The Longshan orogenic belt is located in the southwestern margin of Ordos Basin at the junction zone between the Western Qinling and Northern Qilian orogenic belt.Voluminous Early Paleozoic magmatism in this area is o...The Longshan orogenic belt is located in the southwestern margin of Ordos Basin at the junction zone between the Western Qinling and Northern Qilian orogenic belt.Voluminous Early Paleozoic magmatism in this area is of key significance for determining the Early Paleozoic tectonic evolution and deep crust-mantle structure.Previous studies mainly focused on the Paleozoic granites;the coeval mafic rocks in this area are still poorly understood.A set of Late Silurian intraplate tholeiitic basalts has been discovered in Longshan area,providing key evidence for the mantle source and deep geodynamic background in this area.The Late Silurian Angou basalt has similar geochemical features as intraplate tholeiitic basalt,with high Na_(2)O/K_(2)O ratios(5.22-8.25),enriched in large ion lithophile elements and LREE.In combination with their relatively evolved Sr-Nd isotopic composition[^(87)Sr/^(86)Sr(i)=0.7128-0.7140;ε_(Nd)(t)=-5.55 to-3.40],it is suggested that it originated from decompression melting of metasomatized enriched mantle in extensional setting.These results indicate that the mantle source in the junction zone of the West Qinling-North Qilian orogenic belt evolved from depleted to enriched with the continuation of Proto-Tethys subduction from the Cambrian to the Silurian.These results are of great significance to understanding the genesis of contemporaneous granite and the crust-mantle interaction in the junction zone between the Western Qinling and Northern Qilian orogenic belt.展开更多
The Yarlung Zangbo Suture Zone(YZSZ)on the southern margin of the Lhasa block and the Tangjia-Sumdo ultrahigh-pressure metamorphic belt(TSMB)within the block represent natural laboratories for the study of plate tecto...The Yarlung Zangbo Suture Zone(YZSZ)on the southern margin of the Lhasa block and the Tangjia-Sumdo ultrahigh-pressure metamorphic belt(TSMB)within the block represent natural laboratories for the study of plate tectonics and oceanic slab subduction.It is generally believed that these two zones represent the remnants of the ancient oceanic crust and upper mantle of the Yarlung Zangbo Neo-Tethys(YZNT)and the Tangjia-Sumdo Paleo-Tethys(TSPT).However,the evolutionary patterns and spatiotemporal relationships of the TSPT and the YZNT have been debated.展开更多
The Zongwulong Shan-Qinghai Nanshan tectonic belt of the northern Xizang Plateau experienced a protracted tectonica history,including the openings and closures of the Proto-and Paleo-Tethyan Oceans.Although the tecton...The Zongwulong Shan-Qinghai Nanshan tectonic belt of the northern Xizang Plateau experienced a protracted tectonica history,including the openings and closures of the Proto-and Paleo-Tethyan Oceans.Although the tectonic belt has been extensively studied,details regarding the tectonic processes involved in its development remain controversial.To better constrain the tectonic processes of this tectonic belt,we conducted detailed field geological mapping,zircon U-Pb geochronology,and whole-rock geochemical and Sr-Nd isotopic analyses.Our results show that intrusive rocks in the tectonic belt crystallized in ca.292-233 Ma,perhaps in an arc/subduction setting.Geochemical and Sr-Nd isotopic data suggest that Early Permian-Late Triassic ultramaficintermediate intrusions were sourced from the enriched mantle,whereas intermediate-acidic rocks were sourced from mixed crust-mantle.We present the tectonic model that involves:(1)Early Devonian-Early Permian intracontinental extension occurred in the northern margin of the Qaidam continent(ca.416-292 Ma);(2)Early Permian-Late Triassic northward subduction of the Paleo-Tethyan Ocean resulted in arc magmatism(ca.292-233 Ma);and(3)subsequent Late Triassic intracontinental extension(ca.233-215 Ma).Our results suggest that the Late Paleozoic-Early Mesozoic development of the Zongwulong Shan-Qinghai Nanshan was related to the opening,subduction,and slab retreat of the Paleo-Tethyan Ocean,which has key implications for the tectonic evolution of the northern Tibetan Plateau.展开更多
The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu...The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu(LH)granitic rocks in the western NQTB.LA-ICP-MS U-Pb dating of zircons from LH granitic rocks yields emplacement ages of 253±4 Ma and 264±4 Ma,indicating a two-stage emplacement process.Geochemi-cal analyses show that the LH granitic rocks have low ACNK values and are enriched in LILEs(Rb,Th,Ba)and depleted in HFSEs(Sr,Nd,and Ta).The samples are enriched in LREEs(LREE/HREE=1.5-7.3).Values of(La/Yb)N range between 0.9 and 6.5,and all samples show negative Eu anomalies(δEu=0.2-0.6),with typical characteristics of island arc magmatism.The LH granitic rocks haveεHf(t)values of-3.7 to+8.0 and yield a TCDM age of 1.51-0.78 Ga.The data suggest that the LH granitic rocks were derived from partial melting of Proterozoic crust-related mafic to intermediate rocks with significant crust-mantle interac-tions.The results,combined with regional magmatic informa-tion,indicate that the Late Permian-early Triassic magmatism in western NQTB were controlled by subduction rollback-retraction of South Kunlun Oceanic plate under the Kun-lun-Qaidam Block.展开更多
The Late Cretaceous Jiepailing granitoids,located at the central Nanling Range in South China,are closely associated with significant Sn-Li-Be-F polymetallic metallogeny.The Jiepailing granitoids mainly consist of gra...The Late Cretaceous Jiepailing granitoids,located at the central Nanling Range in South China,are closely associated with significant Sn-Li-Be-F polymetallic metallogeny.The Jiepailing granitoids mainly consist of granitic porphyry and zinnwaldite granite.The two granitoids have an A-type affinity,showing elevated Rb/Sr ratios and significant depletions in Ba,Sr and P.Integrated zircon and monazite U-Pb dating results suggest that granitic porphyry and zinnwaldite granite were emplaced at~89 Ma and~94 Ma,respectively.The low Ce^(4+)/Ce^(3+)ratios of the Jiepailing granitoids,together with significant negative Eu anomalies of the zircons,indicate that their formation occurred under conditions of reduced oxygen fugacity.Through the analysis of zircon Hf-O and whole-rock Nd isotopes,it has been determined that both stages of the Jiepailing granitoids originated in the lower-middle Mesoproterozoic crustal basement[ε_(Nd)(t)=−5.33 to−4.96,t^(C)_(DM)(Nd)=1289-1234 Ma,ε_(Hf)(t)=−4.13 to+2.22,t^(C)_(DM)(Hf)=1418-1015 Ma andδ^(18)O_(Zrc)=6.33‰-7.72‰],with the involvement of mantle-derived materials.Both granitic porphyry and zinnwaldite granite exhibit elevated concentrations of fluorine(F),with the positive correlation between F and Sn emphasizing the crucial role of high F sources in tin mineralization.Drawing upon the study of the Late Cretaceous magma systems in southern Hunan and through comparison with the mineralized granites observed in coastal regions during the Late Cretaceous,a genetic model for the mineralized granites in the Nanling region is developed.When the Paleo-Pacific Plate retreated to the coastal region,the continental crust in southern China underwent extensional thinning and asthenospheric upwelling due to gravitational collapse.Such processes resulted in the partial melting of the middle-lower crustal metamorphic sedimentary basement and the subsequent formation of F-rich granitic magmas,related to tin mineralization.展开更多
Excellent progress has been made in the last few decades in the cure rates of pediatric malignancies,with more than 80%of children with cancer who have access to contemporary treatment being cured.However,the therapie...Excellent progress has been made in the last few decades in the cure rates of pediatric malignancies,with more than 80%of children with cancer who have access to contemporary treatment being cured.However,the therapies responsible for this survival can also produce adverse physical and psychological long-term outcomes,referred to as late effects,which appear months to years after the completion of cancer treatment.Research has shown that 60%to 90%of childhood cancer survivors(CCSs)develop one or more chronic health conditions,and 20%to 80%of survivors experience severe or life-threatening complications during adulthood.Therefore,understanding the late side effects of such treatments is important to improve the health and quality of life of the growing population of CCSs.展开更多
A relatively well-preserved rodent fossil,including its incisors,cheek teeth,and postcranial skeleton,was collected from the Baiyin Obo in Siziwang Banner,Nei Mongol.A multifaceted research approach was undertaken in ...A relatively well-preserved rodent fossil,including its incisors,cheek teeth,and postcranial skeleton,was collected from the Baiyin Obo in Siziwang Banner,Nei Mongol.A multifaceted research approach was undertaken in this study to conduct a comprehensive analysis on the newly discovered specimen.Based on a morphological comparison,the new specimen was identified as Hulgana cf.H.ertnia within the Ischyromyidae family.Incisive enamel microstructure analysis revealed the typical pauciserial enamel structure of Hulgana.Bone histological analysis indicates that the specimen represents a juvenile individual,which is consistent with the ontogenetic stage indicated by dental developmental stage and wear pattern.The application of geometric morphometrics to the calcaneus and bone histology of the femur and phalanx further substantiates the taxonomic classification of Hulgana as a terrestrial and cursorial rodent,exhibiting a degree of fossorial ability.This classification is analogous to that of certain extant cricetids and ground squirrels.展开更多
This study presents LA–ICP–MS U–Pb dating and whole-rock geochemical analyses of the Late Triassic Gangshan harzburgite in the Qingyuan area,with the aim of elucidating its petrogenesis and further constraining the...This study presents LA–ICP–MS U–Pb dating and whole-rock geochemical analyses of the Late Triassic Gangshan harzburgite in the Qingyuan area,with the aim of elucidating its petrogenesis and further constraining the early Mesozoic tectonic evolution of the eastern segment of the northern margin of the North China Block(NCB).Zircons from the harzburgites exhibit typical oscillatory growth zoning or striped absorp-tion in cathodoluminescence images.U–Pb analyses of zircons yield ages ranging from 2525 Ma to 225 Ma,with two youngest ages(225±7 Ma)indicating that the harzburgites were formed during Late Triassic.Geochemical analyses of the Gangshan harzburgites show that the rocks have low concentrations of SiO_(2)(42.38%–42.85%)and Al_(2)O_(3)(3.31%–3.33%),along with high concentrations of MgO(41.32%–41.76%),Cr(4856×10^(-6)–5191×10^(-6))and Ni(1942×10^(-6)–2041×10^(-6)).They also display low REE abundances(∑REE=4.38×10^(-6)–4.69×10^(-6))and flat REE patterns with low(La/Yb)_(N) ratios(1.24–1.56)and slightly po-sitive Eu anomalies(δEu=1.13–1.16).These features suggest that the Gangshan harzburgites are cumulates of basaltic magma derived from the depleted lithospheric mantle.Combined with previous studies,these Late Triassic mafic–ultramafic rocks,together with coeval granitoids in adjacent regions,constitute a typical bimodal association,suggesting that they formed in a post-orogenic extensional environment after the final closure of the Paleo-Asian Ocean.展开更多
The origins of peloidal micrites in reefal limestone are not yet well understood.Moscovian microbial reefs with abundant peloidal micrites from Guizhou,South China,provide an opportunity to study the peloids and their...The origins of peloidal micrites in reefal limestone are not yet well understood.Moscovian microbial reefs with abundant peloidal micrites from Guizhou,South China,provide an opportunity to study the peloids and their geological significance for this time interval.Three types of peloids are differentiated:microbial,lithic,and bioclastic peloids.Microbial peloids that are well-sorted and may form in situ by microbial activities.The poorly sorted lithic peloids are derived from erosion and redeposition of the micrite matrix caused by the bottom turbulence induced by periodic storms.Bioclastic peloids are completely micritized fragments of hard parts and shells.Microbial boring and encrustations promote the processes of micritization.Microbial peloids commonly develop in zones with low or normal energy levels,and contribute to the construction and stabilization of the framework.In contrast,the occurrence of lithic peloids reflects that the reefs are destroyed by bottom turbulence during growth.It is suggested that the microbial reefs were deposited under a dynamic balance between constructional versus destructive processes.By comparative analysis,the peloids as microbial in origin play a key role in the growth and stabilization of bioconstructions during Carboniferous,which should be paid more attention in the studies of Carboniferous buildups.展开更多
High-Mg andesite/diorite(HMA)is useful for identifying subduction-related processes in orogenic belts,including the identification of ophiolites formed in suprasubduction zone(SSZ)environments.The E'rentaolegai hi...High-Mg andesite/diorite(HMA)is useful for identifying subduction-related processes in orogenic belts,including the identification of ophiolites formed in suprasubduction zone(SSZ)environments.The E'rentaolegai high-Mg diorite from the Diyanmiao ophiolite in central Inner Mongolia,North China,has been investigated revealing low-K tholeiitic-calc-alkaline characteristics and have SiO_(2)contents of 53.44-54.92 wt%,MgO contents of 8.44-9.54 wt%,and Mg~#of 54.35-57.60,with variable Fe_(2)O_(3)(7.51-8.61 wt%),Al_(2)O_(3)(11.95-15.09 wt%),and Na_(2)O(3.42-3.94 wt%)contents,low K_(2)O(0.34-0.97 wt%),TiO_(2)(0.35-0.67 wt%),and P2O5(0.12-0.15 wt%)contents,and high Ni(43-193 ppm)and Cr(189-556 ppm)contents.Samples collected have low total rare earth element(REE)contents(30.58-77.80 ppm),with flat or slightly right-dipping REE patterns(La_(N)/Yb_(N)=2.19-3.11)and a lack of pronounced Eu anomalies.The samples are also enriched in large-ion lithophile elements(LILEs,e.g.,K,Rb,Ba,U,and Sr)and depleted in high field strength elements(e.g.,Ta,Nb,Ti,and P).The E'rentaolegai high-Mg diorite has characteristics typical of HMA,and are similar to those of sanukites from the Setouchi Arc in SW Japan.They also display high positiveε_(Nd)(t)values(+6.32 to+7.80),comparable to the values of their host rocks.Petrogenetic analyses suggest that the E'rentaolegai HMA was probably formed by the interaction of partial melts and aqueous fluids from subducted sediments with mantle peridotite.Zircon U-Pb dating reveals that the high-Mg diorite crystallized at 313.6±2.4 Ma,i.e.,late Carboniferous.Combining our data with the temporal and spatial distribution of the Diyanmiao SSZ-type ophiolite,we propose that the eastern Paleo-Asian Ocean had not closed by the late Carboniferous,but intra-oceanic subduction was ongoing.A new model of the initiation of subduction in the eastern PAO during the late Paleozoic.展开更多
BACKGROUND In the treatment of rectal cancer,a temporary loop ileostomy(TLI)is created after low anterior resection to protect bowel function in the postoperative period.Dehydration and kidney failure are significant ...BACKGROUND In the treatment of rectal cancer,a temporary loop ileostomy(TLI)is created after low anterior resection to protect bowel function in the postoperative period.Dehydration and kidney failure are significant potential complications in loop ileostomies.Compared to late closure(3-6 months),early closure(10-14 days)of the TLI may facilitate faster patient recovery and shorter hospital stays.AIM To compare early and late closure of TLIs and demonstrate that early stoma closure can be performed without increasing morbidity.METHODS This study included patients who underwent TLI for rectal cancer,with data collected prospectively between June 2016 and October 2024 and analyzed retrospectively.Patients whose stomas were closed in the late period(3-6 months)between June 2016 and October 2022(group A)were compared with those who underwent early closure(10-14 days)between October 2022 and 2024(group B),with the primary outcome being complication rate and the secondary outcome being quality of life.RESULTS A total of 270 TLIs were created(70.9%).Of these,120(44.4%)were closed in the late period(group A),and 150(55.6%)were closed in the early period(group B).There was no statistically significant difference between group A and group B in terms of demographic and clinicopathological characteristics(P>0.05).Perioperative(anesthesia management,operative time,blood loss,surgical technique)and postoperative findings(anastomotic leak,infection)were similar between the two groups and were not statistically significant(P>0.05).There were no statistically significant differences in complication rates as the primary outcome between the two groups.Quality of life as a secondary outcome was significantly higher in the early closure group(P<0.05).CONCLUSION No statistically significant difference was found between early and late loop ileostomy closure in terms of perioperative and postoperative morbidity.Early closure accelerated patients’psychological and social recovery.展开更多
The late Carboniferous to early Permian period is renowned for extensive coal formation and frequent paleowildfires.Nonetheless,the nature and distribution of these wildfires varied significantly over time.In an effor...The late Carboniferous to early Permian period is renowned for extensive coal formation and frequent paleowildfires.Nonetheless,the nature and distribution of these wildfires varied significantly over time.In an effort to elucidate the patterns of paleowildfires during the late Paleozoic Ice Age and to probe into the controlling mechanisms of paleowildfires under icehouse conditions,a comprehensive analysis was performed on coal samples from the Taiyuan and Shanxi formations within the Dacheng coalfield of Hebei Province,North China.The dataset was augmented with global inertinite data from the late Carboniferous to early Permian periods and was compared to paleowildfire patterns from the Pliocene to Holocene epochs.The results show that paleowildfires in the Dacheng coalfield of North China transitioned from moderate-scale,low-intensity surface fires to large-scale,relatively high-intensity ground fires.Globally,the distribution of paleowildfires shifted from Euramerica to Gondwana,Cathaysia,and Angara from 300 Ma to 290 Ma,accompanied by a corresponding increase in inertinite content.This spatial and temporal variation in wildfire activity appears to have been strongly influenced by paleoclimate and atmospheric conditions.At 300 Ma,cooler and wetter paleoclimate,coupled with relatively low atmospheric pO_(2) levels,likely contributed to a reduced incidence of paleowildfires.In contrast,at 290 Ma,warmer paleoclimate,higher atmospheric pO_(2) levels,and the flourishing mires in Gondwana,Cathaysia,and Angara were conducive to more intense paleowildfires.This pattern is further supported by the comparison to more recent icehouse periods.Similar to the late Carboniferous–early Permian period,wildfire activity increased from the Pliocene to the Holocene,highlighting the critical role of climatic conditions in driving wildfire proliferation under icehouse conditions.However,the Pleistocene to Holocene wildfires were less intense than those of the late Carboniferous–early Permian,suggesting that atmospheric oxygen concentrations played a key role in modulating the evolution of the fire systems over geological timescales.These findings underscore the complex interplay between climate,atmospheric composition,and vegetation in shaping wildfire dynamics across Earth’s history.展开更多
High-resolution,continuous Late Holocene lacustrine records are scarce in the Qaidam Basin,but is of especially important for our understanding the future climate variability in the western China.Here,we use grain siz...High-resolution,continuous Late Holocene lacustrine records are scarce in the Qaidam Basin,but is of especially important for our understanding the future climate variability in the western China.Here,we use grain size,element content and XRD-identified data from the Lake Hurleg in the eastern Qaidam Basin to present the Late Holocene climate variability,which have been temporally constrained using 210Pb-,137Cs-and AMS 14C dating.Our records demonstrate that decreased precipitation climate occurred at~800–1000 yr and~1300–1800 yr intervals,and increased precipitation occurred at~354–800 yr,~1000–1300 yr and~1800 yr to the present.The results show that the Qaidam Basin has undergone a process of warming and humidification since the Industrial Revolution,which is consistent with the meteorological records.The climate in the northeastern Qaidam Basin is dominated by the Asian Monsoon.展开更多
Late embryogenesis abundant (LEA) proteins generally accumulate in seeds during the later stages of maturation.Here we studied the LEA genes in two wild peanut species (Arachis duranensis and Arachis ipaensis) in an e...Late embryogenesis abundant (LEA) proteins generally accumulate in seeds during the later stages of maturation.Here we studied the LEA genes in two wild peanut species (Arachis duranensis and Arachis ipaensis) in an effort to create a genetic resource for peanut crop improvement.we identified 65 AdLEA and 69 AiLEA genes representing all 8 LEA subfamilies,which were unevenly distributed across 10 peanut chromosomes.The majority of LEA proteins were found to be highly hydrophilic.MEME analysis indicated that LEA gene motifs were conserved within groups,but not between groups.The LEA genes contained a diverse array of stress-and phytohormoneresponsive cis-acting elements,with the AdLEA2-20 and AiLEA2-20 genes containing the greatest number of elements.Both AdLEA2-20 and AiLEA2-20 were upregulated in response to cold temperatures,drought,salinity,and abscisic acid exposure,although the dynamics were tissue-dependent.This study lays the foundation for future studies on the LEA gene family and abiotic stress in peanut,and our results will be invaluable for the genetic improvement of peanut by characterizing the genetic resources of wild peanut species.展开更多
Cenozoic trachytes are characteristic of some active volcanic fields in China.In particular,the origin and mechanisms of the evolution of trachytes from the Tianchi(Changbaishan)volcano(TV,China/North Korea)are poorly...Cenozoic trachytes are characteristic of some active volcanic fields in China.In particular,the origin and mechanisms of the evolution of trachytes from the Tianchi(Changbaishan)volcano(TV,China/North Korea)are poorly known.Here,we present new geochronological,geochemical and isotopic data on two trachytic suites outcropping on the northern and southern upper slopes of TV.Detailed zircon laser ablation-multicollector-inductively coupled plasma-mass spectrometry(LA-MC-ICP-MS)U-Pb dating,Rb-Sr isochron dating of plagioclase and hornblende,^(40)Ar/^(39)Ar chronology with mineral chemistry,whole-rock element and Sr-Nd-Pb isotope data are used to explore their origins and evolutionary mechanisms during the late Middle Pleistocene.Our data indicate that the trachytes mainly consist of sanidine,orthoclase and plagioclase,with minor albite,quartz and hornblende.They formed at 0.353-0.346 Ma(lava flow from the northern slope)and 0.383-0.311 Ma(lava flow from the southern slope),respectively.The TV trachytes are characterized by high K_(2)O/Na_(2)O and AR values,with low A/CNK and Mg~#values.They are enriched in rare earth elements(REEs;except Eu),depleted in Sr and Ba,crystallizing at 742-858℃.The TV trachytes have high(^(87)Sr/^(86)Sr)_i values(0.70776-0.71195),positiveε_(Nd)(t)values(0.61-2.93)and radiogenic^(206)Pb/^(204)Pb values(17.515-17.806).These values are similar to those of the Pleistocene and Holocene TV trachytes.Geochemical data indicate that they were formed by fractional crystallization from a basaltic melt and assimilated upper crust material.The trace element pattern of the studied trachytes is consistent with an evolution from basaltic melts representative of an enriched mantle source.The vent from which the trachytic magma was erupted probably collapsed inside the caldera during the TV'Millennium'eruption(ME)in 946 AD.The contemporaneous emission of basaltic and trachytic magma during the Middle-Late Pleistocene suggests the coexistence of fissural basaltic volcanism and central-type trachytic volcanism,the latter of which was associated with a magma chamber in the upper crust during the TV cone-construction stage.展开更多
Recent studies have highlighted the presence of lithium enrichment in coals within the Ordos Basin,which has garnered significant attention due to the potential economic value.However,most research has concentrated pr...Recent studies have highlighted the presence of lithium enrichment in coals within the Ordos Basin,which has garnered significant attention due to the potential economic value.However,most research has concentrated primarily on the coal seams of the Taiyuan and Shanxi formations,with limited reports on the Benxi Formation.To address this gap,our study focused on elucidating the geochemical characteristics and origins of the lithium enrichment in the No.8 coal of the Benxi Formation through the use of optical microscopy and inductively coupled plasma mass spectrometry(ICP-MS).The results showed that the No.8 coal was a bituminous coal,characterized by medium ash yield,low volatile matter,high total sulfur content and medium vitrinite proportion.The No.8 coal was enriched in Li(average 91.7 ppm,CC=6.55)and Zr(average 191 ppm,CC=5.30),the unusual enrichment of Li being primarily located in the middle of the coal.The minerals in the coal were predominantly clay minerals,along with minor amounts of pyrite,quartz and calcite.The occurrence mode of Li in the No.8 coal was associated with aluminosilicate minerals,presumably kaolinite.Based on geochemical characteristics,the sedimentary source of the No.8 coal was intermediate-felsic volcanic rock from the Yinshan oldland.The enrichment of Li can be attributed to the supply of terrestrial debris from the Yinshan oldland and the depositional environment.Our analysis identifies three distinct stages of lithium enrichment,emphasizing the critical role played by the terrestrial debris,as well as the acidic to partially reducing conditions,in facilitating this process.In conclusion,our study sheds light on the mechanisms underlying lithium enrichment in the No.8 coal of the Benxi Formation,highlighting the significance of geological factors in shaping the distribution and concentration of critical metals in coal.展开更多
The Late Cretaceous global transgression is one of the best documented episodes of continental submergence events.The extent of transgression of the Neotethys Ocean into the African continent is generally thought to b...The Late Cretaceous global transgression is one of the best documented episodes of continental submergence events.The extent of transgression of the Neotethys Ocean into the African continent is generally thought to be limited to north Africa.Here,we describe transgression traces in the Muglad Basin in central Africa that indicate a greater spatial extend of the Neotethys during the late Cretaceous.A series of molecular markers detected in the Upper Cretaceous Santonian-Maastrichtian sediments of the Muglad Basin are typical for marine depositional conditions and differ from those in the typical lacustrine sediments of the Lower Cretaceous Barremian-Aptian.Combining the geological-geochemical implications of these markers with the paleogeographic,paleontological and lithological records,we propose that the Muglad Basin received intermittent marine inundations during the Santonian-Maastrichtian stages(86.3-66.0 Ma)and these special molecular markers are therefore the products of seawater incursion.Consequently,this study proposes that the transgression extent of the Neotethys Ocean into the African continent southern extended to the central Africa during the Late Cretaceous.展开更多
基金supported by the National Natural Science Foundation of China(42172010,42372071,41102037)。
文摘The Longshan orogenic belt is located in the southwestern margin of Ordos Basin at the junction zone between the Western Qinling and Northern Qilian orogenic belt.Voluminous Early Paleozoic magmatism in this area is of key significance for determining the Early Paleozoic tectonic evolution and deep crust-mantle structure.Previous studies mainly focused on the Paleozoic granites;the coeval mafic rocks in this area are still poorly understood.A set of Late Silurian intraplate tholeiitic basalts has been discovered in Longshan area,providing key evidence for the mantle source and deep geodynamic background in this area.The Late Silurian Angou basalt has similar geochemical features as intraplate tholeiitic basalt,with high Na_(2)O/K_(2)O ratios(5.22-8.25),enriched in large ion lithophile elements and LREE.In combination with their relatively evolved Sr-Nd isotopic composition[^(87)Sr/^(86)Sr(i)=0.7128-0.7140;ε_(Nd)(t)=-5.55 to-3.40],it is suggested that it originated from decompression melting of metasomatized enriched mantle in extensional setting.These results indicate that the mantle source in the junction zone of the West Qinling-North Qilian orogenic belt evolved from depleted to enriched with the continuation of Proto-Tethys subduction from the Cambrian to the Silurian.These results are of great significance to understanding the genesis of contemporaneous granite and the crust-mantle interaction in the junction zone between the Western Qinling and Northern Qilian orogenic belt.
基金supported by the Science and Technology Research Program of Chongqing Municipal Education Commission(Grant No.KJQN202404310,KJQN202304302)National Natural Science Foundation of China(41972118).
文摘The Yarlung Zangbo Suture Zone(YZSZ)on the southern margin of the Lhasa block and the Tangjia-Sumdo ultrahigh-pressure metamorphic belt(TSMB)within the block represent natural laboratories for the study of plate tectonics and oceanic slab subduction.It is generally believed that these two zones represent the remnants of the ancient oceanic crust and upper mantle of the Yarlung Zangbo Neo-Tethys(YZNT)and the Tangjia-Sumdo Paleo-Tethys(TSPT).However,the evolutionary patterns and spatiotemporal relationships of the TSPT and the YZNT have been debated.
基金supported by the National Natural Science Foundation of China(No.42372256)the Basic Science Center for Tibetan Plateau Earth System(No.41988101)the Second Tibetan Plateau Scientific Expedition and Research Program(No.2019QZKK0708)。
文摘The Zongwulong Shan-Qinghai Nanshan tectonic belt of the northern Xizang Plateau experienced a protracted tectonica history,including the openings and closures of the Proto-and Paleo-Tethyan Oceans.Although the tectonic belt has been extensively studied,details regarding the tectonic processes involved in its development remain controversial.To better constrain the tectonic processes of this tectonic belt,we conducted detailed field geological mapping,zircon U-Pb geochronology,and whole-rock geochemical and Sr-Nd isotopic analyses.Our results show that intrusive rocks in the tectonic belt crystallized in ca.292-233 Ma,perhaps in an arc/subduction setting.Geochemical and Sr-Nd isotopic data suggest that Early Permian-Late Triassic ultramaficintermediate intrusions were sourced from the enriched mantle,whereas intermediate-acidic rocks were sourced from mixed crust-mantle.We present the tectonic model that involves:(1)Early Devonian-Early Permian intracontinental extension occurred in the northern margin of the Qaidam continent(ca.416-292 Ma);(2)Early Permian-Late Triassic northward subduction of the Paleo-Tethyan Ocean resulted in arc magmatism(ca.292-233 Ma);and(3)subsequent Late Triassic intracontinental extension(ca.233-215 Ma).Our results suggest that the Late Paleozoic-Early Mesozoic development of the Zongwulong Shan-Qinghai Nanshan was related to the opening,subduction,and slab retreat of the Paleo-Tethyan Ocean,which has key implications for the tectonic evolution of the northern Tibetan Plateau.
基金supported by the National Natural Science Foundation of China(No.41702204)the China Geology Survey(grant number DD20189614)the Basic Science Founda-tion of the Institute of Geomechanics(grant DZLXJK202004).
文摘The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu(LH)granitic rocks in the western NQTB.LA-ICP-MS U-Pb dating of zircons from LH granitic rocks yields emplacement ages of 253±4 Ma and 264±4 Ma,indicating a two-stage emplacement process.Geochemi-cal analyses show that the LH granitic rocks have low ACNK values and are enriched in LILEs(Rb,Th,Ba)and depleted in HFSEs(Sr,Nd,and Ta).The samples are enriched in LREEs(LREE/HREE=1.5-7.3).Values of(La/Yb)N range between 0.9 and 6.5,and all samples show negative Eu anomalies(δEu=0.2-0.6),with typical characteristics of island arc magmatism.The LH granitic rocks haveεHf(t)values of-3.7 to+8.0 and yield a TCDM age of 1.51-0.78 Ga.The data suggest that the LH granitic rocks were derived from partial melting of Proterozoic crust-related mafic to intermediate rocks with significant crust-mantle interac-tions.The results,combined with regional magmatic informa-tion,indicate that the Late Permian-early Triassic magmatism in western NQTB were controlled by subduction rollback-retraction of South Kunlun Oceanic plate under the Kun-lun-Qaidam Block.
基金financially supported by the National Natural Science Foundation of China(Grant No.42303073).
文摘The Late Cretaceous Jiepailing granitoids,located at the central Nanling Range in South China,are closely associated with significant Sn-Li-Be-F polymetallic metallogeny.The Jiepailing granitoids mainly consist of granitic porphyry and zinnwaldite granite.The two granitoids have an A-type affinity,showing elevated Rb/Sr ratios and significant depletions in Ba,Sr and P.Integrated zircon and monazite U-Pb dating results suggest that granitic porphyry and zinnwaldite granite were emplaced at~89 Ma and~94 Ma,respectively.The low Ce^(4+)/Ce^(3+)ratios of the Jiepailing granitoids,together with significant negative Eu anomalies of the zircons,indicate that their formation occurred under conditions of reduced oxygen fugacity.Through the analysis of zircon Hf-O and whole-rock Nd isotopes,it has been determined that both stages of the Jiepailing granitoids originated in the lower-middle Mesoproterozoic crustal basement[ε_(Nd)(t)=−5.33 to−4.96,t^(C)_(DM)(Nd)=1289-1234 Ma,ε_(Hf)(t)=−4.13 to+2.22,t^(C)_(DM)(Hf)=1418-1015 Ma andδ^(18)O_(Zrc)=6.33‰-7.72‰],with the involvement of mantle-derived materials.Both granitic porphyry and zinnwaldite granite exhibit elevated concentrations of fluorine(F),with the positive correlation between F and Sn emphasizing the crucial role of high F sources in tin mineralization.Drawing upon the study of the Late Cretaceous magma systems in southern Hunan and through comparison with the mineralized granites observed in coastal regions during the Late Cretaceous,a genetic model for the mineralized granites in the Nanling region is developed.When the Paleo-Pacific Plate retreated to the coastal region,the continental crust in southern China underwent extensional thinning and asthenospheric upwelling due to gravitational collapse.Such processes resulted in the partial melting of the middle-lower crustal metamorphic sedimentary basement and the subsequent formation of F-rich granitic magmas,related to tin mineralization.
文摘Excellent progress has been made in the last few decades in the cure rates of pediatric malignancies,with more than 80%of children with cancer who have access to contemporary treatment being cured.However,the therapies responsible for this survival can also produce adverse physical and psychological long-term outcomes,referred to as late effects,which appear months to years after the completion of cancer treatment.Research has shown that 60%to 90%of childhood cancer survivors(CCSs)develop one or more chronic health conditions,and 20%to 80%of survivors experience severe or life-threatening complications during adulthood.Therefore,understanding the late side effects of such treatments is important to improve the health and quality of life of the growing population of CCSs.
文摘A relatively well-preserved rodent fossil,including its incisors,cheek teeth,and postcranial skeleton,was collected from the Baiyin Obo in Siziwang Banner,Nei Mongol.A multifaceted research approach was undertaken in this study to conduct a comprehensive analysis on the newly discovered specimen.Based on a morphological comparison,the new specimen was identified as Hulgana cf.H.ertnia within the Ischyromyidae family.Incisive enamel microstructure analysis revealed the typical pauciserial enamel structure of Hulgana.Bone histological analysis indicates that the specimen represents a juvenile individual,which is consistent with the ontogenetic stage indicated by dental developmental stage and wear pattern.The application of geometric morphometrics to the calcaneus and bone histology of the femur and phalanx further substantiates the taxonomic classification of Hulgana as a terrestrial and cursorial rodent,exhibiting a degree of fossorial ability.This classification is analogous to that of certain extant cricetids and ground squirrels.
基金Supported by projects of the National Natural Science Foundation of China(Nos.42372063,41722204).
文摘This study presents LA–ICP–MS U–Pb dating and whole-rock geochemical analyses of the Late Triassic Gangshan harzburgite in the Qingyuan area,with the aim of elucidating its petrogenesis and further constraining the early Mesozoic tectonic evolution of the eastern segment of the northern margin of the North China Block(NCB).Zircons from the harzburgites exhibit typical oscillatory growth zoning or striped absorp-tion in cathodoluminescence images.U–Pb analyses of zircons yield ages ranging from 2525 Ma to 225 Ma,with two youngest ages(225±7 Ma)indicating that the harzburgites were formed during Late Triassic.Geochemical analyses of the Gangshan harzburgites show that the rocks have low concentrations of SiO_(2)(42.38%–42.85%)and Al_(2)O_(3)(3.31%–3.33%),along with high concentrations of MgO(41.32%–41.76%),Cr(4856×10^(-6)–5191×10^(-6))and Ni(1942×10^(-6)–2041×10^(-6)).They also display low REE abundances(∑REE=4.38×10^(-6)–4.69×10^(-6))and flat REE patterns with low(La/Yb)_(N) ratios(1.24–1.56)and slightly po-sitive Eu anomalies(δEu=1.13–1.16).These features suggest that the Gangshan harzburgites are cumulates of basaltic magma derived from the depleted lithospheric mantle.Combined with previous studies,these Late Triassic mafic–ultramafic rocks,together with coeval granitoids in adjacent regions,constitute a typical bimodal association,suggesting that they formed in a post-orogenic extensional environment after the final closure of the Paleo-Asian Ocean.
基金supported by the National Natural Science Foundation of China(Grant Nos.42272008 and 41972002).
文摘The origins of peloidal micrites in reefal limestone are not yet well understood.Moscovian microbial reefs with abundant peloidal micrites from Guizhou,South China,provide an opportunity to study the peloids and their geological significance for this time interval.Three types of peloids are differentiated:microbial,lithic,and bioclastic peloids.Microbial peloids that are well-sorted and may form in situ by microbial activities.The poorly sorted lithic peloids are derived from erosion and redeposition of the micrite matrix caused by the bottom turbulence induced by periodic storms.Bioclastic peloids are completely micritized fragments of hard parts and shells.Microbial boring and encrustations promote the processes of micritization.Microbial peloids commonly develop in zones with low or normal energy levels,and contribute to the construction and stabilization of the framework.In contrast,the occurrence of lithic peloids reflects that the reefs are destroyed by bottom turbulence during growth.It is suggested that the microbial reefs were deposited under a dynamic balance between constructional versus destructive processes.By comparative analysis,the peloids as microbial in origin play a key role in the growth and stabilization of bioconstructions during Carboniferous,which should be paid more attention in the studies of Carboniferous buildups.
基金supported by the Ministry of Science and Technology of the People’s Republic of China(Grant No.2022FY101704)the National Natural Science Foundation of China(Grant No.41972061)+1 种基金Science and Technology Innovation Team of Hebei GEO University(30801071)the China Geological Survey(Grant Nos.1212011120701 and 1212011120711)。
文摘High-Mg andesite/diorite(HMA)is useful for identifying subduction-related processes in orogenic belts,including the identification of ophiolites formed in suprasubduction zone(SSZ)environments.The E'rentaolegai high-Mg diorite from the Diyanmiao ophiolite in central Inner Mongolia,North China,has been investigated revealing low-K tholeiitic-calc-alkaline characteristics and have SiO_(2)contents of 53.44-54.92 wt%,MgO contents of 8.44-9.54 wt%,and Mg~#of 54.35-57.60,with variable Fe_(2)O_(3)(7.51-8.61 wt%),Al_(2)O_(3)(11.95-15.09 wt%),and Na_(2)O(3.42-3.94 wt%)contents,low K_(2)O(0.34-0.97 wt%),TiO_(2)(0.35-0.67 wt%),and P2O5(0.12-0.15 wt%)contents,and high Ni(43-193 ppm)and Cr(189-556 ppm)contents.Samples collected have low total rare earth element(REE)contents(30.58-77.80 ppm),with flat or slightly right-dipping REE patterns(La_(N)/Yb_(N)=2.19-3.11)and a lack of pronounced Eu anomalies.The samples are also enriched in large-ion lithophile elements(LILEs,e.g.,K,Rb,Ba,U,and Sr)and depleted in high field strength elements(e.g.,Ta,Nb,Ti,and P).The E'rentaolegai high-Mg diorite has characteristics typical of HMA,and are similar to those of sanukites from the Setouchi Arc in SW Japan.They also display high positiveε_(Nd)(t)values(+6.32 to+7.80),comparable to the values of their host rocks.Petrogenetic analyses suggest that the E'rentaolegai HMA was probably formed by the interaction of partial melts and aqueous fluids from subducted sediments with mantle peridotite.Zircon U-Pb dating reveals that the high-Mg diorite crystallized at 313.6±2.4 Ma,i.e.,late Carboniferous.Combining our data with the temporal and spatial distribution of the Diyanmiao SSZ-type ophiolite,we propose that the eastern Paleo-Asian Ocean had not closed by the late Carboniferous,but intra-oceanic subduction was ongoing.A new model of the initiation of subduction in the eastern PAO during the late Paleozoic.
文摘BACKGROUND In the treatment of rectal cancer,a temporary loop ileostomy(TLI)is created after low anterior resection to protect bowel function in the postoperative period.Dehydration and kidney failure are significant potential complications in loop ileostomies.Compared to late closure(3-6 months),early closure(10-14 days)of the TLI may facilitate faster patient recovery and shorter hospital stays.AIM To compare early and late closure of TLIs and demonstrate that early stoma closure can be performed without increasing morbidity.METHODS This study included patients who underwent TLI for rectal cancer,with data collected prospectively between June 2016 and October 2024 and analyzed retrospectively.Patients whose stomas were closed in the late period(3-6 months)between June 2016 and October 2022(group A)were compared with those who underwent early closure(10-14 days)between October 2022 and 2024(group B),with the primary outcome being complication rate and the secondary outcome being quality of life.RESULTS A total of 270 TLIs were created(70.9%).Of these,120(44.4%)were closed in the late period(group A),and 150(55.6%)were closed in the early period(group B).There was no statistically significant difference between group A and group B in terms of demographic and clinicopathological characteristics(P>0.05).Perioperative(anesthesia management,operative time,blood loss,surgical technique)and postoperative findings(anastomotic leak,infection)were similar between the two groups and were not statistically significant(P>0.05).There were no statistically significant differences in complication rates as the primary outcome between the two groups.Quality of life as a secondary outcome was significantly higher in the early closure group(P<0.05).CONCLUSION No statistically significant difference was found between early and late loop ileostomy closure in terms of perioperative and postoperative morbidity.Early closure accelerated patients’psychological and social recovery.
基金supported by the National Natural Science Foundation of China(Grant No.42302205 and No.42002128)the Fundamental Research Funding Project of Liaoning Education Department(Grant No.LJKMZ20220692)the Open Fund of State Key Laboratory of Coal Resources and Safe Mining(Grant No.SKLCRSM22KFA07 and No.SKLCRSM20KFA02).
文摘The late Carboniferous to early Permian period is renowned for extensive coal formation and frequent paleowildfires.Nonetheless,the nature and distribution of these wildfires varied significantly over time.In an effort to elucidate the patterns of paleowildfires during the late Paleozoic Ice Age and to probe into the controlling mechanisms of paleowildfires under icehouse conditions,a comprehensive analysis was performed on coal samples from the Taiyuan and Shanxi formations within the Dacheng coalfield of Hebei Province,North China.The dataset was augmented with global inertinite data from the late Carboniferous to early Permian periods and was compared to paleowildfire patterns from the Pliocene to Holocene epochs.The results show that paleowildfires in the Dacheng coalfield of North China transitioned from moderate-scale,low-intensity surface fires to large-scale,relatively high-intensity ground fires.Globally,the distribution of paleowildfires shifted from Euramerica to Gondwana,Cathaysia,and Angara from 300 Ma to 290 Ma,accompanied by a corresponding increase in inertinite content.This spatial and temporal variation in wildfire activity appears to have been strongly influenced by paleoclimate and atmospheric conditions.At 300 Ma,cooler and wetter paleoclimate,coupled with relatively low atmospheric pO_(2) levels,likely contributed to a reduced incidence of paleowildfires.In contrast,at 290 Ma,warmer paleoclimate,higher atmospheric pO_(2) levels,and the flourishing mires in Gondwana,Cathaysia,and Angara were conducive to more intense paleowildfires.This pattern is further supported by the comparison to more recent icehouse periods.Similar to the late Carboniferous–early Permian period,wildfire activity increased from the Pliocene to the Holocene,highlighting the critical role of climatic conditions in driving wildfire proliferation under icehouse conditions.However,the Pleistocene to Holocene wildfires were less intense than those of the late Carboniferous–early Permian,suggesting that atmospheric oxygen concentrations played a key role in modulating the evolution of the fire systems over geological timescales.These findings underscore the complex interplay between climate,atmospheric composition,and vegetation in shaping wildfire dynamics across Earth’s history.
基金supported by the National Natural Science Foundation of China(No.41401059)Science and Technology Plan Project of Qinghai Province(2022-ZJ-732)West Light Foundation of Chinese Academy of Sciences(No.Y510091019)。
文摘High-resolution,continuous Late Holocene lacustrine records are scarce in the Qaidam Basin,but is of especially important for our understanding the future climate variability in the western China.Here,we use grain size,element content and XRD-identified data from the Lake Hurleg in the eastern Qaidam Basin to present the Late Holocene climate variability,which have been temporally constrained using 210Pb-,137Cs-and AMS 14C dating.Our records demonstrate that decreased precipitation climate occurred at~800–1000 yr and~1300–1800 yr intervals,and increased precipitation occurred at~354–800 yr,~1000–1300 yr and~1800 yr to the present.The results show that the Qaidam Basin has undergone a process of warming and humidification since the Industrial Revolution,which is consistent with the meteorological records.The climate in the northeastern Qaidam Basin is dominated by the Asian Monsoon.
基金supported by the Undergraduate Training Program for Innovation and Entrepreneurship (S202110580053,202410580011)the Zhaoqing University Project (190060,QN202329)Science and Technology Program of Zhaoqing (2023040308001)。
文摘Late embryogenesis abundant (LEA) proteins generally accumulate in seeds during the later stages of maturation.Here we studied the LEA genes in two wild peanut species (Arachis duranensis and Arachis ipaensis) in an effort to create a genetic resource for peanut crop improvement.we identified 65 AdLEA and 69 AiLEA genes representing all 8 LEA subfamilies,which were unevenly distributed across 10 peanut chromosomes.The majority of LEA proteins were found to be highly hydrophilic.MEME analysis indicated that LEA gene motifs were conserved within groups,but not between groups.The LEA genes contained a diverse array of stress-and phytohormoneresponsive cis-acting elements,with the AdLEA2-20 and AiLEA2-20 genes containing the greatest number of elements.Both AdLEA2-20 and AiLEA2-20 were upregulated in response to cold temperatures,drought,salinity,and abscisic acid exposure,although the dynamics were tissue-dependent.This study lays the foundation for future studies on the LEA gene family and abiotic stress in peanut,and our results will be invaluable for the genetic improvement of peanut by characterizing the genetic resources of wild peanut species.
基金financially supported by the project of the National Observation and Research Station of the Institute of Geology,China Earthquake Administration(Grant No.NORSCBS22-06)the Youth Science and Technology Development Project of the Jilin Earthquake Agency(Grant No.JZQ-202402)+1 种基金the Earthquake Science and Technology Spark Project(Grant No.XH23013B)the China Scholarship Council(Grant No.202104190014)。
文摘Cenozoic trachytes are characteristic of some active volcanic fields in China.In particular,the origin and mechanisms of the evolution of trachytes from the Tianchi(Changbaishan)volcano(TV,China/North Korea)are poorly known.Here,we present new geochronological,geochemical and isotopic data on two trachytic suites outcropping on the northern and southern upper slopes of TV.Detailed zircon laser ablation-multicollector-inductively coupled plasma-mass spectrometry(LA-MC-ICP-MS)U-Pb dating,Rb-Sr isochron dating of plagioclase and hornblende,^(40)Ar/^(39)Ar chronology with mineral chemistry,whole-rock element and Sr-Nd-Pb isotope data are used to explore their origins and evolutionary mechanisms during the late Middle Pleistocene.Our data indicate that the trachytes mainly consist of sanidine,orthoclase and plagioclase,with minor albite,quartz and hornblende.They formed at 0.353-0.346 Ma(lava flow from the northern slope)and 0.383-0.311 Ma(lava flow from the southern slope),respectively.The TV trachytes are characterized by high K_(2)O/Na_(2)O and AR values,with low A/CNK and Mg~#values.They are enriched in rare earth elements(REEs;except Eu),depleted in Sr and Ba,crystallizing at 742-858℃.The TV trachytes have high(^(87)Sr/^(86)Sr)_i values(0.70776-0.71195),positiveε_(Nd)(t)values(0.61-2.93)and radiogenic^(206)Pb/^(204)Pb values(17.515-17.806).These values are similar to those of the Pleistocene and Holocene TV trachytes.Geochemical data indicate that they were formed by fractional crystallization from a basaltic melt and assimilated upper crust material.The trace element pattern of the studied trachytes is consistent with an evolution from basaltic melts representative of an enriched mantle source.The vent from which the trachytic magma was erupted probably collapsed inside the caldera during the TV'Millennium'eruption(ME)in 946 AD.The contemporaneous emission of basaltic and trachytic magma during the Middle-Late Pleistocene suggests the coexistence of fissural basaltic volcanism and central-type trachytic volcanism,the latter of which was associated with a magma chamber in the upper crust during the TV cone-construction stage.
基金funded by a grant from the National Natural Science Foundation of China(Grant No.41772130)the Natural Science Foundation of Jiangsu Province(Grant No.BK20210521)+4 种基金the Fundamental Research Funds for the Central Universities(Grant No.2021QN1061)‘Energy and Environment Youth Talent Training Program’by China’s Energy Society,China’s Environmental Protection Foundation and the Beijing Energy Society(Grant No.RCJH2022081)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX25_2782)the Graduate Innovation Program of China University of Mining and Technology(No.2025WLKXJ003)the Fundamental Research Funds for the Central Universities(No.202500044)。
文摘Recent studies have highlighted the presence of lithium enrichment in coals within the Ordos Basin,which has garnered significant attention due to the potential economic value.However,most research has concentrated primarily on the coal seams of the Taiyuan and Shanxi formations,with limited reports on the Benxi Formation.To address this gap,our study focused on elucidating the geochemical characteristics and origins of the lithium enrichment in the No.8 coal of the Benxi Formation through the use of optical microscopy and inductively coupled plasma mass spectrometry(ICP-MS).The results showed that the No.8 coal was a bituminous coal,characterized by medium ash yield,low volatile matter,high total sulfur content and medium vitrinite proportion.The No.8 coal was enriched in Li(average 91.7 ppm,CC=6.55)and Zr(average 191 ppm,CC=5.30),the unusual enrichment of Li being primarily located in the middle of the coal.The minerals in the coal were predominantly clay minerals,along with minor amounts of pyrite,quartz and calcite.The occurrence mode of Li in the No.8 coal was associated with aluminosilicate minerals,presumably kaolinite.Based on geochemical characteristics,the sedimentary source of the No.8 coal was intermediate-felsic volcanic rock from the Yinshan oldland.The enrichment of Li can be attributed to the supply of terrestrial debris from the Yinshan oldland and the depositional environment.Our analysis identifies three distinct stages of lithium enrichment,emphasizing the critical role played by the terrestrial debris,as well as the acidic to partially reducing conditions,in facilitating this process.In conclusion,our study sheds light on the mechanisms underlying lithium enrichment in the No.8 coal of the Benxi Formation,highlighting the significance of geological factors in shaping the distribution and concentration of critical metals in coal.
基金supported by the National Natural Science Foundation of China(No.42202134)Science Foundation of China University of Petroleum,Beijing(No.2462023YJRC010)the postdoctoral fellowship by the Central Research and Development Fund of the University of Bremen.The authors would like to thank the editor and the two anonymous reviewers for their constructive comments and suggestions which significantly improved the quality of the manuscript.
文摘The Late Cretaceous global transgression is one of the best documented episodes of continental submergence events.The extent of transgression of the Neotethys Ocean into the African continent is generally thought to be limited to north Africa.Here,we describe transgression traces in the Muglad Basin in central Africa that indicate a greater spatial extend of the Neotethys during the late Cretaceous.A series of molecular markers detected in the Upper Cretaceous Santonian-Maastrichtian sediments of the Muglad Basin are typical for marine depositional conditions and differ from those in the typical lacustrine sediments of the Lower Cretaceous Barremian-Aptian.Combining the geological-geochemical implications of these markers with the paleogeographic,paleontological and lithological records,we propose that the Muglad Basin received intermittent marine inundations during the Santonian-Maastrichtian stages(86.3-66.0 Ma)and these special molecular markers are therefore the products of seawater incursion.Consequently,this study proposes that the transgression extent of the Neotethys Ocean into the African continent southern extended to the central Africa during the Late Cretaceous.
