The carbon cycle of global inland waters is quantitatively comparable to other components in the global carbon budget. Among inland waters, a significant part is man-made lakes formed by damming rivers. Manmade lakes ...The carbon cycle of global inland waters is quantitatively comparable to other components in the global carbon budget. Among inland waters, a significant part is man-made lakes formed by damming rivers. Manmade lakes are undergoing a rapid increase in number and size. Human impacts and frequent algae blooms lead to it necessary to make a better constraint on their carbon cycles. Here, we make a primary estimation on the air–water CO_2 transfer flux through an algae bloom year for a subtropical man-made lake—Hongfeng Lake, Southwest China. To do this a new type of glass bottles was designed for content and isotopic analysis of DIC and other environmental parameters. At the early stage of algae bloom,CO_2 was transferred from the atmosphere to the lake with a net flux of 1.770 g·C·m^(-2). Later, the partial pressure(pCO_2) of the aqueous CO_2 increased rapidly and the lake outgassed to the atmosphere with a net flux of 95.727 g·C·m^(-2). In the remaining days, the lake again took up CO_2 from the atmosphere with a net flux of 14.804 g·C·m^(-2). As a whole, Lake Hongfeng released 4527 t C to the atmosphere, accounting for one-third of the atmosphere/soil CO_2 sequestered by chemical weathering in the whole drainage. With an empirical mode decomposition method, we found air temperature plays a major role in controlling water temperature, aqueous pCO_2 and hence CO_2 flux. This work indicates a necessity to make detailed and comprehensive carbon budgets in man-made lakes.展开更多
e penetrative depth in undisturbed surface soil is within 4 mm.7￣Be activity shows exponential decrease with soil depth, which is expressed as a diffusion process.7￣Be penetrative depth in undisturbed surface soil i...e penetrative depth in undisturbed surface soil is within 4 mm.7￣Be activity shows exponential decrease with soil depth, which is expressed as a diffusion process.7￣Be penetrative depth in undisturbed surface soil is apparently deeper in the fall (0.22-0.37 g cm￣(-2) than in the spring (0.11-0.28 g cm￣(-2) at the same site; Whereas, ￣7Be apparent activity at the top of surface soil is higher in the spring (0.3-2.2 Bq g￣(-1_) than in the fall (0.2-0.5 Bq g￣(-1) at the same site. The ￣7Be inventory (189-544 Bq m￣(-2) changes with both locations and seasons. Although the ￣7Be flux to the earth's surface increases with amount of precipitation, its maximum inventory in the soil profiles decreases to 30%-40% after the rainy period. Calculated by the diffusion equation, the erosion and accumulation rates of soil particles are agreeable with the observation in situ., which shows that the rates in fall are 1.5 times those in spring. The eroded soil particles almost all have been removed on the tablelands rather than transported into the drainage system. This indicstes that the soil erosion process in the karst region is only partial transportation within a short distance.展开更多
The purification efficiency of eutrophic water by five aqua-cultured plants(Chlorophytum comosum, Salix babylonica, Dracaena sanderiana, Myriophyllum verticillatum, Alternanthera philoxeroides) in Lake Hongfeng, China...The purification efficiency of eutrophic water by five aqua-cultured plants(Chlorophytum comosum, Salix babylonica, Dracaena sanderiana, Myriophyllum verticillatum, Alternanthera philoxeroides) in Lake Hongfeng, China, was investigated. The results indicated that the biomass of Myriophyllum verticillatum and Alternanthera philoxeroides reached the highest level in 87 days after transplant. The removal efficiencies of total nitrate(TN), total phosphorus(TP), chemical oxygen demand(CODCr), and chlorophyll(Chl-a) by the plants ranged from 44% to 96%. The Secchi depth(SD) increased from 0.08-0.1 m to 1.3-3.2 m for the experiments with five cultivars of aqua-cultured plants. Purification efficiency of eutrophic water correlated significantly, in a positive way, with biomass amount and plant productivity. The Carlson's trophic state indexes decreased from 76 to 21 when the cultivar was Myriophyllum verticillatum, suggesting that Myriophyllum verticillatum can be selected as the plant to remediate karst drainage areas of Guizhou Plateau, where the water body underwent eutrophication. The research results provided a good case for lake environmental management and recovery in karst areas of Yunnan-Guizhou Plateau, China.展开更多
In this work, enzymatic and microbial degradation of organic matter in Lake Hongfeng, Guizhou Province, is described in terms of variations in DNA, α-glucosidase and sulfate-reduction bacteria (SRB). Organic matter i...In this work, enzymatic and microbial degradation of organic matter in Lake Hongfeng, Guizhou Province, is described in terms of variations in DNA, α-glucosidase and sulfate-reduction bacteria (SRB). Organic matter is degraded by microbes and extracellular enzymes excreted by the former, to a relatively low content below the 11-cm sediment depth. The distribution of DNA indicated that microbes are very active at the 9-cm sediment depth, where organic matter is degraded by microbes intensively. The contents of α-glucosidase are highest in suspend layer ({0.75} μmol·min+{-1}·g+{-1} dry sediments), showing that starch and hepatin in organic matter have been degraded intensively. α-glucosidase activity weakens with sediment depth. At the 11-cm depth where the degradation of organic matter started to slow down, α-glucosidase activity has been reduced to {0.17} μmol·min+{-1}·g+{-1} (dry sediment). Molecular biological research indicated that sulfate reduction bacteria (SRB) are distributed mainly at the upper 7-cm sediments in Lake Hongfeng. Combined with the results of research on the variations of organic matter and SO+{2-}-4, it is indicated that SO+{2-}-4 is unlikely to become an important electron acceptor and sulfate reduction is not limited by the supply of organic matter in Lake Hongfeng.展开更多
[Objective] The research aimed to know the ecological environment pollution characteristics of Hongfeng Lake water area and the evolution rule,which provided the theory basis for improving the water quality condition....[Objective] The research aimed to know the ecological environment pollution characteristics of Hongfeng Lake water area and the evolution rule,which provided the theory basis for improving the water quality condition.[Method] Based on the investigation and research of indoor and outdoor,the water quality,aquatic ecosystem,pollution characteristic of sediment and occurrence law of algae blooms in Hongfeng Lake were comprehensively analyzed by combining with the relevant literatures.[Result] Hongfeng Lake was in moderate-heavy eutrophication situation,and the water quality was V-bad V class.The sediment accumulated a lot of nutrient salt,which was the important pollution source of eutrophication in Hongfeng Lake Reservoir.The aquatic ecosystem degraded,and it was easy to form the algae blooms.[Conclusion] The pollution treatment of Hongfeng Lake was extremely urgent.展开更多
Xiayun Township watershed in the upper reaches of Hongfeng Lake is selected to study the relationship between stream grade and water quality.Turbidity and ammonium nitrogen concentration are obviously related to the s...Xiayun Township watershed in the upper reaches of Hongfeng Lake is selected to study the relationship between stream grade and water quality.Turbidity and ammonium nitrogen concentration are obviously related to the stream grade,generally speaking,are positively correlated,and the water quality is degrading from the upper reaches to the lower reaches.In the future,the influence of different land use types on the water quality should be fully analyzed on the basis of enhancing the water quality monitoring to provide supports for effectively controlling non-point source pollutions and treating the water environment of Hongfeng Lake.展开更多
Zn isotope is a useful tool for tracing biogeochemical processes as zinc plays important roles in the biogeochemistry of natural systems. However, the Zn isotope composition in the lake ecosystems has not been well ch...Zn isotope is a useful tool for tracing biogeochemical processes as zinc plays important roles in the biogeochemistry of natural systems. However, the Zn isotope composition in the lake ecosystems has not been well characterized. In order to resolve this problem, we investigate the Zn isotope compositions of suspended particulate matter(SPM) and biological samples collected from the Aha Lake and Hongfeng Lake, and their tributaries in summer and winter, aiming to explore the potential of this novel isotope system as a proxy for biogeochemical processes in aqueous environments. Concentration of dissolved Zn ranges from 0.65 to 5.06 μg/L and 0.74 to 12.04 μg/L for Aha Lake and Hongfeng Lake, respectively, while Zn(SPM) ranges from 0.18 to 0.70 mg/g and 0.24 to 0.75 mg/g for Aha Lake and Hongfeng Lake, respectively. The Zn isotope composition in SPM from Aha Lake and its main tributaries ranges from -0.18‰ to 0.27‰ and -0.17‰ to 0.46‰, respectively, and it varies from -0.29‰ to 0.26‰ and -0.04‰ to 0.48‰, respectively in Hongfeng Lake and its main tributaries, displaying a wider range in tributaries than lakes. These results imply that Zn isotope compositions are mainly affected by tributaries inputting into Aha Lake, while adsorption process by algae is the major factor for the Zn isotope composition in Hongfeng Lake, and ZnS precipitation leads to the light Zn isotope composition of SPM in summer. These data and results provide the basic information of the Zn isotope for the lake ecosystem, and promote the application of Zn isotope in biogeochemistry.展开更多
In situ microscale distributions of 02, H2S, pH and redox potential in sediments of Hongfeng Lake, SW China, were investigated using the powerful microsensor technique. Our results show that O2 was depleted within the...In situ microscale distributions of 02, H2S, pH and redox potential in sediments of Hongfeng Lake, SW China, were investigated using the powerful microsensor technique. Our results show that O2 was depleted within the top 3.9 mm in surface sediments, and H2S was subsequently detected at -6.0 mm depth, and reached its maximum concentrations at -25 mm. The degradation of organic matter and reduction of sulfate might be the major pathways of producing H2S in sediments, pH rapidly reduced in surface layers mainly due to H＋ release in the oxidation of organic matter. Eh also decreased sharply in surface sediments, probabl indicating the coexistence of Fe and Mn oxides with O2 in aerobic region. Furthermore, the programme of PROFILE was applied to model the 02 gradient, and good fit was obtained between the simulative values and the factual values both in sediments and in the diffusive boundary layer （DBL）. The results indicate that the depth-integrated O2 consumption rates within sediments were 0.083 and 0.134 nmol·m-3·s-1 in site S1 and site S2, respectively. In addition, there were distinct DBL in two sediment profiles, with 1.2 mm thickness in S1 and 0.9 mm thickness in S2. The diffusive fluxes of O2 within the DBL were 67.13 nmol·m-2·s-1 in S1 and 88.54 nmol·m-2·s-1 in S2.展开更多
In order to characterize the oxygen isotopic composition of internal phosphate and explore the possibility of using these data to identify phosphate sources, we measured oxygen isotopic compositions of phosphate(δ^(1...In order to characterize the oxygen isotopic composition of internal phosphate and explore the possibility of using these data to identify phosphate sources, we measured oxygen isotopic compositions of phosphate(δ^(18)O_p) in sediment pore water in Hongfeng Lake, a typical deep-water lake in a mountainous area. These data, in combination with δ^(18)O_p in surface water samples and water column samples, were successfully used to identify phosphate sources. The δ^(18)O_p value of sediment pore water ranged from 15.2% to 15.8%, with an average value of 15.5%—the δ^(18)O_p value of internal phosphate. The δ^(18)O_p values decreased gradually through the water column from 19.4% in surface water to 16.4% in deeper water, implying that internal phosphate had more negative δ^(18)O_p values than external phosphate. This finding was substantiated by horizontal variations in δ^(18)O_p values, which decreased with increasing distance from inflowing rivers. All collected evidence suggests that external and internal phosphate have distinctly different isotopic signatures and that these signatures have not been considerably altered by biological mediation in Hongfeng Lake. Therefore, δ^(18)O_p can be used to distinguish phosphate sources. A two-endmember mixing model showed that internal phosphate had an average contribution of 40%, highlighting the influence of internal phosphorus loading on aqueous phosphate and eutrophication. This study illustrates the need to reduce the internal phosphorus load from sediment and provides guidance for nutrient management and in-lake restoration treatment in Hongfeng Lake. The data presented here are limited, but serve to highlight the great potential of δ^(18)O_p as an effective tracer for identifying phosphate sources. Systematic investigations of the oxygen isotopic compositions of external phosphate, internal phosphate, and phosphate through the water column, in combination with in-lake P biogeochemical cycle study, would be desirable in further research.展开更多
The identities and concentrations of low-molecular-weight organic acids （LMWOAs） were determined by ion chromatography throughout a 20-m water column in Hongfeng Lake, China. The spatiotemporal variations of LMWOAs ...The identities and concentrations of low-molecular-weight organic acids （LMWOAs） were determined by ion chromatography throughout a 20-m water column in Hongfeng Lake, China. The spatiotemporal variations of LMWOAs and their contributions to dissolved organic matter （DOM） in a research period of 24 hr were also investigated. The results demonstrated that five LMWOAs （lactic, acetic, pyruvic, sorbic, oxalic acid） were detected, and their total concentration and proportion in DOC were 6.55 μmol/L and 7.47%. Their average levels were 2.50, 0.65, 2.35, 0.96 and 0.09 μmol/L, respectively. LMWOAs were higher during daytime （10：00-18：00 on Jun 13, 2008） than nighttime （21：00-6：00 the next morning）, in particular 4.99 μmol/L high in the epilimnion （ 1 m water depth）, reflecting the fact that direct import from terrigenous sources and photochemical production from humic materials were dominant during LMWOAs＇ origin and accumulation. The same factors caused LMWOAs to be 0.63 μmol/L in the epilimnion higher than in the hypolimnion. The rapid decrease of total organic acid （TOA） up until 18：00 mainly resulted from bio-uptake and mineralization in the hypolimnion （〉1 m water depth）. Pyruvic acid increased with time in the epilimnion and decreased in the hypolimnion, largely related to the two contrary processes of continuous degradation and synthesis of macromolecular organic matter during life materials＇ cycle mediated by organisms. Simultaneously, plankton behavior and thermal stratification played a pivotal role in LMWOAs＇ behavior in the water column, causing decreasing and increasing profiles. The distribution of LMWOAs represents an interesting resource for biogeochemical research of DOM in aquatic ecosystems.展开更多
On the basis of investigating rural population, land types, livestock and poultry breeding scale in drinking water conservation area of the Hongfeng Lake in Guiyang City, as well as the urban domestic pol utant discha...On the basis of investigating rural population, land types, livestock and poultry breeding scale in drinking water conservation area of the Hongfeng Lake in Guiyang City, as well as the urban domestic pol utant discharge coefficient, livestock and poultry excretion coefficient, nitrogen fertilizer and phosphate fertilizer loss rate in the first national pollution source survey, this paper tried to explore current situation of agricultural non-point source pollution, and provide scientific support for the pollution control. The results showed that in the drinking water conservation area of the Hongfeng lake in 2013, contribution rate of pollution sources to the water pollution in the Hongfeng Lake followed the sequence "livestock and poultry breeding > rural life > farmland fertilizer". Among all agricultural non-point source pollutants, livestock and poultry breeding pollutants were major pollution sources, with a contribution rate to CODCr, TP and NH3-N in water above 50%; rural domestic pollutants were also important pollution sources, its contribution rate to CODCr and NH3-N was 43.49% and 46.69%, respectively; contribution rate of farmland fertilizer pollutants to TN and TP was 33.76% and 27.71%, respectively, higher than that of rural domestic pollutants(25.87% and 6.75%). Therefore, the control of non-point source pollution within the drinking water conservation area should be enhanced, so as to control the pollution from the source.展开更多
Hongfeng Lake is an eutrophic freshwater atificial reservior.It began to restore water in 1960. Three sediment cores were taken from both about 25m of water in the center of Hongfeng bake in May 1991. The stratigraphy...Hongfeng Lake is an eutrophic freshwater atificial reservior.It began to restore water in 1960. Three sediment cores were taken from both about 25m of water in the center of Hongfeng bake in May 1991. The stratigraphy of the three cores was easily matched .by using prominent marking horizons and characteristic aqnences of laminations. In three layer Samples studied, diatom and other algae taxa appear in repeating apuences. The presence of laminations may reflect either the regular changes of physical-chemical conditions within the lake or the variation in the intensity of erosion and transport of material from the catchment, pat iculaly where instability in the lake-water system has occult as a result of human activities. The larninations were mainly cantal by seasonal variation of envionmental conditions,particularly climate.Unlike t of the previous examples, they have ben fo￣ at most recent Sediments, in a small freshwater lake in the eastern slOPe of the QinghaiXiZang Plateau, China in a subtropical climate, which is adenly controlled by ￣theastern and southwestern mon￣n. It is believed that it's the first reported instanceOf laminated lake sediments from China.展开更多
基金carried out with funding from the National Key Research and Development Project provided by the Ministry of Science and Technology of China through Grant 2016YFA0601000
文摘The carbon cycle of global inland waters is quantitatively comparable to other components in the global carbon budget. Among inland waters, a significant part is man-made lakes formed by damming rivers. Manmade lakes are undergoing a rapid increase in number and size. Human impacts and frequent algae blooms lead to it necessary to make a better constraint on their carbon cycles. Here, we make a primary estimation on the air–water CO_2 transfer flux through an algae bloom year for a subtropical man-made lake—Hongfeng Lake, Southwest China. To do this a new type of glass bottles was designed for content and isotopic analysis of DIC and other environmental parameters. At the early stage of algae bloom,CO_2 was transferred from the atmosphere to the lake with a net flux of 1.770 g·C·m^(-2). Later, the partial pressure(pCO_2) of the aqueous CO_2 increased rapidly and the lake outgassed to the atmosphere with a net flux of 95.727 g·C·m^(-2). In the remaining days, the lake again took up CO_2 from the atmosphere with a net flux of 14.804 g·C·m^(-2). As a whole, Lake Hongfeng released 4527 t C to the atmosphere, accounting for one-third of the atmosphere/soil CO_2 sequestered by chemical weathering in the whole drainage. With an empirical mode decomposition method, we found air temperature plays a major role in controlling water temperature, aqueous pCO_2 and hence CO_2 flux. This work indicates a necessity to make detailed and comprehensive carbon budgets in man-made lakes.
文摘e penetrative depth in undisturbed surface soil is within 4 mm.7￣Be activity shows exponential decrease with soil depth, which is expressed as a diffusion process.7￣Be penetrative depth in undisturbed surface soil is apparently deeper in the fall (0.22-0.37 g cm￣(-2) than in the spring (0.11-0.28 g cm￣(-2) at the same site; Whereas, ￣7Be apparent activity at the top of surface soil is higher in the spring (0.3-2.2 Bq g￣(-1_) than in the fall (0.2-0.5 Bq g￣(-1) at the same site. The ￣7Be inventory (189-544 Bq m￣(-2) changes with both locations and seasons. Although the ￣7Be flux to the earth's surface increases with amount of precipitation, its maximum inventory in the soil profiles decreases to 30%-40% after the rainy period. Calculated by the diffusion equation, the erosion and accumulation rates of soil particles are agreeable with the observation in situ., which shows that the rates in fall are 1.5 times those in spring. The eroded soil particles almost all have been removed on the tablelands rather than transported into the drainage system. This indicstes that the soil erosion process in the karst region is only partial transportation within a short distance.
基金Supported by the National Natural Science Foundation of China(21767007)the Science and Technology Department of Guizhou Province([2015]3014)the Doctoral Scientific Research Foundation of Guizhou Normal University for 2014
文摘The purification efficiency of eutrophic water by five aqua-cultured plants(Chlorophytum comosum, Salix babylonica, Dracaena sanderiana, Myriophyllum verticillatum, Alternanthera philoxeroides) in Lake Hongfeng, China, was investigated. The results indicated that the biomass of Myriophyllum verticillatum and Alternanthera philoxeroides reached the highest level in 87 days after transplant. The removal efficiencies of total nitrate(TN), total phosphorus(TP), chemical oxygen demand(CODCr), and chlorophyll(Chl-a) by the plants ranged from 44% to 96%. The Secchi depth(SD) increased from 0.08-0.1 m to 1.3-3.2 m for the experiments with five cultivars of aqua-cultured plants. Purification efficiency of eutrophic water correlated significantly, in a positive way, with biomass amount and plant productivity. The Carlson's trophic state indexes decreased from 76 to 21 when the cultivar was Myriophyllum verticillatum, suggesting that Myriophyllum verticillatum can be selected as the plant to remediate karst drainage areas of Guizhou Plateau, where the water body underwent eutrophication. The research results provided a good case for lake environmental management and recovery in karst areas of Yunnan-Guizhou Plateau, China.
文摘In this work, enzymatic and microbial degradation of organic matter in Lake Hongfeng, Guizhou Province, is described in terms of variations in DNA, α-glucosidase and sulfate-reduction bacteria (SRB). Organic matter is degraded by microbes and extracellular enzymes excreted by the former, to a relatively low content below the 11-cm sediment depth. The distribution of DNA indicated that microbes are very active at the 9-cm sediment depth, where organic matter is degraded by microbes intensively. The contents of α-glucosidase are highest in suspend layer ({0.75} μmol·min+{-1}·g+{-1} dry sediments), showing that starch and hepatin in organic matter have been degraded intensively. α-glucosidase activity weakens with sediment depth. At the 11-cm depth where the degradation of organic matter started to slow down, α-glucosidase activity has been reduced to {0.17} μmol·min+{-1}·g+{-1} (dry sediment). Molecular biological research indicated that sulfate reduction bacteria (SRB) are distributed mainly at the upper 7-cm sediments in Lake Hongfeng. Combined with the results of research on the variations of organic matter and SO+{2-}-4, it is indicated that SO+{2-}-4 is unlikely to become an important electron acceptor and sulfate reduction is not limited by the supply of organic matter in Lake Hongfeng.
基金Supported by Department of Education Key Item in Guizhou Province (200910040)Guizhou Province UNRISD Research Item (SY20103176)Guizhou Province Fund Item(20082239)~~
文摘[Objective] The research aimed to know the ecological environment pollution characteristics of Hongfeng Lake water area and the evolution rule,which provided the theory basis for improving the water quality condition.[Method] Based on the investigation and research of indoor and outdoor,the water quality,aquatic ecosystem,pollution characteristic of sediment and occurrence law of algae blooms in Hongfeng Lake were comprehensively analyzed by combining with the relevant literatures.[Result] Hongfeng Lake was in moderate-heavy eutrophication situation,and the water quality was V-bad V class.The sediment accumulated a lot of nutrient salt,which was the important pollution source of eutrophication in Hongfeng Lake Reservoir.The aquatic ecosystem degraded,and it was easy to form the algae blooms.[Conclusion] The pollution treatment of Hongfeng Lake was extremely urgent.
文摘Xiayun Township watershed in the upper reaches of Hongfeng Lake is selected to study the relationship between stream grade and water quality.Turbidity and ammonium nitrogen concentration are obviously related to the stream grade,generally speaking,are positively correlated,and the water quality is degrading from the upper reaches to the lower reaches.In the future,the influence of different land use types on the water quality should be fully analyzed on the basis of enhancing the water quality monitoring to provide supports for effectively controlling non-point source pollutions and treating the water environment of Hongfeng Lake.
基金supported by the National Natural Science Foundation of China(No.40903005)
文摘Zn isotope is a useful tool for tracing biogeochemical processes as zinc plays important roles in the biogeochemistry of natural systems. However, the Zn isotope composition in the lake ecosystems has not been well characterized. In order to resolve this problem, we investigate the Zn isotope compositions of suspended particulate matter(SPM) and biological samples collected from the Aha Lake and Hongfeng Lake, and their tributaries in summer and winter, aiming to explore the potential of this novel isotope system as a proxy for biogeochemical processes in aqueous environments. Concentration of dissolved Zn ranges from 0.65 to 5.06 μg/L and 0.74 to 12.04 μg/L for Aha Lake and Hongfeng Lake, respectively, while Zn(SPM) ranges from 0.18 to 0.70 mg/g and 0.24 to 0.75 mg/g for Aha Lake and Hongfeng Lake, respectively. The Zn isotope composition in SPM from Aha Lake and its main tributaries ranges from -0.18‰ to 0.27‰ and -0.17‰ to 0.46‰, respectively, and it varies from -0.29‰ to 0.26‰ and -0.04‰ to 0.48‰, respectively in Hongfeng Lake and its main tributaries, displaying a wider range in tributaries than lakes. These results imply that Zn isotope compositions are mainly affected by tributaries inputting into Aha Lake, while adsorption process by algae is the major factor for the Zn isotope composition in Hongfeng Lake, and ZnS precipitation leads to the light Zn isotope composition of SPM in summer. These data and results provide the basic information of the Zn isotope for the lake ecosystem, and promote the application of Zn isotope in biogeochemistry.
基金supported by the National Natural Science Foundation of China (Nos.41173125 and 41403113)
文摘In situ microscale distributions of 02, H2S, pH and redox potential in sediments of Hongfeng Lake, SW China, were investigated using the powerful microsensor technique. Our results show that O2 was depleted within the top 3.9 mm in surface sediments, and H2S was subsequently detected at -6.0 mm depth, and reached its maximum concentrations at -25 mm. The degradation of organic matter and reduction of sulfate might be the major pathways of producing H2S in sediments, pH rapidly reduced in surface layers mainly due to H＋ release in the oxidation of organic matter. Eh also decreased sharply in surface sediments, probabl indicating the coexistence of Fe and Mn oxides with O2 in aerobic region. Furthermore, the programme of PROFILE was applied to model the 02 gradient, and good fit was obtained between the simulative values and the factual values both in sediments and in the diffusive boundary layer （DBL）. The results indicate that the depth-integrated O2 consumption rates within sediments were 0.083 and 0.134 nmol·m-3·s-1 in site S1 and site S2, respectively. In addition, there were distinct DBL in two sediment profiles, with 1.2 mm thickness in S1 and 0.9 mm thickness in S2. The diffusive fluxes of O2 within the DBL were 67.13 nmol·m-2·s-1 in S1 and 88.54 nmol·m-2·s-1 in S2.
基金financially supported by the National Key Research and Development Project by MOST of China(No.2016YFA0601003)the National Natural Science Foundation of China(Nos.U1612441 and 41173125)Science and Technology Project of Guizhou Province
文摘In order to characterize the oxygen isotopic composition of internal phosphate and explore the possibility of using these data to identify phosphate sources, we measured oxygen isotopic compositions of phosphate(δ^(18)O_p) in sediment pore water in Hongfeng Lake, a typical deep-water lake in a mountainous area. These data, in combination with δ^(18)O_p in surface water samples and water column samples, were successfully used to identify phosphate sources. The δ^(18)O_p value of sediment pore water ranged from 15.2% to 15.8%, with an average value of 15.5%—the δ^(18)O_p value of internal phosphate. The δ^(18)O_p values decreased gradually through the water column from 19.4% in surface water to 16.4% in deeper water, implying that internal phosphate had more negative δ^(18)O_p values than external phosphate. This finding was substantiated by horizontal variations in δ^(18)O_p values, which decreased with increasing distance from inflowing rivers. All collected evidence suggests that external and internal phosphate have distinctly different isotopic signatures and that these signatures have not been considerably altered by biological mediation in Hongfeng Lake. Therefore, δ^(18)O_p can be used to distinguish phosphate sources. A two-endmember mixing model showed that internal phosphate had an average contribution of 40%, highlighting the influence of internal phosphorus loading on aqueous phosphate and eutrophication. This study illustrates the need to reduce the internal phosphorus load from sediment and provides guidance for nutrient management and in-lake restoration treatment in Hongfeng Lake. The data presented here are limited, but serve to highlight the great potential of δ^(18)O_p as an effective tracer for identifying phosphate sources. Systematic investigations of the oxygen isotopic compositions of external phosphate, internal phosphate, and phosphate through the water column, in combination with in-lake P biogeochemical cycle study, would be desirable in further research.
基金supported by the National Basic Research Program (973) of China (No.2008CB418200,2008CB418000)the National Natural Science Foundation of China (No.41003055, U0833603, 40632011,40873080)the Chinese Research Academy of Environmental Sciences (No.2007KYYW01)
文摘The identities and concentrations of low-molecular-weight organic acids （LMWOAs） were determined by ion chromatography throughout a 20-m water column in Hongfeng Lake, China. The spatiotemporal variations of LMWOAs and their contributions to dissolved organic matter （DOM） in a research period of 24 hr were also investigated. The results demonstrated that five LMWOAs （lactic, acetic, pyruvic, sorbic, oxalic acid） were detected, and their total concentration and proportion in DOC were 6.55 μmol/L and 7.47%. Their average levels were 2.50, 0.65, 2.35, 0.96 and 0.09 μmol/L, respectively. LMWOAs were higher during daytime （10：00-18：00 on Jun 13, 2008） than nighttime （21：00-6：00 the next morning）, in particular 4.99 μmol/L high in the epilimnion （ 1 m water depth）, reflecting the fact that direct import from terrigenous sources and photochemical production from humic materials were dominant during LMWOAs＇ origin and accumulation. The same factors caused LMWOAs to be 0.63 μmol/L in the epilimnion higher than in the hypolimnion. The rapid decrease of total organic acid （TOA） up until 18：00 mainly resulted from bio-uptake and mineralization in the hypolimnion （〉1 m water depth）. Pyruvic acid increased with time in the epilimnion and decreased in the hypolimnion, largely related to the two contrary processes of continuous degradation and synthesis of macromolecular organic matter during life materials＇ cycle mediated by organisms. Simultaneously, plankton behavior and thermal stratification played a pivotal role in LMWOAs＇ behavior in the water column, causing decreasing and increasing profiles. The distribution of LMWOAs represents an interesting resource for biogeochemical research of DOM in aquatic ecosystems.
基金Sponsored by Significant Scientific and Technological Program of Guizhou Province([2015]2001)
文摘On the basis of investigating rural population, land types, livestock and poultry breeding scale in drinking water conservation area of the Hongfeng Lake in Guiyang City, as well as the urban domestic pol utant discharge coefficient, livestock and poultry excretion coefficient, nitrogen fertilizer and phosphate fertilizer loss rate in the first national pollution source survey, this paper tried to explore current situation of agricultural non-point source pollution, and provide scientific support for the pollution control. The results showed that in the drinking water conservation area of the Hongfeng lake in 2013, contribution rate of pollution sources to the water pollution in the Hongfeng Lake followed the sequence "livestock and poultry breeding > rural life > farmland fertilizer". Among all agricultural non-point source pollutants, livestock and poultry breeding pollutants were major pollution sources, with a contribution rate to CODCr, TP and NH3-N in water above 50%; rural domestic pollutants were also important pollution sources, its contribution rate to CODCr and NH3-N was 43.49% and 46.69%, respectively; contribution rate of farmland fertilizer pollutants to TN and TP was 33.76% and 27.71%, respectively, higher than that of rural domestic pollutants(25.87% and 6.75%). Therefore, the control of non-point source pollution within the drinking water conservation area should be enhanced, so as to control the pollution from the source.
文摘Hongfeng Lake is an eutrophic freshwater atificial reservior.It began to restore water in 1960. Three sediment cores were taken from both about 25m of water in the center of Hongfeng bake in May 1991. The stratigraphy of the three cores was easily matched .by using prominent marking horizons and characteristic aqnences of laminations. In three layer Samples studied, diatom and other algae taxa appear in repeating apuences. The presence of laminations may reflect either the regular changes of physical-chemical conditions within the lake or the variation in the intensity of erosion and transport of material from the catchment, pat iculaly where instability in the lake-water system has occult as a result of human activities. The larninations were mainly cantal by seasonal variation of envionmental conditions,particularly climate.Unlike t of the previous examples, they have ben fo￣ at most recent Sediments, in a small freshwater lake in the eastern slOPe of the QinghaiXiZang Plateau, China in a subtropical climate, which is adenly controlled by ￣theastern and southwestern mon￣n. It is believed that it's the first reported instanceOf laminated lake sediments from China.
