Heat transport in one kind of double-bond linear chains of fullerenes （C60＇s） is investigated by the classical nonequilibrium molecular dynamics method. It is found that the negative differential thermal resistance...Heat transport in one kind of double-bond linear chains of fullerenes （C60＇s） is investigated by the classical nonequilibrium molecular dynamics method. It is found that the negative differential thermal resistance （NDTR） is more likely to occur at larger temperature difference and shorter length. In addition, with the increase of the length, the thermal conductivity of the chains increases, and NDTR region shrinks and vanishes in the end. The temperature profiles reveal that a large temperature jump exists at a high-temperature boundary of the chains when NDTR occurs. These results may be helpful for designing thermal devices where low-dimensional C60 polymers can be used.展开更多
Using Lindblad approach to study decoherence of quantum systems, we study the decoherence and decay of entangled states, formed by two basic states of a chain of thee qubits. We look on these states for a possible reg...Using Lindblad approach to study decoherence of quantum systems, we study the decoherence and decay of entangled states, formed by two basic states of a chain of thee qubits. We look on these states for a possible regular dependence on their decay as a function of their energy separation between the basic states under different types of environments. We didn’t find regular or significant dependence on this energy separation for the type of environment considered.展开更多
The linear-chain structure in which three alpha particles are arranged in a straight line was initially proposed by H.Morinaga[1]as the structure of the Hoyle state of carbon-12[2].This unique idea attracted much atte...The linear-chain structure in which three alpha particles are arranged in a straight line was initially proposed by H.Morinaga[1]as the structure of the Hoyle state of carbon-12[2].This unique idea attracted much attention,but it was rejected because it could not explain the lifetime of the Hoyle state.Half a century later,the concept of the linear chain structure was revived in the physics of unstable nuclei,and experimental and theoretical research have demonstrated that this structure exists in carbon-14 and 16.The authors have conducted internationally recognized experimental research on the linear-chain structure of carbon-14 and carbon-16.展开更多
Carbon materials have long been a subject of study, offering diverse properties based on their hybridized structures. Except sp^(2)-hybridized graphene and carbon nanotubes, the focus on sp^(1)-hybridized carbon chain...Carbon materials have long been a subject of study, offering diverse properties based on their hybridized structures. Except sp^(2)-hybridized graphene and carbon nanotubes, the focus on sp^(1)-hybridized carbon chains has garnered significant interest due to its unique predicted properties, despite limitations in research and development stemming from its high reactivity. This comprehensive review summaries recent advancements in synthetic methodologies and characterization of the sp^(1)-hybridized carbon chains, encompassing linear carbon chains and cyclo[n]carbons. The review traces significant milestones in synthesis and offers a thorough overview of various properties on linear and cyclic carbon chains, from their initial discovery to recent development. The advancing synthetic methods have led to practical breakthroughs, transitioning theoretical concepts into tangible carbon-chain materials. However, challenges persist in achieving controlled and scalable preparation due to the high reactivity associated with sp^(1)-hybridization. Future research prospects focus on fundamental studies, such as exploring the transition length from polyyne to carbyne and experimentally determining the properties of single carbon chains.This review underscores both the progress made and the compelling avenues for future exploration in the dynamic field of sp^(1)-hybridized carbon chains.展开更多
Linear carbon chains(LCCs)are a one-dimensional sp1-hybridized allo trope of ca rbon.LCCs are extre mely unstable:The longer the LCCs,the less stable the materials.Thus,it is a big challenge to synthesize long LCCs.Al...Linear carbon chains(LCCs)are a one-dimensional sp1-hybridized allo trope of ca rbon.LCCs are extre mely unstable:The longer the LCCs,the less stable the materials.Thus,it is a big challenge to synthesize long LCCs.Although the research on the short LCCs,e.g.,polyynes,can be traced back to the 18th,LCCs are still not well-known compared to other allotropes of carbon,e.g.,fullerenes,carbon nanotubes and graphene.Therefore,introducing recent progress on LCCs is of great significance to draw more attention in the community of nanocarbons as well as nanomaterials in general.Theoretically,various excellent properties have been predicted.Experimentally,LCCs with different length in many kinds of forms have been successfully synthesized.In this review,we summarized recent studies of polyynic LCCs from both theoretical and experimental aspects.Also,perspectives are highlighted to point out the further investigations of the materials.展开更多
The stability of the linear chain structure of three α clusters for 12C against the bending and fission is investigated in the cranking covariant density functional theory, in which the equation of motion is solved o...The stability of the linear chain structure of three α clusters for 12C against the bending and fission is investigated in the cranking covariant density functional theory, in which the equation of motion is solved on a 3D lattice with the inverse Hamiltonian and the Fourier spectral methods. Starting from a twisted three α initial configuration, it is found that the linear chain structure is stable when the rotational frequency is within the range of ~2.0-~2.5 MeV. Beyond this range, the final states are not stable against fission. By examining the density distributions and the occupation of single-particle levels, however, these fissions are found to arise from the occupation of unphysical continuum with large angular momenta. To properly remove these unphysical continuum, a damping function for the cranking term is introduced. Eventually, the stable linear chain structure could survive up to the rotational frequency ~3.5 MeV, but the fission still occurs when the rotational frequency approaches ~4.0 MeV.展开更多
The plastification modification of poly （vinyl chloride） （PVC） with the long-chain linear polyester （LP） synthesized by linear dodecanedioic acid （DC12） or tetradecanedioic acid （DC14） with different diols i...The plastification modification of poly （vinyl chloride） （PVC） with the long-chain linear polyester （LP） synthesized by linear dodecanedioic acid （DC12） or tetradecanedioic acid （DC14） with different diols is investigated. The processing characteristics, mechanical properties and extraction property of the PVC/LP blends in different solvents （xylene, cyclohexane, ethanol） were also studied in detail. All results were compared with that of the PVC plasticized with dioctyl phthalate （DOP）. The results show that the molecular weight, molecular structure and loading of LP greatly influence the mechanical properties of the PVC/LP blends. The processability and the mechanical properties of PVC plasticized by LP are comparable to those of the corresponding PVC/DOP blends. However, the PVC/LP blends posses much better migration resistance property than the corresponding PVC/DOP blends, which makes the long-chain linear polyester become a very good plasticizer candidate for PVC industry.展开更多
Linear carbon chains as new one-dimensional(1D)nanomaterials attract attention for the predicted outstanding properties.However,the high reactivity of linear carbon chains hampers further experimental research.To date...Linear carbon chains as new one-dimensional(1D)nanomaterials attract attention for the predicted outstanding properties.However,the high reactivity of linear carbon chains hampers further experimental research.To date,different methods have been developed to synthesize new materials containing linear carbon chains.Among them,the arc-discharge method is a practical way to prepare both finite and infinite linear carbon chains.This review provides a brief discussion of the recent progress in the techniques to prepare carbon chain-based materials and then focuses on the arc-discharge method.The configuration of apparatus,optimal conditions,and the corresponding mechanism of arc-discharge method to prepare long linear carbon chain inside multi-walled carbon nanotubes are summarized in detail.The characterization techniques are introduced to evaluate the quality of products.Moreover,remaining challenges and perspectives are presented for further investigation of long linear carbon chains.展开更多
The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 ...The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr = 438. 01, and the convergence factors R = 0. 045, Rw =0. 055 for 341 observed reflections (I>3σ(I)). The anion structure can be viewed as apolymeric single chain consisting of unlimited extended rhombic fragruents of -AgS2W-which are alternately perpendicular to each other. Additionally, influence of di- and tri-valent complex cations on the assembIy of WS2-4 and Ag+ is briefly discussed.展开更多
With respect to different risk preference of an agent in a supply chain, linear-contract models are designed according to the principal-agent theory. The study shows that the risk preference of an agent directly corre...With respect to different risk preference of an agent in a supply chain, linear-contract models are designed according to the principal-agent theory. The study shows that the risk preference of an agent directly correlates with the incentive compensation coefficient of principal, order quantity of principal and production capability level of the agent. The principal should offer an appropriate incentive contract according to the risk preference of the agent, or choose an agent holding a different risk preference to establish the supply chain.展开更多
A new inelastic excitation and cluster-decay experiment was conducted to investigate the negative-parity linear-chain structure in 16C.The helium and beryllium isotopes emitted from the highly excited states of 16C an...A new inelastic excitation and cluster-decay experiment was conducted to investigate the negative-parity linear-chain structure in 16C.The helium and beryllium isotopes emitted from the highly excited states of 16C and the recoil target deuteron were detected in coincidence.The 16C excitation-energy spectra associated with different decay paths were reconstructed using the invariant mass method.Owing to the newly reconfigured detector setup,the detection acceptance was extended to a higher excitation-energy range,allowing a number of new resonant states to be observed beyond the previously reportedπ^(2)σ^(2)-bond positive-parity linear-chain band.Based on comparison with the AMD calculations for both resonance energies and relative decay widths,these newly observed states can be tentatively assigned as the 1^(-),3^(-),5^(-)and 1^(-)members of the negative-parity linear-chain molecular rotational band.More experimental studies are expected to directly measure the spins of these states.展开更多
Two new complexes, [W2Ag2S8?Ca(DMF)6]n 1 and [WAgS4?Na(DMF)3]n 2, have been synthesized and characterized. Single-crystal X-ray analyses show both 1 and 2 have {WAgS4}n anion linear chains, but 1 has a discrete [Ca(DM...Two new complexes, [W2Ag2S8?Ca(DMF)6]n 1 and [WAgS4?Na(DMF)3]n 2, have been synthesized and characterized. Single-crystal X-ray analyses show both 1 and 2 have {WAgS4}n anion linear chains, but 1 has a discrete [Ca(DMF)6]2+ cation while 2 is a linear chain. UV-Visible-Near-IR spectroscopy data show that the bandgaps of the two complexes are 1.86 and 1.99 eV, respectively. Electrical conductivity measurements reveal the conductivities of 1 and 2 are 10?7 and 10?8 Scm?1, respectively and they exhibit thermally activated temperature depen- dence, which may be attributed to semiconductors.展开更多
The syntheses and structures of eleven novel polymeric transition metal complexes having one dimensional chain structures or three dimensional networks are summarized. They are prepared from the controlled assemblin...The syntheses and structures of eleven novel polymeric transition metal complexes having one dimensional chain structures or three dimensional networks are summarized. They are prepared from the controlled assembling reactions in organic solvents and characterized by X ray diffraction analyses. The spectroscopic or magnetic properties of some complexes are studied.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 11004082 and 11005048the Natural Science Foundation of Guangdong Province under Grant No 2014A030313367
文摘Heat transport in one kind of double-bond linear chains of fullerenes （C60＇s） is investigated by the classical nonequilibrium molecular dynamics method. It is found that the negative differential thermal resistance （NDTR） is more likely to occur at larger temperature difference and shorter length. In addition, with the increase of the length, the thermal conductivity of the chains increases, and NDTR region shrinks and vanishes in the end. The temperature profiles reveal that a large temperature jump exists at a high-temperature boundary of the chains when NDTR occurs. These results may be helpful for designing thermal devices where low-dimensional C60 polymers can be used.
文摘Using Lindblad approach to study decoherence of quantum systems, we study the decoherence and decay of entangled states, formed by two basic states of a chain of thee qubits. We look on these states for a possible regular dependence on their decay as a function of their energy separation between the basic states under different types of environments. We didn’t find regular or significant dependence on this energy separation for the type of environment considered.
文摘The linear-chain structure in which three alpha particles are arranged in a straight line was initially proposed by H.Morinaga[1]as the structure of the Hoyle state of carbon-12[2].This unique idea attracted much attention,but it was rejected because it could not explain the lifetime of the Hoyle state.Half a century later,the concept of the linear chain structure was revived in the physics of unstable nuclei,and experimental and theoretical research have demonstrated that this structure exists in carbon-14 and 16.The authors have conducted internationally recognized experimental research on the linear-chain structure of carbon-14 and carbon-16.
基金supported by National Natural Science Foundation of China (No. 52472059)Fundamental Research Funds for the Central Universities, Sun Yat-sen University (No. 22lgqb03)State Key Laboratory of Optoelectronic Materials and Technologies (No. OEMT-2022-ZRC-01)。
文摘Carbon materials have long been a subject of study, offering diverse properties based on their hybridized structures. Except sp^(2)-hybridized graphene and carbon nanotubes, the focus on sp^(1)-hybridized carbon chains has garnered significant interest due to its unique predicted properties, despite limitations in research and development stemming from its high reactivity. This comprehensive review summaries recent advancements in synthetic methodologies and characterization of the sp^(1)-hybridized carbon chains, encompassing linear carbon chains and cyclo[n]carbons. The review traces significant milestones in synthesis and offers a thorough overview of various properties on linear and cyclic carbon chains, from their initial discovery to recent development. The advancing synthetic methods have led to practical breakthroughs, transitioning theoretical concepts into tangible carbon-chain materials. However, challenges persist in achieving controlled and scalable preparation due to the high reactivity associated with sp^(1)-hybridization. Future research prospects focus on fundamental studies, such as exploring the transition length from polyyne to carbyne and experimentally determining the properties of single carbon chains.This review underscores both the progress made and the compelling avenues for future exploration in the dynamic field of sp^(1)-hybridized carbon chains.
基金the National Natural Science Foundation of China(No.51902353)the Natural ScienceFoundation of Guangdong Province(No.2019A1515011227)the Sun Yat-sen University(Nos.29000-18841218,2900031610028)。
文摘Linear carbon chains(LCCs)are a one-dimensional sp1-hybridized allo trope of ca rbon.LCCs are extre mely unstable:The longer the LCCs,the less stable the materials.Thus,it is a big challenge to synthesize long LCCs.Although the research on the short LCCs,e.g.,polyynes,can be traced back to the 18th,LCCs are still not well-known compared to other allotropes of carbon,e.g.,fullerenes,carbon nanotubes and graphene.Therefore,introducing recent progress on LCCs is of great significance to draw more attention in the community of nanocarbons as well as nanomaterials in general.Theoretically,various excellent properties have been predicted.Experimentally,LCCs with different length in many kinds of forms have been successfully synthesized.In this review,we summarized recent studies of polyynic LCCs from both theoretical and experimental aspects.Also,perspectives are highlighted to point out the further investigations of the materials.
基金supported by the National Key R&D Program of China(Grant Nos.2018YFA0404400,and 2017YFE0116700)the National Natural Science Foundation of China(Grant Nos.11621131001,and 11875075)the Laboratory Computing Resource Center at Argonne National Laboratory
文摘The stability of the linear chain structure of three α clusters for 12C against the bending and fission is investigated in the cranking covariant density functional theory, in which the equation of motion is solved on a 3D lattice with the inverse Hamiltonian and the Fourier spectral methods. Starting from a twisted three α initial configuration, it is found that the linear chain structure is stable when the rotational frequency is within the range of ~2.0-~2.5 MeV. Beyond this range, the final states are not stable against fission. By examining the density distributions and the occupation of single-particle levels, however, these fissions are found to arise from the occupation of unphysical continuum with large angular momenta. To properly remove these unphysical continuum, a damping function for the cranking term is introduced. Eventually, the stable linear chain structure could survive up to the rotational frequency ~3.5 MeV, but the fission still occurs when the rotational frequency approaches ~4.0 MeV.
基金the Engineering Developing Foundation of Tongji University
文摘The plastification modification of poly （vinyl chloride） （PVC） with the long-chain linear polyester （LP） synthesized by linear dodecanedioic acid （DC12） or tetradecanedioic acid （DC14） with different diols is investigated. The processing characteristics, mechanical properties and extraction property of the PVC/LP blends in different solvents （xylene, cyclohexane, ethanol） were also studied in detail. All results were compared with that of the PVC plasticized with dioctyl phthalate （DOP）. The results show that the molecular weight, molecular structure and loading of LP greatly influence the mechanical properties of the PVC/LP blends. The processability and the mechanical properties of PVC plasticized by LP are comparable to those of the corresponding PVC/DOP blends. However, the PVC/LP blends posses much better migration resistance property than the corresponding PVC/DOP blends, which makes the long-chain linear polyester become a very good plasticizer candidate for PVC industry.
基金Project supported by the Fund from the Huzhou Key Laboratory of Environmental Functional Materials and Pollution Control at Huzhou University
文摘Linear carbon chains as new one-dimensional(1D)nanomaterials attract attention for the predicted outstanding properties.However,the high reactivity of linear carbon chains hampers further experimental research.To date,different methods have been developed to synthesize new materials containing linear carbon chains.Among them,the arc-discharge method is a practical way to prepare both finite and infinite linear carbon chains.This review provides a brief discussion of the recent progress in the techniques to prepare carbon chain-based materials and then focuses on the arc-discharge method.The configuration of apparatus,optimal conditions,and the corresponding mechanism of arc-discharge method to prepare long linear carbon chain inside multi-walled carbon nanotubes are summarized in detail.The characterization techniques are introduced to evaluate the quality of products.Moreover,remaining challenges and perspectives are presented for further investigation of long linear carbon chains.
文摘The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr = 438. 01, and the convergence factors R = 0. 045, Rw =0. 055 for 341 observed reflections (I>3σ(I)). The anion structure can be viewed as apolymeric single chain consisting of unlimited extended rhombic fragruents of -AgS2W-which are alternately perpendicular to each other. Additionally, influence of di- and tri-valent complex cations on the assembIy of WS2-4 and Ag+ is briefly discussed.
基金The paper is supported by National Natural Science Foundation of China under Grant No60372085,60404011the Youth Foundation of Northwestern Polytechnical University
文摘With respect to different risk preference of an agent in a supply chain, linear-contract models are designed according to the principal-agent theory. The study shows that the risk preference of an agent directly correlates with the incentive compensation coefficient of principal, order quantity of principal and production capability level of the agent. The principal should offer an appropriate incentive contract according to the risk preference of the agent, or choose an agent holding a different risk preference to establish the supply chain.
基金Supported by the National Key R&D Program of China(2023YFA1606403,2023YFE0101600,2022YFA1605100)the National Natural Science Foundation of China(12350007,12275007,12027809)。
文摘A new inelastic excitation and cluster-decay experiment was conducted to investigate the negative-parity linear-chain structure in 16C.The helium and beryllium isotopes emitted from the highly excited states of 16C and the recoil target deuteron were detected in coincidence.The 16C excitation-energy spectra associated with different decay paths were reconstructed using the invariant mass method.Owing to the newly reconfigured detector setup,the detection acceptance was extended to a higher excitation-energy range,allowing a number of new resonant states to be observed beyond the previously reportedπ^(2)σ^(2)-bond positive-parity linear-chain band.Based on comparison with the AMD calculations for both resonance energies and relative decay widths,these newly observed states can be tentatively assigned as the 1^(-),3^(-),5^(-)and 1^(-)members of the negative-parity linear-chain molecular rotational band.More experimental studies are expected to directly measure the spins of these states.
基金This research was supported by the State Key Laboratory of Structural Chemistry, the National Science and Technology of China (001CB1089), the Chinese Academy of Sciences (CAS), the National Science Foundation of China (20273073, 20333070, 90206040)
文摘Two new complexes, [W2Ag2S8?Ca(DMF)6]n 1 and [WAgS4?Na(DMF)3]n 2, have been synthesized and characterized. Single-crystal X-ray analyses show both 1 and 2 have {WAgS4}n anion linear chains, but 1 has a discrete [Ca(DMF)6]2+ cation while 2 is a linear chain. UV-Visible-Near-IR spectroscopy data show that the bandgaps of the two complexes are 1.86 and 1.99 eV, respectively. Electrical conductivity measurements reveal the conductivities of 1 and 2 are 10?7 and 10?8 Scm?1, respectively and they exhibit thermally activated temperature depen- dence, which may be attributed to semiconductors.
文摘The syntheses and structures of eleven novel polymeric transition metal complexes having one dimensional chain structures or three dimensional networks are summarized. They are prepared from the controlled assembling reactions in organic solvents and characterized by X ray diffraction analyses. The spectroscopic or magnetic properties of some complexes are studied.
