Rapid carrier recombination and slow charge transfer dynamics have significantly reduced the performance of photocatalytic hydrogen production.Construction of heterojunctions via utilizing the sulfur-edge and metal-ed...Rapid carrier recombination and slow charge transfer dynamics have significantly reduced the performance of photocatalytic hydrogen production.Construction of heterojunctions via utilizing the sulfur-edge and metal-edge sites of metal sulfide semiconductor for improving photocatalytic activity remains a significant challenge.Herein,a novel ZnIn_(2)S_(4)/MnS S-scheme heterojunction was prepared by hydrothermal synthesis to accelerate charge carrier transfer for efficient photocatalysis.Notably,ZnIn_(2)S_(4)/MnS exhibited excellent photocatalytic hydrogen evolution activity(7.95 mmol g^(-1)h^(-1))under visible light irradiation(≥420 nm),up to 4.7 times higher than that of pure ZnIn_(2)S_(4).Additionally,cycling experiments showed that ZM-2 remained high stability after four cycles.Density-functional theory(DFT)calculations and in situ XPS results confirm the formation of S-scheme heterojunction,indicating that the tight interfacial contact between ZnIn_(2)S_(4)and Mn S with the presence of Mn-S bonds(the unsaturated Mn edges of MnS and the uncoordinated S atoms in the edge of ZnIn_(2)S_(4))promoted faster charge transfer.Besides,the unsaturated S atom on the surface of Mn S is an active site with strong H+binding ability,which can effectively reduce the overpotential or activation barrier for hydrogen evolution.This study illustrates the critical influence of the interfacial Mn-S bond on the ZnIn_(2)S_(4)/MnS S-scheme heterojunction to achieve efficient photocatalytic hydrogen production and provides relevant guidance for carrying out rational structural/interfacial modulation.展开更多
The key role of oxide inclusions on the microstructure and mechanical property of a high-strength low-alloy steel was investigated.The field emission scanning electron microscope equipped with energy-dispersive spectr...The key role of oxide inclusions on the microstructure and mechanical property of a high-strength low-alloy steel was investigated.The field emission scanning electron microscope equipped with energy-dispersive spectrometry was used to characterize MnS precipitates.Oxide inclusions play an important role in the shape control of MnS precipitates.More oxides fovored to decrease the size and the aspect ratio of MnS precipitates.With less oxide inclusions in the steel,approximately over 16.7%MnS precipitates were with aspect ratio a>5 and pure MnS precipitates accounted for 75.9%in number.However,with more oxide inclusions in the steel,only 7.4%MnS precipitates were with a>5 and pure MnS precipitates accounted for 60.1%in number.Refinement of MnS by oxide inclusions improved the strength and inhibited the anisotropy.More oxide inclusions in the steel increased the yield strength and tensile strength of the steel in both longitudinal and transverse directions,and lowered the anisotropy of the mechanical property.展开更多
An overview of the current research status and control methods of MnS in non-quenched and tempered steel was provided.As a low-melting plastic inclusion,the morphology and distribution of MnS were influenced by variou...An overview of the current research status and control methods of MnS in non-quenched and tempered steel was provided.As a low-melting plastic inclusion,the morphology and distribution of MnS were influenced by various production processes.Therefore,control of MnS is a systematic problem that must be integrated into the entire production process.Based on the production process,the factors affecting the morphology and distribution of MnS in steel were introduced.The effects of oxygen activity,manganese,sulfur,and some alloys on MnS inclusion precipitation were summarized,mainly including MnS modification treatment and oxygen-sulfide composite precipitation control.It is believed that MnS precipitates during the solidification process of steel,and controlling the solidification cooling rate could effectively regulate the size and morphology of MnS,avoiding the precipitation of II-MnS.Additionally,by changing the deformation rate,deformation amount,deformation temperature during the hot deformation process,and heating time and temperature during heat treatment,the distribution and morphology of MnS could be improved.Through the fine control of the above process parameters,the number of II-MnS in steel could be effectively reduced,and their morphology could be improved,thereby enhancing the performance of non-quenched and tempered steel and promoting its wider application.Furthermore,applying laboratory research results to industrial production is an important direction for future research efforts in this field.展开更多
The inherent catalytic anisotropy of two-dimensional(2D) materials has limited the enhancement of LiO_(2) batteries(LOBs) performance due to the significantly different adsorption energies on 2D and edge surfaces.Tuni...The inherent catalytic anisotropy of two-dimensional(2D) materials has limited the enhancement of LiO_(2) batteries(LOBs) performance due to the significantly different adsorption energies on 2D and edge surfaces.Tuning the adsorption strength in 2D materials to the reaction intermediates is essential for achieving high-performance LOBs.Herein,a MnS/MoS_(2) heterostructure is designed as a cathode catalyst by adjusting the adsorption behavior at the surface.Different from the toroidal-like discharge products on the MoS_(2) cathode,the MnS/MoS_(2) surface displays an improved adsorption energy to reaction species,thereby promoting the growth of the film-like discharge products.MnS can disturb the layer growth of MoS_(2),in which the stack edge plane features a strong interaction with the intermediates and limits the growth of the discharge products.Experimental and theoretical results confirm that the MnS/MoS_(2) heterostructure possesses improved electron transfer kinetics at the interface and plays an important role in the adsorption process for reaction species,which finally affects the morphology of Li_2O_(2),In consequence,the MnS/MoS_(2) heterostructure exhibits a high specific capacity of 11696.0 mA h g^(-1) and good cycle stability over 1800 h with a fixed specific capacity of 600 mA h g^(-1) at current density of100 mA g^(-1) This work provides a novel interfacial engineering strategy to enhance the performance of LOBs by tuning the adsorption properties of 2D materials.展开更多
To clarify the deformation behavior of MnS inclusions in a non-quenched and tempered steel at three different positions (edge, 1/2 radius and center) in the cross-section of the billet in the course of hot rolling, is...To clarify the deformation behavior of MnS inclusions in a non-quenched and tempered steel at three different positions (edge, 1/2 radius and center) in the cross-section of the billet in the course of hot rolling, isothermal compression experiments were performed under the deformation temperature range from 1073 to 1473 K, the reduction rates from 25% to 75% and the strain rates from 0.01 to 10 s^(−1). The variations of deformability features (i.e., aspect ratios, size distributions, and morphologies) of MnS inclusions with those isothermal compression parameters were revealed. The evaluation of the probable maximum aspect ratio of MnS inclusions at the three different positions in the cross-section of the billet after hot rolling was examined using the statistical analysis of extreme values. Results showed that the number densities of MnS inclusions at three different positions (edge, 1/2 radius and center) in the cross-section of the steel billet only fluctuated slightly when the deformation parameters varied in the isothermal compression, while the average inclusion aspect ratios in all cases generally have a negative correlation with the deformation temperature and positive correlations with the reduction ratio and the strain rate. Statistical analysis reveals that larger inclusions deform more easily during hot rolling. The effect of rolling temperature on the extreme value of the aspect ratio of inclusions is the smallest, while the effects of initial size, reduction ratio and strain rate are more significant.展开更多
Effective design of nanoheterostructure anode with high ion/electron migration kinetics can give electrode with superior electrochemical performance.However,the design and preparation of nanoheterostructure composites...Effective design of nanoheterostructure anode with high ion/electron migration kinetics can give electrode with superior electrochemical performance.However,the design and preparation of nanoheterostructure composites with high-capacity and long cycling life in half and pouch full cells remain a big challenge.Here,a novel micro-pore MnS/Mn_(2)SnS_(4)heterostructure nanowire were in situ encapsulated into the N and S elements co-doped amorphous carbon tubes(abbreviated as(MnS/Mn_(2)SnS_(4))@N,S-ACTs)and showed superior energy storage properties in Na-/Li-ion half cells and pouch full cells.The Na-/Li-storage capabilities improvement are attribute to the strong synergistic effect between MnS/Mn_(2)SnS_(4)heterostructure and N,S-ACTs protective layer,the former induces an local built-in electric field between Mn_(2)Sn S_(4)and MnS during charging/discharging,accelerating interfacial ion/electron diffusion dynamics,the latter effective maintains the morphology and volume evolution during Na~+/Li~+charging/discharging,achieving a long-term cycling stability(e.g.,high discharge capacity of 79.2 mAh/g with the capacity retention of 79.3%can be gained after 2200 cycles at 3 C in(Mn S/Mn_(2)Sn S_(4))@N,S-ACTs//LiFePO_(4)pouch full cells;a high capacity of~34 mAh/g at 10 C can be got with a Coulombic efficiency of 100%after 1000 cycles in pouch(Mn S/Mn_(2)Sn S_(4))@N,S-ACTs//Na_(3)V_(2)(PO_(4))_(2)O_(2)F full cells.展开更多
基金the National Nature Science Foundation of China(No.22108069)Natural Science Foundation of Hunan Province,China(No.2021JJ40260)for the financial support。
文摘Rapid carrier recombination and slow charge transfer dynamics have significantly reduced the performance of photocatalytic hydrogen production.Construction of heterojunctions via utilizing the sulfur-edge and metal-edge sites of metal sulfide semiconductor for improving photocatalytic activity remains a significant challenge.Herein,a novel ZnIn_(2)S_(4)/MnS S-scheme heterojunction was prepared by hydrothermal synthesis to accelerate charge carrier transfer for efficient photocatalysis.Notably,ZnIn_(2)S_(4)/MnS exhibited excellent photocatalytic hydrogen evolution activity(7.95 mmol g^(-1)h^(-1))under visible light irradiation(≥420 nm),up to 4.7 times higher than that of pure ZnIn_(2)S_(4).Additionally,cycling experiments showed that ZM-2 remained high stability after four cycles.Density-functional theory(DFT)calculations and in situ XPS results confirm the formation of S-scheme heterojunction,indicating that the tight interfacial contact between ZnIn_(2)S_(4)and Mn S with the presence of Mn-S bonds(the unsaturated Mn edges of MnS and the uncoordinated S atoms in the edge of ZnIn_(2)S_(4))promoted faster charge transfer.Besides,the unsaturated S atom on the surface of Mn S is an active site with strong H+binding ability,which can effectively reduce the overpotential or activation barrier for hydrogen evolution.This study illustrates the critical influence of the interfacial Mn-S bond on the ZnIn_(2)S_(4)/MnS S-scheme heterojunction to achieve efficient photocatalytic hydrogen production and provides relevant guidance for carrying out rational structural/interfacial modulation.
基金the National Natural Science Foundation of China(Grant Nos.52274398 and U22A20171)S&T Program of Hebei(Grant Nos.20311005D and 20591001D)the High Steel Center(HSC)at North China University of Technology and Yanshan University,China.
文摘The key role of oxide inclusions on the microstructure and mechanical property of a high-strength low-alloy steel was investigated.The field emission scanning electron microscope equipped with energy-dispersive spectrometry was used to characterize MnS precipitates.Oxide inclusions play an important role in the shape control of MnS precipitates.More oxides fovored to decrease the size and the aspect ratio of MnS precipitates.With less oxide inclusions in the steel,approximately over 16.7%MnS precipitates were with aspect ratio a>5 and pure MnS precipitates accounted for 75.9%in number.However,with more oxide inclusions in the steel,only 7.4%MnS precipitates were with a>5 and pure MnS precipitates accounted for 60.1%in number.Refinement of MnS by oxide inclusions improved the strength and inhibited the anisotropy.More oxide inclusions in the steel increased the yield strength and tensile strength of the steel in both longitudinal and transverse directions,and lowered the anisotropy of the mechanical property.
基金support from the Project funded by China Postdoctoral Science Foundation(2022M720982).
文摘An overview of the current research status and control methods of MnS in non-quenched and tempered steel was provided.As a low-melting plastic inclusion,the morphology and distribution of MnS were influenced by various production processes.Therefore,control of MnS is a systematic problem that must be integrated into the entire production process.Based on the production process,the factors affecting the morphology and distribution of MnS in steel were introduced.The effects of oxygen activity,manganese,sulfur,and some alloys on MnS inclusion precipitation were summarized,mainly including MnS modification treatment and oxygen-sulfide composite precipitation control.It is believed that MnS precipitates during the solidification process of steel,and controlling the solidification cooling rate could effectively regulate the size and morphology of MnS,avoiding the precipitation of II-MnS.Additionally,by changing the deformation rate,deformation amount,deformation temperature during the hot deformation process,and heating time and temperature during heat treatment,the distribution and morphology of MnS could be improved.Through the fine control of the above process parameters,the number of II-MnS in steel could be effectively reduced,and their morphology could be improved,thereby enhancing the performance of non-quenched and tempered steel and promoting its wider application.Furthermore,applying laboratory research results to industrial production is an important direction for future research efforts in this field.
基金supported by the National Natural Science Foundation of China (52173286, 52207249)Major basic research project of Natural Science Foundation of Shandong Province (ZR2023ZD12)+1 种基金the State Key Laboratory of Marine Resource Utilization in South China Sea (Hainan University) (MRUKF2023013)Open Program of Guangxi Key Laboratory of Information Materials (221024-K)。
文摘The inherent catalytic anisotropy of two-dimensional(2D) materials has limited the enhancement of LiO_(2) batteries(LOBs) performance due to the significantly different adsorption energies on 2D and edge surfaces.Tuning the adsorption strength in 2D materials to the reaction intermediates is essential for achieving high-performance LOBs.Herein,a MnS/MoS_(2) heterostructure is designed as a cathode catalyst by adjusting the adsorption behavior at the surface.Different from the toroidal-like discharge products on the MoS_(2) cathode,the MnS/MoS_(2) surface displays an improved adsorption energy to reaction species,thereby promoting the growth of the film-like discharge products.MnS can disturb the layer growth of MoS_(2),in which the stack edge plane features a strong interaction with the intermediates and limits the growth of the discharge products.Experimental and theoretical results confirm that the MnS/MoS_(2) heterostructure possesses improved electron transfer kinetics at the interface and plays an important role in the adsorption process for reaction species,which finally affects the morphology of Li_2O_(2),In consequence,the MnS/MoS_(2) heterostructure exhibits a high specific capacity of 11696.0 mA h g^(-1) and good cycle stability over 1800 h with a fixed specific capacity of 600 mA h g^(-1) at current density of100 mA g^(-1) This work provides a novel interfacial engineering strategy to enhance the performance of LOBs by tuning the adsorption properties of 2D materials.
基金supported by the National Natural Science Foundation of China(Grant Nos.52074198,52374342 and U21A20113)also supported by the Department of Science and Technology of Hubei Province(Grant No.2023AFB603 and No.2023DJC140).
文摘To clarify the deformation behavior of MnS inclusions in a non-quenched and tempered steel at three different positions (edge, 1/2 radius and center) in the cross-section of the billet in the course of hot rolling, isothermal compression experiments were performed under the deformation temperature range from 1073 to 1473 K, the reduction rates from 25% to 75% and the strain rates from 0.01 to 10 s^(−1). The variations of deformability features (i.e., aspect ratios, size distributions, and morphologies) of MnS inclusions with those isothermal compression parameters were revealed. The evaluation of the probable maximum aspect ratio of MnS inclusions at the three different positions in the cross-section of the billet after hot rolling was examined using the statistical analysis of extreme values. Results showed that the number densities of MnS inclusions at three different positions (edge, 1/2 radius and center) in the cross-section of the steel billet only fluctuated slightly when the deformation parameters varied in the isothermal compression, while the average inclusion aspect ratios in all cases generally have a negative correlation with the deformation temperature and positive correlations with the reduction ratio and the strain rate. Statistical analysis reveals that larger inclusions deform more easily during hot rolling. The effect of rolling temperature on the extreme value of the aspect ratio of inclusions is the smallest, while the effects of initial size, reduction ratio and strain rate are more significant.
基金financial support from the project funded by National Natural Science Foundation of China(Nos.52372188,51902090)2023 Introduction of studying abroad talent program,Science Technology Program of Jilin Province(No.20220508141RC)+5 种基金the 111 Project(No.B13013)China Postdoctoral Science Foundation(No.2019M652546)Henan Province Postdoctoral Start-Up Foundation(No.1901017)Henan Normal University Doctoral Start-Up Project Foundation,“111”project(No.D17007)Henan Center for Outstanding Overseas Scientists(No.GZS2018003)the Dalian Revitalization Talents Program(No.2022RG01)。
文摘Effective design of nanoheterostructure anode with high ion/electron migration kinetics can give electrode with superior electrochemical performance.However,the design and preparation of nanoheterostructure composites with high-capacity and long cycling life in half and pouch full cells remain a big challenge.Here,a novel micro-pore MnS/Mn_(2)SnS_(4)heterostructure nanowire were in situ encapsulated into the N and S elements co-doped amorphous carbon tubes(abbreviated as(MnS/Mn_(2)SnS_(4))@N,S-ACTs)and showed superior energy storage properties in Na-/Li-ion half cells and pouch full cells.The Na-/Li-storage capabilities improvement are attribute to the strong synergistic effect between MnS/Mn_(2)SnS_(4)heterostructure and N,S-ACTs protective layer,the former induces an local built-in electric field between Mn_(2)Sn S_(4)and MnS during charging/discharging,accelerating interfacial ion/electron diffusion dynamics,the latter effective maintains the morphology and volume evolution during Na~+/Li~+charging/discharging,achieving a long-term cycling stability(e.g.,high discharge capacity of 79.2 mAh/g with the capacity retention of 79.3%can be gained after 2200 cycles at 3 C in(Mn S/Mn_(2)Sn S_(4))@N,S-ACTs//LiFePO_(4)pouch full cells;a high capacity of~34 mAh/g at 10 C can be got with a Coulombic efficiency of 100%after 1000 cycles in pouch(Mn S/Mn_(2)Sn S_(4))@N,S-ACTs//Na_(3)V_(2)(PO_(4))_(2)O_(2)F full cells.
