A series of new Co–Ln heterometallic clusters formulated as[Co_(2)Ln_(4)(μ_(3)-OH)_(2)(piv)_(4)(hmmp)_(4)(ae)_(2)]·(NO_(3))_(2)·2H_(2)O(Ln=Eu(1),Gd(2),Tb(3),Dy(4),H2hmmp=2-[(2-hydroxyethylimino)methyl]-6-m...A series of new Co–Ln heterometallic clusters formulated as[Co_(2)Ln_(4)(μ_(3)-OH)_(2)(piv)_(4)(hmmp)_(4)(ae)_(2)]·(NO_(3))_(2)·2H_(2)O(Ln=Eu(1),Gd(2),Tb(3),Dy(4),H2hmmp=2-[(2-hydroxyethylimino)methyl]-6-methoxyphenol,Hae=2-aminoethanol,Hpiv=pivalic acid)were synthesized and characterized.展开更多
基金the National Basic Research Program of China(973 program,2012CB821702)the National Natural Science Foundation of China(21233009 and 21173221)the State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences for financial support.
文摘A series of new Co–Ln heterometallic clusters formulated as[Co_(2)Ln_(4)(μ_(3)-OH)_(2)(piv)_(4)(hmmp)_(4)(ae)_(2)]·(NO_(3))_(2)·2H_(2)O(Ln=Eu(1),Gd(2),Tb(3),Dy(4),H2hmmp=2-[(2-hydroxyethylimino)methyl]-6-methoxyphenol,Hae=2-aminoethanol,Hpiv=pivalic acid)were synthesized and characterized.
