect induced by electro-magnetic loading and the adhesion weakening effect resulting from interfacial shear stress have been observed and widely reported in open literature.However,the adhesion behavior of multiferroic composites in the simultaneous presence of these two effects and the competitive mechanism between them are still unclear.In this paper,the non-slipping adhesive contact problem between a multiferroic half-space and a perfectly conducting rigid cylinder subject to multi-field loading is studied.The stated problem is reduced to a system of coupled singular integral equations,which are analytically solved with the analytical function theory.The closed-form solutions of the generalized stress fields including the contact stress,normal electric displacement,and magnetic induction are obtained.The stable equilibrium state of the adhesion system is determined with the Griffith energy balance criterion.The adhesion behavior subject to mechanical-electro-magnetic loading and a mismatch strain is discussed in detail.Numerical results indicate that exerting electro-magnetic loading can enhance the adhesion effect for both two types of multiferroic composites,namely,κ-class(non-oscillatory singularity)andε-class,which is different from the case of piezoelectric materials.It is found that the contact size finally decreases in the simultaneous presence of the electro-magnetic enhancing and shear-stress weakening effects.The results derived from this work not only are helpful to understand the contact behavior of multiferroic composites at micro/nano scale,but also have potential application value in achieving switchable adhesion.展开更多
We have investigated the magnetic, dielectric, pyroelectric, and thermal expansion properties of a layered perovskite metal–organic framework, [NH_(4)Cl]_(2)[Ni(HCOO)_(2)(NH_(3))_(2)]. The material undergoes three ph...We have investigated the magnetic, dielectric, pyroelectric, and thermal expansion properties of a layered perovskite metal–organic framework, [NH_(4)Cl]_(2)[Ni(HCOO)_(2)(NH_(3))_(2)]. The material undergoes three phase transitions including a canted antiferromagnetic transition at ~36 K, and two successive structural transitions around 100 K and 110 K, respectively. The temperature dependence of dielectric permittivity and pyroelectric current suggests that the structural transitions induce weak ferroelectricity along the c-axis and antiferroelectricity in the ab plane. A negative thermal expansion along the c-axis is observed between two structural phase transitions, which is ascribed to the abnormal shrinkage of interlayer hydrogen bonding length. Moreover, the ferroelectric/antiferroelectric phase transition temperature shifts towards a higher temperature under a magnetic field, suggesting certain magnetoelectric coupling in the paramagnetic phase. Our study suggests that the layered metal–organic frameworks provide a unique playground for exploring exotic physical properties such as multiferroicity and abnormal thermal expansion.展开更多
The switching characteristics of ferroelectrics and multiferroics are influenced by the interaction of topological defects with domain walls.We report on the pinning of polarization due to antiphase boundaries in thin...The switching characteristics of ferroelectrics and multiferroics are influenced by the interaction of topological defects with domain walls.We report on the pinning of polarization due to antiphase boundaries in thin films of the multiferroic hexagonal YbFeO_(3).We have directly resolved the atomic structure of a sharp antiphase boundary(APB)in YbFeO_(3) thin films using a combination of aberration-corrected scanning transmission electron microscopy(STEM)and total energy calculations based on density-functional theory(DFT).We find the presence of a layer of FeO_(6) octahedra at the APB that bridges the adjacent domains.STEM imaging shows a reversal in the direction of polarization on moving across the APB,which DFT calculations confirm is structural in nature as the polarization reversal reduces the distortion of the FeO_(6) octahedral layer at the APB.Such APBs in hexagonal perovskites are expected to serve as domain-wall pinning sites and hinder ferroelectric switching of the domains.展开更多
Magneto-electro-elastic(MEE)materials are a specific class of advanced smart materials that simultaneouslymanifest the coupling behavior under electric,magnetic,and mechanical loads.This unique combination ofpropertie...Magneto-electro-elastic(MEE)materials are a specific class of advanced smart materials that simultaneouslymanifest the coupling behavior under electric,magnetic,and mechanical loads.This unique combination ofproperties allows MEE materials to respond to mechanical,electric,and magnetic stimuli,making them versatile forvarious applications.This paper investigates the static and time-harmonic field solutions induced by the surface loadin a three-dimensional(3D)multilayered transversally isotropic(TI)linear MEE layered solid.Green’s functionscorresponding to the applied uniform load(in both horizontal and vertical directions)are derived using the Fourier-Bessel series(FBS)system of vector functions.By virtue of this FBS method,two sets of first-order ordinarydifferential equations(i.e.,N-type and LM-type)are obtained,with the expansion coefficients being Love numbers.It is noted that the LM-type system corresponds to the MEE-coupled P-,SV-,and Rayleigh waves,while the N-typecorresponds to the purely elastic SH-and Love waves.By applying the continuity conditions across interfaces,the solutions for each layer of the structure(from the bottom to the top)are derived using the dual-variable andposition(DVP)method.This method(i.e.,DVP)is unconditionally stable when propagating solutions throughdifferent layers.Numerical examples illustrate the impact of load types,layering,and frequency on the response ofthe structure,as well as the accuracy and convergence of the proposed approach.The numerical results are usefulin designing smart devices made of MEE solids,which are applicable to engineering fields like renewable energy.展开更多
In this paper, a three-dimensional finite-element formulation for the multiferroic composite is developed and implemented into the commercial software ABAQUS for its transient analysis. First, a special three-dimensio...In this paper, a three-dimensional finite-element formulation for the multiferroic composite is developed and implemented into the commercial software ABAQUS for its transient analysis. First, a special three-dimensional eight-node solid element is designed to handle the multiferroic composite made of elastic, piezoelectric, and piezomagnetic materials. Second, a userdefined subroutine for this newly developed element is implemented into ABAQUS. Finally, the transient responses of a bi-layered multiferroic composite are calculated by using the direct time integration method. Two typical magnetic potential signals, Gauss and Ricker pulses, are applied to the composite with various time durations of excitation. The induced electric field shows that the transient response can be substantially influenced by the input signal, which could be tuned for the strongest electric output.展开更多
The 0.6（Bi1-xLax）FeO 3-0.4SrTiO 3（x = 0,0.1） multiferroic ceramics are prepared by a modified Pechini method to study the effect of substitution of SrTiO3 and La in BiFeO3.The X-ray diffraction patterns confirm th...The 0.6（Bi1-xLax）FeO 3-0.4SrTiO 3（x = 0,0.1） multiferroic ceramics are prepared by a modified Pechini method to study the effect of substitution of SrTiO3 and La in BiFeO3.The X-ray diffraction patterns confirm the single phase characteristics of all the compositions each with a rhombohedral structure.The magnetic properties of the ceramics are significantly improved by a solid solution with SrTiO3 and substitution of La.The values of the dielectric constant ε r and loss tangent tan δ of all the samples decrease with increasing frequency and become constant at room temperature.The La-doped 0.6BiFeO3-0.4SrTiO3 ceramics exhibit improved dielectric and ferroelectric properties,with higher dielectric constant enhanced remnant polarization（Pr） and lower leakage current at room temperature.Compared with a anti-ferromagnetic BiFeO3 compound,the 0.6（Bi0.9La0.1）FeO3-0.4SrTiO3 sample shows the optimal ferromagnetism with remnant magnetization M r ～ 0.135 emμ/g and ferroelectricity with Pr ～ 5.94 μC/cm 2 at room temperature.展开更多
Multiferroic bi-layer Fe/BaTiO3 （BTO） thin films were successfully deposited on Pt（200）/MgO（100） substrates using ion beam sputter deposition （1BSD）, and the mutiferroic properties were studied at room tempera...Multiferroic bi-layer Fe/BaTiO3 （BTO） thin films were successfully deposited on Pt（200）/MgO（100） substrates using ion beam sputter deposition （1BSD）, and the mutiferroic properties were studied at room temperature. X-ray diffraction （XRD） analyses showed that BTO films were c-axis oriented and epitaxially grown on platinum coated MgO substrates, and （110） epitaxial Fe films were subsequently grown on （001） BTO films. Fe/BTO bi-layer films showed good ferroelectric and ferromagnetic properties at room temperature and the multiferroic coupling was observed, which should be attributed to the hybridization of Fe and Ti occurring at the ferromagnetic-ferroelectric interface.展开更多
An analytical solution is obtained for a rotating multiferroic composite hollow cylinder made of radially polarized piezoelectric and piezomagnetic materials. Both the number of layers and the stacking sequence of the...An analytical solution is obtained for a rotating multiferroic composite hollow cylinder made of radially polarized piezoelectric and piezomagnetic materials. Both the number of layers and the stacking sequence of the composite cylinder can be arbitrary. General mechanical, electric and magnetic boundary conditions can be applied at both the inner and outer cylindrical surfaces. The state space method is employed so that only a 2×2 matrix is involved in the whole solving procedure. In the nu-merical experiments, the distributions of elastic, electric as well as magnetic fields in an internally pressurized rotating BaTiO3/CoFe2O4 composite hollow cylinder subjected to different boundary conditions are presented graphically. The results clearly show that the stress fields in a multiferroic composite cylinder are controllable.展开更多
The magnetic and dielectric properties of Sr-substituted Zn2-Y hexagonal ferrites （Ba2-x SrxZn2Fe12O22, 1.0 〈 x ≤ 1.5） are studied in this paper. Sr substitution will lead to the variation of cation occupation, wh...The magnetic and dielectric properties of Sr-substituted Zn2-Y hexagonal ferrites （Ba2-x SrxZn2Fe12O22, 1.0 〈 x ≤ 1.5） are studied in this paper. Sr substitution will lead to the variation of cation occupation, which influences both the magnetic and electric properties. As Sr content x rises from 1.0 to 1.5, magnetic hysteresis loop gets wider gradually and the permeability drops rapidly due to the transformation from ferrimagnetic to antiferromagnetic phase. Moreover, permittivity rises with increasing Sr content. Under a certain external magnetic field, the phase transition of helical spin structure of Ba0.5Srl.5Zn2Fe12O22 at about 295 K seems to open a possibility for the room-temperature ferroelectricity induced by magnetic field. But its low resistivity prevents the observation of ferroelectric and magnetoelectric properties at room-temperature.展开更多
Y-type hexaferrites with tunable conical magnetic structures are promising single-phase multiferroics that exhibit large magnetoelectric effects.We have investigated the influence of Co substitution on the magnetoelec...Y-type hexaferrites with tunable conical magnetic structures are promising single-phase multiferroics that exhibit large magnetoelectric effects.We have investigated the influence of Co substitution on the magnetoelectric properties in the Y-type hexaferrites Ba_(0.3)Sr_(1.7)Co_(x)Mg_(2-x)Fe_(12)O_(22)(x=0.0,0.4,1.0,1.6).The spin-induced electric polarization can be reversed by applying a low magnetic field for all the samples.The magnetoelectric phase diagrams of Ba_(0.3)Sr_(1.7)Co_(x)Mg_(2-x)Fe_(12)O_(22)are obtained based on the measurements of magnetic field dependence of dielectric constant at selected temperatures.It is found that the substitution of Co ions can preserve the ferroelectric phase up to a higher temperature,and thus is beneficial for achieving single-phase multiferroics at room temperature.展开更多
The multiferroicity in the RMn_(2)O_(5)family remains unclear,and less attention has been paid to its dependence on high-temperature(high-T)polarized configuration.Moreover,no consensus on the high-T space group symme...The multiferroicity in the RMn_(2)O_(5)family remains unclear,and less attention has been paid to its dependence on high-temperature(high-T)polarized configuration.Moreover,no consensus on the high-T space group symmetry has been reached so far.In view of this consideration,one may argue that the multiferroicity of RMn_(2)O_(5)in the low-T range depends on the poling sequence starting far above the multiferroic ordering temperature.In this work,we investigate in detail the variation of magnetically induced electric polarization in GdMn_(2)O_(5)and its dependence on electric field poling routine in the high-T range.It is revealed that the multiferroicity does exhibit qualitatively different behaviors if the high-T poling routine changes,indicating the close correlation with the possible high-T polarized state.These emergent phenomena may be qualitatively explained by the co-existence of two low-T polarization components,a scenario that was proposed earlier.One is the component associated with the Mn^(3+)–Mn^(4+)–Mn^(3+)exchange striction that seems to be tightly clamped by the high-T polarized state,and the other is the component associated with the Gd Mn^(3+)–Mn^(4+)–Mn^(3+)exchange striction that is free of the clamping.The present findings may offer a different scheme for the electric control of the multiferroicity in RMn_(2)O_(5).展开更多
A new sol-foam-gel method was developed to fabricate La-doped BiFeO3 muttiferroic materials. It was demonstrated that a gradual increase in the content of La-doped into BiFeO3 results in its structure changing from rh...A new sol-foam-gel method was developed to fabricate La-doped BiFeO3 muttiferroic materials. It was demonstrated that a gradual increase in the content of La-doped into BiFeO3 results in its structure changing from rhombohedral to orthorhombic. A study of other property changes indicates that La-doping in BiFeO3 enhances its ferromagnetism and ferroelectricity. A temperature-dependent magnetization study suggests that the magnetic property of La-doped BiFeO3 samples varied from antiferromagnetic to ferromagnetic as the content of La-doped into BiFeO3 increased from 0 to 20%. Unique temperature-dependent zero field cooling （ZFC） and field cooling （FC） magnetization behaviors were observed in 15% La-doped BiFeO3 -- its ZFC temperature-dependent magnetization being ferromagnetic and its FC temperature- dependent magnetization being antiferromagnetic. A possible mechanism of such an interesting M-T behavior is discussed.展开更多
Multiferroic NiFe2O4 （NFO）-BaTiO3 （BTO） bilayered thin films are epitaxially grown on （001） Nb-doped SrTiO3 （STO） substrates by pulsed-laser deposition （PLD）. Different growth sequences of NFO and BTO on the...Multiferroic NiFe2O4 （NFO）-BaTiO3 （BTO） bilayered thin films are epitaxially grown on （001） Nb-doped SrTiO3 （STO） substrates by pulsed-laser deposition （PLD）. Different growth sequences of NFO and BTO on the substrate yield two kinds of epitaxial heterostructures with （001）-orientation, i.e. （001）-NFO/（001）-BTO/substrate and （001）- BTO/（001）-NFO/substrate. Microstructure studies from x-ray diffraction （XRD） and electron microscopies show differences between these two heterostructures, which result in different multiferroic behaviours. The heterostructured composite films exhibit good coexistence of both ferroelectric and ferromagnetic properties, in particular, obvious magnetoelectric （ME） effect on coupling response.展开更多
The semi-quantum two-orbital exchange model is used to investigate the effect of small rare-earth ion substitution on orthorhombic RMnO 3 with A-type antiferromagnetic order,using the Monte Carlo algorithm,exact diago...The semi-quantum two-orbital exchange model is used to investigate the effect of small rare-earth ion substitution on orthorhombic RMnO 3 with A-type antiferromagnetic order,using the Monte Carlo algorithm,exact diagonalization,and zero-temperature optimization approaches.It is revealed that the substitution results in a rich multiferroic phase diagram where the coexisting A-type antiferromagnetic phase and spiral spin phase,pure spiral spin phase,coexisting spiral spin phase,the E-type antiferromagnetic phase,and the pure E-type antiferromagnetic phase emerge in sequence.The multiferroic phase transitions modulate substantially the electric polarization,which is consistent qualitatively with recent experiments.展开更多
An improved technique was used to prepare the ceramic samples of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18)(BRFNT,R=Eu,Sm,Nd,Bi,and La).The five-layer Aurivillius phase of the samples was confirmed by X-ray diffrac...An improved technique was used to prepare the ceramic samples of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18)(BRFNT,R=Eu,Sm,Nd,Bi,and La).The five-layer Aurivillius phase of the samples was confirmed by X-ray diffraction(XRD)without detectable impurities.BRFNT samples exhibit the pseudo-tetragonal except the orthorhombic BSmFNT samples.The characteristic plate-like morphology was revealed by field emission transmission electron microscopy(FETEM)images.At ambient tempe rature,all the samples present both ferroelectric and magnetic properties and BEuFNT shows the best ferroelectric behavior with its remanent polarization as high as 14.9μC/cm^(2)under 155 kV/cm,which is three times higher than that of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18).Moreover,the remanent magnetization of BEuFNT is increased up to 1.20 emu/g compared to that of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18)which is only 0.53 emu/g.With increasing radius of the introduced A-site ions,the ferroelectric phase transition temperature(T_(CE))is decreased while the magnetic phase transition temperature(T_(CM))fluctuates.The decrease in both T_(CE)and T_(CM) corresponds to the upward shift of the related Raman modes and vice versa,indicating that the T_(CE)and the T_(CM) depend not only on the t factor,but also on the strength of the covalent bonds.展开更多
Multiferroic composite structures are widely used in sensing,driving and communication.The study of their magnetoelectric(ME)behavior under various excitations is crucial.This study investigates the nonlinear ME influ...Multiferroic composite structures are widely used in sensing,driving and communication.The study of their magnetoelectric(ME)behavior under various excitations is crucial.This study investigates the nonlinear ME influence of a multilayer composite ring structure consisting of Terfenol-D(TD)magnetostrictive and lead zirconate titanate(PZT)piezoelectric rings utilizing a multiphysics field modeling framework based on the fully coupled finite element method.The ME coupling coefficient of the PZT/TD concentric composite ring is predicted using the linear piezoelectric constitutive model and the nonlinear magnetostrictive constitutive model,which is congruent to the experimental data.The effect of the interface area of a trilayered structure on the coupling performance at the resonant frequency is investigated,considering the magnitude and frequency of the magnetic field and keeping the material ratio constant.The ME coupling coefficient of a trilayered structure is larger than that of a bilayered structure with the same material ratio,and the maximum ME coupling coefficient of a trilayered structure increases nonlinearly with the increase in the interface area.At the resonant frequency,the structure's ME coupling performance is considerably improved.An optimization technique based on structural geometric design and magnetic field control is presented to optimize the ME coupling coefficient.展开更多
Multiferroic materials are promising candidates for next-generation multi-functional devices, because of the coexistence of multi-orders and the coupling between the orders. FeVO4 has been confirmed to be a multiferro...Multiferroic materials are promising candidates for next-generation multi-functional devices, because of the coexistence of multi-orders and the coupling between the orders. FeVO4 has been confirmed to be a multiferroic compound,since it exhibits both ferroelectricity and antiferromagnetic ordering at low temperatures. In this paper, we have performed careful Raman scattering measurements on high-quality Fe VO4 single crystals. The compound has a very rich phonon structure due to its low crystal symmetry（P- 1） and at least 47 Raman-active phonon modes have been resolved in the low and hightemperature spectra. Most of the observed modes are well assigned with aid of first-principles calculations and symmetry analysis. The present study provides an experimental basis for exploring spin-lattice coupling and the mechanism of multiferroicity in FeVO4展开更多
基金supported by the National Key R&D Program of China(Grant No.2022YFB3505301)the National Key R&D Program of Shanxi Province(Grant No.202302050201014)+1 种基金the National Natural Science Foundation of China(Grant No.12304148)the Natural Science Basic Research Program of Shanxi Province(Grant No.202203021222219)。
文摘Multiferroic tunnel junctions(MFTJs),which combine tunneling magnetoresistance(TMR)and electroresistance(TER)efects,have emerged as key candidates for data storage.Two-dimensional van der Waals(vdW)MFTJs,in particular,are promising spintronic devices for the post-Moore era.However,these vdW MFTJs are typically based on multiferroics composed of ferromagnetic and ferroelectric materials or multilayer magnetic materials with sliding ferroelectricity,which increases device fabrication complexity.In this work,we design a vdW MFTJ using bilayer MoPtGe_(2)S_(6),a material with homologous multiferroicity in each monolayer,combined with symmetric PtTe_(2)electrodes.Using frst-principles calculations based on density functional theory and nonequilibrium Green's functions,we theoretically explore the spin-polarized electronic transport properties of this MFTJ.By controlling the ferroelectric and ferromagnetic polarization directions of bilayer MoPtGe_(2)S_(6),the MFTJ can exhibit six distinct non-volatile resistance states,with maximum TMR(137%)and TER(1943%)ratios.Under biaxial strain,TMR and TER can increase to 265%and 4210%,respectively.The TER ratio also increases to 2186%under a 0.1 V bias voltage.Remarkably,the MFTJ exhibits a pronounced spin-fltering and a signifcant negative diferential resistance efect.These fndings not only highlight the potential of monolayer multiferroic MoPtGe_(2)S_(6)for MFTJs but also ofer valuable theoretical insights for future experimental investigations.
基金supported by the National Natural Science Foundation of China(Grant Nos.12074213,11574108,and 12104253)the National Key R&D Program of China(Grant No.2022YFA1403103)+2 种基金the Major Basic Program of the Natural Science Foundation of Shandong Province(Grant No.ZR2021ZD01)the Natural Science Foundation of Shandong Provincial(Grant No.ZR2023MA082)the Project of Introduction and Cultivation for Young Innovative Talents in Colleges and Universities of Shandong Province。
文摘Ferromagnetic materials play an important role in memory materials,but conventional control methods are often limited by issues such as high power consumption and volatility.Multiferroic heterostructures provide a promising alternative to achieve low power consumption and nonvolatile electric control of magnetic properties.In this paper,a two-dimensional multiferroic van der Waals heterostructure OsCl_(2)/Sc_(2)CO_(2),which is composed of ferromagnetic monolayer OsCl_(2)and ferroelectric monolayer Sc_(2)CO_(2),is studied by first-principles density functional theory.The results show that by reversing the direction of the electric polarization of Sc_(2)CO_(2),OsCl_(2)can be transformed from a semiconductor to a half-metal,demonstrating a nonvolatile electrical manipulation of the heterostructure through ferroelectric polarization.The underlying physical mechanism is explained by band alignments and charge density differences.Furthermore,based on the heterostructure,we construct a multiferroic tunnel junction with a tunnel electroresistance ratio of 3.38×10^(14)%and a tunnel magnetoresistance ratio of 5.04×10^(6)%,allowing control of conduction states via instantaneous electric or magnetic fields.The findings provide a feasible strategy for designing advanced nanodevices based on the giant tunnel electroresistance and tunnel magnetoresistance effects.
基金support from the National Natural Science Foundation of China(12102085)the Postdoctoral Science Foundation of China(2023M730504)+2 种基金the Sichuan Province Regional Innovation and Cooperation Project(2024YFHZ0210)supported by the European Union-NextGenerationEU through the Italian Ministry of University and Research under the following programs:(NM)PRIN2022(Projects of Relevant National Interest)grant no.2022SJ8HTC-Electroactive Gripper for Micro-Object Manipulation(ELFIN)(NM)PRIN2022 PNRR(Projects of Relevant National Interest)grant no.P2022MAZHX-Tribological Modeling for Sustainable Design of Industrial Frictional Interfaces(TRIBOSCORE).
文摘This paper investigates the frictional adhesive contact of a rigid,electrically/magnetically conductive spherical indenter sliding past a multiferroic coating deposed onto a rigid substrate,based on the hybrid element method.The adhesion behavior is described based on the Maugis-Dugdale model.The adhesion-driven conjugate gradient method is employed to calculate the distribution of unknown pressures,while the discrete convolution-fast Fourier transform is utilized to compute the deformations,surface electric and magnetic potentials as well as the subsurface stresses,electric displacements,and magnetic inductions.The goal of this study is to investigate the influences of adhesion parameter,friction coefficient,coating thickness,and surface electric and magnetic charge densities on contact behaviors,such as contact area and pressures,electric and magnetic potentials,and subsurface stresses.
基金Project supported by the National Natural Science Foundation of China(Nos.12272269,11972257,and 11472193)the Shanghai Pilot Program for Basic Researchthe Shanghai Gaofeng Project for University Academic Program Development。
文摘The adhesion enhancing effect induced by electro-magnetic loading and the adhesion weakening effect resulting from interfacial shear stress have been observed and widely reported in open literature.However,the adhesion behavior of multiferroic composites in the simultaneous presence of these two effects and the competitive mechanism between them are still unclear.In this paper,the non-slipping adhesive contact problem between a multiferroic half-space and a perfectly conducting rigid cylinder subject to multi-field loading is studied.The stated problem is reduced to a system of coupled singular integral equations,which are analytically solved with the analytical function theory.The closed-form solutions of the generalized stress fields including the contact stress,normal electric displacement,and magnetic induction are obtained.The stable equilibrium state of the adhesion system is determined with the Griffith energy balance criterion.The adhesion behavior subject to mechanical-electro-magnetic loading and a mismatch strain is discussed in detail.Numerical results indicate that exerting electro-magnetic loading can enhance the adhesion effect for both two types of multiferroic composites,namely,κ-class(non-oscillatory singularity)andε-class,which is different from the case of piezoelectric materials.It is found that the contact size finally decreases in the simultaneous presence of the electro-magnetic enhancing and shear-stress weakening effects.The results derived from this work not only are helpful to understand the contact behavior of multiferroic composites at micro/nano scale,but also have potential application value in achieving switchable adhesion.
基金Project supported by the National Key Research and Development Program of China (Grant No. 2021YFA1400303)the National Natural Science Foundation of China (Grant No. 12227806)。
文摘We have investigated the magnetic, dielectric, pyroelectric, and thermal expansion properties of a layered perovskite metal–organic framework, [NH_(4)Cl]_(2)[Ni(HCOO)_(2)(NH_(3))_(2)]. The material undergoes three phase transitions including a canted antiferromagnetic transition at ~36 K, and two successive structural transitions around 100 K and 110 K, respectively. The temperature dependence of dielectric permittivity and pyroelectric current suggests that the structural transitions induce weak ferroelectricity along the c-axis and antiferroelectricity in the ab plane. A negative thermal expansion along the c-axis is observed between two structural phase transitions, which is ascribed to the abnormal shrinkage of interlayer hydrogen bonding length. Moreover, the ferroelectric/antiferroelectric phase transition temperature shifts towards a higher temperature under a magnetic field, suggesting certain magnetoelectric coupling in the paramagnetic phase. Our study suggests that the layered metal–organic frameworks provide a unique playground for exploring exotic physical properties such as multiferroicity and abnormal thermal expansion.
基金supported by the National Science Foundation(NSF)(Grant Nos.DMR-2122070,2145797,and 1454618)by the Nebraska Center for Energy Sciences Research(NCESR)supported by NSF grants#2138259,#2138286,#2138307,#2137603,and#2138296。
文摘The switching characteristics of ferroelectrics and multiferroics are influenced by the interaction of topological defects with domain walls.We report on the pinning of polarization due to antiphase boundaries in thin films of the multiferroic hexagonal YbFeO_(3).We have directly resolved the atomic structure of a sharp antiphase boundary(APB)in YbFeO_(3) thin films using a combination of aberration-corrected scanning transmission electron microscopy(STEM)and total energy calculations based on density-functional theory(DFT).We find the presence of a layer of FeO_(6) octahedra at the APB that bridges the adjacent domains.STEM imaging shows a reversal in the direction of polarization on moving across the APB,which DFT calculations confirm is structural in nature as the polarization reversal reduces the distortion of the FeO_(6) octahedral layer at the APB.Such APBs in hexagonal perovskites are expected to serve as domain-wall pinning sites and hinder ferroelectric switching of the domains.
基金The National Science and Technology Council of Taiwan(Grant No.NSTC 111-2811-E-516 A49-534)provided financial support for this study。
文摘Magneto-electro-elastic(MEE)materials are a specific class of advanced smart materials that simultaneouslymanifest the coupling behavior under electric,magnetic,and mechanical loads.This unique combination ofproperties allows MEE materials to respond to mechanical,electric,and magnetic stimuli,making them versatile forvarious applications.This paper investigates the static and time-harmonic field solutions induced by the surface loadin a three-dimensional(3D)multilayered transversally isotropic(TI)linear MEE layered solid.Green’s functionscorresponding to the applied uniform load(in both horizontal and vertical directions)are derived using the Fourier-Bessel series(FBS)system of vector functions.By virtue of this FBS method,two sets of first-order ordinarydifferential equations(i.e.,N-type and LM-type)are obtained,with the expansion coefficients being Love numbers.It is noted that the LM-type system corresponds to the MEE-coupled P-,SV-,and Rayleigh waves,while the N-typecorresponds to the purely elastic SH-and Love waves.By applying the continuity conditions across interfaces,the solutions for each layer of the structure(from the bottom to the top)are derived using the dual-variable andposition(DVP)method.This method(i.e.,DVP)is unconditionally stable when propagating solutions throughdifferent layers.Numerical examples illustrate the impact of load types,layering,and frequency on the response ofthe structure,as well as the accuracy and convergence of the proposed approach.The numerical results are usefulin designing smart devices made of MEE solids,which are applicable to engineering fields like renewable energy.
基金supported by the National Natural Science Foundation of China (No.50775028)
文摘In this paper, a three-dimensional finite-element formulation for the multiferroic composite is developed and implemented into the commercial software ABAQUS for its transient analysis. First, a special three-dimensional eight-node solid element is designed to handle the multiferroic composite made of elastic, piezoelectric, and piezomagnetic materials. Second, a userdefined subroutine for this newly developed element is implemented into ABAQUS. Finally, the transient responses of a bi-layered multiferroic composite are calculated by using the direct time integration method. Two typical magnetic potential signals, Gauss and Ricker pulses, are applied to the composite with various time durations of excitation. The induced electric field shows that the transient response can be substantially influenced by the input signal, which could be tuned for the strongest electric output.
基金Project supported by the Science Foundation from the Ministry of Education,China (Grant Nos. 20090142120069 and 309020)the Special Scientific Foundation from the Chinese Central University (Grant No. 20102D006)
文摘The 0.6（Bi1-xLax）FeO 3-0.4SrTiO 3（x = 0,0.1） multiferroic ceramics are prepared by a modified Pechini method to study the effect of substitution of SrTiO3 and La in BiFeO3.The X-ray diffraction patterns confirm the single phase characteristics of all the compositions each with a rhombohedral structure.The magnetic properties of the ceramics are significantly improved by a solid solution with SrTiO3 and substitution of La.The values of the dielectric constant ε r and loss tangent tan δ of all the samples decrease with increasing frequency and become constant at room temperature.The La-doped 0.6BiFeO3-0.4SrTiO3 ceramics exhibit improved dielectric and ferroelectric properties,with higher dielectric constant enhanced remnant polarization（Pr） and lower leakage current at room temperature.Compared with a anti-ferromagnetic BiFeO3 compound,the 0.6（Bi0.9La0.1）FeO3-0.4SrTiO3 sample shows the optimal ferromagnetism with remnant magnetization M r ～ 0.135 emμ/g and ferroelectricity with Pr ～ 5.94 μC/cm 2 at room temperature.
基金Project supported by the Yeungnam University Research Grant in 2010Project (507111403888) supported by the National Science Foundation of China for International Communication and CooperationProject (50672034) supported by the National Natural Science Foundation of China
文摘Multiferroic bi-layer Fe/BaTiO3 （BTO） thin films were successfully deposited on Pt（200）/MgO（100） substrates using ion beam sputter deposition （1BSD）, and the mutiferroic properties were studied at room temperature. X-ray diffraction （XRD） analyses showed that BTO films were c-axis oriented and epitaxially grown on platinum coated MgO substrates, and （110） epitaxial Fe films were subsequently grown on （001） BTO films. Fe/BTO bi-layer films showed good ferroelectric and ferromagnetic properties at room temperature and the multiferroic coupling was observed, which should be attributed to the hybridization of Fe and Ti occurring at the ferromagnetic-ferroelectric interface.
基金supported by the National Natural Science Foundation of China (Nos. 10872179 and 10725210)the Zhejiang Provincial Natural Science Foundation of China (No. Y7080298)the Zijin Plan of Zhejiang University, China
文摘An analytical solution is obtained for a rotating multiferroic composite hollow cylinder made of radially polarized piezoelectric and piezomagnetic materials. Both the number of layers and the stacking sequence of the composite cylinder can be arbitrary. General mechanical, electric and magnetic boundary conditions can be applied at both the inner and outer cylindrical surfaces. The state space method is employed so that only a 2×2 matrix is involved in the whole solving procedure. In the nu-merical experiments, the distributions of elastic, electric as well as magnetic fields in an internally pressurized rotating BaTiO3/CoFe2O4 composite hollow cylinder subjected to different boundary conditions are presented graphically. The results clearly show that the stress fields in a multiferroic composite cylinder are controllable.
基金Project supported by the National Natural Science Foundation of China (Grant No 50702005)the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No 20070008027)the Beijing Municipal Commission of Education (Grant No SYS100080419)
文摘The magnetic and dielectric properties of Sr-substituted Zn2-Y hexagonal ferrites （Ba2-x SrxZn2Fe12O22, 1.0 〈 x ≤ 1.5） are studied in this paper. Sr substitution will lead to the variation of cation occupation, which influences both the magnetic and electric properties. As Sr content x rises from 1.0 to 1.5, magnetic hysteresis loop gets wider gradually and the permeability drops rapidly due to the transformation from ferrimagnetic to antiferromagnetic phase. Moreover, permittivity rises with increasing Sr content. Under a certain external magnetic field, the phase transition of helical spin structure of Ba0.5Srl.5Zn2Fe12O22 at about 295 K seems to open a possibility for the room-temperature ferroelectricity induced by magnetic field. But its low resistivity prevents the observation of ferroelectric and magnetoelectric properties at room-temperature.
基金Project supported by the National Natural Science Foundation of China(Grant No.51725104)Beijing Natural Science Foundation,China(Grant No.Z180009)。
文摘Y-type hexaferrites with tunable conical magnetic structures are promising single-phase multiferroics that exhibit large magnetoelectric effects.We have investigated the influence of Co substitution on the magnetoelectric properties in the Y-type hexaferrites Ba_(0.3)Sr_(1.7)Co_(x)Mg_(2-x)Fe_(12)O_(22)(x=0.0,0.4,1.0,1.6).The spin-induced electric polarization can be reversed by applying a low magnetic field for all the samples.The magnetoelectric phase diagrams of Ba_(0.3)Sr_(1.7)Co_(x)Mg_(2-x)Fe_(12)O_(22)are obtained based on the measurements of magnetic field dependence of dielectric constant at selected temperatures.It is found that the substitution of Co ions can preserve the ferroelectric phase up to a higher temperature,and thus is beneficial for achieving single-phase multiferroics at room temperature.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11804088,11234005,11374147,51431006,and 11704109)the National Key Research Program of China(Grant No.2016YFA0300101)the Research Project of Hubei Provincial Department of Education,China(Grant No.B2018146)
文摘The multiferroicity in the RMn_(2)O_(5)family remains unclear,and less attention has been paid to its dependence on high-temperature(high-T)polarized configuration.Moreover,no consensus on the high-T space group symmetry has been reached so far.In view of this consideration,one may argue that the multiferroicity of RMn_(2)O_(5)in the low-T range depends on the poling sequence starting far above the multiferroic ordering temperature.In this work,we investigate in detail the variation of magnetically induced electric polarization in GdMn_(2)O_(5)and its dependence on electric field poling routine in the high-T range.It is revealed that the multiferroicity does exhibit qualitatively different behaviors if the high-T poling routine changes,indicating the close correlation with the possible high-T polarized state.These emergent phenomena may be qualitatively explained by the co-existence of two low-T polarization components,a scenario that was proposed earlier.One is the component associated with the Mn^(3+)–Mn^(4+)–Mn^(3+)exchange striction that seems to be tightly clamped by the high-T polarized state,and the other is the component associated with the Gd Mn^(3+)–Mn^(4+)–Mn^(3+)exchange striction that is free of the clamping.The present findings may offer a different scheme for the electric control of the multiferroicity in RMn_(2)O_(5).
文摘A new sol-foam-gel method was developed to fabricate La-doped BiFeO3 muttiferroic materials. It was demonstrated that a gradual increase in the content of La-doped into BiFeO3 results in its structure changing from rhombohedral to orthorhombic. A study of other property changes indicates that La-doping in BiFeO3 enhances its ferromagnetism and ferroelectricity. A temperature-dependent magnetization study suggests that the magnetic property of La-doped BiFeO3 samples varied from antiferromagnetic to ferromagnetic as the content of La-doped into BiFeO3 increased from 0 to 20%. Unique temperature-dependent zero field cooling （ZFC） and field cooling （FC） magnetization behaviors were observed in 15% La-doped BiFeO3 -- its ZFC temperature-dependent magnetization being ferromagnetic and its FC temperature- dependent magnetization being antiferromagnetic. A possible mechanism of such an interesting M-T behavior is discussed.
基金Project supported by the State Key Development Program for Basic Research of China (Grant No 2002CB613303)the National High Technology Research and Development Program for Advanced Materials of China (Grant No 2006AA03Z101)the National Natural Science Foundation of China (Grant Nos 10574078 and 50621201)
文摘Multiferroic NiFe2O4 （NFO）-BaTiO3 （BTO） bilayered thin films are epitaxially grown on （001） Nb-doped SrTiO3 （STO） substrates by pulsed-laser deposition （PLD）. Different growth sequences of NFO and BTO on the substrate yield two kinds of epitaxial heterostructures with （001）-orientation, i.e. （001）-NFO/（001）-BTO/substrate and （001）- BTO/（001）-NFO/substrate. Microstructure studies from x-ray diffraction （XRD） and electron microscopies show differences between these two heterostructures, which result in different multiferroic behaviours. The heterostructured composite films exhibit good coexistence of both ferroelectric and ferromagnetic properties, in particular, obvious magnetoelectric （ME） effect on coupling response.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 51031004,11004027,and 11074113)the National Basic Research Program of China (Grant Nos. 2011CB922101 and 2009CB929501)the Priority Academic Program Development of Jiangsu Provincial Higher Education Institutions,China
文摘The semi-quantum two-orbital exchange model is used to investigate the effect of small rare-earth ion substitution on orthorhombic RMnO 3 with A-type antiferromagnetic order,using the Monte Carlo algorithm,exact diagonalization,and zero-temperature optimization approaches.It is revealed that the substitution results in a rich multiferroic phase diagram where the coexisting A-type antiferromagnetic phase and spiral spin phase,pure spiral spin phase,coexisting spiral spin phase,the E-type antiferromagnetic phase,and the pure E-type antiferromagnetic phase emerge in sequence.The multiferroic phase transitions modulate substantially the electric polarization,which is consistent qualitatively with recent experiments.
基金Project supported by the National Natural Science Foundation of China(51072177)。
文摘An improved technique was used to prepare the ceramic samples of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18)(BRFNT,R=Eu,Sm,Nd,Bi,and La).The five-layer Aurivillius phase of the samples was confirmed by X-ray diffraction(XRD)without detectable impurities.BRFNT samples exhibit the pseudo-tetragonal except the orthorhombic BSmFNT samples.The characteristic plate-like morphology was revealed by field emission transmission electron microscopy(FETEM)images.At ambient tempe rature,all the samples present both ferroelectric and magnetic properties and BEuFNT shows the best ferroelectric behavior with its remanent polarization as high as 14.9μC/cm^(2)under 155 kV/cm,which is three times higher than that of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18).Moreover,the remanent magnetization of BEuFNT is increased up to 1.20 emu/g compared to that of Bi_(5.75)R_(0.25)Fe_(1.4)Ni_(0.6)Ti_(3)O_(18)which is only 0.53 emu/g.With increasing radius of the introduced A-site ions,the ferroelectric phase transition temperature(T_(CE))is decreased while the magnetic phase transition temperature(T_(CM))fluctuates.The decrease in both T_(CE)and T_(CM) corresponds to the upward shift of the related Raman modes and vice versa,indicating that the T_(CE)and the T_(CM) depend not only on the t factor,but also on the strength of the covalent bonds.
基金supported by the National Key Research and Development Program of China(2018YFB0703500)the Natural Science Foundation of Beijing(3202001).
文摘Multiferroic composite structures are widely used in sensing,driving and communication.The study of their magnetoelectric(ME)behavior under various excitations is crucial.This study investigates the nonlinear ME influence of a multilayer composite ring structure consisting of Terfenol-D(TD)magnetostrictive and lead zirconate titanate(PZT)piezoelectric rings utilizing a multiphysics field modeling framework based on the fully coupled finite element method.The ME coupling coefficient of the PZT/TD concentric composite ring is predicted using the linear piezoelectric constitutive model and the nonlinear magnetostrictive constitutive model,which is congruent to the experimental data.The effect of the interface area of a trilayered structure on the coupling performance at the resonant frequency is investigated,considering the magnitude and frequency of the magnetic field and keeping the material ratio constant.The ME coupling coefficient of a trilayered structure is larger than that of a bilayered structure with the same material ratio,and the maximum ME coupling coefficient of a trilayered structure increases nonlinearly with the increase in the interface area.At the resonant frequency,the structure's ME coupling performance is considerably improved.An optimization technique based on structural geometric design and magnetic field control is presented to optimize the ME coupling coefficient.
基金Project supported by the National Basic Research Program of China(Grant No.2012CB921701)the National Natural Science Foundation of China(Grant Nos.11174367 and 11004243)+4 种基金the China Postdoctoral Science Foundationthe Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(Grant Nos.10XNI03814XNLF06and 14XNLQ03)
文摘Multiferroic materials are promising candidates for next-generation multi-functional devices, because of the coexistence of multi-orders and the coupling between the orders. FeVO4 has been confirmed to be a multiferroic compound,since it exhibits both ferroelectricity and antiferromagnetic ordering at low temperatures. In this paper, we have performed careful Raman scattering measurements on high-quality Fe VO4 single crystals. The compound has a very rich phonon structure due to its low crystal symmetry（P- 1） and at least 47 Raman-active phonon modes have been resolved in the low and hightemperature spectra. Most of the observed modes are well assigned with aid of first-principles calculations and symmetry analysis. The present study provides an experimental basis for exploring spin-lattice coupling and the mechanism of multiferroicity in FeVO4
