近年来,部分特高压换流变压器在运行中相继发生电弧短路故障并引发爆炸、起火事故,严重威胁直流系统安全稳定运行。充油设备故障冲击下的结构失效机制尚不明确,且缺乏成熟的数值计算方法,制约故障防爆技术的发展。基于此,该文提出一套...近年来,部分特高压换流变压器在运行中相继发生电弧短路故障并引发爆炸、起火事故,严重威胁直流系统安全稳定运行。充油设备故障冲击下的结构失效机制尚不明确,且缺乏成熟的数值计算方法,制约故障防爆技术的发展。基于此,该文提出一套适用于高能电弧故障冲击的结构失效仿真计算方法。首先,建立有限腔体内油中电弧能量持续注入的气泡动力学模型,准确描述故障气泡的脉动膨胀行为;其次,提出自适应有限元-光滑粒子流体动力学(finite element method-smoothed particle hydrodynamics,FEM-SPH)耦合方法,利用SPH粒子继承失效前的物理信息参与FEM计算;进行不同能量、不同位置的电弧故障仿真计算,获得换流变压器结构的薄弱区域及其破裂行为,复现了油箱结构失效行为。研究发现,油箱顶盖两侧及侧壁转角接缝位置容易发生应力集中现象。一旦结构出现裂缝,将在极短时间内沿着应力集中方向快速发展,最终导致壁面整体撕裂。可知,该方法揭示的结构失效行为可为改进变压器设计和提高设备安全性提供依据。展开更多
In this paper, the improved version of the meshless singular boundary method (ISBM) is developed for analyzing the hydrodynamic performance of bottom-standing submerged breakwaters in regular normally incident waves. ...In this paper, the improved version of the meshless singular boundary method (ISBM) is developed for analyzing the hydrodynamic performance of bottom-standing submerged breakwaters in regular normally incident waves. Both the single and dual prismatic breakwaters of rectangular and trapezoidal forms are examined. Only the impermeable breakwaters are considered in this study. The physical problem is cast in terms of the Laplace equation governing an irrotational flow and incompressible fluid motion with the appropriate mixed-type boundary conditions, and it is solved numerically using the ISBM. The numerical results are presented in terms of the hydrodynamic quantities of reflection and transmission coefficients. The values are first validated against the data of previous studies, computed, and discussed for a variety of structural conditions, including the height, width, and spacing of breakwater submergence. An excellent agreement is observed between the ISBM results and those of other methods. The breakwater width is found to feature marginal effects compared with the height. The present method is shown to accurately predict the resonant conditions at which the maximum reflection and transmission occur. The trapezoidal breakwaters are found to generally present a wide spectrum of reflections, suggesting that they would function better than the rectangular breakwaters. The dual breakwater systems are confirmed to perform much better than single structures.展开更多
Natural gas hydrate(NGH)has a bright future as a clean energy source with huge reserves.Coring is one of the most direct methods for NGH exploration and research.Preserving the in-situ properties of the core as much a...Natural gas hydrate(NGH)has a bright future as a clean energy source with huge reserves.Coring is one of the most direct methods for NGH exploration and research.Preserving the in-situ properties of the core as much as possible during the coring process is crucial for the assessment of NGH resources.However,most existing NGH coring techniques cannot preserve the in-situ temperature of NGH,leading to distortion of the physical properties of the obtained core,which makes it difficult to effectively guide NGH exploration and development.To overcome this limitation,this study introduces an innovative active temperature-preserved coring method for NGH utilizing phase change materials(PCM).An active temperature-preserved corer(ATPC)is designed and developed,and an indoor experimental system is established to investigate the heat transfer during the coring process.Based on the experimental results under different environment temperatures,a heat transfer model for the entire ATPC coring process has been established.The indoor experimental results are consistent with the theoretical predictions of the heat transfer model,confirming its validity.This model has reconstructed the temperature changes of the NGH core during the coring process,demonstrating that compared to the traditional coring method with only passive temperature-preserved measures,ATPC can effectively reduce the core temperature by more than 5.25℃.With ATPC,at environment temperatures of 15,20,25,and 30℃,the duration of low-temperature state for the NGH core is 53.85,32.87,20.32,and 11.83 min,respectively.These findings provide new perspectives on temperature-preserving core sampling in NGH and provide technical support for exploration and development in NGH.展开更多
We adopted the solution impregnation route with aluminum dihydrogen phosphate solution as liquid medium for effective surface modification on graphite substrate.The mass ratio of graphite to Al(H_(2)PO_(4))_(3) change...We adopted the solution impregnation route with aluminum dihydrogen phosphate solution as liquid medium for effective surface modification on graphite substrate.The mass ratio of graphite to Al(H_(2)PO_(4))_(3) changed from 0.5:1 to 4:1,and the impregnation time changed from 1 to 7 h.The typical composite phase change thermal storage materials doped with the as-treated graphite were fabricated using form-stable technique.To investigate the oxidation and anti-oxidation behavior of the impregnated graphite at high temperatures,the samples were put into a muffle furnace for a cyclic heat test.Based on SEM,EDS,DSC techniques,analyses on the impregnated technique suggested an optimized processing conditions of a 3 h impregnation time with the ratio of graphite:Al(H_(2)PO_(4))_(3) as 1:3 for graphite impregnation treatment.Further investigations on high-temperature phase change heat storage materials doped by the treated graphite suggested excellent oxidation resistance and thermal cycling performance.展开更多
The commercial development of lithium-sulfur batteries(Li-S)is severely limited by the shuttle effect of lithium polysulfides(LPSs)and the non-conductivity of sulfur.Herein,porous g-C_(3)N_(4) nanotubes(PCNNTs)are syn...The commercial development of lithium-sulfur batteries(Li-S)is severely limited by the shuttle effect of lithium polysulfides(LPSs)and the non-conductivity of sulfur.Herein,porous g-C_(3)N_(4) nanotubes(PCNNTs)are synthesized via a self-template method and utilized as an efficient sulfur host material.The one-dimensional PCNNTs have a high specific surface area(143.47 m^(2)·g^(-1))and an abundance of macro-/mesopores,which could achieve a high sulfur loading rate of 74.7wt%.A Li-S battery bearing the PCNNTs/S composite as a cathode displays a low capacity decay of 0.021% per cycle over 800 cycles at 0.5 C with an initial capacity of 704.8 mAh·g^(-1).PCNNTs with a tubular structure could alleviate the volume expansion caused by sulfur and lithium sulfide during charge/discharge cycling.High N contents could greatly enhance the adsorption capacity of the carbon nitride for LPSs.These synergistic effects contribute to the excellent cycling stability and rate performance of the PCNNTs/S composite electrode.展开更多
Lithium-ion(Li-ion) battery and lithium-sulfur(Li-S) battery have attracted significant attention as promising components for large-scale energy storage because of high theoretical capacity of Li,excellent energy dens...Lithium-ion(Li-ion) battery and lithium-sulfur(Li-S) battery have attracted significant attention as promising components for large-scale energy storage because of high theoretical capacity of Li,excellent energy density or environmental friendness for two kinds of batteries.However,there still exist some respective obstacles for commercial applications,such as limited theoretical capacity,high cost and low conductivity of Li-ion cells or shuttle effect of lithium polysulfides of Li-S cells.As typical twodimensional materials,layered double hydroxides(LDHs) exhibit excellent potential in the field of energy storage due to facile tunability of composition,structure and morphology as well as convenient composite and strong catalytic properties.Consequently,various LDHs toward novel separators or interlayers,cathodes,anodes,and interesting catalytic templates are researched to resolve these challenges.In this review,the recent progress for LDHs applied in Li-ion batteries and Li-S batteries including the synthesis methods,designs and applications is presented and reviewed.Meanwhile,the existing challenges and future perspectives associated with material designs and practical applications of LDHs for these two classes of cells are discussed.WeWe hope that the review can attract more attention and inspire more profound researches toward the LDH-based electrochemical materials for energy storage.展开更多
A method to predict the solid-liquid interface stability during unidirectional solidification is developed by coupling M-S model with CALPHAD method. The method was applied to AI-0.38 Zn and AI-0.34 Si-0.14 Mg (wt pct...A method to predict the solid-liquid interface stability during unidirectional solidification is developed by coupling M-S model with CALPHAD method. The method was applied to AI-0.38 Zn and AI-0.34 Si-0.14 Mg (wt pct) alloys, and the predicted results were compared with some former experimental data of the two alloys. The good agreement between the calculation results and the experimental data demonstrates the superiority of the present method to the classical one based on constant parameter assumptions.展开更多
The active equalization of lithium-ion batteries involves transferring energy from high-voltage cells to low-voltage cells,ensuring consistent voltage levels across the battery pack and maintaining safety.This paper p...The active equalization of lithium-ion batteries involves transferring energy from high-voltage cells to low-voltage cells,ensuring consistent voltage levels across the battery pack and maintaining safety.This paper presents a voltage balancing circuit and control method.First,a single capacitor method is used to design the circuit topology for energy transfer.Next,real-time voltage detection and control are employed to balance energy between cells.Finally,simulation and experimental results demonstrate the effectiveness of the proposed method,achieving balanced voltages of 3.97 V from initial voltages of 4.10,3.97,and 3.90 V.The proposed circuit is simple,reliable,and effectively prevents overcharge and overdischarge.展开更多
Numerical simulation plays an important role in the dynamic analysis of multibody system.With the rapid development of computer science,the numerical solution technology has been further developed.Recently,data-driven...Numerical simulation plays an important role in the dynamic analysis of multibody system.With the rapid development of computer science,the numerical solution technology has been further developed.Recently,data-driven method has become a very popular computing method.However,due to lack of necessary mechanism information of the traditional pure data-driven methods based on neural network,its numerical accuracy cannot be guaranteed for strong nonlinear system.Therefore,this work proposes a mechanism-data hybrid-driven strategy for solving nonlinear multibody system based on physics-informed neural network to overcome the limitation of traditional data-driven methods.The strategy proposed in this paper introduces scaling coefficients to introduce the dynamic model of multibody system into neural network,ensuring that the training results of neural network conform to the mechanics principle of the system,thereby ensuring the good reliability of the data-driven method.Finally,the stability,generalization ability and numerical accuracy of the proposed method are discussed and analyzed using three typical multibody systems,and the constrained default situations can be controlled within the range of 10^(-2)-10^(-4).展开更多
Dispersed and peripheral spaces in the urban core are influenced both by the trend towards constant growth as well as social ways of life which are constantly evolving. Following a connotation, these two factors there...Dispersed and peripheral spaces in the urban core are influenced both by the trend towards constant growth as well as social ways of life which are constantly evolving. Following a connotation, these two factors therefore play a crucial role in defining the alternation of urban space--in particular, that of the centers. The main focus of this research article is on the methodology used in the survey and evaluation of ＂centralities＂ as well as their developments over the past four decades （1974-2014） in approaches to urban development that has been developed in Graz.~ The analysis has drawn on the four editions （＂evolution＂） of approaches to urban development as conceived by the city of Graz in order to examine their verbal characteristics in regard to centralities. At the same time, the analysis does not examine presentations of plans which exist in supplementary forms （e.g., explanatory reports and supplemented plans）--it restricts itself solely to the various plans set out in the STEKs.2 The highest degree of accuracy has been applied to the notion of ＂centralis＂ in approaches to urban development. The goal of the research project was to depict the modulation of the notion of ＂centrality＂ in the urban context as a space-forming dimension. Furthermore, it clearly shows the extent to which the notion of the ＂centre＂ （in the widest sense of the word） has become distanced from qualitative, spatial development and at the current time of urban development is experiencing a sort of Renaissance. In the field of ＂urban development＂, architectural references in the context of＂centrality＂ have scarcely been researched. This has led to the opening-up of a complex interdisciplinary research field. In order to make the complex architectural determinants of ＂centrality＂ more accessible to the participating disciplines, approaches to urban development have been explored in the form of a social and spatial analysis.展开更多
BACKGROUND Helicobacter pylori(H.pylori),a globally prevalent pathogen,is exhibiting increasing rates of antimicrobial resistance.However,clinical implementation of pre-treatment susceptibility testing remains limited...BACKGROUND Helicobacter pylori(H.pylori),a globally prevalent pathogen,is exhibiting increasing rates of antimicrobial resistance.However,clinical implementation of pre-treatment susceptibility testing remains limited due to the organism’s fastidious growth requirements and prolonged culture time.AIM To propose a novel detection method utilizing antibiotic-supplemented media to inhibit susceptible strains,while resistant isolates were identified through urease-mediated hydrolysis of urea,inducing a phenol red color change for visual confirmation.METHODS Colombia agar was supplemented with urea,phenol red,and nickel chloride,and the final pH was adjusted to 7.35.Antibiotic-selective media were prepared by incorporating amoxicillin(0.5μg/mL),clarithromycin(2μg/mL),metronidazole(8μg/mL),or levofloxacin(2μg/mL)into separate batches.Gastric antral biopsies were homogenized and inoculated at 1.0×105 CFU onto the media,and then incubated under microaerobic conditions at 37°C for 28-36 hours.Resistance was determined based on a color change from yellow to pink,and the results were validated via broth microdilution according to Clinical and Laboratory Standards Institute guidelines.RESULTS After 28-36 hours of incubation,the drug-resistant H.pylori isolates induced a light red color change in the medium.Conversely,susceptible strains(H.pylori 26695 and G27)produced no visible color change.Compared with the conventional 11-day protocol,the novel method significantly reduced detection time.Among 201 clinical isolates,182 were successfully evaluated using the new method,resulting in a 90.5%detection rate.This was consistent with the 95.5%agreement rate observed when compared with microdilution-based susceptibility testing.The success rate of the novel approach was significantly higher than that of the comparative method(P<0.01).The accuracy of the new method was comparable to that of the dilution method.CONCLUSION The novel detection method can rapidly detect H.pylori drug resistance within 28-36 hours.With its operational simplicity and high diagnostic performance,it holds strong potential for clinical application in the management of H.pylori antimicrobial resistance.展开更多
In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to ...In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method.展开更多
Objective: To explore the clinical efficacy of shoulder arthroscopic one-knot-two-wire suture bridge technique in the treatment of small and medium-sized rotator cuff tears. Methods: The clinical data of 22 patients w...Objective: To explore the clinical efficacy of shoulder arthroscopic one-knot-two-wire suture bridge technique in the treatment of small and medium-sized rotator cuff tears. Methods: The clinical data of 22 patients with small and medium-sized rotator cuff injuries treated with the one-knot-two-wire suture bridge technique from February 2022 to June 2023 in the Department of Orthopaedics of Jingzhou Hospital Affiliated to Yangtze University were retrospectively analysed, among which 14 cases were male and 8 cases were female;the age ranged from 35 to 68 years old, with an average of (50.86 ± 10.80) years old. All cases underwent an MRI examination of the shoulder joint to understand the type and degree of injury. The duration of the disease ranged from 120 to 166 d, with a mean of (141.23 ± 13.46) d. The evaluation of the operation time, intraoperative bleeding, visual analogue scale (VAS) of pain, Constant-Murley score and Sugaya grading of shoulder MRI were performed at the last follow-up. Results: All 22 patients were followed up for 12 - 18 months, with a mean of (14.68 ± 1.89 d). The operation time was 38 - 58 min, mean (48.18 ± 5.92) min;intraoperative bleeding was 5 - 15 mL, mean (10.00 ± 3.45) mL. All patients achieved normal healing without re-tear, vascular and nerve injury, incision infection, anchor nail loosening and dislodgement and other complications. At the last follow-up, both shoulders were normal in shape and symmetrical on both sides. The VAS score was 0 - 1.2 points, with an average of 0.61 ± 0.42 points, and the Constant-Murley score was 70 - 98 points, with an average of 86.09 ± 8.56 points. The Sugaya classification of MRI examination was 17 cases of grade I, 4 cases of grade II, and 1 case of grade III. Conclusion: One-knot-two-wire suture bridge technique is used for the treatment of small and medium-sized rotator cuff tears with short operative time, low bleeding, and good clinical outcome.展开更多
Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The t...Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.展开更多
Senior high school is an important stage for students to learn and a key time for students to enter the desired university. For junior high school knowledge, the difficulty of senior high school knowledge also rises s...Senior high school is an important stage for students to learn and a key time for students to enter the desired university. For junior high school knowledge, the difficulty of senior high school knowledge also rises sharply compared with junior high school. All subjects require stronger logical thinking and divergent thinking. As an important subject in senior high school, chemistry is very comprehensive and experimental. For high school students, they are facing great pressure from the college entrance examination and their studies. Therefore, excellent problem-solving skills can help students to learn more efficiently, and can also promote the cultivation of logical thinking ability, eventually forming a virtuous circle, making learning easier. As a common method in chemical problem solving, conservation method can greatly save students' time and improve the correct rate of problem solving, thus improving learning efficiency. This paper gives a brief introduction to the application of conservation method in high school chemistry problem solving, hoping to be helpful to the students.展开更多
Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization...Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization. The amount of carbon in the composite is less than 10% （mass fraction）, and the X-ray diffraction result confirms that the sample is of pure single phase indexed with the orthorhombic Pmn21 space group. The particle size of the Li2FeSiO4/C synthesized at 700 °C for 9 h is very fine and spherical-like with a size of 200 nm. The electrochemical performance of this material, including reversible capacity, cycle number, and charge-discharge characteristics, were tested. The cell of this sample can deliver a discharge capacity of 166 mA-h/g at C/20 rate in the first three cycles. After 30 cycles, the capacity decreases to 158 mA-h/g, and the capacity retention is up to 95%. The results show that this method can prepare nanosphere-like Li2FeSiO4/C composite with good electrochemical performance.展开更多
文摘近年来,部分特高压换流变压器在运行中相继发生电弧短路故障并引发爆炸、起火事故,严重威胁直流系统安全稳定运行。充油设备故障冲击下的结构失效机制尚不明确,且缺乏成熟的数值计算方法,制约故障防爆技术的发展。基于此,该文提出一套适用于高能电弧故障冲击的结构失效仿真计算方法。首先,建立有限腔体内油中电弧能量持续注入的气泡动力学模型,准确描述故障气泡的脉动膨胀行为;其次,提出自适应有限元-光滑粒子流体动力学(finite element method-smoothed particle hydrodynamics,FEM-SPH)耦合方法,利用SPH粒子继承失效前的物理信息参与FEM计算;进行不同能量、不同位置的电弧故障仿真计算,获得换流变压器结构的薄弱区域及其破裂行为,复现了油箱结构失效行为。研究发现,油箱顶盖两侧及侧壁转角接缝位置容易发生应力集中现象。一旦结构出现裂缝,将在极短时间内沿着应力集中方向快速发展,最终导致壁面整体撕裂。可知,该方法揭示的结构失效行为可为改进变压器设计和提高设备安全性提供依据。
基金supported by the Direction Général des Enseignements et de la Formation Supérieure of Algeria under Grant CNEPRU number G0301920140029
文摘In this paper, the improved version of the meshless singular boundary method (ISBM) is developed for analyzing the hydrodynamic performance of bottom-standing submerged breakwaters in regular normally incident waves. Both the single and dual prismatic breakwaters of rectangular and trapezoidal forms are examined. Only the impermeable breakwaters are considered in this study. The physical problem is cast in terms of the Laplace equation governing an irrotational flow and incompressible fluid motion with the appropriate mixed-type boundary conditions, and it is solved numerically using the ISBM. The numerical results are presented in terms of the hydrodynamic quantities of reflection and transmission coefficients. The values are first validated against the data of previous studies, computed, and discussed for a variety of structural conditions, including the height, width, and spacing of breakwater submergence. An excellent agreement is observed between the ISBM results and those of other methods. The breakwater width is found to feature marginal effects compared with the height. The present method is shown to accurately predict the resonant conditions at which the maximum reflection and transmission occur. The trapezoidal breakwaters are found to generally present a wide spectrum of reflections, suggesting that they would function better than the rectangular breakwaters. The dual breakwater systems are confirmed to perform much better than single structures.
基金financially supported by Shenzhen Science and Technology Program(Nos.JSGG20220831105002005 and KJZD20231025152759002)the National Natural Science Foundation of China(Nos.52274133 and 523B2101).
文摘Natural gas hydrate(NGH)has a bright future as a clean energy source with huge reserves.Coring is one of the most direct methods for NGH exploration and research.Preserving the in-situ properties of the core as much as possible during the coring process is crucial for the assessment of NGH resources.However,most existing NGH coring techniques cannot preserve the in-situ temperature of NGH,leading to distortion of the physical properties of the obtained core,which makes it difficult to effectively guide NGH exploration and development.To overcome this limitation,this study introduces an innovative active temperature-preserved coring method for NGH utilizing phase change materials(PCM).An active temperature-preserved corer(ATPC)is designed and developed,and an indoor experimental system is established to investigate the heat transfer during the coring process.Based on the experimental results under different environment temperatures,a heat transfer model for the entire ATPC coring process has been established.The indoor experimental results are consistent with the theoretical predictions of the heat transfer model,confirming its validity.This model has reconstructed the temperature changes of the NGH core during the coring process,demonstrating that compared to the traditional coring method with only passive temperature-preserved measures,ATPC can effectively reduce the core temperature by more than 5.25℃.With ATPC,at environment temperatures of 15,20,25,and 30℃,the duration of low-temperature state for the NGH core is 53.85,32.87,20.32,and 11.83 min,respectively.These findings provide new perspectives on temperature-preserving core sampling in NGH and provide technical support for exploration and development in NGH.
基金Funded by Scientific and Technological Innovation Project of Carbon Emission Peak and Carbon Neutrality of Jiangsu Province(No.BE2022028-4)。
文摘We adopted the solution impregnation route with aluminum dihydrogen phosphate solution as liquid medium for effective surface modification on graphite substrate.The mass ratio of graphite to Al(H_(2)PO_(4))_(3) changed from 0.5:1 to 4:1,and the impregnation time changed from 1 to 7 h.The typical composite phase change thermal storage materials doped with the as-treated graphite were fabricated using form-stable technique.To investigate the oxidation and anti-oxidation behavior of the impregnated graphite at high temperatures,the samples were put into a muffle furnace for a cyclic heat test.Based on SEM,EDS,DSC techniques,analyses on the impregnated technique suggested an optimized processing conditions of a 3 h impregnation time with the ratio of graphite:Al(H_(2)PO_(4))_(3) as 1:3 for graphite impregnation treatment.Further investigations on high-temperature phase change heat storage materials doped by the treated graphite suggested excellent oxidation resistance and thermal cycling performance.
基金financially supported by the Natural Science Sci-ence Foundation of Jiangsu Province,China(No.BK20181469)the Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110035)the Science and Technology Planning Social Development Project of Zhenji-ang City,China(No.SSH20190140049).
文摘The commercial development of lithium-sulfur batteries(Li-S)is severely limited by the shuttle effect of lithium polysulfides(LPSs)and the non-conductivity of sulfur.Herein,porous g-C_(3)N_(4) nanotubes(PCNNTs)are synthesized via a self-template method and utilized as an efficient sulfur host material.The one-dimensional PCNNTs have a high specific surface area(143.47 m^(2)·g^(-1))and an abundance of macro-/mesopores,which could achieve a high sulfur loading rate of 74.7wt%.A Li-S battery bearing the PCNNTs/S composite as a cathode displays a low capacity decay of 0.021% per cycle over 800 cycles at 0.5 C with an initial capacity of 704.8 mAh·g^(-1).PCNNTs with a tubular structure could alleviate the volume expansion caused by sulfur and lithium sulfide during charge/discharge cycling.High N contents could greatly enhance the adsorption capacity of the carbon nitride for LPSs.These synergistic effects contribute to the excellent cycling stability and rate performance of the PCNNTs/S composite electrode.
基金the National Natural Science Foundation of China(51973157,51673148 and 51678411)the Special Grade of the Financial Support from the China Postdoctoral Science Foundation(2020 T130469)+1 种基金the China Postdoctoral Science Foundation Grant(2019 M651047)the Science and Technology Plans of Tianjin(No.17PTSYJC00040 and18PTSYJC00180)for their financial support。
文摘Lithium-ion(Li-ion) battery and lithium-sulfur(Li-S) battery have attracted significant attention as promising components for large-scale energy storage because of high theoretical capacity of Li,excellent energy density or environmental friendness for two kinds of batteries.However,there still exist some respective obstacles for commercial applications,such as limited theoretical capacity,high cost and low conductivity of Li-ion cells or shuttle effect of lithium polysulfides of Li-S cells.As typical twodimensional materials,layered double hydroxides(LDHs) exhibit excellent potential in the field of energy storage due to facile tunability of composition,structure and morphology as well as convenient composite and strong catalytic properties.Consequently,various LDHs toward novel separators or interlayers,cathodes,anodes,and interesting catalytic templates are researched to resolve these challenges.In this review,the recent progress for LDHs applied in Li-ion batteries and Li-S batteries including the synthesis methods,designs and applications is presented and reviewed.Meanwhile,the existing challenges and future perspectives associated with material designs and practical applications of LDHs for these two classes of cells are discussed.WeWe hope that the review can attract more attention and inspire more profound researches toward the LDH-based electrochemical materials for energy storage.
基金the State Key Fundamental Research Project(G2000067202-1).
文摘A method to predict the solid-liquid interface stability during unidirectional solidification is developed by coupling M-S model with CALPHAD method. The method was applied to AI-0.38 Zn and AI-0.34 Si-0.14 Mg (wt pct) alloys, and the predicted results were compared with some former experimental data of the two alloys. The good agreement between the calculation results and the experimental data demonstrates the superiority of the present method to the classical one based on constant parameter assumptions.
基金funded by the Basic Science(Natural Science)Research Project of Colleges and Universities in Jiangsu Province,Grant Number 22KJD470002.
文摘The active equalization of lithium-ion batteries involves transferring energy from high-voltage cells to low-voltage cells,ensuring consistent voltage levels across the battery pack and maintaining safety.This paper presents a voltage balancing circuit and control method.First,a single capacitor method is used to design the circuit topology for energy transfer.Next,real-time voltage detection and control are employed to balance energy between cells.Finally,simulation and experimental results demonstrate the effectiveness of the proposed method,achieving balanced voltages of 3.97 V from initial voltages of 4.10,3.97,and 3.90 V.The proposed circuit is simple,reliable,and effectively prevents overcharge and overdischarge.
基金supported by the National Natural Science Foundation of China(Grant No.U2241263)the fellowship of China Postdoctoral Science Foundation(Grant No.2024M750310).
文摘Numerical simulation plays an important role in the dynamic analysis of multibody system.With the rapid development of computer science,the numerical solution technology has been further developed.Recently,data-driven method has become a very popular computing method.However,due to lack of necessary mechanism information of the traditional pure data-driven methods based on neural network,its numerical accuracy cannot be guaranteed for strong nonlinear system.Therefore,this work proposes a mechanism-data hybrid-driven strategy for solving nonlinear multibody system based on physics-informed neural network to overcome the limitation of traditional data-driven methods.The strategy proposed in this paper introduces scaling coefficients to introduce the dynamic model of multibody system into neural network,ensuring that the training results of neural network conform to the mechanics principle of the system,thereby ensuring the good reliability of the data-driven method.Finally,the stability,generalization ability and numerical accuracy of the proposed method are discussed and analyzed using three typical multibody systems,and the constrained default situations can be controlled within the range of 10^(-2)-10^(-4).
文摘Dispersed and peripheral spaces in the urban core are influenced both by the trend towards constant growth as well as social ways of life which are constantly evolving. Following a connotation, these two factors therefore play a crucial role in defining the alternation of urban space--in particular, that of the centers. The main focus of this research article is on the methodology used in the survey and evaluation of ＂centralities＂ as well as their developments over the past four decades （1974-2014） in approaches to urban development that has been developed in Graz.~ The analysis has drawn on the four editions （＂evolution＂） of approaches to urban development as conceived by the city of Graz in order to examine their verbal characteristics in regard to centralities. At the same time, the analysis does not examine presentations of plans which exist in supplementary forms （e.g., explanatory reports and supplemented plans）--it restricts itself solely to the various plans set out in the STEKs.2 The highest degree of accuracy has been applied to the notion of ＂centralis＂ in approaches to urban development. The goal of the research project was to depict the modulation of the notion of ＂centrality＂ in the urban context as a space-forming dimension. Furthermore, it clearly shows the extent to which the notion of the ＂centre＂ （in the widest sense of the word） has become distanced from qualitative, spatial development and at the current time of urban development is experiencing a sort of Renaissance. In the field of ＂urban development＂, architectural references in the context of＂centrality＂ have scarcely been researched. This has led to the opening-up of a complex interdisciplinary research field. In order to make the complex architectural determinants of ＂centrality＂ more accessible to the participating disciplines, approaches to urban development have been explored in the form of a social and spatial analysis.
基金Supported by the Guangxi Science and Technology Major Projects,No.AA23073012the National Natural Science Foundation of China,No.32360035 and No.32060018。
文摘BACKGROUND Helicobacter pylori(H.pylori),a globally prevalent pathogen,is exhibiting increasing rates of antimicrobial resistance.However,clinical implementation of pre-treatment susceptibility testing remains limited due to the organism’s fastidious growth requirements and prolonged culture time.AIM To propose a novel detection method utilizing antibiotic-supplemented media to inhibit susceptible strains,while resistant isolates were identified through urease-mediated hydrolysis of urea,inducing a phenol red color change for visual confirmation.METHODS Colombia agar was supplemented with urea,phenol red,and nickel chloride,and the final pH was adjusted to 7.35.Antibiotic-selective media were prepared by incorporating amoxicillin(0.5μg/mL),clarithromycin(2μg/mL),metronidazole(8μg/mL),or levofloxacin(2μg/mL)into separate batches.Gastric antral biopsies were homogenized and inoculated at 1.0×105 CFU onto the media,and then incubated under microaerobic conditions at 37°C for 28-36 hours.Resistance was determined based on a color change from yellow to pink,and the results were validated via broth microdilution according to Clinical and Laboratory Standards Institute guidelines.RESULTS After 28-36 hours of incubation,the drug-resistant H.pylori isolates induced a light red color change in the medium.Conversely,susceptible strains(H.pylori 26695 and G27)produced no visible color change.Compared with the conventional 11-day protocol,the novel method significantly reduced detection time.Among 201 clinical isolates,182 were successfully evaluated using the new method,resulting in a 90.5%detection rate.This was consistent with the 95.5%agreement rate observed when compared with microdilution-based susceptibility testing.The success rate of the novel approach was significantly higher than that of the comparative method(P<0.01).The accuracy of the new method was comparable to that of the dilution method.CONCLUSION The novel detection method can rapidly detect H.pylori drug resistance within 28-36 hours.With its operational simplicity and high diagnostic performance,it holds strong potential for clinical application in the management of H.pylori antimicrobial resistance.
基金Supported in part by Natural Science Foundation of Guangxi(2023GXNSFAA026246)in part by the Central Government's Guide to Local Science and Technology Development Fund(GuikeZY23055044)in part by the National Natural Science Foundation of China(62363003)。
文摘In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method.
文摘Objective: To explore the clinical efficacy of shoulder arthroscopic one-knot-two-wire suture bridge technique in the treatment of small and medium-sized rotator cuff tears. Methods: The clinical data of 22 patients with small and medium-sized rotator cuff injuries treated with the one-knot-two-wire suture bridge technique from February 2022 to June 2023 in the Department of Orthopaedics of Jingzhou Hospital Affiliated to Yangtze University were retrospectively analysed, among which 14 cases were male and 8 cases were female;the age ranged from 35 to 68 years old, with an average of (50.86 ± 10.80) years old. All cases underwent an MRI examination of the shoulder joint to understand the type and degree of injury. The duration of the disease ranged from 120 to 166 d, with a mean of (141.23 ± 13.46) d. The evaluation of the operation time, intraoperative bleeding, visual analogue scale (VAS) of pain, Constant-Murley score and Sugaya grading of shoulder MRI were performed at the last follow-up. Results: All 22 patients were followed up for 12 - 18 months, with a mean of (14.68 ± 1.89 d). The operation time was 38 - 58 min, mean (48.18 ± 5.92) min;intraoperative bleeding was 5 - 15 mL, mean (10.00 ± 3.45) mL. All patients achieved normal healing without re-tear, vascular and nerve injury, incision infection, anchor nail loosening and dislodgement and other complications. At the last follow-up, both shoulders were normal in shape and symmetrical on both sides. The VAS score was 0 - 1.2 points, with an average of 0.61 ± 0.42 points, and the Constant-Murley score was 70 - 98 points, with an average of 86.09 ± 8.56 points. The Sugaya classification of MRI examination was 17 cases of grade I, 4 cases of grade II, and 1 case of grade III. Conclusion: One-knot-two-wire suture bridge technique is used for the treatment of small and medium-sized rotator cuff tears with short operative time, low bleeding, and good clinical outcome.
基金Supported by the National Natural Science Foundation of China under Grant No.51975138the High-Tech Ship Scientific Research Project from the Ministry of Industry and Information Technology under Grant No.CJ05N20the National Defense Basic Research Project under Grant No.JCKY2023604C006.
文摘Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.
文摘Senior high school is an important stage for students to learn and a key time for students to enter the desired university. For junior high school knowledge, the difficulty of senior high school knowledge also rises sharply compared with junior high school. All subjects require stronger logical thinking and divergent thinking. As an important subject in senior high school, chemistry is very comprehensive and experimental. For high school students, they are facing great pressure from the college entrance examination and their studies. Therefore, excellent problem-solving skills can help students to learn more efficiently, and can also promote the cultivation of logical thinking ability, eventually forming a virtuous circle, making learning easier. As a common method in chemical problem solving, conservation method can greatly save students' time and improve the correct rate of problem solving, thus improving learning efficiency. This paper gives a brief introduction to the application of conservation method in high school chemistry problem solving, hoping to be helpful to the students.
基金Project supported by Ministry of Education Key Laboratory of Synthetic and Natural Functional Molecular Chemistry, China Project (2010JK765) supported by the Education Department of Shaanxi Province, China
文摘Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization. The amount of carbon in the composite is less than 10% （mass fraction）, and the X-ray diffraction result confirms that the sample is of pure single phase indexed with the orthorhombic Pmn21 space group. The particle size of the Li2FeSiO4/C synthesized at 700 °C for 9 h is very fine and spherical-like with a size of 200 nm. The electrochemical performance of this material, including reversible capacity, cycle number, and charge-discharge characteristics, were tested. The cell of this sample can deliver a discharge capacity of 166 mA-h/g at C/20 rate in the first three cycles. After 30 cycles, the capacity decreases to 158 mA-h/g, and the capacity retention is up to 95%. The results show that this method can prepare nanosphere-like Li2FeSiO4/C composite with good electrochemical performance.
