Based upon the thiophene-2,5-dicarboxylic acid(H_(2)Tdc),a novel[Sc_(3)(μ_(2)-OH)_(3)(CO_(2))_(4)O_(6)]n inorganic chain-based Sc-MOF with decorated nitrate ions,{[Sc_(3)(OH)_(2)(Tdc)_(3)(NO_(3))]⋅H_(2)O}_(∞)(AEU-1;...Based upon the thiophene-2,5-dicarboxylic acid(H_(2)Tdc),a novel[Sc_(3)(μ_(2)-OH)_(3)(CO_(2))_(4)O_(6)]n inorganic chain-based Sc-MOF with decorated nitrate ions,{[Sc_(3)(OH)_(2)(Tdc)_(3)(NO_(3))]⋅H_(2)O}_(∞)(AEU-1;AEU for Army Engineering University of PLA),was synthesized,which shows good water and chemical stabilities.Significantly,due to channel constriction accompanied by the polar window caused by introducing nitrate ions,AEU-1 exhibits high C_(2)H_(6)/C_(2)H_(4)adsorption selectivity comparable to many famous C_(2)H_(6)-selective MOFs,making it a promising candidate for the purification of methanol-to-olefin(MTO)products.Furthermore,theoretical investigations reveal that the introduced nitrate ions in AEU-1 as the main adsorption sites could provide strong interactions between the framework and C2H6/C3H6 in the full-contacting mode,leading to an increase in the adsorption enthalpies(Qst)of C_(2)H_(6)and C_(3)H_(6),and thus further improving the C_(2)H_(6)/C_(2)H_(4)and C_(3)H_(6)/C_(2)H_(4)adsorption selectivity.Our work could open up a new avenue for constructing MOFs with inorganic polar moieties as adsorption sites for one-step C_(2)H_(4)purification and C3H6 recovery from MTO mixtures with high selectivity.展开更多
研究按订单生产(make to order,MTO)模式下随机订单的准入策略.本文提出的准入决策方法分为两步,首先在考虑随机订单的不同属性基础上,采用TOPSIS(technique for order preference by similarity to an ideal solution)方法计算新到订...研究按订单生产(make to order,MTO)模式下随机订单的准入策略.本文提出的准入决策方法分为两步,首先在考虑随机订单的不同属性基础上,采用TOPSIS(technique for order preference by similarity to an ideal solution)方法计算新到订单与理想订单的接近程度,以此作为订单的综合收益,从而对新订单进行分层排序;其次采用MDP(Markov decision process)模型分别计算接受和拒绝订单的期望收益,从而决定是否接受该订单.研究发现,当市场需求接近或大于产能时,企业可从订单分层中获益;反之,市场需求显著小于产能时,分层不会带来额外收益.企业分层收益随需求增加或产能减少而递增,且与生产前置期呈倒U型关系.数值模拟发现,订单分层越精细,收益越大,且分层数约为需求与企业产能的比值时,订单分层收益接近最大值.展开更多
基金supported by the Youth Autonomous Innovation Funding from Army Engineering University of PLA(KYJBJKQTZQ23005)the Basic Discipline Incubation Funding from Army Engineering University of PLA(KYJBJKQTZK23011).
文摘Based upon the thiophene-2,5-dicarboxylic acid(H_(2)Tdc),a novel[Sc_(3)(μ_(2)-OH)_(3)(CO_(2))_(4)O_(6)]n inorganic chain-based Sc-MOF with decorated nitrate ions,{[Sc_(3)(OH)_(2)(Tdc)_(3)(NO_(3))]⋅H_(2)O}_(∞)(AEU-1;AEU for Army Engineering University of PLA),was synthesized,which shows good water and chemical stabilities.Significantly,due to channel constriction accompanied by the polar window caused by introducing nitrate ions,AEU-1 exhibits high C_(2)H_(6)/C_(2)H_(4)adsorption selectivity comparable to many famous C_(2)H_(6)-selective MOFs,making it a promising candidate for the purification of methanol-to-olefin(MTO)products.Furthermore,theoretical investigations reveal that the introduced nitrate ions in AEU-1 as the main adsorption sites could provide strong interactions between the framework and C2H6/C3H6 in the full-contacting mode,leading to an increase in the adsorption enthalpies(Qst)of C_(2)H_(6)and C_(3)H_(6),and thus further improving the C_(2)H_(6)/C_(2)H_(4)and C_(3)H_(6)/C_(2)H_(4)adsorption selectivity.Our work could open up a new avenue for constructing MOFs with inorganic polar moieties as adsorption sites for one-step C_(2)H_(4)purification and C3H6 recovery from MTO mixtures with high selectivity.
文摘研究按订单生产(make to order,MTO)模式下随机订单的准入策略.本文提出的准入决策方法分为两步,首先在考虑随机订单的不同属性基础上,采用TOPSIS(technique for order preference by similarity to an ideal solution)方法计算新到订单与理想订单的接近程度,以此作为订单的综合收益,从而对新订单进行分层排序;其次采用MDP(Markov decision process)模型分别计算接受和拒绝订单的期望收益,从而决定是否接受该订单.研究发现,当市场需求接近或大于产能时,企业可从订单分层中获益;反之,市场需求显著小于产能时,分层不会带来额外收益.企业分层收益随需求增加或产能减少而递增,且与生产前置期呈倒U型关系.数值模拟发现,订单分层越精细,收益越大,且分层数约为需求与企业产能的比值时,订单分层收益接近最大值.
