It is shown that time asymmetry is essential for deriving thermodynamic law and arises from the turnover of energy while reducing its information content and driving entropy increase. A dynamically interpreted princip...It is shown that time asymmetry is essential for deriving thermodynamic law and arises from the turnover of energy while reducing its information content and driving entropy increase. A dynamically interpreted principle of least action enables time asymmetry and time flow as a generation of action and redefines useful energy as an information system which implements a form of acting information. This is demonstrated using a basic formula, originally applied for time symmetry/energy conservation considerations, relating time asymmetry (which is conventionally denied but here expressly allowed), to energy behaviour. The results derived then explained that a dynamic energy is driving time asymmetry. It is doing it by decreasing the information content of useful energy, thus generating action and entropy increase, explaining action-time as an information phenomenon. Thermodynamic laws follow directly. The formalism derived readily explains what energy is, why it is conserved (1st law of thermodynamics), why entropy increases (2nd law) and that maximum entropy production within the restraints of the system controls self-organized processes of non-linear irreversible thermodynamics. The general significance of the principle of least action arises from its role of controlling the action generating oriented time of nature. These results contrast with present understanding of time neutrality and clock-time, which are here considered a source of paradoxes, intellectual contradictions and dead-end roads in models explaining nature and the universe.展开更多
In order to deal with the issue of huge computational cost very well in direct numerical simulation, the traditional response surface method (RSM) as a classical regression algorithm is used to approximate a functiona...In order to deal with the issue of huge computational cost very well in direct numerical simulation, the traditional response surface method (RSM) as a classical regression algorithm is used to approximate a functional relationship between the state variable and basic variables in reliability design. The algorithm has treated successfully some problems of implicit performance function in reliability analysis. However, its theoretical basis of empirical risk minimization narrows its range of applications for...展开更多
A multi-loop adaptive internal model control (IMC) strategy based on a dynamic partial least squares (PLS) frame-work is proposed to account for plant model errors caused by slow aging,drift in operational conditions,...A multi-loop adaptive internal model control (IMC) strategy based on a dynamic partial least squares (PLS) frame-work is proposed to account for plant model errors caused by slow aging,drift in operational conditions,or environmental changes.Since PLS decomposition structure enables multi-loop controller design within latent spaces,a multivariable adaptive control scheme can be converted easily into several independent univariable control loops in the PLS space.In each latent subspace,once the model error exceeds a specific threshold,online adaptation rules are implemented separately to correct the plant model mismatch via a recursive least squares (RLS) algorithm.Because the IMC extracts the inverse of the minimum part of the internal model as its structure,the IMC controller is self-tuned by explicitly updating the parameters,which are parts of the internal model.Both parameter convergence and system stability are briefly analyzed,and proved to be effective.Finally,the proposed control scheme is tested and evaluated using a widely-used benchmark of a multi-input multi-output (MIMO) system with pure delay.展开更多
Through theoretical derivation, some properties of the total least squares estimation are found. The total least squares estimation is the linear transformation of the least squares estimation, and the total least squ...Through theoretical derivation, some properties of the total least squares estimation are found. The total least squares estimation is the linear transformation of the least squares estimation, and the total least squares estimation is unbiased. The condition number of the total least squares estimation is greater than the least squares estimation, so the total least squares estimation is easier to be affected by the data error than the least squares estimation. Then through the further derivation, the relationships of solutions, residuals and unit weight variance estimations between the total least squares and the least squares are given.展开更多
An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partia...An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partial least squares(MPLS),are not suitable due to their intrinsic linearity when the variations are nonlinear.To address this issue,kernel partial least squares(KPLS) was used to capture the nonlinear relationship between the latent structures and predictive variables.In addition,KPLS requires only linear algebra and does not involve any nonlinear optimization.In this paper,the application of KPLS was extended to on-line monitoring of batch processes.The proposed batch monitoring method was applied to a simulation benchmark of fed-batch penicillin fermentation process.And the results demonstrate the superior monitoring performance of MKPLS in comparison to MPLS monitoring.展开更多
Consider solving an overdetermined system of linear algebraic equations by both the least squares method (LS) and the total least squares method (TLS). Extensive published computational evidence shows that when the or...Consider solving an overdetermined system of linear algebraic equations by both the least squares method (LS) and the total least squares method (TLS). Extensive published computational evidence shows that when the original system is consistent. one often obtains more accurate solutions by using the TLS method rather than the LS method. These numerical observations contrast with existing analytic perturbation theories for the LS and TLS methods which show that the upper bounds for the LS solution are always smaller than the corresponding upper bounds for the TLS solutions. In this paper we derive a new upper bound for the TLS solution and indicate when the TLS method can be more accurate than the LS method.Many applied problems in signal processing lead to overdetermined systems of linear equations where the matrix and right hand side are determined by the experimental observations (usually in the form of a lime series). It often happens that as the number of columns of the matrix becomes larger, the展开更多
The least trimmed squares estimator (LTS) is a well known robust estimator in terms of protecting the estimate from the outliers. Its high computational complexity is however a problem in practice. We show that the LT...The least trimmed squares estimator (LTS) is a well known robust estimator in terms of protecting the estimate from the outliers. Its high computational complexity is however a problem in practice. We show that the LTS estimate can be obtained by a simple algorithm with the complexity 0( N In N) for large N, where N is the number of measurements. We also show that though the LTS is robust in terms of the outliers, it is sensitive to the inliers. The concept of the inliers is introduced. Moreover, the Generalized Least Trimmed Squares estimator (GLTS) together with its solution are presented that reduces the effect of both the outliers and the inliers. Keywords Least squares - Least trimmed squares - Outliers - System identification - Parameter estimation - Robust parameter estimation This work was supported in part by NSF ECS — 9710297 and ECS — 0098181.展开更多
In this paper, we extend matrix scaled total least squares (MSTLS) problem with a single right-hand side to the case of multiple right-hand sides. Firstly, under some mild conditions, this paper gives an explicit expr...In this paper, we extend matrix scaled total least squares (MSTLS) problem with a single right-hand side to the case of multiple right-hand sides. Firstly, under some mild conditions, this paper gives an explicit expression of the minimum norm solution of MSTLS problem with multiple right-hand sides. Then, we present the Kronecker-product-based formulae for the normwise, mixed and componentwise condition numbers of the MSTLS problem. For easy estimation, we also exhibit Kronecker-product-free upper bounds for these condition numbers. All these results can reduce to those of the total least squares (TLS) problem which were given by Zheng et al. Finally, two numerical experiments are performed to illustrate our results.展开更多
One-class classification problem has become a popular problem in many fields, with a wide range of applications in anomaly detection, fault diagnosis, and face recognition. We investigate the one-class classification ...One-class classification problem has become a popular problem in many fields, with a wide range of applications in anomaly detection, fault diagnosis, and face recognition. We investigate the one-class classification problem for second-order tensor data. Traditional vector-based one-class classification methods such as one-class support vector machine (OCSVM) and least squares one-class support vector machine (LSOCSVM) have limitations when tensor is used as input data, so we propose a new tensor one-class classification method, LSOCSTM, which directly uses tensor as input data. On one hand, using tensor as input data not only enables to classify tensor data, but also for vector data, classifying it after high dimensionalizing it into tensor still improves the classification accuracy and overcomes the over-fitting problem. On the other hand, different from one-class support tensor machine (OCSTM), we use squared loss instead of the original loss function so that we solve a series of linear equations instead of quadratic programming problems. Therefore, we use the distance to the hyperplane as a metric for classification, and the proposed method is more accurate and faster compared to existing methods. The experimental results show the high efficiency of the proposed method compared with several state-of-the-art methods.展开更多
Simultaneous-source acquisition has been recog- nized as an economic and efficient acquisition method, but the direct imaging of the simultaneous-source data produces migration artifacts because of the interference of...Simultaneous-source acquisition has been recog- nized as an economic and efficient acquisition method, but the direct imaging of the simultaneous-source data produces migration artifacts because of the interference of adjacent sources. To overcome this problem, we propose the regularized least-squares reverse time migration method （RLSRTM） using the singular spectrum analysis technique that imposes sparseness constraints on the inverted model. Additionally, the difference spectrum theory of singular values is presented so that RLSRTM can be implemented adaptively to eliminate the migration artifacts. With numerical tests on a fiat layer model and a Marmousi model, we validate the superior imaging quality, efficiency and convergence of RLSRTM compared with LSRTM when dealing with simultaneoussource data, incomplete data and noisy data.展开更多
Detecting plant health conditions plays a key role in farm pest management and crop protection. In this study, measurement of hyperspectral leaf reflectance in rice crop (Oryzasativa L.) was conducted on groups of hea...Detecting plant health conditions plays a key role in farm pest management and crop protection. In this study, measurement of hyperspectral leaf reflectance in rice crop (Oryzasativa L.) was conducted on groups of healthy and infected leaves by the fungus Bipolaris oryzae (Helminthosporium oryzae Breda. de Hann) through the wavelength range from 350 to 2 500 nm. The percentage of leaf surface lesions was estimated and defined as the disease severity. Statistical methods like multiple stepwise regression, principal component analysis and partial least-square regression were utilized to calculate and estimate the disease severity of rice brown spot at the leaf level. Our results revealed that multiple stepwise linear regressions could efficiently estimate disease severity with three wavebands in seven steps. The root mean square errors (RMSEs) for training (n=210) and testing (n=53) dataset were 6.5% and 5.8%, respectively. Principal component analysis showed that the first principal component could explain approximately 80% of the variance of the original hyperspectral reflectance. The regression model with the first two principal components predicted a disease severity with RMSEs of 16.3% and 13.9% for the training and testing dataset, respec-tively. Partial least-square regression with seven extracted factors could most effectively predict disease severity compared with other statistical methods with RMSEs of 4.1% and 2.0% for the training and testing dataset, respectively. Our research demon-strates that it is feasible to estimate the disease severity of rice brown spot using hyperspectral reflectance data at the leaf level.展开更多
Vehicle mass is an important parameter in vehicle dynamics control systems. Although many algorithms have been developed for the estimation of mass, none of them have yet taken into account the different types of resi...Vehicle mass is an important parameter in vehicle dynamics control systems. Although many algorithms have been developed for the estimation of mass, none of them have yet taken into account the different types of resistance that occur under different conditions. This paper proposes a vehicle mass estimator. The estimator incorporates road gradient information in the longitudinal accelerometer signal, and it removes the road grade from the longitudinal dynamics of the vehicle. Then, two different recursive least square method （RLSM） schemes are proposed to estimate the driving resistance and the mass independently based on the acceleration partition under different conditions. A 6 DOF dynamic model of four In-wheel Motor Vehicle is built to assist in the design of the algorithm and in the setting of the parameters. The acceleration limits are determined to not only reduce the estimated error but also ensure enough data for the resistance estimation and mass estimation in some critical situations. The modification of the algorithm is also discussed to improve the result of the mass estimation. Experiment data on asphalt road, plastic runway, and gravel road and on sloping roads are used to validate the estimation algorithm. The adaptability of the algorithm is improved by using data collected under several critical operating conditions. The experimental results show the error of the estimation process to be within 2.6%, which indicates that the algorithm can estimate mass with great accuracy regardless of the road surface and gradient changes and that it may be valuable in engineering applications. This paper proposes a recursive least square vehicle mass estimation method based on acceleration partition.展开更多
Near-infrared spectroscopy（NIR）,which is generally used for online monitoring of the food analysis and production process, was applied to determine the internal quality of toothpaste samples.It is acknowledged that ...Near-infrared spectroscopy（NIR）,which is generally used for online monitoring of the food analysis and production process, was applied to determine the internal quality of toothpaste samples.It is acknowledged that the spectra can be significantly influenced by non-linearities introduced by light scatter,therefore,four data preprocessing methods,including off-set correction, 1st-derivative,standard normal variate（SNV） and multiplicative scatter correction（MSC）,were employed before the date analysis. The multivariate calibration model of partial least squares（PLS） was established and then was used to predict the pH values of the toothpaste samples of different brand.The results showed that the spectral date processed by MSC was the best one for predicting the pH value of the toothpaste samples.展开更多
In this paper, an improved weighted least squares （WLS）, together with autoregressive （AR） model, is proposed to improve prediction accuracy of earth rotation parameters（ERP）. Four weighting schemes are develope...In this paper, an improved weighted least squares （WLS）, together with autoregressive （AR） model, is proposed to improve prediction accuracy of earth rotation parameters（ERP）. Four weighting schemes are developed and the optimal power e for determination of the weight elements is studied. The results show that the improved WLS-AR model can improve the ERP prediction accuracy effectively, and for different prediction intervals of ERP, different weight scheme should be chosen.展开更多
In nature, many physical phenomena follow the least-action principle, which is also abided by the course of explosive welding of stainless steel/steel. The optimal welding interface can be obtained with the least expl...In nature, many physical phenomena follow the least-action principle, which is also abided by the course of explosive welding of stainless steel/steel. The optimal welding interface can be obtained with the least explosive charge by theoretical analysis and interface test. The bonding energy can be acknowledged as the ＂action＂ in explosive welding. To minimize the bonding energy, these rules must be followed such as the lower limit of explosive charge, the upper limit of span and the explosive of critical explosion velocity. The principle of least-action is achieved in the course of explosive welding, and the interface will be optimum.展开更多
文摘It is shown that time asymmetry is essential for deriving thermodynamic law and arises from the turnover of energy while reducing its information content and driving entropy increase. A dynamically interpreted principle of least action enables time asymmetry and time flow as a generation of action and redefines useful energy as an information system which implements a form of acting information. This is demonstrated using a basic formula, originally applied for time symmetry/energy conservation considerations, relating time asymmetry (which is conventionally denied but here expressly allowed), to energy behaviour. The results derived then explained that a dynamic energy is driving time asymmetry. It is doing it by decreasing the information content of useful energy, thus generating action and entropy increase, explaining action-time as an information phenomenon. Thermodynamic laws follow directly. The formalism derived readily explains what energy is, why it is conserved (1st law of thermodynamics), why entropy increases (2nd law) and that maximum entropy production within the restraints of the system controls self-organized processes of non-linear irreversible thermodynamics. The general significance of the principle of least action arises from its role of controlling the action generating oriented time of nature. These results contrast with present understanding of time neutrality and clock-time, which are here considered a source of paradoxes, intellectual contradictions and dead-end roads in models explaining nature and the universe.
基金National High-tech Research and Development Pro-gram (2006AA04Z405)
文摘In order to deal with the issue of huge computational cost very well in direct numerical simulation, the traditional response surface method (RSM) as a classical regression algorithm is used to approximate a functional relationship between the state variable and basic variables in reliability design. The algorithm has treated successfully some problems of implicit performance function in reliability analysis. However, its theoretical basis of empirical risk minimization narrows its range of applications for...
基金Project supported by the National Natural Science Foundation of China (No.60574047)the National High-Tech R & D Program (863)of China (No.2007AA04Z168)the Research Fund for the Doctoral Program of Higher Education of China (No.20050335018)
文摘A multi-loop adaptive internal model control (IMC) strategy based on a dynamic partial least squares (PLS) frame-work is proposed to account for plant model errors caused by slow aging,drift in operational conditions,or environmental changes.Since PLS decomposition structure enables multi-loop controller design within latent spaces,a multivariable adaptive control scheme can be converted easily into several independent univariable control loops in the PLS space.In each latent subspace,once the model error exceeds a specific threshold,online adaptation rules are implemented separately to correct the plant model mismatch via a recursive least squares (RLS) algorithm.Because the IMC extracts the inverse of the minimum part of the internal model as its structure,the IMC controller is self-tuned by explicitly updating the parameters,which are parts of the internal model.Both parameter convergence and system stability are briefly analyzed,and proved to be effective.Finally,the proposed control scheme is tested and evaluated using a widely-used benchmark of a multi-input multi-output (MIMO) system with pure delay.
基金The research was supported by the National Natural Science Foundation of China(41204003)Scientific Research Foundation of ECIT(DHBK201113)Scientific Research Foundation of Jiangxi Province Key Laboratory for Digital Land(DLLJ201207)
文摘Through theoretical derivation, some properties of the total least squares estimation are found. The total least squares estimation is the linear transformation of the least squares estimation, and the total least squares estimation is unbiased. The condition number of the total least squares estimation is greater than the least squares estimation, so the total least squares estimation is easier to be affected by the data error than the least squares estimation. Then through the further derivation, the relationships of solutions, residuals and unit weight variance estimations between the total least squares and the least squares are given.
基金National Natural Science Foundation of China (No. 61074079)Shanghai Leading Academic Discipline Project,China (No.B504)
文摘An approach for batch processes monitoring and fault detection based on multiway kernel partial least squares(MKPLS) was presented.It is known that conventional batch process monitoring methods,such as multiway partial least squares(MPLS),are not suitable due to their intrinsic linearity when the variations are nonlinear.To address this issue,kernel partial least squares(KPLS) was used to capture the nonlinear relationship between the latent structures and predictive variables.In addition,KPLS requires only linear algebra and does not involve any nonlinear optimization.In this paper,the application of KPLS was extended to on-line monitoring of batch processes.The proposed batch monitoring method was applied to a simulation benchmark of fed-batch penicillin fermentation process.And the results demonstrate the superior monitoring performance of MKPLS in comparison to MPLS monitoring.
基金This author was supported by the National Natural Sciences Foundation,PRC. This author was supported by the Air Force Office of Scientific Research, USA, Grant No. AFOSR-91-0309
文摘Consider solving an overdetermined system of linear algebraic equations by both the least squares method (LS) and the total least squares method (TLS). Extensive published computational evidence shows that when the original system is consistent. one often obtains more accurate solutions by using the TLS method rather than the LS method. These numerical observations contrast with existing analytic perturbation theories for the LS and TLS methods which show that the upper bounds for the LS solution are always smaller than the corresponding upper bounds for the TLS solutions. In this paper we derive a new upper bound for the TLS solution and indicate when the TLS method can be more accurate than the LS method.Many applied problems in signal processing lead to overdetermined systems of linear equations where the matrix and right hand side are determined by the experimental observations (usually in the form of a lime series). It often happens that as the number of columns of the matrix becomes larger, the
文摘The least trimmed squares estimator (LTS) is a well known robust estimator in terms of protecting the estimate from the outliers. Its high computational complexity is however a problem in practice. We show that the LTS estimate can be obtained by a simple algorithm with the complexity 0( N In N) for large N, where N is the number of measurements. We also show that though the LTS is robust in terms of the outliers, it is sensitive to the inliers. The concept of the inliers is introduced. Moreover, the Generalized Least Trimmed Squares estimator (GLTS) together with its solution are presented that reduces the effect of both the outliers and the inliers. Keywords Least squares - Least trimmed squares - Outliers - System identification - Parameter estimation - Robust parameter estimation This work was supported in part by NSF ECS — 9710297 and ECS — 0098181.
文摘In this paper, we extend matrix scaled total least squares (MSTLS) problem with a single right-hand side to the case of multiple right-hand sides. Firstly, under some mild conditions, this paper gives an explicit expression of the minimum norm solution of MSTLS problem with multiple right-hand sides. Then, we present the Kronecker-product-based formulae for the normwise, mixed and componentwise condition numbers of the MSTLS problem. For easy estimation, we also exhibit Kronecker-product-free upper bounds for these condition numbers. All these results can reduce to those of the total least squares (TLS) problem which were given by Zheng et al. Finally, two numerical experiments are performed to illustrate our results.
文摘One-class classification problem has become a popular problem in many fields, with a wide range of applications in anomaly detection, fault diagnosis, and face recognition. We investigate the one-class classification problem for second-order tensor data. Traditional vector-based one-class classification methods such as one-class support vector machine (OCSVM) and least squares one-class support vector machine (LSOCSVM) have limitations when tensor is used as input data, so we propose a new tensor one-class classification method, LSOCSTM, which directly uses tensor as input data. On one hand, using tensor as input data not only enables to classify tensor data, but also for vector data, classifying it after high dimensionalizing it into tensor still improves the classification accuracy and overcomes the over-fitting problem. On the other hand, different from one-class support tensor machine (OCSTM), we use squared loss instead of the original loss function so that we solve a series of linear equations instead of quadratic programming problems. Therefore, we use the distance to the hyperplane as a metric for classification, and the proposed method is more accurate and faster compared to existing methods. The experimental results show the high efficiency of the proposed method compared with several state-of-the-art methods.
基金financial support from the National Natural Science Foundation of China (Grant Nos. 41104069, 41274124)National Key Basic Research Program of China (973 Program) (Grant No. 2014CB239006)+2 种基金National Science and Technology Major Project (Grant No. 2011ZX05014-001-008)the Open Foundation of SINOPEC Key Laboratory of Geophysics (Grant No. 33550006-15-FW2099-0033)the Fundamental Research Funds for the Central Universities (Grant No. 16CX06046A)
文摘Simultaneous-source acquisition has been recog- nized as an economic and efficient acquisition method, but the direct imaging of the simultaneous-source data produces migration artifacts because of the interference of adjacent sources. To overcome this problem, we propose the regularized least-squares reverse time migration method （RLSRTM） using the singular spectrum analysis technique that imposes sparseness constraints on the inverted model. Additionally, the difference spectrum theory of singular values is presented so that RLSRTM can be implemented adaptively to eliminate the migration artifacts. With numerical tests on a fiat layer model and a Marmousi model, we validate the superior imaging quality, efficiency and convergence of RLSRTM compared with LSRTM when dealing with simultaneoussource data, incomplete data and noisy data.
基金the Hi-Tech Research and Development Program (863) of China (No. 2006AA10Z203)the National Scienceand Technology Task Force Project (No. 2006BAD10A01), China
文摘Detecting plant health conditions plays a key role in farm pest management and crop protection. In this study, measurement of hyperspectral leaf reflectance in rice crop (Oryzasativa L.) was conducted on groups of healthy and infected leaves by the fungus Bipolaris oryzae (Helminthosporium oryzae Breda. de Hann) through the wavelength range from 350 to 2 500 nm. The percentage of leaf surface lesions was estimated and defined as the disease severity. Statistical methods like multiple stepwise regression, principal component analysis and partial least-square regression were utilized to calculate and estimate the disease severity of rice brown spot at the leaf level. Our results revealed that multiple stepwise linear regressions could efficiently estimate disease severity with three wavebands in seven steps. The root mean square errors (RMSEs) for training (n=210) and testing (n=53) dataset were 6.5% and 5.8%, respectively. Principal component analysis showed that the first principal component could explain approximately 80% of the variance of the original hyperspectral reflectance. The regression model with the first two principal components predicted a disease severity with RMSEs of 16.3% and 13.9% for the training and testing dataset, respec-tively. Partial least-square regression with seven extracted factors could most effectively predict disease severity compared with other statistical methods with RMSEs of 4.1% and 2.0% for the training and testing dataset, respectively. Our research demon-strates that it is feasible to estimate the disease severity of rice brown spot using hyperspectral reflectance data at the leaf level.
基金Supported by National Basic Research Program of China(Grant No.2011CB711200)
文摘Vehicle mass is an important parameter in vehicle dynamics control systems. Although many algorithms have been developed for the estimation of mass, none of them have yet taken into account the different types of resistance that occur under different conditions. This paper proposes a vehicle mass estimator. The estimator incorporates road gradient information in the longitudinal accelerometer signal, and it removes the road grade from the longitudinal dynamics of the vehicle. Then, two different recursive least square method （RLSM） schemes are proposed to estimate the driving resistance and the mass independently based on the acceleration partition under different conditions. A 6 DOF dynamic model of four In-wheel Motor Vehicle is built to assist in the design of the algorithm and in the setting of the parameters. The acceleration limits are determined to not only reduce the estimated error but also ensure enough data for the resistance estimation and mass estimation in some critical situations. The modification of the algorithm is also discussed to improve the result of the mass estimation. Experiment data on asphalt road, plastic runway, and gravel road and on sloping roads are used to validate the estimation algorithm. The adaptability of the algorithm is improved by using data collected under several critical operating conditions. The experimental results show the error of the estimation process to be within 2.6%, which indicates that the algorithm can estimate mass with great accuracy regardless of the road surface and gradient changes and that it may be valuable in engineering applications. This paper proposes a recursive least square vehicle mass estimation method based on acceleration partition.
基金the financial support by the National Natural Science Foundation of China (No.21065007)the State Key Laboratory of Food Science and Technology of Nanchang University(Nos.MB-201002 and TS-200919)
文摘Near-infrared spectroscopy（NIR）,which is generally used for online monitoring of the food analysis and production process, was applied to determine the internal quality of toothpaste samples.It is acknowledged that the spectra can be significantly influenced by non-linearities introduced by light scatter,therefore,four data preprocessing methods,including off-set correction, 1st-derivative,standard normal variate（SNV） and multiplicative scatter correction（MSC）,were employed before the date analysis. The multivariate calibration model of partial least squares（PLS） was established and then was used to predict the pH values of the toothpaste samples of different brand.The results showed that the spectral date processed by MSC was the best one for predicting the pH value of the toothpaste samples.
基金supported by the Foundation for the Author of National Excellent Doctoral Dissertation of China (2007B51)Natural Science Foundation of China (41174008)
文摘In this paper, an improved weighted least squares （WLS）, together with autoregressive （AR） model, is proposed to improve prediction accuracy of earth rotation parameters（ERP）. Four weighting schemes are developed and the optimal power e for determination of the weight elements is studied. The results show that the improved WLS-AR model can improve the ERP prediction accuracy effectively, and for different prediction intervals of ERP, different weight scheme should be chosen.
基金Sponsored by Jiangsu Provincial Foundation of Technology Achievement Transform of China(BA2012030)
文摘In nature, many physical phenomena follow the least-action principle, which is also abided by the course of explosive welding of stainless steel/steel. The optimal welding interface can be obtained with the least explosive charge by theoretical analysis and interface test. The bonding energy can be acknowledged as the ＂action＂ in explosive welding. To minimize the bonding energy, these rules must be followed such as the lower limit of explosive charge, the upper limit of span and the explosive of critical explosion velocity. The principle of least-action is achieved in the course of explosive welding, and the interface will be optimum.
