By applying the mastersymmetry of degree one to the time-independent symmetry K_(1), the fifth-order asymmetric Nizhnik-Novikov-Veselov system is derived. The variable separation solution is obtained by using the trun...By applying the mastersymmetry of degree one to the time-independent symmetry K_(1), the fifth-order asymmetric Nizhnik-Novikov-Veselov system is derived. The variable separation solution is obtained by using the truncated Painlevé expansion with a special seed solution. New patterns of localized excitations, such as dromioff, instanton moving on a curved line, and tempo-spatial breather, are constructed. Additionally, fission or fusion solitary wave solutions are presented,graphically illustrated by several interesting examples.展开更多
By using a mapping approach and a linear variable separation approach, a new family of solitary wave solutions with arbitrary functions for the （2＋1）-dimensional modified dispersive water-wave system （MDWW） is de...By using a mapping approach and a linear variable separation approach, a new family of solitary wave solutions with arbitrary functions for the （2＋1）-dimensional modified dispersive water-wave system （MDWW） is derived. Based on the derived solutions and using some multi-valued functions, we obtain some novel folded localized excitations of the system.展开更多
Based on the B/icklund method and the multilinear variable separation approach （MLVSA）, this paper finds a general solution including two arbitrary functions for the （2＋1）-dimensional Burgers equations. Then a cl...Based on the B/icklund method and the multilinear variable separation approach （MLVSA）, this paper finds a general solution including two arbitrary functions for the （2＋1）-dimensional Burgers equations. Then a class of new doubly periodic wave solutions for （2＋l）-dimensional Burgers equations is obtained by introducing appropriate Jacobi elliptic functions, Weierstrass elliptic functions and their combination in the general solutions （which contains two arbitrary functions）. Two types of limit cases are considered. Firstly, taking one of the moduli to be unity and the other zero, it obtains particular wave （called semi-localized） patterns, which is periodic in one direction, but localized in the other direction. Secondly, if both moduli are tending to 1 as a limit, it derives some novel localized excitations （two-dromion solution）.展开更多
Periodic wave solutions and solitary wave solutions to a generalized （3＋1）-dimensional Gross Pitaevskii equation with time-modulated dispersion, nonlinearity, and potential are derived in terms of an improved homog...Periodic wave solutions and solitary wave solutions to a generalized （3＋1）-dimensional Gross Pitaevskii equation with time-modulated dispersion, nonlinearity, and potential are derived in terms of an improved homogeneous balance principle and a mapping approach. These exact solutions exist under certain conditions via imposing suitable constraints on the functions describing dispersion, nonlinearity, and potential. The dynamics of the derived solutions can be manipulated by prescribing specific time-modulated dispersions, nonlinearities, and potentials. The results show that the periodic waves and solitary waves with novel behaviors are similar to the similaritons reported in other nonlinear systems.展开更多
Using a special Painleve-Baecklund transformation as well as the extended mapping approach and the linear superposition theorem, we obtain new families of variable separation solutions to the （2＋1）-dimensional gene...Using a special Painleve-Baecklund transformation as well as the extended mapping approach and the linear superposition theorem, we obtain new families of variable separation solutions to the （2＋1）-dimensional generalized Broer-Kaup （GBK） system. Based on the derived exact solution, we reveal some novel evolutional behaviors of localized excitations, i.e. fission and fusion phenomena in the （2＋1）-dimensional GBK system.展开更多
In this letter, by means of the Lax pair, Darboux transformation, and variable separation approach, a new exact solution of a sixth-order (1+ 1)-dimensional nonlinear evolution equation, which includes some arbitrary ...In this letter, by means of the Lax pair, Darboux transformation, and variable separation approach, a new exact solution of a sixth-order (1+ 1)-dimensional nonlinear evolution equation, which includes some arbitrary functions,is obtained. Abundant new localized excitations can be found by selecting appropriate functions and they are illustrated both analytically and graphically.展开更多
We report on the localized spatial soliton excitations in the multidimensional nonlinear Schrodinger equation with radially variable nonlinearity coefficient and an external potential. By using Hirota＇s binary differ...We report on the localized spatial soliton excitations in the multidimensional nonlinear Schrodinger equation with radially variable nonlinearity coefficient and an external potential. By using Hirota＇s binary differential operators, we determine a variety of external potentials and nonlinearity coefficients that can support nonlinear localized solutions of different but desired forms. For some specific external potentials and nonlinearity coefficients, we discuss features of the corresponding （2＋1）-dimensional multisolitonic solutions, including ring solitons, lump solitons, and soliton clusters.展开更多
Electronic circular dichroism(ECD)spectrum is an important tool for as-sessing molecular chirality.Tradition-al methods,like linear response time-dependent density functional theory(LR-TDDFT),predict ECD spectra well ...Electronic circular dichroism(ECD)spectrum is an important tool for as-sessing molecular chirality.Tradition-al methods,like linear response time-dependent density functional theory(LR-TDDFT),predict ECD spectra well for small or medium-sized molecules,but struggle with large sys-tems due to high computational costs,making it a significant challenge to ac-curately and efficiently predict the ECD properties of complex systems.Within the framework of the generalized energy-based fragmentation(GEBF)method for localized excited states(ESs)calculation,we propose a combination algorithm for calculating rotatory strengths of ESs in condensed phase systems.This algorithm estimates the rotatory strength of the total system by calculating and combin-ing the transition electric and magnetic dipole moments of subsystems.We have used the GEBF method to calculate the ECD properties of chiral drug molecule derivatives,green fluo-rescent protein,and cyclodextrin derivatives,and compared their results with traditional methods or experimental data.The results show that this method can efficiently and accu-rately predict the ECD spectra of these systems.Thus,the GEBF method for ECD spectra demonstrates great potential in the chiral analysis of complex systems and chiral material design,promising to become a powerful theoretical tool in chiral chemistry.展开更多
A pair of asymmetric rigid carbazole-benzonitrile-based emitters were synthesized by strategically alternating donor and acceptor groups along the molecular edges.The spin-flip process is accelerated by both the forma...A pair of asymmetric rigid carbazole-benzonitrile-based emitters were synthesized by strategically alternating donor and acceptor groups along the molecular edges.The spin-flip process is accelerated by both the formation of localized and delocalized charge transfer states due to linearly positioned donors and strong spin-orbital coupling between different excitation feature of the lowest singlet and triplet excited states.This molecular architecture results in a remarkable short delayed lifespan of around 100 ns.The application of the two emitters in organic light-emitting diodes(OLEDs)achieves the highest external quantum efficiencies of 13.0%for the green emitter and 9.1%for the sky-blue emitter.Impressively,these devices maintain their high efficiency even at high luminance levels.The sustained efficiency is ascribed to the effective suppression of exciton quenching by substantially shortening delayed lifespan.These findings underscore the practical utility of the molecular design strategy that incorporates alternate donor and acceptor groups at the molecular periphery for shortening delayed fluorescence lifetime,and hold great promise for the development of high-performance OLEDs.展开更多
A wire rope defects detection method based on permanent magnet excitation is proposed.A detection system,mainly composed of permanent magnet excitation,distance detection,multi-sensor magnetic flux leakage signal acqu...A wire rope defects detection method based on permanent magnet excitation is proposed.A detection system,mainly composed of permanent magnet excitation,distance detection,multi-sensor magnetic flux leakage signal acquisition and data analysis device,is set up.According to the different characteristics of the multi-sensor magnetic flux leakage signal,the localized fault(LF)and loss of metallic cross-sectional area(LMA)signal is separated,and then the two defects can be detected.The experiments show that the method can effectively detect the two defects when they appear simultaneously on the wire rope.展开更多
With the help of an extended mapping approach, a new type of variable separation excitation with three arbitrary functions of the (2+1)-dimensional dispersive long-water wave system (DLW) is derived. Based on the deri...With the help of an extended mapping approach, a new type of variable separation excitation with three arbitrary functions of the (2+1)-dimensional dispersive long-water wave system (DLW) is derived. Based on the derived variable separation excitation, abundant non-propagating solitons such as dromion, ring, peakon, and compacton etc.are revealed by selecting appropriate functions in this paper.展开更多
By means of the variable separation method, new exact solutions of some （1 ＋ 1）-dimensionaJ nonlinear evolution equations are obtained. Abundant localized excitations can be found by selecting corresponding arbitra...By means of the variable separation method, new exact solutions of some （1 ＋ 1）-dimensionaJ nonlinear evolution equations are obtained. Abundant localized excitations can be found by selecting corresponding arbitrary functions appropriately. Namely, the new soliton-like localized excitations and instanton-like localized excitations are presented.展开更多
With the help of an objective reduction approach （ORA）, abundant exact solutions of （2＋1）-dimensional higher-order Boussinesq system （including some hyperboloid function solutions, trigonometric function solutio...With the help of an objective reduction approach （ORA）, abundant exact solutions of （2＋1）-dimensional higher-order Boussinesq system （including some hyperboloid function solutions, trigonometric function solutions, and a rational function solution） are obtained. It is shown that some novel soliton structures, like single linearity soliton structure, breath soliton structure, single linearity y-periodic solitary wave structure, libration dromion structure, and kink-like multisoliton structure with actual physical meaning exist in the （2＋1）-dimensional higher-order Boussinesq system.展开更多
By means of a Painlevé-Baicklund transformation and a multi-linear separation-of-variable approach, abundant localized coherent excitations of a modified Broer-Kaup system are derived. There appear possible phase...By means of a Painlevé-Baicklund transformation and a multi-linear separation-of-variable approach, abundant localized coherent excitations of a modified Broer-Kaup system are derived. There appear possible phase shifts for the interactions of the （2＋1）-dimensional novel localized structures, which are discussed in this paper.展开更多
Using an extended projective method, a new type of variable separation solution with two arbitrary functions of the (2+1)-dimensional generalized Broer-Kaup system (GBK) is derived. Based on the derived variable separ...Using an extended projective method, a new type of variable separation solution with two arbitrary functions of the (2+1)-dimensional generalized Broer-Kaup system (GBK) is derived. Based on the derived variable separation solution, some special localized coherent soliton excitations with or without elastic behaviors such as dromions, peakons,and foldons etc. are revealed by selecting appropriate functions in this paper.展开更多
By means of an extended mapping approach and a linear variable separation approach, a new family of exact solutions of the （3＋1）-dimensional Jimbo-Miwa system is derived. Based on the derived solitary wave solution...By means of an extended mapping approach and a linear variable separation approach, a new family of exact solutions of the （3＋1）-dimensional Jimbo-Miwa system is derived. Based on the derived solitary wave solution, we obtain some special localized excitations and study the interactions between two solitary waves of the system.展开更多
A class of new doubly periodic wave solutions for （2＋1）-dimensional KdV equation are obtained by introducing appropriate Jacobi elliptic functions and Weierstrass elliptic functions in the general solution（contain...A class of new doubly periodic wave solutions for （2＋1）-dimensional KdV equation are obtained by introducing appropriate Jacobi elliptic functions and Weierstrass elliptic functions in the general solution（contains two arbitrary functions） got by means of multilinear variable separation approach for （2＋1）-dimensional KdV equation. Limiting cases are considered and some localized excitations are derived, such as dromion, multidromions, dromion-antidromion, multidromions-antidromions, and so on. Some solutions of the dromion-antidromion and multidromions-antidromions are periodic in one direction but localized in the other direction. The interaction properties of these solutions, which are numerically studied, reveal that some of them are nonelastic and some are completely elastic. Furthermore, these results are visualized.展开更多
Extended mapping approach is introduced to solve （2＋1）-dimensional Nizhnik-Novikov Veselov equation. A new type of variable separation solutions is derived with arbitrary functions in the model. Based on this excit...Extended mapping approach is introduced to solve （2＋1）-dimensional Nizhnik-Novikov Veselov equation. A new type of variable separation solutions is derived with arbitrary functions in the model. Based on this excitation, rich localized structures such as multi-lump soliton and ring soliton are revealed by selecting the arbitrary function appropriately.展开更多
Spectral and photophysical investigations of 4＇-（p-aminophenyl）-2,2＇：6＇,2″-terpyridine （APT） have been performed in various solvents with different polarity and hydrogen-bonding ability. The emission spectra ...Spectral and photophysical investigations of 4＇-（p-aminophenyl）-2,2＇：6＇,2″-terpyridine （APT） have been performed in various solvents with different polarity and hydrogen-bonding ability. The emission spectra of APT are found to exhibit dual fluorescence in polar solvents, which attributes to the local excited and intramolecular charge transfer states, respectively. The two-state model is proven out for APT in polar solvent by the time-correlated single photon counting emission decay measurement. Interestingly, the linear relationships of different emission maxima and solvent polarity parameter are found for APT in protic and aprotic solvents, because of the hydrogen bond formation between APT and alcohols at the amino nitrogen N25. Furthermore, the effects of the complexation of the metal ion with tpy group of APT and the hydrogen bond formation between APT with methanol at the terpyridine nitrogen N4-NS-N14 are also presented. The appearance of new long-wave absorption and fluorescence bands indicates that a new ground state of the complexes is formed.展开更多
The development of fluorescent materials capable of harvesting triplet excitons efficiently is of great importance in achieving high-performance low-cost organic light-emitting diodes（OLEDs）.Among the three mechanis...The development of fluorescent materials capable of harvesting triplet excitons efficiently is of great importance in achieving high-performance low-cost organic light-emitting diodes（OLEDs）.Among the three mechanisms converting triplet to singlet excitons,triplet fusion delayed fluorescence（TFDF） plays a key role in the demonstration of highly efficient and reliable OLEDs,especially blue devices,for practice applications.This review focuses on the recent development of TFDF materials and their applications in OLEDs.Fundamental TFDF mechanism,molecular design principles,and the structure-property relationship of TFDF materials with a particular emphasis on their different excited state characters,are presented and discussed.Moreover,the future perspectives and ongoing challenges of TFDF materials are also highlighted.展开更多
文摘By applying the mastersymmetry of degree one to the time-independent symmetry K_(1), the fifth-order asymmetric Nizhnik-Novikov-Veselov system is derived. The variable separation solution is obtained by using the truncated Painlevé expansion with a special seed solution. New patterns of localized excitations, such as dromioff, instanton moving on a curved line, and tempo-spatial breather, are constructed. Additionally, fission or fusion solitary wave solutions are presented,graphically illustrated by several interesting examples.
基金Project supported by the Natural Science Foundation of Zhejiang Province, China (Grant Nos. Y6100257 and Y6110140)
文摘By using a mapping approach and a linear variable separation approach, a new family of solitary wave solutions with arbitrary functions for the （2＋1）-dimensional modified dispersive water-wave system （MDWW） is derived. Based on the derived solutions and using some multi-valued functions, we obtain some novel folded localized excitations of the system.
基金Project supported by the National Natural Science Foundation of China (Grant No 10647112)the Foundation of Donghua University
文摘Based on the B/icklund method and the multilinear variable separation approach （MLVSA）, this paper finds a general solution including two arbitrary functions for the （2＋1）-dimensional Burgers equations. Then a class of new doubly periodic wave solutions for （2＋l）-dimensional Burgers equations is obtained by introducing appropriate Jacobi elliptic functions, Weierstrass elliptic functions and their combination in the general solutions （which contains two arbitrary functions）. Two types of limit cases are considered. Firstly, taking one of the moduli to be unity and the other zero, it obtains particular wave （called semi-localized） patterns, which is periodic in one direction, but localized in the other direction. Secondly, if both moduli are tending to 1 as a limit, it derives some novel localized excitations （two-dromion solution）.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11172181)the Natural Science Foundation of Guangdong Province, China (Grant No. 10151200501000008)+1 种基金the Special Foundation of Talent Engineering of Guangdong Province, China (Grant No.2009109)the Scientific Research Foundation of Key Discipline of Shaoguan University, China(Grant No. ZD2009001)
文摘Periodic wave solutions and solitary wave solutions to a generalized （3＋1）-dimensional Gross Pitaevskii equation with time-modulated dispersion, nonlinearity, and potential are derived in terms of an improved homogeneous balance principle and a mapping approach. These exact solutions exist under certain conditions via imposing suitable constraints on the functions describing dispersion, nonlinearity, and potential. The dynamics of the derived solutions can be manipulated by prescribing specific time-modulated dispersions, nonlinearities, and potentials. The results show that the periodic waves and solitary waves with novel behaviors are similar to the similaritons reported in other nonlinear systems.
基金The project supported by the Natural Science Foundation of Zhejiang Province of China under Grant No. Y604106, the Foundation of ＂New Century 151 Talent Engineering＂ of Zhejiang Province, and the Key Academic Discipline Foundation of Zhejiang Province .The authors would like to thank Profs. J.F. Zhang, L.Q. Chen, and J.P. Fang for their fruitful discussions.
文摘Using a special Painleve-Baecklund transformation as well as the extended mapping approach and the linear superposition theorem, we obtain new families of variable separation solutions to the （2＋1）-dimensional generalized Broer-Kaup （GBK） system. Based on the derived exact solution, we reveal some novel evolutional behaviors of localized excitations, i.e. fission and fusion phenomena in the （2＋1）-dimensional GBK system.
文摘In this letter, by means of the Lax pair, Darboux transformation, and variable separation approach, a new exact solution of a sixth-order (1+ 1)-dimensional nonlinear evolution equation, which includes some arbitrary functions,is obtained. Abundant new localized excitations can be found by selecting appropriate functions and they are illustrated both analytically and graphically.
基金Supported by the Natural Science Foundation of Guangdong Province under Grant No. 1015283001000000,Chinasupported by the NPRP 09-462-1-074 project with the Qatar National Research Foundation
文摘We report on the localized spatial soliton excitations in the multidimensional nonlinear Schrodinger equation with radially variable nonlinearity coefficient and an external potential. By using Hirota＇s binary differential operators, we determine a variety of external potentials and nonlinearity coefficients that can support nonlinear localized solutions of different but desired forms. For some specific external potentials and nonlinearity coefficients, we discuss features of the corresponding （2＋1）-dimensional multisolitonic solutions, including ring solitons, lump solitons, and soliton clusters.
基金supported by the National Natural Science Foundation of China(No.22273038 and No.22033004).
文摘Electronic circular dichroism(ECD)spectrum is an important tool for as-sessing molecular chirality.Tradition-al methods,like linear response time-dependent density functional theory(LR-TDDFT),predict ECD spectra well for small or medium-sized molecules,but struggle with large sys-tems due to high computational costs,making it a significant challenge to ac-curately and efficiently predict the ECD properties of complex systems.Within the framework of the generalized energy-based fragmentation(GEBF)method for localized excited states(ESs)calculation,we propose a combination algorithm for calculating rotatory strengths of ESs in condensed phase systems.This algorithm estimates the rotatory strength of the total system by calculating and combin-ing the transition electric and magnetic dipole moments of subsystems.We have used the GEBF method to calculate the ECD properties of chiral drug molecule derivatives,green fluo-rescent protein,and cyclodextrin derivatives,and compared their results with traditional methods or experimental data.The results show that this method can efficiently and accu-rately predict the ECD spectra of these systems.Thus,the GEBF method for ECD spectra demonstrates great potential in the chiral analysis of complex systems and chiral material design,promising to become a powerful theoretical tool in chiral chemistry.
基金supported by the National Natural Science Foundation of China(Nos.T2441002 and 22175186)。
文摘A pair of asymmetric rigid carbazole-benzonitrile-based emitters were synthesized by strategically alternating donor and acceptor groups along the molecular edges.The spin-flip process is accelerated by both the formation of localized and delocalized charge transfer states due to linearly positioned donors and strong spin-orbital coupling between different excitation feature of the lowest singlet and triplet excited states.This molecular architecture results in a remarkable short delayed lifespan of around 100 ns.The application of the two emitters in organic light-emitting diodes(OLEDs)achieves the highest external quantum efficiencies of 13.0%for the green emitter and 9.1%for the sky-blue emitter.Impressively,these devices maintain their high efficiency even at high luminance levels.The sustained efficiency is ascribed to the effective suppression of exciton quenching by substantially shortening delayed lifespan.These findings underscore the practical utility of the molecular design strategy that incorporates alternate donor and acceptor groups at the molecular periphery for shortening delayed fluorescence lifetime,and hold great promise for the development of high-performance OLEDs.
文摘A wire rope defects detection method based on permanent magnet excitation is proposed.A detection system,mainly composed of permanent magnet excitation,distance detection,multi-sensor magnetic flux leakage signal acquisition and data analysis device,is set up.According to the different characteristics of the multi-sensor magnetic flux leakage signal,the localized fault(LF)and loss of metallic cross-sectional area(LMA)signal is separated,and then the two defects can be detected.The experiments show that the method can effectively detect the two defects when they appear simultaneously on the wire rope.
文摘With the help of an extended mapping approach, a new type of variable separation excitation with three arbitrary functions of the (2+1)-dimensional dispersive long-water wave system (DLW) is derived. Based on the derived variable separation excitation, abundant non-propagating solitons such as dromion, ring, peakon, and compacton etc.are revealed by selecting appropriate functions in this paper.
文摘By means of the variable separation method, new exact solutions of some （1 ＋ 1）-dimensionaJ nonlinear evolution equations are obtained. Abundant localized excitations can be found by selecting corresponding arbitrary functions appropriately. Namely, the new soliton-like localized excitations and instanton-like localized excitations are presented.
基金the Natural Science Foundation of Zhejiang Province under Grant Nos. Y604106 and Y606181the Foundation of New Century "151 Talent Engineering" of Zhejiang Province+1 种基金the Scientific Research Foundation of Key Discipline of Zhejiang Provincethe Natural Science Foundation of Zhejiang Lishui University under Grant No. KZ06002
文摘With the help of an objective reduction approach （ORA）, abundant exact solutions of （2＋1）-dimensional higher-order Boussinesq system （including some hyperboloid function solutions, trigonometric function solutions, and a rational function solution） are obtained. It is shown that some novel soliton structures, like single linearity soliton structure, breath soliton structure, single linearity y-periodic solitary wave structure, libration dromion structure, and kink-like multisoliton structure with actual physical meaning exist in the （2＋1）-dimensional higher-order Boussinesq system.
基金Project supported by the National Natural Science Foundation of China （Grant No 10272071） and the Key Assisted Academic Discipline of Zhejiang Province （Grant No 200337）.
文摘By means of a Painlevé-Baicklund transformation and a multi-linear separation-of-variable approach, abundant localized coherent excitations of a modified Broer-Kaup system are derived. There appear possible phase shifts for the interactions of the （2＋1）-dimensional novel localized structures, which are discussed in this paper.
文摘Using an extended projective method, a new type of variable separation solution with two arbitrary functions of the (2+1)-dimensional generalized Broer-Kaup system (GBK) is derived. Based on the derived variable separation solution, some special localized coherent soliton excitations with or without elastic behaviors such as dromions, peakons,and foldons etc. are revealed by selecting appropriate functions in this paper.
基金The project supported by the Natural Science Foundation of Zhejiang Province under Grant No.Y604106the Natural Science Foundation of Zhejiang Lishui University under Grant Nos.FC06001 and QN06009
文摘By means of an extended mapping approach and a linear variable separation approach, a new family of exact solutions of the （3＋1）-dimensional Jimbo-Miwa system is derived. Based on the derived solitary wave solution, we obtain some special localized excitations and study the interactions between two solitary waves of the system.
基金Foundation item： Supported by the National Natural Science Foundation of China（10647112, 10871040） Acknowledgement The authors are in debt to thank the helpful discussions with Prof Qin and Dr A P Deng.
文摘A class of new doubly periodic wave solutions for （2＋1）-dimensional KdV equation are obtained by introducing appropriate Jacobi elliptic functions and Weierstrass elliptic functions in the general solution（contains two arbitrary functions） got by means of multilinear variable separation approach for （2＋1）-dimensional KdV equation. Limiting cases are considered and some localized excitations are derived, such as dromion, multidromions, dromion-antidromion, multidromions-antidromions, and so on. Some solutions of the dromion-antidromion and multidromions-antidromions are periodic in one direction but localized in the other direction. The interaction properties of these solutions, which are numerically studied, reveal that some of them are nonelastic and some are completely elastic. Furthermore, these results are visualized.
基金The authors would like to thank Profs. Jie-Fang Zhang and Chun-Long Zheng for helpful discussions.
文摘Extended mapping approach is introduced to solve （2＋1）-dimensional Nizhnik-Novikov Veselov equation. A new type of variable separation solutions is derived with arbitrary functions in the model. Based on this excitation, rich localized structures such as multi-lump soliton and ring soliton are revealed by selecting the arbitrary function appropriately.
文摘Spectral and photophysical investigations of 4＇-（p-aminophenyl）-2,2＇：6＇,2″-terpyridine （APT） have been performed in various solvents with different polarity and hydrogen-bonding ability. The emission spectra of APT are found to exhibit dual fluorescence in polar solvents, which attributes to the local excited and intramolecular charge transfer states, respectively. The two-state model is proven out for APT in polar solvent by the time-correlated single photon counting emission decay measurement. Interestingly, the linear relationships of different emission maxima and solvent polarity parameter are found for APT in protic and aprotic solvents, because of the hydrogen bond formation between APT and alcohols at the amino nitrogen N25. Furthermore, the effects of the complexation of the metal ion with tpy group of APT and the hydrogen bond formation between APT with methanol at the terpyridine nitrogen N4-NS-N14 are also presented. The appearance of new long-wave absorption and fluorescence bands indicates that a new ground state of the complexes is formed.
基金supported by National Natural Science Foundation of China(No.21372168)
文摘The development of fluorescent materials capable of harvesting triplet excitons efficiently is of great importance in achieving high-performance low-cost organic light-emitting diodes（OLEDs）.Among the three mechanisms converting triplet to singlet excitons,triplet fusion delayed fluorescence（TFDF） plays a key role in the demonstration of highly efficient and reliable OLEDs,especially blue devices,for practice applications.This review focuses on the recent development of TFDF materials and their applications in OLEDs.Fundamental TFDF mechanism,molecular design principles,and the structure-property relationship of TFDF materials with a particular emphasis on their different excited state characters,are presented and discussed.Moreover,the future perspectives and ongoing challenges of TFDF materials are also highlighted.
