The electrochemical behavior of Ce（III） was investigated in the molten LiF-BaF2 （81 mol.%-19 mol.%） on a molybdenum elec-trode in the temperature range of 1098-1188 K using cyclic voltammetry and chronopotentiomet...The electrochemical behavior of Ce（III） was investigated in the molten LiF-BaF2 （81 mol.%-19 mol.%） on a molybdenum elec-trode in the temperature range of 1098-1188 K using cyclic voltammetry and chronopotentiometry. It was observed that CeF3 could be re-duced into cerium metal in a reversible one-step process exchanging three electrons （Ce（III）＋3e-→Ce（0）） at the operating temperatures on a molybdenum cathode. The electrochemical reduction process was controlled by the diffusion of Ce（III） in the solution. The Ce（III） diffusion coefficients were calculated at different temperatures and the values obeyed the Arrhenius law with an activation energy of 87.5 kJ/mol.展开更多
基金Project supported by 863 Project of Ministry of Science and Technology of China (2009AA050702)
文摘The electrochemical behavior of Ce（III） was investigated in the molten LiF-BaF2 （81 mol.%-19 mol.%） on a molybdenum elec-trode in the temperature range of 1098-1188 K using cyclic voltammetry and chronopotentiometry. It was observed that CeF3 could be re-duced into cerium metal in a reversible one-step process exchanging three electrons （Ce（III）＋3e-→Ce（0）） at the operating temperatures on a molybdenum cathode. The electrochemical reduction process was controlled by the diffusion of Ce（III） in the solution. The Ce（III） diffusion coefficients were calculated at different temperatures and the values obeyed the Arrhenius law with an activation energy of 87.5 kJ/mol.
