Due to global warming, glaciers on the Tibetan Plateau(TP) are experiencing widespread shrinkage; however, the mechanisms controlling glacier variations across the TP are still rather unclear, especially on the northe...Due to global warming, glaciers on the Tibetan Plateau(TP) are experiencing widespread shrinkage; however, the mechanisms controlling glacier variations across the TP are still rather unclear, especially on the northeastern TP. In this study, a physically based, distributed surface-energy and mass-balance model was used to simulate glacier mass balance forced by meteorological data. The model was applied to Laohugou No. 12 Glacier, western Qilian Mountains, China, during2010~2012. The simulated albedo and mass balance were validated and calibrated by in situ measurements. The simulated annual glacier-wide mass balances were-385 mm water equivalent(w.e.) in 2010/2011 and-232 mm w.e. in 2011/2012,respectively. The mean equilibrium-line altitude(ELA) was 5,015 m a.s.l., during 2010~2012, which ascended by 215 m compared to that in the 1970 s. The mean accumulation area ratio(AAR) was 39% during the two years. Climatic-sensitivity experiments indicated that the change of glacier mass balance resulting from a 1.5 °C increase in air temperature could be offset by a 30% increase in annual precipitation. The glacier mass balance varied linearly with precipitation, at a rate of130 mm w.e. per 10% change in total precipitation.展开更多
The aim of this study is to investigate the impact of temperature trend on glacier-mass balance, snow density, snowmelt, snow depth and runoff by using observations of nine glacier stations that covered most of the Ch...The aim of this study is to investigate the impact of temperature trend on glacier-mass balance, snow density, snowmelt, snow depth and runoff by using observations of nine glacier stations that covered most of the China over the period of 1979-2013. Trend analysis showed an increasing trend of temperature on all of the selected stations. On an average, temperature was increasing at the rate of 0.46/10a. The increasing trend of temperature showed a negative relationship with annual glacier-mass balance on most of the stations and caused a decrease in annual balance. Results of Pearson’s correlation analysis showed a highly significant negative correlation between temperature and snow density (correlation coefficient (CC = -0.661 at 0.01 significance level). There was a significant positive correlation between temperature and snowmelt (CC = 0.532 at 0.01 significance level). There was a significant negative correlation between temperature and snow depth (correlation coefficient (CC = -0.342 at 0.05 significance level). Moreover, there was a significant positive correlation between temperature and runoff (CC = 0.586 at 0.01 significance level). Increasing trend of temperature caused an increasing trend of annual snowmelt and runoff anomaly% at the rate of 24.82/10a and 9.87/10a, respectively. On the other hand, a declining trend in annual snow density and snow depth anomaly% was found at a rate of -5.32/10a and -1.93/10a, respectively. We concluded that the snow density, snowmelt and runoff are significantly sensitive to temperature in China. This contribution has provided information for further understanding of glacier variation and its influencing factors.展开更多
Sulphur (S) cycling and implications on S fertilizer requirement in sheep-grazed pastures receiving three levels of S fertilizer at rates of 0, 30 and 60 kg S/hm 2 in 1995 and 1996 were studied using a mass-balance a...Sulphur (S) cycling and implications on S fertilizer requirement in sheep-grazed pastures receiving three levels of S fertilizer at rates of 0, 30 and 60 kg S/hm 2 in 1995 and 1996 were studied using a mass-balance approach which accounted both for S inputs to and outputs from the soil-plant-animal system. Results indicated that S fertilizer increased by 50% of herbage S uptake and 15% or more of S bio-cycling rate in grazing system. The total S recovery of 30 and 60 kg S/hm 2 treatments from 1995 to 1996 was 74.0% and 37.6% respectively. Mineralization of organic S may be an important source of S for pasture when other S sources are low, accounted for 70% of the total S inputs without S fertilizer. The grazing sheep has an important ecological function, the feature of S cycling in grazed pastures was that 90% of herbage S ingested by grazing sheep was returned to soils as excreta. The amount of S released by sheep excreta accounted about 30% of the total released S through S bio-recycling. Loss from soil S leaching beyond the major plant rooting zone was the main S output from grazing system. However, urinary and fecal S losses, including transfer and leaching losses, also affected S budgets of grazing system. It is therefore important to investigate the recycling rate of both urinary and fecal S under field conditions. Based on the mass-balance principle, at least 10 kg S/hm 2 per year may be necessary for sustainable development of grazing system.展开更多
Mercury(Hg)is a global pollutant that is subject to strict regulations to reduce anthropogenic emissions.The production of energy represents an important activity that leads to Hg emissions into the atmosphere.Of all ...Mercury(Hg)is a global pollutant that is subject to strict regulations to reduce anthropogenic emissions.The production of energy represents an important activity that leads to Hg emissions into the atmosphere.Of all the systems used,IGCC plants are the most promising for reducing Hg emissions,since it is possible to remove Hg from syngas prior to combustion.The aim of the present work was to evaluate the presence of Hg in the main streams of an experimental IGCC plant(ELCOGAS,Puertollano)in order to quantify Hg emissions and investigate the possibility of reducing them.The main streams of the system were sampled for three consecutive days and both the solids,i.e.,raw material(coal and petroleum coke),fine and coarse slags,fly ash,sulphur,and the liquids,i.e.,slag system,Venturi scrubber and saturator,were studied.The results show that an average of 12.9%of the Hg that enters the IGCC power plant is eliminated with solid waste and only 0.08%with liquid waste.There is still an average of 87.12%of Hg that is not accounted for in the mass balance and that could remain in the system and/or be eliminated in the streams that were not analysed.Although it is impossible to offer an explanation for the final fate of the Hg lost in the system based on the obtained results,the data suggest that sulphur byproducts could be primarily responsible for the elimination of Hg from the syngas,and that a major proportion of Hg should be emitted via the chimney after the syngas combustion process.展开更多
Molybdenum(Mo) proxies, including bulk concentration and isotopic composition, have been increasingly used to reconstruct ancient ocean redox states. This study systematically reviews Mo cycles and their accompanying ...Molybdenum(Mo) proxies, including bulk concentration and isotopic composition, have been increasingly used to reconstruct ancient ocean redox states. This study systematically reviews Mo cycles and their accompanying isotopic fractionations in modern ocean as well as their application in paleo-ocean redox reconstruction. Our review indicates that Mo enrichment in sediments mainly records the adsorption of Fe-Mn oxides/hydroxides and chemical bonding of H2 S. Thus, Mo enrichment in anoxic sediments generally reflects the presence of H2 S in the water column or pore waters. In addition to the effect of euxinia, sedimentary Mo enrichment is related to the size of the oceanic Mo reservoir. Given these primary mechanisms for oceanic Mo cycling, Mo abundance data and Mo/TOC ratios acquired from euxinic sediments in geological times show that fluctuations of the oceanic Mo reservoir are well correlated with oxygenation of the atmosphere and oceans and suggest that oxygenation occurred in phases. Mo proxies suggest that Mo isotopes in strongly euxinic sediments reflect the contemporaneous Mo isotopic composition of seawater, but other processes such as iron-manganese(Fe-Mn) adsorption and weak euxinia can result in different fractionations. Diagenesis may complicate Mo enrichment and its isotopic fractionation in sediments. With appropriate constraints on the Mo isotopic composition of seawater and various outputs, a Mo isotope mass-balance model can quantitatively reconstruct global redox conditions over geological history. In summary, Mo proxies can be effectively used to reconstruct oceanic redox conditions on various timescales due to their sensitivity to both local and global marine redox conditions. However, given the complexity of geochemical processes, particularly the effects of diagenesis, further work is required to apply Mo proxies to ancient oceans.展开更多
基金supported by the Chinese Academy of Sciences(KJZD-EW-G03-04)the National Natural Science Foundation of China(41721091,41671071)Open Foundation of State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering(No.2017490711)
文摘Due to global warming, glaciers on the Tibetan Plateau(TP) are experiencing widespread shrinkage; however, the mechanisms controlling glacier variations across the TP are still rather unclear, especially on the northeastern TP. In this study, a physically based, distributed surface-energy and mass-balance model was used to simulate glacier mass balance forced by meteorological data. The model was applied to Laohugou No. 12 Glacier, western Qilian Mountains, China, during2010~2012. The simulated albedo and mass balance were validated and calibrated by in situ measurements. The simulated annual glacier-wide mass balances were-385 mm water equivalent(w.e.) in 2010/2011 and-232 mm w.e. in 2011/2012,respectively. The mean equilibrium-line altitude(ELA) was 5,015 m a.s.l., during 2010~2012, which ascended by 215 m compared to that in the 1970 s. The mean accumulation area ratio(AAR) was 39% during the two years. Climatic-sensitivity experiments indicated that the change of glacier mass balance resulting from a 1.5 °C increase in air temperature could be offset by a 30% increase in annual precipitation. The glacier mass balance varied linearly with precipitation, at a rate of130 mm w.e. per 10% change in total precipitation.
文摘The aim of this study is to investigate the impact of temperature trend on glacier-mass balance, snow density, snowmelt, snow depth and runoff by using observations of nine glacier stations that covered most of the China over the period of 1979-2013. Trend analysis showed an increasing trend of temperature on all of the selected stations. On an average, temperature was increasing at the rate of 0.46/10a. The increasing trend of temperature showed a negative relationship with annual glacier-mass balance on most of the stations and caused a decrease in annual balance. Results of Pearson’s correlation analysis showed a highly significant negative correlation between temperature and snow density (correlation coefficient (CC = -0.661 at 0.01 significance level). There was a significant positive correlation between temperature and snowmelt (CC = 0.532 at 0.01 significance level). There was a significant negative correlation between temperature and snow depth (correlation coefficient (CC = -0.342 at 0.05 significance level). Moreover, there was a significant positive correlation between temperature and runoff (CC = 0.586 at 0.01 significance level). Increasing trend of temperature caused an increasing trend of annual snowmelt and runoff anomaly% at the rate of 24.82/10a and 9.87/10a, respectively. On the other hand, a declining trend in annual snow density and snow depth anomaly% was found at a rate of -5.32/10a and -1.93/10a, respectively. We concluded that the snow density, snowmelt and runoff are significantly sensitive to temperature in China. This contribution has provided information for further understanding of glacier variation and its influencing factors.
文摘Sulphur (S) cycling and implications on S fertilizer requirement in sheep-grazed pastures receiving three levels of S fertilizer at rates of 0, 30 and 60 kg S/hm 2 in 1995 and 1996 were studied using a mass-balance approach which accounted both for S inputs to and outputs from the soil-plant-animal system. Results indicated that S fertilizer increased by 50% of herbage S uptake and 15% or more of S bio-cycling rate in grazing system. The total S recovery of 30 and 60 kg S/hm 2 treatments from 1995 to 1996 was 74.0% and 37.6% respectively. Mineralization of organic S may be an important source of S for pasture when other S sources are low, accounted for 70% of the total S inputs without S fertilizer. The grazing sheep has an important ecological function, the feature of S cycling in grazed pastures was that 90% of herbage S ingested by grazing sheep was returned to soils as excreta. The amount of S released by sheep excreta accounted about 30% of the total released S through S bio-recycling. Loss from soil S leaching beyond the major plant rooting zone was the main S output from grazing system. However, urinary and fecal S losses, including transfer and leaching losses, also affected S budgets of grazing system. It is therefore important to investigate the recycling rate of both urinary and fecal S under field conditions. Based on the mass-balance principle, at least 10 kg S/hm 2 per year may be necessary for sustainable development of grazing system.
基金funded by Spanish Ministry of Economy and Competitiveness(Project CTM2012-33918)ICEX España Exportación e Inversiones(Project 2014/03076).
文摘Mercury(Hg)is a global pollutant that is subject to strict regulations to reduce anthropogenic emissions.The production of energy represents an important activity that leads to Hg emissions into the atmosphere.Of all the systems used,IGCC plants are the most promising for reducing Hg emissions,since it is possible to remove Hg from syngas prior to combustion.The aim of the present work was to evaluate the presence of Hg in the main streams of an experimental IGCC plant(ELCOGAS,Puertollano)in order to quantify Hg emissions and investigate the possibility of reducing them.The main streams of the system were sampled for three consecutive days and both the solids,i.e.,raw material(coal and petroleum coke),fine and coarse slags,fly ash,sulphur,and the liquids,i.e.,slag system,Venturi scrubber and saturator,were studied.The results show that an average of 12.9%of the Hg that enters the IGCC power plant is eliminated with solid waste and only 0.08%with liquid waste.There is still an average of 87.12%of Hg that is not accounted for in the mass balance and that could remain in the system and/or be eliminated in the streams that were not analysed.Although it is impossible to offer an explanation for the final fate of the Hg lost in the system based on the obtained results,the data suggest that sulphur byproducts could be primarily responsible for the elimination of Hg from the syngas,and that a major proportion of Hg should be emitted via the chimney after the syngas combustion process.
基金supported by the National Basic Research Program of China(Grant No.2013CB955704)the National Natural Science Fundation of China(Grant No.41172030)
文摘Molybdenum(Mo) proxies, including bulk concentration and isotopic composition, have been increasingly used to reconstruct ancient ocean redox states. This study systematically reviews Mo cycles and their accompanying isotopic fractionations in modern ocean as well as their application in paleo-ocean redox reconstruction. Our review indicates that Mo enrichment in sediments mainly records the adsorption of Fe-Mn oxides/hydroxides and chemical bonding of H2 S. Thus, Mo enrichment in anoxic sediments generally reflects the presence of H2 S in the water column or pore waters. In addition to the effect of euxinia, sedimentary Mo enrichment is related to the size of the oceanic Mo reservoir. Given these primary mechanisms for oceanic Mo cycling, Mo abundance data and Mo/TOC ratios acquired from euxinic sediments in geological times show that fluctuations of the oceanic Mo reservoir are well correlated with oxygenation of the atmosphere and oceans and suggest that oxygenation occurred in phases. Mo proxies suggest that Mo isotopes in strongly euxinic sediments reflect the contemporaneous Mo isotopic composition of seawater, but other processes such as iron-manganese(Fe-Mn) adsorption and weak euxinia can result in different fractionations. Diagenesis may complicate Mo enrichment and its isotopic fractionation in sediments. With appropriate constraints on the Mo isotopic composition of seawater and various outputs, a Mo isotope mass-balance model can quantitatively reconstruct global redox conditions over geological history. In summary, Mo proxies can be effectively used to reconstruct oceanic redox conditions on various timescales due to their sensitivity to both local and global marine redox conditions. However, given the complexity of geochemical processes, particularly the effects of diagenesis, further work is required to apply Mo proxies to ancient oceans.
