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预还原催化剂LaNiO3,La4Ni3O10,La3Ni2O7和La2NiO4催化分解CH4制碳纳米管的研究 被引量:6
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作者 李贺 梁奇 +4 位作者 唐水花 高利珍 陈召勇 张伯兰 于作龙 《化学学报》 SCIE CAS CSCD 北大核心 2001年第8期1236-1240,共5页
通过预还原的LaNiO3,La4Ni3O10,LaNi2O7和La2 NiO4催化分解CH4可以制备大量高度石墨化的碳纳米管.还原前后的催化剂的结构和组分通过X射线衍射(XBD)测定.所制得的碳纳米管由扫描电镜(TEM)、X射线光电子能谱(XPS)表征.碳纳米管在空气中... 通过预还原的LaNiO3,La4Ni3O10,LaNi2O7和La2 NiO4催化分解CH4可以制备大量高度石墨化的碳纳米管.还原前后的催化剂的结构和组分通过X射线衍射(XBD)测定.所制得的碳纳米管由扫描电镜(TEM)、X射线光电子能谱(XPS)表征.碳纳米管在空气中的热氧化性由热重实验(TG)测定.实验结果表明不同催化剂前驱中的La/Ni比会影响碳纳米管的管径分布和石墨化程度.La/Ni比越小,碳纳米管的管径越大,石墨化程度越高. 展开更多
关键词 碳纳米管 LANIO3 La4Ni3O10 la3ni2o7 La2NiO4 CH4 预还原催化剂 镍酸镧 甲烷 催化分解 制备
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A Study on Production of Carbon Nanotubes by CH_4 Decomposition over LaNiO_3,La_4Ni_3O_(10),La_3Ni_2O_7 and La_2NiO_4
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作者 He LI Shui Hua TANG +5 位作者 Bao Chun LIU Li Zhen GAO Bai Ling LIU Qi LIANG Bo Lan ZHANG Zuo Long YU 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第9期839-842,共4页
Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4. The CNTs obtained were characterized by m... Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4. The CNTs obtained were characterized by means of transmission electron microscopy (TEM). Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The results revealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature. 展开更多
关键词 Carbon nanotubes LANIO3 La2NiO4 la3ni2o7 La4Ni3O10 CH4
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