The phenomena of thermal runaway and accidental deformation due to external stresses in lithium batteries or film capacitors consti-tute their primary failure mechanisms.Therefore,monitoring and early warning of overh...The phenomena of thermal runaway and accidental deformation due to external stresses in lithium batteries or film capacitors consti-tute their primary failure mechanisms.Therefore,monitoring and early warning of overheating or localized strain are of great value for the safe use of lithium batteries or film capacitors;however,this function usually requires a system of multiple complex sensors.The realization of the above multiple hazards using a single sensor for monitoring and alarm functions has not been reported.Here,we exploit the thermally induced conductivity and modulus change during solid-liquid conversion of low melting point polyalloys to modulate the electronic relaxation polariza-tion and interfacial polarization in the composites for dielectric switching,and the reduction of alloy particle spacing during bending/compres-sive strain can be used to generate switchable tunneling effects for insulator-conductor transition.By synergizing dielectric switching and insula-tor-conductor transition,the final flexible thermoplastic polyurethane elastomer/low-melting-point polyalloy composite film achieves the func-tional integration of multi-level overheating warning and small deformation monitoring.展开更多
Battery safety is influenced by various factors,with thermal runaway being one of the most significant concerns.While most studies have concentrated on developing one-time,self-activating mechanism for thermal protect...Battery safety is influenced by various factors,with thermal runaway being one of the most significant concerns.While most studies have concentrated on developing one-time,self-activating mechanism for thermal protection,such as temperature-responsive electrodes,and thermal-shutdown separators,these methods only provide irreversible protection.Recently,reversible temperature-sensitive electrolytes have emerged as promising alternatives,offering both thermo-reversibility and self-protective properties.However,further research is crucial to fully understand these thermal-shutdown electrolytes.In this study,we propose lower critical solution temperature(LCST)phase behavior poly(benzyl methacrylate)/imidazolium-based ionic liquid mixtures to prepare temperature-sensitive electrolytes that provide reversible thermal shutdown protection of batteries.This electrolyte features an appropriate protection temperature(~105℃)and responds quickly within a 1 min at 105℃,causing cells to hardly discharge as the voltage suddenly drops to 3.38 V,and providing efficient thermal shutdown protection within 30 min.Upon cooling back to room temperature,the battery regains its original performance.Additionally,the electrolyte exhibits excellent cycling stability with the capacity retention of the battery is 91.6%after 500 cycles.This work provides a viable solution for preventing batteries from thermal runaway triggered by overheating.展开更多
Investigations into the long-term creep behavior of Beishan granite in uniaxial compression were conducted.Four levels of axial stress(60,70,87,and 95 MPa)were applied to rock specimens.Contrasting with earlier resear...Investigations into the long-term creep behavior of Beishan granite in uniaxial compression were conducted.Four levels of axial stress(60,70,87,and 95 MPa)were applied to rock specimens.Contrasting with earlier research,the long-term creep data in this work present a substantial advancement in the time dimension.Except for the sample subjected to 60 MPa axial loading,which did not fail after a loading duration of 1650 d,the specimens under the other three stresses all failed after sustained constant loading durations of 1204,1023,and 839 d,respectively.A lower envelope of driving stress-ratio for crystalline rocks was obtained,tending towards approximately 0.45 over an infinite time scale.According to the experimental results,as axial stress increases,both the axial strain accumulated in the transient creep process and the strain rate associated with steady-state creep deformation increase exponentially;however,the share of steady-state creep strain remains nearly constant at about82.53%.A novel damage-based creep model was put forward.It provides an enhanced depiction of the comprehensive creep process in rocks,notably improving the accuracy in forecasting the accelerated creep phase,which significantly impacts the long-term stability of engineering structures.展开更多
While oceanic and coastal acidification has gained increased attention,long-term pH trends and their drivers in large freshwater systems remain poorly understood.The Laurentian Great Lakes are the world’s largest fre...While oceanic and coastal acidification has gained increased attention,long-term pH trends and their drivers in large freshwater systems remain poorly understood.The Laurentian Great Lakes are the world’s largest freshwater system,and in many ways resemble marine ecosystems.However,unlike the open ocean and coastal waters where pH has declined due to rising atmospheric CO_(2),no significant pH trends have been observed in the Laurentian Great Lakes,despite significant ecosystem changes driven partly by the invasion of dreissenid mussels.This study examined 41 years of field observations from Lake Michigan to investigate the long-term carbonate chemistry dynamics.Observational results revealed substantial declines in both total alkalinity(TA)and dissolved inorganic carbon(DIC)over the four decades.Mussel shell calcification emerged as the primary mechanism behind these declines,accounting for 97%and 47%of the observed changes in TA and DIC,respectively,lowering water column pH by 0.24 units.Elevated carbon accumulation in soft mussel tissues,coupled with long-term changes in the air-water pCO_(2)gradient during summer,significantly contributed to long-term DIC variations,explaining 18%and 28%of the lake-wide DIC loss.These two mechanisms also resulted in an overall pH increase of 0.09 and 0.12 units,largely offsetting the calcification-driven pH decrease.These findings bridge a gap in acidification research for large freshwater systems and provide valuable insights for comprehensive lake-wide management strategies.展开更多
Objective:To investigate the long-term prognosis and postoperative cosmetic outcomes of breast-conserving surgery combined with sentinel lymph node biopsy in patients with early-stage breast cancer,providing a referen...Objective:To investigate the long-term prognosis and postoperative cosmetic outcomes of breast-conserving surgery combined with sentinel lymph node biopsy in patients with early-stage breast cancer,providing a reference for the selection of clinical treatment plans.Methods:A retrospective analysis was conducted on the clinical data of 68 patients with early-stage breast cancer admitted from January 2022 to December 2025.Based on the surgical approach,patients were divided into an observation group(breast-conserving surgery+sentinel lymph node biopsy)and a control group(other surgical methods such as modified radical mastectomy/total mastectomy).Clinical and pathological characteristics,incidence of postoperative complications,follow-up prognosis,and satisfaction with cosmetic outcomes were compared between the two groups.Results:Among the 68 patients,41 were in the observation group and 27 in the control group.The average age of patients in the observation group was(54.32±8.15)years,while that in the control group was(62.45±9.76)years.The average tumor size in the observation group was(1.86±0.72)cm,compared to(3.21±1.45)cm in the control group.The incidence of postoperative complications in the observation group was 9.76%,significantly lower than that in the control group at 33.33%(P<0.05).The 6-month disease-free survival rate was 95.12%in the observation group and 88.89%in the control group,with no statistically significant difference between the two groups(P>0.05).The excellent and good rate of cosmetic outcomes in the observation group was 87.80%,significantly higher than that in the control group at 29.63%(P<0.05).Conclusion:Breast-conserving surgery combined with sentinel lymph node biopsy for early-stage breast cancer can achieve long-term prognostic outcomes comparable to those of traditional radical surgery,with the advantages of fewer postoperative complications and superior cosmetic results.This approach is worthy of clinical promotion and application,particularly for early-stage breast cancer patients who have a demand for preserving breast morphology.展开更多
Taking the rural low-income population of Zhejiang Province as its subject, this paper examines how to build a sustainable income-growth mechanism and identify feasible implementation paths within the context of the c...Taking the rural low-income population of Zhejiang Province as its subject, this paper examines how to build a sustainable income-growth mechanism and identify feasible implementation paths within the context of the common prosperity strategy. The research identifies key obstacles to income expansion, including an undiversified industrial structure, insufficient human capital, and a lack of robust social protection. These call for systemic solutions featuring institutional innovation, resource consolidation, and capability enhancement. Building on Zhejiang's experience as a common prosperity demonstration zone, the article constructs an integrated framework centered on four pillars: industrial empowerment, education upgrading, social security reinforcement, and digital coordination. It further offers concrete policy proposals involving the cultivation of localized industries, vocational skill training, enhanced safety nets, and the adoption of digital tools. The study thus offers both theoretical insights and practical paradigms for tackling the challenge of raising incomes in low-income rural areas.展开更多
AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longit...AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longitudinal observational study,detailed medical histories of APAC patients and comprehensive ophthalmic examinations at final followup were collected.Logistic regression analysis was performed to identify predictors of blindness.Univariate and multivariate linear regression analyses were conducted to determine risk factors associated with visual outcomes.RESULTS:This study included 39 affected eyes of 31 subjects(26 females)with an average age of 74.1±8.0y.At 6.7±4.2y after APAC attack,2(5.7%)eyes had bestcorrected visual acuity(VA)worse than 3/60.Advanced glaucomatous visual field loss was observed in 15(39.5%)affected eyes and 5(25.0%)fellow eyes.Nine affected eyes(23.7%)had GON,and 11(28.9%)were blind.Six(15.4%)affected eyes and 2(9.1%)fellow eyes had suspicious progression.A significantly higher blindness rate in factory workers compared to office workers.Logistic regression identified that worse VA at attack(OR 10.568,95%CI 1.288-86.695;P=0.028)and worse early postoperative VA(OR 13.214,95%CI 1.157-150.881;P=0.038)were risk factors for blindness.Multivariate regression showed that longer duration of elevated intraocular pressure(P=0.004)and worse early postoperative VA(P=0.009)were associated with worse visual outcomes.CONCLUSION:Despite LE surgery,some APAC patients experience continued visual function deterioration.Lifelong monitoring is necessary.Target pressure and progression rates should be re-evaluated during follow-up.展开更多
Subarachnoid hemorrhage is a subtype of stroke that causes severe neurological damage and is associated with poor long-term prognosis.Cognitive impairment is a major manifestation of long-term neurological dysfunction...Subarachnoid hemorrhage is a subtype of stroke that causes severe neurological damage and is associated with poor long-term prognosis.Cognitive impairment is a major manifestation of long-term neurological dysfunction in patients with subarachnoid hemorrhage.However,there is notable absence of biological markers to predict long-term prognosis in this patient population.Given the aging-like neurocognitive phenomena associated with subarachnoid hemorrhage,this study postulates that telomere length,a recognized biomarker for aging,could be used as a prognostic indicator for subarachnoid hemorrhage.A left internal carotid artery intravascular puncture mouse model was used to simulate subarachnoid hemorrhage.Comprehensive neurological test scores were obtained through neurobehavioral assessments conducted at one-month intervals.Concurrently,the relative telomere length was analyzed by quantitative polymerase chain reaction,which was performed using DNA extracted from ear notch and brain tissue after each assessment.Furthermore,proteomic analysis was employed to investigate differential protein expression in hippocampal tissue.Subarachnoid hemorrhage mice exhibited persistent neurocognitive impairment over a prolonged period of time.There was a significant positive correlation between telomere length and neurological test scores,confirming the usefulness of telomere length as a prognostic indicator in subarachnoid hemorrhage.Hippocampal tissue from subarachnoid hemorrhage mice showed reduced expression of acetyl-coenzyme A synthetase-2 and abnormalities in the expression of proteins related to ribosomes,energy metabolism,and cellular signal transduction.This study confirmed telomere shortening in the brain and metabolic disturbances in the hippocampi of subarachnoid hemorrhage mice.Thus,telomere length is a predictive marker for long-term impairment of cognitive function in mice following experimental subarachnoid hemorrhage.展开更多
Long-term manure application has the potential to alleviate soil acidification, and increase carbon sequestration and nutrient availability, thus improving cropland fertility. However, the mechanisms behind greenhouse...Long-term manure application has the potential to alleviate soil acidification, and increase carbon sequestration and nutrient availability, thus improving cropland fertility. However, the mechanisms behind greenhouse gas N_(2)O emissions from acidic soil mediated by long-term manure application remain poorly understood. Herein, we investigated N_(2)O emission and its linkage with gross N mineralization and nitrification rates, as well as nitrifying and denitrifying microbes in an acidic upland soil subjected to 36-year fertilization treatments, including an unfertilized control(CK), inorganic fertilizer(F), 2× rate of inorganic fertilizer(2F), manure(M), and the combination of inorganic fertilizer and manure(FM) treatments. Compared to the CK treatment(1.34 μg N kg^(-1) d^(-1)), fertilization strongly increased N_(2)O emissions by 34-fold on average, with more pronounced increases in the manure-amendment(10.6-169 μg N kg^(-1) d^(-1)) than those in the inorganic fertilizer treatments(3.26-5.51 μg N kg^(-1) d^(-1)). The manure amendment-stimulated N_(2)O emissions were highly associated with increased soil pH, mean weight diameter of soil aggregates, substrate availability(e.g., particulate organic carbon, NO_(3)^(-)and available phosphorus), gross N mineralization rates, denitrifier abundances and the(nirK+nirS)/nosZ ratio. These findings suggest that the increased N_(2)O emissions primarily resulted from alleviated acidification, increased substrate availability and improved soil structure, thus enhancing microbial N mineralization and favoring N_(2)O^(-)producing denitrifiers over N_(2)O consumers. Moreover, ammonia-oxidizing bacteria(AOB) rather than ammonia-oxidizing archaea(AOA) positively correlated with soil NO_(3)^(-)concentration and N_(2)O emissions, indicating that nitrification indirectly contributed to N_(2)O production by supplying NO_(3)^(-)for denitrification. Collectively, manure amendment potentially stimulates N_(2)O emissions, primarily resulting from alleviated soil acidification and increased substrate availability, thus enhancing N mineralization and denitrifier-mediated N_(2)O production. Our findings suggest that consideration should be given to the greenhouse gas budgets of agricultural ecosystems when applying manure for managing the pH and fertility of acidic soils.展开更多
In Alzheimer’s disease,perturbations of glutamate neurotransmission lead to synaptic dysfunction and synapse loss.Several studies have used glutamate transport inhibitors to demonstrate that soluble oligomers of amyl...In Alzheimer’s disease,perturbations of glutamate neurotransmission lead to synaptic dysfunction and synapse loss.Several studies have used glutamate transport inhibitors to demonstrate that soluble oligomers of amyloid-βinduce synaptic dysfunction by interrupting glutamate uptake mediated by glutamate transporter 1,the major glutamate transporter in the brain.The cellular targets of the synaptic effects of soluble amyloid-βoligomers,including the nature of any interaction with glutamate transporter 1,remain ill-defined.We have generated a conditional glutamate transporter 1 knockout mouse to investigate cell-type specific functions of glutamate transporter 1.Field excitatory postsynaptic potentials were examined in the CA1 region of mouse hippocampal slices.We confirmed that hippocampal long-term potentiation impairment is induced by both soluble amyloid-β oligomers and glutamate uptake inhibitors.Amyloid-βoligomers,including those isolated directly from the cortex of patients with Alzheimer’s disease,failed to inhibit hippocampal long-term potentiation in neuronal glutamate transporter 1 but not astrocytic glutamate transporter 1 knockout mice.The masking or occlusion of the effect of soluble amyloid-β oligomers by knockout of glutamate transporter 1 in neurons suggests that the metabolic or signaling consequences of knockout of glutamate transporter 1 in neurons and amyloid-βoligomer inhibition of synaptic plasticity show epistasis and thus share a similar molecular pathway.To extend these observations,we tested the effects of other types of manipulation of glutamate homeostasis on synaptic plasticity and the pathophysiology of soluble amyloid-β oligomers.Ceftriaxone,which upregulates glutamate transporter 1 levels,among other effects,prevented the impairment of long-term potentiation by soluble amyloid-β oligomers.Collectively,our findings suggest that the effects of amyloid-βon synaptic function are highly dependent on glutamate reuptake homeostasis and that the disruption of synaptic function by soluble amyloid-β oligomers is mediated by pathways linked to neuronal,not astrocytic,glutamate transporter 1.The findings of this study highlight the translational potential of targeting neuronal glutamate transporter 1 to counteract amyloid-β-induced synaptic dysfunction in Alzheimer’s disease.By showing that glutamate transporter 1 upregulation(e.g.,via ceftriaxone)can prevent amyloid-β-related impairments,this research supports developing therapies aimed at modulating glutamate homeostasis to preserve synaptic function and combat cognitive decline in patients with Alzheimer’s disease.展开更多
Long-term traffic flow prediction is a crucial component of intelligent transportation systems within intelligent networks,requiring predictive models that balance accuracy with low-latency and lightweight computation...Long-term traffic flow prediction is a crucial component of intelligent transportation systems within intelligent networks,requiring predictive models that balance accuracy with low-latency and lightweight computation to optimize trafficmanagement and enhance urban mobility and sustainability.However,traditional predictivemodels struggle to capture long-term temporal dependencies and are computationally intensive,limiting their practicality in real-time.Moreover,many approaches overlook the periodic characteristics inherent in traffic data,further impacting performance.To address these challenges,we introduce ST-MambaGCN,a State-Space-Based Spatio-Temporal Graph Convolution Network.Unlike conventionalmodels,ST-MambaGCN replaces the temporal attention layer withMamba,a state-space model that efficiently captures long-term dependencies with near-linear computational complexity.The model combines Chebyshev polynomial-based graph convolutional networks(GCN)to explore spatial correlations.Additionally,we incorporate a multi-temporal feature capture mechanism,where the final integrated features are generated through the Hadamard product based on learnable parameters.This mechanism explicitly models shortterm,daily,and weekly traffic patterns to enhance the network’s awareness of traffic periodicity.Extensive experiments on the PeMS04 and PeMS08 datasets demonstrate that ST-MambaGCN significantly outperforms existing benchmarks,offering substantial improvements in both prediction accuracy and computational efficiency for long-term traffic flow prediction.展开更多
Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrate...Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.展开更多
The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx（x=10, 12） glass-forming alloyswerestudied by differential thermal analysis combining with ...The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx（x=10, 12） glass-forming alloyswerestudied by differential thermal analysis combining with solidification structure analysis. The results indicate that the undercooling degree of Nd9Fe85-xTi4C2Bx（x=10, 12） alloys significantly increaseswith the rise of melt overheating degree, and two overheating degree thresholds corresponding to the drastic increase of the mean undercooling degree are found for each of the alloys. The existence of two turning points of the mean undercooling degreescan be linked to the structure transitions inside the overheated melts, which result in the evident increase of volume fraction of amorphous phasein the solidified structures.展开更多
The microstructure and overheating characteristics of the direct chill semicontinuous casting ingot of 7B04 high strength aluminum alloy,and those after industrial homogenization treatment and multi-stage homogenizati...The microstructure and overheating characteristics of the direct chill semicontinuous casting ingot of 7B04 high strength aluminum alloy,and those after industrial homogenization treatment and multi-stage homogenization treatments,were studied by differential scanning calorimetry(DSC),optical microscopy(OM)and scanning electron microscopy with energy dispersive X-ray spectroscopy(SEM-EDX).The results show that the microstructure of direct chill semicontinuous casting ingot of the 7B04 alloy contains a large number of constituents in the form of dendritic networks that consist of nonequilibrium eutectic and Fe-containing phases.The nonequilibrium eutectic contains Al,Zn,Mg and Cu,and the Fe-containing phases include two kinds of phases,one containing Al,Fe,Mn and Cu,and the other having Al,Fe,Mn,Cr,Si and Cu.The melting point of the nonequilibrium eutectic is 478℃for the casting ingot of the 7B04 alloy which is usually considered as its overheating temperature.During industrial homogenization treatment processing at 470℃,the nonequilibrium eutectic dissolves into the matrix of this alloy partly,and the remainder transforms into Al2CuMg phase that cannot be dissolved into the matrix at that temperature completely.The melting point of the Al2CuMg phase which can dissolve into the matrix completely by slow heating is about 490℃.The overheating temperature of this high strength aluminum alloy can rise to 500?520℃.By means of special multi-stage homogenization,the temperature of the homogenization treatment of the ingot of the 7B04 high strength aluminum alloy can reach 500℃without overheating.展开更多
Through the long time track examination and disintegration to SF6 circuit breaker, we obtain the massive monitor data and massive pictures. The criteria of resuming insulation discharge failure conforming to CSO2/CH2S...Through the long time track examination and disintegration to SF6 circuit breaker, we obtain the massive monitor data and massive pictures. The criteria of resuming insulation discharge failure conforming to CSO2/CH2S>7, is quite broad to SO2 and the H2S concentration permission. Even if it reaches 100μL/L, it will not be in danger immediately to the safe operation of equipment. We may plan, arrange, and overhaul calmly. When obtaining the bare conductor overheating failure, it has not involved the resuming insulation. We may use the resuming insulation discharge failure criterion.展开更多
Thermal barrier coatings(TBC)on superalloy blade/vane enable an increase in turbine inlet temperature(TIT)and aero-engine efficiency.However,the deposition of dust on TBC significantly ablates superalloys and becomes ...Thermal barrier coatings(TBC)on superalloy blade/vane enable an increase in turbine inlet temperature(TIT)and aero-engine efficiency.However,the deposition of dust on TBC significantly ablates superalloys and becomes a bottleneck for advanced engine development.This paper presents a comprehensive mod-eling approach,based on an experiment involving dust deposition on a TBC-coated substrate,aimed at understanding the fundamental cause of substrate ablation.The results show that a significant increase in surface roughness is obtained experimentally with dust accumulation.The temperature field within the TBC-substrate system is disturbed by surface roughening.Consequently,the film cooling is seriously destroyed.While the dust accumulated on the TBC surface also contributes to heat insulation by increas-ing the effective TBC thickness,localized overheating of the substrate occurs and then leads to ablation and premature failure of the substrate.This elucidation of the overheating mechanism could inform the development of strategies to resist dust accumulation in advanced aero engines.展开更多
Melt treatment is well known to have an important influence on the properties of metallic glasses(MGs).However,for the MGs quenched from different melt temperatures with a quartz tube,the underlying physical origin re...Melt treatment is well known to have an important influence on the properties of metallic glasses(MGs).However,for the MGs quenched from different melt temperatures with a quartz tube,the underlying physical origin responsible for the variation of properties remains poorly understood.In the present work,we systematically studied the influence of melt treatment on the thermal properties of a Zr50Cu36Al14 glass-forming alloy and unveiled the microscopic origins.Specifically,we quenched the melt at different temperatures ranging from 1.1Tl to 1.5Tl(Tl is the liquidus temperature)to obtain melt-spun MG ribbons and investigated the variation of thermal properties of the MGs upon heating.We found that glass transition temperature,Tg,increases by as much as 36 K,and the supercooled liquid region disappears in the curve of differential scanning calorimetry when the melt is quenched at a high temperature up to 1.5Tl.The careful chemical analyses indicate that the change in glass transition behavior originates from the incorporation of oxygen and silicon in the molten alloys.The incorporated oxygen and silicon can both enhance the interactions between atoms,which renders the cooperative rearrangements of atoms difficult,and thus enhances the kinetic stability of the MGs.展开更多
The subject of this study is the oxidation of fuel rod cladding made of material Zr1Nb(0.1% O) in steam at temperatures in the range of 660℃ to 1200℃ with a surface in the initial state (after manufacturing - grindi...The subject of this study is the oxidation of fuel rod cladding made of material Zr1Nb(0.1% O) in steam at temperatures in the range of 660℃ to 1200℃ with a surface in the initial state (after manufacturing - grinding) and after additional chemical etching. The changes in the microstructure of tubes due to the interaction with steam were investigated. A comparison was made between the oxidation rate of this material (weight gain) and the data on the oxidation of other alloys for nuclear power plants. The oxidation rate of Zr1Nb(0.1% O) is close to the oxidation rate of other zirconium alloys. It is shown that after chemical treatment of the surface of the samples there is a more even growth of oxide films, and they have a smaller thickness for the same time of exposure than after mechanical grinding. Surface treatment before oxidation also affects the change of microstructure of samples when heated to high temperatures.展开更多
On June 19th,2017,the registration system of ITMA ASIA＋CITME 2018 came online officially.In the past five months,the exhibition recruitment work has obtained the general concentration of the industry.What is the bigg...On June 19th,2017,the registration system of ITMA ASIA＋CITME 2018 came online officially.In the past five months,the exhibition recruitment work has obtained the general concentration of the industry.What is the biggest difference of this exhibition with the previous ones？What will the audiences and exhibitors get from this exhibition？展开更多
During the Covid-19 pandemic in Serbia on March 6.to 03.04.2020.I cured 41 cases with a very severe clinical picture of influenza or possibly Covid-19.At that time,the Health Center in Sjenica did not have the materia...During the Covid-19 pandemic in Serbia on March 6.to 03.04.2020.I cured 41 cases with a very severe clinical picture of influenza or possibly Covid-19.At that time,the Health Center in Sjenica did not have the material for the diagnosis of Covid-19,and the patients refused to go to the neighboring Health Center because of the fear that caused sudden deaths.In my scientific work:“The role of cold in the origin and development of diseases with special review of some diseases of the respiratory system-treatment and prevention”,I proved the effect of cold and overheating on all organs and effective treatment.Under the effect of cooling,vasoconstriction,impaired circulation and impaired metabolism occur.Macrophage motility is reduced,phagocytes are weakened,ingestion,which causes easy implantation of the virus in the lungs.All the viral infections I followed for more than 35 years passed with mild symptoms if there was no previous cold or during the illness,even with the highly infectious Mexican flu(A/H1N1)and influenza.Patients with Covid-19 reported minimal,minor or more intense colds,which also determined the severity of the clinical picture.展开更多
基金financially supported by the National Natural Science Foundation of China (No.51503158)Key R&D Program of Hubei Province (No.2023BAB104)Open Project Program of High-Tech Organic Fibers Key Laboratory of Sichuan Province(No.PLN2024-08)
文摘The phenomena of thermal runaway and accidental deformation due to external stresses in lithium batteries or film capacitors consti-tute their primary failure mechanisms.Therefore,monitoring and early warning of overheating or localized strain are of great value for the safe use of lithium batteries or film capacitors;however,this function usually requires a system of multiple complex sensors.The realization of the above multiple hazards using a single sensor for monitoring and alarm functions has not been reported.Here,we exploit the thermally induced conductivity and modulus change during solid-liquid conversion of low melting point polyalloys to modulate the electronic relaxation polariza-tion and interfacial polarization in the composites for dielectric switching,and the reduction of alloy particle spacing during bending/compres-sive strain can be used to generate switchable tunneling effects for insulator-conductor transition.By synergizing dielectric switching and insula-tor-conductor transition,the final flexible thermoplastic polyurethane elastomer/low-melting-point polyalloy composite film achieves the func-tional integration of multi-level overheating warning and small deformation monitoring.
基金funded by the National Natural Science Foundation of China(no.22075155)the Zhejiang Provincial Natural Science Foundation of China(No.LY24B030002)+2 种基金Ningbo Natural Science Foundation(2023J089)the China Scholarship Council(CSC)the Ningbo Science and Technology Bureau(2024QL036).
文摘Battery safety is influenced by various factors,with thermal runaway being one of the most significant concerns.While most studies have concentrated on developing one-time,self-activating mechanism for thermal protection,such as temperature-responsive electrodes,and thermal-shutdown separators,these methods only provide irreversible protection.Recently,reversible temperature-sensitive electrolytes have emerged as promising alternatives,offering both thermo-reversibility and self-protective properties.However,further research is crucial to fully understand these thermal-shutdown electrolytes.In this study,we propose lower critical solution temperature(LCST)phase behavior poly(benzyl methacrylate)/imidazolium-based ionic liquid mixtures to prepare temperature-sensitive electrolytes that provide reversible thermal shutdown protection of batteries.This electrolyte features an appropriate protection temperature(~105℃)and responds quickly within a 1 min at 105℃,causing cells to hardly discharge as the voltage suddenly drops to 3.38 V,and providing efficient thermal shutdown protection within 30 min.Upon cooling back to room temperature,the battery regains its original performance.Additionally,the electrolyte exhibits excellent cycling stability with the capacity retention of the battery is 91.6%after 500 cycles.This work provides a viable solution for preventing batteries from thermal runaway triggered by overheating.
基金financially supported by the China Atomic Energy Authority(CAEA)through the Geological Disposal Programthe National Natural Science Foundation of China(No.42307258)the China National Nuclear Corporation Fundamental Research Project(No.CNNC-JCYJ-202307)。
文摘Investigations into the long-term creep behavior of Beishan granite in uniaxial compression were conducted.Four levels of axial stress(60,70,87,and 95 MPa)were applied to rock specimens.Contrasting with earlier research,the long-term creep data in this work present a substantial advancement in the time dimension.Except for the sample subjected to 60 MPa axial loading,which did not fail after a loading duration of 1650 d,the specimens under the other three stresses all failed after sustained constant loading durations of 1204,1023,and 839 d,respectively.A lower envelope of driving stress-ratio for crystalline rocks was obtained,tending towards approximately 0.45 over an infinite time scale.According to the experimental results,as axial stress increases,both the axial strain accumulated in the transient creep process and the strain rate associated with steady-state creep deformation increase exponentially;however,the share of steady-state creep strain remains nearly constant at about82.53%.A novel damage-based creep model was put forward.It provides an enhanced depiction of the comprehensive creep process in rocks,notably improving the accuracy in forecasting the accelerated creep phase,which significantly impacts the long-term stability of engineering structures.
基金Supported by the National Natural Science Foundation of China(No.43277051)the Key Laboratory of Integrated Regulation and Resources Development of Shallow Lakes of Ministry of Education(No.B230203006).
文摘While oceanic and coastal acidification has gained increased attention,long-term pH trends and their drivers in large freshwater systems remain poorly understood.The Laurentian Great Lakes are the world’s largest freshwater system,and in many ways resemble marine ecosystems.However,unlike the open ocean and coastal waters where pH has declined due to rising atmospheric CO_(2),no significant pH trends have been observed in the Laurentian Great Lakes,despite significant ecosystem changes driven partly by the invasion of dreissenid mussels.This study examined 41 years of field observations from Lake Michigan to investigate the long-term carbonate chemistry dynamics.Observational results revealed substantial declines in both total alkalinity(TA)and dissolved inorganic carbon(DIC)over the four decades.Mussel shell calcification emerged as the primary mechanism behind these declines,accounting for 97%and 47%of the observed changes in TA and DIC,respectively,lowering water column pH by 0.24 units.Elevated carbon accumulation in soft mussel tissues,coupled with long-term changes in the air-water pCO_(2)gradient during summer,significantly contributed to long-term DIC variations,explaining 18%and 28%of the lake-wide DIC loss.These two mechanisms also resulted in an overall pH increase of 0.09 and 0.12 units,largely offsetting the calcification-driven pH decrease.These findings bridge a gap in acidification research for large freshwater systems and provide valuable insights for comprehensive lake-wide management strategies.
文摘Objective:To investigate the long-term prognosis and postoperative cosmetic outcomes of breast-conserving surgery combined with sentinel lymph node biopsy in patients with early-stage breast cancer,providing a reference for the selection of clinical treatment plans.Methods:A retrospective analysis was conducted on the clinical data of 68 patients with early-stage breast cancer admitted from January 2022 to December 2025.Based on the surgical approach,patients were divided into an observation group(breast-conserving surgery+sentinel lymph node biopsy)and a control group(other surgical methods such as modified radical mastectomy/total mastectomy).Clinical and pathological characteristics,incidence of postoperative complications,follow-up prognosis,and satisfaction with cosmetic outcomes were compared between the two groups.Results:Among the 68 patients,41 were in the observation group and 27 in the control group.The average age of patients in the observation group was(54.32±8.15)years,while that in the control group was(62.45±9.76)years.The average tumor size in the observation group was(1.86±0.72)cm,compared to(3.21±1.45)cm in the control group.The incidence of postoperative complications in the observation group was 9.76%,significantly lower than that in the control group at 33.33%(P<0.05).The 6-month disease-free survival rate was 95.12%in the observation group and 88.89%in the control group,with no statistically significant difference between the two groups(P>0.05).The excellent and good rate of cosmetic outcomes in the observation group was 87.80%,significantly higher than that in the control group at 29.63%(P<0.05).Conclusion:Breast-conserving surgery combined with sentinel lymph node biopsy for early-stage breast cancer can achieve long-term prognostic outcomes comparable to those of traditional radical surgery,with the advantages of fewer postoperative complications and superior cosmetic results.This approach is worthy of clinical promotion and application,particularly for early-stage breast cancer patients who have a demand for preserving breast morphology.
文摘Taking the rural low-income population of Zhejiang Province as its subject, this paper examines how to build a sustainable income-growth mechanism and identify feasible implementation paths within the context of the common prosperity strategy. The research identifies key obstacles to income expansion, including an undiversified industrial structure, insufficient human capital, and a lack of robust social protection. These call for systemic solutions featuring institutional innovation, resource consolidation, and capability enhancement. Building on Zhejiang's experience as a common prosperity demonstration zone, the article constructs an integrated framework centered on four pillars: industrial empowerment, education upgrading, social security reinforcement, and digital coordination. It further offers concrete policy proposals involving the cultivation of localized industries, vocational skill training, enhanced safety nets, and the adoption of digital tools. The study thus offers both theoretical insights and practical paradigms for tackling the challenge of raising incomes in low-income rural areas.
文摘AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longitudinal observational study,detailed medical histories of APAC patients and comprehensive ophthalmic examinations at final followup were collected.Logistic regression analysis was performed to identify predictors of blindness.Univariate and multivariate linear regression analyses were conducted to determine risk factors associated with visual outcomes.RESULTS:This study included 39 affected eyes of 31 subjects(26 females)with an average age of 74.1±8.0y.At 6.7±4.2y after APAC attack,2(5.7%)eyes had bestcorrected visual acuity(VA)worse than 3/60.Advanced glaucomatous visual field loss was observed in 15(39.5%)affected eyes and 5(25.0%)fellow eyes.Nine affected eyes(23.7%)had GON,and 11(28.9%)were blind.Six(15.4%)affected eyes and 2(9.1%)fellow eyes had suspicious progression.A significantly higher blindness rate in factory workers compared to office workers.Logistic regression identified that worse VA at attack(OR 10.568,95%CI 1.288-86.695;P=0.028)and worse early postoperative VA(OR 13.214,95%CI 1.157-150.881;P=0.038)were risk factors for blindness.Multivariate regression showed that longer duration of elevated intraocular pressure(P=0.004)and worse early postoperative VA(P=0.009)were associated with worse visual outcomes.CONCLUSION:Despite LE surgery,some APAC patients experience continued visual function deterioration.Lifelong monitoring is necessary.Target pressure and progression rates should be re-evaluated during follow-up.
基金National Natural Science Foundation of China,No.81901336(to JM).
文摘Subarachnoid hemorrhage is a subtype of stroke that causes severe neurological damage and is associated with poor long-term prognosis.Cognitive impairment is a major manifestation of long-term neurological dysfunction in patients with subarachnoid hemorrhage.However,there is notable absence of biological markers to predict long-term prognosis in this patient population.Given the aging-like neurocognitive phenomena associated with subarachnoid hemorrhage,this study postulates that telomere length,a recognized biomarker for aging,could be used as a prognostic indicator for subarachnoid hemorrhage.A left internal carotid artery intravascular puncture mouse model was used to simulate subarachnoid hemorrhage.Comprehensive neurological test scores were obtained through neurobehavioral assessments conducted at one-month intervals.Concurrently,the relative telomere length was analyzed by quantitative polymerase chain reaction,which was performed using DNA extracted from ear notch and brain tissue after each assessment.Furthermore,proteomic analysis was employed to investigate differential protein expression in hippocampal tissue.Subarachnoid hemorrhage mice exhibited persistent neurocognitive impairment over a prolonged period of time.There was a significant positive correlation between telomere length and neurological test scores,confirming the usefulness of telomere length as a prognostic indicator in subarachnoid hemorrhage.Hippocampal tissue from subarachnoid hemorrhage mice showed reduced expression of acetyl-coenzyme A synthetase-2 and abnormalities in the expression of proteins related to ribosomes,energy metabolism,and cellular signal transduction.This study confirmed telomere shortening in the brain and metabolic disturbances in the hippocampi of subarachnoid hemorrhage mice.Thus,telomere length is a predictive marker for long-term impairment of cognitive function in mice following experimental subarachnoid hemorrhage.
基金financially supported by the National Science & Technology Fundamental Resources Investigation Project of China (2021FY100501)the Youth Innovation of Chinese Academy of Agricultural Sciences (Y2023QC16)。
文摘Long-term manure application has the potential to alleviate soil acidification, and increase carbon sequestration and nutrient availability, thus improving cropland fertility. However, the mechanisms behind greenhouse gas N_(2)O emissions from acidic soil mediated by long-term manure application remain poorly understood. Herein, we investigated N_(2)O emission and its linkage with gross N mineralization and nitrification rates, as well as nitrifying and denitrifying microbes in an acidic upland soil subjected to 36-year fertilization treatments, including an unfertilized control(CK), inorganic fertilizer(F), 2× rate of inorganic fertilizer(2F), manure(M), and the combination of inorganic fertilizer and manure(FM) treatments. Compared to the CK treatment(1.34 μg N kg^(-1) d^(-1)), fertilization strongly increased N_(2)O emissions by 34-fold on average, with more pronounced increases in the manure-amendment(10.6-169 μg N kg^(-1) d^(-1)) than those in the inorganic fertilizer treatments(3.26-5.51 μg N kg^(-1) d^(-1)). The manure amendment-stimulated N_(2)O emissions were highly associated with increased soil pH, mean weight diameter of soil aggregates, substrate availability(e.g., particulate organic carbon, NO_(3)^(-)and available phosphorus), gross N mineralization rates, denitrifier abundances and the(nirK+nirS)/nosZ ratio. These findings suggest that the increased N_(2)O emissions primarily resulted from alleviated acidification, increased substrate availability and improved soil structure, thus enhancing microbial N mineralization and favoring N_(2)O^(-)producing denitrifiers over N_(2)O consumers. Moreover, ammonia-oxidizing bacteria(AOB) rather than ammonia-oxidizing archaea(AOA) positively correlated with soil NO_(3)^(-)concentration and N_(2)O emissions, indicating that nitrification indirectly contributed to N_(2)O production by supplying NO_(3)^(-)for denitrification. Collectively, manure amendment potentially stimulates N_(2)O emissions, primarily resulting from alleviated soil acidification and increased substrate availability, thus enhancing N mineralization and denitrifier-mediated N_(2)O production. Our findings suggest that consideration should be given to the greenhouse gas budgets of agricultural ecosystems when applying manure for managing the pH and fertility of acidic soils.
文摘In Alzheimer’s disease,perturbations of glutamate neurotransmission lead to synaptic dysfunction and synapse loss.Several studies have used glutamate transport inhibitors to demonstrate that soluble oligomers of amyloid-βinduce synaptic dysfunction by interrupting glutamate uptake mediated by glutamate transporter 1,the major glutamate transporter in the brain.The cellular targets of the synaptic effects of soluble amyloid-βoligomers,including the nature of any interaction with glutamate transporter 1,remain ill-defined.We have generated a conditional glutamate transporter 1 knockout mouse to investigate cell-type specific functions of glutamate transporter 1.Field excitatory postsynaptic potentials were examined in the CA1 region of mouse hippocampal slices.We confirmed that hippocampal long-term potentiation impairment is induced by both soluble amyloid-β oligomers and glutamate uptake inhibitors.Amyloid-βoligomers,including those isolated directly from the cortex of patients with Alzheimer’s disease,failed to inhibit hippocampal long-term potentiation in neuronal glutamate transporter 1 but not astrocytic glutamate transporter 1 knockout mice.The masking or occlusion of the effect of soluble amyloid-β oligomers by knockout of glutamate transporter 1 in neurons suggests that the metabolic or signaling consequences of knockout of glutamate transporter 1 in neurons and amyloid-βoligomer inhibition of synaptic plasticity show epistasis and thus share a similar molecular pathway.To extend these observations,we tested the effects of other types of manipulation of glutamate homeostasis on synaptic plasticity and the pathophysiology of soluble amyloid-β oligomers.Ceftriaxone,which upregulates glutamate transporter 1 levels,among other effects,prevented the impairment of long-term potentiation by soluble amyloid-β oligomers.Collectively,our findings suggest that the effects of amyloid-βon synaptic function are highly dependent on glutamate reuptake homeostasis and that the disruption of synaptic function by soluble amyloid-β oligomers is mediated by pathways linked to neuronal,not astrocytic,glutamate transporter 1.The findings of this study highlight the translational potential of targeting neuronal glutamate transporter 1 to counteract amyloid-β-induced synaptic dysfunction in Alzheimer’s disease.By showing that glutamate transporter 1 upregulation(e.g.,via ceftriaxone)can prevent amyloid-β-related impairments,this research supports developing therapies aimed at modulating glutamate homeostasis to preserve synaptic function and combat cognitive decline in patients with Alzheimer’s disease.
基金supported byNationalNatural Science Foundation of China,GrantNo.62402046the Beijing Forestry University Science and Technology Innovation Project under Grant No.BLX202358.
文摘Long-term traffic flow prediction is a crucial component of intelligent transportation systems within intelligent networks,requiring predictive models that balance accuracy with low-latency and lightweight computation to optimize trafficmanagement and enhance urban mobility and sustainability.However,traditional predictivemodels struggle to capture long-term temporal dependencies and are computationally intensive,limiting their practicality in real-time.Moreover,many approaches overlook the periodic characteristics inherent in traffic data,further impacting performance.To address these challenges,we introduce ST-MambaGCN,a State-Space-Based Spatio-Temporal Graph Convolution Network.Unlike conventionalmodels,ST-MambaGCN replaces the temporal attention layer withMamba,a state-space model that efficiently captures long-term dependencies with near-linear computational complexity.The model combines Chebyshev polynomial-based graph convolutional networks(GCN)to explore spatial correlations.Additionally,we incorporate a multi-temporal feature capture mechanism,where the final integrated features are generated through the Hadamard product based on learnable parameters.This mechanism explicitly models shortterm,daily,and weekly traffic patterns to enhance the network’s awareness of traffic periodicity.Extensive experiments on the PeMS04 and PeMS08 datasets demonstrate that ST-MambaGCN significantly outperforms existing benchmarks,offering substantial improvements in both prediction accuracy and computational efficiency for long-term traffic flow prediction.
基金Project(52373065)supported by the National Natural Science Foundation of ChinaProject(2220004002898)supported by the Zhuhai Industry University Research Cooperation and Basic and Applied Research Projects,China。
文摘Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.
基金Projects(51174121,51274125)supported by the National Natural Science Foundation of ChinaProject(2010R50016-30)supported by Zhejiang Province Science and Technology Innovation Team of Key Projects,ChinaProject supported by the K.C.Wong Magna Fund of Ningbo University,China
文摘The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx（x=10, 12） glass-forming alloyswerestudied by differential thermal analysis combining with solidification structure analysis. The results indicate that the undercooling degree of Nd9Fe85-xTi4C2Bx（x=10, 12） alloys significantly increaseswith the rise of melt overheating degree, and two overheating degree thresholds corresponding to the drastic increase of the mean undercooling degree are found for each of the alloys. The existence of two turning points of the mean undercooling degreescan be linked to the structure transitions inside the overheated melts, which result in the evident increase of volume fraction of amorphous phasein the solidified structures.
基金Project(2003AA331100)supported by the Hi-tech Research and Development Program of China
文摘The microstructure and overheating characteristics of the direct chill semicontinuous casting ingot of 7B04 high strength aluminum alloy,and those after industrial homogenization treatment and multi-stage homogenization treatments,were studied by differential scanning calorimetry(DSC),optical microscopy(OM)and scanning electron microscopy with energy dispersive X-ray spectroscopy(SEM-EDX).The results show that the microstructure of direct chill semicontinuous casting ingot of the 7B04 alloy contains a large number of constituents in the form of dendritic networks that consist of nonequilibrium eutectic and Fe-containing phases.The nonequilibrium eutectic contains Al,Zn,Mg and Cu,and the Fe-containing phases include two kinds of phases,one containing Al,Fe,Mn and Cu,and the other having Al,Fe,Mn,Cr,Si and Cu.The melting point of the nonequilibrium eutectic is 478℃for the casting ingot of the 7B04 alloy which is usually considered as its overheating temperature.During industrial homogenization treatment processing at 470℃,the nonequilibrium eutectic dissolves into the matrix of this alloy partly,and the remainder transforms into Al2CuMg phase that cannot be dissolved into the matrix at that temperature completely.The melting point of the Al2CuMg phase which can dissolve into the matrix completely by slow heating is about 490℃.The overheating temperature of this high strength aluminum alloy can rise to 500?520℃.By means of special multi-stage homogenization,the temperature of the homogenization treatment of the ingot of the 7B04 high strength aluminum alloy can reach 500℃without overheating.
文摘Through the long time track examination and disintegration to SF6 circuit breaker, we obtain the massive monitor data and massive pictures. The criteria of resuming insulation discharge failure conforming to CSO2/CH2S>7, is quite broad to SO2 and the H2S concentration permission. Even if it reaches 100μL/L, it will not be in danger immediately to the safe operation of equipment. We may plan, arrange, and overhaul calmly. When obtaining the bare conductor overheating failure, it has not involved the resuming insulation. We may use the resuming insulation discharge failure criterion.
基金National Natural Science Foundation of China(No.51901175)China Postdoctoral Science Foundation Grant(Nos.2020T130499 and 2019M653602)HPC platform in Xi'an Jiaotong University.
文摘Thermal barrier coatings(TBC)on superalloy blade/vane enable an increase in turbine inlet temperature(TIT)and aero-engine efficiency.However,the deposition of dust on TBC significantly ablates superalloys and becomes a bottleneck for advanced engine development.This paper presents a comprehensive mod-eling approach,based on an experiment involving dust deposition on a TBC-coated substrate,aimed at understanding the fundamental cause of substrate ablation.The results show that a significant increase in surface roughness is obtained experimentally with dust accumulation.The temperature field within the TBC-substrate system is disturbed by surface roughening.Consequently,the film cooling is seriously destroyed.While the dust accumulated on the TBC surface also contributes to heat insulation by increas-ing the effective TBC thickness,localized overheating of the substrate occurs and then leads to ablation and premature failure of the substrate.This elucidation of the overheating mechanism could inform the development of strategies to resist dust accumulation in advanced aero engines.
基金The work was financially supported by the National Key Research and Development Program of China(Grant Nos.2018YFA0703600,2021YFA0716302,and 2021YFA0718703)the National Natural Science Foundation of China(Grant Nos.51825104 and 52192602)China Postdoctoral Science Foundation(Grant No.2022T150691).
文摘Melt treatment is well known to have an important influence on the properties of metallic glasses(MGs).However,for the MGs quenched from different melt temperatures with a quartz tube,the underlying physical origin responsible for the variation of properties remains poorly understood.In the present work,we systematically studied the influence of melt treatment on the thermal properties of a Zr50Cu36Al14 glass-forming alloy and unveiled the microscopic origins.Specifically,we quenched the melt at different temperatures ranging from 1.1Tl to 1.5Tl(Tl is the liquidus temperature)to obtain melt-spun MG ribbons and investigated the variation of thermal properties of the MGs upon heating.We found that glass transition temperature,Tg,increases by as much as 36 K,and the supercooled liquid region disappears in the curve of differential scanning calorimetry when the melt is quenched at a high temperature up to 1.5Tl.The careful chemical analyses indicate that the change in glass transition behavior originates from the incorporation of oxygen and silicon in the molten alloys.The incorporated oxygen and silicon can both enhance the interactions between atoms,which renders the cooperative rearrangements of atoms difficult,and thus enhances the kinetic stability of the MGs.
文摘The subject of this study is the oxidation of fuel rod cladding made of material Zr1Nb(0.1% O) in steam at temperatures in the range of 660℃ to 1200℃ with a surface in the initial state (after manufacturing - grinding) and after additional chemical etching. The changes in the microstructure of tubes due to the interaction with steam were investigated. A comparison was made between the oxidation rate of this material (weight gain) and the data on the oxidation of other alloys for nuclear power plants. The oxidation rate of Zr1Nb(0.1% O) is close to the oxidation rate of other zirconium alloys. It is shown that after chemical treatment of the surface of the samples there is a more even growth of oxide films, and they have a smaller thickness for the same time of exposure than after mechanical grinding. Surface treatment before oxidation also affects the change of microstructure of samples when heated to high temperatures.
文摘On June 19th,2017,the registration system of ITMA ASIA＋CITME 2018 came online officially.In the past five months,the exhibition recruitment work has obtained the general concentration of the industry.What is the biggest difference of this exhibition with the previous ones？What will the audiences and exhibitors get from this exhibition？
文摘During the Covid-19 pandemic in Serbia on March 6.to 03.04.2020.I cured 41 cases with a very severe clinical picture of influenza or possibly Covid-19.At that time,the Health Center in Sjenica did not have the material for the diagnosis of Covid-19,and the patients refused to go to the neighboring Health Center because of the fear that caused sudden deaths.In my scientific work:“The role of cold in the origin and development of diseases with special review of some diseases of the respiratory system-treatment and prevention”,I proved the effect of cold and overheating on all organs and effective treatment.Under the effect of cooling,vasoconstriction,impaired circulation and impaired metabolism occur.Macrophage motility is reduced,phagocytes are weakened,ingestion,which causes easy implantation of the virus in the lungs.All the viral infections I followed for more than 35 years passed with mild symptoms if there was no previous cold or during the illness,even with the highly infectious Mexican flu(A/H1N1)and influenza.Patients with Covid-19 reported minimal,minor or more intense colds,which also determined the severity of the clinical picture.
