Resonance energies of the Cl II-[3s23p3(2D5/2)]nd and [3s23p3(2P3/2)]nd, Ar II-3s23p4(1D2)ns, nd and of the Kr II [4s24p4(1D2)]ns, nd and 4s24p4(3P2,3P1)]ns, 4s24p4(3D2)]ns, nd and 4s24p4(3D2, 1S0)]ns, nd Rydberg seri...Resonance energies of the Cl II-[3s23p3(2D5/2)]nd and [3s23p3(2P3/2)]nd, Ar II-3s23p4(1D2)ns, nd and of the Kr II [4s24p4(1D2)]ns, nd and 4s24p4(3P2,3P1)]ns, 4s24p4(3D2)]ns, nd and 4s24p4(3D2, 1S0)]ns, nd Rydberg series are reported. Natural widths of the Ar II-[3s23p4(1D2)]ns, nd series are also reported. Calculations are done in the framework of the Modified Atomic Orbital Theory (MAOT). Excellent agreements are obtained with available theoretical and experimental data. High lying accurate resonance energies up to n = 40 are tabulated. The possibility to use the MAOT formalism report rapidly with an excellent accuracy the position of the excitation resonances as well as their width within simple analytical formulae is demonstrated.展开更多
We consider the 4s^(2)4p^(4)(^(3)P_(1))nd,4s^(2)4p^(4)(^(1)D_(2))nd and 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series of Rb^(2+)originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2...We consider the 4s^(2)4p^(4)(^(3)P_(1))nd,4s^(2)4p^(4)(^(1)D_(2))nd and 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series of Rb^(2+)originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+)converging respectively to the 4s^(2)4p^(4)(^(3)P_(1)),4s^(2)4p^(4)(^(1)D_(2))and 4s^(2)4p^(4)(^(1)S_(0))series limit in Rb^(3+).The semi-empirical procedure of Modified Atomic Orbital Theory(MAOT)is applied to perform calculations in the present work from n=6 up to n=45.We note that the MAOT procedure gives accurate results compared to available Advanced Light Source(ALS)experimental data and other theoretical results.We tabulate new data from n=22-45 for 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+).The other Rydberg series 4s^(2)4p^(4)(^(3)P_(1))nd and 4s^(2)4p^(4)(^(1)D_(2))nd are extended up to n=45.展开更多
文摘Resonance energies of the Cl II-[3s23p3(2D5/2)]nd and [3s23p3(2P3/2)]nd, Ar II-3s23p4(1D2)ns, nd and of the Kr II [4s24p4(1D2)]ns, nd and 4s24p4(3P2,3P1)]ns, 4s24p4(3D2)]ns, nd and 4s24p4(3D2, 1S0)]ns, nd Rydberg series are reported. Natural widths of the Ar II-[3s23p4(1D2)]ns, nd series are also reported. Calculations are done in the framework of the Modified Atomic Orbital Theory (MAOT). Excellent agreements are obtained with available theoretical and experimental data. High lying accurate resonance energies up to n = 40 are tabulated. The possibility to use the MAOT formalism report rapidly with an excellent accuracy the position of the excitation resonances as well as their width within simple analytical formulae is demonstrated.
文摘We consider the 4s^(2)4p^(4)(^(3)P_(1))nd,4s^(2)4p^(4)(^(1)D_(2))nd and 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series of Rb^(2+)originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+)converging respectively to the 4s^(2)4p^(4)(^(3)P_(1)),4s^(2)4p^(4)(^(1)D_(2))and 4s^(2)4p^(4)(^(1)S_(0))series limit in Rb^(3+).The semi-empirical procedure of Modified Atomic Orbital Theory(MAOT)is applied to perform calculations in the present work from n=6 up to n=45.We note that the MAOT procedure gives accurate results compared to available Advanced Light Source(ALS)experimental data and other theoretical results.We tabulate new data from n=22-45 for 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+).The other Rydberg series 4s^(2)4p^(4)(^(3)P_(1))nd and 4s^(2)4p^(4)(^(1)D_(2))nd are extended up to n=45.
