The main purpose of this study is to characterize the surface sediments of the Kokumbo artisanal gold mining sites in Metallic trace Elements (MTEs). A total of 12 samples of surface water sediments were collected for...The main purpose of this study is to characterize the surface sediments of the Kokumbo artisanal gold mining sites in Metallic trace Elements (MTEs). A total of 12 samples of surface water sediments were collected for this study. The samples were analyzed using the Atomic Absorption Spectrophotometer (AAS). The mean concentrations of Mn (611.37 mg/kg) and Zn (955.86 mg/kg) in the sediments were very high compared to the standard in unpolluted sediments. The enrichment factor (EF) shows that there is an enrichment of Mn at some sites (EF (Mn) > 2). The presence of As, Mn, and Zn is also highlighted by the geo-accumulation index (I-geo) which shows slight pollution in Mn (0 < I-geo (Mn) < 1) on some sites. Moderate pollution for As (1 < I-geo (As) < 2) was determined at the treatment site and high pollution in Zn at some sites in the area (I-geo (Zn) > 3). This study shows that the presence of Zn in the sediments is linked to artisanal gold mining activities. Indeed, Zn is much used for gold recovery. The statistical analysis (PCA) shows, on the one hand, natural mineralization of the sediments and addition of metals linked to anthropic activities corresponding to the erosion of mining discharges. The surface sediments of the Kokumbo mining sites show pollution in As, Mn, and Zn.展开更多
Spontaneous polarization due to symmetry breaking in the transition metal ditellurides(MTe_(2))family exhibits intriguing sliding ferroelectricity.Although theoretical predictions of MTe_(2)ferroelectric metals with n...Spontaneous polarization due to symmetry breaking in the transition metal ditellurides(MTe_(2))family exhibits intriguing sliding ferroelectricity.Although theoretical predictions of MTe_(2)ferroelectric metals with noncentrosymmetric stacking have been reported,the realization of such polarization structure remains a challenge.Here,we demonstrate the synthesis of PtTe_(2)with non-centrosymmetric stacking layers,in contrast to bulk AA stacking,achieved within a scanning transmission electron microscope(STEM)by irradiating amorphous PtxTeythin flms with an electron beam probe.Cross-sectional STEM imaging combined with frst-principles calculations reveals that the diverse stacking confgurations due to an intralayerπ-stacking system break centrosymmetry in PtTe_(2),giving rise to the out-of-plane polarization.Three-dimensional atomic positions identifed by the atomic electron tomography method further demonstrate the local distortions associated with the non-centrosymmetric stacking layers in PtTe_(2).The understanding of the atomic origin of polarization in PtTe_(2)is of signifcant importance for developing devices that integrate ferroelectricity with metallicity.展开更多
基于高分辨率图像对比法,利用同一卫星平台上空间分辨率19.5m的CCD相机图像对CBERS-02B卫星上空间分辨率为258m的WFI成像仪图像进行在轨MTF(modulate transfer function)测量,获得WFI(wide field imager)相机沿轨、跨轨与45o方向的MTF曲...基于高分辨率图像对比法,利用同一卫星平台上空间分辨率19.5m的CCD相机图像对CBERS-02B卫星上空间分辨率为258m的WFI成像仪图像进行在轨MTF(modulate transfer function)测量,获得WFI(wide field imager)相机沿轨、跨轨与45o方向的MTF曲线,并计算出3个方向的线扩展函数LSF(line spread function),获得3个方向的有效半带宽。结果表明WFI相机红波段跨轨、沿轨与45o方向的有效半带宽,即有效瞬时视场,分别为1.188,1.165与1.281个像元,近红外波段为1.258,1.195与1.326个像元。基于获得的MTF,利用维纳滤波法对WFI图像进行补偿,部分恢复了WFI图像的细部信息。展开更多
In the department of Zouan-Hounien, gold mining is booming. This activity, marked by the excavation of rocks and the use of chemicals such as mercury, is likely to contaminate the region’s groundwater resources and e...In the department of Zouan-Hounien, gold mining is booming. This activity, marked by the excavation of rocks and the use of chemicals such as mercury, is likely to contaminate the region’s groundwater resources and expose populations to serious diseases. This study aims to assess the health risks associated with the consumption of this water by the population. To this end, 72 groundwater samples were taken in eight (08) villages of the department at the rate of forty-six (46) well water samples and twenty-six (26) borehole water samples. A total of twenty-twenty-three wells and thirteen boreholes were sampled during two campaigns. An atomic absorption spectrometer (AAS) was used to determine the concentrations of metallic trace elements (MTEs), such as mercury (Hg), lead (Pb), cadmium (Cd), Arsenic (As), and iron (Fe) in the different samples. The daily exposure doses for oral ingestion (CDIing) and skin contact (Expderm) were calculated. The non-carcinogenic (HQ) and carcinogenic risks (CR) were estimated. The results show that the mean concentrations of Fe, Pb, Hg, As and Cd are respectively 2233.48 > 3.10 > 0.60 > 1.18 > 0.08 μg<span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">·</span>L<sup>-1</sup> in the wells and 2427.94 > 4.08 > 1.27 > 1.76 > 0.08 μg<span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">·</span>L<sup>-1</sup> in boreholes. Evaluating the risks to human health reveals that the mean values of hazard quotient (HQ) and cancer risk (CR) for all the elements in the wells and boreholes are lower than 1 and 10<sup>-4</sup> respectively in children and adults for oral and dermal exposure. However, at the oral exposure level, 9 wells and 6 boreholes recorded HQ and CR above the define<span>d critical limits. These values indicate that the occurrence of non-cancero</span>us and cancerous diseases in populations consuming these waters by contamination with mercury and arsenic is not excluded. Dermal exposure to MTEs also poses no potential health risk to the population.展开更多
文摘The main purpose of this study is to characterize the surface sediments of the Kokumbo artisanal gold mining sites in Metallic trace Elements (MTEs). A total of 12 samples of surface water sediments were collected for this study. The samples were analyzed using the Atomic Absorption Spectrophotometer (AAS). The mean concentrations of Mn (611.37 mg/kg) and Zn (955.86 mg/kg) in the sediments were very high compared to the standard in unpolluted sediments. The enrichment factor (EF) shows that there is an enrichment of Mn at some sites (EF (Mn) > 2). The presence of As, Mn, and Zn is also highlighted by the geo-accumulation index (I-geo) which shows slight pollution in Mn (0 < I-geo (Mn) < 1) on some sites. Moderate pollution for As (1 < I-geo (As) < 2) was determined at the treatment site and high pollution in Zn at some sites in the area (I-geo (Zn) > 3). This study shows that the presence of Zn in the sediments is linked to artisanal gold mining activities. Indeed, Zn is much used for gold recovery. The statistical analysis (PCA) shows, on the one hand, natural mineralization of the sediments and addition of metals linked to anthropic activities corresponding to the erosion of mining discharges. The surface sediments of the Kokumbo mining sites show pollution in As, Mn, and Zn.
基金supported by the National Key R&D Program of China(Grant Nos.2024YFA1208201,2022YFA1403000,and 2021YFA1400204)the National Natural Science Foundation of China(Grant Nos.52322311,12334001,52427802,12174432,12250710675,and 52461160301)the support from Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices(Grant No.2022B1212010008)。
文摘Spontaneous polarization due to symmetry breaking in the transition metal ditellurides(MTe_(2))family exhibits intriguing sliding ferroelectricity.Although theoretical predictions of MTe_(2)ferroelectric metals with noncentrosymmetric stacking have been reported,the realization of such polarization structure remains a challenge.Here,we demonstrate the synthesis of PtTe_(2)with non-centrosymmetric stacking layers,in contrast to bulk AA stacking,achieved within a scanning transmission electron microscope(STEM)by irradiating amorphous PtxTeythin flms with an electron beam probe.Cross-sectional STEM imaging combined with frst-principles calculations reveals that the diverse stacking confgurations due to an intralayerπ-stacking system break centrosymmetry in PtTe_(2),giving rise to the out-of-plane polarization.Three-dimensional atomic positions identifed by the atomic electron tomography method further demonstrate the local distortions associated with the non-centrosymmetric stacking layers in PtTe_(2).The understanding of the atomic origin of polarization in PtTe_(2)is of signifcant importance for developing devices that integrate ferroelectricity with metallicity.
文摘基于高分辨率图像对比法,利用同一卫星平台上空间分辨率19.5m的CCD相机图像对CBERS-02B卫星上空间分辨率为258m的WFI成像仪图像进行在轨MTF(modulate transfer function)测量,获得WFI(wide field imager)相机沿轨、跨轨与45o方向的MTF曲线,并计算出3个方向的线扩展函数LSF(line spread function),获得3个方向的有效半带宽。结果表明WFI相机红波段跨轨、沿轨与45o方向的有效半带宽,即有效瞬时视场,分别为1.188,1.165与1.281个像元,近红外波段为1.258,1.195与1.326个像元。基于获得的MTF,利用维纳滤波法对WFI图像进行补偿,部分恢复了WFI图像的细部信息。
文摘In the department of Zouan-Hounien, gold mining is booming. This activity, marked by the excavation of rocks and the use of chemicals such as mercury, is likely to contaminate the region’s groundwater resources and expose populations to serious diseases. This study aims to assess the health risks associated with the consumption of this water by the population. To this end, 72 groundwater samples were taken in eight (08) villages of the department at the rate of forty-six (46) well water samples and twenty-six (26) borehole water samples. A total of twenty-twenty-three wells and thirteen boreholes were sampled during two campaigns. An atomic absorption spectrometer (AAS) was used to determine the concentrations of metallic trace elements (MTEs), such as mercury (Hg), lead (Pb), cadmium (Cd), Arsenic (As), and iron (Fe) in the different samples. The daily exposure doses for oral ingestion (CDIing) and skin contact (Expderm) were calculated. The non-carcinogenic (HQ) and carcinogenic risks (CR) were estimated. The results show that the mean concentrations of Fe, Pb, Hg, As and Cd are respectively 2233.48 > 3.10 > 0.60 > 1.18 > 0.08 μg<span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">·</span>L<sup>-1</sup> in the wells and 2427.94 > 4.08 > 1.27 > 1.76 > 0.08 μg<span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">·</span>L<sup>-1</sup> in boreholes. Evaluating the risks to human health reveals that the mean values of hazard quotient (HQ) and cancer risk (CR) for all the elements in the wells and boreholes are lower than 1 and 10<sup>-4</sup> respectively in children and adults for oral and dermal exposure. However, at the oral exposure level, 9 wells and 6 boreholes recorded HQ and CR above the define<span>d critical limits. These values indicate that the occurrence of non-cancero</span>us and cancerous diseases in populations consuming these waters by contamination with mercury and arsenic is not excluded. Dermal exposure to MTEs also poses no potential health risk to the population.
