In order to develop a facile and precisely controlled approach to synthesize hierarchical mesoporous materials with tailored property, in this work, a novel study was carried out to fabricate montmorillonitechitosan h...In order to develop a facile and precisely controlled approach to synthesize hierarchical mesoporous materials with tailored property, in this work, a novel study was carried out to fabricate montmorillonitechitosan hollow and hierarchical mesoporous spheres(MMTNS@CS-HMPHS) based on single-template layer-by-layer(Lb L) assembly. Scanning electron microscopy(SEM), transmission electron microscopy(TEM), specific surface area analysis and X-ray photoelectron spectroscopy(XPS) analyses were carried out to characterize the morphology and surface properties of MMTNS@CS-HMPHS. Benefitting from the unique lamellar structure of MMTNS, mesoporous channels are formed on the shell of MMTNS@CS hollow spheres, resulting in high surface area. Moreover, the surface functionalization and pore size of MMTNS@CS-HMPHS can be easily tuned, due to the tailored property through Lb L assembly method.Besides the unique microstructure, MMTNS@CS-HMPHS also possesses the active sites generated from both MMT and chitosan, which greatly promotes its performance in fields of adsorption, drug delivery and catalyst supports, etc.展开更多
基金supported financially by the National Natural Science Foundation of China (Nos. 51874220 and 51674183)the Natural Science Foundation of Hubei Province of China (No. 2018CFB468)the Excellent Dissertation Cultivation Funds of Wuhan University of Technology (No. 2018-YS-050)
文摘In order to develop a facile and precisely controlled approach to synthesize hierarchical mesoporous materials with tailored property, in this work, a novel study was carried out to fabricate montmorillonitechitosan hollow and hierarchical mesoporous spheres(MMTNS@CS-HMPHS) based on single-template layer-by-layer(Lb L) assembly. Scanning electron microscopy(SEM), transmission electron microscopy(TEM), specific surface area analysis and X-ray photoelectron spectroscopy(XPS) analyses were carried out to characterize the morphology and surface properties of MMTNS@CS-HMPHS. Benefitting from the unique lamellar structure of MMTNS, mesoporous channels are formed on the shell of MMTNS@CS hollow spheres, resulting in high surface area. Moreover, the surface functionalization and pore size of MMTNS@CS-HMPHS can be easily tuned, due to the tailored property through Lb L assembly method.Besides the unique microstructure, MMTNS@CS-HMPHS also possesses the active sites generated from both MMT and chitosan, which greatly promotes its performance in fields of adsorption, drug delivery and catalyst supports, etc.
