Laser processing technologies enable the precise fabrication of arbitrary structures and devices with broad applications in micro-optics,micro-mechanics,and biomedicine.However,its adoption is limited by the large siz...Laser processing technologies enable the precise fabrication of arbitrary structures and devices with broad applications in micro-optics,micro-mechanics,and biomedicine.However,its adoption is limited by the large size,complexity,high cost,and low flexibility of optical systems.Metasurfaces enable precise multidimensional control of light fields,aligning well with the development trend toward compact,high-performance optical systems.Here,we review several recent studies on the application of metasurfaces in laser processing technologies,including 3D nanolithography,direct laser writing,and laser cutting.Metasurfaces provide an integrated operational platform with exceptional performance,poised to disrupt conventional laser processing workflows.This combination presents significant cost efficiency and substantial development potential,with promising applications in areas such as imaging,optical storage,advanced sensing,and space on-orbit manufacturing.展开更多
Graphene oxide,as a 2D material with nanometer thickness,offers ultra-high mobility,chaotic properties,and low cost.These make graphene oxide memristors beneficial for reservoir computing(RC)networks.In this study,con...Graphene oxide,as a 2D material with nanometer thickness,offers ultra-high mobility,chaotic properties,and low cost.These make graphene oxide memristors beneficial for reservoir computing(RC)networks.In this study,continuous-wave(CW)laser processing is used to reduce chaotic graphene oxide(CGO)films,resulting in the non-volatile storage capability based on the reduced chaotic graphene oxide(rCGO)films.Laser power significantly impacts the characteristics of the rCGO memristor.Material characterization indicates that laser radiation can effectively reduce the oxygen content in CGO films.With optimized laser power,the rCGO memristor achieves a large ratio at 18 mW laser power.Benefiting from the short-term mem-ory characteristics,distinct conductive states are achieved,which are further utilized to construct RC networks.With a third con-trol probe,the rCGO memristor can express rich reservoir states,demonstrating accuracy in predicting the Hénon map with an NRMSE below 0.3.These findings provide the potential for developing flexible RC networks based on graphene oxide memris-tors via laser processing.展开更多
The biological performance of Ti-6Al-4V implant is primarily determined by their surface properties.However,traditional surface modification methods,such as acid etching,hardly make improvement in their osseointegrati...The biological performance of Ti-6Al-4V implant is primarily determined by their surface properties.However,traditional surface modification methods,such as acid etching,hardly make improvement in their osseointegration ability and antibacterial capacity.In this study,we prepared a multi-scale composite structure coated with zinc oxide(ZnO)on Ti-6Al-4V implant by an innovative technology of two-step laser processing combined with solution-assistant.Compared with the acid etching method,the physicochemical properties of surface significantly improved.The in vitro results showed that the particular dimension of micro-nano structure and the multifaceted nature of ZnO synergistically affected MC3T3-E1 osteogenesis and bacterial activities:(1)The surface morphology showed a‘contact guidance'effect on cell arrangement,which was conducive to the adhesion of filopodia and cell spreading,and the osteogenesis level of MC3T3-E1 was enhanced due to the release of zinc ions(Zn^(2+));(2)the characterization of bacterial response revealed that periodic nanostructures and Zn^(2+)released could cause damage to the cell wall of E.coli and reduce the adhesion and aggregation of S.aureus.In conclusion,the modified surface showed a synergistic effect of physical topography and chemical composition,making this a promising method and providing new insight into bone defect repairment.展开更多
The model of heat source(MHS) which reflects the thermal interaction between materials and laser during processing determines the accuracy of simulation results. To acquire desirable simulations results, although vari...The model of heat source(MHS) which reflects the thermal interaction between materials and laser during processing determines the accuracy of simulation results. To acquire desirable simulations results, although various modifications of heat sources in the aspect of absorption process of laser by materials have been purposed, the distribution of laser power density(DLPD) in MHS is still modeled theoretically. However, in the actual situations of laser processing, the DLPD is definitely different from the ideal models. So, it is indispensable to build MHS using actual DLPD to improve the accuracy of simulation results. Besides, an automatic modeling method will be benefit to simplify the tedious pre-processing of simulations. This paper presents a modeling method and corresponding algorithm to model heat source using measured DLPD. This algorithm automatically processes original data to get modeling parameters and provides a step MHS combining with absorption models. Simulations and experiments of heat transfer in steel plates irradiated by laser prove the mothed and the step MHS. Moreover, the investigations of laser induced thermal-crack propagation in glass highlight the signification of modeling heat source based on actual DLPD and demonstrate the enormous application of this method in the simulation of laser processing.展开更多
We report the femtosecond(fs)laser fabrication of biomimetic omnidirectional iridescent metallic surfaces exhibiting efficient diffraction for practically any angle of light incidence.Such diffractive behavior is real...We report the femtosecond(fs)laser fabrication of biomimetic omnidirectional iridescent metallic surfaces exhibiting efficient diffraction for practically any angle of light incidence.Such diffractive behavior is realized by means of multi-directional low-spatial-frequency,laser-induced periodic surface structures(LSFL)formed upon exploiting the cylindrical symmetry of a cylindrical vector(CV)fs field.We particularly demonstrate that the multi-directional gratings formed on stainless steel surface by a radially polarized fs beam,could mimic the omnidirectional structural coloration properties found in some natural species.Accordingly,the fabricated grating structures can spatially disperse the incident light into individual wavelength with high efficiency,exhibiting structural iridescence at all viewing angles.Analytical calculations using the grating equation reproduced the characteristic variation of the vivid colors observed as a function of incident angle.We envisage that our results will significantly contribute to the development of new photonic and light sensing devices.展开更多
A new process for the fabrication of sharkskin bionic structures on metal surfaces is proposed.The sharkskin bionic surface was successfully machined on the surface of IN718 by laser sequencing of the abrasive belt su...A new process for the fabrication of sharkskin bionic structures on metal surfaces is proposed.The sharkskin bionic surface was successfully machined on the surface of IN718 by laser sequencing of the abrasive belt surface,laser processing of the layered scale-like structure,and ribbed texture grinding.The flexible contact properties of belt grinding allow ribbed structures to be machined uniformly on a hierarchical,scale-like microstructure.Sharkskin bionic microstructures with radii greater than 75µm were prepared after parameter optimisation.The influence of processing parameters on the geometrical accuracy of the microstructure was investigated,the microstructure microform and elemental distribution were analyzed,and the relationship between the ribbed microstructure and chemical properties of the surface of the bionic sharkskin on wettability was revealed.The results indicate that reducing the laser power and increasing the laser scan rate can reduce the laser thermal effect and improve the microstructure processing accuracy.The laser ablation process is accompanied by a violent chemical reaction that introduces a large amount of oxygen and carbon elements and infiltrates them at a certain depth.The wettability of the surface undergoes a transition from hydrophilic(contact angle 69.72°)to hydrophobic(contact angle 131.56°)due to the adsorption of C-C/C-H and the reduction of C=O/O=C-O during the placement process.The ribbed microstructure changes the solid-liquid contact on the surface into a solid-liquid-gas contact,which has an enhanced effect on hydrophobicity.This study is a valuable guide to the processing of hydrophobic layered bionic microstructures.展开更多
Indoor air quality(IAQ) directly affects the health of occupants. Household manufacturing equipment(HME) used for hobbies or educational purposes is a new and unexplored source of air pollution. In this study, we eval...Indoor air quality(IAQ) directly affects the health of occupants. Household manufacturing equipment(HME) used for hobbies or educational purposes is a new and unexplored source of air pollution. In this study, we evaluated the characteristics of particulate and gaseous pollutants produced by a household laser processing equipment(HLPE). Various target materials were tested using a commercial HLPE under various operating conditions of laser power and sheath air flow rate. The mode diameters of the emitted particles gradually decreased as laser power increased, while the particle number concentration(PNC) and particle emission rate(PER) increased. In addition, as the sheath air flow rate quadrupled from 10 to 40 L/min, the mode diameter of the emitted particles decreased by nearly 25%, but the effect on the PNC was insignificant. When the laser induced the target materials at 53 m W, the mode diameters of particles were < 150 nm, and PNCs were > 2.0 × 10^(4) particles/cm^(3). Particularly, analyses of sampled aerosols indicated that harmful substances such as sulfur and barium were present in particles emitted from leather. The carcinogenic gaseous pollutants such as acrylonitrile, acetaldehyde, 1,3-butadiene, benzene, and C 8 aromatics(ethylbenzene) were emitted from all target materials. In an actual indoor environment, the PNC of inhalable ultrafine particles(UFPs) was > 5 × 10^(4) particles/cm^(3) during 30 min of HLPE operation. Our results suggest that more meticulous control methods are needed, including the use of less harmful target materials along with filters or adsorbents that prevent emission of pollutants.展开更多
In this paper, we use femtosecond laser pulse to scribe 304 stainless steel foil, detect the Fourier transform infrared spectrum of the sample before and after processing, confirm the "cold processing" and &...In this paper, we use femtosecond laser pulse to scribe 304 stainless steel foil, detect the Fourier transform infrared spectrum of the sample before and after processing, confirm the "cold processing" and "thermal processing" and their mutual conversion, and determine the "cold processing" parameter window. The ablation threshold and incubation coefficient of 304 stainless steel foil are calculated, and the effects of scanning speed and effective pulse number on the ablation threshold are analyzed. The ANSYS software is used to simulate the radial and axial temperature distributions of the surface on 304 stainless steel foil sample and the heat-affected zone with a femtosecond laser fluence of 10 J/cm2 and an effective number of pulses of 1 200 are obtained. In the aspect of spectral detection, the Fourier transform infrared spectra of the sample before and after processing are measured and two processing mechanisms of "cold processing" and "hot processing" are confirmed, which proves that we can achieve the conversion between "cold processing" and "hot processing" by changing the laser fluence and determine the "cold processing" laser fluence range.展开更多
The first multi-function laser processing system in the domestic for clutch manufacture,with abilities of cutting, jointing and heat treatment,was reported in this paper.One external optical path,double laser heads,ad...The first multi-function laser processing system in the domestic for clutch manufacture,with abilities of cutting, jointing and heat treatment,was reported in this paper.One external optical path,double laser heads,adjust device by manual operation,automatically track were employed in this system Also the other parts of vehicles can be fabricated by this system,as well as clutches.The special processing to manufacture the clutches of heavy vehicles,which was developed by the project of this laser processing system,achieved the international standards and satisfied the economic development and nation defense in the do- mestic.展开更多
Able to precisely control and manipulate materials'states at micro/nano-scale level,femtosecond(fs)laser micro/nano processing technology has undergone tremendous development over the past three decades.Free-formi...Able to precisely control and manipulate materials'states at micro/nano-scale level,femtosecond(fs)laser micro/nano processing technology has undergone tremendous development over the past three decades.Free-forming three-dimensional(3D)microscale functional devices and inducing fascinating and unique physical or chemical phenomena have granted this technology powerful versatility that no other technology can match.As this technology advances rapidly in various fields of application,some key challenges have emerged and remain to be urgently addressed.This review firstly introduces the fundamental principles for understanding how fs laser pulses interact with materials and the associated unique phenomena in section 2.Then micro/nano-fabrication in transparent materials by fs laser processing is presented in section 3.Thereafter,several high efficiency/throughput fabrication methods as well as pulse-shaping techniques are listed in sections 4 and 5 reviews four-dimensional(4D)and nanoscale printing realized by fs laser processing technology.Special attention is paid to the heterogeneous integration(HI)of functional materials enabled by fs laser processing in section 6.Several intriguing examples of 3D functional micro-devices created by fs laser-based manufacturing methods such as microfluidics,lab-on-chip,micro-optics,micro-mechanics,micro-electronics,micro-bots and micro-biodevices are reviewed in section 7.Finally,a summary of the review and a perspective are proposed to explore the challenges and future opportunities for further betterment of fs laser micro/nano processing technology.展开更多
This review examines the state-of-the-art in spatial manipulation of ultrafast laser processing using dynamic light modulators,with a particular focus on liquid crystal-based systems.We discuss phase modulation strate...This review examines the state-of-the-art in spatial manipulation of ultrafast laser processing using dynamic light modulators,with a particular focus on liquid crystal-based systems.We discuss phase modulation strategies and highlight the current limitations and challenges in surface and bulk processing.Specifically,we emphasize the delicate balance between high-fidelity beam shaping and energy efficiency,both critical for surface and bulk processing applications.Given the inherent physical limitations of spatial light modulators such as spatial resolution,fill factor,and phase modulation range.We explore techniques developed to bridge the gap between desired intensity distributions and actual experimental beam profiles.We present various laser light modulation technologies and the main algorithmic strategies for obtaining modulation patterns.The paper includes application examples across a wide range of fields,from surgery to surface structuring,cutting,bulk photo-inscription of optical functions,and additive manufacturing,highlighting the significant enhancements in processing speed and precision due to spatial beam shaping.The diverse applications and the technological limitations underscore the need for adapted modulation pattern calculation methods.We discuss several advancements addressing these challenges,involving both experimental and algorithmic developments,including the recent incorporation of artificial intelligence.Additionally,we cover recent progress in phase and pulse front control based on spatial modulators,which introduces an extra control parameter for light excitation with high potential for achieving more controlled processing outcomes.展开更多
Over the last few decades,ultrafast laser processing has become a widely used tool for manufacturing microstructures and nanostructures.The real-time monitoring of laser material processing provides opportunities to i...Over the last few decades,ultrafast laser processing has become a widely used tool for manufacturing microstructures and nanostructures.The real-time monitoring of laser material processing provides opportunities to inspect processes and provide feedback.To date,in-situ and real-time monitoring of laser material processing has rarely been performed.To this end,we propose dual-path snapshot compressive microscopy(DP-SCM)for high-speed,large field-of-view,and high-resolution imaging for in-situ and real-time ultrafast laser processing.In the evaluation of DP-SCM,the field of view,lateral resolution,and imaging speed were measured to be 2 mm,775 nm,and 500 fps,respectively.In ultrafast laser processing,the laser scanning process is observed using a DP-SCM system when translating the sample stage and scanning the focused femtosecond laser.Finally,we monitored the development of a self-organized nanograting structure to validate the potential of our system for unveiling new material mechanisms.The proposed method serves as an add-up(plug-and-play)module for any imaging setup and has vast potential for opening new avenues for high-throughput imaging in laser material processing.展开更多
Despite the promising progress in conductive hydrogels made with pure conducting polymer,great challenges remain in the interface adhesion and robustness in longterm monitoring.To address these challenges,Prof.Seung H...Despite the promising progress in conductive hydrogels made with pure conducting polymer,great challenges remain in the interface adhesion and robustness in longterm monitoring.To address these challenges,Prof.Seung Hwan Ko and Taek-Soo Kim’s team introduced a laserinduced phase separation and adhesion method for fabricating conductive hydrogels consisting of pure poly(3,4-ethylenedioxythiophene):polystyrene sulfonate on polymer substrates.The laser-induced phase separation and adhesion treated conducting polymers can be selectively transformed into conductive hydrogels that exhibit wet conductivities of 101.4 S cm^(−1) with a spatial resolution down to 5μm.Moreover,they maintain impedance and charge-storage capacity even after 1 h of sonication.The micropatterned electrode arrays demonstrate their potential in long-term in vivo signal recordings,highlighting their promising role in the field of bioelectronics.展开更多
Gallium nitride(GaN),as a third-generation semiconductor,is highly attractive due to its exceptional physical and chemical properties.Laser direct writing offers an efficient method for the precise processing of hard ...Gallium nitride(GaN),as a third-generation semiconductor,is highly attractive due to its exceptional physical and chemical properties.Laser direct writing offers an efficient method for the precise processing of hard and brittle materials.In this work,various types of surface microtexture were processed on GaN epilayers using a femtosecond laser with a wavelength of 1030 nm.The effects of the laser energy,singlepulse interval,number of pulses,and number of scan passes on groove machining were investigated with a view to achieving high-quality micromachining.The depth,width,surface morphology,and roughness of the grooves were analyzed using scanning electron microscopy,laser scanning confocal microscopy,and atomic force microscopy.Damage and stress were characterized at the microscale using Raman spectroscopy.High-quality precision machining of different types of periodic surface microtexture at 40 mW laser power was achieved by controlling the process parameters and laser trajectory.Finally,an initial exploration was conducted to examine vector-light-based microand nanostructure processing.The findings demonstrate the potential of femtosecond lasers for efficient micromachining of hard and brittle materials without the creation of heat-affected zones or microcracks.The high-quality textured structures achieved through this processing technique have broad and promising applications in optoelectronic devices and tribology.展开更多
Metallic nanowires have served as novel materials for soft electronics due to their outstanding mechanical compliance and electrical properties.However,weak adhesion and low mechanical robustness of nanowire networks ...Metallic nanowires have served as novel materials for soft electronics due to their outstanding mechanical compliance and electrical properties.However,weak adhesion and low mechanical robustness of nanowire networks to substrates significantly undermine their reliability,necessitating the use of an insulating protective layer,which greatly limits their utility.Herein,we present a versatile and generalized laser-based process that simultaneously achieves strong adhesion and mechanical robustness of nanowire networks on diverse substrates without the need for a protective layer.In this method,the laser-induced photothermal energy at the interface between the nanowire network and the substrate facilitates the interpenetration of the nanowire network and the polymer matrix,resulting in mechanical interlocking through percolation.This mechanism is broadly applicable across different metallic nanowires and thermoplastic substrates,significantly enhancing its universality in diverse applications.Thereby,we demonstrated the mechanical robustness of nanowires in reusable wearable physiological sensors on the skin without compromising the performance of the sensor.Furthermore,enhanced robustness and electrical conductivity by the laser-induced interlocking enables a stable functionalization of conducting polymers in a wet environment,broadening its application into various electrochemical devices.展开更多
Additive manufacturing(AM)has revolutionized modern manufacturing,but the application of magnesium(Mg)alloys in laser-based AM remains underexplored due to challenges such as oxidation,low boiling point,and thermal ex...Additive manufacturing(AM)has revolutionized modern manufacturing,but the application of magnesium(Mg)alloys in laser-based AM remains underexplored due to challenges such as oxidation,low boiling point,and thermal expansion,which lead to defects like porosity and cracking.This study provides a comprehensive analysis of microstructure changes in WE43 magnesium(Mg)alloy after laser surface melting(LSM),examining grain morphology,orientation,size,microsegregation,and defects under various combinations of laser power,scan speed,and spot size.Ourfindings reveal that variations in laser power and spot size exert a more significant influence on the depth and aspect ratio of the keyhole melt pool compared to laser scan speed.Critically,we demonstrate that laser energy density,while widely used as a quantitative metric to describe the combined effects of process parameters,exhibits significant limitations.Notable variations in melt pool depth,normalized width,and microstructure with laser energy density were observed,as reflected by low R²values.Additionally,we underscore the importance of assessing the temperature gradient across the width of the melt pool,which determines whether conduction or keyhole melting modes dominate.These modes exhibit distinct heatflow mechanisms and yield fundamentally different microstructural outcomes.Furthermore,we show that the microstructure and grain size in conduction mode exhibit a good correlation with the temperature gradient(G)and solidification rate(R).This research provides a framework for achieving localized microstructural control in LSM,providing insights to optimize process parameters for laser-based 3D printing of Mg alloys,and advancing the integration of Mg alloys into AM technologies.展开更多
To enhance the adhesion of ceramic coatings in turbine blade Thermal Barrier Coatings(TBCs)systems,Laser Surface Texturing(LST)was employed to create microstructures on the metal bond coat.The bonding conditions and f...To enhance the adhesion of ceramic coatings in turbine blade Thermal Barrier Coatings(TBCs)systems,Laser Surface Texturing(LST)was employed to create microstructures on the metal bond coat.The bonding conditions and failure mechanisms of the ceramic coatings within these microstructures were thoroughly investigated.Femtosecond laser technology was used to fabricate three types of high-quality microstructure grooves:linear,sine wave,and grid patterns.These grooves exhibit uniform morphology,well-defined edges,and smooth inner walls.After ceramic coating deposition,columnar crystal structures grew perpendicularly along the groove walls,completely filling the microstructures and forming an arched support structure that significantly enhances mechanical interlocking and adhesion.Among the different microstructures,grid patterns demonstrated the best adhesion performance.In scratch tests,grid-patterned microstructures exhibited only localized small block spalling under high load conditions,avoiding large-scale delamination.This superior performance is attributed to the ability of grid pattern to effectively distribute stress in multiple directions and prevent crack propagation.By reducing stress concentration and enhancing mechanical interlocking points,grid-patterned microstructures also showed excellent resistance to spallation during thermal cycling,markedly improving the thermal resistance and adhesion of coating.展开更多
Avoiding crystallization while maintaining the original microstructure and mechanical properties of the material are long-term goals of laser welding of Zr-based bulk metallic glass(BMG).In this paper,the effect of pu...Avoiding crystallization while maintaining the original microstructure and mechanical properties of the material are long-term goals of laser welding of Zr-based bulk metallic glass(BMG).In this paper,the effect of pulsed laser welding parameters on the microstructure,crystallization degree,and mechanical properties of Zr57Nb5Cu15.4Ni12.6Al10 BMG is investigated.Non-crystallized welding forming of a zirconium-based amorphous alloy is achieved by optimizing the process parameters of pulsed laser welding.The crystallization degree of Zr-based BMG is mainly determined by the welding speed and power.The welding depth and crystallization area fraction increase with an increase in the effective peak power density.The optimized welding process can effectively reduce the heat accumulation of the weld,thus avoiding crystallization.The flexural strength of the weld can be maintained at 96.5%of the matrix.展开更多
The fatigue properties of laser shock processing （LSP） on both side surfaces of fastener hole with diameter of 3 mm in the LY12CZ aluminum alloy specimens were investigated. The superficial residual stress was measu...The fatigue properties of laser shock processing （LSP） on both side surfaces of fastener hole with diameter of 3 mm in the LY12CZ aluminum alloy specimens were investigated. The superficial residual stress was measured by X-ray diffraction method. Fatigue experiments of specimens with and without LSP were performed, and the microstructural features of fracture of specimens were characterized by scanning electron microscopy （SEM）. The results indicate that the compressive residual stress can be induced into the surface of specimen, and the fatigue life of the specimen with LSP is 3.5 times as long as that of specimen without LSP. The location of fatigue crack initiation is transferred from the top surface to the sub-surface after LSP, and the fatigue striation spacing of the treated specimen during the expanding fatigue crack is narrower than that of the untreated specimen. Furthermore, the diameters of the dimples on the fatigue crack rupture zone of the specimen with LSP are relatively bigger, which is related to the serious plastic deformation in the material with LSP.展开更多
In this paper, we reviewed the fabrications of functional microcavity lasers in soft materials such as polymer and protein by femtosecond laser processing. High-quality （Q） microdisks with a laser dye （Rhodamine B,...In this paper, we reviewed the fabrications of functional microcavity lasers in soft materials such as polymer and protein by femtosecond laser processing. High-quality （Q） microdisks with a laser dye （Rhodamine B, RhB） acting as gain medium were fabricated that produced whispering-gallery-mode （WGM） lasing output. We also obtained unidirectional lasing output with a low lasing threshold in a deformed spiral microcavity at room temperature. Photonic-molecule （PM） microlasers were prepared to investigate the interaction and coupling effects of different cavities, and it was found that the distance between the two disks plays an important role in the lasing behaviors. Single-mode lasing was realized from a stacked PM microlaser through Vernier effect. Furthermore we adopted the biocompatible materials, RhB-doped proteins as a host material and fabricated a three-dimensional （3D） WGM microlaser, which operated well both in air and aqueous environment. The sensing of the protein micro- lasers to Na2SO4 concentration was investigated. Our results of fabricating high-Q microlasers with different materials reveal the potential applications of femtosecond laser processing in the areas of integrated optoelectronic and ultrahigh sensitive bio-sensing devices.展开更多
文摘Laser processing technologies enable the precise fabrication of arbitrary structures and devices with broad applications in micro-optics,micro-mechanics,and biomedicine.However,its adoption is limited by the large size,complexity,high cost,and low flexibility of optical systems.Metasurfaces enable precise multidimensional control of light fields,aligning well with the development trend toward compact,high-performance optical systems.Here,we review several recent studies on the application of metasurfaces in laser processing technologies,including 3D nanolithography,direct laser writing,and laser cutting.Metasurfaces provide an integrated operational platform with exceptional performance,poised to disrupt conventional laser processing workflows.This combination presents significant cost efficiency and substantial development potential,with promising applications in areas such as imaging,optical storage,advanced sensing,and space on-orbit manufacturing.
基金supported by National Key Research and Development Program of China (2023YFB4402500,2023YFB4402400)National Natural Science Foundation of China (621041314)+1 种基金Natural Science Foundation of Shandong Province (ZR2023LZH007)Program of Qilu Young Scholars of Shandong University.
文摘Graphene oxide,as a 2D material with nanometer thickness,offers ultra-high mobility,chaotic properties,and low cost.These make graphene oxide memristors beneficial for reservoir computing(RC)networks.In this study,continuous-wave(CW)laser processing is used to reduce chaotic graphene oxide(CGO)films,resulting in the non-volatile storage capability based on the reduced chaotic graphene oxide(rCGO)films.Laser power significantly impacts the characteristics of the rCGO memristor.Material characterization indicates that laser radiation can effectively reduce the oxygen content in CGO films.With optimized laser power,the rCGO memristor achieves a large ratio at 18 mW laser power.Benefiting from the short-term mem-ory characteristics,distinct conductive states are achieved,which are further utilized to construct RC networks.With a third con-trol probe,the rCGO memristor can express rich reservoir states,demonstrating accuracy in predicting the Hénon map with an NRMSE below 0.3.These findings provide the potential for developing flexible RC networks based on graphene oxide memris-tors via laser processing.
基金supported by the National Natural Science Foundation of China(51975336)Key Research and Development Program of Shandong Province(2020JMRH0202)+1 种基金the National Natural Science Foundation of China(52172282)China Postdoctoral Science Foundation(2021M690106)。
文摘The biological performance of Ti-6Al-4V implant is primarily determined by their surface properties.However,traditional surface modification methods,such as acid etching,hardly make improvement in their osseointegration ability and antibacterial capacity.In this study,we prepared a multi-scale composite structure coated with zinc oxide(ZnO)on Ti-6Al-4V implant by an innovative technology of two-step laser processing combined with solution-assistant.Compared with the acid etching method,the physicochemical properties of surface significantly improved.The in vitro results showed that the particular dimension of micro-nano structure and the multifaceted nature of ZnO synergistically affected MC3T3-E1 osteogenesis and bacterial activities:(1)The surface morphology showed a‘contact guidance'effect on cell arrangement,which was conducive to the adhesion of filopodia and cell spreading,and the osteogenesis level of MC3T3-E1 was enhanced due to the release of zinc ions(Zn^(2+));(2)the characterization of bacterial response revealed that periodic nanostructures and Zn^(2+)released could cause damage to the cell wall of E.coli and reduce the adhesion and aggregation of S.aureus.In conclusion,the modified surface showed a synergistic effect of physical topography and chemical composition,making this a promising method and providing new insight into bone defect repairment.
基金Project(2021YFF0500200) supported by the National Key R&D Program of ChinaProject(52105437) supported by the National Natural Science Foundation of China+1 种基金Project(202006120184) supported by the Heilongjiang Provincial Postdoctoral Science Foundation,ChinaProject(LBH-Z20054) supported by the China Scholarship Council。
文摘The model of heat source(MHS) which reflects the thermal interaction between materials and laser during processing determines the accuracy of simulation results. To acquire desirable simulations results, although various modifications of heat sources in the aspect of absorption process of laser by materials have been purposed, the distribution of laser power density(DLPD) in MHS is still modeled theoretically. However, in the actual situations of laser processing, the DLPD is definitely different from the ideal models. So, it is indispensable to build MHS using actual DLPD to improve the accuracy of simulation results. Besides, an automatic modeling method will be benefit to simplify the tedious pre-processing of simulations. This paper presents a modeling method and corresponding algorithm to model heat source using measured DLPD. This algorithm automatically processes original data to get modeling parameters and provides a step MHS combining with absorption models. Simulations and experiments of heat transfer in steel plates irradiated by laser prove the mothed and the step MHS. Moreover, the investigations of laser induced thermal-crack propagation in glass highlight the signification of modeling heat source based on actual DLPD and demonstrate the enormous application of this method in the simulation of laser processing.
文摘We report the femtosecond(fs)laser fabrication of biomimetic omnidirectional iridescent metallic surfaces exhibiting efficient diffraction for practically any angle of light incidence.Such diffractive behavior is realized by means of multi-directional low-spatial-frequency,laser-induced periodic surface structures(LSFL)formed upon exploiting the cylindrical symmetry of a cylindrical vector(CV)fs field.We particularly demonstrate that the multi-directional gratings formed on stainless steel surface by a radially polarized fs beam,could mimic the omnidirectional structural coloration properties found in some natural species.Accordingly,the fabricated grating structures can spatially disperse the incident light into individual wavelength with high efficiency,exhibiting structural iridescence at all viewing angles.Analytical calculations using the grating equation reproduced the characteristic variation of the vivid colors observed as a function of incident angle.We envisage that our results will significantly contribute to the development of new photonic and light sensing devices.
基金supported by the National Natural Science Foundation of China[Grant No.52175377]the National Science and Technology Major Project[Grant No.2017-VII-0002-0095]the Graduate Scientific Research and Innovation Foundation of Chongqing[Grant No.CYB22009].
文摘A new process for the fabrication of sharkskin bionic structures on metal surfaces is proposed.The sharkskin bionic surface was successfully machined on the surface of IN718 by laser sequencing of the abrasive belt surface,laser processing of the layered scale-like structure,and ribbed texture grinding.The flexible contact properties of belt grinding allow ribbed structures to be machined uniformly on a hierarchical,scale-like microstructure.Sharkskin bionic microstructures with radii greater than 75µm were prepared after parameter optimisation.The influence of processing parameters on the geometrical accuracy of the microstructure was investigated,the microstructure microform and elemental distribution were analyzed,and the relationship between the ribbed microstructure and chemical properties of the surface of the bionic sharkskin on wettability was revealed.The results indicate that reducing the laser power and increasing the laser scan rate can reduce the laser thermal effect and improve the microstructure processing accuracy.The laser ablation process is accompanied by a violent chemical reaction that introduces a large amount of oxygen and carbon elements and infiltrates them at a certain depth.The wettability of the surface undergoes a transition from hydrophilic(contact angle 69.72°)to hydrophobic(contact angle 131.56°)due to the adsorption of C-C/C-H and the reduction of C=O/O=C-O during the placement process.The ribbed microstructure changes the solid-liquid contact on the surface into a solid-liquid-gas contact,which has an enhanced effect on hydrophobicity.This study is a valuable guide to the processing of hydrophobic layered bionic microstructures.
基金supported by a grant from the National Research Foundation of Korea(NRF)funded by the Ministry of Science ICT and Future Planning of Korea(No.2019R1A2C2002398)partially supported by the Alchemist Project(No.20012263)funded by the Ministry of Trade,Industry&Energy of Korea,the KIST Institutional Programthe Sejong University Program(No.20200392)。
文摘Indoor air quality(IAQ) directly affects the health of occupants. Household manufacturing equipment(HME) used for hobbies or educational purposes is a new and unexplored source of air pollution. In this study, we evaluated the characteristics of particulate and gaseous pollutants produced by a household laser processing equipment(HLPE). Various target materials were tested using a commercial HLPE under various operating conditions of laser power and sheath air flow rate. The mode diameters of the emitted particles gradually decreased as laser power increased, while the particle number concentration(PNC) and particle emission rate(PER) increased. In addition, as the sheath air flow rate quadrupled from 10 to 40 L/min, the mode diameter of the emitted particles decreased by nearly 25%, but the effect on the PNC was insignificant. When the laser induced the target materials at 53 m W, the mode diameters of particles were < 150 nm, and PNCs were > 2.0 × 10^(4) particles/cm^(3). Particularly, analyses of sampled aerosols indicated that harmful substances such as sulfur and barium were present in particles emitted from leather. The carcinogenic gaseous pollutants such as acrylonitrile, acetaldehyde, 1,3-butadiene, benzene, and C 8 aromatics(ethylbenzene) were emitted from all target materials. In an actual indoor environment, the PNC of inhalable ultrafine particles(UFPs) was > 5 × 10^(4) particles/cm^(3) during 30 min of HLPE operation. Our results suggest that more meticulous control methods are needed, including the use of less harmful target materials along with filters or adsorbents that prevent emission of pollutants.
基金supported by the National Natural Science Foundation of China (No.11574159)the Open Fund of the State Key Laboratory of High Field Laser Physics,China (Shanghai Institute of Optics and Fine Mechanics)the Special Research Foundation of the Central University of Nankai University (No.63191108)。
文摘In this paper, we use femtosecond laser pulse to scribe 304 stainless steel foil, detect the Fourier transform infrared spectrum of the sample before and after processing, confirm the "cold processing" and "thermal processing" and their mutual conversion, and determine the "cold processing" parameter window. The ablation threshold and incubation coefficient of 304 stainless steel foil are calculated, and the effects of scanning speed and effective pulse number on the ablation threshold are analyzed. The ANSYS software is used to simulate the radial and axial temperature distributions of the surface on 304 stainless steel foil sample and the heat-affected zone with a femtosecond laser fluence of 10 J/cm2 and an effective number of pulses of 1 200 are obtained. In the aspect of spectral detection, the Fourier transform infrared spectra of the sample before and after processing are measured and two processing mechanisms of "cold processing" and "hot processing" are confirmed, which proves that we can achieve the conversion between "cold processing" and "hot processing" by changing the laser fluence and determine the "cold processing" laser fluence range.
文摘The first multi-function laser processing system in the domestic for clutch manufacture,with abilities of cutting, jointing and heat treatment,was reported in this paper.One external optical path,double laser heads,adjust device by manual operation,automatically track were employed in this system Also the other parts of vehicles can be fabricated by this system,as well as clutches.The special processing to manufacture the clutches of heavy vehicles,which was developed by the project of this laser processing system,achieved the international standards and satisfied the economic development and nation defense in the do- mestic.
基金supported by National Key R&D Program of China(Grant Nos.2021YFB2802000 and 2022YFB2804300)Science and Technology Commission of Shanghai Municipality(Grant No.21DZ1100500)+3 种基金Shanghai Municipal Science and Technology Major Projectthe Shanghai Frontiers Science Center Program(2021-2025 No.20)National Natural Science Foundation of China(Grant No.61975123)Shanghai Scienceand Technology Innovation Action Plan(Grant No.23JC1403100)。
文摘Able to precisely control and manipulate materials'states at micro/nano-scale level,femtosecond(fs)laser micro/nano processing technology has undergone tremendous development over the past three decades.Free-forming three-dimensional(3D)microscale functional devices and inducing fascinating and unique physical or chemical phenomena have granted this technology powerful versatility that no other technology can match.As this technology advances rapidly in various fields of application,some key challenges have emerged and remain to be urgently addressed.This review firstly introduces the fundamental principles for understanding how fs laser pulses interact with materials and the associated unique phenomena in section 2.Then micro/nano-fabrication in transparent materials by fs laser processing is presented in section 3.Thereafter,several high efficiency/throughput fabrication methods as well as pulse-shaping techniques are listed in sections 4 and 5 reviews four-dimensional(4D)and nanoscale printing realized by fs laser processing technology.Special attention is paid to the heterogeneous integration(HI)of functional materials enabled by fs laser processing in section 6.Several intriguing examples of 3D functional micro-devices created by fs laser-based manufacturing methods such as microfluidics,lab-on-chip,micro-optics,micro-mechanics,micro-electronics,micro-bots and micro-biodevices are reviewed in section 7.Finally,a summary of the review and a perspective are proposed to explore the challenges and future opportunities for further betterment of fs laser micro/nano processing technology.
基金supported by the French ANRT agence nationale de la recherche technologique under the CIFRE conventions industrielles de formation par la recherche framework.
文摘This review examines the state-of-the-art in spatial manipulation of ultrafast laser processing using dynamic light modulators,with a particular focus on liquid crystal-based systems.We discuss phase modulation strategies and highlight the current limitations and challenges in surface and bulk processing.Specifically,we emphasize the delicate balance between high-fidelity beam shaping and energy efficiency,both critical for surface and bulk processing applications.Given the inherent physical limitations of spatial light modulators such as spatial resolution,fill factor,and phase modulation range.We explore techniques developed to bridge the gap between desired intensity distributions and actual experimental beam profiles.We present various laser light modulation technologies and the main algorithmic strategies for obtaining modulation patterns.The paper includes application examples across a wide range of fields,from surgery to surface structuring,cutting,bulk photo-inscription of optical functions,and additive manufacturing,highlighting the significant enhancements in processing speed and precision due to spatial beam shaping.The diverse applications and the technological limitations underscore the need for adapted modulation pattern calculation methods.We discuss several advancements addressing these challenges,involving both experimental and algorithmic developments,including the recent incorporation of artificial intelligence.Additionally,we cover recent progress in phase and pulse front control based on spatial modulators,which introduces an extra control parameter for light excitation with high potential for achieving more controlled processing outcomes.
基金supported by the National Natural Science Foundation of China(62271414)Science Fund for Distinguished Young Scholars of Zhejiang Province(LR23F010001)Research Center for Industries of the Future(RCIF)at Westlake University.and Key Project of the Westlake Institute for Optoelectronics(Grant No.2023GD007).
文摘Over the last few decades,ultrafast laser processing has become a widely used tool for manufacturing microstructures and nanostructures.The real-time monitoring of laser material processing provides opportunities to inspect processes and provide feedback.To date,in-situ and real-time monitoring of laser material processing has rarely been performed.To this end,we propose dual-path snapshot compressive microscopy(DP-SCM)for high-speed,large field-of-view,and high-resolution imaging for in-situ and real-time ultrafast laser processing.In the evaluation of DP-SCM,the field of view,lateral resolution,and imaging speed were measured to be 2 mm,775 nm,and 500 fps,respectively.In ultrafast laser processing,the laser scanning process is observed using a DP-SCM system when translating the sample stage and scanning the focused femtosecond laser.Finally,we monitored the development of a self-organized nanograting structure to validate the potential of our system for unveiling new material mechanisms.The proposed method serves as an add-up(plug-and-play)module for any imaging setup and has vast potential for opening new avenues for high-throughput imaging in laser material processing.
基金supported by the National Natural Science Foundation of China(52475610)Zhejiang Provincial Natural Science Foundation of China(LDQ24E050001).
文摘Despite the promising progress in conductive hydrogels made with pure conducting polymer,great challenges remain in the interface adhesion and robustness in longterm monitoring.To address these challenges,Prof.Seung Hwan Ko and Taek-Soo Kim’s team introduced a laserinduced phase separation and adhesion method for fabricating conductive hydrogels consisting of pure poly(3,4-ethylenedioxythiophene):polystyrene sulfonate on polymer substrates.The laser-induced phase separation and adhesion treated conducting polymers can be selectively transformed into conductive hydrogels that exhibit wet conductivities of 101.4 S cm^(−1) with a spatial resolution down to 5μm.Moreover,they maintain impedance and charge-storage capacity even after 1 h of sonication.The micropatterned electrode arrays demonstrate their potential in long-term in vivo signal recordings,highlighting their promising role in the field of bioelectronics.
基金supported by the Henan Key Laboratory of Intelligent Manufacturing Equipment Integration for Superhard Materials(Grant No.JDKJ2022-01)the National Natural Science Foundation of China(Grant Nos.52035009 and 51761135106)+1 种基金the 2020 Mobility Programme of the Sino-German Center for Research Promotion(Grant No.M-0396)the“111”project by the State Administration of Foreign Experts Affairs and the Ministry of Education of China(Grant No.B07014).
文摘Gallium nitride(GaN),as a third-generation semiconductor,is highly attractive due to its exceptional physical and chemical properties.Laser direct writing offers an efficient method for the precise processing of hard and brittle materials.In this work,various types of surface microtexture were processed on GaN epilayers using a femtosecond laser with a wavelength of 1030 nm.The effects of the laser energy,singlepulse interval,number of pulses,and number of scan passes on groove machining were investigated with a view to achieving high-quality micromachining.The depth,width,surface morphology,and roughness of the grooves were analyzed using scanning electron microscopy,laser scanning confocal microscopy,and atomic force microscopy.Damage and stress were characterized at the microscale using Raman spectroscopy.High-quality precision machining of different types of periodic surface microtexture at 40 mW laser power was achieved by controlling the process parameters and laser trajectory.Finally,an initial exploration was conducted to examine vector-light-based microand nanostructure processing.The findings demonstrate the potential of femtosecond lasers for efficient micromachining of hard and brittle materials without the creation of heat-affected zones or microcracks.The high-quality textured structures achieved through this processing technique have broad and promising applications in optoelectronic devices and tribology.
基金supported by the National Research Foundation of Korea(NRF)Grant(RS-2024-00343512,RS-2024-00416938).
文摘Metallic nanowires have served as novel materials for soft electronics due to their outstanding mechanical compliance and electrical properties.However,weak adhesion and low mechanical robustness of nanowire networks to substrates significantly undermine their reliability,necessitating the use of an insulating protective layer,which greatly limits their utility.Herein,we present a versatile and generalized laser-based process that simultaneously achieves strong adhesion and mechanical robustness of nanowire networks on diverse substrates without the need for a protective layer.In this method,the laser-induced photothermal energy at the interface between the nanowire network and the substrate facilitates the interpenetration of the nanowire network and the polymer matrix,resulting in mechanical interlocking through percolation.This mechanism is broadly applicable across different metallic nanowires and thermoplastic substrates,significantly enhancing its universality in diverse applications.Thereby,we demonstrated the mechanical robustness of nanowires in reusable wearable physiological sensors on the skin without compromising the performance of the sensor.Furthermore,enhanced robustness and electrical conductivity by the laser-induced interlocking enables a stable functionalization of conducting polymers in a wet environment,broadening its application into various electrochemical devices.
文摘Additive manufacturing(AM)has revolutionized modern manufacturing,but the application of magnesium(Mg)alloys in laser-based AM remains underexplored due to challenges such as oxidation,low boiling point,and thermal expansion,which lead to defects like porosity and cracking.This study provides a comprehensive analysis of microstructure changes in WE43 magnesium(Mg)alloy after laser surface melting(LSM),examining grain morphology,orientation,size,microsegregation,and defects under various combinations of laser power,scan speed,and spot size.Ourfindings reveal that variations in laser power and spot size exert a more significant influence on the depth and aspect ratio of the keyhole melt pool compared to laser scan speed.Critically,we demonstrate that laser energy density,while widely used as a quantitative metric to describe the combined effects of process parameters,exhibits significant limitations.Notable variations in melt pool depth,normalized width,and microstructure with laser energy density were observed,as reflected by low R²values.Additionally,we underscore the importance of assessing the temperature gradient across the width of the melt pool,which determines whether conduction or keyhole melting modes dominate.These modes exhibit distinct heatflow mechanisms and yield fundamentally different microstructural outcomes.Furthermore,we show that the microstructure and grain size in conduction mode exhibit a good correlation with the temperature gradient(G)and solidification rate(R).This research provides a framework for achieving localized microstructural control in LSM,providing insights to optimize process parameters for laser-based 3D printing of Mg alloys,and advancing the integration of Mg alloys into AM technologies.
基金supported by the National Science and Technology Major Project,China(No.J2019-VII-0013-0153)the Sichuan Science and Technology Program,China(Nos.2021ZDZX0001 and 2021ZDZX0002)。
文摘To enhance the adhesion of ceramic coatings in turbine blade Thermal Barrier Coatings(TBCs)systems,Laser Surface Texturing(LST)was employed to create microstructures on the metal bond coat.The bonding conditions and failure mechanisms of the ceramic coatings within these microstructures were thoroughly investigated.Femtosecond laser technology was used to fabricate three types of high-quality microstructure grooves:linear,sine wave,and grid patterns.These grooves exhibit uniform morphology,well-defined edges,and smooth inner walls.After ceramic coating deposition,columnar crystal structures grew perpendicularly along the groove walls,completely filling the microstructures and forming an arched support structure that significantly enhances mechanical interlocking and adhesion.Among the different microstructures,grid patterns demonstrated the best adhesion performance.In scratch tests,grid-patterned microstructures exhibited only localized small block spalling under high load conditions,avoiding large-scale delamination.This superior performance is attributed to the ability of grid pattern to effectively distribute stress in multiple directions and prevent crack propagation.By reducing stress concentration and enhancing mechanical interlocking points,grid-patterned microstructures also showed excellent resistance to spallation during thermal cycling,markedly improving the thermal resistance and adhesion of coating.
基金Supported by Guangdong Major Project of Basic and Applied Research,China(Grant No.2019B030302010)National Natural Science Foundation of China (Grant Nos.51735003,52205456)
文摘Avoiding crystallization while maintaining the original microstructure and mechanical properties of the material are long-term goals of laser welding of Zr-based bulk metallic glass(BMG).In this paper,the effect of pulsed laser welding parameters on the microstructure,crystallization degree,and mechanical properties of Zr57Nb5Cu15.4Ni12.6Al10 BMG is investigated.Non-crystallized welding forming of a zirconium-based amorphous alloy is achieved by optimizing the process parameters of pulsed laser welding.The crystallization degree of Zr-based BMG is mainly determined by the welding speed and power.The welding depth and crystallization area fraction increase with an increase in the effective peak power density.The optimized welding process can effectively reduce the heat accumulation of the weld,thus avoiding crystallization.The flexural strength of the weld can be maintained at 96.5%of the matrix.
基金Project (51175002) supported by the National Natural Science Foundation of ChinaProject (090414156) supported by the Natural Science Foundation of Anhui Province,China
文摘The fatigue properties of laser shock processing （LSP） on both side surfaces of fastener hole with diameter of 3 mm in the LY12CZ aluminum alloy specimens were investigated. The superficial residual stress was measured by X-ray diffraction method. Fatigue experiments of specimens with and without LSP were performed, and the microstructural features of fracture of specimens were characterized by scanning electron microscopy （SEM）. The results indicate that the compressive residual stress can be induced into the surface of specimen, and the fatigue life of the specimen with LSP is 3.5 times as long as that of specimen without LSP. The location of fatigue crack initiation is transferred from the top surface to the sub-surface after LSP, and the fatigue striation spacing of the treated specimen during the expanding fatigue crack is narrower than that of the untreated specimen. Furthermore, the diameters of the dimples on the fatigue crack rupture zone of the specimen with LSP are relatively bigger, which is related to the serious plastic deformation in the material with LSP.
文摘In this paper, we reviewed the fabrications of functional microcavity lasers in soft materials such as polymer and protein by femtosecond laser processing. High-quality （Q） microdisks with a laser dye （Rhodamine B, RhB） acting as gain medium were fabricated that produced whispering-gallery-mode （WGM） lasing output. We also obtained unidirectional lasing output with a low lasing threshold in a deformed spiral microcavity at room temperature. Photonic-molecule （PM） microlasers were prepared to investigate the interaction and coupling effects of different cavities, and it was found that the distance between the two disks plays an important role in the lasing behaviors. Single-mode lasing was realized from a stacked PM microlaser through Vernier effect. Furthermore we adopted the biocompatible materials, RhB-doped proteins as a host material and fabricated a three-dimensional （3D） WGM microlaser, which operated well both in air and aqueous environment. The sensing of the protein micro- lasers to Na2SO4 concentration was investigated. Our results of fabricating high-Q microlasers with different materials reveal the potential applications of femtosecond laser processing in the areas of integrated optoelectronic and ultrahigh sensitive bio-sensing devices.
