Chemical delithiated LixCoO2 （x=1, 0.7, 0.66 and 0.57） has been synthesized by using a strong oxidant, NaS2O8 .The structure investigations indicate that all the samples remain with hexagonal cells, which have expan...Chemical delithiated LixCoO2 （x=1, 0.7, 0.66 and 0.57） has been synthesized by using a strong oxidant, NaS2O8 .The structure investigations indicate that all the samples remain with hexagonal cells, which have expansion of c axis during Li extraction. Transmission electron microscopy （TEM） observations revealed the presence of superstructures arising from intercalated U-ordering corresponding to first-principle calculations. The measurements of the physical properties are also influenced by Li concentration.展开更多
文摘Chemical delithiated LixCoO2 （x=1, 0.7, 0.66 and 0.57） has been synthesized by using a strong oxidant, NaS2O8 .The structure investigations indicate that all the samples remain with hexagonal cells, which have expansion of c axis during Li extraction. Transmission electron microscopy （TEM） observations revealed the presence of superstructures arising from intercalated U-ordering corresponding to first-principle calculations. The measurements of the physical properties are also influenced by Li concentration.
