Photocatalytic water splitting is a promising strategy to produce hydrogen as a sustainable and clean energy carrier,based on abundant solar energy and semiconductor photocatalysts,and it has received extensive resear...Photocatalytic water splitting is a promising strategy to produce hydrogen as a sustainable and clean energy carrier,based on abundant solar energy and semiconductor photocatalysts,and it has received extensive research and discussion over the past several decades.It is challenging,however,to achieve an efficient solar-to-hydrogen evolution process with a single particulate photocatalyst due to the weak solar spectrum harvest and the rapid recombination of photogenerated electron-hole pairs during the photocatalysis reaction.Combining semiconductors to create different co-catalysts presents a viable solution to the above issues.Recently,semiconductor photocatalysts modified by different transition metal sulfidebased co-catalysts with designed functions,especially in light absorption enhancement and chargecarrier-separation efficiency promotion,have attracted much attention.As continued breakthroughs have been made in the preparation,modification,and solar-to-hydrogen evolution application of the 1T phase MS_(2)(M=W,Mo)co-catalyst-based photocatalysis system in recent years,we believe that a comprehensive review of this kind of co-catalyst would further promote its research and development to address the energy and environmental challenges that we are currently facing.Herein,recent studies and progress are summarized on the fabrication of 1T phase MS_(2)(M=W,Mo)-based co-catalyst materials,as well as their roles and functional mechanisms for photocatalytic H;evolution.Finally,concluding perspectives on the opportunities in and challenges for the further exploration of the 1T-MS_(2)(M=W,Mo)-based solar-tohydrogen evolution system are presented.展开更多
The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which we...The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which were trinuclear complexes containing M(O)and determined their crystal structure.展开更多
基金supported by the National Natural Science Foundation of China(21501137)Graduate Education Innovation Fund of Wuhan Institute of Technology(CX2020257)the Australian Research Council for funding through Discovery Early Career Researcher Award(DECRA,No.DE180101478)。
文摘Photocatalytic water splitting is a promising strategy to produce hydrogen as a sustainable and clean energy carrier,based on abundant solar energy and semiconductor photocatalysts,and it has received extensive research and discussion over the past several decades.It is challenging,however,to achieve an efficient solar-to-hydrogen evolution process with a single particulate photocatalyst due to the weak solar spectrum harvest and the rapid recombination of photogenerated electron-hole pairs during the photocatalysis reaction.Combining semiconductors to create different co-catalysts presents a viable solution to the above issues.Recently,semiconductor photocatalysts modified by different transition metal sulfidebased co-catalysts with designed functions,especially in light absorption enhancement and chargecarrier-separation efficiency promotion,have attracted much attention.As continued breakthroughs have been made in the preparation,modification,and solar-to-hydrogen evolution application of the 1T phase MS_(2)(M=W,Mo)co-catalyst-based photocatalysis system in recent years,we believe that a comprehensive review of this kind of co-catalyst would further promote its research and development to address the energy and environmental challenges that we are currently facing.Herein,recent studies and progress are summarized on the fabrication of 1T phase MS_(2)(M=W,Mo)-based co-catalyst materials,as well as their roles and functional mechanisms for photocatalytic H;evolution.Finally,concluding perspectives on the opportunities in and challenges for the further exploration of the 1T-MS_(2)(M=W,Mo)-based solar-tohydrogen evolution system are presented.
文摘The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which were trinuclear complexes containing M(O)and determined their crystal structure.
