The analysis of Greenhouse Effect experiments in the public domain indicated that the lab tests were primarily centered around illustrating the mechanics of conventional greenhouses. They used high-energy visible ligh...The analysis of Greenhouse Effect experiments in the public domain indicated that the lab tests were primarily centered around illustrating the mechanics of conventional greenhouses. They used high-energy visible light (such as sunlight), rather than addressing the Greenhouse Effect, which involves low-energy infrared radiation emitted by the Earth’s surface. Studies with argon, a non-greenhouse gas with similar density to CO2, showed thermal heat transfer as the dominant factor in the temperature profiles, with radiation absorption being undetected. The same conclusion was drawn by another study, which measured infrared back radiation. Experiments using exaggerated CO2 concentrations inadvertently illustrated the principle of the Popper Falsification Test by disproving the Greenhouse Effect applicable to CO2 within the troposphere. A straightforward kitchen test showed that a microwave oven cannot be used as a model for the Greenhouse Effect.展开更多
In fields such as science and engineering, virtual environment is commonly used to provide replacements for practical hands-on laboratories. Sometimes, these environments take the form of a remote interface to the phy...In fields such as science and engineering, virtual environment is commonly used to provide replacements for practical hands-on laboratories. Sometimes, these environments take the form of a remote interface to the physical laboratory apparatus and at other times, in the form of a complete software implementation that simulates the laboratory apparatus. In this paper, we report on the use of a semi-immersive 3D mobile Augmented Reality (mAR) interface and limited simulations as a replacement for practical hands-on laboratories in science and engineering. The 3D-mAR based interfaces implementations for three different experiments (from micro-electronics, power and communications engineering) are presented;the discovered limitations are discussed along with the results of an evaluation by science and engineering students from two different institutions and plans for future work.展开更多
Geophysical fluid dynamics(GFD)is an interdisciplinary field that studies the large-scale motion of fluids in the natural world.With a wide range of applications such as weather forecasts and climate prediction,GFD em...Geophysical fluid dynamics(GFD)is an interdisciplinary field that studies the large-scale motion of fluids in the natural world.With a wide range of applications such as weather forecasts and climate prediction,GFD employs various research approaches including in-situ observations,satellite measurements,numerical simulations,theoretical analysis,artificial intelligence,and physical model experiments in laboratory.Among these approaches,rotating tank experiments provide a valuable tool for simulating naturally-occurring fluid motions in laboratories.With proportional scaling and proper techniques,scientists can reproduce multi-scale physical processes of stratified fluids in the rotation system,which allows for the simulation of essential characteristics of fluid motions in the atmosphere and oceans.In this review,rotating tanks of various scales in the world are introduced,as these tanks have been actively used to explore fundamental scientific questions in ocean and atmosphere dynamics.To illustrate the GFD experiments,three representative cases are presented to demonstrate the frontier achievements in the the GFD study by using rotating tank experiments:mesoscale eddies in the ocean,convection processes,and plume dynamics.Detailed references for the experimental procedures are provided.Future studies are encouraged to further explore the utilization of rotating tanks with improvements in experimental design and integration of other research methods.This is a promising direction of GFD to help enhance our understanding of the complex nature of fluid motions in the natural world and to address the challenges posed by global environmental changes.展开更多
Shales are considered to be sealing units for geological carbon storage and suitable host rocks for nuclear waste repositories due to their low permeability.However,the presence of fractures within these formations ca...Shales are considered to be sealing units for geological carbon storage and suitable host rocks for nuclear waste repositories due to their low permeability.However,the presence of fractures within these formations can significantly alter their flow,transport,and deformation behavior,which is central to the safe implementation of underground storage projects.Fractures not only increase the overall permeability of the rock but also contribute to its anisotropic behavior.This study focuses on characterizing the hydro-mechanical response of a natural fracture to aqueous fluid injection within a shaly specimen of Opalinus Clay.Laboratory experiments were performed to measure the mechanical and flow properties of intact and fractured rock specimens.Subsequently,a three-dimensional(3D)numerical model of water injection into the fractured specimen was developed.This model explicitly accounts for fracture geometry with strain-dependent aperture changes based on the cubic law assumption.Experimental measurements indicate that the fractured shale exhibits permeability up to two orders of magnitude higher than that of the intact counterpart.However,the simulations reveal that fracture permeability locally spans up to eight orders of magnitude.This significant change in permeability affects fluid flow within the rock specimen.The numerical model best reproduces the experimental results for a normal stiffness of the natural fracture of 18.7 MPa/mm at effective mean stresses below 15 MPa,and of 187.2 MPa/mm at higher confinements.This outcome highlights the critical importance of defining the hydro-mechanical parameters of fractures under realistic effective stress conditions with far-reaching implications for secure underground storage.展开更多
Steel mesh is used as a passive skin confinement medium to supplement the active support provided by rock bolts for roof and rib control in underground coal mines. Thin spray-on liners(TSL) are believed to have the po...Steel mesh is used as a passive skin confinement medium to supplement the active support provided by rock bolts for roof and rib control in underground coal mines. Thin spray-on liners(TSL) are believed to have the potential to take the place of steel mesh as the skin confinement medium in underground mines.To confirm this belief, large scale laboratory experiments were conducted to compare the behaviour of welded steel mesh and a TSL, when used in conjunction with rock bolts, in reinforcing strata with weak bedding planes and strata prone to guttering, two common rock conditions which exist in coal mines. It was found that while the peak load taken by the simulated rock mass with weak bedding planes acting as the control sample(no skin confinement) was 2494 kN, the corresponding value of the sample with 5 mm thick TSL reinforcement reached 2856 kN. The peak load of the steel mesh reinforced sample was only2321 kN, but this was attributed to the fact that one of the rock bolts broke during the test. The TSL reinforced sample had a similar post-yield behaviour as the steel mesh reinforced one. The results of the large scale guttering test indicated that a TSL is better than steel mesh in restricting rock movement and thus inhibiting the formation of gutters in the roof.展开更多
Laboratory experiments were conducted in a wave flume on internal solitary wave （ISW） of depression and elevation types propagating over a submarine ridge in semicircular/triangular shape. Tests were arranged in ser...Laboratory experiments were conducted in a wave flume on internal solitary wave （ISW） of depression and elevation types propagating over a submarine ridge in semicircular/triangular shape. Tests were arranged in series for combinations of submarine ridges of different heights and ISW of different amplitudes. The resuhant wave motions were found differing from thee of surface gravity waves. In deeper water, where an ISW of depression-type prevailed, the process of wave breaking displayed downward motion with continuous eddy on the front face of the ridge followed by upward motion towards the apex of the obstacle. Experimental results also suggested that blockage parameter ξ could be applied to classify various degrees of ISW-ridge interaction, i.e., ξ 〈 0.5 for weak interaction, 0.5 〈 ξ 〈 0.7 for moderate interaction, and 0.7 〈 ξ for wave breaking.展开更多
In a Nature Physics report published in late September 2024[1],a team of scientists and engineers at Sandia National Laboratories(Albuquerque,NM,USA)described the results of a laboratory experiment showing that a nucl...In a Nature Physics report published in late September 2024[1],a team of scientists and engineers at Sandia National Laboratories(Albuquerque,NM,USA)described the results of a laboratory experiment showing that a nuclear blast could create a burst of X-rays powerful enough to change the path of a large asteroid that might one day be on a collision course with Earth.展开更多
Abstract Accurate simulation of seismic wave propaga- tion in complex geological structures is of particular interest nowadays. However conventional methods may fail to simulate realistic wavefields in environments wi...Abstract Accurate simulation of seismic wave propaga- tion in complex geological structures is of particular interest nowadays. However conventional methods may fail to simulate realistic wavefields in environments with great and rapid structural changes, due for instance to the presence of shadow zones, diffractions and/or edge effects. Different methods, developed to improve seismic model- ing, are typically tested on synthetic configurations against analytical solutions for simple canonical problems or ref- erence methods, or via direct comparison with real data acquired in situ. Such approaches have limitations,especially if the propagation occurs in a complex envi- ronment with strong-contrast reflectors and surface irreg- ularities, as it can be difficult to determine the method which gives the best approximation of the ＂real＂ solution, or to interpret the results obtained without an a priori knowledge of the geologic environment. An alternative approach for seismics consists in comparing the synthetic data with high-quality data collected in laboratory experi- ments under controlled conditions for a known configuration. In contrast with numerical experiments, laboratory data possess many of the characteristics of field data, as real waves propagate through models with no numerical approximations. We thus present a comparison of laboratory-scaled measurements of 3D zero-offset wave reflection of broadband pulses from a strong topographic environment immersed in a water tank with numerical data simulated by means of a spectral-element method and a discretized Kirchhoff integral method. The results indicate a good quantitative fit in terms of time arrivals and acceptable fit in amplitudes for all datasets.展开更多
We report the observation of Zeeman splitting in multiple spectral lines emitted by a laser-produced,magnetized plasma(1–3×10^(18)cm^(-3),1–15 eV)in the context of a laboratory astrophysics experiment under a c...We report the observation of Zeeman splitting in multiple spectral lines emitted by a laser-produced,magnetized plasma(1–3×10^(18)cm^(-3),1–15 eV)in the context of a laboratory astrophysics experiment under a controlled magneticfield up to 20T.Nitrogen lines(NII)in the visible range were used to diagnose the magneticfield and plasma conditions.This was performed by coupling our data with(563–574 nm)the Stark–Zeeman line-shape code PPPB.The excellent agreement between experiment and simulations paves the way for a non-intrusive experimental platform to get time-resolved measurements of the local magneticfield in laboratory plasmas.展开更多
Compared with the middle-shallow shale gas reservoirs,deep shale formation often reveals lower fracture complexity,smaller effective stimulated volumes,lower conductivity,and faster declined when the same injection mo...Compared with the middle-shallow shale gas reservoirs,deep shale formation often reveals lower fracture complexity,smaller effective stimulated volumes,lower conductivity,and faster declined when the same injection model and technical parameters were used.Therefore,it is necessary to research a special injection model for the deep shale formation.In this paper,a series of laboratory stimulated experiments were carried to analyze the injection method on hydraulic fracturing initiation and propagation in the deep shale formation.The outcrop shale of Longmaxi formation in Sichuan Basin was selected and three different injection methods(constant,stepped-rise and cyclic progressive uplift pump rate)were used in these experiments.The test results showed that the stepped-rise pump rate is conductive to opening the pre-existing natural fracture and bedding planes,the fracture complexity of this injection method is the highest.Meanwhile,the fracturing pressure and total injection volume are the lowest.In contrast,the cyclic-uplift injection method can only form a transverse fracture,and the fracturing pressure is the highest.The research results have an important theoretical guiding value for deep shale hydraulic fracturing operation.展开更多
In order to improve our understanding of rock fracture and fault instability driven by high-pressure fluid sources, the authors carried out rock fracture tests using granite under a confining pressure of 80 MPa with f...In order to improve our understanding of rock fracture and fault instability driven by high-pressure fluid sources, the authors carried out rock fracture tests using granite under a confining pressure of 80 MPa with fluid injection in the laboratory. Furthermore, we tested a number of numerical models using the FLAC;modeling software to find the best model to represent the experimental results. The high-speed multichannel acoustic emission（AE） waveform recording system used in this study made it possible to examine the total fracture process through detailed monitoring of AE hypocenters and seismic velocity.The experimental results show that injecting high-pressure oil into the rock sample can induce AE activity at very low stress levels and can dramatically reduce the strength of the rock. The results of the numerical simulations show that major experimental results, including the strength, the temporal and spatial patterns of the AE events, and the role of the fluid can be represented fairly well by a model involving（1） randomly distributed defect elements to model pre-existing cracks,（2） random modification of rock properties to represent inhomogeneity introduced by different mineral grains, and（3）macroscopic inhomogeneity. Our study, which incorporates laboratory experiments and numerical simulations, indicates that such an approach is helpful in finding a better model not only for simulating experimental results but also for upscaling purposes.展开更多
A novel expandable conductor was designed and applied in deep-water drilling to improve the vertical and lateral bearing capacity with a significant reduction of conductor jetting depth and soaking time. The vertical ...A novel expandable conductor was designed and applied in deep-water drilling to improve the vertical and lateral bearing capacity with a significant reduction of conductor jetting depth and soaking time. The vertical and lateral bearing capability of expandable conductors was depicted based on the ultimate subgrade reaction method and pile foundation bearing theory. The load-bearing characteristics of a laboratory-scale expandable conductor were analyzed through laboratory experiments. The serial simulation experiments are accomplished to study the bearing characteristics(vertical ultimate bearing capacity, lateral soil pressure, and lateral displacement) during the conductor soaking process. The laboratory experimental results show that the larger the length and thickness of expandable materials are,the higher the bearing capacity of the wellhead will be. During the conductor soaking process, the soil pressure around the three expandable conductors increases faster, strings representing a stronger squeezing effect and resulting in higher vertical bearing capacity. Furthermore, the lateral displacement of novel expandable conductor is smaller than that of the conventional conductor. All the advantages mentioned above contributed to the reduction of conductor’s jetting depth and soaking time. Lastly, the application workflow of a novel expandable deep-water drilling conductor was established and the autonomous expandable conductor was successfully applied in the South China Sea with a significant reduction of conductor’s jetting depth and soaking time. According to the soil properties and designed installation depth of the surface conductor, the arrangement of expandable materials should be designed reasonably to meet the safety condition and reduce the construction cost of the subsea wellhead.展开更多
Controlled laboratory experiments are proved to be a valuable tool for investigating changes in underground physical properties and the related response of surface geophysical signals.The self-potential(SP)method is w...Controlled laboratory experiments are proved to be a valuable tool for investigating changes in underground physical properties and the related response of surface geophysical signals.The self-potential(SP)method is widely used in mineral resource exploration due to its direct correlation with underground electrochemical gradients.This paper presented the design and construction of an experimental platform based on a multi-channel SP monitoring system.The proposed platform was used to monitor the anodizing corrosion process of different metal blocks from a laboratory perspective,record the real-time SP signal generated by the redox reaction,as well as investigate the geobattery mechanism associated with the natural polarization process of metal mineral resources.The experimental results demonstrate that the constructed SP monitoring platform effectively captures time-series SP signals and provides direct laboratory evidence for the geobattery model.The measured SP data were quantitatively interpreted using the simulated annealing algorithm,and the inversion results closely match the real model.This finding highlights the potential of the SP method as a promising tool for determining the location and spatial distribution of underground polarizers.The study holds reference value for the exploration and exploitation of mineral resources in both terrestrial and marine environments.展开更多
Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displa...Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved.展开更多
Complexities in mechanical behaviours of rock masses mainly stem from inherent discontinuities,which calls for advanced bolt-grouting techniques for stability enhancement.Understanding the mechanical properties of bol...Complexities in mechanical behaviours of rock masses mainly stem from inherent discontinuities,which calls for advanced bolt-grouting techniques for stability enhancement.Understanding the mechanical properties of bolt-grouted fractured rock mass(BGFR)and developing accurate prediction methods are crucial to optimize the BGFR support strategies.This paper establishes a new elastoplastic(E-P)model based on the orthotropic and the Mohr-Coulomb(M-C)plastic-yielding criteria.The elastic parameters of the model were derived through a meso-mechanical analysis of composite materials mechanics(CMM).Laboratory BGFR specimens were prepared and uniaxial compression test and variable-angle shear test considering different bolt arrangements were carried out to obtain the mechanical parameters of the specimens.Results showed that the anisotropy of BGFR mainly depends on the relative volume content of each component material in a certain direction.Moreover,the mechanical parameters deduced from the theory of composite materials which consider the short fibre effect are shown to be in good agreement with those determined by laboratory experiments,and the variation rules maintained good consistency.Last,a case study of a real tunnel project is provided to highlight the effectiveness,validity and robustness of the developed E-P model in prediction of stresses and deformations.展开更多
This study aims to further enhance the oil recovery of reservoirs in the Zhong-2 Block of the Gudao Oilfield by identifying the most effective microbial-flooding activator systems and applying them in the field.We beg...This study aims to further enhance the oil recovery of reservoirs in the Zhong-2 Block of the Gudao Oilfield by identifying the most effective microbial-flooding activator systems and applying them in the field.We began by analyzing the structure of the reservoirs'endogenous microbial communities to understand the potential impact of microbial flooding.This was followed by determining commonly used activator systems based on their abilities to stimulate oil-displacement functional bacteria.Through laboratory experiments on oil displacement efficiency and sweep characteristics,we determined the optimal activator injection method(injection ratio)and the requisite bacterial concentration for maximal microbial-flooding efficacy.Finally,we selected the optimal activator systems and applied them to field tests.Our findings suggest the target block is highly receptive to microbial-flooding.In terms of performance,the activator systems ranked as No.3>No.4>No.1>No.2.Interestingly,a deep activator system,when compared to the top-performing No.3 system,exhibited a higher bacterial concentration peak and longer peaking duration.Optimal oil displacement effects were observed at a 1:4 vol ratio between the No.3 activator and deep activator systems,with bacterial concentrations of up to 106 cells/mL or above.Field tests with the selected activator systems,following a specific injection protocol,demonstrated a notable increase in oil production and a reduction in water cut.展开更多
Conventional closed lab experiments using high-energy light sources and simple temperature sensors showed that CO_(2)-filled bottles often became hotter than bottles containing air.From this,they concluded that it pro...Conventional closed lab experiments using high-energy light sources and simple temperature sensors showed that CO_(2)-filled bottles often became hotter than bottles containing air.From this,they concluded that it proved the Greenhouse Effect.However,the thermometers and thermocouples used in those experi-ments did not measure absorption by Greenhouse Gases.In this study,a closed system laboratory experiment was designed and constructed to verify the accuracy of the aforesaid conclusion.In this experiment,both thermocou-ples and an infrared detector were used to collect the data.The results showed that the barrier holding the gas absorbed 98.3%of the infrared radiation.And the remaining 1.7%was not observed to be associated with absorption by the Greenhouse Gases.The experiment showed that Non-Greenhouse Gases per-formed as well as or better than the Greenhouse Gases relating to increased temperatures.Data from experiments using only scalar-measuring devices,like thermometers and thermocouples,proved inadequate.It further showed that infrared detectors can measure infrared absorption.However,the amount of absorption by the containment membrane was overwhelming and obscured any measurable observation of any Greenhouse Gas absorption.The conclu-sion was that the conventional Greenhouse Effect laboratory experiments us-ing closed systems failed to prove the Greenhouse Effect theory.展开更多
This is the only Greenhouse Effect experiment conducted in an open system using natural conditions and concentrations.In the test,atmospheric air was blown through a chamber and exposed to infrared radiation of the ty...This is the only Greenhouse Effect experiment conducted in an open system using natural conditions and concentrations.In the test,atmospheric air was blown through a chamber and exposed to infrared radiation of the type emit-ted by the Earth.The absorption temperature was measured by an infrared detector.The results showed that the greenhouse gases absorb the Earth’s in-frared radiation,and adding CO_(2) into the air stream proved that it could in-crease the absorption temperature.As such,this laboratory experiment has confirmed the Greenhouse Effect hypothesis.However,the test data showed that it took large concentrations of the greenhouse gases to trigger any mean-ingful effects.The data demonstrated a logarithmic correlation with 99%ac-curacy.This relationship also corroborated a potential minimum activation concentration as well as a flattened peak,forming an equivalent maximum or saturation point.The data proved that water vapor constituted 93 to 97 per-cent of the natural greenhouse gases,and that CO_(2) at its current atmospheric concentration(0.042%)had no measurable effect on the absorption tempera-ture.The data also showed that CO_(2) does not control atmospheric water vapor or absorption temperature;i.e.,it is not a control knob.The data revealed that CO_(2) and water vapor moved in opposite directions 64%of the time,had differing paths and magnitudes 90%of the time,and exhibited an R^(2) of less than 10%.Concerning CH_(4),the data found no measurable infrared absorption,even at 241 times higher than its current level.The same observation occurred with O_(3) when the concentration was increased 2,500 times higher than normal.All three of these greenhouse gases(CO_(2),CH_(4),O_(3))were too low at current at-mospheric concentrations to trigger a response.Water vapor was the only one that showed a measurable absorption temperature at the natural concentra-tions.The tests with non-greenhouse gases Ar and He ruled out interference by thermal heat transfer mechanisms.展开更多
Generative Artificial Intelligence(GAI)refers to a class of AI systems capable of creating novel,coherent,and contextually relevant content—such as text,images,audio,and video—based on patterns learned from extensiv...Generative Artificial Intelligence(GAI)refers to a class of AI systems capable of creating novel,coherent,and contextually relevant content—such as text,images,audio,and video—based on patterns learned from extensive training datasets.The public release and rapid refinement of large language models(LLMs)like ChatGPT have accelerated the adoption of GAI across various medical specialties,offering new tools for education,clinical simulation,and research.Dermatology training,which heavily relies on visual pattern recognition and requires extensive exposure to diverse morphological presentations,faces persistent challenges such as uneven distribu-tion of educational resources,limited patient exposure for rare conditions,and variability in teaching quality.Exploring the integration of GAI into pedagogical frameworks offers innovative approaches to address these challenges,potentially enhancing the quality,standardization,scalability,and accessibility of dermatology ed-ucation.This comprehensive review examines the core concepts and technical foundations of GAI,highlights its specific applications within dermatology teaching and learning—including simulated case generation,per-sonalized learning pathways,and academic support—and discusses the current limitations,practical challenges,and ethical considerations surrounding its use.The aim is to provide a balanced perspective on the significant potential of GAI for transforming dermatology education and to offer evidence-based insights to guide future exploration,implementation,and policy development.展开更多
Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide （H2S） in oil and gas reservoirs. However, a few recent experiments prel...Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide （H2S） in oil and gas reservoirs. However, a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H2S generation, in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H2S have not been evaluated. In this study, laboratory experiments were conducted from 200 to 450°C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results, preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However, much more organic sulfur compounds （OSCs） were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally, most of sulfur liberated from pyrite at elevated temperatures was converted to H2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H2S, given the main hydrogen source derived from hydrocarbons. In addition, cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C, producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction （TSR） due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless, in some cases, OSCs and/or low contents of H2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters （hydrocarbons）, which still needs further investigation.展开更多
文摘The analysis of Greenhouse Effect experiments in the public domain indicated that the lab tests were primarily centered around illustrating the mechanics of conventional greenhouses. They used high-energy visible light (such as sunlight), rather than addressing the Greenhouse Effect, which involves low-energy infrared radiation emitted by the Earth’s surface. Studies with argon, a non-greenhouse gas with similar density to CO2, showed thermal heat transfer as the dominant factor in the temperature profiles, with radiation absorption being undetected. The same conclusion was drawn by another study, which measured infrared back radiation. Experiments using exaggerated CO2 concentrations inadvertently illustrated the principle of the Popper Falsification Test by disproving the Greenhouse Effect applicable to CO2 within the troposphere. A straightforward kitchen test showed that a microwave oven cannot be used as a model for the Greenhouse Effect.
文摘In fields such as science and engineering, virtual environment is commonly used to provide replacements for practical hands-on laboratories. Sometimes, these environments take the form of a remote interface to the physical laboratory apparatus and at other times, in the form of a complete software implementation that simulates the laboratory apparatus. In this paper, we report on the use of a semi-immersive 3D mobile Augmented Reality (mAR) interface and limited simulations as a replacement for practical hands-on laboratories in science and engineering. The 3D-mAR based interfaces implementations for three different experiments (from micro-electronics, power and communications engineering) are presented;the discovered limitations are discussed along with the results of an evaluation by science and engineering students from two different institutions and plans for future work.
基金Supported by the National Key Research and Development Program of China(Nos.2017YFA0604100,2016YFC1402004,2017YFC1404200)the Program for Innovation Research and Entrepreneurship Team in Jiangsu Provincethe National Natural Science Foundation of China(Nos.41476022,41490643)。
文摘Geophysical fluid dynamics(GFD)is an interdisciplinary field that studies the large-scale motion of fluids in the natural world.With a wide range of applications such as weather forecasts and climate prediction,GFD employs various research approaches including in-situ observations,satellite measurements,numerical simulations,theoretical analysis,artificial intelligence,and physical model experiments in laboratory.Among these approaches,rotating tank experiments provide a valuable tool for simulating naturally-occurring fluid motions in laboratories.With proportional scaling and proper techniques,scientists can reproduce multi-scale physical processes of stratified fluids in the rotation system,which allows for the simulation of essential characteristics of fluid motions in the atmosphere and oceans.In this review,rotating tanks of various scales in the world are introduced,as these tanks have been actively used to explore fundamental scientific questions in ocean and atmosphere dynamics.To illustrate the GFD experiments,three representative cases are presented to demonstrate the frontier achievements in the the GFD study by using rotating tank experiments:mesoscale eddies in the ocean,convection processes,and plume dynamics.Detailed references for the experimental procedures are provided.Future studies are encouraged to further explore the utilization of rotating tanks with improvements in experimental design and integration of other research methods.This is a promising direction of GFD to help enhance our understanding of the complex nature of fluid motions in the natural world and to address the challenges posed by global environmental changes.
基金the funding from the European Research Council(ERC)under the European Union's Horizon 2020 Research and Innovation Program through the Starting Grant GEoREST(www.georest.eu)under Grant agreement No.801809IMEDEA is an accredited“Maria de Maeztu Excellence Unit”(Grant CEX2021-001198+2 种基金funded by MICIU/AEI/10.13039/501100011033)Iman R.Kivi also acknowledges the funding from the Engineering and Physical Sciences Research Council through the UKRI Postdoc Guarantee Award THMC4CCS(Grant No.EP/X026019/1)Hyunbin Kim and Roman Y.Makhnenko are supported by the US National Science Foundation(Grant No.CMMI-2239630).
文摘Shales are considered to be sealing units for geological carbon storage and suitable host rocks for nuclear waste repositories due to their low permeability.However,the presence of fractures within these formations can significantly alter their flow,transport,and deformation behavior,which is central to the safe implementation of underground storage projects.Fractures not only increase the overall permeability of the rock but also contribute to its anisotropic behavior.This study focuses on characterizing the hydro-mechanical response of a natural fracture to aqueous fluid injection within a shaly specimen of Opalinus Clay.Laboratory experiments were performed to measure the mechanical and flow properties of intact and fractured rock specimens.Subsequently,a three-dimensional(3D)numerical model of water injection into the fractured specimen was developed.This model explicitly accounts for fracture geometry with strain-dependent aperture changes based on the cubic law assumption.Experimental measurements indicate that the fractured shale exhibits permeability up to two orders of magnitude higher than that of the intact counterpart.However,the simulations reveal that fracture permeability locally spans up to eight orders of magnitude.This significant change in permeability affects fluid flow within the rock specimen.The numerical model best reproduces the experimental results for a normal stiffness of the natural fracture of 18.7 MPa/mm at effective mean stresses below 15 MPa,and of 187.2 MPa/mm at higher confinements.This outcome highlights the critical importance of defining the hydro-mechanical parameters of fractures under realistic effective stress conditions with far-reaching implications for secure underground storage.
文摘Steel mesh is used as a passive skin confinement medium to supplement the active support provided by rock bolts for roof and rib control in underground coal mines. Thin spray-on liners(TSL) are believed to have the potential to take the place of steel mesh as the skin confinement medium in underground mines.To confirm this belief, large scale laboratory experiments were conducted to compare the behaviour of welded steel mesh and a TSL, when used in conjunction with rock bolts, in reinforcing strata with weak bedding planes and strata prone to guttering, two common rock conditions which exist in coal mines. It was found that while the peak load taken by the simulated rock mass with weak bedding planes acting as the control sample(no skin confinement) was 2494 kN, the corresponding value of the sample with 5 mm thick TSL reinforcement reached 2856 kN. The peak load of the steel mesh reinforced sample was only2321 kN, but this was attributed to the fact that one of the rock bolts broke during the test. The TSL reinforced sample had a similar post-yield behaviour as the steel mesh reinforced one. The results of the large scale guttering test indicated that a TSL is better than steel mesh in restricting rock movement and thus inhibiting the formation of gutters in the roof.
基金The work was supported bythe National Science Council ,Taiwan,China (Grant No. NSC93-2611-M-110-001)
文摘Laboratory experiments were conducted in a wave flume on internal solitary wave （ISW） of depression and elevation types propagating over a submarine ridge in semicircular/triangular shape. Tests were arranged in series for combinations of submarine ridges of different heights and ISW of different amplitudes. The resuhant wave motions were found differing from thee of surface gravity waves. In deeper water, where an ISW of depression-type prevailed, the process of wave breaking displayed downward motion with continuous eddy on the front face of the ridge followed by upward motion towards the apex of the obstacle. Experimental results also suggested that blockage parameter ξ could be applied to classify various degrees of ISW-ridge interaction, i.e., ξ 〈 0.5 for weak interaction, 0.5 〈 ξ 〈 0.7 for moderate interaction, and 0.7 〈 ξ for wave breaking.
文摘In a Nature Physics report published in late September 2024[1],a team of scientists and engineers at Sandia National Laboratories(Albuquerque,NM,USA)described the results of a laboratory experiment showing that a nuclear blast could create a burst of X-rays powerful enough to change the path of a large asteroid that might one day be on a collision course with Earth.
基金the INSIS Institute of the French CNRS,Aix-Marseille Universitythe Carnot Star Institute,the VISTA Projectthe Norwegian Research Council through the ROSE Project for financial support
文摘Abstract Accurate simulation of seismic wave propaga- tion in complex geological structures is of particular interest nowadays. However conventional methods may fail to simulate realistic wavefields in environments with great and rapid structural changes, due for instance to the presence of shadow zones, diffractions and/or edge effects. Different methods, developed to improve seismic model- ing, are typically tested on synthetic configurations against analytical solutions for simple canonical problems or ref- erence methods, or via direct comparison with real data acquired in situ. Such approaches have limitations,especially if the propagation occurs in a complex envi- ronment with strong-contrast reflectors and surface irreg- ularities, as it can be difficult to determine the method which gives the best approximation of the ＂real＂ solution, or to interpret the results obtained without an a priori knowledge of the geologic environment. An alternative approach for seismics consists in comparing the synthetic data with high-quality data collected in laboratory experi- ments under controlled conditions for a known configuration. In contrast with numerical experiments, laboratory data possess many of the characteristics of field data, as real waves propagate through models with no numerical approximations. We thus present a comparison of laboratory-scaled measurements of 3D zero-offset wave reflection of broadband pulses from a strong topographic environment immersed in a water tank with numerical data simulated by means of a spectral-element method and a discretized Kirchhoff integral method. The results indicate a good quantitative fit in terms of time arrivals and acceptable fit in amplitudes for all datasets.
基金supported by grants managed by l’Agence Nationale de la Recherche under the Investissements d’Avenir programs Grant Nos. ANR-18-EURE-0014, ANR-10-LABX-0039-PALM, and ANR-22-CE30-0044supported by grants from Japan Society for the Promotion of Science (JSPS) KAKENHI (Grant No. 23K20038)+2 种基金JSPS Core-to-Core program (Grant No. JPJSCCA20230003)carried out within the framework of the EUROfusion Consortium, funded by the European Union via the Euratom Research and Training Programme (Grant Agreement No. 101052200-EUROfusion)operated within the framework of the Enabling Research Project No. AWP24-ENR-IFE.02.CEA-01 “Magnetized ICF”
文摘We report the observation of Zeeman splitting in multiple spectral lines emitted by a laser-produced,magnetized plasma(1–3×10^(18)cm^(-3),1–15 eV)in the context of a laboratory astrophysics experiment under a controlled magneticfield up to 20T.Nitrogen lines(NII)in the visible range were used to diagnose the magneticfield and plasma conditions.This was performed by coupling our data with(563–574 nm)the Stark–Zeeman line-shape code PPPB.The excellent agreement between experiment and simulations paves the way for a non-intrusive experimental platform to get time-resolved measurements of the local magneticfield in laboratory plasmas.
基金funded by the National Science and Technology Major Project of China,2016ZX05060-004,2017ZX05036-003the National Natural Science Foundation of China,51574218Strategic Priority Research Program of the Chinese Academy of Sciences,grant number XDB10040200。
文摘Compared with the middle-shallow shale gas reservoirs,deep shale formation often reveals lower fracture complexity,smaller effective stimulated volumes,lower conductivity,and faster declined when the same injection model and technical parameters were used.Therefore,it is necessary to research a special injection model for the deep shale formation.In this paper,a series of laboratory stimulated experiments were carried to analyze the injection method on hydraulic fracturing initiation and propagation in the deep shale formation.The outcrop shale of Longmaxi formation in Sichuan Basin was selected and three different injection methods(constant,stepped-rise and cyclic progressive uplift pump rate)were used in these experiments.The test results showed that the stepped-rise pump rate is conductive to opening the pre-existing natural fracture and bedding planes,the fracture complexity of this injection method is the highest.Meanwhile,the fracturing pressure and total injection volume are the lowest.In contrast,the cyclic-uplift injection method can only form a transverse fracture,and the fracturing pressure is the highest.The research results have an important theoretical guiding value for deep shale hydraulic fracturing operation.
基金supported by State Key Laboratory of Earthquake Dynamics,China
文摘In order to improve our understanding of rock fracture and fault instability driven by high-pressure fluid sources, the authors carried out rock fracture tests using granite under a confining pressure of 80 MPa with fluid injection in the laboratory. Furthermore, we tested a number of numerical models using the FLAC;modeling software to find the best model to represent the experimental results. The high-speed multichannel acoustic emission（AE） waveform recording system used in this study made it possible to examine the total fracture process through detailed monitoring of AE hypocenters and seismic velocity.The experimental results show that injecting high-pressure oil into the rock sample can induce AE activity at very low stress levels and can dramatically reduce the strength of the rock. The results of the numerical simulations show that major experimental results, including the strength, the temporal and spatial patterns of the AE events, and the role of the fluid can be represented fairly well by a model involving（1） randomly distributed defect elements to model pre-existing cracks,（2） random modification of rock properties to represent inhomogeneity introduced by different mineral grains, and（3）macroscopic inhomogeneity. Our study, which incorporates laboratory experiments and numerical simulations, indicates that such an approach is helpful in finding a better model not only for simulating experimental results but also for upscaling purposes.
基金financially supported by the National Natural Science Foundation of China (Grant Nos.51434009 and 51221003)。
文摘A novel expandable conductor was designed and applied in deep-water drilling to improve the vertical and lateral bearing capacity with a significant reduction of conductor jetting depth and soaking time. The vertical and lateral bearing capability of expandable conductors was depicted based on the ultimate subgrade reaction method and pile foundation bearing theory. The load-bearing characteristics of a laboratory-scale expandable conductor were analyzed through laboratory experiments. The serial simulation experiments are accomplished to study the bearing characteristics(vertical ultimate bearing capacity, lateral soil pressure, and lateral displacement) during the conductor soaking process. The laboratory experimental results show that the larger the length and thickness of expandable materials are,the higher the bearing capacity of the wellhead will be. During the conductor soaking process, the soil pressure around the three expandable conductors increases faster, strings representing a stronger squeezing effect and resulting in higher vertical bearing capacity. Furthermore, the lateral displacement of novel expandable conductor is smaller than that of the conventional conductor. All the advantages mentioned above contributed to the reduction of conductor’s jetting depth and soaking time. Lastly, the application workflow of a novel expandable deep-water drilling conductor was established and the autonomous expandable conductor was successfully applied in the South China Sea with a significant reduction of conductor’s jetting depth and soaking time. According to the soil properties and designed installation depth of the surface conductor, the arrangement of expandable materials should be designed reasonably to meet the safety condition and reduce the construction cost of the subsea wellhead.
基金Project(42174170)supported by the National Natural Science Foundation of China。
文摘Controlled laboratory experiments are proved to be a valuable tool for investigating changes in underground physical properties and the related response of surface geophysical signals.The self-potential(SP)method is widely used in mineral resource exploration due to its direct correlation with underground electrochemical gradients.This paper presented the design and construction of an experimental platform based on a multi-channel SP monitoring system.The proposed platform was used to monitor the anodizing corrosion process of different metal blocks from a laboratory perspective,record the real-time SP signal generated by the redox reaction,as well as investigate the geobattery mechanism associated with the natural polarization process of metal mineral resources.The experimental results demonstrate that the constructed SP monitoring platform effectively captures time-series SP signals and provides direct laboratory evidence for the geobattery model.The measured SP data were quantitatively interpreted using the simulated annealing algorithm,and the inversion results closely match the real model.This finding highlights the potential of the SP method as a promising tool for determining the location and spatial distribution of underground polarizers.The study holds reference value for the exploration and exploitation of mineral resources in both terrestrial and marine environments.
基金Supported by Basic and Forward-Looking Project of the Science and Technology Department of SINOPEC(P22213-4)。
文摘Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved.
基金funded by the National Key Research and Development Plan(No.2022YFC3203200)Department of Science and Technology of Guangdong Province(No.2021ZT09G087)the National Natural Science Foundation Project of China(No.42167025).
文摘Complexities in mechanical behaviours of rock masses mainly stem from inherent discontinuities,which calls for advanced bolt-grouting techniques for stability enhancement.Understanding the mechanical properties of bolt-grouted fractured rock mass(BGFR)and developing accurate prediction methods are crucial to optimize the BGFR support strategies.This paper establishes a new elastoplastic(E-P)model based on the orthotropic and the Mohr-Coulomb(M-C)plastic-yielding criteria.The elastic parameters of the model were derived through a meso-mechanical analysis of composite materials mechanics(CMM).Laboratory BGFR specimens were prepared and uniaxial compression test and variable-angle shear test considering different bolt arrangements were carried out to obtain the mechanical parameters of the specimens.Results showed that the anisotropy of BGFR mainly depends on the relative volume content of each component material in a certain direction.Moreover,the mechanical parameters deduced from the theory of composite materials which consider the short fibre effect are shown to be in good agreement with those determined by laboratory experiments,and the variation rules maintained good consistency.Last,a case study of a real tunnel project is provided to highlight the effectiveness,validity and robustness of the developed E-P model in prediction of stresses and deformations.
基金funded by the National Natural Science Foun-dation of China(No.51974343)the China Postdoctoral Science Foundation(No.2021M703588)the Open Fund of Hubei Key Laboratory of Drilling and Production Engineering for Oil and Gas(Yangtze University)(No.YQZC202307).
文摘This study aims to further enhance the oil recovery of reservoirs in the Zhong-2 Block of the Gudao Oilfield by identifying the most effective microbial-flooding activator systems and applying them in the field.We began by analyzing the structure of the reservoirs'endogenous microbial communities to understand the potential impact of microbial flooding.This was followed by determining commonly used activator systems based on their abilities to stimulate oil-displacement functional bacteria.Through laboratory experiments on oil displacement efficiency and sweep characteristics,we determined the optimal activator injection method(injection ratio)and the requisite bacterial concentration for maximal microbial-flooding efficacy.Finally,we selected the optimal activator systems and applied them to field tests.Our findings suggest the target block is highly receptive to microbial-flooding.In terms of performance,the activator systems ranked as No.3>No.4>No.1>No.2.Interestingly,a deep activator system,when compared to the top-performing No.3 system,exhibited a higher bacterial concentration peak and longer peaking duration.Optimal oil displacement effects were observed at a 1:4 vol ratio between the No.3 activator and deep activator systems,with bacterial concentrations of up to 106 cells/mL or above.Field tests with the selected activator systems,following a specific injection protocol,demonstrated a notable increase in oil production and a reduction in water cut.
文摘Conventional closed lab experiments using high-energy light sources and simple temperature sensors showed that CO_(2)-filled bottles often became hotter than bottles containing air.From this,they concluded that it proved the Greenhouse Effect.However,the thermometers and thermocouples used in those experi-ments did not measure absorption by Greenhouse Gases.In this study,a closed system laboratory experiment was designed and constructed to verify the accuracy of the aforesaid conclusion.In this experiment,both thermocou-ples and an infrared detector were used to collect the data.The results showed that the barrier holding the gas absorbed 98.3%of the infrared radiation.And the remaining 1.7%was not observed to be associated with absorption by the Greenhouse Gases.The experiment showed that Non-Greenhouse Gases per-formed as well as or better than the Greenhouse Gases relating to increased temperatures.Data from experiments using only scalar-measuring devices,like thermometers and thermocouples,proved inadequate.It further showed that infrared detectors can measure infrared absorption.However,the amount of absorption by the containment membrane was overwhelming and obscured any measurable observation of any Greenhouse Gas absorption.The conclu-sion was that the conventional Greenhouse Effect laboratory experiments us-ing closed systems failed to prove the Greenhouse Effect theory.
文摘This is the only Greenhouse Effect experiment conducted in an open system using natural conditions and concentrations.In the test,atmospheric air was blown through a chamber and exposed to infrared radiation of the type emit-ted by the Earth.The absorption temperature was measured by an infrared detector.The results showed that the greenhouse gases absorb the Earth’s in-frared radiation,and adding CO_(2) into the air stream proved that it could in-crease the absorption temperature.As such,this laboratory experiment has confirmed the Greenhouse Effect hypothesis.However,the test data showed that it took large concentrations of the greenhouse gases to trigger any mean-ingful effects.The data demonstrated a logarithmic correlation with 99%ac-curacy.This relationship also corroborated a potential minimum activation concentration as well as a flattened peak,forming an equivalent maximum or saturation point.The data proved that water vapor constituted 93 to 97 per-cent of the natural greenhouse gases,and that CO_(2) at its current atmospheric concentration(0.042%)had no measurable effect on the absorption tempera-ture.The data also showed that CO_(2) does not control atmospheric water vapor or absorption temperature;i.e.,it is not a control knob.The data revealed that CO_(2) and water vapor moved in opposite directions 64%of the time,had differing paths and magnitudes 90%of the time,and exhibited an R^(2) of less than 10%.Concerning CH_(4),the data found no measurable infrared absorption,even at 241 times higher than its current level.The same observation occurred with O_(3) when the concentration was increased 2,500 times higher than normal.All three of these greenhouse gases(CO_(2),CH_(4),O_(3))were too low at current at-mospheric concentrations to trigger a response.Water vapor was the only one that showed a measurable absorption temperature at the natural concentra-tions.The tests with non-greenhouse gases Ar and He ruled out interference by thermal heat transfer mechanisms.
文摘Generative Artificial Intelligence(GAI)refers to a class of AI systems capable of creating novel,coherent,and contextually relevant content—such as text,images,audio,and video—based on patterns learned from extensive training datasets.The public release and rapid refinement of large language models(LLMs)like ChatGPT have accelerated the adoption of GAI across various medical specialties,offering new tools for education,clinical simulation,and research.Dermatology training,which heavily relies on visual pattern recognition and requires extensive exposure to diverse morphological presentations,faces persistent challenges such as uneven distribu-tion of educational resources,limited patient exposure for rare conditions,and variability in teaching quality.Exploring the integration of GAI into pedagogical frameworks offers innovative approaches to address these challenges,potentially enhancing the quality,standardization,scalability,and accessibility of dermatology ed-ucation.This comprehensive review examines the core concepts and technical foundations of GAI,highlights its specific applications within dermatology teaching and learning—including simulated case generation,per-sonalized learning pathways,and academic support—and discusses the current limitations,practical challenges,and ethical considerations surrounding its use.The aim is to provide a balanced perspective on the significant potential of GAI for transforming dermatology education and to offer evidence-based insights to guide future exploration,implementation,and policy development.
基金the National Natural Science Foundations of China(No.41472095 and No.40902034)the Foundation of State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing(No.PRP/open-1508)PetroChina Innovation Foundation(No.2012D-5006-0104)
文摘Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide （H2S） in oil and gas reservoirs. However, a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H2S generation, in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H2S have not been evaluated. In this study, laboratory experiments were conducted from 200 to 450°C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results, preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However, much more organic sulfur compounds （OSCs） were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally, most of sulfur liberated from pyrite at elevated temperatures was converted to H2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H2S, given the main hydrogen source derived from hydrocarbons. In addition, cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C, producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction （TSR） due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless, in some cases, OSCs and/or low contents of H2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters （hydrocarbons）, which still needs further investigation.
