This paper studies cooperative robust parallel operation of multiple actuators over an undirected communication graph.The plant is modeled as an uncertain linear system,and the actuators are linear and identical.Based...This paper studies cooperative robust parallel operation of multiple actuators over an undirected communication graph.The plant is modeled as an uncertain linear system,and the actuators are linear and identical.Based on the internal model principle,a distributed dynamic output feedback control law is proposed to achieve both robust output regulation of the closed-loop system and plant input sharing among the actuators.A practical example of five motors cooperatively driving an uncertain shaft under an external load torque is presented to show the effectiveness of the proposed control law.展开更多
Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operato...Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operator training,etc.;thus,a hierarchical digital twin would be a comprehensive solution to that.In this study,a novel and general framework of the digital twin is proposed for operations in process industry.With the hierarchical structure,the framework can handle various tasks driven by different roles in process industry,including managers,engineers,and operators.To complete these tasks,the framework consists of three modules:OAS(Operation Analysis System),OMS(Operation Monitoring System),and OTS(Operator Training System).Each module focuses on one unique type of demand from the staff,as well as interactions among them enabling efficient data sharing.Based on the hierarchical framework,a digital twin system is applied for one complex industrial nitration process,which successfully enhances the operation efficiency and safety in several industrial scenarios with different demands.展开更多
In order to explore the effects of CaO,lignite dust and sawdust on the drying characteristics ofmunicipal sludge at different concentrations,a three-factor three-level regression experiment was carried out based on th...In order to explore the effects of CaO,lignite dust and sawdust on the drying characteristics ofmunicipal sludge at different concentrations,a three-factor three-level regression experiment was carried out based on the results of thermogravimetric experiment and single factor experiment.By fitting three common mathematical models,the Page model with the highest fitting degree was selected to determine the most suitable mathematical model to describe the municipal sludge drying process.In addition,the Box-Behnken design principle in the response surface method was used to analyze the interaction of three factors on the drying characteristics of municipal sludge.The results of the study show that below 100℃is the optimal drying temperature range for municipal sludge.The results of single factor experiments showed that the order of influence of the three factors on sludge drying time was CaO concentration>sawdust concentration>lignite dust concentration.In the single factor experiment,the optimal process parameterswere CaOconcentration 3%,lignite powder concentration 7%,and sawdust concentration 7%.In themulti-factor interaction analysis,the interaction between CaO and sawdust had the most significant effect on the reduction of drying time,and the order of influence was as follows:CaO interaction with sawdust>lignite dust interaction with sawdust>CaO interaction with lignite powder.Further analysis showed that the optimal process ratio was 3%CaO concentration and 3%sawdust concentration.展开更多
Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temp...Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temperature(LT)operation.Therefore,a more comprehensive and systematic understanding of LIB behavior at LT is urgently required.This review article comprehensively reviews recent advancements in electrolyte engineering strategies aimed at improving the low-temperature operational capabilities of LIBs.The study methodically examines critical performance-limiting mechanisms through fundamental analysis of four primary challenges:insufficient ionic conductivity under cryogenic conditions,kinetically hindered charge transfer processes,Li+transport limitations across the solidelectrolyte interphase(SEI),and uncontrolled lithium dendrite growth.The work elaborates on innovative optimization approaches encompassing lithium salt molecular design with tailored dissociation characteristics,solvent matrix optimization through dielectric constant and viscosity regulation,interfacial engineering additives for constructing low-impedance SEI layers,and gel-polymer composite electrolyte systems.Notably,particular emphasis is placed on emerging machine learning-guided electrolyte formulation strategies that enable high-throughput virtual screening of constituent combinations and prediction of structure-property relationships.These artificial intelligence-assisted rational design frameworks demonstrate significant potential for accelerating the development of next-generation LT electrolytes by establishing quantitative composition-performance correlations through advanced data-driven methodologies.展开更多
This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0...This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.1)Mo_(0.05)O_(3-δ)(B S CNM_(0.05)),Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.05)Mo_(0.1)O_(3-δ)(BSCNM_(0.1)),and Ba_(0.6)Sr_(0.4)Co_(0.85)Mo_(0.15)O_(3-δ)(BSCM)—with Mo doping contents of 5mol%,10mol%,and15mol%,respectively,were successfully prepared using the sol-gel method.The effects of Mo doping on the crystal structure,conductivity,thermal expansion coefficient,oxygen reduction reaction(ORR)activity,and electrochemical performance were systematically evaluated using X-ray diffraction analysis,thermally induced characterization,electrochemical impedance spectroscopy,and single-cell performance tests.The results revealed that Mo doping could improve the conductivity of the materials,suppress their thermal expansion effects,and significantly improve the electrochemical performance.Surface chemical state analysis using X-ray photoelectron spectroscopy revealed that 5mol%Mo doping could facilitate a high adsorbed oxygen concentration leading to enhanced ORR activity in the materials.Density functional theory calculations confirmed that Mo doping promoted the ORR activity in the materials.At an operating temperature of 600℃,the BSCNM_(0.05)cathode material exhibited significantly enhanced electrochemical impedance characteristics,with a reduced area specific resistance of 0.048Ω·cm~2,which was lower than that of the undoped BSCN matrix material by 32.39%.At the same operating temperature,an anode-supported single cell using a BSCNM_(0.05)cathode achieved a peak power density of 1477 mW·cm^(-2),which was 30.71%,56.30%,and 171.50%higher than those of BSCN,BSCNM_(0.1),and B SCM,respectively.The improved ORR activity and electrochemical performance of BSCNM_(0.05)indicate that it can be used as a cathode material in low-temperature solid oxide fuel cells.展开更多
On December 18,2025, Hainan Free Trade Port (Hainan FTP) officially began islandwide special customs operations.Although only two months have passed since this landmark step, the shift is already visible everywhere—f...On December 18,2025, Hainan Free Trade Port (Hainan FTP) officially began islandwide special customs operations.Although only two months have passed since this landmark step, the shift is already visible everywhere—from the bustling flow of international passengers at Haikou Meilan International Airport to the steady stream of cargo vessels calling at Yangpu Port, and even in the sustained attention investors are paying to “Hainan-related” stocks.Together, these signals point to one clear conclusion:China’s largest special economic zone has entered a new phase of development.展开更多
Efficient implementation of fundamental matrix operations on quantum computers,such as matrix products and Hadamard operations,holds significant potential for accelerating machine learning algorithms.A critical prereq...Efficient implementation of fundamental matrix operations on quantum computers,such as matrix products and Hadamard operations,holds significant potential for accelerating machine learning algorithms.A critical prerequisite for quantum implementations is the effective encoding of classical data into quantum states.We propose two quantum computing frameworks for preparing the distinct encoded states corresponding to matrix operations,including the matrix product,matrix sum,matrix Hadamard product and division.Quantum algorithms based on the digital encoding computing framework are capable of implementing the matrix Hadamard operation with a time complexity of O(poly log(mn/ε))and the matrix product with a time complexity of O(poly log(mnl/ε)),achieving an exponential speedup in contrast to the classical methods of O(mn)and O(mnl).Quantum algorithms based on the analog-encoding framework are capable of implementing the matrix Hadamard operation with a time complexity of O(k_(1)√mn·poly log(mn/ε))and the matrix product with a time complexity of O(k_(2)√1·poly log(mnl/ε)),where k_(1)and k_(2)are coefficients correlated with the elements of the matrix,achieving a square speedup in contrast to the classical counterparts.As applications,we construct an oracle that can access the trace of a matrix within logarithmic time,and propose several algorithms to respectively estimate the trace of a matrix,the trace of the product of two matrices,and the trace inner product of two matrices within logarithmic time.展开更多
Loday introduced di-associative algebras and tri-associative algebras motivated by periodicity phenomena in algebraic K-theory.The purpose of this paper is to study the splittings of operations on di-associative algeb...Loday introduced di-associative algebras and tri-associative algebras motivated by periodicity phenomena in algebraic K-theory.The purpose of this paper is to study the splittings of operations on di-associative algebras and tri-associative algebras.We introduce the notion of a quad-dendriform algebra,which is a splitting of a di-associative algebra.We show that a relative averaging operator on dendriform algebras gives rise to a quad-dendriform algebra.Furthermore,we introduce the notion of six-dendriform algebras,which are splittings of the tri-associative algebras,and demonstrate that homomorphic relative averaging operators induce six-dendriform algebras.展开更多
In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm ...In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm co-design framework:the T-type three-level bidirectional converter(100 kHz switching frequency)based on silicon carbide(SiC)MOSFET is deeply integrated with fuzzy model predictive control(Fuzzy-MPC).At the hardware level,the switching trajectory and resonance suppression circuit(attenuation resonance peak 18 dB)are optimized,and the total loss is reduced by 23%compared with the traditional silicon-based IGBT.At the algorithm level,the adaptive parameter update mechanism and multi-objective rolling optimization are adopted,and the 5 ms level dynamic power allocation is realized by relying on edge computing.Experiments on 800 V DC microgrid(including 600 kW photovoltaic and 150 A·h energy storage)built based on MATLAB/Simulink hardware-in-the-loop(HIL)platform show that the system shortens the battery charging time from 42 to 28 min(the charging speed is increased by 33%).Through the 78%valley power utilization rate,the power purchase cost of high-priced power grids was significantly reduced,and the levelized electricity price decreased by 10.3%;Under the irradiation fluctuation,the renewable energy consumption rate increases by 10.1%,and the DC bus voltage fluctuation is stable within±10 V when the load step is±30%.The co-design provides an economically feasible and dynamically robust solution for the efficient integration of PV-ESG-EV in the smart grid.展开更多
As joint operations have become a key trend in modern military development,unmanned aerial vehicles(UAVs)play an increasingly important role in enhancing the intelligence and responsiveness of combat systems.However,t...As joint operations have become a key trend in modern military development,unmanned aerial vehicles(UAVs)play an increasingly important role in enhancing the intelligence and responsiveness of combat systems.However,the heterogeneity of aircraft,partial observability,and dynamic uncertainty in operational airspace pose significant challenges to autonomous collision avoidance using traditional methods.To address these issues,this paper proposes an adaptive collision avoidance approach for UAVs based on deep reinforcement learning.First,a unified uncertainty model incorporating dynamic wind fields is constructed to capture the complexity of joint operational environments.Then,to effectively handle the heterogeneity between manned and unmanned aircraft and the limitations of dynamic observations,a sector-based partial observation mechanism is designed.A Dynamic Threat Prioritization Assessment algorithm is also proposed to evaluate potential collision threats from multiple dimensions,including time to closest approach,minimum separation distance,and aircraft type.Furthermore,a Hierarchical Prioritized Experience Replay(HPER)mechanism is introduced,which classifies experience samples into high,medium,and low priority levels to preferentially sample critical experiences,thereby improving learning efficiency and accelerating policy convergence.Simulation results show that the proposed HPER-D3QN algorithm outperforms existing methods in terms of learning speed,environmental adaptability,and robustness,significantly enhancing collision avoidance performance and convergence rate.Finally,transfer experiments on a high-fidelity battlefield airspace simulation platform validate the proposed method's deployment potential and practical applicability in complex,real-world joint operational scenarios.展开更多
For ordinary tourists, simpler entry and exit procedures and a broader range of duty-free goods in Hainan create a better travel and shopping experience.For China’s earnest endeavor to deepen reform and opening-up, i...For ordinary tourists, simpler entry and exit procedures and a broader range of duty-free goods in Hainan create a better travel and shopping experience.For China’s earnest endeavor to deepen reform and opening-up, implementation of the special customs operations policy in Hainan represents a significant step forward. For businesses in Malaysia and other ASEAN member states, especially export-oriented small and medium-sized enterprises (SMEs), Hainan serves as a“transit hub” for accessing the Chinese market and even other Asian markets.展开更多
With the gradual implementation of a series of institutional arrangements, H ainan is becoming a new hot spot for global investment and an ideal destination for starting businesses and developing industry. While attra...With the gradual implementation of a series of institutional arrangements, H ainan is becoming a new hot spot for global investment and an ideal destination for starting businesses and developing industry. While attracting foreign investment projects, it is also creating more favorable conditions for local enterprises to expand into international markets.展开更多
At 11:00 p.m. on January 13, 2026, floodlights illuminated the launch pad at the Hainan Commercial Space Launch Site in Wenchang,south China’s Hainan Province. A Long March-8A (CZ-8A) carrier rocket lifted off with a...At 11:00 p.m. on January 13, 2026, floodlights illuminated the launch pad at the Hainan Commercial Space Launch Site in Wenchang,south China’s Hainan Province. A Long March-8A (CZ-8A) carrier rocket lifted off with a steady roar, its exhaust lighting up the night sky as it delivered a satellite into its designated orbit.The development of China’s first commercial space launch site has been striking. Since its inaugural launch in2024, it has completed 11 missions in less than 14 months—each a success.展开更多
THE Hainan Free Trade Port(FTP)officially launched island-wide special customs operations on December 18,2025.One month in,a reporting team from China International Communications Group(CICG)conducted an exclusive int...THE Hainan Free Trade Port(FTP)officially launched island-wide special customs operations on December 18,2025.One month in,a reporting team from China International Communications Group(CICG)conducted an exclusive interview with Feng Fei,secretary of the Hainan Provincial Committee of the Communist Party of China(CPC)and chairman of the Standing Committee of the Hainan Provincial People’s Congress.展开更多
The low-temperature spray drying technology was developed to process instant berry powder with high efficiency and higher anthocyanin retention.The maltodextrin,whey protein and inulin were selected as additives for i...The low-temperature spray drying technology was developed to process instant berry powder with high efficiency and higher anthocyanin retention.The maltodextrin,whey protein and inulin were selected as additives for instant properties formation in berry powder.The effects of inlet air temperature(40℃–80℃),vacuum degree(0.02–0.06 MPa)and additive amount on the physicochemical properties of berry powder were analyzed through solubility,anthocyanin retention and powder yield,based on moisture content and microstructure.The findings indicated that adding maltodextrin to berry enhanced the powder yield and instant solubility.Whey protein,as an additive,provided effective protection for the anthocyanins of berry powder,and the addition less than 10 g·100^(-1) g improved the powder yield.Inulin,as an additive,reduced moisture content of berry powder,which was conducive to the higher anthocyanin retention and solubility.Technique for order preference by similarity to ideal solution(TOPSIS)analysis was conducted to optimize the spray drying parameters for anthocyanin protection and solubility.The addition of 100%maltodextrin enhanced anthocyanin protection and solubility,while maintaining the desired moisture content and powder yield.This approach was used to evaluate the comprehensive quality of berry powder.This research can provide technical guidance for producing berry powder under low-temperature spray drying.展开更多
Constructing potential anodes for sodium-ion batteries(SIBs)with a wide temperature property has captured enormous interests in recent years.Fe1-xS,a zero-band gap material confirmed by density states calculation,is a...Constructing potential anodes for sodium-ion batteries(SIBs)with a wide temperature property has captured enormous interests in recent years.Fe1-xS,a zero-band gap material confirmed by density states calculation,is an ideal electrode for fast energy storage on account of its low cost and high theoretical capacity.Herein,Fe1-xS nanosheet wrapped by nitrogen-doped carbon(Fe1-xS@NC)is engineered through a post-sulfidation strategy using Fe-based metal-organic framework(Fe-MOF)as the precursor.The obtained Fe1-xS@NC agaric-like structure can well shorten the charge diffusion pathway,and significantly enhance the ionic/electronic conductivities and the reaction kinetics.As expected,the Fe1-xS@NC electrode,as a prospective SIB anode,delivers a desirable capacity up to 510.2 mA h g^-1 at a high rate of8000 mA g^-1.Additionally,even operated at low temperatures of 0 and-25°C,high reversible capacities of 387.1 and 223.4 mA h g^-1 can still be obtained at 2000 mA g^-1,respectively,indicating its huge potential use at harsh temperatures.More noticeably,the full battery made by the Fe1-xS@NC anode and Na3 V2(PO4)2 O2 F cathode achieves a remarkable rate capacity(186.8 mA h g^-1 at 2000 m A g^-1)and an impressive cycle performance(183.6 m A h g^-1 after 100 cycles at700 mA g^-1)between 0.3 and 3.8 V.Such excellent electrochemical performance is mainly contributed by its pseudocapacitive-dominated behavior,which brings fast electrode kinetics and robust structural stability to the whole electrode.展开更多
Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longe...Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.展开更多
Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is g...Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current efficiency.Thus,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical reactions.This review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical fields.The regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and mechanisms.Finally,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic electrodeposition.An in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.展开更多
Shenmu(SM)subbituminous coal without caking property was treated by low-temperature rapid pyrolysis(LTRP)to modify its caking and coking properties.The treated samples were characterized by Fourier transform infrared ...Shenmu(SM)subbituminous coal without caking property was treated by low-temperature rapid pyrolysis(LTRP)to modify its caking and coking properties.The treated samples were characterized by Fourier transform infrared spectrometry,vitrinite reflectance,and X-ray diffraction to determine the modification mechanism.Moreover,caking index(G)and coking indices(mechanical strength,coke reactivity,and coke strength after reaction)were employed to evaluate caking and coking properties,respectively.The results showed that SM coal was gradually upgraded with increasing processing temperature.Furthermore,the G values for the treated samples were significantly higher than that for SM coal,and G reached the maximum value at 450℃,implying the modification of caking property and the existence of an optimum temperature(450℃).Additionally,laboratory coking determinations showed that LTRP increased the mechanical strength of coke and coke strength after reaction and decreased coke reactivity when the treated coals were used in the coal blends instead of raw SM coal.Overall,LTRP treatment is effective to improve the caking and coking properties of SM coal.A mechanism was proposed for the modification.Suitable upgrading degree with suitable molecular masses and some releasable hydrogen-rich donor species present within the coal,which dominate the development of caking property,is important.展开更多
Catalytic properties of MnOx-FeOx complex oxide （hereafter denoted as Mn-Fe） catalysts modified with different loadings of chromium oxide were investigated by using the combination of physico-cbemical techniques, su...Catalytic properties of MnOx-FeOx complex oxide （hereafter denoted as Mn-Fe） catalysts modified with different loadings of chromium oxide were investigated by using the combination of physico-cbemical techniques, such as N2 physisorption, X-ray diffraction （XRD）, high-resolution transmission electron microscope （HRTEM）, in situ Fourier transform infrared spectroscopy （in situ FT-IR） and temperature-programmed reduction （TPR） and their catalytic activities were evaluated with the selective catalytic reduction （SCR） of NOx by NH3. It was found that with the addition of Cr, more NO could be removed in the low-temperature window （below 120 ℃）. Among the tested catalysts, Mn-Fe- Cr （2 ： 2 ： 1） catalyst exhibited the best catalytic performance at 80 ℃ with the NO conversion higher than 90%. The combination of the reaction and characterization results indicated that （1） the strong interaction among tertiary metal oxides existed in the catalysts when Cr was appropriately added, which made the active components better dispersed with less agglomeration and sintering and the largest BET specific surface area could be obtained; （2） Cr improved the low-temperature reducibility of the catalyst and promoted the formation of the active intermediate （-NH3＋）, which favored the low-temperature SCR reaction.展开更多
基金Supported by the Shenzhen Key Laboratory of Control Theory and Intelligent Systems (ZDSYS20220330161800001)the National Natural Science Foundation of China (62303207)the Guangdong Basic and Applied Basic Research Foundation (2024A1515010725)。
文摘This paper studies cooperative robust parallel operation of multiple actuators over an undirected communication graph.The plant is modeled as an uncertain linear system,and the actuators are linear and identical.Based on the internal model principle,a distributed dynamic output feedback control law is proposed to achieve both robust output regulation of the closed-loop system and plant input sharing among the actuators.A practical example of five motors cooperatively driving an uncertain shaft under an external load torque is presented to show the effectiveness of the proposed control law.
基金support of the“Pioneer”and“Leading Goose”Research&Development Program of Zhejiang(2024C01028)the State Key Laboratory of Industrial Control Technology,China(ICT2024C04)are gratefully acknowledged.
文摘Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operator training,etc.;thus,a hierarchical digital twin would be a comprehensive solution to that.In this study,a novel and general framework of the digital twin is proposed for operations in process industry.With the hierarchical structure,the framework can handle various tasks driven by different roles in process industry,including managers,engineers,and operators.To complete these tasks,the framework consists of three modules:OAS(Operation Analysis System),OMS(Operation Monitoring System),and OTS(Operator Training System).Each module focuses on one unique type of demand from the staff,as well as interactions among them enabling efficient data sharing.Based on the hierarchical framework,a digital twin system is applied for one complex industrial nitration process,which successfully enhances the operation efficiency and safety in several industrial scenarios with different demands.
基金the National Natural Science Foundation of China,grant number 52406074the China Postdoctoral Science Foundation under Grant Number 2025T180171+1 种基金the Natural Science Foundation of Guangdong Province(2025A1515011270)the China Southern Power Grid Technology Project(GDKJXM20231415/030100KC23120104).
文摘In order to explore the effects of CaO,lignite dust and sawdust on the drying characteristics ofmunicipal sludge at different concentrations,a three-factor three-level regression experiment was carried out based on the results of thermogravimetric experiment and single factor experiment.By fitting three common mathematical models,the Page model with the highest fitting degree was selected to determine the most suitable mathematical model to describe the municipal sludge drying process.In addition,the Box-Behnken design principle in the response surface method was used to analyze the interaction of three factors on the drying characteristics of municipal sludge.The results of the study show that below 100℃is the optimal drying temperature range for municipal sludge.The results of single factor experiments showed that the order of influence of the three factors on sludge drying time was CaO concentration>sawdust concentration>lignite dust concentration.In the single factor experiment,the optimal process parameterswere CaOconcentration 3%,lignite powder concentration 7%,and sawdust concentration 7%.In themulti-factor interaction analysis,the interaction between CaO and sawdust had the most significant effect on the reduction of drying time,and the order of influence was as follows:CaO interaction with sawdust>lignite dust interaction with sawdust>CaO interaction with lignite powder.Further analysis showed that the optimal process ratio was 3%CaO concentration and 3%sawdust concentration.
基金the financial support from the Key Project of Shaanxi Provincial Natural Science Foundation-Key Project of Laboratory(2025SYS-SYSZD-117)the Natural Science Basic Research Program of Shaanxi(2025JCYBQN-125)+8 种基金Young Talent Fund of Xi'an Association for Science and Technology(0959202513002)the Key Industrial Chain Technology Research Program of Xi'an(24ZDCYJSGG0048)the Key Research and Development Program of Xianyang(L2023-ZDYF-SF-077)Postdoctoral Fellowship Program of CPSF(GZC20241442)Shaanxi Postdoctoral Science Foundation(2024BSHSDZZ070)Research Funds for the Interdisciplinary Projects,CHU(300104240913)the Fundamental Research Funds for the Central Universities,CHU(300102385739,300102384201,300102384103)the Scientific Innovation Practice Project of Postgraduate of Chang'an University(300103725063)the financial support from the Australian Research Council。
文摘Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temperature(LT)operation.Therefore,a more comprehensive and systematic understanding of LIB behavior at LT is urgently required.This review article comprehensively reviews recent advancements in electrolyte engineering strategies aimed at improving the low-temperature operational capabilities of LIBs.The study methodically examines critical performance-limiting mechanisms through fundamental analysis of four primary challenges:insufficient ionic conductivity under cryogenic conditions,kinetically hindered charge transfer processes,Li+transport limitations across the solidelectrolyte interphase(SEI),and uncontrolled lithium dendrite growth.The work elaborates on innovative optimization approaches encompassing lithium salt molecular design with tailored dissociation characteristics,solvent matrix optimization through dielectric constant and viscosity regulation,interfacial engineering additives for constructing low-impedance SEI layers,and gel-polymer composite electrolyte systems.Notably,particular emphasis is placed on emerging machine learning-guided electrolyte formulation strategies that enable high-throughput virtual screening of constituent combinations and prediction of structure-property relationships.These artificial intelligence-assisted rational design frameworks demonstrate significant potential for accelerating the development of next-generation LT electrolytes by establishing quantitative composition-performance correlations through advanced data-driven methodologies.
基金financially supported by the National Natural Science Foundation of China(No.22309067)the Open Project Program of the State Key Laboratory of Materials-Oriented Chemical Engineering,China(No.KL21-05)the Marine Equipment and Technology Institute,Jiangsu University of Science and Technology,China(No.XTCX202404)。
文摘This study focused on improving the cathode performance of Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.15)O_(3-δ)(BSCN)-based perovskite materials through molybdenum(Mo)doping.Pure BSCN and Mo-modified-BSCN—Ea_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.1)Mo_(0.05)O_(3-δ)(B S CNM_(0.05)),Ba_(0.6)Sr_(0.4)Co_(0.85)Nb_(0.05)Mo_(0.1)O_(3-δ)(BSCNM_(0.1)),and Ba_(0.6)Sr_(0.4)Co_(0.85)Mo_(0.15)O_(3-δ)(BSCM)—with Mo doping contents of 5mol%,10mol%,and15mol%,respectively,were successfully prepared using the sol-gel method.The effects of Mo doping on the crystal structure,conductivity,thermal expansion coefficient,oxygen reduction reaction(ORR)activity,and electrochemical performance were systematically evaluated using X-ray diffraction analysis,thermally induced characterization,electrochemical impedance spectroscopy,and single-cell performance tests.The results revealed that Mo doping could improve the conductivity of the materials,suppress their thermal expansion effects,and significantly improve the electrochemical performance.Surface chemical state analysis using X-ray photoelectron spectroscopy revealed that 5mol%Mo doping could facilitate a high adsorbed oxygen concentration leading to enhanced ORR activity in the materials.Density functional theory calculations confirmed that Mo doping promoted the ORR activity in the materials.At an operating temperature of 600℃,the BSCNM_(0.05)cathode material exhibited significantly enhanced electrochemical impedance characteristics,with a reduced area specific resistance of 0.048Ω·cm~2,which was lower than that of the undoped BSCN matrix material by 32.39%.At the same operating temperature,an anode-supported single cell using a BSCNM_(0.05)cathode achieved a peak power density of 1477 mW·cm^(-2),which was 30.71%,56.30%,and 171.50%higher than those of BSCN,BSCNM_(0.1),and B SCM,respectively.The improved ORR activity and electrochemical performance of BSCNM_(0.05)indicate that it can be used as a cathode material in low-temperature solid oxide fuel cells.
文摘On December 18,2025, Hainan Free Trade Port (Hainan FTP) officially began islandwide special customs operations.Although only two months have passed since this landmark step, the shift is already visible everywhere—from the bustling flow of international passengers at Haikou Meilan International Airport to the steady stream of cargo vessels calling at Yangpu Port, and even in the sustained attention investors are paying to “Hainan-related” stocks.Together, these signals point to one clear conclusion:China’s largest special economic zone has entered a new phase of development.
基金Project supported by the National Natural Science Foundation of China(Grant No.61573266)the Natural Science Basic Research Program of Shaanxi(Grant No.2021JM-133)the Fundamental Research Funds for the Central Universities and the Innovation Fund of Xidian University(Grant No.YJSJ25009)。
文摘Efficient implementation of fundamental matrix operations on quantum computers,such as matrix products and Hadamard operations,holds significant potential for accelerating machine learning algorithms.A critical prerequisite for quantum implementations is the effective encoding of classical data into quantum states.We propose two quantum computing frameworks for preparing the distinct encoded states corresponding to matrix operations,including the matrix product,matrix sum,matrix Hadamard product and division.Quantum algorithms based on the digital encoding computing framework are capable of implementing the matrix Hadamard operation with a time complexity of O(poly log(mn/ε))and the matrix product with a time complexity of O(poly log(mnl/ε)),achieving an exponential speedup in contrast to the classical methods of O(mn)and O(mnl).Quantum algorithms based on the analog-encoding framework are capable of implementing the matrix Hadamard operation with a time complexity of O(k_(1)√mn·poly log(mn/ε))and the matrix product with a time complexity of O(k_(2)√1·poly log(mnl/ε)),where k_(1)and k_(2)are coefficients correlated with the elements of the matrix,achieving a square speedup in contrast to the classical counterparts.As applications,we construct an oracle that can access the trace of a matrix within logarithmic time,and propose several algorithms to respectively estimate the trace of a matrix,the trace of the product of two matrices,and the trace inner product of two matrices within logarithmic time.
基金Supported by the Science and Technology Program of Guizhou Province(Grant No.QKHJC QN[2025]362)the National Natural Science Foundation of China(Grant No.12361005).
文摘Loday introduced di-associative algebras and tri-associative algebras motivated by periodicity phenomena in algebraic K-theory.The purpose of this paper is to study the splittings of operations on di-associative algebras and tri-associative algebras.We introduce the notion of a quad-dendriform algebra,which is a splitting of a di-associative algebra.We show that a relative averaging operator on dendriform algebras gives rise to a quad-dendriform algebra.Furthermore,we introduce the notion of six-dendriform algebras,which are splittings of the tri-associative algebras,and demonstrate that homomorphic relative averaging operators induce six-dendriform algebras.
基金Jiangsu Provincial College Student Innovation and Entrepreneurship Program(Grant No.SJCX25_2184)—“Multi-energy Complementary Optimization and Vehicle-Storage Bidirectional Interaction Technology Driven by Novel 5E Framework”(Principal Investigator:Yuan-Yuan ShiFunding Agency:Jiangsu Provincial Education Department)+3 种基金Huaian Natural Science Research Project(Grant No.HAB2024046)—“Optimal Control of Flexible Cold-Heat-Power Integrated System with Source-Grid-Load-Storage Coordination”(Principal Investigator:Jie JiFunding Agency:Huaian Science and Technology Bureau)Huaiyin Institute of TechnologyUniversity-funded Project(GrantNo.HGYK202511)—“Data-driven CooperativeOptimization Dispatch for Source-Grid-Load Systems”(Principal Investigator:Chu-Tong ZhangFunding Agency:Huaiyin Institute of Technology).
文摘In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm co-design framework:the T-type three-level bidirectional converter(100 kHz switching frequency)based on silicon carbide(SiC)MOSFET is deeply integrated with fuzzy model predictive control(Fuzzy-MPC).At the hardware level,the switching trajectory and resonance suppression circuit(attenuation resonance peak 18 dB)are optimized,and the total loss is reduced by 23%compared with the traditional silicon-based IGBT.At the algorithm level,the adaptive parameter update mechanism and multi-objective rolling optimization are adopted,and the 5 ms level dynamic power allocation is realized by relying on edge computing.Experiments on 800 V DC microgrid(including 600 kW photovoltaic and 150 A·h energy storage)built based on MATLAB/Simulink hardware-in-the-loop(HIL)platform show that the system shortens the battery charging time from 42 to 28 min(the charging speed is increased by 33%).Through the 78%valley power utilization rate,the power purchase cost of high-priced power grids was significantly reduced,and the levelized electricity price decreased by 10.3%;Under the irradiation fluctuation,the renewable energy consumption rate increases by 10.1%,and the DC bus voltage fluctuation is stable within±10 V when the load step is±30%.The co-design provides an economically feasible and dynamically robust solution for the efficient integration of PV-ESG-EV in the smart grid.
基金supported by the National Key Research and Development Program of China(No.2022YFB4300902).
文摘As joint operations have become a key trend in modern military development,unmanned aerial vehicles(UAVs)play an increasingly important role in enhancing the intelligence and responsiveness of combat systems.However,the heterogeneity of aircraft,partial observability,and dynamic uncertainty in operational airspace pose significant challenges to autonomous collision avoidance using traditional methods.To address these issues,this paper proposes an adaptive collision avoidance approach for UAVs based on deep reinforcement learning.First,a unified uncertainty model incorporating dynamic wind fields is constructed to capture the complexity of joint operational environments.Then,to effectively handle the heterogeneity between manned and unmanned aircraft and the limitations of dynamic observations,a sector-based partial observation mechanism is designed.A Dynamic Threat Prioritization Assessment algorithm is also proposed to evaluate potential collision threats from multiple dimensions,including time to closest approach,minimum separation distance,and aircraft type.Furthermore,a Hierarchical Prioritized Experience Replay(HPER)mechanism is introduced,which classifies experience samples into high,medium,and low priority levels to preferentially sample critical experiences,thereby improving learning efficiency and accelerating policy convergence.Simulation results show that the proposed HPER-D3QN algorithm outperforms existing methods in terms of learning speed,environmental adaptability,and robustness,significantly enhancing collision avoidance performance and convergence rate.Finally,transfer experiments on a high-fidelity battlefield airspace simulation platform validate the proposed method's deployment potential and practical applicability in complex,real-world joint operational scenarios.
文摘For ordinary tourists, simpler entry and exit procedures and a broader range of duty-free goods in Hainan create a better travel and shopping experience.For China’s earnest endeavor to deepen reform and opening-up, implementation of the special customs operations policy in Hainan represents a significant step forward. For businesses in Malaysia and other ASEAN member states, especially export-oriented small and medium-sized enterprises (SMEs), Hainan serves as a“transit hub” for accessing the Chinese market and even other Asian markets.
文摘With the gradual implementation of a series of institutional arrangements, H ainan is becoming a new hot spot for global investment and an ideal destination for starting businesses and developing industry. While attracting foreign investment projects, it is also creating more favorable conditions for local enterprises to expand into international markets.
文摘At 11:00 p.m. on January 13, 2026, floodlights illuminated the launch pad at the Hainan Commercial Space Launch Site in Wenchang,south China’s Hainan Province. A Long March-8A (CZ-8A) carrier rocket lifted off with a steady roar, its exhaust lighting up the night sky as it delivered a satellite into its designated orbit.The development of China’s first commercial space launch site has been striking. Since its inaugural launch in2024, it has completed 11 missions in less than 14 months—each a success.
文摘THE Hainan Free Trade Port(FTP)officially launched island-wide special customs operations on December 18,2025.One month in,a reporting team from China International Communications Group(CICG)conducted an exclusive interview with Feng Fei,secretary of the Hainan Provincial Committee of the Communist Party of China(CPC)and chairman of the Standing Committee of the Hainan Provincial People’s Congress.
基金Supported by the National Natural Science Foundation of China(32072352)。
文摘The low-temperature spray drying technology was developed to process instant berry powder with high efficiency and higher anthocyanin retention.The maltodextrin,whey protein and inulin were selected as additives for instant properties formation in berry powder.The effects of inlet air temperature(40℃–80℃),vacuum degree(0.02–0.06 MPa)and additive amount on the physicochemical properties of berry powder were analyzed through solubility,anthocyanin retention and powder yield,based on moisture content and microstructure.The findings indicated that adding maltodextrin to berry enhanced the powder yield and instant solubility.Whey protein,as an additive,provided effective protection for the anthocyanins of berry powder,and the addition less than 10 g·100^(-1) g improved the powder yield.Inulin,as an additive,reduced moisture content of berry powder,which was conducive to the higher anthocyanin retention and solubility.Technique for order preference by similarity to ideal solution(TOPSIS)analysis was conducted to optimize the spray drying parameters for anthocyanin protection and solubility.The addition of 100%maltodextrin enhanced anthocyanin protection and solubility,while maintaining the desired moisture content and powder yield.This approach was used to evaluate the comprehensive quality of berry powder.This research can provide technical guidance for producing berry powder under low-temperature spray drying.
基金financially supported by the National Natural Science Foundation of China (21873018, 21573036 and 21274017)the open project of Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis (130028655)
文摘Constructing potential anodes for sodium-ion batteries(SIBs)with a wide temperature property has captured enormous interests in recent years.Fe1-xS,a zero-band gap material confirmed by density states calculation,is an ideal electrode for fast energy storage on account of its low cost and high theoretical capacity.Herein,Fe1-xS nanosheet wrapped by nitrogen-doped carbon(Fe1-xS@NC)is engineered through a post-sulfidation strategy using Fe-based metal-organic framework(Fe-MOF)as the precursor.The obtained Fe1-xS@NC agaric-like structure can well shorten the charge diffusion pathway,and significantly enhance the ionic/electronic conductivities and the reaction kinetics.As expected,the Fe1-xS@NC electrode,as a prospective SIB anode,delivers a desirable capacity up to 510.2 mA h g^-1 at a high rate of8000 mA g^-1.Additionally,even operated at low temperatures of 0 and-25°C,high reversible capacities of 387.1 and 223.4 mA h g^-1 can still be obtained at 2000 mA g^-1,respectively,indicating its huge potential use at harsh temperatures.More noticeably,the full battery made by the Fe1-xS@NC anode and Na3 V2(PO4)2 O2 F cathode achieves a remarkable rate capacity(186.8 mA h g^-1 at 2000 m A g^-1)and an impressive cycle performance(183.6 m A h g^-1 after 100 cycles at700 mA g^-1)between 0.3 and 3.8 V.Such excellent electrochemical performance is mainly contributed by its pseudocapacitive-dominated behavior,which brings fast electrode kinetics and robust structural stability to the whole electrode.
基金supported by a Horizontal Project on the Development of a Hybrid Energy Storage Simulation Model for Wind Power Based on an RT-LAB Simulation System(PH2023000190)the Inner Mongolia Natural Science Foundation Project and the Optimization of Exergy Efficiency of a Hybrid Energy Storage System with Crossover Control for Wind Power(2023JQ04).
文摘Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.
基金supported by Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2023SP243)the National Key Research and Development Program of China(No.2022YFC2906100)the National Natural Science Foundation of China(No.92475202)are acknowledged.
文摘Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current efficiency.Thus,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical reactions.This review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical fields.The regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and mechanisms.Finally,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic electrodeposition.An in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.
基金The authors are grateful to the National Natural Science Foundation of China(No.21776002)Natural Science Foundation of Anhui Provincial Education Department(Nos.KJ2016A097 and KJ2017A056)+1 种基金Innovation Project of Overseas People of Anhui Province,Student Research Training Program of Anhui Province(201810360190)Youth Natural Science Foundation of Anhui University of Technology(No.QZ201806)for financial support.
文摘Shenmu(SM)subbituminous coal without caking property was treated by low-temperature rapid pyrolysis(LTRP)to modify its caking and coking properties.The treated samples were characterized by Fourier transform infrared spectrometry,vitrinite reflectance,and X-ray diffraction to determine the modification mechanism.Moreover,caking index(G)and coking indices(mechanical strength,coke reactivity,and coke strength after reaction)were employed to evaluate caking and coking properties,respectively.The results showed that SM coal was gradually upgraded with increasing processing temperature.Furthermore,the G values for the treated samples were significantly higher than that for SM coal,and G reached the maximum value at 450℃,implying the modification of caking property and the existence of an optimum temperature(450℃).Additionally,laboratory coking determinations showed that LTRP increased the mechanical strength of coke and coke strength after reaction and decreased coke reactivity when the treated coals were used in the coal blends instead of raw SM coal.Overall,LTRP treatment is effective to improve the caking and coking properties of SM coal.A mechanism was proposed for the modification.Suitable upgrading degree with suitable molecular masses and some releasable hydrogen-rich donor species present within the coal,which dominate the development of caking property,is important.
基金supported by Jiangsu Natural Science Foundation (No. BK2012347)the National High Technology and Development Program of China (863 Programs, No.2007AA061802)
文摘Catalytic properties of MnOx-FeOx complex oxide （hereafter denoted as Mn-Fe） catalysts modified with different loadings of chromium oxide were investigated by using the combination of physico-cbemical techniques, such as N2 physisorption, X-ray diffraction （XRD）, high-resolution transmission electron microscope （HRTEM）, in situ Fourier transform infrared spectroscopy （in situ FT-IR） and temperature-programmed reduction （TPR） and their catalytic activities were evaluated with the selective catalytic reduction （SCR） of NOx by NH3. It was found that with the addition of Cr, more NO could be removed in the low-temperature window （below 120 ℃）. Among the tested catalysts, Mn-Fe- Cr （2 ： 2 ： 1） catalyst exhibited the best catalytic performance at 80 ℃ with the NO conversion higher than 90%. The combination of the reaction and characterization results indicated that （1） the strong interaction among tertiary metal oxides existed in the catalysts when Cr was appropriately added, which made the active components better dispersed with less agglomeration and sintering and the largest BET specific surface area could be obtained; （2） Cr improved the low-temperature reducibility of the catalyst and promoted the formation of the active intermediate （-NH3＋）, which favored the low-temperature SCR reaction.
