Alkaline lacustrine shale is highly heterogeneous,and the complex relationship between the organicinorganic porosity network and hydrocarbon occurrence restricts the effectiveness of shale oil exploration and developm...Alkaline lacustrine shale is highly heterogeneous,and the complex relationship between the organicinorganic porosity network and hydrocarbon occurrence restricts the effectiveness of shale oil exploration and development.Herein,we investigated the Fengcheng Formation(P_(1)f)in Mahu Sag.This study integrated geochemistry,Soxhlet extraction,scanning electron microscopy,gas adsorption,and nuclear magnetic resonance T_(1)-T_(2)spectroscopy to elucidate the microscopic oil occurrence mechanisms in shales.Results indicate the presence of felsic shale,dolomitic shale,lime shale,and mixed shale within the P_(1)f.Matrix pores and microfractures associated with inorganic minerals are the predominant pore types in P_(1)f.Adsorbed oil primarily resides on the surfaces of organic matter and clay minerals,while free oil predominantly occupies inorganic pores and microfractures with larger pore sizes.Variations exist in the quantity and distribution of shale oil accumulation across different scales,where free oil and adsorbed oil are governed by dominant pores with diameters exceeding 10 nm and ineffective pores with diameters below 10 nm,respectively.Shale oil occurrence characteristics are influenced by organic matter,pore structure,and mineral composition.Felsic shale exhibits a high abundance of dominant pores,possesses the highest oil content,predominantly harbors free oil within these dominant pores,and demonstrates good mobility.Fluid occurrence in dolomitic shale and lime shale is intricate,with low oil content and a free oil to adsorbed oil ratio of 1:1.Mixed shale exhibits elevated clay mineral content and a scarcity of dominant pores.Moreover,ineffective pores contain increased bound water,resulting in medium oil content and limited mobility predominantly due to adsorption.Presently,shale oil mainly occurs in the dominant pores with a diameter larger than 10 nm in a free state.During the exploration and development of alkaline lacustrine shale oil resources,emphasis should be placed on identifying sweet spots within the felsic shale characterized by dominant pores.展开更多
In addition to the organic matter type,abundance,thermal maturity,and shale reservoir space,the preservation conditions of source rocks play a key factor in affecting the quantity and quality of retained hydrocarbons ...In addition to the organic matter type,abundance,thermal maturity,and shale reservoir space,the preservation conditions of source rocks play a key factor in affecting the quantity and quality of retained hydrocarbons in source rocks of lacustrine shale,yet this aspect has received little attention.This paper,based on the case analysis,explores how preservation conditions influence the enrichment of mobile hydrocarbons in shale oil.Research showns that good preservation conditions play three key roles.(1)Ensure the retention of sufficient light hydrocarbons(C_(1)–C_(13)),medium hydrocarbons(C_(14)–C_(25))and small molecular aromatics(including 1–2 benzene rings)in the formation,which enhances the fluidity and flow of shale oil;(2)Maintain a high energy field(abnormally high pressure),thus facilitating the maximum outflow of shale oil;(3)Ensure that the retained hydrocarbons have the miscible flow condition of multi-component hydrocarbons(light hydrocarbons,medium hydrocarbons,heavy hydrocarbons,and heteroatomic compounds),so that the heavy hydrocarbons(C_(25+))and heavy components(non-hydrocarbons and asphaltenes)have improved fluidity and maximum flow capacity.In conclusion,in addition to the advantages of organic matter type,abundance,thermal maturity,and reservoir space,good preservation conditions of shale layers are essential for the formation of economically viable shale oil reservoirs,which should be incorporated into the evaluation criteria of shale oil-rich areas/segments and considered a necessary factor when selecting favorable exploration targets.展开更多
Lacustrine rift basins in China are characterized by pronounced structural segmentation,strong sedimentary heterogeneity,extensive fault-fracture development,and significant variability in thermal maturity and mobilit...Lacustrine rift basins in China are characterized by pronounced structural segmentation,strong sedimentary heterogeneity,extensive fault-fracture development,and significant variability in thermal maturity and mobility of shale oil.This study reviews the current status of exploration and development of shale oil in such basins and examines theoretical frameworks such as“binary enrichment”and source-reservoir configuration,with a focus on five key subjects:(1)sedimentation-diagenesis coupling mechanisms of fine-grained shale reservoir formation;(2)dynamic diagenetic evolution and hydrocarbon occurrence mechanisms of organic-rich shale;(3)dominant controls and evaluation methods for shale oil enrichment;(4)fracturing mechanisms of organic-rich shale and simulation of artificial fracture networks;and(5)flow mechanisms and effective development strategies for shale oil.Integrated analysis suggests that two major scientific challenges must be addressed:the coupled evolution of fine-grained sedimentation,differential diagenesis,and hydrocarbon generation under tectonic influence and its control on shale oil occurrence and enrichment;and multi-scale,multiphase flow mechanisms and three-dimensional development strategies for lacustrine shale oil in complex fault blocks.In response to current exploration and development bottlenecks,future research will be conducted primarily to:(1)deeply understand organic-inorganic interactions and reservoir formation mechanisms in organic-rich shales,and clarify the influence of high-frequency sequence evolution and diagenetic fluids on reservoir space;(2)elucidate the dynamic processes of hydrocarbon generation,expulsion,and retention across different lithofacies,and quantify their relationship with thermal maturity,including the conditions for the formation of self-sealing systems;(3)develop a geologically adaptive,data-and intelligence-driven shale oil classification and grading evaluation system of shale oil;(4)reveal artificial fracture propagation pattern and optimize physical field coupled fracturing technologies for complex lithofacies assemblages;and(5)overcome challenges in multi-scale geological modeling and multiphase flow characterization,and establish advanced numerical simulation methodologies.展开更多
The relationship between marine transgression and the distribution of lacustrine organic matter has restricted shale oil and gas exploration for decades.In this study,the research objective is to analyze the sedimenta...The relationship between marine transgression and the distribution of lacustrine organic matter has restricted shale oil and gas exploration for decades.In this study,the research objective is to analyze the sedimentary environment and evaluate its influence on organic matter in transgressive lacustrine shale.The study uses various analyses including total organic carbon(TOC),Rock-Eval pyrolysis,gas chromatography-mass spectrometry(GC-MS),trace element and isotope analysis.Finally,the study proposes an enrichment model for organic matter.The lacustrine shale of the second member of the Funing Formation(E_(1)f^(2))is divided into three sequences.The results indicate that the depositional environment of the organic matter during this period was an arid and humid,reduced,closed,rift lake basin.In the first sequence,high salinity resulted from increased evaporation,leading to low primary biological productivity.At this time,the lake basin belonged to a salinized closed lake basin.Intermittent transgressions began in the second sequence,with the deep lake area still being dominated by a reducing environment.The third sequence saw the environment evolve into a closed lake basin characterized by a warm and humid freshwater environment with high primary productivity.Marine transgressions introduce a substantial amount of marine plankton,nutrient elements,as well as more CO_(2) and CO_(3)^(2−)into the lake,leading to increased primary productivity.The sedimentary model for transgressive lacustrine source rocks proposed here serves as an example for similar transgressive lake basins.展开更多
China's lacustrine shale oil reserves are abundant,making it a key area for future exploration and development.Most lacustrine shales feature a mix of mineral compositions and interlayer sedimentary structures.Hig...China's lacustrine shale oil reserves are abundant,making it a key area for future exploration and development.Most lacustrine shales feature a mix of mineral compositions and interlayer sedimentary structures.High-quality reservoirs exhibit significant heterogeneity,which influences the stress distribution during fracturing,leading to complex fracture network patterns.This complexity presents challenges for the comprehensive well logging evaluation of the geological-engineering"double sweet spots"in shale oil,severely restricting efficient development.This study focuses on the impact of shale sedimentary layering on the radial slowness of dipole shear waves.It employs rock physics experiments combined with advanced well logging techniques to explore the relationship between reservoir anisotropy caused by sedimentary layering and reservoir quality,thereby establishing a logging evaluation method for vertical identification of"sweet spots"in lacustrine shale oil.The shales in the Fengcheng Formation of the Mahu Sag into three types according to sedimentary structure scale:laminated,interlayer,and massive.Each type has different mineral compositions,affecting reservoir quality and fracturing potential.Laminated shales develop more fractures under stress along the beddings,showing moderate anisotropy,with reservoir capacity dependent on intercrystalline porosity within carbonate layers.Interlayer shales easily form complex fracture networks,exhibiting significant anisotropy,and their reservoir capacity depends on the porosity within sandy bands.Massive mudstones have the fewest fractures under stress,appearing isotropic with reservoir capacity dependent on matrix pore size.The intensity of reservoir anisotropy correlates positively with storage capacity and the propensity to form irregular and complex fracture networks during hydraulic fracturing.In sections without natural fractures,a larger difference between fast and slow shear waves corresponds to a radial profile shift towards warm tones,indicating stronger anisotropy and better reservoir quality,thus forming complex fracture networks during fracturing.Conversely,a smaller difference leads to a profile energy shift towards cooler tones,indicating stronger isotropy and poorer reservoir quality,hindering the formation of complex fracture networks during hydraulic fracturing.In sections with natural fractures,the difference between fast and slow shear waves exhibits erratic behavior,showing a cross-pattern in radial profiles,indicating strong anisotropy.The presence of natural fractures can synergize with induced fracture networks to form more complex systems,significantly enhancing reservoir productivity.展开更多
Pore structure directly affects the occurrence and migration of shale hydrocarbon,and the lack of research on the mechanism of the pore structure is an important reason for the hindrance of shale hydrocarbon explorati...Pore structure directly affects the occurrence and migration of shale hydrocarbon,and the lack of research on the mechanism of the pore structure is an important reason for the hindrance of shale hydrocarbon exploration.By analysing the geochemistry and reservoir characteristics of Jurassic lacustrine shales in Sichuan Basin,this study recovers their paleoenvironments and further discusses paleoenvironmental constraints on pore structure.The results show that the Lower Jurassic lacustrine shales in the Sichuan Basin are in a warm and humid semi-anoxic to anoxic lake environment with high productivity,a strong stagnant environment,and a rapid sedimentation rate,with water depths ranging from about 11.54-55.22 m,and a mixture of type Ⅱ/Ⅲ kerogen is developed.In terms of reservoir characteristics,they are dominated by open-slit pores,and the pores are relatively complex.The percentage of mesopores is the highest,while the percentage of macropores is the lowest.Further analysis shows that paleoclimate controls the overall pore complexity and surface relaxation of shales by influencing the weathering rate of mother rocks.Paleoredox conditions control the proportion and complexity of shale pores by influencing TOC content.The research results will provide theoretical basis for improving the exploration efficiency of lacustrine shale resources and expanding exploration target areas.展开更多
Lacustrine shale oil reservoirs of the Upper Triassic Chang 7 Member in the Ordos Basin have demonstrated significant potential for hydrocarbon resources.Natural fractures play a crucial role in hydrocarbon enrichment...Lacustrine shale oil reservoirs of the Upper Triassic Chang 7 Member in the Ordos Basin have demonstrated significant potential for hydrocarbon resources.Natural fractures play a crucial role in hydrocarbon enrichment and production.Outcrops,cores,borehole image logs,thin sections,and FE-SEM images were used to investigate the types and characteristics of natural fractures in the Chang 7 Member.The factors controlling fracture development and the mechanisms of bedding-parallel fracture formation were revealed by integrating TOC analysis,XRD analysis,and rock pyrolysis.Results show that natural fractures in the study area include high-angle tectonic fractures and nearly horizontal bedding-parallel fractures.Brittle minerals and bed thickness control the occurrence and attributes of tectonic fractures.High TOC content and thermal maturity positively affect the development of bedding-parallel fractures,formed through the conversion of organic matter to hydrocarbons or the smectite-to-illite transformation.Additionally,the dominant orientations of tectonic fractures intersect the present-day maximum horizontal principal stress at a small angle,resulting in large apertures and good effectiveness.Bedding-parallel fractures contribute to enhance porosity and provide favorable pathways for lateral hydrocarbon migration.Collectively,this study could provide valuable insights for finding promising exploration areas in lacustrine shale oil reservoirs in the Ordos Basin and worldwide.展开更多
Taking the shale oil of the first member of the Cretaceous Qingshankou Formation of Changling Sag in southern Songliao Basin as an example,this paper establishes a saturation model of lacustrine shale oil considering ...Taking the shale oil of the first member of the Cretaceous Qingshankou Formation of Changling Sag in southern Songliao Basin as an example,this paper establishes a saturation model of lacustrine shale oil considering the influence of organic matter on clay-bound water conductivity.Based on the fluid characterization results of sealed samples and two-dimensional nuclear magnetic resonance,the differential influence of organic matter on clay-bound water conductivity was quantitatively revealed,and the conductivity mechanism and rock-electrical relationships of lacustrine shale were systematically analyzed.The results show that there are two conductive networks for lacustrine shales,i.e.the matrix free water and the clay-bound water.The bound water cementation index msh was introduced to reflect the impact of organic matter on clay-bound water conductivity,and it is positively correlated with the effective porosity.When there is sufficient rigid framework support and well-developed pores,organic matter is more likely to fill or adsorb onto clay interlayers.This reduces the ion exchange capacity of the electrical double layer,leading to an increase in msh and a decrease in the conductivity of clay-bound water.The overall conductivity of shale is controlled by the clay-bound water conductivity,and the relative contributions of the mentioned two conductive networks to formation conductivity are affected by the effective porosity and msh.The larger the effective porosity and msh,the more the contribution of the matrix free water to formation conductivity.According to the experimental results,the proposed saturation model yields a significantly higher interpretation accuracy in oil saturation than the Archie model and the Total-shale model.展开更多
The deep-water systems in different types of sedimentary basins exhibit significant variability.Current knowledge of deep-water deposition is mainly derived from deep-marine turbidite systems.However,the characteristi...The deep-water systems in different types of sedimentary basins exhibit significant variability.Current knowledge of deep-water deposition is mainly derived from deep-marine turbidite systems.However,the characteristics and differences of sub-lacustrine gravity flow deposition systems have been a research focus in the fields of sedimentology and petroleum geology.This study investigates the facies archi-tecture,depositional processes,and sediment distribution patterns of a sub-lacustrine debrite system in the Eocene Dongying Rift of the Bohai Bay Basin,China,through the analysis of integrated core data,3-D seismic data,and well-log data.Nine facies have been identified within the debrite system,representing various depositional processes such as sandy debris flow,muddy debris flow,turbidity currents,sandy slide,sandy slide/slump,and mud flow.Our research indicates that the sub-lacustrine system is primarily influenced by debris flow rather than turbidity currents,as supported by facies quantification,inter-pretation,and flow rheology analysis.Additionally,we have identified five basic facies building blocks in debrite systems,including slide masses,slump masses,debrite channels,debrite lobes,and turbidite sheets.We have also elucidated and proposed detailed sedimentary processes,flow transport,and transformation within the sub-lacustrine system through analysis of flow origins,facies sequences,and distribution characteristics.Our findings highlight the evolutionary progression from delta-front collapse to sandy slide/slump,sandy debris flow,and finally muddy debris flow.The efficient generation of turbidity currents from parental landslides on sand-prone slopes is deemed unlikely due to rift-basin morphology and transport distances.The formation of the five basic facies building blocks is closely linked to depositional processes and dominant flow types.Consequently,we present a deep-water depositional model for sub-lacustrine debrite systems,focusing on flow dynamics,sediment distribu-tion patterns,and basin morphology within deep lacustrine rifts.This model offers valuable insights into the variability of deep-water deposition in diverse basin settings and aids in predicting lithologic res-ervoirs during deep-water hydrocarbon exploration.展开更多
Based on the analysis of typical lacustrine shale oil zones in China and their geological characteristics,this study elucidates the fundamental differences between the enrichment patterns of shale oil sweet spots and ...Based on the analysis of typical lacustrine shale oil zones in China and their geological characteristics,this study elucidates the fundamental differences between the enrichment patterns of shale oil sweet spots and conventional oil and gas.The key parameters and evaluation methods for assessing the large-scale production potential of lacustrine shale oil are proposed.The results show that shale oil is a petroleum resource that exists in organic-rich shale formations,in other words,it is preserved in its source bed,following a different process of generation-accumulation-enrichment from conventional oil and gas.Thus,the concept of“reservoir”seems to be inapplicable to shale oil.In China,lacustrine shale oil is distributed widely,but the geological characteristics and sweet spots enrichment patterns of shale oil vary significantly in lacustrine basins where the water environment and the tectonic evolution and diagenetic transformation frameworks are distinct.The core of the evaluation of lacustrine shale oil is“sweet spot volume”.The key factors for evaluating the large-scale production of continental shale oil are the oil storage capacity,oil-bearing capacity and oil producing capacity.The key parameters for evaluating these capacities are total porosity,oil content,and free oil content,respectively.It is recommended to determine the total porosity of shale by combining helium porosity measurement with nuclear magnetic resonance(NMR)method,the oil content of key layers by using organic solvent extraction,NMR method and high pressure mercury intrusion methods,and the free oil content by using NMR fluid distribution secondary spectral stripping decomposition and logging.The research results contribute supplemental insights on continental shale oil deliverability in China,and provide a scientific basis for the rapid exploration and large-scale production of lacustrine shale oil.展开更多
To clarify the mechanism of differential enrichment of intrasource shale oil,taking the third of seventh member of the Triassic Yanchang Formation(Chang 7_(3)submember for short)in the Ordos Basin,NW China as an examp...To clarify the mechanism of differential enrichment of intrasource shale oil,taking the third of seventh member of the Triassic Yanchang Formation(Chang 7_(3)submember for short)in the Ordos Basin,NW China as an example,we integrated high-resolution scanning electron microscopy(SEM),optical microscopy,laser Raman spectroscopy,rock pyrolysis,and organic solvent extraction experiments to identify solid bitumen of varying origins,obtain direct evidence of intrasource micro-migration of shale oil,and establish the coupling between the shale nano/micro-fabric and the oil generation,migration and accumulation.The Chang 7_(3)shale with rich alginite in laminae has the highest hydrocarbon generation potential but a low thermal transformation ratio.Frequent alternations of micron-scale argillaceous-felsic laminae enhance the hydrocarbon expulsion efficiency,yielding consistent aromaticity between in-situ and migrated solid bitumen.Mudstone laminae rich in terrestrial organic matter(OM)and clay minerals exhibit lower hydrocarbon generation threshold but stronger hydrocarbon retention capacity,with a certain amount of light oil/bitumen preserved to differentiate the chemical structure of in-situ versus migrated bitumen.Tuffaceous and sandy laminae contain abundant felsic minerals and migrated bitumen.Tuffaceous laminae develop high-angle microfractures under shale overpressure,facilitating oil charging into rigid mineral intergranular pores of sandy laminae.Fractionation during micro-migration progressively decreases the aromatization of solid bitumen from shale,through tuffaceous and mudstone,to sandy laminae,while increasing light hydrocarbon components and enhancing OM-hosted pore development.The intrasource micro-migration and enrichment of the Chang 7_(3)shale oil result from synergistic organic-inorganic diagenesis,with crude oil component fractionation being a key mechanism for forming sweet spots in laminated shale oil reservoirs.展开更多
Based on the technological demands for significantly enhancing oil recovery and long-term CO_(2)sequestration in the lacustrine oil reservoirs of China,this study systematically reviews the progress and practices of C...Based on the technological demands for significantly enhancing oil recovery and long-term CO_(2)sequestration in the lacustrine oil reservoirs of China,this study systematically reviews the progress and practices of CO_(2)flooding and storage technologies in recent years.It addresses the key technological needs and challenges faced in scaling up the application of CO_(2)flooding and storage to mature,developed oil fields,and analyzes future development directions.During the pilot test phase(2006-2019),continuous development and application practices led to the establishment of the first-generation CO_(2)flooding and storage technology system for lacustrine reservoirs.In the industrialization phase(since 2020),significant advances and insights have been achieved in terms of confined phase behavior,storage mechanisms,reservoir engineering,sweep control,engineering process and storage monitoring,enabling the maturation of the second-generation CO_(2)flooding and storage theories and technologies to effectively support the demonstration projects of Carbon Capture,Utilization and Storage(CCUS).To overcome key technical issues such as low miscibility,difficulty in gas channeling control,high process requirements,limited application scenarios,and coordination challenges in CO_(2)flooding and storage,and to support the large-scale application of CCUS,it is necessary to strengthen research on key technologies for establishing the third-generation CO_(2)flooding and storage technological system incorporating miscibility enhancement and transformation,comprehensive regulation for sweep enhancement,whole-process engineering techniques and equipment,long-term storage monitoring safety,and synergistic optimization of flooding and storage.展开更多
To accurately investigate the evolution characteristics and generation mechanism of retained oil,the study analyzed organic-rich lacustrine shale samples from the Paleogene Kongdian Formation in Cangdong Sag,Bohai Bay...To accurately investigate the evolution characteristics and generation mechanism of retained oil,the study analyzed organic-rich lacustrine shale samples from the Paleogene Kongdian Formation in Cangdong Sag,Bohai Bay Basin.This analysis involves Rock-Eval pyrolysis,pyrolysis simulation experiments,Gas Chromatograph Mass Spectrometer(GC-MS),and reactive molecular dynamics simulations(ReaxFF).The results revealed the retained oil primarily consisted of n-alkanes with carbon numbers ranging from C14 to C36.The generation of retained oil occurred through three stages.A slow growth stage of production rate was observed before reaching the peak of oil production in Stage Ⅰ.Stage Ⅱ involved a rapid increase in oil retention,with C12-C17 and C24-C32 serving as the primary components,increasing continuously during the pyrolysis process.The generation process involved the cleavage of weak bonds,including bridging bonds(hydroxyl,oxy,peroxy,imino,amino,and nitro),ether bonds,and acid amides in the first stage(Ro=0.50%-0.75%).The carbon chains in aromatic ring structures with heteroatomic functional groups breaks in the second stage(R_(o)=0.75%-1.20%).In the third stage(R_(o)=1.20%-2.50%),the ring structures underwent ring-opening reactions to synthesize iso-short-chain olefins and radicals,while further breakdown of aliphatic chains occurred.By coupling pyrolysis simu-lation experiments and molecular simulation technology,the evolution characteristics and bond breaking mechanism of retained oil in three stages were revealed,providing a reference for the for-mation and evolution mechanism of retained oil.展开更多
To elucidate the mechanism by which supercritical CO_(2)(SCCO_(2))-water-shale interactions during CO_(2)energized fracturing influence proppant embedment in lacustrine shale,shale samples from the Bohai Bay Basin wer...To elucidate the mechanism by which supercritical CO_(2)(SCCO_(2))-water-shale interactions during CO_(2)energized fracturing influence proppant embedment in lacustrine shale,shale samples from the Bohai Bay Basin were selected for SCCO_(2)-water-shale interaction experiments.X-ray diffraction(XRD),SEM large-area high-resolution imaging,automated mineral identification and characterization system(AMICS),and nanoindentation tests were employed to examine the micro-mechanical damage mechanisms of fracture surfaces and the evolving patterns of proppant embedment characteristics.The results reveal that:Prolonged interaction time reduces the contents of dolomite,feldspar,and clay minerals,while quartz content increases,with dolomite showing the most pronounced dissolution effect.As interaction time increases,the hardness and elasticity modulus of shale follow a power-law decay pattern,with the peak degradation rate occurring at 1 d,followed by a gradual decline of degradation velocity.Increasing interaction time results in growth in both the number and depth of embedment pits on the sample surface.After more than 3 d of interaction,clustered proppant embedment is observed,accompanied by the formation of deep embedment pits on the surface.展开更多
Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organ...Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.展开更多
Reactive transport modeling(RTM)is an emerging method used to address geological issues in diagenesis research.However,the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood....Reactive transport modeling(RTM)is an emerging method used to address geological issues in diagenesis research.However,the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood.This paper presents a case study of the Eocene Qaidam Basin that combines RTM results with petrological and mineralogical evidence.The results show that the Eocene Xiaganchaigou Formation is characterized by mixed siliciclastic-carbonate-evaporite sedimentation in a semiclosed saline lacustrine environment.Periodic evaporation and salinization processes during the syngeneticpenecontemporaneous stage gave rise to the replacive genesis of dolomites and the cyclic enrichment of dolomite in the middle-upper parts of the meter-scale depositional sequences.The successive change in mineral paragenesis from terrigenous clastics to carbonates to evaporites was reconstructed using RTM simulations.Parametric uncertainty analyses further suggest that the evaporation intensity(brine salinity)and particle size of sediments(reactive surface area)were important rate-determining factors in the dolomitization,as shown by the relatively higher reaction rates under conditions of higher brine salinity and fine-grained sediments.Combining the simulation results with measured mineralogical and reservoir physical property data indicates that the preservation of original intergranular pores and the generation of porosity via replacive dolomitization were the major formation mechanisms of the distinctive lacustrine dolomite reservoirs(widespread submicron intercrystalline micropores)in the Eocene Qaidam Basin.The results confirm that RTM can be effectively used in geological studies,can provide a better general understanding of the dolomitizing fluid-rock interactions,and can shed light on the spatiotemporal evolution of mineralogy and porosity during dolomitization and the formation of lacustrine dolomite reservoirs.展开更多
The organic-rich mudstones and dolostones of the Permian Fengcheng Formation(Fm.)are typically alkaline lacustrine source rocks,which are typified by impressively abundantβ-carotane.Abundant β-carotane has been well...The organic-rich mudstones and dolostones of the Permian Fengcheng Formation(Fm.)are typically alkaline lacustrine source rocks,which are typified by impressively abundantβ-carotane.Abundant β-carotane has been well acknowledged as an effective indicator of biological sources or depositional environments.However,the specific biological sources of β-carotane and the coupling control of biological sources and environmental factors on the enrichment of β-carotane in the Fengcheng Fm.remains obscure.Based on a comprehensive investigation of the bulk,molecular geochemistry,and organic petrology of sedimentary rocks and the biochemistry of phytoplankton in modern alkaline lakes,we proposed a new understanding of the biological precursors of β-carotane and elucidated the enrichment mechanism of β-carotane in the Fengcheng Fm.The results show that the biological precursors crucially control the enrichment of β-carotane in the Fengcheng Fm.The haloalkaliphilic cyanobacteria are the primary biological sources of β-carotane,which is suggested by a good positive correlation between the 2-methylhopane index,7-+8-methyl heptadecanes/C_(max),C_(29%),and β-carotane/C_(max)in sedimentary rocks and the predominance of cyanobacteria with abundantβ-carotene in modern alkaline lakes.The enrichment of β-carotane requires the reducing condition,and the paleoredox state that affects the enrichment of β-carotane appears to have a threshold.The paleoclimate conditions do not considerably impact the enrichment of β-carotane,but they have some influence on the water's paleosalinity by affecting evaporation and precipitation.While it does not directly affect the enrichment of β-carotane in the Fengcheng Fm.,paleosalinity does have an impact on the cyanobacterial precursor supply and the preservation conditions.展开更多
Hyperpycnal deposits has gradually emerged as a current research hotspot,with a special focus on lacustrine hyperpycnal deposits.However,our understanding of the formation mechanism and distribution of high-quality re...Hyperpycnal deposits has gradually emerged as a current research hotspot,with a special focus on lacustrine hyperpycnal deposits.However,our understanding of the formation mechanism and distribution of high-quality reservoirs in hyperpycnal deposits remains insufficient.In this study,the formation mechanism and distribution of high-quality reservoirs in the second member of the Sangonghe Formation are studied through sedimentology,petrology,and geochemistry,and 10 types of lithofacies were identified in the depositional sequences of the hyperpycnal flow.These can be summarized as gravelly bed to suspended load lithofacies association(GBS),gravelly reverse to normal compound-graded(GNR),coarse-grained sandy suspended load(CSS),and fine-grained sandy suspended load(FSS)lithofacies associations.The hyperpycnal system can be divided into four individual units:restricted channel,unrestricted channel,lobe,and levee.The reservoir quality varies with lithofacies.Gravelly bed load lithofacies has coarse grain sizes,high content of rigid minerals,and soluble components,such as magmatic rock fragments.Therefore,the gravelly bed load lithofacies reservoir has developed dissolution pores and well-preserved pore throats.Its reservoir quality is good.GBS and GNR are the main lithofacies associations in the restricted channel,where type I and type II reservoirs developed.The unrestricted channel is dominated by the CSS lithofacies association,with type III reservoirs developed.The lobe is dominated by the CSS and FSS lithofacies associations,with type III and type IV reservoirs developed.High-quality reservoirs mainly develop in the restricted and unrestricted channels,whereas reservoirs in the lobe have poor quality.The levees are dominated by siltstone and gray mudstone and are generally nonreservoirs.展开更多
Due to limited data on the geochemical properties of natural gas,estimations are needed for the effective gas source rock in evaluating gas potential.However,the pronounced heterogeneity of mudstones in lacustrine suc...Due to limited data on the geochemical properties of natural gas,estimations are needed for the effective gas source rock in evaluating gas potential.However,the pronounced heterogeneity of mudstones in lacustrine successions complicates the prediction of the presence and geochemical characteristics of gas source rocks.In this paper,the Liaohe Subbasin of Northeast China is used as an example to construct a practical methodology for locating effective gas source rocks in typical lacustrine basins.Three types of gas source rocks,microbial,oil-type,and coal-type,were distinguished according to the different genetic types of their natural gas.A practical three-dimensional geological model was developed,refined,and applied to determine the spatial distribution of the mudstones in the Western Depression of the Liaohe Subbasin and to describe the geochemical characteristics(the abundance,type,and maturation levels of the organic matter).Application of the model in the subbasin indicates that the sedimentary facies have led to heterogeneity in the mudstones,particularly with respect to organic matter types.The effective gas source rock model constructed for the Western Depression shows that the upper sequence(SQ2)of the Fourth member(Mbr 4)of the Eocene Shahejie Formation(Fm)and the lower and middle sequences(SQ3 and SQ4)of the Third member(Mbr 3)form the principal gas-generating interval.The total volume of effective gas source rocks is estimated to be 586 km^(3).The effective microbial,oil-type,and coal-type gas source rocks are primarily found in the shallow western slope,the central sags,and the eastern slope of the Western Depression,respectively.This study provides a practical approach for more accurately identifying the occurrence and geochemical characteristics of effective natural gas source rocks,enabling a precise quantitative estimation of natural gas reserves.展开更多
The saline lacustrine hybrid sedimentary rocks are complex in lithology and unknown for their sedimentary mechanisms.The hybrid sedimentary rocks samples from the Neogene upper Ganchaigou Formation to lower Youshashan...The saline lacustrine hybrid sedimentary rocks are complex in lithology and unknown for their sedimentary mechanisms.The hybrid sedimentary rocks samples from the Neogene upper Ganchaigou Formation to lower Youshashan Formation(N_(1)-N_(2)^(1))in the Fengxi area Qaidam Basin,were investigated through core-log and petrology-geochemistry cross-analysis by using the core,casting thin section,scanning electron microscope,X-ray diffraction,logging,and carbon/oxygen isotopic data.The hybrid sedimentary rocks in the Fengxi area,including terrigenous clastic rock and lacustrine carbonate rock,were deposited in a shallow lake environment far from the source,or occasionally in a semi-deep lake environment,with 5 lithofacies types and 6 microfacies types recognized.Stable carbon and oxygen isotopic compositions reveal that the formation of sedimentary cycles is controlled by a climate-driven compensation-undercompensation cyclic mechanism.A sedimentary cycle model of hybrid sedimentary rocks in an arid and saline setting is proposed.According to this model,in the compensation period,the lake level rises sharply,and microfacies such as mud flat,sand-mud flat and beach are developed,with physical subsidence as the dominant sedimentary mechanism;in the undercompensation period,the lake level falls slowly,and microfacies such as lime-mud flat,lime-dolomite flat and algal mound/mat are developed,with chemical-biological process as the dominant sedimentary mechanism.In the saline lacustrine sedimentary system,lacustrine carbonate rock is mainly formed along with regression,the facies change is not interpreted by the accommodation believed traditionally,but controlled by the temporary fluctuation of lake water chemistry caused by climate change.The research results update the interpreted high-resolution sequence model and genesis of hybrid sedimentary rocks in the saline lacustrine basin and provide a valuable guidance for exploring unconventional hydrocarbons of saline lacustrine facies.展开更多
基金financially supported by the State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Efficient Development(33550000-22-ZC0613-0006)National Natural Science Foundation of China(42202133)+2 种基金CNPC Innovation Fund(2022DQ02-0106)Strategic Cooperation Technology Projects of the CNPC and CUPB(ZLZX2020-01-05)Key Laboratory of Tectonics and Petroleum Resources(China University of Geosciences),Ministry of Education,China(TPR-2023-05)。
文摘Alkaline lacustrine shale is highly heterogeneous,and the complex relationship between the organicinorganic porosity network and hydrocarbon occurrence restricts the effectiveness of shale oil exploration and development.Herein,we investigated the Fengcheng Formation(P_(1)f)in Mahu Sag.This study integrated geochemistry,Soxhlet extraction,scanning electron microscopy,gas adsorption,and nuclear magnetic resonance T_(1)-T_(2)spectroscopy to elucidate the microscopic oil occurrence mechanisms in shales.Results indicate the presence of felsic shale,dolomitic shale,lime shale,and mixed shale within the P_(1)f.Matrix pores and microfractures associated with inorganic minerals are the predominant pore types in P_(1)f.Adsorbed oil primarily resides on the surfaces of organic matter and clay minerals,while free oil predominantly occupies inorganic pores and microfractures with larger pore sizes.Variations exist in the quantity and distribution of shale oil accumulation across different scales,where free oil and adsorbed oil are governed by dominant pores with diameters exceeding 10 nm and ineffective pores with diameters below 10 nm,respectively.Shale oil occurrence characteristics are influenced by organic matter,pore structure,and mineral composition.Felsic shale exhibits a high abundance of dominant pores,possesses the highest oil content,predominantly harbors free oil within these dominant pores,and demonstrates good mobility.Fluid occurrence in dolomitic shale and lime shale is intricate,with low oil content and a free oil to adsorbed oil ratio of 1:1.Mixed shale exhibits elevated clay mineral content and a scarcity of dominant pores.Moreover,ineffective pores contain increased bound water,resulting in medium oil content and limited mobility predominantly due to adsorption.Presently,shale oil mainly occurs in the dominant pores with a diameter larger than 10 nm in a free state.During the exploration and development of alkaline lacustrine shale oil resources,emphasis should be placed on identifying sweet spots within the felsic shale characterized by dominant pores.
基金Supported by the National Natural Science Foundation of China(U22B6004)Project of PetroChina Research Institute of Petroleum Exploration and Development(2022yjcq03)Core Technology Key Project of China Petroleum Changqing Oilfield Company(KJZX2023-01).
文摘In addition to the organic matter type,abundance,thermal maturity,and shale reservoir space,the preservation conditions of source rocks play a key factor in affecting the quantity and quality of retained hydrocarbons in source rocks of lacustrine shale,yet this aspect has received little attention.This paper,based on the case analysis,explores how preservation conditions influence the enrichment of mobile hydrocarbons in shale oil.Research showns that good preservation conditions play three key roles.(1)Ensure the retention of sufficient light hydrocarbons(C_(1)–C_(13)),medium hydrocarbons(C_(14)–C_(25))and small molecular aromatics(including 1–2 benzene rings)in the formation,which enhances the fluidity and flow of shale oil;(2)Maintain a high energy field(abnormally high pressure),thus facilitating the maximum outflow of shale oil;(3)Ensure that the retained hydrocarbons have the miscible flow condition of multi-component hydrocarbons(light hydrocarbons,medium hydrocarbons,heavy hydrocarbons,and heteroatomic compounds),so that the heavy hydrocarbons(C_(25+))and heavy components(non-hydrocarbons and asphaltenes)have improved fluidity and maximum flow capacity.In conclusion,in addition to the advantages of organic matter type,abundance,thermal maturity,and reservoir space,good preservation conditions of shale layers are essential for the formation of economically viable shale oil reservoirs,which should be incorporated into the evaluation criteria of shale oil-rich areas/segments and considered a necessary factor when selecting favorable exploration targets.
基金Supported by the National Natural Science Foundation of China(U24B6002)National Science and Technology Major Project(2024ZD14001)Project of the Sinopec Science and Technology Department(P25196,P24207).
文摘Lacustrine rift basins in China are characterized by pronounced structural segmentation,strong sedimentary heterogeneity,extensive fault-fracture development,and significant variability in thermal maturity and mobility of shale oil.This study reviews the current status of exploration and development of shale oil in such basins and examines theoretical frameworks such as“binary enrichment”and source-reservoir configuration,with a focus on five key subjects:(1)sedimentation-diagenesis coupling mechanisms of fine-grained shale reservoir formation;(2)dynamic diagenetic evolution and hydrocarbon occurrence mechanisms of organic-rich shale;(3)dominant controls and evaluation methods for shale oil enrichment;(4)fracturing mechanisms of organic-rich shale and simulation of artificial fracture networks;and(5)flow mechanisms and effective development strategies for shale oil.Integrated analysis suggests that two major scientific challenges must be addressed:the coupled evolution of fine-grained sedimentation,differential diagenesis,and hydrocarbon generation under tectonic influence and its control on shale oil occurrence and enrichment;and multi-scale,multiphase flow mechanisms and three-dimensional development strategies for lacustrine shale oil in complex fault blocks.In response to current exploration and development bottlenecks,future research will be conducted primarily to:(1)deeply understand organic-inorganic interactions and reservoir formation mechanisms in organic-rich shales,and clarify the influence of high-frequency sequence evolution and diagenetic fluids on reservoir space;(2)elucidate the dynamic processes of hydrocarbon generation,expulsion,and retention across different lithofacies,and quantify their relationship with thermal maturity,including the conditions for the formation of self-sealing systems;(3)develop a geologically adaptive,data-and intelligence-driven shale oil classification and grading evaluation system of shale oil;(4)reveal artificial fracture propagation pattern and optimize physical field coupled fracturing technologies for complex lithofacies assemblages;and(5)overcome challenges in multi-scale geological modeling and multiphase flow characterization,and establish advanced numerical simulation methodologies.
基金financially supported by the National Natural Science Foundation of China(Grant No.42072150)and we thank the sponsors of these projects.
文摘The relationship between marine transgression and the distribution of lacustrine organic matter has restricted shale oil and gas exploration for decades.In this study,the research objective is to analyze the sedimentary environment and evaluate its influence on organic matter in transgressive lacustrine shale.The study uses various analyses including total organic carbon(TOC),Rock-Eval pyrolysis,gas chromatography-mass spectrometry(GC-MS),trace element and isotope analysis.Finally,the study proposes an enrichment model for organic matter.The lacustrine shale of the second member of the Funing Formation(E_(1)f^(2))is divided into three sequences.The results indicate that the depositional environment of the organic matter during this period was an arid and humid,reduced,closed,rift lake basin.In the first sequence,high salinity resulted from increased evaporation,leading to low primary biological productivity.At this time,the lake basin belonged to a salinized closed lake basin.Intermittent transgressions began in the second sequence,with the deep lake area still being dominated by a reducing environment.The third sequence saw the environment evolve into a closed lake basin characterized by a warm and humid freshwater environment with high primary productivity.Marine transgressions introduce a substantial amount of marine plankton,nutrient elements,as well as more CO_(2) and CO_(3)^(2−)into the lake,leading to increased primary productivity.The sedimentary model for transgressive lacustrine source rocks proposed here serves as an example for similar transgressive lake basins.
基金supported by supportedby the China Postdoctoral Science Foundation under Grant Nos.2024M753612 and GZC20233101Supported by the Strategic Cooperation Technology Projects of CNPC and CUPB(ZLZX2020-05)the Science Foundation of China University of Petroleum,Beijing(No.2462023XKBH012).
文摘China's lacustrine shale oil reserves are abundant,making it a key area for future exploration and development.Most lacustrine shales feature a mix of mineral compositions and interlayer sedimentary structures.High-quality reservoirs exhibit significant heterogeneity,which influences the stress distribution during fracturing,leading to complex fracture network patterns.This complexity presents challenges for the comprehensive well logging evaluation of the geological-engineering"double sweet spots"in shale oil,severely restricting efficient development.This study focuses on the impact of shale sedimentary layering on the radial slowness of dipole shear waves.It employs rock physics experiments combined with advanced well logging techniques to explore the relationship between reservoir anisotropy caused by sedimentary layering and reservoir quality,thereby establishing a logging evaluation method for vertical identification of"sweet spots"in lacustrine shale oil.The shales in the Fengcheng Formation of the Mahu Sag into three types according to sedimentary structure scale:laminated,interlayer,and massive.Each type has different mineral compositions,affecting reservoir quality and fracturing potential.Laminated shales develop more fractures under stress along the beddings,showing moderate anisotropy,with reservoir capacity dependent on intercrystalline porosity within carbonate layers.Interlayer shales easily form complex fracture networks,exhibiting significant anisotropy,and their reservoir capacity depends on the porosity within sandy bands.Massive mudstones have the fewest fractures under stress,appearing isotropic with reservoir capacity dependent on matrix pore size.The intensity of reservoir anisotropy correlates positively with storage capacity and the propensity to form irregular and complex fracture networks during hydraulic fracturing.In sections without natural fractures,a larger difference between fast and slow shear waves corresponds to a radial profile shift towards warm tones,indicating stronger anisotropy and better reservoir quality,thus forming complex fracture networks during fracturing.Conversely,a smaller difference leads to a profile energy shift towards cooler tones,indicating stronger isotropy and poorer reservoir quality,hindering the formation of complex fracture networks during hydraulic fracturing.In sections with natural fractures,the difference between fast and slow shear waves exhibits erratic behavior,showing a cross-pattern in radial profiles,indicating strong anisotropy.The presence of natural fractures can synergize with induced fracture networks to form more complex systems,significantly enhancing reservoir productivity.
基金supported from the Opening fund of State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development(33550000-22-ZC0613-0297)National Natural Science Foundation of China(42102196)the Natural Science Basis Research Plan in Shaanxi Province of China(2022JM-147).
文摘Pore structure directly affects the occurrence and migration of shale hydrocarbon,and the lack of research on the mechanism of the pore structure is an important reason for the hindrance of shale hydrocarbon exploration.By analysing the geochemistry and reservoir characteristics of Jurassic lacustrine shales in Sichuan Basin,this study recovers their paleoenvironments and further discusses paleoenvironmental constraints on pore structure.The results show that the Lower Jurassic lacustrine shales in the Sichuan Basin are in a warm and humid semi-anoxic to anoxic lake environment with high productivity,a strong stagnant environment,and a rapid sedimentation rate,with water depths ranging from about 11.54-55.22 m,and a mixture of type Ⅱ/Ⅲ kerogen is developed.In terms of reservoir characteristics,they are dominated by open-slit pores,and the pores are relatively complex.The percentage of mesopores is the highest,while the percentage of macropores is the lowest.Further analysis shows that paleoclimate controls the overall pore complexity and surface relaxation of shales by influencing the weathering rate of mother rocks.Paleoredox conditions control the proportion and complexity of shale pores by influencing TOC content.The research results will provide theoretical basis for improving the exploration efficiency of lacustrine shale resources and expanding exploration target areas.
基金supported by the National Natural Science Foundation of China(42090025,42302148)State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development(33550000-22-ZC0613-0336)CNPC Innovation Found(2023DQ02-0103)。
文摘Lacustrine shale oil reservoirs of the Upper Triassic Chang 7 Member in the Ordos Basin have demonstrated significant potential for hydrocarbon resources.Natural fractures play a crucial role in hydrocarbon enrichment and production.Outcrops,cores,borehole image logs,thin sections,and FE-SEM images were used to investigate the types and characteristics of natural fractures in the Chang 7 Member.The factors controlling fracture development and the mechanisms of bedding-parallel fracture formation were revealed by integrating TOC analysis,XRD analysis,and rock pyrolysis.Results show that natural fractures in the study area include high-angle tectonic fractures and nearly horizontal bedding-parallel fractures.Brittle minerals and bed thickness control the occurrence and attributes of tectonic fractures.High TOC content and thermal maturity positively affect the development of bedding-parallel fractures,formed through the conversion of organic matter to hydrocarbons or the smectite-to-illite transformation.Additionally,the dominant orientations of tectonic fractures intersect the present-day maximum horizontal principal stress at a small angle,resulting in large apertures and good effectiveness.Bedding-parallel fractures contribute to enhance porosity and provide favorable pathways for lateral hydrocarbon migration.Collectively,this study could provide valuable insights for finding promising exploration areas in lacustrine shale oil reservoirs in the Ordos Basin and worldwide.
基金Supported by National Natural Science Foundation of China(42472217).
文摘Taking the shale oil of the first member of the Cretaceous Qingshankou Formation of Changling Sag in southern Songliao Basin as an example,this paper establishes a saturation model of lacustrine shale oil considering the influence of organic matter on clay-bound water conductivity.Based on the fluid characterization results of sealed samples and two-dimensional nuclear magnetic resonance,the differential influence of organic matter on clay-bound water conductivity was quantitatively revealed,and the conductivity mechanism and rock-electrical relationships of lacustrine shale were systematically analyzed.The results show that there are two conductive networks for lacustrine shales,i.e.the matrix free water and the clay-bound water.The bound water cementation index msh was introduced to reflect the impact of organic matter on clay-bound water conductivity,and it is positively correlated with the effective porosity.When there is sufficient rigid framework support and well-developed pores,organic matter is more likely to fill or adsorb onto clay interlayers.This reduces the ion exchange capacity of the electrical double layer,leading to an increase in msh and a decrease in the conductivity of clay-bound water.The overall conductivity of shale is controlled by the clay-bound water conductivity,and the relative contributions of the mentioned two conductive networks to formation conductivity are affected by the effective porosity and msh.The larger the effective porosity and msh,the more the contribution of the matrix free water to formation conductivity.According to the experimental results,the proposed saturation model yields a significantly higher interpretation accuracy in oil saturation than the Archie model and the Total-shale model.
基金supported by the National Natural Science Foundation of China(No.42202170,42172109,42072140,42102133,42202122)the Natural Science Foundation of Chongqing(CSTB2022NSCQ-MSX1166,CSTB2022NSCQ-JQX0031)+1 种基金the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202201511,KJZD-M202101502)Project of Chongqing University of Science&Technology(ckrc2022028,YKJCX2320109).
文摘The deep-water systems in different types of sedimentary basins exhibit significant variability.Current knowledge of deep-water deposition is mainly derived from deep-marine turbidite systems.However,the characteristics and differences of sub-lacustrine gravity flow deposition systems have been a research focus in the fields of sedimentology and petroleum geology.This study investigates the facies archi-tecture,depositional processes,and sediment distribution patterns of a sub-lacustrine debrite system in the Eocene Dongying Rift of the Bohai Bay Basin,China,through the analysis of integrated core data,3-D seismic data,and well-log data.Nine facies have been identified within the debrite system,representing various depositional processes such as sandy debris flow,muddy debris flow,turbidity currents,sandy slide,sandy slide/slump,and mud flow.Our research indicates that the sub-lacustrine system is primarily influenced by debris flow rather than turbidity currents,as supported by facies quantification,inter-pretation,and flow rheology analysis.Additionally,we have identified five basic facies building blocks in debrite systems,including slide masses,slump masses,debrite channels,debrite lobes,and turbidite sheets.We have also elucidated and proposed detailed sedimentary processes,flow transport,and transformation within the sub-lacustrine system through analysis of flow origins,facies sequences,and distribution characteristics.Our findings highlight the evolutionary progression from delta-front collapse to sandy slide/slump,sandy debris flow,and finally muddy debris flow.The efficient generation of turbidity currents from parental landslides on sand-prone slopes is deemed unlikely due to rift-basin morphology and transport distances.The formation of the five basic facies building blocks is closely linked to depositional processes and dominant flow types.Consequently,we present a deep-water depositional model for sub-lacustrine debrite systems,focusing on flow dynamics,sediment distribu-tion patterns,and basin morphology within deep lacustrine rifts.This model offers valuable insights into the variability of deep-water deposition in diverse basin settings and aids in predicting lithologic res-ervoirs during deep-water hydrocarbon exploration.
基金Supported by the National Key R&D Program of China(2024YFE0114000)Science and Technology Project of China National Petroleum Corporation(2024DJ8702).
文摘Based on the analysis of typical lacustrine shale oil zones in China and their geological characteristics,this study elucidates the fundamental differences between the enrichment patterns of shale oil sweet spots and conventional oil and gas.The key parameters and evaluation methods for assessing the large-scale production potential of lacustrine shale oil are proposed.The results show that shale oil is a petroleum resource that exists in organic-rich shale formations,in other words,it is preserved in its source bed,following a different process of generation-accumulation-enrichment from conventional oil and gas.Thus,the concept of“reservoir”seems to be inapplicable to shale oil.In China,lacustrine shale oil is distributed widely,but the geological characteristics and sweet spots enrichment patterns of shale oil vary significantly in lacustrine basins where the water environment and the tectonic evolution and diagenetic transformation frameworks are distinct.The core of the evaluation of lacustrine shale oil is“sweet spot volume”.The key factors for evaluating the large-scale production of continental shale oil are the oil storage capacity,oil-bearing capacity and oil producing capacity.The key parameters for evaluating these capacities are total porosity,oil content,and free oil content,respectively.It is recommended to determine the total porosity of shale by combining helium porosity measurement with nuclear magnetic resonance(NMR)method,the oil content of key layers by using organic solvent extraction,NMR method and high pressure mercury intrusion methods,and the free oil content by using NMR fluid distribution secondary spectral stripping decomposition and logging.The research results contribute supplemental insights on continental shale oil deliverability in China,and provide a scientific basis for the rapid exploration and large-scale production of lacustrine shale oil.
基金Supported by the National Science and Technology Major Project(2024ZD1404901,2017ZX05035)Strategic Priority Research Program(Category B)of the Chinese Academy of Sciences(XDB10050100).
文摘To clarify the mechanism of differential enrichment of intrasource shale oil,taking the third of seventh member of the Triassic Yanchang Formation(Chang 7_(3)submember for short)in the Ordos Basin,NW China as an example,we integrated high-resolution scanning electron microscopy(SEM),optical microscopy,laser Raman spectroscopy,rock pyrolysis,and organic solvent extraction experiments to identify solid bitumen of varying origins,obtain direct evidence of intrasource micro-migration of shale oil,and establish the coupling between the shale nano/micro-fabric and the oil generation,migration and accumulation.The Chang 7_(3)shale with rich alginite in laminae has the highest hydrocarbon generation potential but a low thermal transformation ratio.Frequent alternations of micron-scale argillaceous-felsic laminae enhance the hydrocarbon expulsion efficiency,yielding consistent aromaticity between in-situ and migrated solid bitumen.Mudstone laminae rich in terrestrial organic matter(OM)and clay minerals exhibit lower hydrocarbon generation threshold but stronger hydrocarbon retention capacity,with a certain amount of light oil/bitumen preserved to differentiate the chemical structure of in-situ versus migrated bitumen.Tuffaceous and sandy laminae contain abundant felsic minerals and migrated bitumen.Tuffaceous laminae develop high-angle microfractures under shale overpressure,facilitating oil charging into rigid mineral intergranular pores of sandy laminae.Fractionation during micro-migration progressively decreases the aromatization of solid bitumen from shale,through tuffaceous and mudstone,to sandy laminae,while increasing light hydrocarbon components and enhancing OM-hosted pore development.The intrasource micro-migration and enrichment of the Chang 7_(3)shale oil result from synergistic organic-inorganic diagenesis,with crude oil component fractionation being a key mechanism for forming sweet spots in laminated shale oil reservoirs.
基金Supported by the China National Key R&D Program(2023YFF0614100)National Science and Technology Major Project of China(2024ZD14066)+1 种基金Major Project of PetroChina Company Limited(2021ZZ01)Key R&D Project of Xinjiang Uygur Autonomous Region of China(2024B03001).
文摘Based on the technological demands for significantly enhancing oil recovery and long-term CO_(2)sequestration in the lacustrine oil reservoirs of China,this study systematically reviews the progress and practices of CO_(2)flooding and storage technologies in recent years.It addresses the key technological needs and challenges faced in scaling up the application of CO_(2)flooding and storage to mature,developed oil fields,and analyzes future development directions.During the pilot test phase(2006-2019),continuous development and application practices led to the establishment of the first-generation CO_(2)flooding and storage technology system for lacustrine reservoirs.In the industrialization phase(since 2020),significant advances and insights have been achieved in terms of confined phase behavior,storage mechanisms,reservoir engineering,sweep control,engineering process and storage monitoring,enabling the maturation of the second-generation CO_(2)flooding and storage theories and technologies to effectively support the demonstration projects of Carbon Capture,Utilization and Storage(CCUS).To overcome key technical issues such as low miscibility,difficulty in gas channeling control,high process requirements,limited application scenarios,and coordination challenges in CO_(2)flooding and storage,and to support the large-scale application of CCUS,it is necessary to strengthen research on key technologies for establishing the third-generation CO_(2)flooding and storage technological system incorporating miscibility enhancement and transformation,comprehensive regulation for sweep enhancement,whole-process engineering techniques and equipment,long-term storage monitoring safety,and synergistic optimization of flooding and storage.
基金financially supported by the National Natural Science Foundation of China (Grant No. 42072150)
文摘To accurately investigate the evolution characteristics and generation mechanism of retained oil,the study analyzed organic-rich lacustrine shale samples from the Paleogene Kongdian Formation in Cangdong Sag,Bohai Bay Basin.This analysis involves Rock-Eval pyrolysis,pyrolysis simulation experiments,Gas Chromatograph Mass Spectrometer(GC-MS),and reactive molecular dynamics simulations(ReaxFF).The results revealed the retained oil primarily consisted of n-alkanes with carbon numbers ranging from C14 to C36.The generation of retained oil occurred through three stages.A slow growth stage of production rate was observed before reaching the peak of oil production in Stage Ⅰ.Stage Ⅱ involved a rapid increase in oil retention,with C12-C17 and C24-C32 serving as the primary components,increasing continuously during the pyrolysis process.The generation process involved the cleavage of weak bonds,including bridging bonds(hydroxyl,oxy,peroxy,imino,amino,and nitro),ether bonds,and acid amides in the first stage(Ro=0.50%-0.75%).The carbon chains in aromatic ring structures with heteroatomic functional groups breaks in the second stage(R_(o)=0.75%-1.20%).In the third stage(R_(o)=1.20%-2.50%),the ring structures underwent ring-opening reactions to synthesize iso-short-chain olefins and radicals,while further breakdown of aliphatic chains occurred.By coupling pyrolysis simu-lation experiments and molecular simulation technology,the evolution characteristics and bond breaking mechanism of retained oil in three stages were revealed,providing a reference for the for-mation and evolution mechanism of retained oil.
基金Supported by the National Natural Science Foundation of China(52425402,52204021,52404038)Scientific Research Fund of China University of Petroleum(Beijing)(2462022BJRC002).
文摘To elucidate the mechanism by which supercritical CO_(2)(SCCO_(2))-water-shale interactions during CO_(2)energized fracturing influence proppant embedment in lacustrine shale,shale samples from the Bohai Bay Basin were selected for SCCO_(2)-water-shale interaction experiments.X-ray diffraction(XRD),SEM large-area high-resolution imaging,automated mineral identification and characterization system(AMICS),and nanoindentation tests were employed to examine the micro-mechanical damage mechanisms of fracture surfaces and the evolving patterns of proppant embedment characteristics.The results reveal that:Prolonged interaction time reduces the contents of dolomite,feldspar,and clay minerals,while quartz content increases,with dolomite showing the most pronounced dissolution effect.As interaction time increases,the hardness and elasticity modulus of shale follow a power-law decay pattern,with the peak degradation rate occurring at 1 d,followed by a gradual decline of degradation velocity.Increasing interaction time results in growth in both the number and depth of embedment pits on the sample surface.After more than 3 d of interaction,clustered proppant embedment is observed,accompanied by the formation of deep embedment pits on the surface.
基金This research is supported by the Joint Fund of the National Natural Science Foundation of China(grant number U19B6003-02)the Cooperation Program of PetroChina Liaohe Oilfield Company(grant Number HX20180604)the AAPG Foundation Grants-in-Aid Program(grant number 22269437).This study has benefited considerably from PetroChina Liaohe Oilfield Company for data support.We also thank the editor and the anonymous reviewers for their professional suggestions and comments.
文摘Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.
文摘Reactive transport modeling(RTM)is an emerging method used to address geological issues in diagenesis research.However,the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood.This paper presents a case study of the Eocene Qaidam Basin that combines RTM results with petrological and mineralogical evidence.The results show that the Eocene Xiaganchaigou Formation is characterized by mixed siliciclastic-carbonate-evaporite sedimentation in a semiclosed saline lacustrine environment.Periodic evaporation and salinization processes during the syngeneticpenecontemporaneous stage gave rise to the replacive genesis of dolomites and the cyclic enrichment of dolomite in the middle-upper parts of the meter-scale depositional sequences.The successive change in mineral paragenesis from terrigenous clastics to carbonates to evaporites was reconstructed using RTM simulations.Parametric uncertainty analyses further suggest that the evaporation intensity(brine salinity)and particle size of sediments(reactive surface area)were important rate-determining factors in the dolomitization,as shown by the relatively higher reaction rates under conditions of higher brine salinity and fine-grained sediments.Combining the simulation results with measured mineralogical and reservoir physical property data indicates that the preservation of original intergranular pores and the generation of porosity via replacive dolomitization were the major formation mechanisms of the distinctive lacustrine dolomite reservoirs(widespread submicron intercrystalline micropores)in the Eocene Qaidam Basin.The results confirm that RTM can be effectively used in geological studies,can provide a better general understanding of the dolomitizing fluid-rock interactions,and can shed light on the spatiotemporal evolution of mineralogy and porosity during dolomitization and the formation of lacustrine dolomite reservoirs.
基金financial support from the National Key Research and Development Program of China(2019YFC0605502)the National Natural Science Foundation of China(42302156)+1 种基金the Major Projects of Petro China Science and Technology Fund(2021DJ0206)the Natural Science Foundation of China University of Petroleum(22CX06046A)。
文摘The organic-rich mudstones and dolostones of the Permian Fengcheng Formation(Fm.)are typically alkaline lacustrine source rocks,which are typified by impressively abundantβ-carotane.Abundant β-carotane has been well acknowledged as an effective indicator of biological sources or depositional environments.However,the specific biological sources of β-carotane and the coupling control of biological sources and environmental factors on the enrichment of β-carotane in the Fengcheng Fm.remains obscure.Based on a comprehensive investigation of the bulk,molecular geochemistry,and organic petrology of sedimentary rocks and the biochemistry of phytoplankton in modern alkaline lakes,we proposed a new understanding of the biological precursors of β-carotane and elucidated the enrichment mechanism of β-carotane in the Fengcheng Fm.The results show that the biological precursors crucially control the enrichment of β-carotane in the Fengcheng Fm.The haloalkaliphilic cyanobacteria are the primary biological sources of β-carotane,which is suggested by a good positive correlation between the 2-methylhopane index,7-+8-methyl heptadecanes/C_(max),C_(29%),and β-carotane/C_(max)in sedimentary rocks and the predominance of cyanobacteria with abundantβ-carotene in modern alkaline lakes.The enrichment of β-carotane requires the reducing condition,and the paleoredox state that affects the enrichment of β-carotane appears to have a threshold.The paleoclimate conditions do not considerably impact the enrichment of β-carotane,but they have some influence on the water's paleosalinity by affecting evaporation and precipitation.While it does not directly affect the enrichment of β-carotane in the Fengcheng Fm.,paleosalinity does have an impact on the cyanobacterial precursor supply and the preservation conditions.
基金supported by the State Key Laboratory of Petroleum Resources and Engineering,China University of Petroleum(Beijing).
文摘Hyperpycnal deposits has gradually emerged as a current research hotspot,with a special focus on lacustrine hyperpycnal deposits.However,our understanding of the formation mechanism and distribution of high-quality reservoirs in hyperpycnal deposits remains insufficient.In this study,the formation mechanism and distribution of high-quality reservoirs in the second member of the Sangonghe Formation are studied through sedimentology,petrology,and geochemistry,and 10 types of lithofacies were identified in the depositional sequences of the hyperpycnal flow.These can be summarized as gravelly bed to suspended load lithofacies association(GBS),gravelly reverse to normal compound-graded(GNR),coarse-grained sandy suspended load(CSS),and fine-grained sandy suspended load(FSS)lithofacies associations.The hyperpycnal system can be divided into four individual units:restricted channel,unrestricted channel,lobe,and levee.The reservoir quality varies with lithofacies.Gravelly bed load lithofacies has coarse grain sizes,high content of rigid minerals,and soluble components,such as magmatic rock fragments.Therefore,the gravelly bed load lithofacies reservoir has developed dissolution pores and well-preserved pore throats.Its reservoir quality is good.GBS and GNR are the main lithofacies associations in the restricted channel,where type I and type II reservoirs developed.The unrestricted channel is dominated by the CSS lithofacies association,with type III reservoirs developed.The lobe is dominated by the CSS and FSS lithofacies associations,with type III and type IV reservoirs developed.High-quality reservoirs mainly develop in the restricted and unrestricted channels,whereas reservoirs in the lobe have poor quality.The levees are dominated by siltstone and gray mudstone and are generally nonreservoirs.
文摘Due to limited data on the geochemical properties of natural gas,estimations are needed for the effective gas source rock in evaluating gas potential.However,the pronounced heterogeneity of mudstones in lacustrine successions complicates the prediction of the presence and geochemical characteristics of gas source rocks.In this paper,the Liaohe Subbasin of Northeast China is used as an example to construct a practical methodology for locating effective gas source rocks in typical lacustrine basins.Three types of gas source rocks,microbial,oil-type,and coal-type,were distinguished according to the different genetic types of their natural gas.A practical three-dimensional geological model was developed,refined,and applied to determine the spatial distribution of the mudstones in the Western Depression of the Liaohe Subbasin and to describe the geochemical characteristics(the abundance,type,and maturation levels of the organic matter).Application of the model in the subbasin indicates that the sedimentary facies have led to heterogeneity in the mudstones,particularly with respect to organic matter types.The effective gas source rock model constructed for the Western Depression shows that the upper sequence(SQ2)of the Fourth member(Mbr 4)of the Eocene Shahejie Formation(Fm)and the lower and middle sequences(SQ3 and SQ4)of the Third member(Mbr 3)form the principal gas-generating interval.The total volume of effective gas source rocks is estimated to be 586 km^(3).The effective microbial,oil-type,and coal-type gas source rocks are primarily found in the shallow western slope,the central sags,and the eastern slope of the Western Depression,respectively.This study provides a practical approach for more accurately identifying the occurrence and geochemical characteristics of effective natural gas source rocks,enabling a precise quantitative estimation of natural gas reserves.
基金Supported by CNPC Prospective and Basic Science and Technology Major Project(2023ZZ02)Petro China Science and Technology Major Project(2021DJ0402.2021DJ0202)。
文摘The saline lacustrine hybrid sedimentary rocks are complex in lithology and unknown for their sedimentary mechanisms.The hybrid sedimentary rocks samples from the Neogene upper Ganchaigou Formation to lower Youshashan Formation(N_(1)-N_(2)^(1))in the Fengxi area Qaidam Basin,were investigated through core-log and petrology-geochemistry cross-analysis by using the core,casting thin section,scanning electron microscope,X-ray diffraction,logging,and carbon/oxygen isotopic data.The hybrid sedimentary rocks in the Fengxi area,including terrigenous clastic rock and lacustrine carbonate rock,were deposited in a shallow lake environment far from the source,or occasionally in a semi-deep lake environment,with 5 lithofacies types and 6 microfacies types recognized.Stable carbon and oxygen isotopic compositions reveal that the formation of sedimentary cycles is controlled by a climate-driven compensation-undercompensation cyclic mechanism.A sedimentary cycle model of hybrid sedimentary rocks in an arid and saline setting is proposed.According to this model,in the compensation period,the lake level rises sharply,and microfacies such as mud flat,sand-mud flat and beach are developed,with physical subsidence as the dominant sedimentary mechanism;in the undercompensation period,the lake level falls slowly,and microfacies such as lime-mud flat,lime-dolomite flat and algal mound/mat are developed,with chemical-biological process as the dominant sedimentary mechanism.In the saline lacustrine sedimentary system,lacustrine carbonate rock is mainly formed along with regression,the facies change is not interpreted by the accommodation believed traditionally,but controlled by the temporary fluctuation of lake water chemistry caused by climate change.The research results update the interpreted high-resolution sequence model and genesis of hybrid sedimentary rocks in the saline lacustrine basin and provide a valuable guidance for exploring unconventional hydrocarbons of saline lacustrine facies.
