In recent years,the path planning for multi-agent technology has gradually matured,and has made breakthrough progress.The main difficulties in path planning for multi-agent are large state space,long algorithm running...In recent years,the path planning for multi-agent technology has gradually matured,and has made breakthrough progress.The main difficulties in path planning for multi-agent are large state space,long algorithm running time,multiple optimization objectives,and asynchronous action of multiple agents.To solve the above problems,this paper first introduces the main problem of the research:multi-objective multi-agent path finding with asynchronous action,and proposes the algorithm framework of multi-objective loose synchronous(MO-LS)search.By combining A*and M*,MO-LS-A*and MO-LS-M*algorithms are respectively proposed.The completeness and optimality of the algorithm are proved,and a series of comparative experiments are designed to analyze the factors affecting the performance of the algorithm,verifying that the proposed MO-LS-M*algorithm has certain advantages.展开更多
In 2024,China’s economy gradually trended towards recovery from the COVID-19 pandemic.According to official data released by the National Bureau of Statistics on January 17,preliminary estimates show China’s gross d...In 2024,China’s economy gradually trended towards recovery from the COVID-19 pandemic.According to official data released by the National Bureau of Statistics on January 17,preliminary estimates show China’s gross domestic product(GDP)at nearly 134 trillion yuan(US$18.7 trillion)in 2024,an increase of 5.0 percent over the previous year at constant prices.展开更多
A novel block–particle discrete-element simulation method that matches the double medium of overlying rock(OLR)and loose layer(LSL)in coal mining is developed in this study.This method achieves the collaborative fail...A novel block–particle discrete-element simulation method that matches the double medium of overlying rock(OLR)and loose layer(LSL)in coal mining is developed in this study.This method achieves the collaborative failure characteristics of mining damage under the conduction of double media between the OLR and LSL by combining the self-weight stress loading of the LSL and the breakage morphology of the bedrock top.Based on this,the conduction law of high-strength mining damage in the double medium in a western mining area is simulated and analyzed.The combining effect of the OLR breakage morphology and LSL characteristics on the surface-subsidence characteristics is analyzed and verified based on on-site measurements.The results indicate that the OLR is guided by the“double-control layer and thick-soft rock buffer layer”and shows“grouping subsidence”,whereas the surface forms collaborative subsidence with the thick-soft rock buffer layer.In the ultra-full mining stage,the surface presents an“asymmetric inverted trapezoidal”subsidence trough shape.The simulation results agree well the on-site measurements in terms of the surface-subsidence and bedrock-subsidence coefficients.The proposed simulation method provides a scientific approach for investigating the micro-conduction mechanism of mining damage under the effect of high-strength mining in western mining areas.It will benefit future investigations pertaining to the characteristics of OLR breakage and surface subsidence under conditions such as LSL thickness and proportion.展开更多
Maintaining the stability of the excavation face is key for ensuring the safety of underwater shield tunnel construction.However,the majority of current studies on the stability of excavation face focus on the homogen...Maintaining the stability of the excavation face is key for ensuring the safety of underwater shield tunnel construction.However,the majority of current studies on the stability of excavation face focus on the homogeneous strata,with limited research conducted on the upper loose and lower dense strata.Active instability tests are conducted in this study,in concert with the digital image correlation(DIC)technique,to investigate the effects of different water pressure ratios in upper loose and lower dense water-rich strata.The accuracy of these model tests is verified using numerical simulations.The results indicate that as water pressure ratio decreases,there is an increase in both the peak displacement of surface settlement and the seepage path range of water ahead of the excavation face expands.In contrast,decreasing water pressure ratio will break the limit equilibrium state of the strata faster,cause the earth pressure on the cutterhead to change more rapidly,and increase the instability range of the strata.展开更多
In this paper,the nonlinear dynamics of a curved pipe is investigated in the case of principal parametric resonance due to pulsating flow and impact with loose supports.The coupled in-plane and out-of-plane governing ...In this paper,the nonlinear dynamics of a curved pipe is investigated in the case of principal parametric resonance due to pulsating flow and impact with loose supports.The coupled in-plane and out-of-plane governing equations with the consideration of von Karman geometric nonUnearity are presented and discretized via the differential quadrature method(DQM).The nonlinear dynamic responses are calculated numerically to demonstrate the influence of pulsating frequency.Finally,the impact is taken into consideration.The influence of clearance on frettingwear damage,such as normal work rate,contact ratio and impact force level,is demonstrated.展开更多
The dynamical cluster-decay model (DCM) is employed to investigate the decay of ^(6870)Ge~* compound nuclei formed respectively via tightly (~4He) and loosely (~6He) bound projectiles, using ^(64)Zn target. The study ...The dynamical cluster-decay model (DCM) is employed to investigate the decay of ^(6870)Ge~* compound nuclei formed respectively via tightly (~4He) and loosely (~6He) bound projectiles, using ^(64)Zn target. The study is carried out over a wide energy range (E_(c.m.)~5 MeV to 16 MeV) by including the quadrupole deformations (β_(2i)) and optimum orientations (θ_i^(opt)) of the decaying fragments. The fusion cross-sections, obtained by adding various evaporation channels show nice agreement with the experimental data for ~4He+^(64)Zn reaction. The contribution from competing compound inelastic scattering channel is also analyzed particularly for ^(68)Ge~* nucleus at above barrier energies. On the other hand,the decrement in the fusion cross-sections of ^(70)Ge~* nuclear system is addressed by presuming that ^(65)Zn ER is formed via two different modes:(i) the αn evaporation of ^(70Ge)~* nucleus, and(ii) 1n-evaporation of ^(66)Zn~*nuclear system,formed via breakup and 2n-transfer channels due to halo structure of the ~6He projectile. Besides this, the suppression in2 np evaporation cross-sections suggests the contribution of another breakup and transfer process of ~6He i.e. ~4He+ ^(64)Zn.The contribution of breakup+transfer channels for ~6He+^(64)Zn reaction is duly addressed by applying relevant energy corrections due to the breakup of "~6He" projectile into 2n and ~4He. In addition to this, the barrier lowering, angular momentum and energy dependence effects are also explored in view of the dynamics of chosen reactions.展开更多
A hindcast simulation of 75 typhoons and winter monsoons which affected the coastal areas of Korean Peninsula is performed by use of a third generation ocean wave prediction model, WAM-cycle 4 model, loosely coupled w...A hindcast simulation of 75 typhoons and winter monsoons which affected the coastal areas of Korean Peninsula is performed by use of a third generation ocean wave prediction model, WAM-cycle 4 model, loosely coupled with a com-bined tide and surge model. Typhoon wind fields are derived from the planetary marine boundary layer model for effective neutral winds embedding the vortical storm wind from the parameterized Rankin vortex type model in the limited areas of the overall modeled region. The hindcasted results illustrate that significant wave heights (SWH) considering the wave-tide-surge coupled process are significantly different from the results via the decoupled case especially in the region of the estuaries of the Changjiang Estuary, The Hangzhou Bay, and the southwestern tip of Korean Peninsula. This extensive model simulation is the first attempt to investigate the strong wave-tide-surge interaction for the shallow depth area along the coasts of the Yellow Sea and the East China Sea Continental shelf.展开更多
The high and steep slopes along a high-speed railway in the mountainous area of Southwest China are mostly composed of loose accumulations of debris with large internal pores and poor stability,which can easily induce...The high and steep slopes along a high-speed railway in the mountainous area of Southwest China are mostly composed of loose accumulations of debris with large internal pores and poor stability,which can easily induce adverse geological disasters under rainfall conditions.To ensure the smooth construction of the high-speed railway and the subsequent safe operation,it is necessary to master the stability evolution process of the loose accumulation slope under rainfall.This article simulates rainfall using the finite element analysis software’s hydromechanical coupling module.The slope stability under various rainfall situations is calculated and analysed based on the strength reduction method.To validate the simulation results,a field monitoring system is established to study the deformation characteristics of the slope under rainfall.The results show that rainfall duration is the key factor affecting slope stability.Given a constant amount of rainfall,the stability of the slope decreases with increasing duration of rainfall.Moreover,when the amount and duration of rainfall are constant,continuous rainfall has a greater impact on slope stability than intermittent rainfall.The setting of the field retaining structures has a significant role in improving slope stability.The field monitoring data show that the slope is in the initial deformation stage and has good stability,which verifies the rationality of the numerical simulation method.The research results can provide some references for understanding the influence of rainfall on the stability of loose accumulation slopes along high-speed railways and establishing a monitoring system.展开更多
With the rapid development of information technology, adopting advanced distributed computing technology to construct robot control system is becoming an effective approach gradually. This paper proposes a distributed...With the rapid development of information technology, adopting advanced distributed computing technology to construct robot control system is becoming an effective approach gradually. This paper proposes a distributed loosely coupled software architecture based on Agent and CORBA to control multiple robots. This model provides the robot user with agent control units at the semantic level and CORBA provides function interfaces to agent at the syntax level, which shows a good adaptability, flexibility and transparence.展开更多
Under investigation in this paper is a complex modified Korteweg–de Vries(KdV) equation, which describes the propagation of short pulses in optical fibers. Bilinear forms and multi-soliton solutions are obtained thro...Under investigation in this paper is a complex modified Korteweg–de Vries(KdV) equation, which describes the propagation of short pulses in optical fibers. Bilinear forms and multi-soliton solutions are obtained through the Hirota method and symbolic computation. Breather-like and bound-state solitons are constructed in which the signs of the imaginary parts of the complex wave numbers and the initial separations of the two parallel solitons are important factors for the interaction patterns. The periodic structures and position-induced phase shift of some solutions are introduced.展开更多
Background: Loose bodies (LBs) within the knee joint are commonly encountered during clinical practice and are frequently observed during knee arthroscopy. The primary treatment involves the removal of loose bodies;ho...Background: Loose bodies (LBs) within the knee joint are commonly encountered during clinical practice and are frequently observed during knee arthroscopy. The primary treatment involves the removal of loose bodies;however, their complete eradication is often challenging and may not address underlying diseases, leading to persistent symptoms and the risk of new loose body formation. Aim: This case report aims to present the findings and surgical management of a 52-year-old male with an unusually large osseous loose body in the knee joint and associated pathologies. Case Presentation: The patient, a 52-year-old male, experienced recurrent episodes of severe, sudden, and painful locking of the knee joint, leading to difficulties moving. A plain MRI study was conducted to evaluate the condition of the knee joint, which revealed various degenerative changes and the presence of a loose body. Subsequently, an arthroscopic examination was performed under general anesthesia, uncovering the presence of an abnormally large loose body, as well as other pathologies including chondropathy, meniscal degeneration, and Baker’s cyst. Conclusion: Loose bodies (LBs) in the knee joint pose significant challenges and may lead to debilitating symptoms. Timely diagnosis and appropriate surgical intervention are crucial for symptom relief and the prevention of further joint damage as arthroscopic excision. Comprehensive imaging has a vital role in guiding treatment decisions and optimizing patient outcomes. In this case, the removal of the loose body improved patient outcomes and helped prevent potential joint complications.展开更多
Solar-driven water splitting for photocatalytic hydrogen evolution is considered a highly promising and costeffective solution to achieve a stable renewable energy supply.However,the sluggish kinetics of electron-hole...Solar-driven water splitting for photocatalytic hydrogen evolution is considered a highly promising and costeffective solution to achieve a stable renewable energy supply.However,the sluggish kinetics of electron-hole pairs’separation poses challenges in attaining satisfactory hydrogen production efficiency.Herein,we synthesized the exceptional performance of highly crystalline C_(3)N_(5)(HC–C_(3)N_(5))nanosheet as a photocatalyst,demonstrating a remarkable hydrogen evolution rate of 3.01 mmol h^(-1)g^(-1),which surpasses that of bulk C_(3)N_(5)(B–C_(3)N_(5))by a factor of 3.27.Experimental and theoretical analyses reveal that HC-C_(3)N_(5)nanosheets exhibit intriguing macroscopic photoinduced color changes,effectively broadening the absorption spectrum and significantly enhancing the generation of excitons.Besides,the cyano groups in HC-C_(3)N_(5)efficiently captures and converts photoexcited electrons into bound states,thereby prolonging their lifetimes and effectively separating electrons and holes into catalytically active regions.This research provides valuable insights into the establishment of bound electronic states for developing efficient photocatalysts.展开更多
Barley production has been constrained by various factors,of which loose smut(Ustilago nuda)is the main biotic factor.Molecular and agronomical screening analyses were evaluated to study the similarity levels and mark...Barley production has been constrained by various factors,of which loose smut(Ustilago nuda)is the main biotic factor.Molecular and agronomical screening analyses were evaluated to study the similarity levels and marker assisted selection associated with resistance to loose smut among eight barley genotypes using sequence-related amplified polymorphism(SRAP).Agronomical parameters during two consecutive 2021 and 2022 seasons were studied to identify their reaction to loose smut.The results exhibited significant differences among all studied genotypes for all studied characters,and the highest mean values for all studied traits were detected in Giza 136 and Giza 137.Six SRAP selected primer combinations were amplified and gave 56 total fragments,where primer combination me1+em3 gave the highest polymorphism(100%)and the highest polymorphic information content of PIC was 0.96.The dendrogram of SRAP markers had clustered all studied genotypes into two main clusters.Cluster I includes all the resistance genotypes Giza 136,Giza 137,Giza 123,Giza 132,Giza 138 and Line 2.However,cluster II includes only Line 1 and Line 3 as susceptible genotypes.Thus,SRAP marker could be efficiently used to assess genetic variation among barley genotypes and useful for barley germplasm management in terms of biodiversity protection and design of new crosses for loose smut breeding programs,and seed dressings are commonly used to prevent infected seed from developing smutted heads.Some effective seed dressings include Triticonazole,Black seed oil and gamma rays 150,200,250 Gy.The tested fungicide was highly effective in controlling the disease and gave more than 99%disease control with high grain yield while nature product as black seed oil and utilizing radiation gamma ray 250 GY was the most effective.Utilizing radiation and natural ingredients to manage loose barley smut is economical.展开更多
基金Aeronautical Science Foundation of China(No.20220001057001)。
文摘In recent years,the path planning for multi-agent technology has gradually matured,and has made breakthrough progress.The main difficulties in path planning for multi-agent are large state space,long algorithm running time,multiple optimization objectives,and asynchronous action of multiple agents.To solve the above problems,this paper first introduces the main problem of the research:multi-objective multi-agent path finding with asynchronous action,and proposes the algorithm framework of multi-objective loose synchronous(MO-LS)search.By combining A*and M*,MO-LS-A*and MO-LS-M*algorithms are respectively proposed.The completeness and optimality of the algorithm are proved,and a series of comparative experiments are designed to analyze the factors affecting the performance of the algorithm,verifying that the proposed MO-LS-M*algorithm has certain advantages.
文摘In 2024,China’s economy gradually trended towards recovery from the COVID-19 pandemic.According to official data released by the National Bureau of Statistics on January 17,preliminary estimates show China’s gross domestic product(GDP)at nearly 134 trillion yuan(US$18.7 trillion)in 2024,an increase of 5.0 percent over the previous year at constant prices.
基金support for this work is provided by the National Key R&D Program of China(2023YFC3012101)the National Natural Science Foundation of China(52474161)the Fundamental Research Funds for the Central Universities(2024ZKPYNY01).
文摘A novel block–particle discrete-element simulation method that matches the double medium of overlying rock(OLR)and loose layer(LSL)in coal mining is developed in this study.This method achieves the collaborative failure characteristics of mining damage under the conduction of double media between the OLR and LSL by combining the self-weight stress loading of the LSL and the breakage morphology of the bedrock top.Based on this,the conduction law of high-strength mining damage in the double medium in a western mining area is simulated and analyzed.The combining effect of the OLR breakage morphology and LSL characteristics on the surface-subsidence characteristics is analyzed and verified based on on-site measurements.The results indicate that the OLR is guided by the“double-control layer and thick-soft rock buffer layer”and shows“grouping subsidence”,whereas the surface forms collaborative subsidence with the thick-soft rock buffer layer.In the ultra-full mining stage,the surface presents an“asymmetric inverted trapezoidal”subsidence trough shape.The simulation results agree well the on-site measurements in terms of the surface-subsidence and bedrock-subsidence coefficients.The proposed simulation method provides a scientific approach for investigating the micro-conduction mechanism of mining damage under the effect of high-strength mining in western mining areas.It will benefit future investigations pertaining to the characteristics of OLR breakage and surface subsidence under conditions such as LSL thickness and proportion.
基金supported by the National Natural Science Foundation of China(No.51978019)the Natural Science Foundation of Beijing Municipality(No.8222004),China.
文摘Maintaining the stability of the excavation face is key for ensuring the safety of underwater shield tunnel construction.However,the majority of current studies on the stability of excavation face focus on the homogeneous strata,with limited research conducted on the upper loose and lower dense strata.Active instability tests are conducted in this study,in concert with the digital image correlation(DIC)technique,to investigate the effects of different water pressure ratios in upper loose and lower dense water-rich strata.The accuracy of these model tests is verified using numerical simulations.The results indicate that as water pressure ratio decreases,there is an increase in both the peak displacement of surface settlement and the seepage path range of water ahead of the excavation face expands.In contrast,decreasing water pressure ratio will break the limit equilibrium state of the strata faster,cause the earth pressure on the cutterhead to change more rapidly,and increase the instability range of the strata.
文摘In this paper,the nonlinear dynamics of a curved pipe is investigated in the case of principal parametric resonance due to pulsating flow and impact with loose supports.The coupled in-plane and out-of-plane governing equations with the consideration of von Karman geometric nonUnearity are presented and discretized via the differential quadrature method(DQM).The nonlinear dynamic responses are calculated numerically to demonstrate the influence of pulsating frequency.Finally,the impact is taken into consideration.The influence of clearance on frettingwear damage,such as normal work rate,contact ratio and impact force level,is demonstrated.
基金Supported by CSIR-Scheme No.03(1341)/15/EMR-IIthe University Grants Commission(UGC),in the form of Maulana Azad National Fellowship(MANF)
文摘The dynamical cluster-decay model (DCM) is employed to investigate the decay of ^(6870)Ge~* compound nuclei formed respectively via tightly (~4He) and loosely (~6He) bound projectiles, using ^(64)Zn target. The study is carried out over a wide energy range (E_(c.m.)~5 MeV to 16 MeV) by including the quadrupole deformations (β_(2i)) and optimum orientations (θ_i^(opt)) of the decaying fragments. The fusion cross-sections, obtained by adding various evaporation channels show nice agreement with the experimental data for ~4He+^(64)Zn reaction. The contribution from competing compound inelastic scattering channel is also analyzed particularly for ^(68)Ge~* nucleus at above barrier energies. On the other hand,the decrement in the fusion cross-sections of ^(70)Ge~* nuclear system is addressed by presuming that ^(65)Zn ER is formed via two different modes:(i) the αn evaporation of ^(70Ge)~* nucleus, and(ii) 1n-evaporation of ^(66)Zn~*nuclear system,formed via breakup and 2n-transfer channels due to halo structure of the ~6He projectile. Besides this, the suppression in2 np evaporation cross-sections suggests the contribution of another breakup and transfer process of ~6He i.e. ~4He+ ^(64)Zn.The contribution of breakup+transfer channels for ~6He+^(64)Zn reaction is duly addressed by applying relevant energy corrections due to the breakup of "~6He" projectile into 2n and ~4He. In addition to this, the barrier lowering, angular momentum and energy dependence effects are also explored in view of the dynamics of chosen reactions.
基金The research is a part of the second phase(1998-2000)of Natural Hazard Prevention Research funded by the Ministry of Science and Technology through Korea Institute of Science and Technology Evaluation and Planning (KISTEP) and Group for Natural Hazard Pr
文摘A hindcast simulation of 75 typhoons and winter monsoons which affected the coastal areas of Korean Peninsula is performed by use of a third generation ocean wave prediction model, WAM-cycle 4 model, loosely coupled with a com-bined tide and surge model. Typhoon wind fields are derived from the planetary marine boundary layer model for effective neutral winds embedding the vortical storm wind from the parameterized Rankin vortex type model in the limited areas of the overall modeled region. The hindcasted results illustrate that significant wave heights (SWH) considering the wave-tide-surge coupled process are significantly different from the results via the decoupled case especially in the region of the estuaries of the Changjiang Estuary, The Hangzhou Bay, and the southwestern tip of Korean Peninsula. This extensive model simulation is the first attempt to investigate the strong wave-tide-surge interaction for the shallow depth area along the coasts of the Yellow Sea and the East China Sea Continental shelf.
基金supported by the National Natural Science Foundation of China (No.51978588).
文摘The high and steep slopes along a high-speed railway in the mountainous area of Southwest China are mostly composed of loose accumulations of debris with large internal pores and poor stability,which can easily induce adverse geological disasters under rainfall conditions.To ensure the smooth construction of the high-speed railway and the subsequent safe operation,it is necessary to master the stability evolution process of the loose accumulation slope under rainfall.This article simulates rainfall using the finite element analysis software’s hydromechanical coupling module.The slope stability under various rainfall situations is calculated and analysed based on the strength reduction method.To validate the simulation results,a field monitoring system is established to study the deformation characteristics of the slope under rainfall.The results show that rainfall duration is the key factor affecting slope stability.Given a constant amount of rainfall,the stability of the slope decreases with increasing duration of rainfall.Moreover,when the amount and duration of rainfall are constant,continuous rainfall has a greater impact on slope stability than intermittent rainfall.The setting of the field retaining structures has a significant role in improving slope stability.The field monitoring data show that the slope is in the initial deformation stage and has good stability,which verifies the rationality of the numerical simulation method.The research results can provide some references for understanding the influence of rainfall on the stability of loose accumulation slopes along high-speed railways and establishing a monitoring system.
文摘With the rapid development of information technology, adopting advanced distributed computing technology to construct robot control system is becoming an effective approach gradually. This paper proposes a distributed loosely coupled software architecture based on Agent and CORBA to control multiple robots. This model provides the robot user with agent control units at the semantic level and CORBA provides function interfaces to agent at the syntax level, which shows a good adaptability, flexibility and transparence.
基金Project supported by the National Natural Science Foundation of China (Grant No. 12161061)the Fundamental Research Funds for the Inner Mongolia University of Finance and Economics (Grant No. NCYWT23036)+2 种基金the Young Innovative and Entrepreneurial Talents of the Inner Mongolia Grassland Talents Project in 2022,Autonomous Region “Five Major Tasks” Research Special Project for the Inner Mongolia University of Finance and Economics in 2024 (Grant No. NCXWD2422)High Quality Research Achievement Cultivation Fund for the Inner Mongolia University of Finance and Economics in 2024 (Grant No. GZCG2426)the Talent Development Fund of Inner Mongolia Autonomous Region, China。
文摘Under investigation in this paper is a complex modified Korteweg–de Vries(KdV) equation, which describes the propagation of short pulses in optical fibers. Bilinear forms and multi-soliton solutions are obtained through the Hirota method and symbolic computation. Breather-like and bound-state solitons are constructed in which the signs of the imaginary parts of the complex wave numbers and the initial separations of the two parallel solitons are important factors for the interaction patterns. The periodic structures and position-induced phase shift of some solutions are introduced.
文摘Background: Loose bodies (LBs) within the knee joint are commonly encountered during clinical practice and are frequently observed during knee arthroscopy. The primary treatment involves the removal of loose bodies;however, their complete eradication is often challenging and may not address underlying diseases, leading to persistent symptoms and the risk of new loose body formation. Aim: This case report aims to present the findings and surgical management of a 52-year-old male with an unusually large osseous loose body in the knee joint and associated pathologies. Case Presentation: The patient, a 52-year-old male, experienced recurrent episodes of severe, sudden, and painful locking of the knee joint, leading to difficulties moving. A plain MRI study was conducted to evaluate the condition of the knee joint, which revealed various degenerative changes and the presence of a loose body. Subsequently, an arthroscopic examination was performed under general anesthesia, uncovering the presence of an abnormally large loose body, as well as other pathologies including chondropathy, meniscal degeneration, and Baker’s cyst. Conclusion: Loose bodies (LBs) in the knee joint pose significant challenges and may lead to debilitating symptoms. Timely diagnosis and appropriate surgical intervention are crucial for symptom relief and the prevention of further joint damage as arthroscopic excision. Comprehensive imaging has a vital role in guiding treatment decisions and optimizing patient outcomes. In this case, the removal of the loose body improved patient outcomes and helped prevent potential joint complications.
基金supported by the National Natural Science Foundation of China(No.22006057,21906072 and 21908115)Postgraduate Research&Practice Innovation Program of Jiangsu Province(China)(SJCX23_2197)Natural Science Foundation of Zhejiang Province of China(LY20E080014).
文摘Solar-driven water splitting for photocatalytic hydrogen evolution is considered a highly promising and costeffective solution to achieve a stable renewable energy supply.However,the sluggish kinetics of electron-hole pairs’separation poses challenges in attaining satisfactory hydrogen production efficiency.Herein,we synthesized the exceptional performance of highly crystalline C_(3)N_(5)(HC–C_(3)N_(5))nanosheet as a photocatalyst,demonstrating a remarkable hydrogen evolution rate of 3.01 mmol h^(-1)g^(-1),which surpasses that of bulk C_(3)N_(5)(B–C_(3)N_(5))by a factor of 3.27.Experimental and theoretical analyses reveal that HC-C_(3)N_(5)nanosheets exhibit intriguing macroscopic photoinduced color changes,effectively broadening the absorption spectrum and significantly enhancing the generation of excitons.Besides,the cyano groups in HC-C_(3)N_(5)efficiently captures and converts photoexcited electrons into bound states,thereby prolonging their lifetimes and effectively separating electrons and holes into catalytically active regions.This research provides valuable insights into the establishment of bound electronic states for developing efficient photocatalysts.
文摘Barley production has been constrained by various factors,of which loose smut(Ustilago nuda)is the main biotic factor.Molecular and agronomical screening analyses were evaluated to study the similarity levels and marker assisted selection associated with resistance to loose smut among eight barley genotypes using sequence-related amplified polymorphism(SRAP).Agronomical parameters during two consecutive 2021 and 2022 seasons were studied to identify their reaction to loose smut.The results exhibited significant differences among all studied genotypes for all studied characters,and the highest mean values for all studied traits were detected in Giza 136 and Giza 137.Six SRAP selected primer combinations were amplified and gave 56 total fragments,where primer combination me1+em3 gave the highest polymorphism(100%)and the highest polymorphic information content of PIC was 0.96.The dendrogram of SRAP markers had clustered all studied genotypes into two main clusters.Cluster I includes all the resistance genotypes Giza 136,Giza 137,Giza 123,Giza 132,Giza 138 and Line 2.However,cluster II includes only Line 1 and Line 3 as susceptible genotypes.Thus,SRAP marker could be efficiently used to assess genetic variation among barley genotypes and useful for barley germplasm management in terms of biodiversity protection and design of new crosses for loose smut breeding programs,and seed dressings are commonly used to prevent infected seed from developing smutted heads.Some effective seed dressings include Triticonazole,Black seed oil and gamma rays 150,200,250 Gy.The tested fungicide was highly effective in controlling the disease and gave more than 99%disease control with high grain yield while nature product as black seed oil and utilizing radiation gamma ray 250 GY was the most effective.Utilizing radiation and natural ingredients to manage loose barley smut is economical.