The opening, subduction and final closure of the Paleo-Asian Ocean led to the formation of the Central Asian Orogenic Belt. Controversy has long surrounded the timing of final closure of the Paleo-Asian Ocean. Here we...The opening, subduction and final closure of the Paleo-Asian Ocean led to the formation of the Central Asian Orogenic Belt. Controversy has long surrounded the timing of final closure of the Paleo-Asian Ocean. Here we present zircon U-Pb ages and petrological, geochemical and in situ Hf isotope data for the Xierzi biotite monzogranite pluton, Linxi, SE Inner Mongolia. U-Pb dating of zircon by LA-ICP-MS yields a middle Permian emplacement age(268.7 ± 2.3 Ma) for the Xierzi pluton that is dominated by biotite monzogranites with high SiO_2(71.2-72.8 wt.%),alkali(Na_2 O + K_2 O =8.05-8.44 wt.%), Al_2 O_3(14.4-15.2 wt.%) and Fe_2 O_3~T relative to low MgO contents, yielding Fe_2 O_3~T/MgO ratios of 2.87-3.44, and plotting within the high-K calc-alkaline field on a SiO_2 vs. K_2 O diagram. The aluminum saturation indexes(A/CNK) of the biotite monzogranites range from 1.06 to 1.19, corresponding to weakly to strongly peraluminous. They are enriched in rare earth elements(REE), high field strength elements(HFSEs; Zr,Hf). and large ion lithophile elements(LILEs; Rb, U, Th). The LREEs are enriched relative to the HREEs,with a distinct negative Eu anomaly in a chondrite-normalized REE diagram. Geochemically, the Xierzi biotite monzogranite is classified as an aluminous A-type granite, with all samples plotting within the A2-type granite field on a Y/Nb vs. Rb/Nb diagram. Zircon ε_(Hf)(t) values and two-stage modal ages of the zircons within the pluton range from +4.80 to +13.65 and from 983 to 418 Ma, respectively, indicating that the primary magma was generated through partial melting of felsic rocks from juvenile crust.Consequently, these results demonstrate that the Xierzi pluton formed under the post-orogenic extensional setting after arc-continent collision in the middle Permian.展开更多
The Linxi Formation occupies an extensive area in the eastern Inner Mongolia in the Central Asian Orogenic Belt （CAOB）. The Linxi Formation is composed of slate, siltstone, sandstone and plant, lamellibranch microfo...The Linxi Formation occupies an extensive area in the eastern Inner Mongolia in the Central Asian Orogenic Belt （CAOB）. The Linxi Formation is composed of slate, siltstone, sandstone and plant, lamellibranch microfossils in the associated strata. Major and trace element data （including REE） for sandstones from the formation indicate that these rocks have a greywacke protolith and have been deposited during a strong tectonic activity. LA-ICPMS U-Pb dating of detrital zircons yield ages of 1801 to 238 Ma for four samples from the Linxi Formation. 425-585 Ma, together with the ~500 Ma age for the metamorphism event previously determined for Northeast China, indicates that their provenance is the metamorphic rocks of Pan-African age that have a tectonic affinity to NE China. A few older zircons with U-Pb ages at 1689-1801 Ma, 1307 1414 Ma, 593-978 Ma are also present, revealing the Neoproterozoic history of NE China. The youngest population shows a peak at ca. 252 Ma, suggesting that the main deposition of the Linxi Formation was at late Permain. Moreover, the ca. 250 Ma zircon grains of all four samples yield weighted mean ^206pb/^238U ages of 250 ± 3 Ma, 248 ± 3 Ma, 249 ± 3 Ma, and 250 ± 2 Ma, respectively. These ages, together with the youngest zircon age in the sample ZJB-28 （ca. 238 Ma）, suggest that the deposition of the Linxi Formation extended to the early Triassic. Combining with previous results, we suggest that the final collision of the Central Asian Orogenic Belt （CAOB） in the southern of Linxi Formation, which located in the Solonker-Xra Moron-Changchun suture, and the timing for final collision should be at early Triassic.展开更多
In order to explore the oil and gas resource prospects in the Carboniferous–Permian strata in northern Songliao Basin,geological survey boreholes(HFD 1 and HFD 2)were drilled in the area,and thick dark mudstone and s...In order to explore the oil and gas resource prospects in the Carboniferous–Permian strata in northern Songliao Basin,geological survey boreholes(HFD 1 and HFD 2)were drilled in the area,and thick dark mudstone and slate of the Upper Permian Linxi Formation were encountered.Source rock geochemistry analysis of the samples show that the organic matter abundance of the Upper Permian Linxi Formation source rock in the north of Songliao Basin is high,which belongs to medium to good source rock.The organic matter belongs to type Ⅱ,and it is in the evolution stage of highly mature to over mature.The Pr/Ph ratios of the source rocks range from 0.16 to 0.93,with an average of 0.53.The phytane predominance is obvious,and indicates a strong reduction to reduction sedimentary environment,which is conducive to the preservation of organic matter.Pr/nC_(17),Ph/nC_(18) and C_(27)–C_(28)–C_(29) regular steranes indicate that the organic matter was derived from a mixture of vascular plants and aquatic organisms such as algae,and is mainly contributed by phytoplankton.Through comprehensive analysis,it is considered that the source rocks of the Upper Permian Linxi Formation in northern Songliao Basin have entered the gas generation stage and have shale gas exploration prospects.展开更多
Objective Two important geological issues have long been controversial in the Xing-Meng area of North China. The first concerns the final closure of Paleo-Asian Ocean in Xing-Meng area, and the other concerns the fol...Objective Two important geological issues have long been controversial in the Xing-Meng area of North China. The first concerns the final closure of Paleo-Asian Ocean in Xing-Meng area, and the other concerns the folding and lifting of the Xing-Meng Trough. The focus of thses issues is the Late Permian sedimentary environment, which is generally considered to be either an exclusively continental environment or from the closed inland sea environment in the Early to Middle stage to continental lacustrine environment in the late stage. In recent years, we have successively discovered abundant typical marine fossils （e.g., bryozoans and calcareous algae） in the Upper Permian thick limestone layer from Linxi County and Ar Horqin Banner in eastern region of Inner Mongolia and Jiutain County in Jilin Province. These significant findings have attracted the attention from fellow academics.展开更多
Based on gas chromatography and gas chromatography mass spectrometry techniques, the authors researched biomarker characteristics of the Linxi Formation source rocks in the area of Taohaiyingzi, and analyzed the infor...Based on gas chromatography and gas chromatography mass spectrometry techniques, the authors researched biomarker characteristics of the Linxi Formation source rocks in the area of Taohaiyingzi, and analyzed the information and petroleum geological significance that were indicated by source of organic matter, sedimentary environment, maturity and so on. Gas chromatography peak of saturated hydrocarbons from Linxi Formation source rocks showed ‘‘the former peak'' of the single peak distribution and the C23-dominant main peak. This indicates that the main source of organic matter was mixed organic matter; Pr/Ph ratios ranged from 0.3 to 0.6, indicating a strongly reducing sedimentary environment.Molecular fossil assemblages in Linxi Formation source rocks were abundant in tricyclic terpane with long side chains, had high level of gammacerane, and showed dominant distribution of C27 steranes. Gammacerane ratios range from 0.15 to 0.29, with an average of 0.19, implying that Linxi Formation hydrocarbon source rocks were formed in the environment of micro-saltwater water to half-saltwater water. The hopanes/steranes ratios are mainly between 0.6 and 1.0, with an average of 0.84, implying that bacteria and algae had almost the samecontribution to organic matter. C27 steranes abundance is high and the ratio of C27steranes/C29 steranes is 1.13,showing that algae is the main source of hydrocarbon precursors.展开更多
基金financially supported by the 973 Program(Grant No.2013CB429802)the Natural Science Foundation of China(Grant Nos.41272223,41340024 and 41602209)
文摘The opening, subduction and final closure of the Paleo-Asian Ocean led to the formation of the Central Asian Orogenic Belt. Controversy has long surrounded the timing of final closure of the Paleo-Asian Ocean. Here we present zircon U-Pb ages and petrological, geochemical and in situ Hf isotope data for the Xierzi biotite monzogranite pluton, Linxi, SE Inner Mongolia. U-Pb dating of zircon by LA-ICP-MS yields a middle Permian emplacement age(268.7 ± 2.3 Ma) for the Xierzi pluton that is dominated by biotite monzogranites with high SiO_2(71.2-72.8 wt.%),alkali(Na_2 O + K_2 O =8.05-8.44 wt.%), Al_2 O_3(14.4-15.2 wt.%) and Fe_2 O_3~T relative to low MgO contents, yielding Fe_2 O_3~T/MgO ratios of 2.87-3.44, and plotting within the high-K calc-alkaline field on a SiO_2 vs. K_2 O diagram. The aluminum saturation indexes(A/CNK) of the biotite monzogranites range from 1.06 to 1.19, corresponding to weakly to strongly peraluminous. They are enriched in rare earth elements(REE), high field strength elements(HFSEs; Zr,Hf). and large ion lithophile elements(LILEs; Rb, U, Th). The LREEs are enriched relative to the HREEs,with a distinct negative Eu anomaly in a chondrite-normalized REE diagram. Geochemically, the Xierzi biotite monzogranite is classified as an aluminous A-type granite, with all samples plotting within the A2-type granite field on a Y/Nb vs. Rb/Nb diagram. Zircon ε_(Hf)(t) values and two-stage modal ages of the zircons within the pluton range from +4.80 to +13.65 and from 983 to 418 Ma, respectively, indicating that the primary magma was generated through partial melting of felsic rocks from juvenile crust.Consequently, these results demonstrate that the Xierzi pluton formed under the post-orogenic extensional setting after arc-continent collision in the middle Permian.
基金funded by grants from the Chinese Ministry of Science and Technology(Grant No.2013CB429802)National Natural Science Foundation of China(Grant Nos.41390441,41190075, and 41272241)the Chinese Geological Survey(Grant No. 1212011120153)
文摘The Linxi Formation occupies an extensive area in the eastern Inner Mongolia in the Central Asian Orogenic Belt （CAOB）. The Linxi Formation is composed of slate, siltstone, sandstone and plant, lamellibranch microfossils in the associated strata. Major and trace element data （including REE） for sandstones from the formation indicate that these rocks have a greywacke protolith and have been deposited during a strong tectonic activity. LA-ICPMS U-Pb dating of detrital zircons yield ages of 1801 to 238 Ma for four samples from the Linxi Formation. 425-585 Ma, together with the ~500 Ma age for the metamorphism event previously determined for Northeast China, indicates that their provenance is the metamorphic rocks of Pan-African age that have a tectonic affinity to NE China. A few older zircons with U-Pb ages at 1689-1801 Ma, 1307 1414 Ma, 593-978 Ma are also present, revealing the Neoproterozoic history of NE China. The youngest population shows a peak at ca. 252 Ma, suggesting that the main deposition of the Linxi Formation was at late Permain. Moreover, the ca. 250 Ma zircon grains of all four samples yield weighted mean ^206pb/^238U ages of 250 ± 3 Ma, 248 ± 3 Ma, 249 ± 3 Ma, and 250 ± 2 Ma, respectively. These ages, together with the youngest zircon age in the sample ZJB-28 （ca. 238 Ma）, suggest that the deposition of the Linxi Formation extended to the early Triassic. Combining with previous results, we suggest that the final collision of the Central Asian Orogenic Belt （CAOB） in the southern of Linxi Formation, which located in the Solonker-Xra Moron-Changchun suture, and the timing for final collision should be at early Triassic.
基金Supported by the National Key Research and Development Program of China(No.2019YFC0605404)China Geological Survey Project(Nos.DD20221664 and DD20190097)。
文摘In order to explore the oil and gas resource prospects in the Carboniferous–Permian strata in northern Songliao Basin,geological survey boreholes(HFD 1 and HFD 2)were drilled in the area,and thick dark mudstone and slate of the Upper Permian Linxi Formation were encountered.Source rock geochemistry analysis of the samples show that the organic matter abundance of the Upper Permian Linxi Formation source rock in the north of Songliao Basin is high,which belongs to medium to good source rock.The organic matter belongs to type Ⅱ,and it is in the evolution stage of highly mature to over mature.The Pr/Ph ratios of the source rocks range from 0.16 to 0.93,with an average of 0.53.The phytane predominance is obvious,and indicates a strong reduction to reduction sedimentary environment,which is conducive to the preservation of organic matter.Pr/nC_(17),Ph/nC_(18) and C_(27)–C_(28)–C_(29) regular steranes indicate that the organic matter was derived from a mixture of vascular plants and aquatic organisms such as algae,and is mainly contributed by phytoplankton.Through comprehensive analysis,it is considered that the source rocks of the Upper Permian Linxi Formation in northern Songliao Basin have entered the gas generation stage and have shale gas exploration prospects.
基金financially supported by the National Natural Science Foundation of China (grant No.41572098)the geological survey project (grants No.121201103000161114 and 121201103000150019 ) of the China Geological Survey
文摘Objective Two important geological issues have long been controversial in the Xing-Meng area of North China. The first concerns the final closure of Paleo-Asian Ocean in Xing-Meng area, and the other concerns the folding and lifting of the Xing-Meng Trough. The focus of thses issues is the Late Permian sedimentary environment, which is generally considered to be either an exclusively continental environment or from the closed inland sea environment in the Early to Middle stage to continental lacustrine environment in the late stage. In recent years, we have successively discovered abundant typical marine fossils （e.g., bryozoans and calcareous algae） in the Upper Permian thick limestone layer from Linxi County and Ar Horqin Banner in eastern region of Inner Mongolia and Jiutain County in Jilin Province. These significant findings have attracted the attention from fellow academics.
文摘Based on gas chromatography and gas chromatography mass spectrometry techniques, the authors researched biomarker characteristics of the Linxi Formation source rocks in the area of Taohaiyingzi, and analyzed the information and petroleum geological significance that were indicated by source of organic matter, sedimentary environment, maturity and so on. Gas chromatography peak of saturated hydrocarbons from Linxi Formation source rocks showed ‘‘the former peak'' of the single peak distribution and the C23-dominant main peak. This indicates that the main source of organic matter was mixed organic matter; Pr/Ph ratios ranged from 0.3 to 0.6, indicating a strongly reducing sedimentary environment.Molecular fossil assemblages in Linxi Formation source rocks were abundant in tricyclic terpane with long side chains, had high level of gammacerane, and showed dominant distribution of C27 steranes. Gammacerane ratios range from 0.15 to 0.29, with an average of 0.19, implying that Linxi Formation hydrocarbon source rocks were formed in the environment of micro-saltwater water to half-saltwater water. The hopanes/steranes ratios are mainly between 0.6 and 1.0, with an average of 0.84, implying that bacteria and algae had almost the samecontribution to organic matter. C27 steranes abundance is high and the ratio of C27steranes/C29 steranes is 1.13,showing that algae is the main source of hydrocarbon precursors.
