Developing efficient photocatalysts to address collaborative energy and environmental crises still faces significant challenges.In this report,we present a highly efficient MXene–based photocatalyst,which is combined...Developing efficient photocatalysts to address collaborative energy and environmental crises still faces significant challenges.In this report,we present a highly efficient MXene–based photocatalyst,which is combined with MoS_(2)nano patches and TiO_(2)/Ti_(3)C_(2)(TTC)nanowires through hydrothermal treatment.Of all the composites tested,the optimized photocatalyst gave a remarkable H_(2)and revolving polylactic acid(PLA)into pyruvic acid(PA).Achieving a remarkable H_(2)evolution rate of 637.1 and 243.2μmol g^(−1)h^(−1),in the presence of TEOA and PLA as a sacrificial reagent under UV-vis(λ≥365 nm)light irradiation.The improved photocatalytic activity is a result of the combination of dual cocatalyst on the surface of TTC photocatalyst,which create an ideal synergistic effect for the generation of PA and the production of H_(2)simultaneously.The MoS_(2)TiO_(2)/Ti_(3)C_(2)(MTT)composite can generate more photoexcited charge carriers,leading to the generation of more active radicals,which may enhance the system's photocatalytic activity.This work aims at demonstrating its future significance and guide the scientific community towards a more efficient approach to commercializing H_(2)through photocatalysis.展开更多
The increasing deployment of electronics in everyday life has generated great concerns regarding the effective disposal of waste from these components.Here,we focused on a facile sustainable and economical strategy to...The increasing deployment of electronics in everyday life has generated great concerns regarding the effective disposal of waste from these components.Here,we focused on a facile sustainable and economical strategy to provide ideas for this issue.This strategy relied on using appropriate mechanical treatment and sodium lignosulfonate coating to improve the dispersion and interfacial compatibility of bamboo fibers in poly(lactic acid).By optimising the particle size and concentration of sodium lignosulphonate,high value-added and green composites were prepared using sectional pressurization with a venting procedure.The treated composite displayed an ultra-smooth surface(roughness of 0.592 nm),impressive transient properties(disintegration and degradation behaviour after 30 d),and outstanding ultraviolet(UV)shielding properties(100%).These properties hold the promise of being an excellent substrate for electronic devices,especially for high-precision processing,transient electronics,and UV damage prevention.The satisfactory interfacial compatibility of the composites was confirmed by detailed characterisation regarding the related physicochemical properties.This investigation offers a sustainable approach for producing high value-added green composites from biomass and biomass-derived materials.展开更多
This study examined the effects of pasteurization(PAS),ultrasonic sterilization(ULS),and microwave sterilization(MWS)on the quality and storage characteristics of brine-fermented tofu(BFT)and fermented tofu(FT).Compar...This study examined the effects of pasteurization(PAS),ultrasonic sterilization(ULS),and microwave sterilization(MWS)on the quality and storage characteristics of brine-fermented tofu(BFT)and fermented tofu(FT).Comparative analysis revealed that MWS had a negligible detrimental effect on the structural integrity and organoleptic properties of BFT and FT,while effectively maintaining its water-holding capacity(WHC)and exhibiting the least impact on its texture.In contrast,PAS and ULS increased hardness and chewiness significantly(P<0.05),but ULS also enhanced the brightness of tofu.Throughout the storage period,the WHC,elasticity,and sensory properties of tofu generally decreased,whereas the hardness and chewiness increased.PAS-BFT and MWS-FT maintained sensory quality for the longest periods of 14 and 12 days respectively,and could be decomposed to more small molecule peptides within 0–8 days and 0–6 days,which are more easily to be absorbed by the body.The findings discovered that MWS is the most suitable method for sterilization of tofu,with superior capability in maintaining the quality,extending shelf life,and improving digestibility of tofu.展开更多
Photocatalytic selective synthesis of lactic acid(LA)from biomass sugars with a single heterogeneous catalyst is promising but challenging due to the multiple reaction steps involved.Herein,a K-doped C-rich red polyme...Photocatalytic selective synthesis of lactic acid(LA)from biomass sugars with a single heterogeneous catalyst is promising but challenging due to the multiple reaction steps involved.Herein,a K-doped C-rich red polymerized carbon nitride(RPCN)photocatalyst with uniform K/C dual sites was constructed by a molten salt template method,which was highly efficient for cascade isomerization dehydration of glucose to LA with>90%selectivity under visible light and gentle conditions.Control experiments and theoretical calculations expounded that the introduced K/C dual sites could improve the light capture ability and photogenerated charge separation efficiency,while the K species provided sufficient Lewis acid sites(adsorption sites)for the isomerization of glucose to fructose.Meanwhile,the introduced C sites that substitute N atoms could promote electrons to be captured by adsorbed oxygen for selective generation of superoxide radicals,which was highly efficient for the scission of the C3-C4 bond in fructose,exclusively furnishing LA.Importantly,the RPCN photocatalyst was also suitable for the photocatalytic upgrading of various biomass saccharides into LA with high yields of 81.3%-95.3%and could be recycled for five consecutive cycles.The tailored construction of dual sites by localization of space charge lightens an avenue for multi-step conversion of biomass with pronounced selectivity.展开更多
Photocatalytic transformation of biomass into biofuels and value-added chemicals is of great significance for carbon neutrality.Metal-free carbon nitride has extensive applications but with almost no absorption and ut...Photocatalytic transformation of biomass into biofuels and value-added chemicals is of great significance for carbon neutrality.Metal-free carbon nitride has extensive applications but with almost no absorption and utilization of near-infrared light,accounting for 50%of sunlight.Here,a molten salt-assisted in-plane“stitching”and interlayer“cutting”protocol is developed for constructing a highly crystalline carbon nitride catalyst containing structural oxygen(HC-CN).HC-CN is highly efficient for the photothermal cascade transformation of biomass-derived glucose into lactic acid(LA)with an unprecedented yield(94.3%)at 25°C under full-spectrum light irradiation within 50 min,which is also applicable to quantitatively photo-upgrading various saccharides.Theoretical calculations expound that the light-induced glucose-to-catalyst charge transfer can activate the Cβ-H bond to promote the rate-determining step of intramolecular hydrogen shift in glucose-to-fructose isomerization.Meanwhile,the introduced structural oxygen in HC-CN can not only facilitate the local electric field formation to achieve rapid charge transport/separation and regulate selective·O^(-)_(2)generation for oriented C3-C4 bond cleavage of fructose but also narrow the energy band gap to broaden the light absorption range of HC-CN,contributing to enhanced LA production without exogenous heating.Moreover,HC-CN is highly recyclable and exhibits negligible environmental burden and low energy consumption,as disclosed by the life cycle assessment.Tailored construction of full-spectrum light adsorption and versatile reaction sites provides a reference for implementing multi-step biomass and organic conversion processes under mild conditions.展开更多
This article provided a preparation protocol for poly(lactic acid)(PLA)/modified epoxidized soybean oil(ECP)/nano-magnesium oxide(n-MgO)ternary composites and studied their mechanical and antibacterial properties.By m...This article provided a preparation protocol for poly(lactic acid)(PLA)/modified epoxidized soybean oil(ECP)/nano-magnesium oxide(n-MgO)ternary composites and studied their mechanical and antibacterial properties.By means of an organic synthesis technique,epoxidized soybean oil(ESO)is chemically grafted to PLA to synthesize ESO chemically plastically modified PLA,abbreviated ECP.To fabricate PLA/ECP/n-MgO composite materials,ECP acts as a plasticizer and a compatibilizer simultaneously,and n-MgO acts as an enhancer.Then scanning electron microscopy,X-ray diffraction,differential scanning calorimetry,universal tester,and antibacterial research were exploited to characterize the morphology,thermal resistance,mechanical properties,and antibacterial performance of PLA/ECP/n-MgO composites.The experimental results show that ECP acts as a plasticizer by causing heterogeneous nucleation,which increases PLA's crystallinity.Evenly distributed n-MgO can greatly improve PLA's antibacterial qualities.Furthermore,ECP and n-MgO work together to improve the positive aspects of PLA/ECP/n-MgO composites,with PLA/ECP/n-MgO 100/1/0.5 composites having the best overall properties.While improving the mechanical performance and toughness of PLA,this work offers a prospective approach and foundational database for the creation of multifunctional biodegradable composites.展开更多
Hyperuricemia(HUA)is characterized by elevated levels of uric acid(UA)in the bloodstream,resulting from either excessive production or insufficient excretion of UA within the body.If left untreated,progressive or pers...Hyperuricemia(HUA)is characterized by elevated levels of uric acid(UA)in the bloodstream,resulting from either excessive production or insufficient excretion of UA within the body.If left untreated,progressive or persistent HUA can lead to gout,causing significant harm to human health.Lactic acid bacteria(LAB),generally recognized as safe(GRAS)probiotics,have been shown to alleviate symptoms associated with gastrointestinal disorders such as irritable bowel syndrome and inflammatory bowel disease while supporting overall bodily functions and health.Recently,LAB has emerged as a potentially safe,cost-effective and efficient treatment for HUA.This comprehensive review aims to explore the current literature on the mechanisms through which LAB controls HUA.These mechanisms include suppressing purine metabolism,absorbing purine compounds,modulating microbiota to maintain host global purine homeostasis,reducing intestinal permeability,producing metabolites that alleviate HUA symptoms,promoting the expression of urate excretory proteins and inhibiting the expression of urate reabsorption proteins.The findings presented in this review provide a framework for further investigation into how probiotic LAB can alleviate HUA by influencing UA metabolism and elucidating their underlying action mechanisms.展开更多
To retain its inherent biodegradability,simultaneously improving the strength and toughness of poly(lactic acid)(PLA)is a significant challenge.In this study,we propose an innovative multiple dynamic pressure(MDP)proc...To retain its inherent biodegradability,simultaneously improving the strength and toughness of poly(lactic acid)(PLA)is a significant challenge.In this study,we propose an innovative multiple dynamic pressure(MDP)process that can produce pure PLA with excellent mechanical properties.The MDP process generates a dynamic stretching effect by regulating the application and release of pressure,prompting disordered molecular chains to be arranged regularly along the direction of the dynamic force field.This promoted the formation of more ordered crystal forms(α-form)and strengthened the connection between the crystalline and amorphous regions.Results show that after MDP treatment,the tensile strength and strain at break of MDP-PLA are significantly improved,reaching 91.6 MPa and 80.1%respectively,which are 49.4%higher and 10 times higher than those of the samples before treatment.The mechanical properties of MDP-PLA can be regulated as needed by adjusting the cycle times and peak pressure.In addition,through a systematic study of the structural evolution of MDP-PLA,the performance regulation mechanism of the MDP process was thoroughly investigated,and the internal relationship among the process-structure-performance was clarified.This research not only opens a new technical path for the preparation of high-performance pure PLA but also provides important guidance for the high-performance modification of other semi-crystalline polymers,thus possessing significant scientific and engineering value.展开更多
Poly(lactic acid)(PLA),a bio-based polymer,is considered to be a sustainable alternative to conventional petroleum-based plastics.However,owing to its widespread use and relatively slow degradation rate in water,PLA s...Poly(lactic acid)(PLA),a bio-based polymer,is considered to be a sustainable alternative to conventional petroleum-based plastics.However,owing to its widespread use and relatively slow degradation rate in water,PLA still poses potential environmental pollution risks after being discarded.The efficient chemical recycling of PLA represents an attractive approach to addressing both resource reuse and environmental pollution challenges caused by its waste.Hydrolysis is the predominant method of industrial recycling.However,because PLA is insoluble in water,efficient heterogeneous hydrolysis requires high-temperature and high-pressure conditions.In this study,an efficient homogenous hydrolysis method capable of simultaneously dissolving PLA and calcium hydroxide(Ca(OH)_(2))was developed.Suitable solvents for this method were screened,and it was found that PLA hydrolysis using dioxane and 1,4,7,10,13-Pen-taoxacyclopentadecane as solvents achieved conversion rates of 93%and 90%,respectively,within 2 h at room temperature.Notably,the hydrolysis product,calcium lactate,precipitated as a solid from the solvent and therefore self-separated from the reaction solution.The solvent,acid/base conditions,water content,and depolymerization kinetics were investigated.Compared with previously reported hydrolysis methods,the enhanced efficiency observed in this study can be attributed to the concurrent solvation of PLA and Ca(OH)_(2),which maintains homogeneity throughout the reaction process.Additionally,this method facilitates closed-loop recycling of PLA and is compatible with the highly selective recovery of PLA from various types of PLA products.展开更多
Lactic acid bacteria(LAB)exopolysaccharides(EPS)reveal high safety and multiple activities,and are typical postbiotics produced by LAB during fermentation.In this paper,6583 articles on LAB-EPS from Web of Science and...Lactic acid bacteria(LAB)exopolysaccharides(EPS)reveal high safety and multiple activities,and are typical postbiotics produced by LAB during fermentation.In this paper,6583 articles on LAB-EPS from Web of Science and Elsevier databases were retrieved,and 236 articles related to this review were screened.The EPS from 90 LAB strains were summarized in terms of their extraction methods,yield,molecular weight,monosaccharide composition,glycosidic bond configuration and the structural and activity relationships(SARs).However,there exist great challenges as for the low yield and high cost in EPS production.Therefore,this review further elaborated the mechanism of EPS secretion,the anabolic pathway of EPS,the structure and mechanism of key enzymes involving in EPS synthesis process,the prospect of gene regulation for EPS secretion,and proposed the engineering strategies for increasing EPS yield or tailored EPS design in recent years.In addition,CRISPR/Cas9 gene editing technology was also discussed in the production control of EPS in LAB.Finally,the engineering strategy of increasing EPS yield in recent years was proposed.This work might provide important theoretical support for the production and application of LAB-based EPS.展开更多
BACKGROUND The central link between septic shock and acute skin failure(ASF)is the inflammatory response,which occurs throughout disease progression and can lead to systemic inflammatory response syndrome.Patients oft...BACKGROUND The central link between septic shock and acute skin failure(ASF)is the inflammatory response,which occurs throughout disease progression and can lead to systemic inflammatory response syndrome.Patients often experience bad moods,sleep disorders,and other health issues.Despite recognizing these factors,no studies have examined the correlation between inflammatory factors,lactic acid levels,ASF,mood disturbances,and sleep quality in critically ill patients.We hypothesize that higher levels of inflammatory factors and lactic acid are associated with more severe ASF and poorer mood and sleep quality,which may inform clinical treatment for septic shock and ASF.AIM To explore the relationship between inflammatory factors,lactic acid levels,the severity of ASF,bad mood,and sleep quality.METHODS The retrospective study included 150 patients with septic shock from the Second Hospital of Dalian Medical University,categorized into ASF(n=35)or non-ASF groups(n=115).We compared the peripheral blood inflammatory factors,including tumor necrosis factor-α(TNF-α),C-reactive protein(CRP),interleukin-6(IL-6),lactic acid levels,skin mottling score(SMS),modified early warning score(MEWS),self-rating depression scale(SDS),self-rating anxiety scale(SAS),and Pittsburgh sleep quality index(PSQI)scores.Pearson correlation analysis assessed relationships among these variables.RESULTS The ASF group had significantly higher levels of CRP(19.60±4.10 vs 15.30±2.96 mg/mL),IL-6(298.65±48.65 vs 268.66±33.66 pg/L),procalcitonin,lactic acid(8.42±2.32 vs 5.70±1.27 mmol/L),SMS[0(0,1)vs 3(2,3)],MEWS(9.34±1.92 vs 6.48±1.96),SAS(61.63±12.03 vs 53.71±12.48),SDS(60.17±12.64 vs 52.27±12.64),and PSQI scores(14.23±3.94 vs 8.69±2.46)compared with the non-ASF group(all P<0.001).Pearson correlation analysis revealed that IL-6,CRP,TNF-α,and lactic acid were positively correlated with SMS,MEWS,SAS,SDS,and PSQI scores(P<0.05).CONCLUSION Peripheral blood levels of IL-6,CRP,TNF-α,and lactic acid correlate positively with SMS,MEWS,SAS,SDS,and PSQI in critically ill patients with ASF.展开更多
AIM:To develop a 5-fluorouracil(5-FU)mesoporous poly(lactic)acid(PLA)delivery system for glaucoma filtration surgery suitable for a single subconjunctival implantation.METHODS:The 5-FU was infiltration-loaded into mes...AIM:To develop a 5-fluorouracil(5-FU)mesoporous poly(lactic)acid(PLA)delivery system for glaucoma filtration surgery suitable for a single subconjunctival implantation.METHODS:The 5-FU was infiltration-loaded into mesoporous PLA.In vitro and in vivo release experiments and ocular toxicology evaluation of the formulation were performed.The antiproliferative effect of this 5-FU-PLA tablet after glaucoma filtration surgery in rabbits was evaluated.Pathology,immunohistochemistry,and Western blot were used to further validate the inhibitory effect of this sustained release system.RESULTS:Various drug formulations were tested,and two 5-FU-PLA tablets,namely 1.5P15(5-FU 1.5 mg+PLA 15000 Da)and 2.5P15(5-FU 2.5 mg+PLA 15000 Da),had the most suitable release profiles in vitro.Further in vivo studies confirmed the safety and sustained-release profiles of both drugs.Both 5-FU-PLA tablets,relative to the free drugs,significantly inhibited tissue proliferation after glaucoma filtration and improved surgical success.Western blot showed that transforming growth factor-β(TGF-β)and connective tissue growth factor(CTGF)were inhibited by 5-FU after filtration surgery,with the effects of the 5-FU-PLA tablets being more lasting.CONCLUSION:The tested 5-FU-PLA tablets provide a sustained release of 5-FU,which may be used for a single subconjunctival implantation to inhibit proliferation after filtration surgery.展开更多
The continuous improvement in patient care and recovery is driving the development of innovative materials for medical applications.Medical sutures,essential for securing implants and closing deep wounds,have evolved ...The continuous improvement in patient care and recovery is driving the development of innovative materials for medical applications.Medical sutures,essential for securing implants and closing deep wounds,have evolved to incorporate smart materials capable of responding to various stimuli.This study explores the potential of thermoresponsive sutures,made from shape memory materials,that contract upon heating to bring loose stitches closer together,promoting optimal wound closure.We developed nanocomposites based on a blend of poly(lactic acid)(PLA)and thermoplastic polyurethane(TPU)—biopolymers that inherently exhibit shape memory—enhanced with carbon nanotubes(CNT)and graphene nanoplatelets(GN)to improve mechanical performance.PLA/TPU(50/50)nanocomposites were prepared with 1 and 2 wt%GN,as well as hybrid formulations combining 1 wt%CNT with 1 or 2 wt%GN,using a twin-screw extrusion process to form filaments.These filaments were characterized through differential scanning calorimetry(DSC),field emission gun scanning electron microscopy(FEG-SEM),tensile testing,and shape memory assessments.While the PLA/TPU blend is immiscible,TPU enhances the crystallinity(X_(c))of the PLA phase,further increased by the addition of CNT and GN.FEG-SEM images indicate CNTs primarily in the PLA phase and GN in the TPU phase.PLA/TPU with 1 or 2 wt%GN showed the highest potential for suture applications,with a high elastic modulus(~1000 MPa),significant strain at break(~10%),and effective shape recovery(~20%at 55℃ for 30 min).These findings suggest that these nanocomposites can enhance suture performance with controlled shape recovery that is suitable for medical use.展开更多
The conversion of waste polylactic acid(PLA)plastics into high-value-added chemicals through electrochemical methods is a promising and sustainable approach.However,developing efficient and highly selective catalysts ...The conversion of waste polylactic acid(PLA)plastics into high-value-added chemicals through electrochemical methods is a promising and sustainable approach.However,developing efficient and highly selective catalysts for lactic acid oxidation reaction(LAOR)and understanding the reaction process are challenging.Here,we report the electrooxidation of waste PLA to acetate at a high current density of 100 mA cm-2 with high Faraday efficiency(~95%)and excellent stability(>100 h)over a nickel selenide nanosheet catalyst.In addition,a total Faraday efficiency of up to 190%was achieved for carboxylic acids,including acetic acid and formic acid,by coupling with the cathodic CO_(2) reduction reaction.In situ experimental results and theoretical simulations revealed that the catalytic activity center of LAOR was dynamically formed NiOOH species,and the surface-adsorbed SeO_(x) species accelerated the formation of Ni~(3+)species,thus promoting catalytic activity.The mechanism of lactic acid electrooxidation was further elucidated.Lactic acid was dehydrogenated to produce pyruvate first and then formed CH_3CO due to preferential C-C bond cleavage,resulting in the presence of acetate.This work demonstrated a sustainable method for recycling waste PLA and CO_(2) into high-value-added products.展开更多
Ni-rich layered oxides are potential cathode materials for next-generation high energy density Li-ion batteries due to their high capacity and low cost.However,the inherently unstable surface properties,including high...Ni-rich layered oxides are potential cathode materials for next-generation high energy density Li-ion batteries due to their high capacity and low cost.However,the inherently unstable surface properties,including high levels of residual Li compounds,dissolution of transition metal cations,and parasitic side reactions,have not been effectively addressed,leading to significant degradation in their electrochemical performance.In this study,we propose a simple and effective lactic acid-assisted interface engineering strategy to regulate the surface chemistry and properties of Ni-rich LiNi_(0.8)Co_(0.1)Mr_(0.1)O_(2) cathode.This novel surface treatment method successfully eliminates surface residual Li compounds,inhibits structural collapse,and mitigates cathode-electrolyte interface film growth.As a result,the lactic acidtreated LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) achieved a remarkable capacity retention of 91.7% after 100 cycles at 0.5 C(25℃) and outstanding rate capability of 149.5 mA h g^(-1) at 10 C,significantly outperforming the pristine material.Furthermore,a pouch-type full cell incorporating the modified LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) cathode demonstrates impressive long-term cycle life,retaining 81.5% of its capacity after 500 cycles at 1 C.More importantly,the thermal stability of the modified cathode is also dramatically improved.This study offers a valuable surface modification strategy for enhancing the overall performance of Ni-rich cathode materials.展开更多
For a polymer/polymer dismissible blend with two crystallizable components,the crystallization behavior of different components and the reciprocal influences between different crystals are interesting and important,bu...For a polymer/polymer dismissible blend with two crystallizable components,the crystallization behavior of different components and the reciprocal influences between different crystals are interesting and important,but did not investigate in detail.In this study,the L-poly(lactic acid)/polypropylene(PLLA/PP)blends with different weight ratios were prepared by melt mixing and the crystallization behavior of the blends were investigated.Results showed that the crystalline structures of PLLA and PP were not altered by the composition.For the crystallization of PLLA,both the diffusion of chain segments and crystallization rate were enhanced under the existence of PP crystals.For the crystallization of PP,its crystallization rate was depressed under the existence of amorphous PLLA molecular chains.When the PP crystallized from the existence of PLLA crystals,although the diffusion rate of PP was reduced by PLLA crystals,the nucleation positions were obviously enhanced,which accelerated the formation of PP crystals.This investigation would supply more basic data for the application of PLLA/PP blend.展开更多
In actual physiological environments,bacteria can activate the immune system and release lactic acid.However,the detailed contribution of lactic acid to the passivation behavior of titanium(Ti)alloys is still unclear....In actual physiological environments,bacteria can activate the immune system and release lactic acid.However,the detailed contribution of lactic acid to the passivation behavior of titanium(Ti)alloys is still unclear.The current work investigated the in vitro passivation behavior of Ti-6Al-4V(TC4)alloys fabricated by laser powder bed fusion in Hank's solution with and without adding lactic acid.Electrochemical methods,inductively coupled plasma atomic emission spectrometer,and X-ray photoelectron spectroscopy were jointly used.Adding lactic acid decreases the corrosion resistance of samples by degrading the formed passive film.The film formed in the(lactic acid)-containing solution exhibits a higher level of oxygen vacancies and a lower thickness,attributed to the suppressed formation of Ti^(4+)transformed from Ti^(3+)and Ti^(2+).Moreover,the presence of lactic acid would increase the open circuit potential,relieve the ions release,and hinder the deposition of calcium phosphates within 24 h immersion.展开更多
The effects of 5 lactic acid bacteria(LAB)fermentation on the pasting properties of glutinous rice flour were compared,and suitable fermentation strains were selected based on the changes of viscosity,setback value,an...The effects of 5 lactic acid bacteria(LAB)fermentation on the pasting properties of glutinous rice flour were compared,and suitable fermentation strains were selected based on the changes of viscosity,setback value,and breakdown value to prepare LAB compound starter cultures.The results revealed that Latilactobacillus sakei HSD004 and Lacticaseibacillus rhamnosus HSD005 had apparent advantages in increasing the viscosity and reducing the setback and breakdown values of glutinous rice flour.In particular,the compound starter created using the two abovementioned LAB in the ratio of 3:1 had better performance than that using a single LAB in improving the pasting properties and increasing the water and oil absorption capacity of glutinous rice flour.Moreover,the gelatinization enthalpy of the fermented samples increased significantly.For frozen glutinous rice dough stored for 28 days,the viscoelasticity of frozen dough prepared by compound starter was better than that of control dough,and the freezable water content was lower than that of control dough.These results indicate that compound LAB fermentation is a promising technology in the glutinous rice-based food processing industry,which has significance for its application.展开更多
The effects of the co-inoculation of Debaryomyces hansenii separately with 3 lactic acid bacteria(LAB),Lactobacillus sakei,Lactobacillus plantarum and Lactobacillus curvatus,on the taste and odour profi les of dry sau...The effects of the co-inoculation of Debaryomyces hansenii separately with 3 lactic acid bacteria(LAB),Lactobacillus sakei,Lactobacillus plantarum and Lactobacillus curvatus,on the taste and odour profi les of dry sausages were investigated.The co-inoculated sausages showed higher free amino acid and organic acid contents than the non-inoculated control and sausages inoculated with D.hansenii alone.Meanwhile,the sausages inoculated with D.hansenii+L.plantarum,D.hansenii+L.sakei and D.hansenii+L.curvatus had the highest contents of aldehydes,esters and alcohols,respectively.The results of electronic tongue,electronic nose and sensory evaluation demonstrated that compared with the sausage inoculated with D.hansenii,the sour taste and fl oral odour increased and the fatty odour decreased in the sausage inoculated with D.hansenii+L.sakei;this was more favourable for the development of a desirable fl avour in sausages.Moreover,the partial least squares regression analysis indicated that 10 taste and 33 odour compounds were mainly responsible for the differences in the flavour profiles among the sausages.Overall,these findings contributed to a more comprehensive understanding of the formation of sensory characteristics in dry sausages co-inoculated with yeast and LAB.展开更多
Star-shaped poly(lactic acid)s(PLAs)with two to five arms were synthesized by ring opening polymerization using tin(II)2-ethylhexanoate as catalyst and polyols as initiators.The effects of molecular weight together wi...Star-shaped poly(lactic acid)s(PLAs)with two to five arms were synthesized by ring opening polymerization using tin(II)2-ethylhexanoate as catalyst and polyols as initiators.The effects of molecular weight together with multi-arm architecture on crystallization behavior,spherulite morphology and alkaline degradation behavior of star-shaped PLAs have been investigated.The results indicate that the multi-arm architecture interfered with spherulite growth,but promoted nucleation and alkaline degradation of star-shaped PLAs.Interestingly,with the increase of molecular weight(M_(n)),the crystallization rate first increased and then decreased,while the alkaline degradation rate was the opposite.The characteristic crystallization and alkaline degradation behavior of star-shaped PLAs were discussed based on the competition between segmental mobility and central core confinement.展开更多
文摘Developing efficient photocatalysts to address collaborative energy and environmental crises still faces significant challenges.In this report,we present a highly efficient MXene–based photocatalyst,which is combined with MoS_(2)nano patches and TiO_(2)/Ti_(3)C_(2)(TTC)nanowires through hydrothermal treatment.Of all the composites tested,the optimized photocatalyst gave a remarkable H_(2)and revolving polylactic acid(PLA)into pyruvic acid(PA).Achieving a remarkable H_(2)evolution rate of 637.1 and 243.2μmol g^(−1)h^(−1),in the presence of TEOA and PLA as a sacrificial reagent under UV-vis(λ≥365 nm)light irradiation.The improved photocatalytic activity is a result of the combination of dual cocatalyst on the surface of TTC photocatalyst,which create an ideal synergistic effect for the generation of PA and the production of H_(2)simultaneously.The MoS_(2)TiO_(2)/Ti_(3)C_(2)(MTT)composite can generate more photoexcited charge carriers,leading to the generation of more active radicals,which may enhance the system's photocatalytic activity.This work aims at demonstrating its future significance and guide the scientific community towards a more efficient approach to commercializing H_(2)through photocatalysis.
基金supported by the National Natural Science Foundation of China(Nos.31971741 and 31760195)the Yunnan Fundamental Research Projects(Nos.2018FB066 and 202001AT070141)the Yunnan Agricultural Basic Research Special Projects(No.202101BD070001-086).
文摘The increasing deployment of electronics in everyday life has generated great concerns regarding the effective disposal of waste from these components.Here,we focused on a facile sustainable and economical strategy to provide ideas for this issue.This strategy relied on using appropriate mechanical treatment and sodium lignosulfonate coating to improve the dispersion and interfacial compatibility of bamboo fibers in poly(lactic acid).By optimising the particle size and concentration of sodium lignosulphonate,high value-added and green composites were prepared using sectional pressurization with a venting procedure.The treated composite displayed an ultra-smooth surface(roughness of 0.592 nm),impressive transient properties(disintegration and degradation behaviour after 30 d),and outstanding ultraviolet(UV)shielding properties(100%).These properties hold the promise of being an excellent substrate for electronic devices,especially for high-precision processing,transient electronics,and UV damage prevention.The satisfactory interfacial compatibility of the composites was confirmed by detailed characterisation regarding the related physicochemical properties.This investigation offers a sustainable approach for producing high value-added green composites from biomass and biomass-derived materials.
基金supported by the Innovation Talents Project of Harbin Science and Technology Bureau(2022CXRCCGO11)。
文摘This study examined the effects of pasteurization(PAS),ultrasonic sterilization(ULS),and microwave sterilization(MWS)on the quality and storage characteristics of brine-fermented tofu(BFT)and fermented tofu(FT).Comparative analysis revealed that MWS had a negligible detrimental effect on the structural integrity and organoleptic properties of BFT and FT,while effectively maintaining its water-holding capacity(WHC)and exhibiting the least impact on its texture.In contrast,PAS and ULS increased hardness and chewiness significantly(P<0.05),but ULS also enhanced the brightness of tofu.Throughout the storage period,the WHC,elasticity,and sensory properties of tofu generally decreased,whereas the hardness and chewiness increased.PAS-BFT and MWS-FT maintained sensory quality for the longest periods of 14 and 12 days respectively,and could be decomposed to more small molecule peptides within 0–8 days and 0–6 days,which are more easily to be absorbed by the body.The findings discovered that MWS is the most suitable method for sterilization of tofu,with superior capability in maintaining the quality,extending shelf life,and improving digestibility of tofu.
基金supported by the National Natural Science Foundation of China(Nos.22368014 and 22478087)Guizhou Provincial S&T Project(Nos.GCC[2023]011 and ZK[2022]011).
文摘Photocatalytic selective synthesis of lactic acid(LA)from biomass sugars with a single heterogeneous catalyst is promising but challenging due to the multiple reaction steps involved.Herein,a K-doped C-rich red polymerized carbon nitride(RPCN)photocatalyst with uniform K/C dual sites was constructed by a molten salt template method,which was highly efficient for cascade isomerization dehydration of glucose to LA with>90%selectivity under visible light and gentle conditions.Control experiments and theoretical calculations expounded that the introduced K/C dual sites could improve the light capture ability and photogenerated charge separation efficiency,while the K species provided sufficient Lewis acid sites(adsorption sites)for the isomerization of glucose to fructose.Meanwhile,the introduced C sites that substitute N atoms could promote electrons to be captured by adsorbed oxygen for selective generation of superoxide radicals,which was highly efficient for the scission of the C3-C4 bond in fructose,exclusively furnishing LA.Importantly,the RPCN photocatalyst was also suitable for the photocatalytic upgrading of various biomass saccharides into LA with high yields of 81.3%-95.3%and could be recycled for five consecutive cycles.The tailored construction of dual sites by localization of space charge lightens an avenue for multi-step conversion of biomass with pronounced selectivity.
基金the Natural Science Foundation of China(22368014,22478087)the Guizhou Provincial S&T Project(GCC[2023]011,ZK[2022]011).
文摘Photocatalytic transformation of biomass into biofuels and value-added chemicals is of great significance for carbon neutrality.Metal-free carbon nitride has extensive applications but with almost no absorption and utilization of near-infrared light,accounting for 50%of sunlight.Here,a molten salt-assisted in-plane“stitching”and interlayer“cutting”protocol is developed for constructing a highly crystalline carbon nitride catalyst containing structural oxygen(HC-CN).HC-CN is highly efficient for the photothermal cascade transformation of biomass-derived glucose into lactic acid(LA)with an unprecedented yield(94.3%)at 25°C under full-spectrum light irradiation within 50 min,which is also applicable to quantitatively photo-upgrading various saccharides.Theoretical calculations expound that the light-induced glucose-to-catalyst charge transfer can activate the Cβ-H bond to promote the rate-determining step of intramolecular hydrogen shift in glucose-to-fructose isomerization.Meanwhile,the introduced structural oxygen in HC-CN can not only facilitate the local electric field formation to achieve rapid charge transport/separation and regulate selective·O^(-)_(2)generation for oriented C3-C4 bond cleavage of fructose but also narrow the energy band gap to broaden the light absorption range of HC-CN,contributing to enhanced LA production without exogenous heating.Moreover,HC-CN is highly recyclable and exhibits negligible environmental burden and low energy consumption,as disclosed by the life cycle assessment.Tailored construction of full-spectrum light adsorption and versatile reaction sites provides a reference for implementing multi-step biomass and organic conversion processes under mild conditions.
基金Funded by the National Natural Science Foundation of China(No.21104031)the Education Department of Hunan province in 2020(No.20C1589)。
文摘This article provided a preparation protocol for poly(lactic acid)(PLA)/modified epoxidized soybean oil(ECP)/nano-magnesium oxide(n-MgO)ternary composites and studied their mechanical and antibacterial properties.By means of an organic synthesis technique,epoxidized soybean oil(ESO)is chemically grafted to PLA to synthesize ESO chemically plastically modified PLA,abbreviated ECP.To fabricate PLA/ECP/n-MgO composite materials,ECP acts as a plasticizer and a compatibilizer simultaneously,and n-MgO acts as an enhancer.Then scanning electron microscopy,X-ray diffraction,differential scanning calorimetry,universal tester,and antibacterial research were exploited to characterize the morphology,thermal resistance,mechanical properties,and antibacterial performance of PLA/ECP/n-MgO composites.The experimental results show that ECP acts as a plasticizer by causing heterogeneous nucleation,which increases PLA's crystallinity.Evenly distributed n-MgO can greatly improve PLA's antibacterial qualities.Furthermore,ECP and n-MgO work together to improve the positive aspects of PLA/ECP/n-MgO composites,with PLA/ECP/n-MgO 100/1/0.5 composites having the best overall properties.While improving the mechanical performance and toughness of PLA,this work offers a prospective approach and foundational database for the creation of multifunctional biodegradable composites.
基金funded by National Natural Science Foundation of China(32360564)the Natural Science and Technology Innovation Development Multiplication Plan of Guangxi University(2022BZRC010)。
文摘Hyperuricemia(HUA)is characterized by elevated levels of uric acid(UA)in the bloodstream,resulting from either excessive production or insufficient excretion of UA within the body.If left untreated,progressive or persistent HUA can lead to gout,causing significant harm to human health.Lactic acid bacteria(LAB),generally recognized as safe(GRAS)probiotics,have been shown to alleviate symptoms associated with gastrointestinal disorders such as irritable bowel syndrome and inflammatory bowel disease while supporting overall bodily functions and health.Recently,LAB has emerged as a potentially safe,cost-effective and efficient treatment for HUA.This comprehensive review aims to explore the current literature on the mechanisms through which LAB controls HUA.These mechanisms include suppressing purine metabolism,absorbing purine compounds,modulating microbiota to maintain host global purine homeostasis,reducing intestinal permeability,producing metabolites that alleviate HUA symptoms,promoting the expression of urate excretory proteins and inhibiting the expression of urate reabsorption proteins.The findings presented in this review provide a framework for further investigation into how probiotic LAB can alleviate HUA by influencing UA metabolism and elucidating their underlying action mechanisms.
基金supported by the National Key Research and Development Program of China(No.2023YFC3904604)the Fundamental Research Funds for the Central Universities(No.2024ZYGXZR080)+1 种基金Science and Technology Project of Guangzhou(No.2025A04J3914)Research and Development Program of Jiangmen(No.2023780200030009506).
文摘To retain its inherent biodegradability,simultaneously improving the strength and toughness of poly(lactic acid)(PLA)is a significant challenge.In this study,we propose an innovative multiple dynamic pressure(MDP)process that can produce pure PLA with excellent mechanical properties.The MDP process generates a dynamic stretching effect by regulating the application and release of pressure,prompting disordered molecular chains to be arranged regularly along the direction of the dynamic force field.This promoted the formation of more ordered crystal forms(α-form)and strengthened the connection between the crystalline and amorphous regions.Results show that after MDP treatment,the tensile strength and strain at break of MDP-PLA are significantly improved,reaching 91.6 MPa and 80.1%respectively,which are 49.4%higher and 10 times higher than those of the samples before treatment.The mechanical properties of MDP-PLA can be regulated as needed by adjusting the cycle times and peak pressure.In addition,through a systematic study of the structural evolution of MDP-PLA,the performance regulation mechanism of the MDP process was thoroughly investigated,and the internal relationship among the process-structure-performance was clarified.This research not only opens a new technical path for the preparation of high-performance pure PLA but also provides important guidance for the high-performance modification of other semi-crystalline polymers,thus possessing significant scientific and engineering value.
基金financially supported by the National Key R&D Program of China(No.2021YFB3801901)the National Natural Science Foundation of China(No.22075188 and U19A2095)supported by State Key Laboratory of Materials Processing and Die&Mould Technology,Huazhong University of Science and Technology。
文摘Poly(lactic acid)(PLA),a bio-based polymer,is considered to be a sustainable alternative to conventional petroleum-based plastics.However,owing to its widespread use and relatively slow degradation rate in water,PLA still poses potential environmental pollution risks after being discarded.The efficient chemical recycling of PLA represents an attractive approach to addressing both resource reuse and environmental pollution challenges caused by its waste.Hydrolysis is the predominant method of industrial recycling.However,because PLA is insoluble in water,efficient heterogeneous hydrolysis requires high-temperature and high-pressure conditions.In this study,an efficient homogenous hydrolysis method capable of simultaneously dissolving PLA and calcium hydroxide(Ca(OH)_(2))was developed.Suitable solvents for this method were screened,and it was found that PLA hydrolysis using dioxane and 1,4,7,10,13-Pen-taoxacyclopentadecane as solvents achieved conversion rates of 93%and 90%,respectively,within 2 h at room temperature.Notably,the hydrolysis product,calcium lactate,precipitated as a solid from the solvent and therefore self-separated from the reaction solution.The solvent,acid/base conditions,water content,and depolymerization kinetics were investigated.Compared with previously reported hydrolysis methods,the enhanced efficiency observed in this study can be attributed to the concurrent solvation of PLA and Ca(OH)_(2),which maintains homogeneity throughout the reaction process.Additionally,this method facilitates closed-loop recycling of PLA and is compatible with the highly selective recovery of PLA from various types of PLA products.
基金supported by the Natural Science Foundation of Heilongjiang Province(LH2021C075)Basic Research Business Expenses and Research Projects of Provincial Higher Education Institutions in Heilongjiang Province(2022-KYYWF-1077).
文摘Lactic acid bacteria(LAB)exopolysaccharides(EPS)reveal high safety and multiple activities,and are typical postbiotics produced by LAB during fermentation.In this paper,6583 articles on LAB-EPS from Web of Science and Elsevier databases were retrieved,and 236 articles related to this review were screened.The EPS from 90 LAB strains were summarized in terms of their extraction methods,yield,molecular weight,monosaccharide composition,glycosidic bond configuration and the structural and activity relationships(SARs).However,there exist great challenges as for the low yield and high cost in EPS production.Therefore,this review further elaborated the mechanism of EPS secretion,the anabolic pathway of EPS,the structure and mechanism of key enzymes involving in EPS synthesis process,the prospect of gene regulation for EPS secretion,and proposed the engineering strategies for increasing EPS yield or tailored EPS design in recent years.In addition,CRISPR/Cas9 gene editing technology was also discussed in the production control of EPS in LAB.Finally,the engineering strategy of increasing EPS yield in recent years was proposed.This work might provide important theoretical support for the production and application of LAB-based EPS.
文摘BACKGROUND The central link between septic shock and acute skin failure(ASF)is the inflammatory response,which occurs throughout disease progression and can lead to systemic inflammatory response syndrome.Patients often experience bad moods,sleep disorders,and other health issues.Despite recognizing these factors,no studies have examined the correlation between inflammatory factors,lactic acid levels,ASF,mood disturbances,and sleep quality in critically ill patients.We hypothesize that higher levels of inflammatory factors and lactic acid are associated with more severe ASF and poorer mood and sleep quality,which may inform clinical treatment for septic shock and ASF.AIM To explore the relationship between inflammatory factors,lactic acid levels,the severity of ASF,bad mood,and sleep quality.METHODS The retrospective study included 150 patients with septic shock from the Second Hospital of Dalian Medical University,categorized into ASF(n=35)or non-ASF groups(n=115).We compared the peripheral blood inflammatory factors,including tumor necrosis factor-α(TNF-α),C-reactive protein(CRP),interleukin-6(IL-6),lactic acid levels,skin mottling score(SMS),modified early warning score(MEWS),self-rating depression scale(SDS),self-rating anxiety scale(SAS),and Pittsburgh sleep quality index(PSQI)scores.Pearson correlation analysis assessed relationships among these variables.RESULTS The ASF group had significantly higher levels of CRP(19.60±4.10 vs 15.30±2.96 mg/mL),IL-6(298.65±48.65 vs 268.66±33.66 pg/L),procalcitonin,lactic acid(8.42±2.32 vs 5.70±1.27 mmol/L),SMS[0(0,1)vs 3(2,3)],MEWS(9.34±1.92 vs 6.48±1.96),SAS(61.63±12.03 vs 53.71±12.48),SDS(60.17±12.64 vs 52.27±12.64),and PSQI scores(14.23±3.94 vs 8.69±2.46)compared with the non-ASF group(all P<0.001).Pearson correlation analysis revealed that IL-6,CRP,TNF-α,and lactic acid were positively correlated with SMS,MEWS,SAS,SDS,and PSQI scores(P<0.05).CONCLUSION Peripheral blood levels of IL-6,CRP,TNF-α,and lactic acid correlate positively with SMS,MEWS,SAS,SDS,and PSQI in critically ill patients with ASF.
基金Supported by the National Natural Science Foundation of China(No.82301211)Beijing Natural Science Foundation(No.J230028).
文摘AIM:To develop a 5-fluorouracil(5-FU)mesoporous poly(lactic)acid(PLA)delivery system for glaucoma filtration surgery suitable for a single subconjunctival implantation.METHODS:The 5-FU was infiltration-loaded into mesoporous PLA.In vitro and in vivo release experiments and ocular toxicology evaluation of the formulation were performed.The antiproliferative effect of this 5-FU-PLA tablet after glaucoma filtration surgery in rabbits was evaluated.Pathology,immunohistochemistry,and Western blot were used to further validate the inhibitory effect of this sustained release system.RESULTS:Various drug formulations were tested,and two 5-FU-PLA tablets,namely 1.5P15(5-FU 1.5 mg+PLA 15000 Da)and 2.5P15(5-FU 2.5 mg+PLA 15000 Da),had the most suitable release profiles in vitro.Further in vivo studies confirmed the safety and sustained-release profiles of both drugs.Both 5-FU-PLA tablets,relative to the free drugs,significantly inhibited tissue proliferation after glaucoma filtration and improved surgical success.Western blot showed that transforming growth factor-β(TGF-β)and connective tissue growth factor(CTGF)were inhibited by 5-FU after filtration surgery,with the effects of the 5-FU-PLA tablets being more lasting.CONCLUSION:The tested 5-FU-PLA tablets provide a sustained release of 5-FU,which may be used for a single subconjunctival implantation to inhibit proliferation after filtration surgery.
基金This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoalde Nível Superior-Brasil(CAPES)-Finance Code 001.
文摘The continuous improvement in patient care and recovery is driving the development of innovative materials for medical applications.Medical sutures,essential for securing implants and closing deep wounds,have evolved to incorporate smart materials capable of responding to various stimuli.This study explores the potential of thermoresponsive sutures,made from shape memory materials,that contract upon heating to bring loose stitches closer together,promoting optimal wound closure.We developed nanocomposites based on a blend of poly(lactic acid)(PLA)and thermoplastic polyurethane(TPU)—biopolymers that inherently exhibit shape memory—enhanced with carbon nanotubes(CNT)and graphene nanoplatelets(GN)to improve mechanical performance.PLA/TPU(50/50)nanocomposites were prepared with 1 and 2 wt%GN,as well as hybrid formulations combining 1 wt%CNT with 1 or 2 wt%GN,using a twin-screw extrusion process to form filaments.These filaments were characterized through differential scanning calorimetry(DSC),field emission gun scanning electron microscopy(FEG-SEM),tensile testing,and shape memory assessments.While the PLA/TPU blend is immiscible,TPU enhances the crystallinity(X_(c))of the PLA phase,further increased by the addition of CNT and GN.FEG-SEM images indicate CNTs primarily in the PLA phase and GN in the TPU phase.PLA/TPU with 1 or 2 wt%GN showed the highest potential for suture applications,with a high elastic modulus(~1000 MPa),significant strain at break(~10%),and effective shape recovery(~20%at 55℃ for 30 min).These findings suggest that these nanocomposites can enhance suture performance with controlled shape recovery that is suitable for medical use.
基金financially supported by the National Key R&D Program of China (2021YFA1501700)the National Science Foundation of China (22272114)+4 种基金the Fundamental Research Funds from Sichuan University (2022SCUNL103)the Funding for Hundred Talent Program of Sichuan University (20822041E4079)the NSFC (22102018 and 52171201)the Huzhou Science and Technology Bureau (2022GZ45)the Hefei National Research Center for Physical Sciences at the Microscale (KF2021005)。
文摘The conversion of waste polylactic acid(PLA)plastics into high-value-added chemicals through electrochemical methods is a promising and sustainable approach.However,developing efficient and highly selective catalysts for lactic acid oxidation reaction(LAOR)and understanding the reaction process are challenging.Here,we report the electrooxidation of waste PLA to acetate at a high current density of 100 mA cm-2 with high Faraday efficiency(~95%)and excellent stability(>100 h)over a nickel selenide nanosheet catalyst.In addition,a total Faraday efficiency of up to 190%was achieved for carboxylic acids,including acetic acid and formic acid,by coupling with the cathodic CO_(2) reduction reaction.In situ experimental results and theoretical simulations revealed that the catalytic activity center of LAOR was dynamically formed NiOOH species,and the surface-adsorbed SeO_(x) species accelerated the formation of Ni~(3+)species,thus promoting catalytic activity.The mechanism of lactic acid electrooxidation was further elucidated.Lactic acid was dehydrogenated to produce pyruvate first and then formed CH_3CO due to preferential C-C bond cleavage,resulting in the presence of acetate.This work demonstrated a sustainable method for recycling waste PLA and CO_(2) into high-value-added products.
基金This work was supported by the Anhui Provincial Natural Science Foundation(Grant No.2308085QB69)the Institute of Energy,Hefei Comprehensive National Science Center(Grant No.21KZS210).
文摘Ni-rich layered oxides are potential cathode materials for next-generation high energy density Li-ion batteries due to their high capacity and low cost.However,the inherently unstable surface properties,including high levels of residual Li compounds,dissolution of transition metal cations,and parasitic side reactions,have not been effectively addressed,leading to significant degradation in their electrochemical performance.In this study,we propose a simple and effective lactic acid-assisted interface engineering strategy to regulate the surface chemistry and properties of Ni-rich LiNi_(0.8)Co_(0.1)Mr_(0.1)O_(2) cathode.This novel surface treatment method successfully eliminates surface residual Li compounds,inhibits structural collapse,and mitigates cathode-electrolyte interface film growth.As a result,the lactic acidtreated LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) achieved a remarkable capacity retention of 91.7% after 100 cycles at 0.5 C(25℃) and outstanding rate capability of 149.5 mA h g^(-1) at 10 C,significantly outperforming the pristine material.Furthermore,a pouch-type full cell incorporating the modified LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) cathode demonstrates impressive long-term cycle life,retaining 81.5% of its capacity after 500 cycles at 1 C.More importantly,the thermal stability of the modified cathode is also dramatically improved.This study offers a valuable surface modification strategy for enhancing the overall performance of Ni-rich cathode materials.
基金supported by the National Natural Science Foundation of China(Nos.51403089 and 21574060)the Major Special Projects of Jiangxi Provincial Department of Science and Technology(No.20114ABF05100)+3 种基金the Project of Jiangxi Provincial Department of Education(No.GJJ170229)the China Postdoctoral Science Foundation(No.2019M652282)the Postdoctoral Science Foundation of Jiangxi Province(No.2018KY37)the Technology Plan Landing Project of Jiangxi Provincial Department of Education(No.GCJ2011-243).
文摘For a polymer/polymer dismissible blend with two crystallizable components,the crystallization behavior of different components and the reciprocal influences between different crystals are interesting and important,but did not investigate in detail.In this study,the L-poly(lactic acid)/polypropylene(PLLA/PP)blends with different weight ratios were prepared by melt mixing and the crystallization behavior of the blends were investigated.Results showed that the crystalline structures of PLLA and PP were not altered by the composition.For the crystallization of PLLA,both the diffusion of chain segments and crystallization rate were enhanced under the existence of PP crystals.For the crystallization of PP,its crystallization rate was depressed under the existence of amorphous PLLA molecular chains.When the PP crystallized from the existence of PLLA crystals,although the diffusion rate of PP was reduced by PLLA crystals,the nucleation positions were obviously enhanced,which accelerated the formation of PP crystals.This investigation would supply more basic data for the application of PLLA/PP blend.
基金The authors acknowledge the Fundamental Research Program of Jiangsu Province(BK20201000)the Australian Research Council through the Discovery Project(DP110101653,DP130103592)+1 种基金the Basic and Applied Basic Research Foundation of Guangdong Province,China(2022A1515140123,2021A1515110729)the Foshan(Southern China)Institute for New Materials(2021AYF25017).The authors are grateful to Jinling Zhu.
文摘In actual physiological environments,bacteria can activate the immune system and release lactic acid.However,the detailed contribution of lactic acid to the passivation behavior of titanium(Ti)alloys is still unclear.The current work investigated the in vitro passivation behavior of Ti-6Al-4V(TC4)alloys fabricated by laser powder bed fusion in Hank's solution with and without adding lactic acid.Electrochemical methods,inductively coupled plasma atomic emission spectrometer,and X-ray photoelectron spectroscopy were jointly used.Adding lactic acid decreases the corrosion resistance of samples by degrading the formed passive film.The film formed in the(lactic acid)-containing solution exhibits a higher level of oxygen vacancies and a lower thickness,attributed to the suppressed formation of Ti^(4+)transformed from Ti^(3+)and Ti^(2+).Moreover,the presence of lactic acid would increase the open circuit potential,relieve the ions release,and hinder the deposition of calcium phosphates within 24 h immersion.
基金supported by the National Key Research and Development Program of China(2021YFD2100902-3)the National Natural Science Foundation of China(32072258)+5 种基金Major Science and Technology Program of Heilongjiang(2020ZX08B02)Harbin University of Commerce“Young Innovative Talents”Support Program(2019CX062020CX262020CX27)the Central Financial Support for the Development of Local Colleges and Universities,Graduate Innovation Research Project of Harbin University of Commerce(YJSCX2021-698HSD)Training plan of Young Innovative Talents in Universities of Heilongjiang(UNPYSCT-2020218).
文摘The effects of 5 lactic acid bacteria(LAB)fermentation on the pasting properties of glutinous rice flour were compared,and suitable fermentation strains were selected based on the changes of viscosity,setback value,and breakdown value to prepare LAB compound starter cultures.The results revealed that Latilactobacillus sakei HSD004 and Lacticaseibacillus rhamnosus HSD005 had apparent advantages in increasing the viscosity and reducing the setback and breakdown values of glutinous rice flour.In particular,the compound starter created using the two abovementioned LAB in the ratio of 3:1 had better performance than that using a single LAB in improving the pasting properties and increasing the water and oil absorption capacity of glutinous rice flour.Moreover,the gelatinization enthalpy of the fermented samples increased significantly.For frozen glutinous rice dough stored for 28 days,the viscoelasticity of frozen dough prepared by compound starter was better than that of control dough,and the freezable water content was lower than that of control dough.These results indicate that compound LAB fermentation is a promising technology in the glutinous rice-based food processing industry,which has significance for its application.
基金funded by the National Natural Science Foundation of China(32172232 and 31771990)the Major Science and Technology Projects of Heilongjiang Province(2021ZX12B05).
文摘The effects of the co-inoculation of Debaryomyces hansenii separately with 3 lactic acid bacteria(LAB),Lactobacillus sakei,Lactobacillus plantarum and Lactobacillus curvatus,on the taste and odour profi les of dry sausages were investigated.The co-inoculated sausages showed higher free amino acid and organic acid contents than the non-inoculated control and sausages inoculated with D.hansenii alone.Meanwhile,the sausages inoculated with D.hansenii+L.plantarum,D.hansenii+L.sakei and D.hansenii+L.curvatus had the highest contents of aldehydes,esters and alcohols,respectively.The results of electronic tongue,electronic nose and sensory evaluation demonstrated that compared with the sausage inoculated with D.hansenii,the sour taste and fl oral odour increased and the fatty odour decreased in the sausage inoculated with D.hansenii+L.sakei;this was more favourable for the development of a desirable fl avour in sausages.Moreover,the partial least squares regression analysis indicated that 10 taste and 33 odour compounds were mainly responsible for the differences in the flavour profiles among the sausages.Overall,these findings contributed to a more comprehensive understanding of the formation of sensory characteristics in dry sausages co-inoculated with yeast and LAB.
基金This work was financially supported by the National Natural Science Foundation of China(No.51973010).
文摘Star-shaped poly(lactic acid)s(PLAs)with two to five arms were synthesized by ring opening polymerization using tin(II)2-ethylhexanoate as catalyst and polyols as initiators.The effects of molecular weight together with multi-arm architecture on crystallization behavior,spherulite morphology and alkaline degradation behavior of star-shaped PLAs have been investigated.The results indicate that the multi-arm architecture interfered with spherulite growth,but promoted nucleation and alkaline degradation of star-shaped PLAs.Interestingly,with the increase of molecular weight(M_(n)),the crystallization rate first increased and then decreased,while the alkaline degradation rate was the opposite.The characteristic crystallization and alkaline degradation behavior of star-shaped PLAs were discussed based on the competition between segmental mobility and central core confinement.
