Vitamin D deficiency(VDD)represents a significant nutritional concern among children and adolescents.The estimated prevalence of VDD in China is 46.8%in this population^([1]).VDD during childhood and adolescence has b...Vitamin D deficiency(VDD)represents a significant nutritional concern among children and adolescents.The estimated prevalence of VDD in China is 46.8%in this population^([1]).VDD during childhood and adolescence has been associated with the onset of various conditions,including acute respiratory infections,asthma,atopic dermatitis,and food allergies^([2]).Multiple factors,including age,sun exposure,adiposity,and genetics,influence vitamin D levels^([2,3]).Increasing attention has been directed toward understanding the environmental determinants that may influence vitamin D status.Given the potential of metallic pollutants to disrupt endocrine function and their ubiquity in the environment,investigating the effects of metal exposure on human vitamin D status,particularly in vulnerable populations,is imperative.展开更多
Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durabili...Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application.展开更多
Extracting rare earth elements(REEs)from coal refuse is challenging due to their low co ncentrations and poor leachability.Bioleaching has emerged as a sustainable technology to recover REEs from low-grade materials.I...Extracting rare earth elements(REEs)from coal refuse is challenging due to their low co ncentrations and poor leachability.Bioleaching has emerged as a sustainable technology to recover REEs from low-grade materials.In this study,a ferric sulfate bio acid(BA)with an acidity of~0.2 mol/L H^(+),generated through regulated pyrite bio-oxidation,was used to leach REEs and critical metals(CMs)from coal refuse(ground to<1 mm)after 20-min roasting at 600℃.The influences of solid/liquid(S/L)ratio(100-300 g/L)and leaching temperature(25-95℃)on the leaching performance were examined.The leaching mechanisms were investigated by conducting stepwise precipitation tests and spectroscopic characterization.Results show that raising the leaching temperature to≥65℃accelerated the REE leaching kinetics but causes the loss of light REEs(LREEs)after reaching peak values at 30-60 min.Stage precipitation tests reveal that the loss is due to the incorporation of REEs,especially for LREEs,by gypsum and schwertmannite.The peak total REE(TREE)recovery of the BA leaching reaches 24.9%after 30 min of leaching at75℃with a S/L ratio of 200 g/L.Implementing the three-stage counter-current leaching increases the overall TREE recovery to 31.8%by recovering the REEs incorporated in the Fe and Ca precipitates.Meanwhile,promising recovery values of Li(55.5%),Mn(74.6%),Ni(41.6%),and Co(35.3%)are also achieved.This method provides a sustainable approach to extract REEs and critical metals from coal waste materials with a high treatment capacity.展开更多
Heavy metal contamination is a global issue caused by anthropogenic activities leading to severe negative effects on the environment and human health.To address this problem,bioremediation strategies utilizing plants ...Heavy metal contamination is a global issue caused by anthropogenic activities leading to severe negative effects on the environment and human health.To address this problem,bioremediation strategies utilizing plants such as Typha latifolia and their symbiotic fungi have been adopted to remediate contaminated areas and mitigate the harmful effects of these pollutants.In this study,the endophytic fungus Neosartorya fischeri was isolated from the roots of T.latifolia plants growing in heavy metal-contaminated sites.N.fischeri colonized the epidermis and root cortex and showed high tolerance to toxic concentrations of silver(Ag)(1 mg/kg),copper(Cu)(60 mg/kg)and cadmium(Cd)(8 mg/kg).N.fischeri removed 8.7%±0.5%Cd from the medium,biosorbed 15.24±0.2 mg/kg into its biomass,and enhanced the tolerance and bioaccumulation of Cd(184.18±1.14 mg/kg)in plant roots.Moreover,N.fischeri produces siderophores,volatile compounds and solubilizes phosphates,which improve plant fitness.This was evidenced by a 28%increase in photosynthetic pigments in T.latifolia plants colonized with N.fischeri.Additionally,N.fischeri inhibits the growth of important phytopathogens from the Fusarium genus.These findings highlight the important role of N.fischeri in enhancing the fitness and resilience of T.latifolia in hostile environments,demonstrating the potential of N.fischeri-T.latifolia association for the bioremediation of contaminated sites.展开更多
The surge in environmental pollution in recent years driven by numerous pollutants has necessitated the search for efficient removal methods.Phytoremediation is an eco-friendly technique that provides multiple benefit...The surge in environmental pollution in recent years driven by numerous pollutants has necessitated the search for efficient removal methods.Phytoremediation is an eco-friendly technique that provides multiple benefits over conventional methods of removing contaminants.Despite the numerous benefits of this technique,it has certain limitations that can be addressed by incorporating nanoparticles to improve its effectiveness.This review paper aims to explore the impact of heavy metal pollution on plants and human health.It highlights the role and mechanism of nanoparticles in enhancing phytoremediation,their application in the detection of heavy metals,and the strategies for the safe disposal of phytoremediation biomass.Biosynthesized nanoparticles are eco-friendly and non-toxic,with applications in biomedical and environmental fields.Nanoparticles can be used in the form of nano biosensors like smartphone-operated wireless sensors made from Cinnamomum camphora,enabling efficient detection of heavy metal ions.According to the studies,nanoparticles remove 80%–97%of heavy metals by various methods like reduction,precipitation,adsorption,etc.The phytoremediation biomass disposal can be done by heat treatment,phytomining,and microbial treatment with some modifications to further enhance their results.Phytoremediation is an environmentally friendly technique but requires further research and integration with biomass energy production to overcome scalability challenges and ensure safe biomass disposal.展开更多
Dear Editor,With the growing food demands and the rapid development of intensive vegetable cultivation,the vegetable yield and planting area have increased to 230 million tons and 2.13 million hectares,respectively,in...Dear Editor,With the growing food demands and the rapid development of intensive vegetable cultivation,the vegetable yield and planting area have increased to 230 million tons and 2.13 million hectares,respectively,in China in 2021(MARAPRC,2023).展开更多
Coal mining activities significantly impact the environment through water,soil,and air pollution of the surrounding areas.The dispersal of pollutants and the degradation of soil quality by toxic metals emitted from co...Coal mining activities significantly impact the environment through water,soil,and air pollution of the surrounding areas.The dispersal of pollutants and the degradation of soil quality by toxic metals emitted from coal mining activities cause significant concerns worldwide,posing serious risks to ecosystems,human health,and vegetation.Restoration of quality of soil contaminated by toxic metals from coal mining is challenging due to the continuous increase in the concentration of toxic metals such as lead,copper,chromium,cadmium,and arsenic within the soil matrix.Conventional approaches utilized for the remediation of soil are often time-consuming and labour-intensive.In addition,they may lead to secondary pollution,particularly when applied at a large scale.Phytoremediation,a technique that utilizes plants with high metal accumulation capacity,has surfaced as a promising,eco-friendly strategy for remediating soil contaminated with toxic metals.These plants can absorb and sequester metals into above-and belowground tissues or stabilize them into less bioavailable forms within the rhizosphere.Species from families such as Brassicaceae and Asteraceae have demonstrated notable effectiveness in phytoremediation applications.The efficiency of phytoremediation can be further enhanced by applying organic and inorganic soil amendments to increase metal bioavailability and plant uptake.Moreover,genetic engineering has enabled the development of plants with improved metal tolerance and accumulation capacities.Complementing these approaches,microbial phytoremediation employs plant-associated microbes to facilitate metal uptake and transformation,increasing the overall remediation efficiency.Following remediation,biomass is proposed for value-added applications,including biochar,biogas,and recovery of metals for industrial reuse.This review summarizes the current progress,emerging strategies,and future prospects of phytoremediation for mitigating toxic metal pollution in coal mining-affected soils.Altogether,these approaches illustrate the potential of integrating circular bioeconomy principles in transforming phytoremediation as a sustainable strategy for mitigating toxic metal pollution in coal mining regions.展开更多
The ectomycorrhizal fungus Paxillus involutus was inoculated onto tissue-cultures of the hybrid poplar,Populus davidiana×P.bolleana,to evaluate the elemental defense effect to heavy metals copper and cadmium at d...The ectomycorrhizal fungus Paxillus involutus was inoculated onto tissue-cultures of the hybrid poplar,Populus davidiana×P.bolleana,to evaluate the elemental defense effect to heavy metals copper and cadmium at different concentrations by simulating Alternaria alternata fungus infection.The enrichment capacity of Populus davidiana×P.bolleana for Cu and Cd was closely associated with the degree of heavy metal stress.There was a significant positive interaction of applying Cu and Cd and the inoculation with P.involutus on A.alternata leaf blight disease index.The incidence rate and disease index of leaf blight underwent a significant reduction compared with the controls.Similarly,the ratio of the area of disease spot to leaf area,incidence rate,and disease index for Populus davidiana×P.bolleana leaves inoculated with Paxillus involutus(Batsch)Fr.were significantly lower than those of their nonmycorrhizal counterparts.With increasing the degree of Cu and Cd stress,a gradual increase in the average value of the membership function for the incidence rate and disease index was observed,indicating the weakened pathogen's ability to cause infection and the improved resistance of Populus davidiana×P.bolleana to leaf blight disease under Cu and Cd stress.Moreover,superoxide dismutase enzyme activity in Populus davidiana×P.bolleana increased significantly,reaching levels of 411.0 U/g FW and 421.6 U/g FW under Cu and Cd treatments,respectively.These changes in metabolic products and antioxidant enzyme activities suggest that P.involutus may enhance the resistance of Populus davidiana×P.bolleana to the fungus,Alternaria alternata Fr.Keissel under heavy metal stress by modulating these physiological indicators.展开更多
In 2021,approximately 537 million people suffered from diabetes mellitus(DM)globally,and this figure will increase to approximately 783 million within the next quarter-century.The increasing burden of DM is a pressing...In 2021,approximately 537 million people suffered from diabetes mellitus(DM)globally,and this figure will increase to approximately 783 million within the next quarter-century.The increasing burden of DM is a pressing global public health issue.Therefore,the early identification of high-risk groups and implementation of effective intervention measures is imperative.展开更多
The recovery of precious metals(PMs)from secondary resources is critical for addressing global supply-chain vulnerabilities and sustainable resource utilization.This review systematically examines the transformative p...The recovery of precious metals(PMs)from secondary resources is critical for addressing global supply-chain vulnerabilities and sustainable resource utilization.This review systematically examines the transformative potential of metal-organic frameworks(MOFs)as next-generation adsorbents for PM recovery,focusing on their synthesis,functionalization,and multiscale adsorption mechanisms.We critically analyze conventional pyrometallurgical and hydrometallurgical methods and highlight their limitations in terms of selectivity,energy consumption,and secondary pollution.In contrast,MOFs offer tunable porosity,abundant active sites,and tunable surface chemistry,enabling efficient PM capture via synergistic physical and chemical adsorption.Advanced modification techniques,including direct synthesis and post-synthetic modification,are reviewed to propose strategies for enhancing the adsorption kinetics and selectivity for Au,Ag,Pt,and Pd.Key structure-property relationships are established through multiscale characterization and thermodynamic models,revealing the critical roles of hierarchical porosity,soft donor atoms,and framework stability.Industrial challenges,such as aqueous stability and scalability,are addressed via Zr-O bond strengthening,hydrophobic functionalization,and support immobilization.This study consolidates the experimental and theoretical advances in MOF-based PM recovery and provides a roadmap for translating laboratory innovations into practical applications within the circular-economy framework.展开更多
Prenatal exposure to bisphenols and metals has raised significant concerns regarding their potential impact on fetal development,particularly the risk of fetal chromosome numerical abnormalities(CNA).In this case-cont...Prenatal exposure to bisphenols and metals has raised significant concerns regarding their potential impact on fetal development,particularly the risk of fetal chromosome numerical abnormalities(CNA).In this case-control study,we analyzed bisphenol and metal concentrations in amniotic fluid of high-risk pregnant women undergoing amniocentesis.Concentrations of bisphenols and metals were measured using ultra-performance liquid chromatography-tandem mass spectrometry and inductively coupled plasma-mass spectrometry,respectively.Logistic regression and quantile-based g-computation were applied to evaluate individual and combined effects,while dose-response relationships were assessed using restricted cubic splines.Our findings indicated that bisphenol S(BPS),bisphenol Z(BPZ),bisphenol AF(BPAF),antimony(Sb),and vanadium(V)were significantly associated with an increased risk of CNA when analyzed individually,whereas manganese,iron,copper(Cu),nickel(Ni),and zinc(Zn)were significantly and inversely associated with CNA risk.Combined exposure to bisphenol and metal mixtures was associated with an increased risk of CNA in multi-pollutant models.Cu and Ni exhibited a positive additive interaction.Furthermore,BPS,BPZ,and BPAF were individually associated with an increased risk of Down syndrome,while Zn was associated with a decreased risk of Down syndrome.BPS,Sb,V,and Zn were individually associated with an increased risk of Klinefelter syndrome.These findings underscore the potential role of prenatal bisphenol and metal exposure in the pathogenesis of fetal CNA,highlighting both additive and synergistic effects.展开更多
Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler ...Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.展开更多
Exploration budgets for primary battery metals-nickel,lithium and cobalt-tempered in 2024 at$1.697 billion,reflecting a marginal 0.4%decline and a virtually flat annual total,compared to$1.704 billion in 2023.Below is...Exploration budgets for primary battery metals-nickel,lithium and cobalt-tempered in 2024 at$1.697 billion,reflecting a marginal 0.4%decline and a virtually flat annual total,compared to$1.704 billion in 2023.Below is an introduction to the 2024 global exploration trends and prospects for lithium,cobalt,and nickel battery metals.展开更多
Diabetes and impaired fasting glucose(IFG)are significant global health concerns.However,the potential effects of mixed heavy metal exposure on these conditions remain underexplored.This study aims to investigate the ...Diabetes and impaired fasting glucose(IFG)are significant global health concerns.However,the potential effects of mixed heavy metal exposure on these conditions remain underexplored.This study aims to investigate the combined effects of multiple metals on diabetes risk and explore the mediating role of BodyMass Index(BMI)in rural China.Across-sectional analysis involved 2313 adults from 12 provinces in rural China.Urinary levels of zinc(Zn),chromium(Cr),nickel(Ni),cadmium(Cd),and lead(Pb)were quantified using inductively coupled plasma mass spectrometry.Fasting blood glucose(FBG)levels were measured with an automatic biochemical analyzer.Logistic regression models and the Bayesian Kernel Machine Regression(BKMR)model were used to examine associations and interactions.Mediation analysis was performed to assess the role of BMI.The results of our study indicate that there is a significant association between urinary Zn(OR=2.38,95%CI:1.57,3.60),Cr(OR=1.24,95%CI:1.31,1.61),and Ni(OR=1.51,95%CI:1.05,2.18)and the diabetes risk.The study revealed that exposure to Ni amplified the associations between Zn,Cr and diabetes/IFG risk.Additionally,BMI was identified as a significant mediator in the relationship between metal exposure,particularly Cr/Cd,and diabetes risk.These findings reveal a complex link between multiple metals,such as Zn,Cr,and Ni,and diabetes risk,and emphasize the potential opposite mediating effects of BMI in different metal-induced diabetes mechanisms.Further investigation of these mechanisms is warranted.展开更多
Biliary system,which is responsible for transporting bile from the liver into the intestine,is commonly damaged by inflammation or tumors eventually causing liver failure or death.The implantation of biliary stents ca...Biliary system,which is responsible for transporting bile from the liver into the intestine,is commonly damaged by inflammation or tumors eventually causing liver failure or death.The implantation of biliary stents can effectively alleviate both benign and malignant biliary strictures,but the plastic and metal stents that are currently used cannot degrade and nearly has no beneficial biological effects,therefore their long-term service can result into inflammation,the formation of sludges and re-obstruction of bile duct.In recent years,magnesium(Mg)metal has been received increasing attention in the field of biomedical application due to its excellent biocompatibility,adequate mechanical properties,biodegradability and other advantages,such as anti-inflammatory and anti-tumor properties.The research on biliary stents made of magnesium metals(BSMM)has also made significant progress and a series of experiments in vitro and vivo has proved their possibility.However,there are still some problems holding back BSMM’s clinical use,including rapid corrosion rate and potential harmful reaction.In this review,we would summarize the current research of BSMM,evaluate their clinical benefits,find the choke points,and discuss the solving method.展开更多
Agricultural soil is related to food security and human health,antibiotics and heavy metals(HMs),as two typical pollutants,possess a high coexistence rate in the environmental medium,which is extremely prone to induci...Agricultural soil is related to food security and human health,antibiotics and heavy metals(HMs),as two typical pollutants,possess a high coexistence rate in the environmental medium,which is extremely prone to inducing antibiotic-HMs combined pollution.Recently,frequent human activities have led to more prominent antibiotics-HMs combined contamination in agricultural soils,especially the production and spread of antibiotic resistance genes(ARGs),heavy metal resistance genes(MRGs),antibiotic resistant bacteria(ARB),and antibiotics-HMs complexes(AMCs),which seriously threaten soil ecology and human health.This review describes the main sources(Intrinsic and manmade sources),composite mechanisms(co-selective resistance,oxidative stress,and Joint toxicity mechanism),environmental fate and the potential risks(soil ecological and human health risks)of antibiotics and HMs in agricultural soils.Finally,the current effective source blocking,transmission control,and attenuation strategies are classified for discussion,such as the application of additives and barrier materials,as well as plant and animal remediation and bioremediation,etc.,pointing out that future research should focus on the whole chain process of“source-processterminal”,intending to provide a theoretical basis and decision-making reference for future research.展开更多
Dissolved copper and iron ions are regarded as friendly and economic catalysts for peroxymonosulfate(PMS)activation,however,neither Cu(Ⅱ)nor Fe(Ⅲ)shows efficient catalytic performance because of the slow rates of Cu...Dissolved copper and iron ions are regarded as friendly and economic catalysts for peroxymonosulfate(PMS)activation,however,neither Cu(Ⅱ)nor Fe(Ⅲ)shows efficient catalytic performance because of the slow rates of Cu(Ⅱ)/Cu(Ⅰ)and Fe(Ⅲ)/Fe(Ⅱ)cycles.Innovatively,we observed a significant enhancement on the degradation of organic contaminants when Cu(Ⅱ)and Fe(Ⅲ)were coupled to activate PMS in borate(BA)buffer.The degradation efficiency of Rhodamine B(RhB,20μmol/L)reached up to 96.3%within 10 min,which was higher than the sum of individual Cu(Ⅱ)-and Fe(Ⅲ)-activated PMS process.Sulfate radical,hydroxyl radical and high-valent metal ions(i.e.,Cu(Ⅲ)and Fe(IV))were identified as the working reactive species for RhB removal in Cu(Ⅱ)/Fe(Ⅲ)/PMS/BA system,while the last played a predominated role.The presence of BA dramatically facilitated the reduction of Cu(Ⅱ)to Cu(Ⅰ)via chelating with Cu(Ⅱ)followed by Fe(Ⅲ)reduction by Cu(Ⅰ),resulting in enhanced PMS activation by Cu(Ⅰ)and Fe(Ⅱ)as well as accelerated generation of reactive species.Additionally,the strong buffering capacity of BA to stabilize the solution pH was satisfying for the pollutants degradation since a slightly alkaline environment favored the PMS activation by coupling Cu(Ⅱ)and Fe(Ⅲ).In a word,this work provides a brand-new insight into the outstanding PMS activation by homogeneous bimetals and an expanded application of iron-based advanced oxidation processes in alkaline conditions.展开更多
Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface w...Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface water,and twelve samples of sediment were analyzed in this case study of the Dashu pyrite mine in southwest China.A comprehensive analysis of the pollution levels,pollution sources,and potential hazards of eight metals(Ni,Cd,Cu,Zn,Fe,Al,Pb,and Mn)that exceeded regulatory standardswas conducted bymonitoring 24 conventional and characteristic indicators.Ultimately,this research evaluated the environmental hazards associated with abandonedmine water using the"pressure-response"model,thereby providing valuable insights for the effective protection of the environment in mining regions.The primary pollutants in mine water were determined to be SO_(4)^(2−),Fe,and Mn,with concentrations of 7700,1450,and 6.78mg/L,respectively.A clear"source-sink"dynamic was observed between themine water and the surrounding water system.surface water was primarily polluted by Ni and Mn,while water system sediments were primarily polluted by Cu and Hg.Ion ratio and Pearson correlation analyses indicated heavy metals in surface water and sediments originated from the same AMD source.The"pressureresponse"model was used to assess the environmental hazards of water from abandoned mines.Mines W1,W2,W5,and W6 were classified as high-risk,while W3 and W4 were medium-risk.This study offers a novel approach and valuable reference for identifying and classifying environmental risks in abandoned mines and targeting AMD treatment.展开更多
The automotive industry increasingly relies on numerical simulations to predict the geometry and forming processes of complex curved parts.Accurate yield stress functions that cover a wide range of stress states,such ...The automotive industry increasingly relies on numerical simulations to predict the geometry and forming processes of complex curved parts.Accurate yield stress functions that cover a wide range of stress states,such as uniaxial tension,equi-biaxial tension,near-plane strain tension,and simple shear,are essential for implementing virtual manufacturing technologies.In this work,a new additive-coupled analytical yield stress function,CPN2025,is proposed to accurately describe plastic anisotropy under various loading conditions.CPN2025 integrates the Poly4 anisotropic yield criterion with the Hosford isotropic yield criterion under a non-associated flow rule.A non-fixed-exponent calibration strategy is introduced,overcoming the limitations of existing yield criteria that typically offer curvature adjustment with only positive or negative correlations.CPN2025 is compared with other non-associated yield functions,including SY2009,CQN2017,and NAFR-Poly4,to evaluate its performance in predicting the plastic anisotropy of DP490,QP1180,AA5754-O,and AA6016-T4.Results show that,while meeting convexity requirements,the additive-coupled approach not only provides greater flexibility than the multiplicative-coupled but also simplifies the acquisition of partial derivative information.CPN2025 delivers the highest accuracy in characterizing anisotropic yield behavior,particularly for near-plane strain tension and simple shear loadings.Additionally,incorporating more uniaxial tensile yield stress-calibrated material parameters significantly improves the prediction capacity of in-plane anisotropic behavior.The use of anisotropic hardening concepts enhances the model's capability to capture the subsequent yield behavior across the entire plastic strain range.展开更多
Particulate matter(PM)can cause adverse health effects by overproducing reactive oxygen species(ROS).Although the ability of PM to induce ROS generation depends on its composi-tion and environmental factors.This study...Particulate matter(PM)can cause adverse health effects by overproducing reactive oxygen species(ROS).Although the ability of PM to induce ROS generation depends on its composi-tion and environmental factors.This study explores how photo-oxidation affects ROS gen-eration from aromatic compounds(ACs,including catechol(CAT),phthalic acid(PA),and 4,4-oxydibenzoic acid(4,4-OBA))and their mixtures with transition metals(TMs,includ-ing Fe(II),Mn(II),and Cu(II))using Fourier-transform infrared(FTIR)and Ultraviolet-visible spectroscopy(UV-Vis).Results showed that photo-oxidation facilitated ROS generation from ACs.CAT-Fe(II)/Cu(II)showed synergistic effects,but 4,4-OBA-Fe(II)/Cu(II)showed antag-onistic effects.ACs-Mn(II)and PA-Fe(II)/Cu(II)exhibited synergistic effects first and then showed antagonistic effects.The different interactions were due to complexation between ACs and TMs.The photo-oxidized ACs-TMs significantly enhanced ROS generation com-pared with ACs-TMs.The study suggested the photo-oxidation mechanism involved that the transfer ofπ-electrons from the ground to an excited state in benzene rings and func-tional groups,leading to the breakage and formation of chemical bonds or easierπ-electron transfer from ACs to TMs.The former could generate ROS directly or produce polymers that promoted ROS generation,while the latter promoted ROS generation by transferringπ-electrons to dissolved oxygen quickly.Our study revealed that both interactions among components and photo-oxidation significantly influenced ROS generation.Future studies should integrate broader atmospheric factors and PM components to fully assess oxidative potential and health impacts.展开更多
基金supported by grants from the National Natural Science Foundation of China(G.F.Wang,grant number 82204071)(P.Y.Su,grant numbers 81874268 and 82473655)the Research Funds of the Center for Big Data and Population Health of IHM(P.Y.Su,No.JKS2023016)Anhui Provincial Health Commission Scientific Research Project(Y.Zhou,No.AHWJ2023A30027)。
文摘Vitamin D deficiency(VDD)represents a significant nutritional concern among children and adolescents.The estimated prevalence of VDD in China is 46.8%in this population^([1]).VDD during childhood and adolescence has been associated with the onset of various conditions,including acute respiratory infections,asthma,atopic dermatitis,and food allergies^([2]).Multiple factors,including age,sun exposure,adiposity,and genetics,influence vitamin D levels^([2,3]).Increasing attention has been directed toward understanding the environmental determinants that may influence vitamin D status.Given the potential of metallic pollutants to disrupt endocrine function and their ubiquity in the environment,investigating the effects of metal exposure on human vitamin D status,particularly in vulnerable populations,is imperative.
基金National MCF Energy R&D Program(2024YFE03260300)。
文摘Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application.
文摘Extracting rare earth elements(REEs)from coal refuse is challenging due to their low co ncentrations and poor leachability.Bioleaching has emerged as a sustainable technology to recover REEs from low-grade materials.In this study,a ferric sulfate bio acid(BA)with an acidity of~0.2 mol/L H^(+),generated through regulated pyrite bio-oxidation,was used to leach REEs and critical metals(CMs)from coal refuse(ground to<1 mm)after 20-min roasting at 600℃.The influences of solid/liquid(S/L)ratio(100-300 g/L)and leaching temperature(25-95℃)on the leaching performance were examined.The leaching mechanisms were investigated by conducting stepwise precipitation tests and spectroscopic characterization.Results show that raising the leaching temperature to≥65℃accelerated the REE leaching kinetics but causes the loss of light REEs(LREEs)after reaching peak values at 30-60 min.Stage precipitation tests reveal that the loss is due to the incorporation of REEs,especially for LREEs,by gypsum and schwertmannite.The peak total REE(TREE)recovery of the BA leaching reaches 24.9%after 30 min of leaching at75℃with a S/L ratio of 200 g/L.Implementing the three-stage counter-current leaching increases the overall TREE recovery to 31.8%by recovering the REEs incorporated in the Fe and Ca precipitates.Meanwhile,promising recovery values of Li(55.5%),Mn(74.6%),Ni(41.6%),and Co(35.3%)are also achieved.This method provides a sustainable approach to extract REEs and critical metals from coal waste materials with a high treatment capacity.
文摘Heavy metal contamination is a global issue caused by anthropogenic activities leading to severe negative effects on the environment and human health.To address this problem,bioremediation strategies utilizing plants such as Typha latifolia and their symbiotic fungi have been adopted to remediate contaminated areas and mitigate the harmful effects of these pollutants.In this study,the endophytic fungus Neosartorya fischeri was isolated from the roots of T.latifolia plants growing in heavy metal-contaminated sites.N.fischeri colonized the epidermis and root cortex and showed high tolerance to toxic concentrations of silver(Ag)(1 mg/kg),copper(Cu)(60 mg/kg)and cadmium(Cd)(8 mg/kg).N.fischeri removed 8.7%±0.5%Cd from the medium,biosorbed 15.24±0.2 mg/kg into its biomass,and enhanced the tolerance and bioaccumulation of Cd(184.18±1.14 mg/kg)in plant roots.Moreover,N.fischeri produces siderophores,volatile compounds and solubilizes phosphates,which improve plant fitness.This was evidenced by a 28%increase in photosynthetic pigments in T.latifolia plants colonized with N.fischeri.Additionally,N.fischeri inhibits the growth of important phytopathogens from the Fusarium genus.These findings highlight the important role of N.fischeri in enhancing the fitness and resilience of T.latifolia in hostile environments,demonstrating the potential of N.fischeri-T.latifolia association for the bioremediation of contaminated sites.
文摘The surge in environmental pollution in recent years driven by numerous pollutants has necessitated the search for efficient removal methods.Phytoremediation is an eco-friendly technique that provides multiple benefits over conventional methods of removing contaminants.Despite the numerous benefits of this technique,it has certain limitations that can be addressed by incorporating nanoparticles to improve its effectiveness.This review paper aims to explore the impact of heavy metal pollution on plants and human health.It highlights the role and mechanism of nanoparticles in enhancing phytoremediation,their application in the detection of heavy metals,and the strategies for the safe disposal of phytoremediation biomass.Biosynthesized nanoparticles are eco-friendly and non-toxic,with applications in biomedical and environmental fields.Nanoparticles can be used in the form of nano biosensors like smartphone-operated wireless sensors made from Cinnamomum camphora,enabling efficient detection of heavy metal ions.According to the studies,nanoparticles remove 80%–97%of heavy metals by various methods like reduction,precipitation,adsorption,etc.The phytoremediation biomass disposal can be done by heat treatment,phytomining,and microbial treatment with some modifications to further enhance their results.Phytoremediation is an environmentally friendly technique but requires further research and integration with biomass energy production to overcome scalability challenges and ensure safe biomass disposal.
基金supported by the Science and Technology Planning Social Development Project of Zhenjiang City,China(No.SH2017045)the Postgraduate Research&Practice Innovation Program of Jiangsu Province,China(No.SJCX23_2065)。
文摘Dear Editor,With the growing food demands and the rapid development of intensive vegetable cultivation,the vegetable yield and planting area have increased to 230 million tons and 2.13 million hectares,respectively,in China in 2021(MARAPRC,2023).
基金Sri Ramaswamy Memorial University,Andhra Pradesh,India for providing fellowship。
文摘Coal mining activities significantly impact the environment through water,soil,and air pollution of the surrounding areas.The dispersal of pollutants and the degradation of soil quality by toxic metals emitted from coal mining activities cause significant concerns worldwide,posing serious risks to ecosystems,human health,and vegetation.Restoration of quality of soil contaminated by toxic metals from coal mining is challenging due to the continuous increase in the concentration of toxic metals such as lead,copper,chromium,cadmium,and arsenic within the soil matrix.Conventional approaches utilized for the remediation of soil are often time-consuming and labour-intensive.In addition,they may lead to secondary pollution,particularly when applied at a large scale.Phytoremediation,a technique that utilizes plants with high metal accumulation capacity,has surfaced as a promising,eco-friendly strategy for remediating soil contaminated with toxic metals.These plants can absorb and sequester metals into above-and belowground tissues or stabilize them into less bioavailable forms within the rhizosphere.Species from families such as Brassicaceae and Asteraceae have demonstrated notable effectiveness in phytoremediation applications.The efficiency of phytoremediation can be further enhanced by applying organic and inorganic soil amendments to increase metal bioavailability and plant uptake.Moreover,genetic engineering has enabled the development of plants with improved metal tolerance and accumulation capacities.Complementing these approaches,microbial phytoremediation employs plant-associated microbes to facilitate metal uptake and transformation,increasing the overall remediation efficiency.Following remediation,biomass is proposed for value-added applications,including biochar,biogas,and recovery of metals for industrial reuse.This review summarizes the current progress,emerging strategies,and future prospects of phytoremediation for mitigating toxic metal pollution in coal mining-affected soils.Altogether,these approaches illustrate the potential of integrating circular bioeconomy principles in transforming phytoremediation as a sustainable strategy for mitigating toxic metal pollution in coal mining regions.
基金supported by the National Natural Science Foundation of China(31800542)Natural Science Foundation of Heilongjiang Province(LH2023C105)Heilongjiang Research Institutes Basic Research Funding Project(LKSB2024-9)。
文摘The ectomycorrhizal fungus Paxillus involutus was inoculated onto tissue-cultures of the hybrid poplar,Populus davidiana×P.bolleana,to evaluate the elemental defense effect to heavy metals copper and cadmium at different concentrations by simulating Alternaria alternata fungus infection.The enrichment capacity of Populus davidiana×P.bolleana for Cu and Cd was closely associated with the degree of heavy metal stress.There was a significant positive interaction of applying Cu and Cd and the inoculation with P.involutus on A.alternata leaf blight disease index.The incidence rate and disease index of leaf blight underwent a significant reduction compared with the controls.Similarly,the ratio of the area of disease spot to leaf area,incidence rate,and disease index for Populus davidiana×P.bolleana leaves inoculated with Paxillus involutus(Batsch)Fr.were significantly lower than those of their nonmycorrhizal counterparts.With increasing the degree of Cu and Cd stress,a gradual increase in the average value of the membership function for the incidence rate and disease index was observed,indicating the weakened pathogen's ability to cause infection and the improved resistance of Populus davidiana×P.bolleana to leaf blight disease under Cu and Cd stress.Moreover,superoxide dismutase enzyme activity in Populus davidiana×P.bolleana increased significantly,reaching levels of 411.0 U/g FW and 421.6 U/g FW under Cu and Cd treatments,respectively.These changes in metabolic products and antioxidant enzyme activities suggest that P.involutus may enhance the resistance of Populus davidiana×P.bolleana to the fungus,Alternaria alternata Fr.Keissel under heavy metal stress by modulating these physiological indicators.
基金supported by the Research Funds of the Center for Big Data and Population Health of IHM(grant number JKS2022015)the Key Scientific Research Fund of the Anhui Provincial Education Department(grant number2023AH050610)the Anhui Natural Science Foundation(grant number 1808085QH252)。
文摘In 2021,approximately 537 million people suffered from diabetes mellitus(DM)globally,and this figure will increase to approximately 783 million within the next quarter-century.The increasing burden of DM is a pressing global public health issue.Therefore,the early identification of high-risk groups and implementation of effective intervention measures is imperative.
基金supported by the National Natural Science Foundation of China(No.52304329)the Yunnan Fundamental Research Projects(No.202201BE070001-003),Guo Lin would like to acknowledge Xing Dian talent support program of Yunnan Province.
文摘The recovery of precious metals(PMs)from secondary resources is critical for addressing global supply-chain vulnerabilities and sustainable resource utilization.This review systematically examines the transformative potential of metal-organic frameworks(MOFs)as next-generation adsorbents for PM recovery,focusing on their synthesis,functionalization,and multiscale adsorption mechanisms.We critically analyze conventional pyrometallurgical and hydrometallurgical methods and highlight their limitations in terms of selectivity,energy consumption,and secondary pollution.In contrast,MOFs offer tunable porosity,abundant active sites,and tunable surface chemistry,enabling efficient PM capture via synergistic physical and chemical adsorption.Advanced modification techniques,including direct synthesis and post-synthetic modification,are reviewed to propose strategies for enhancing the adsorption kinetics and selectivity for Au,Ag,Pt,and Pd.Key structure-property relationships are established through multiscale characterization and thermodynamic models,revealing the critical roles of hierarchical porosity,soft donor atoms,and framework stability.Industrial challenges,such as aqueous stability and scalability,are addressed via Zr-O bond strengthening,hydrophobic functionalization,and support immobilization.This study consolidates the experimental and theoretical advances in MOF-based PM recovery and provides a roadmap for translating laboratory innovations into practical applications within the circular-economy framework.
基金supported by the Key Project of Natural Science Foundation of Tianjin(No.23JCZDJC00330)Tianjin Municipal Education Commission Scientific Research Program(No.2022ZD056).
文摘Prenatal exposure to bisphenols and metals has raised significant concerns regarding their potential impact on fetal development,particularly the risk of fetal chromosome numerical abnormalities(CNA).In this case-control study,we analyzed bisphenol and metal concentrations in amniotic fluid of high-risk pregnant women undergoing amniocentesis.Concentrations of bisphenols and metals were measured using ultra-performance liquid chromatography-tandem mass spectrometry and inductively coupled plasma-mass spectrometry,respectively.Logistic regression and quantile-based g-computation were applied to evaluate individual and combined effects,while dose-response relationships were assessed using restricted cubic splines.Our findings indicated that bisphenol S(BPS),bisphenol Z(BPZ),bisphenol AF(BPAF),antimony(Sb),and vanadium(V)were significantly associated with an increased risk of CNA when analyzed individually,whereas manganese,iron,copper(Cu),nickel(Ni),and zinc(Zn)were significantly and inversely associated with CNA risk.Combined exposure to bisphenol and metal mixtures was associated with an increased risk of CNA in multi-pollutant models.Cu and Ni exhibited a positive additive interaction.Furthermore,BPS,BPZ,and BPAF were individually associated with an increased risk of Down syndrome,while Zn was associated with a decreased risk of Down syndrome.BPS,Sb,V,and Zn were individually associated with an increased risk of Klinefelter syndrome.These findings underscore the potential role of prenatal bisphenol and metal exposure in the pathogenesis of fetal CNA,highlighting both additive and synergistic effects.
基金National Natural Science Foundation of China(U22A20191)。
文摘Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.
文摘Exploration budgets for primary battery metals-nickel,lithium and cobalt-tempered in 2024 at$1.697 billion,reflecting a marginal 0.4%decline and a virtually flat annual total,compared to$1.704 billion in 2023.Below is an introduction to the 2024 global exploration trends and prospects for lithium,cobalt,and nickel battery metals.
基金supported by the National Key Research and Development Program of China(Nos.2022YFC3902100 and 2023YFC3905203)the National Natural Science Foundation of China(Nos.42377438 and 82103799)+1 种基金the Central Publicinterest Scientific Institution Basal Research Fund of South China Institute of Environmental Sciences,MEE(No.PMzx703–202305–183)the Fund of State Environmental Protection Key Laboratory of Radiation Environment&Health(2022).
文摘Diabetes and impaired fasting glucose(IFG)are significant global health concerns.However,the potential effects of mixed heavy metal exposure on these conditions remain underexplored.This study aims to investigate the combined effects of multiple metals on diabetes risk and explore the mediating role of BodyMass Index(BMI)in rural China.Across-sectional analysis involved 2313 adults from 12 provinces in rural China.Urinary levels of zinc(Zn),chromium(Cr),nickel(Ni),cadmium(Cd),and lead(Pb)were quantified using inductively coupled plasma mass spectrometry.Fasting blood glucose(FBG)levels were measured with an automatic biochemical analyzer.Logistic regression models and the Bayesian Kernel Machine Regression(BKMR)model were used to examine associations and interactions.Mediation analysis was performed to assess the role of BMI.The results of our study indicate that there is a significant association between urinary Zn(OR=2.38,95%CI:1.57,3.60),Cr(OR=1.24,95%CI:1.31,1.61),and Ni(OR=1.51,95%CI:1.05,2.18)and the diabetes risk.The study revealed that exposure to Ni amplified the associations between Zn,Cr and diabetes/IFG risk.Additionally,BMI was identified as a significant mediator in the relationship between metal exposure,particularly Cr/Cd,and diabetes risk.These findings reveal a complex link between multiple metals,such as Zn,Cr,and Ni,and diabetes risk,and emphasize the potential opposite mediating effects of BMI in different metal-induced diabetes mechanisms.Further investigation of these mechanisms is warranted.
基金supported by Natural Science Foundation of Hunan Province(2021JJ31081,2024JJ5619)the Science Fund of State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle(No 32215004).
文摘Biliary system,which is responsible for transporting bile from the liver into the intestine,is commonly damaged by inflammation or tumors eventually causing liver failure or death.The implantation of biliary stents can effectively alleviate both benign and malignant biliary strictures,but the plastic and metal stents that are currently used cannot degrade and nearly has no beneficial biological effects,therefore their long-term service can result into inflammation,the formation of sludges and re-obstruction of bile duct.In recent years,magnesium(Mg)metal has been received increasing attention in the field of biomedical application due to its excellent biocompatibility,adequate mechanical properties,biodegradability and other advantages,such as anti-inflammatory and anti-tumor properties.The research on biliary stents made of magnesium metals(BSMM)has also made significant progress and a series of experiments in vitro and vivo has proved their possibility.However,there are still some problems holding back BSMM’s clinical use,including rapid corrosion rate and potential harmful reaction.In this review,we would summarize the current research of BSMM,evaluate their clinical benefits,find the choke points,and discuss the solving method.
基金supported by the National Natural Science Foundation of China(No.32171615)the National Key R&D Program of China(2019YFC1804102)。
文摘Agricultural soil is related to food security and human health,antibiotics and heavy metals(HMs),as two typical pollutants,possess a high coexistence rate in the environmental medium,which is extremely prone to inducing antibiotic-HMs combined pollution.Recently,frequent human activities have led to more prominent antibiotics-HMs combined contamination in agricultural soils,especially the production and spread of antibiotic resistance genes(ARGs),heavy metal resistance genes(MRGs),antibiotic resistant bacteria(ARB),and antibiotics-HMs complexes(AMCs),which seriously threaten soil ecology and human health.This review describes the main sources(Intrinsic and manmade sources),composite mechanisms(co-selective resistance,oxidative stress,and Joint toxicity mechanism),environmental fate and the potential risks(soil ecological and human health risks)of antibiotics and HMs in agricultural soils.Finally,the current effective source blocking,transmission control,and attenuation strategies are classified for discussion,such as the application of additives and barrier materials,as well as plant and animal remediation and bioremediation,etc.,pointing out that future research should focus on the whole chain process of“source-processterminal”,intending to provide a theoretical basis and decision-making reference for future research.
基金supported by the Sichuan Science and Technology Program(No.2021YJ0385)the Project in Yangtze River Ecological Environment Protection and Restoration(No.2022-LHYJ-02-0509-08).
文摘Dissolved copper and iron ions are regarded as friendly and economic catalysts for peroxymonosulfate(PMS)activation,however,neither Cu(Ⅱ)nor Fe(Ⅲ)shows efficient catalytic performance because of the slow rates of Cu(Ⅱ)/Cu(Ⅰ)and Fe(Ⅲ)/Fe(Ⅱ)cycles.Innovatively,we observed a significant enhancement on the degradation of organic contaminants when Cu(Ⅱ)and Fe(Ⅲ)were coupled to activate PMS in borate(BA)buffer.The degradation efficiency of Rhodamine B(RhB,20μmol/L)reached up to 96.3%within 10 min,which was higher than the sum of individual Cu(Ⅱ)-and Fe(Ⅲ)-activated PMS process.Sulfate radical,hydroxyl radical and high-valent metal ions(i.e.,Cu(Ⅲ)and Fe(IV))were identified as the working reactive species for RhB removal in Cu(Ⅱ)/Fe(Ⅲ)/PMS/BA system,while the last played a predominated role.The presence of BA dramatically facilitated the reduction of Cu(Ⅱ)to Cu(Ⅰ)via chelating with Cu(Ⅱ)followed by Fe(Ⅲ)reduction by Cu(Ⅰ),resulting in enhanced PMS activation by Cu(Ⅰ)and Fe(Ⅱ)as well as accelerated generation of reactive species.Additionally,the strong buffering capacity of BA to stabilize the solution pH was satisfying for the pollutants degradation since a slightly alkaline environment favored the PMS activation by coupling Cu(Ⅱ)and Fe(Ⅲ).In a word,this work provides a brand-new insight into the outstanding PMS activation by homogeneous bimetals and an expanded application of iron-based advanced oxidation processes in alkaline conditions.
基金supported by the National Key Research and Development Program of China(No.2023YFC3710000)the National Natural Science Foundation of China(Nos.42277078 and 42307118).
文摘Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface water,and twelve samples of sediment were analyzed in this case study of the Dashu pyrite mine in southwest China.A comprehensive analysis of the pollution levels,pollution sources,and potential hazards of eight metals(Ni,Cd,Cu,Zn,Fe,Al,Pb,and Mn)that exceeded regulatory standardswas conducted bymonitoring 24 conventional and characteristic indicators.Ultimately,this research evaluated the environmental hazards associated with abandonedmine water using the"pressure-response"model,thereby providing valuable insights for the effective protection of the environment in mining regions.The primary pollutants in mine water were determined to be SO_(4)^(2−),Fe,and Mn,with concentrations of 7700,1450,and 6.78mg/L,respectively.A clear"source-sink"dynamic was observed between themine water and the surrounding water system.surface water was primarily polluted by Ni and Mn,while water system sediments were primarily polluted by Cu and Hg.Ion ratio and Pearson correlation analyses indicated heavy metals in surface water and sediments originated from the same AMD source.The"pressureresponse"model was used to assess the environmental hazards of water from abandoned mines.Mines W1,W2,W5,and W6 were classified as high-risk,while W3 and W4 were medium-risk.This study offers a novel approach and valuable reference for identifying and classifying environmental risks in abandoned mines and targeting AMD treatment.
基金financial support from the National Natural Science Foundation of China(Grant Nos.52305396,52371116,and 52375310)support of the research fellowship from the Alexander von Humboldt Foundation.
文摘The automotive industry increasingly relies on numerical simulations to predict the geometry and forming processes of complex curved parts.Accurate yield stress functions that cover a wide range of stress states,such as uniaxial tension,equi-biaxial tension,near-plane strain tension,and simple shear,are essential for implementing virtual manufacturing technologies.In this work,a new additive-coupled analytical yield stress function,CPN2025,is proposed to accurately describe plastic anisotropy under various loading conditions.CPN2025 integrates the Poly4 anisotropic yield criterion with the Hosford isotropic yield criterion under a non-associated flow rule.A non-fixed-exponent calibration strategy is introduced,overcoming the limitations of existing yield criteria that typically offer curvature adjustment with only positive or negative correlations.CPN2025 is compared with other non-associated yield functions,including SY2009,CQN2017,and NAFR-Poly4,to evaluate its performance in predicting the plastic anisotropy of DP490,QP1180,AA5754-O,and AA6016-T4.Results show that,while meeting convexity requirements,the additive-coupled approach not only provides greater flexibility than the multiplicative-coupled but also simplifies the acquisition of partial derivative information.CPN2025 delivers the highest accuracy in characterizing anisotropic yield behavior,particularly for near-plane strain tension and simple shear loadings.Additionally,incorporating more uniaxial tensile yield stress-calibrated material parameters significantly improves the prediction capacity of in-plane anisotropic behavior.The use of anisotropic hardening concepts enhances the model's capability to capture the subsequent yield behavior across the entire plastic strain range.
基金supported by the Weiqiao-UCAS Special Projects on Low-Carbon Technology Development(No.GYY-DTFZ-2022-007)the Fundamental Research Funds for the Central Universities(No.E0E48927×2)the National Natural Science Foundation of China(No.21677145).
文摘Particulate matter(PM)can cause adverse health effects by overproducing reactive oxygen species(ROS).Although the ability of PM to induce ROS generation depends on its composi-tion and environmental factors.This study explores how photo-oxidation affects ROS gen-eration from aromatic compounds(ACs,including catechol(CAT),phthalic acid(PA),and 4,4-oxydibenzoic acid(4,4-OBA))and their mixtures with transition metals(TMs,includ-ing Fe(II),Mn(II),and Cu(II))using Fourier-transform infrared(FTIR)and Ultraviolet-visible spectroscopy(UV-Vis).Results showed that photo-oxidation facilitated ROS generation from ACs.CAT-Fe(II)/Cu(II)showed synergistic effects,but 4,4-OBA-Fe(II)/Cu(II)showed antag-onistic effects.ACs-Mn(II)and PA-Fe(II)/Cu(II)exhibited synergistic effects first and then showed antagonistic effects.The different interactions were due to complexation between ACs and TMs.The photo-oxidized ACs-TMs significantly enhanced ROS generation com-pared with ACs-TMs.The study suggested the photo-oxidation mechanism involved that the transfer ofπ-electrons from the ground to an excited state in benzene rings and func-tional groups,leading to the breakage and formation of chemical bonds or easierπ-electron transfer from ACs to TMs.The former could generate ROS directly or produce polymers that promoted ROS generation,while the latter promoted ROS generation by transferringπ-electrons to dissolved oxygen quickly.Our study revealed that both interactions among components and photo-oxidation significantly influenced ROS generation.Future studies should integrate broader atmospheric factors and PM components to fully assess oxidative potential and health impacts.
