Silica mesoporous material MCFs with 16.0 nm pore sizes was prepared by using non-ionic block copolymers and the swelling agents, and was used as the support for the immobilization of enzyme. Penicillin G acylase, an ...Silica mesoporous material MCFs with 16.0 nm pore sizes was prepared by using non-ionic block copolymers and the swelling agents, and was used as the support for the immobilization of enzyme. Penicillin G acylase, an enzyme, was assembled in the channel of MCFs by immersion method. The activity and stability of immobilized penicillin G acylase were studied. It was found that the activity and stability of the immobilized penicillin G acylase increased significantly compared to those of free enzyme. The optimum reaction temperature is 60 ℃. After incubation at 60 ℃ for 1 h, the activity of these immobilized penicillin G acylase remains 69%. These results showed that thermostability and durability on heating of the immobilized penicillin G acylase in MCFs was improved remarkably. The silica mesoporous material MCFs with 3-dimensional channel structure is a good support for the immobilization of enzyme.展开更多
以水热法合成出介孔泡沫二氧化硅材料(MCFs),以MCFs吸附茜素红S得到最佳吸附条件,最大吸附容量为3.750 mg/g。从293.15~323.15 K温度区间获得了吸附体系的热力学性质,反应焓变△H0=48.038 k J/mol>0,说明MCFs吸附茜素红S的过程属于...以水热法合成出介孔泡沫二氧化硅材料(MCFs),以MCFs吸附茜素红S得到最佳吸附条件,最大吸附容量为3.750 mg/g。从293.15~323.15 K温度区间获得了吸附体系的热力学性质,反应焓变△H0=48.038 k J/mol>0,说明MCFs吸附茜素红S的过程属于吸热反应。熵变△S0=243.3 J/(mol·K)>0,说明MCFs吸附茜素红S为熵增加过程。该温度区间吸附反应的自由能变化值△G0<0,该吸附处于自发反应,而且吸附反应同时伴随物理吸附和化学吸附。MCFs吸附茜素红S的过程符合动力学准二阶方程。Freundlich吸附等温方程拟合效果较之Langmuir更好,吸附结果符合Freundlich吸附等温线,该吸附过程属于多分子层吸附。展开更多
Nano mesocellular foam silica(MCFs)was synthesized through the hydrothermal method in this study.Powder X-ray diffraction and scanning electron microscopy were used to characterize the MCFs sample.The sample presented...Nano mesocellular foam silica(MCFs)was synthesized through the hydrothermal method in this study.Powder X-ray diffraction and scanning electron microscopy were used to characterize the MCFs sample.The sample presented spherical particles and regular morphology.The results of transmission electron microscopy showed that synthesized MCFs has a three-dimensional honeycomb pore structure,which aids in the adsorption of nickel ion(Ni^2+).The results of low-temperature nitrogen gas adsorption-desorption showed that the pore diameter of the synthesized MCFs was 19.6 nm.The impacts of pH,temperature,amount of adsorbent,initial concentration of Ni^2+,and contact time on the adsorption effect of Ni^2+ by MCFs were studied.Under the optimized adsorption conditions,the adsorption rate reached 96.10%and the adsorption capacity was 7.69 mg/g.It has been determined through the study of kinetics and adsorption isotherms that the adsorption of Ni^2+ by MCFs follows the pattern of the pseudo-second-order kinetic model,simultaneously belonging to the Freundlich adsorption type.The thermodynamic results of adsorption showed that,when the temperature is between 25℃ and 45℃,the adsorption is a spontaneous exothermic reaction.展开更多
This article presents a comprehensive framework for advancing sustainable transportation through the integration of next-generation energy technologies.It explores the convergence of Vernova green energy,nuclear fissi...This article presents a comprehensive framework for advancing sustainable transportation through the integration of next-generation energy technologies.It explores the convergence of Vernova green energy,nuclear fission from ARCs(advanced reactor concepts)and SMRs(small modular reactors),and future-focused nuclear fusion methods-MCF(magnetic confinement fusion)and ICF(inertial confinement fusion).Central to this integration is the use of AI(artificial intelligence)to enhance smart grid efficiency,enable real-time optimization,and ensure resilient energy delivery.The synergy between these zero-carbon energy sources and AI-driven infrastructure promises a transformative impact on electric mobility,hydrogen-powered systems,and autonomous transport.By detailing the architecture of an AI-augmented,carbon-neutral transport ecosystem,this paper contributes to the roadmap for future global mobility.展开更多
文摘Silica mesoporous material MCFs with 16.0 nm pore sizes was prepared by using non-ionic block copolymers and the swelling agents, and was used as the support for the immobilization of enzyme. Penicillin G acylase, an enzyme, was assembled in the channel of MCFs by immersion method. The activity and stability of immobilized penicillin G acylase were studied. It was found that the activity and stability of the immobilized penicillin G acylase increased significantly compared to those of free enzyme. The optimum reaction temperature is 60 ℃. After incubation at 60 ℃ for 1 h, the activity of these immobilized penicillin G acylase remains 69%. These results showed that thermostability and durability on heating of the immobilized penicillin G acylase in MCFs was improved remarkably. The silica mesoporous material MCFs with 3-dimensional channel structure is a good support for the immobilization of enzyme.
基金supported by the Natural Science Foundation of the Department of Science and Technology of Jilin Province,China(Grants No.20180101180JC,222180102051,and KYC-JC-XM-2018-051)
文摘Nano mesocellular foam silica(MCFs)was synthesized through the hydrothermal method in this study.Powder X-ray diffraction and scanning electron microscopy were used to characterize the MCFs sample.The sample presented spherical particles and regular morphology.The results of transmission electron microscopy showed that synthesized MCFs has a three-dimensional honeycomb pore structure,which aids in the adsorption of nickel ion(Ni^2+).The results of low-temperature nitrogen gas adsorption-desorption showed that the pore diameter of the synthesized MCFs was 19.6 nm.The impacts of pH,temperature,amount of adsorbent,initial concentration of Ni^2+,and contact time on the adsorption effect of Ni^2+ by MCFs were studied.Under the optimized adsorption conditions,the adsorption rate reached 96.10%and the adsorption capacity was 7.69 mg/g.It has been determined through the study of kinetics and adsorption isotherms that the adsorption of Ni^2+ by MCFs follows the pattern of the pseudo-second-order kinetic model,simultaneously belonging to the Freundlich adsorption type.The thermodynamic results of adsorption showed that,when the temperature is between 25℃ and 45℃,the adsorption is a spontaneous exothermic reaction.
文摘This article presents a comprehensive framework for advancing sustainable transportation through the integration of next-generation energy technologies.It explores the convergence of Vernova green energy,nuclear fission from ARCs(advanced reactor concepts)and SMRs(small modular reactors),and future-focused nuclear fusion methods-MCF(magnetic confinement fusion)and ICF(inertial confinement fusion).Central to this integration is the use of AI(artificial intelligence)to enhance smart grid efficiency,enable real-time optimization,and ensure resilient energy delivery.The synergy between these zero-carbon energy sources and AI-driven infrastructure promises a transformative impact on electric mobility,hydrogen-powered systems,and autonomous transport.By detailing the architecture of an AI-augmented,carbon-neutral transport ecosystem,this paper contributes to the roadmap for future global mobility.
