In this study,a series of triaxial tests are conducted on sandstone specimens to investigate the evolution of their mechanics and permeability characteristics under the combined action of immersion corrosion and seepa...In this study,a series of triaxial tests are conducted on sandstone specimens to investigate the evolution of their mechanics and permeability characteristics under the combined action of immersion corrosion and seepage of different chemical solutions.It is observed that with the increase of confining pressure,the peak stress,dilatancy stress,dilatancy stress ratio,peak strain,and elastic modulus of the sandstone increase while the Poisson ratio decreases and less secondary cracks are produced when the samples are broken.The pore pressure and confining pressure have opposite influences on the mechanical properties.With the increase of the applied axial stress,three stages are clearly identified in the permeability evolution curves:initial compaction stage,linear elasticity stage and plastic deformation stage.The permeability reaches the maximum value when the highest volumetric dilatancy is obtained.In addition,the hydrochemical action of salt solution with pH=7 and 4 has an obvious deteriorating effect on the mechanical properties and induces the increase of permeability.The obtained results will be useful in engineering to understand the mechanical and seepage properties of sandstone under the coupled chemical-seepage-stress multiple fields.展开更多
This paper presents an improved level set method for topology optimization of geometrically nonlinear structures accounting for the effect of thermo-mechanical couplings.It derives a new expression for element couplin...This paper presents an improved level set method for topology optimization of geometrically nonlinear structures accounting for the effect of thermo-mechanical couplings.It derives a new expression for element coupling stress resulting from the combination of mechanical and thermal loading,using geometric nonlinear finite element analysis.A topological model is then developed to minimize compliance while meeting displacement and frequency constraints to fulfill design requirements of structural members.Since the conventional Lagrange multiplier search method is unable to handle convergence instability arising from large deformation,a novel Lagrange multiplier search method is proposed.Additionally,the proposed method can be extended to multi-constrained geometrically nonlinear topology optimization,accommodating multiple physical field couplings.展开更多
Photoelectrocatalytic coupling CO_(2)and volatile organic compounds (VOCs) is a promising green strategy for the synergistic conversion of the two carbon-containing resources to C2products.The catalytic efficiency is ...Photoelectrocatalytic coupling CO_(2)and volatile organic compounds (VOCs) is a promising green strategy for the synergistic conversion of the two carbon-containing resources to C2products.The catalytic efficiency is always at the mercy of chemical inertness of CO_(2)and the competitive hydrogen evolution of H2O.Herein,a modified g-C_(3)N_(4)/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely constructed.The Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol g^(-1)h^(-1).As revealed by in-situ characterizations and density functional theory calculations,CO_(2)and HCHO were absorbed at Zn site and N site,respectively.Then,*CO generated from CO_(2)and HCHO was converted to*CH_(3)O and*CHO on the dual-active-site heterojunction.The detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH_(3)O in electrocatalysis process.Apart from the“*CO+*CH_(3)O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic process.The selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO_(2)and HCHO simultaneously driven by light and electricity.展开更多
The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the ...The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the compact integration of the OMP presents challenges inefficiently dissipating internal heat,leading to a performance degradation of the EHA due to ele-vated temperatures.Therefore,accurately modeling and predicting the internal thermal dynamicsof the OMP hold considerable significance for monitoring the operational condition of the EHA.In view of this,a modeling method considering cumulative thermal coupling was hereby proposed.Based on the proposed method,the thermal models of the motor and the pump were established,taking into account heat accumulation and transfer.Taking the leakage oil as the heat couplingpoint between the motor and the pump,the dynamic thermal coupling model of the OMP wasdeveloped,with the thermal characteristics of the oil considered.Additionally,the comparativeexperiments were conducted to illustrate the efficiency of the proposed model.The experimentalresults demonstrate that the proposed dynamic thermal coupling model accurately captured thethermal behavior of OMP,outperforming the static thermal parameter model.Overall,thisadvancement is crucial for effectively monitoring the health of EHA and ensuring flight safety.展开更多
Photo-reforming methanol into valuable chemicals represents an energetically sustainable alternative to conventional thermal catalysis,yet controlling-specific C-C coupling way still remains elusive.In this work,we re...Photo-reforming methanol into valuable chemicals represents an energetically sustainable alternative to conventional thermal catalysis,yet controlling-specific C-C coupling way still remains elusive.In this work,we report a sulfide-based photocatalytic paradigm,where atomic-level control of nickel species directly dictates reaction selectivity.The electrostatic constructing ZnIn_(2)S_(4)/Zn_(0.5)Cd_(0.5)S(ZIS/ZCS)heterostructures enable single atom Ni to facilitate ethylene glycol(EG)production with a rate of 11.2 mmol·gcat^(−1)·h^(−1),surpassing reported non-precious metal systems,whereas the Ni aggregates drive exclusive formaldehyde formation.The operando spectroscopy and density functional theory reveal dual roles of Ni as electron reservoir and chemical bond breakage inducers,lowering C-H activation barriers while stabilizing·CH2OH intermediates for cross-coupling.This interfacial configuration engineering creates an electron highway that couples carrier dissociation with radical recombination kinetics,achieving atom-economic steering of methanol oxidative valorization.The metal dispersion assisting catalysis correlation here provides a design blueprint for selective bond scission and reconstruction in sustainable organic synthesis.展开更多
The collective dynamic of a fractional-order globally coupled system with time delays and fluctuating frequency is investigated.The power-law memory of the system is characterized using the Caputo fractional derivativ...The collective dynamic of a fractional-order globally coupled system with time delays and fluctuating frequency is investigated.The power-law memory of the system is characterized using the Caputo fractional derivative operator.Additionally,time delays in the potential field force and coupling force transmission are both considered.Firstly,based on the delay decoupling formula,combined with statistical mean method and the fractional-order Shapiro–Loginov formula,the“statistic synchronization”among particles is obtained,revealing the statistical equivalence between the mean field behavior of the system and the behavior of individual particles.Due to the existence of the coupling delay,the impact of the coupling force on synchronization exhibits non-monotonic,which is different from the previous monotonic effects.Then,two kinds of theoretical expression of output amplitude gains G and G are derived by time-delay decoupling formula and small delay approximation theorem,respectively.Compared to G,G is an exact theoretical solution,which means that G is not only more accurate in the region of small delay,but also applies to the region of large delay.Finally,the study of the output amplitude gain G and its resonance behavior are explored.Due to the presence of the potential field delay,a new resonance phenomenon termed“periodic resonance”is discovered,which arises from the periodic matching between the potential field delay and the driving frequency.This resonance phenomenon is analyzed qualitatively and quantitatively,uncovering undiscovered characteristics in previous studies.展开更多
This study presents a comprehensive mechanical analysis of P110S oil tubing subjected to thermal and chemical coupling effects,with particular attention to the presence of rectangular corrosion defects.Drawing on the ...This study presents a comprehensive mechanical analysis of P110S oil tubing subjected to thermal and chemical coupling effects,with particular attention to the presence of rectangular corrosion defects.Drawing on the material’s stress–strain constitutive behavior,thermal expansion coefficient,thermal conductivity,and electrochemical test data,the research incorporates geometric nonlinearities arising from large deformations induced by corrosion.A detailed three-dimensional finite element(FE)model of the corroded P110S tubing is developed to simulate its response under complex loading conditions.The proposed model is rigorously validated through full-scale burst experiments and analytical calculations based on theoretical formulations.Building upon this validation,the Extended Finite Element Method(XFEM)and a failure criterion grounded in damage evolution mechanics are applied to investigate the mechanical behavior of the tubing under the coupled influences of temperature,stress,and chemical corrosion.Special emphasis is placed on the role of rectangular corrosion features in determining failure mechanisms.To further elucidate the impact of multiple interacting parameters,a sensitivity analysis is performed by integrating grey correlation theory with simulation outcomes.Based on these findings,the study systematically explores the elastic–plastic deformation process,crack initiation and propagation behavior,and the burst failure response of tubing specimens with varying axial lengths and depths of corrosion.The proposed methodology provides a robust predictive framework for petroleum engineers to evaluate fracture pressure,diagnose failure modes,assess operational risks,and optimize production strategies.展开更多
The Lithium-ion deintercalation induces a significant volume change in battery electrodes during charging and discharging processes,which in turn generates a large diffusion-induced stress(DIS).This stress can cause m...The Lithium-ion deintercalation induces a significant volume change in battery electrodes during charging and discharging processes,which in turn generates a large diffusion-induced stress(DIS).This stress can cause microstructural damage,consequently degrading battery performance.This work simplifies the particles making up the electrode into spheres and studies the impact of the surface microstructure on the distribution of diffusion-induced stress.A mechanical-chemical coupling model was established to study the DIS in secondary particles,which were constructed by adding convex particles to the ball-shaped particle surfaces of the electrode material.It is observed that an increase in the number of convex particles results in a higher concentration of lithium ions within the electrode material,along with the first principal stresses within the material particles.In addition,the convex particles increase the local stresses around the ball-shaped particle surface.Therefore,a round surface on the electrode material particles is beneficial for preventing potential fractures.展开更多
Azoxy aromatics are extensively utilized in materials science,pharmaceuticals,and synthetic chemistry,but their controlled and environmentally-friendly synthesis has rarely been reported.Herein,a potential-mediated el...Azoxy aromatics are extensively utilized in materials science,pharmaceuticals,and synthetic chemistry,but their controlled and environmentally-friendly synthesis has rarely been reported.Herein,a potential-mediated electrosynthesis strategy was developed by selective reduction of 4-nitrobenzyl alcohol(4-NBA)on Mn-doped Ni_(2)P nanosheets@nickel foam(Mn-Ni_(2)P/NF),enabling efficient N−N coupling to produce Azoxy with 100%selectivity at potentials of−0.6 to−0.8 V(vs.Hg/HgO).At more cathodic potentials,the product was converted to Azo and then to amino aromatics due to facilitated nitrogen hydrogenation.Additionally,the organic energetic material,5,5′-azotetrazolate,was also synthesized by anodic N−N coupling of 5-amino-1H-tetrazole on Cu(OH)_(2)nanowires@copper foam(Cu(OH)_(2)/CF).It bypassed harsh conditions(strong oxidants,high temperature,by-products separation,etc.)for the traditional synthesis of this class of materials.As a consequence,a two-electrode electrolyzer Cu(OH)_(2)/CF||Mn-Ni_(2)P/NF was assembled,allowing paired electrochemical N−N coupling into Azoxy and 5,5′-azotetrazolate.It achieves a current density of 50 mA cm^(−2)at a voltage of only 1.19 V,880 mV lower than the competitive water splitting.This electrolyzer can be efficiently driven by a 1.2 V solar panel with excellent yield and selectivity,paving the way for green synthesis of valuable chemicals through electrochemical N−N coupling strategies.展开更多
Within the prefrontal-cingulate cortex,abnormalities in coupling between neuronal networks can disturb the emotion-cognition interactions,contributing to the development of mental disorders such as depression.Despite ...Within the prefrontal-cingulate cortex,abnormalities in coupling between neuronal networks can disturb the emotion-cognition interactions,contributing to the development of mental disorders such as depression.Despite this understanding,the neural circuit mechanisms underlying this phenomenon remain elusive.In this study,we present a biophysical computational model encompassing three crucial regions,including the dorsolateral prefrontal cortex,subgenual anterior cingulate cortex,and ventromedial prefrontal cortex.The objective is to investigate the role of coupling relationships within the prefrontal-cingulate cortex networks in balancing emotions and cognitive processes.The numerical results confirm that coupled weights play a crucial role in the balance of emotional cognitive networks.Furthermore,our model predicts the pathogenic mechanism of depression resulting from abnormalities in the subgenual cortex,and network functionality was restored through intervention in the dorsolateral prefrontal cortex.This study utilizes computational modeling techniques to provide an insight explanation for the diagnosis and treatment of depression.展开更多
In the current situation of decelerating economic expansion,examining the digital economy(DE)as a novel economic model is beneficial for the local economy’s sustainable and high-quality development(HQD).We analyzed p...In the current situation of decelerating economic expansion,examining the digital economy(DE)as a novel economic model is beneficial for the local economy’s sustainable and high-quality development(HQD).We analyzed panel data from the Yellow River(YR)region from 2013 to 2021 and discovered notable spatial variances in the composite index and coupling coordination of the two systems.Specifically,the downstream region exhibited the highest coupling coordination,while the upstream region had the lowest.We identified that favorable factors such as economic development,innovation,industrial upgrading,and government intervention can bolster the coupling.Our findings provide a valuable framework for promoting DE and HQD in the YR region.展开更多
Oxidative coupling of methane(OCM)is a catalytic partial oxidation process that directly converts methane into C_(2) products.For this high temperature reaction,understanding the radical behavior through experimental ...Oxidative coupling of methane(OCM)is a catalytic partial oxidation process that directly converts methane into C_(2) products.For this high temperature reaction,understanding the radical behavior through experimental investigation is important in correlating the catalytic activity and the products.In this work,a spatial resolution online mass spectrometry(MS)system was developed and applied to a Mn-Na_(2)WO_(4)/SiO_(2) catalyzed OCM system.In addition to the residue gas analysis,the system obtained the distribution information of the reactants and products in the reactor.At various setting temperatures,all species online MS signals were collected at different positions,mapping the reaction activity covering parameters including temperature,time and space.The distribution behavior of the catalytic activity,selectivity,and apparent activation energy were kinetically analyzed.Selectivity and additional carbon balance analysis strongly supported the radical coupling model of OCM and indicated that after the catalytic bed layer,there is a significant length in the reactor(>2 mm)filled with radicals.Based on the result,a designed new method by tuning the temperature field in the reactor was found effectively to improve the catalytic activity,especially the C_(2) yield from 702 to 773℃.展开更多
The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials.The assumption used in the method that lithium is uniformly distributed in...The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials.The assumption used in the method that lithium is uniformly distributed in the active layer lacks quantitative evaluation,and the uniformity of concentration distribution is crucial for accurate in-situ measurements of concentration-related material properties and stress in bilayer electrodes.Therefore,this paper proposes a mechanical-electrochemical coupled model to study the lithium concentration distribution in the active layer during lithiation.This model includes lithium concentration diffusion and active layer deformation.By comparing experimental and simulated curvature evolution of the active layer during lithiation and delithiation,the reliability of this simulation model is verified.We then derive the precise concentration distribution inside the active layer and suggest using relative error to quantitatively evaluate the uniformity of lithium concentration in the active layer.Results show that a low relative error in lithium concentration can be achieved in the middle region of the active layer.Additionally,the effects of different rates and geometric parameters on the lithium concentration distribution in the active layer are discussed.Results indicate that reduced rates,thinner active layers,shorter active layer lengths,and increased spacing between the working and counter electrodes can lead to a more uniform distribution of lithium concentration in the active layer.These insights help improve experimental methods and equipment,promoting uniform distribution of lithium in the active layer and enhancing measurement accuracy.展开更多
A debris flow forecast model based on a water-soil coupling mechanism that takes the debrisflow watershed as a basic forecast unit was established here for the prediction of disasters at the watershed scale.This was a...A debris flow forecast model based on a water-soil coupling mechanism that takes the debrisflow watershed as a basic forecast unit was established here for the prediction of disasters at the watershed scale.This was achieved through advances in our understanding of the formation mechanism of debris flow.To expand the applicable spatial scale of this forecasting model,a method of identifying potential debris flow watersheds was used to locate areas vulnerable to debris flow within a forecast region.Using these watersheds as forecasting units and a prediction method based on the water-soil coupling mechanism,a new forecasting method of debris flow at the regional scale was established.In order to test the prediction ability of this new forecasting method,the Sichuan province,China was selected as a study zone and the large-scale debris flow disasters attributable to heavy rainfall in this region on July 9,2013 were taken as the study case.According to debris flow disaster data on July 9,2013 which were provided by the geo-environmental monitoring station of Sichuan province,there were 252 watersheds in which debris flow events actually occurred.The current model predicted that 265 watersheds were likely to experience a debris flow event.Among these,43 towns including 204 debrisflow watersheds were successfully forecasted and 24 towns including 48 watersheds failed.The false prediction rate and failure prediction rate of thisforecast model were 23% and 19%,respectively.The results show that this method is more accurate and more applicable than traditional methods.展开更多
In this paper,a high-fidelity computational fluid dynamics(CFD)and rigid body dynamics(RBD)coupled platform for virtual flight simulation is developed to investigate the flight stability of fixed canard dual-spin proj...In this paper,a high-fidelity computational fluid dynamics(CFD)and rigid body dynamics(RBD)coupled platform for virtual flight simulation is developed to investigate the flight stability of fixed canard dual-spin projectile.The platform's reliability is validated by reproducing the characteristic resonance instability of such projectiles.By coupling the solution of the Unsteady Reynolds-Averaged Navier-Stokes equations and the seven-degree-of-freedom RBD equations,the virtual flight simulations of fixed canard dual-spin projectiles at various curvature trajectories are achieved,and the dynamic mechanism of the trajectory following process is analyzed.The instability mechanism of the dynamic instability during trajectory following process of the fixed canard dual-spin projectile is elucidated by simulating the rolling/coning coupled forced motion,and subsequently validated through virtual flight simulations.The findings suggest that an appropriate yaw moment can drive the projectile axis to precession in the tangential direction of the trajectory,thereby enhancing the trajectory following stability.However,the damping of the projectile attains its minimum value when the forward body equilibrium rotational speed(-128 rad/s)is equal to the negative of the fast mode frequency of the projectile.Insufficient damping leads to the fixed canard dual-spin projectile exiting the dynamic stability domain during the trajectory following,resulting in weakly damped instability.Keeping the forward body not rotating or increasing the spin rates to-192 rad/s can enhance the projectile's damping,thereby improving its dynamic stability.展开更多
The coupling effects of rainfall,earthquake,and complex topographic and geological conditions complicate the dynamic responses and disasters of slope-tunnel systems.For this,the large-scale shaking table tests were ca...The coupling effects of rainfall,earthquake,and complex topographic and geological conditions complicate the dynamic responses and disasters of slope-tunnel systems.For this,the large-scale shaking table tests were carried out to explore the dynamic responses of steep bedding slope-tunnel system under the coupling effect of rainfall and earthquake.Results show that the slope surface and elevation amplification effect exhibit pronounced nonlinear change caused by the tunnel and weak interlayers.When seismic wave propagates to tunnels,the weak interlayers and rock intersecting areas present complex wave field distribution characteristics.The dynamic responses of the slope are influenced by the frequency,amplitude,and direction of seismic waves.The acceleration amplification coefficient initially rises and then falls as increasing seismic frequency,peaking at 20 Hz.Additionally,the seismic damage process of slope is categorized into elastic(2-3 m/s^(2)),elastoplastic(4-5 m/s^(2))and plastic damage stages(≥6.5 m/s^(2)).In elastic stage,ΔMPGA(ratio of acceleration amplification factor)increases with increasing seismic intensity,without obvious strain distribution change.In plastic stage,ΔMPGA begins to gradually plummet,and the strain is mainly distributed in the damaged area.The modes of seismic damage in the slope-tunnel system are mainly of tensile failure of the weak interlayer,cracking failure of tunnel lining,formation of persistent cracks on the slope crest and waist,development and outward shearing of the sliding mass,and buckling failure at the slope foot under extrusion of the upper rock body.This study can serve as a reference for predicting the failure modes of tunnel-slope system in strong seismic regions.展开更多
Cells live in a multiphysics-coupled microenvironment in vivo,in which electric fields(EFs)and mechanical cues are the most essential induction signals.The regulatory effects of EFs and stiffness on cells have been in...Cells live in a multiphysics-coupled microenvironment in vivo,in which electric fields(EFs)and mechanical cues are the most essential induction signals.The regulatory effects of EFs and stiffness on cells have been independently demonstrated.However,how cells respond to electromechanical coupling cues remains mysterious.In this study,an electro-stiffness-coupled chip system was designed and fabricated,freely integrating and precisely controlling EF strength and the mechanical stiffness applied to cells across the physiological spectrum.Utilizing the innovative bioreactor,it was observed that electromechanical coupling stimulations can shape cancer cell morphology and cytoskeleton into a unique anteroposterior polarization state and orient cancer cell migration in a voltage-dependent manner through cytoskeleton-associated mechanisms.Moreover,the mechanical stiffness regulated cancer cell susceptibility to EFs,and the orientation effect of EFs on cells required a stiffness threshold.Furthermore,transforming growth factor-β1 suppressed the orientation of cancer cells induced by electromechanical coupling signals and showed a splitting effect on the directionality and velocity of cancer cell migration,indicating a comprehensive cross-talk of biochemical–electromechanical signals.Together with the dual-physical bioreactor we designed,these findings provide a robust and convenient platform for exploring cellular responses to electro-stiffness coupling signals,reveal the biophysical mechanisms of cell polarization and migration from the perspective of electromechanical coupling,and lay a promising foundation for biophysical-based cell manipulation and therapeutic interventions.展开更多
In this paper,we develop the teleportation scheme in[Zheng in Phys Rev A 69,064302,2004],in the sense that,we work in the strong atom-field coupling regime wherein the rotating wave approximation(RWA)is no longer vali...In this paper,we develop the teleportation scheme in[Zheng in Phys Rev A 69,064302,2004],in the sense that,we work in the strong atom-field coupling regime wherein the rotating wave approximation(RWA)is no longer valid.To achieve the purpose,a scheme consisting of a qubit interacting with a single-mode quantized field is described via the Rabi model(counter rotation terms are taken into account).Our first aim is to teleport an unknown atomic state of a qubit(which interacts with the quantized field in a cavity)to a second qubit(exists in another distant cavity field),beyond the RWA and without the Bell-state measurement method.In the continuation,in a similar way,we teleport an unknown state of a single-mode field too.In fact,it is shown that,in this regime,after applying some particular conditions,containing the interaction time of atom-field in the cavities,adjusting the involved frequencies,as well as the atom-field coupling in the model,if a proper measurement is performed on the state of the first qubit(the related field in the cavity),the unknown states of the qubit(field)can be teleported from the first qubit(cavity field)to the second qubit(cavity field),appropriately.We show that in both considered cases,the teleportation protocol is successfully performed with the maximum possible fidelity,1,and the acceptable success probability,0.25.展开更多
A hierarchy of non-isospectral Ablowitz-Kaup-Newell-Segur （AKNS） equations with self-consistent sources is derived. As a general reduction case, a hierarchy of non-isospectral nonlinear SchrSdinger equations （NLSE...A hierarchy of non-isospectral Ablowitz-Kaup-Newell-Segur （AKNS） equations with self-consistent sources is derived. As a general reduction case, a hierarchy of non-isospectral nonlinear SchrSdinger equations （NLSE） with selfconsistent sources is obtained. Moreover, a new non-isospectral integrable coupling of the AKNS soliton hierarchy with self-consistent sources is constructed by using the Kronecker product.展开更多
（E）-α-Iodovinyl sulfones 1 underwent the Sonogashira coupling reactions with terminal alkynes 2 in piperidine at room temperature in the presence of 5 mol% of Pd（PPh3）4 and 10 mol% of CuI to stereospecifically af...（E）-α-Iodovinyl sulfones 1 underwent the Sonogashira coupling reactions with terminal alkynes 2 in piperidine at room temperature in the presence of 5 mol% of Pd（PPh3）4 and 10 mol% of CuI to stereospecifically afford the corresponding （Z）-2-sulfonyl-substituted 1,3-enynes 3 in high yields.展开更多
基金Projects(12072102,12102129)supported by the National Natural Science Foundation of ChinaProject(DM2022B01)supported by the Key Laboratory of Safe Mining of Deep Metal Mines,Ministry of Education,ChinaProject(JZ-008)supported by the Six Talent Peaks Project in Jiangsu Province,China。
文摘In this study,a series of triaxial tests are conducted on sandstone specimens to investigate the evolution of their mechanics and permeability characteristics under the combined action of immersion corrosion and seepage of different chemical solutions.It is observed that with the increase of confining pressure,the peak stress,dilatancy stress,dilatancy stress ratio,peak strain,and elastic modulus of the sandstone increase while the Poisson ratio decreases and less secondary cracks are produced when the samples are broken.The pore pressure and confining pressure have opposite influences on the mechanical properties.With the increase of the applied axial stress,three stages are clearly identified in the permeability evolution curves:initial compaction stage,linear elasticity stage and plastic deformation stage.The permeability reaches the maximum value when the highest volumetric dilatancy is obtained.In addition,the hydrochemical action of salt solution with pH=7 and 4 has an obvious deteriorating effect on the mechanical properties and induces the increase of permeability.The obtained results will be useful in engineering to understand the mechanical and seepage properties of sandstone under the coupled chemical-seepage-stress multiple fields.
基金supported by grants from the National Natural Science Foundation of China (51478130)the Guangzhou Municipal Education Bureau’s Scientific Research Project, China (2024312217)+1 种基金the China Scholarship Council (201808440070)the 111 Project of China (D21021).
文摘This paper presents an improved level set method for topology optimization of geometrically nonlinear structures accounting for the effect of thermo-mechanical couplings.It derives a new expression for element coupling stress resulting from the combination of mechanical and thermal loading,using geometric nonlinear finite element analysis.A topological model is then developed to minimize compliance while meeting displacement and frequency constraints to fulfill design requirements of structural members.Since the conventional Lagrange multiplier search method is unable to handle convergence instability arising from large deformation,a novel Lagrange multiplier search method is proposed.Additionally,the proposed method can be extended to multi-constrained geometrically nonlinear topology optimization,accommodating multiple physical field couplings.
基金Natural Science Foundation of Shanxi Province,China (Grant No. 20210302123001)DNL Cooperation Fund,CAS (DNL202004),ICC CAS (Grant No. SCJCWRW-2023-21)Key Research and Development Program of Shanxi Province (202202090301020)。
文摘Photoelectrocatalytic coupling CO_(2)and volatile organic compounds (VOCs) is a promising green strategy for the synergistic conversion of the two carbon-containing resources to C2products.The catalytic efficiency is always at the mercy of chemical inertness of CO_(2)and the competitive hydrogen evolution of H2O.Herein,a modified g-C_(3)N_(4)/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely constructed.The Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol g^(-1)h^(-1).As revealed by in-situ characterizations and density functional theory calculations,CO_(2)and HCHO were absorbed at Zn site and N site,respectively.Then,*CO generated from CO_(2)and HCHO was converted to*CH_(3)O and*CHO on the dual-active-site heterojunction.The detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH_(3)O in electrocatalysis process.Apart from the“*CO+*CH_(3)O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic process.The selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO_(2)and HCHO simultaneously driven by light and electricity.
基金supported by the National Key R&D Program of China(No.2021YFB2011300)the National Natural Science Foundation of China(Nos.52275044,U2233212)。
文摘The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the compact integration of the OMP presents challenges inefficiently dissipating internal heat,leading to a performance degradation of the EHA due to ele-vated temperatures.Therefore,accurately modeling and predicting the internal thermal dynamicsof the OMP hold considerable significance for monitoring the operational condition of the EHA.In view of this,a modeling method considering cumulative thermal coupling was hereby proposed.Based on the proposed method,the thermal models of the motor and the pump were established,taking into account heat accumulation and transfer.Taking the leakage oil as the heat couplingpoint between the motor and the pump,the dynamic thermal coupling model of the OMP wasdeveloped,with the thermal characteristics of the oil considered.Additionally,the comparativeexperiments were conducted to illustrate the efficiency of the proposed model.The experimentalresults demonstrate that the proposed dynamic thermal coupling model accurately captured thethermal behavior of OMP,outperforming the static thermal parameter model.Overall,thisadvancement is crucial for effectively monitoring the health of EHA and ensuring flight safety.
基金supported by the National Natural Science Foundation of China(No.22275139)the Key Project of Natural Science Foundation of Tianjin City(No.22JCZDJC00510)The authors thank the Shanghai Synchrotron Radiation Facility of Experiment Assist System(https://cstr.cn/31124.02.SSRF.LAB)for the assistance on BL11B.
文摘Photo-reforming methanol into valuable chemicals represents an energetically sustainable alternative to conventional thermal catalysis,yet controlling-specific C-C coupling way still remains elusive.In this work,we report a sulfide-based photocatalytic paradigm,where atomic-level control of nickel species directly dictates reaction selectivity.The electrostatic constructing ZnIn_(2)S_(4)/Zn_(0.5)Cd_(0.5)S(ZIS/ZCS)heterostructures enable single atom Ni to facilitate ethylene glycol(EG)production with a rate of 11.2 mmol·gcat^(−1)·h^(−1),surpassing reported non-precious metal systems,whereas the Ni aggregates drive exclusive formaldehyde formation.The operando spectroscopy and density functional theory reveal dual roles of Ni as electron reservoir and chemical bond breakage inducers,lowering C-H activation barriers while stabilizing·CH2OH intermediates for cross-coupling.This interfacial configuration engineering creates an electron highway that couples carrier dissociation with radical recombination kinetics,achieving atom-economic steering of methanol oxidative valorization.The metal dispersion assisting catalysis correlation here provides a design blueprint for selective bond scission and reconstruction in sustainable organic synthesis.
基金supported by the Natural Science Foundation of Sichuan Province,China(Youth Science Foundation)(Grant No.2022NSFSC1952).
文摘The collective dynamic of a fractional-order globally coupled system with time delays and fluctuating frequency is investigated.The power-law memory of the system is characterized using the Caputo fractional derivative operator.Additionally,time delays in the potential field force and coupling force transmission are both considered.Firstly,based on the delay decoupling formula,combined with statistical mean method and the fractional-order Shapiro–Loginov formula,the“statistic synchronization”among particles is obtained,revealing the statistical equivalence between the mean field behavior of the system and the behavior of individual particles.Due to the existence of the coupling delay,the impact of the coupling force on synchronization exhibits non-monotonic,which is different from the previous monotonic effects.Then,two kinds of theoretical expression of output amplitude gains G and G are derived by time-delay decoupling formula and small delay approximation theorem,respectively.Compared to G,G is an exact theoretical solution,which means that G is not only more accurate in the region of small delay,but also applies to the region of large delay.Finally,the study of the output amplitude gain G and its resonance behavior are explored.Due to the presence of the potential field delay,a new resonance phenomenon termed“periodic resonance”is discovered,which arises from the periodic matching between the potential field delay and the driving frequency.This resonance phenomenon is analyzed qualitatively and quantitatively,uncovering undiscovered characteristics in previous studies.
文摘This study presents a comprehensive mechanical analysis of P110S oil tubing subjected to thermal and chemical coupling effects,with particular attention to the presence of rectangular corrosion defects.Drawing on the material’s stress–strain constitutive behavior,thermal expansion coefficient,thermal conductivity,and electrochemical test data,the research incorporates geometric nonlinearities arising from large deformations induced by corrosion.A detailed three-dimensional finite element(FE)model of the corroded P110S tubing is developed to simulate its response under complex loading conditions.The proposed model is rigorously validated through full-scale burst experiments and analytical calculations based on theoretical formulations.Building upon this validation,the Extended Finite Element Method(XFEM)and a failure criterion grounded in damage evolution mechanics are applied to investigate the mechanical behavior of the tubing under the coupled influences of temperature,stress,and chemical corrosion.Special emphasis is placed on the role of rectangular corrosion features in determining failure mechanisms.To further elucidate the impact of multiple interacting parameters,a sensitivity analysis is performed by integrating grey correlation theory with simulation outcomes.Based on these findings,the study systematically explores the elastic–plastic deformation process,crack initiation and propagation behavior,and the burst failure response of tubing specimens with varying axial lengths and depths of corrosion.The proposed methodology provides a robust predictive framework for petroleum engineers to evaluate fracture pressure,diagnose failure modes,assess operational risks,and optimize production strategies.
基金supported by the Science and Technology Project of the Hebei Education Department(JZX2023004)the Research Program of Local Science and Technology Development under the Guidance of Central China(246Z1808G)the support from the“Yuanguang”Scholar Program of Hebei University of Technology.
文摘The Lithium-ion deintercalation induces a significant volume change in battery electrodes during charging and discharging processes,which in turn generates a large diffusion-induced stress(DIS).This stress can cause microstructural damage,consequently degrading battery performance.This work simplifies the particles making up the electrode into spheres and studies the impact of the surface microstructure on the distribution of diffusion-induced stress.A mechanical-chemical coupling model was established to study the DIS in secondary particles,which were constructed by adding convex particles to the ball-shaped particle surfaces of the electrode material.It is observed that an increase in the number of convex particles results in a higher concentration of lithium ions within the electrode material,along with the first principal stresses within the material particles.In addition,the convex particles increase the local stresses around the ball-shaped particle surface.Therefore,a round surface on the electrode material particles is beneficial for preventing potential fractures.
基金supported by the National Key R&D Program of China(2024YFA1211004)the National Natural Science Foundation of China(22402150,22072107)+1 种基金the Natural Science Foundation of Shanghai(23ZR1464800,24ZR1470200)the Foundation of State Key Laboratory of Pollution Control and Resource Reuse(Tongji University)。
文摘Azoxy aromatics are extensively utilized in materials science,pharmaceuticals,and synthetic chemistry,but their controlled and environmentally-friendly synthesis has rarely been reported.Herein,a potential-mediated electrosynthesis strategy was developed by selective reduction of 4-nitrobenzyl alcohol(4-NBA)on Mn-doped Ni_(2)P nanosheets@nickel foam(Mn-Ni_(2)P/NF),enabling efficient N−N coupling to produce Azoxy with 100%selectivity at potentials of−0.6 to−0.8 V(vs.Hg/HgO).At more cathodic potentials,the product was converted to Azo and then to amino aromatics due to facilitated nitrogen hydrogenation.Additionally,the organic energetic material,5,5′-azotetrazolate,was also synthesized by anodic N−N coupling of 5-amino-1H-tetrazole on Cu(OH)_(2)nanowires@copper foam(Cu(OH)_(2)/CF).It bypassed harsh conditions(strong oxidants,high temperature,by-products separation,etc.)for the traditional synthesis of this class of materials.As a consequence,a two-electrode electrolyzer Cu(OH)_(2)/CF||Mn-Ni_(2)P/NF was assembled,allowing paired electrochemical N−N coupling into Azoxy and 5,5′-azotetrazolate.It achieves a current density of 50 mA cm^(−2)at a voltage of only 1.19 V,880 mV lower than the competitive water splitting.This electrolyzer can be efficiently driven by a 1.2 V solar panel with excellent yield and selectivity,paving the way for green synthesis of valuable chemicals through electrochemical N−N coupling strategies.
基金supported by the Major Research Instrument Development Project of the National Natural Science Foundation of China(82327810)the Foundation of the President of Hebei University(XZJJ202202)the Hebei Province“333 talent project”(A202101058).
文摘Within the prefrontal-cingulate cortex,abnormalities in coupling between neuronal networks can disturb the emotion-cognition interactions,contributing to the development of mental disorders such as depression.Despite this understanding,the neural circuit mechanisms underlying this phenomenon remain elusive.In this study,we present a biophysical computational model encompassing three crucial regions,including the dorsolateral prefrontal cortex,subgenual anterior cingulate cortex,and ventromedial prefrontal cortex.The objective is to investigate the role of coupling relationships within the prefrontal-cingulate cortex networks in balancing emotions and cognitive processes.The numerical results confirm that coupled weights play a crucial role in the balance of emotional cognitive networks.Furthermore,our model predicts the pathogenic mechanism of depression resulting from abnormalities in the subgenual cortex,and network functionality was restored through intervention in the dorsolateral prefrontal cortex.This study utilizes computational modeling techniques to provide an insight explanation for the diagnosis and treatment of depression.
基金supported by the National Office for Philosophy and Social Sciences(grant reference 22&ZD067).
文摘In the current situation of decelerating economic expansion,examining the digital economy(DE)as a novel economic model is beneficial for the local economy’s sustainable and high-quality development(HQD).We analyzed panel data from the Yellow River(YR)region from 2013 to 2021 and discovered notable spatial variances in the composite index and coupling coordination of the two systems.Specifically,the downstream region exhibited the highest coupling coordination,while the upstream region had the lowest.We identified that favorable factors such as economic development,innovation,industrial upgrading,and government intervention can bolster the coupling.Our findings provide a valuable framework for promoting DE and HQD in the YR region.
文摘Oxidative coupling of methane(OCM)is a catalytic partial oxidation process that directly converts methane into C_(2) products.For this high temperature reaction,understanding the radical behavior through experimental investigation is important in correlating the catalytic activity and the products.In this work,a spatial resolution online mass spectrometry(MS)system was developed and applied to a Mn-Na_(2)WO_(4)/SiO_(2) catalyzed OCM system.In addition to the residue gas analysis,the system obtained the distribution information of the reactants and products in the reactor.At various setting temperatures,all species online MS signals were collected at different positions,mapping the reaction activity covering parameters including temperature,time and space.The distribution behavior of the catalytic activity,selectivity,and apparent activation energy were kinetically analyzed.Selectivity and additional carbon balance analysis strongly supported the radical coupling model of OCM and indicated that after the catalytic bed layer,there is a significant length in the reactor(>2 mm)filled with radicals.Based on the result,a designed new method by tuning the temperature field in the reactor was found effectively to improve the catalytic activity,especially the C_(2) yield from 702 to 773℃.
基金supported by the National Natural Science Foundation of China(Grant No.11872236).
文摘The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials.The assumption used in the method that lithium is uniformly distributed in the active layer lacks quantitative evaluation,and the uniformity of concentration distribution is crucial for accurate in-situ measurements of concentration-related material properties and stress in bilayer electrodes.Therefore,this paper proposes a mechanical-electrochemical coupled model to study the lithium concentration distribution in the active layer during lithiation.This model includes lithium concentration diffusion and active layer deformation.By comparing experimental and simulated curvature evolution of the active layer during lithiation and delithiation,the reliability of this simulation model is verified.We then derive the precise concentration distribution inside the active layer and suggest using relative error to quantitatively evaluate the uniformity of lithium concentration in the active layer.Results show that a low relative error in lithium concentration can be achieved in the middle region of the active layer.Additionally,the effects of different rates and geometric parameters on the lithium concentration distribution in the active layer are discussed.Results indicate that reduced rates,thinner active layers,shorter active layer lengths,and increased spacing between the working and counter electrodes can lead to a more uniform distribution of lithium concentration in the active layer.These insights help improve experimental methods and equipment,promoting uniform distribution of lithium in the active layer and enhancing measurement accuracy.
基金supported by the foundation of the Research Fund for Commonweal Trades (Meteorology) (Grant No. GYHY201006039)the International Cooperation Project of the Department of Science and Technology of Sichuan Province (Grant No. 2009HH0005)
文摘A debris flow forecast model based on a water-soil coupling mechanism that takes the debrisflow watershed as a basic forecast unit was established here for the prediction of disasters at the watershed scale.This was achieved through advances in our understanding of the formation mechanism of debris flow.To expand the applicable spatial scale of this forecasting model,a method of identifying potential debris flow watersheds was used to locate areas vulnerable to debris flow within a forecast region.Using these watersheds as forecasting units and a prediction method based on the water-soil coupling mechanism,a new forecasting method of debris flow at the regional scale was established.In order to test the prediction ability of this new forecasting method,the Sichuan province,China was selected as a study zone and the large-scale debris flow disasters attributable to heavy rainfall in this region on July 9,2013 were taken as the study case.According to debris flow disaster data on July 9,2013 which were provided by the geo-environmental monitoring station of Sichuan province,there were 252 watersheds in which debris flow events actually occurred.The current model predicted that 265 watersheds were likely to experience a debris flow event.Among these,43 towns including 204 debrisflow watersheds were successfully forecasted and 24 towns including 48 watersheds failed.The false prediction rate and failure prediction rate of thisforecast model were 23% and 19%,respectively.The results show that this method is more accurate and more applicable than traditional methods.
基金supported by the National Natural Science Foundation of China(Grant Nos.U2141254 and U23B6009)。
文摘In this paper,a high-fidelity computational fluid dynamics(CFD)and rigid body dynamics(RBD)coupled platform for virtual flight simulation is developed to investigate the flight stability of fixed canard dual-spin projectile.The platform's reliability is validated by reproducing the characteristic resonance instability of such projectiles.By coupling the solution of the Unsteady Reynolds-Averaged Navier-Stokes equations and the seven-degree-of-freedom RBD equations,the virtual flight simulations of fixed canard dual-spin projectiles at various curvature trajectories are achieved,and the dynamic mechanism of the trajectory following process is analyzed.The instability mechanism of the dynamic instability during trajectory following process of the fixed canard dual-spin projectile is elucidated by simulating the rolling/coning coupled forced motion,and subsequently validated through virtual flight simulations.The findings suggest that an appropriate yaw moment can drive the projectile axis to precession in the tangential direction of the trajectory,thereby enhancing the trajectory following stability.However,the damping of the projectile attains its minimum value when the forward body equilibrium rotational speed(-128 rad/s)is equal to the negative of the fast mode frequency of the projectile.Insufficient damping leads to the fixed canard dual-spin projectile exiting the dynamic stability domain during the trajectory following,resulting in weakly damped instability.Keeping the forward body not rotating or increasing the spin rates to-192 rad/s can enhance the projectile's damping,thereby improving its dynamic stability.
基金supported by the National Natural Science Foundation of China (Grant No.52109125)the Natural Science Foundation of Jiangsu Province,China (Grant No.BK20231217)the Key Laboratory of Geomechanics and Geotechnical Engineering Safety,Chinese Academy of Sciences (Grant No.SKLGME023001).
文摘The coupling effects of rainfall,earthquake,and complex topographic and geological conditions complicate the dynamic responses and disasters of slope-tunnel systems.For this,the large-scale shaking table tests were carried out to explore the dynamic responses of steep bedding slope-tunnel system under the coupling effect of rainfall and earthquake.Results show that the slope surface and elevation amplification effect exhibit pronounced nonlinear change caused by the tunnel and weak interlayers.When seismic wave propagates to tunnels,the weak interlayers and rock intersecting areas present complex wave field distribution characteristics.The dynamic responses of the slope are influenced by the frequency,amplitude,and direction of seismic waves.The acceleration amplification coefficient initially rises and then falls as increasing seismic frequency,peaking at 20 Hz.Additionally,the seismic damage process of slope is categorized into elastic(2-3 m/s^(2)),elastoplastic(4-5 m/s^(2))and plastic damage stages(≥6.5 m/s^(2)).In elastic stage,ΔMPGA(ratio of acceleration amplification factor)increases with increasing seismic intensity,without obvious strain distribution change.In plastic stage,ΔMPGA begins to gradually plummet,and the strain is mainly distributed in the damaged area.The modes of seismic damage in the slope-tunnel system are mainly of tensile failure of the weak interlayer,cracking failure of tunnel lining,formation of persistent cracks on the slope crest and waist,development and outward shearing of the sliding mass,and buckling failure at the slope foot under extrusion of the upper rock body.This study can serve as a reference for predicting the failure modes of tunnel-slope system in strong seismic regions.
基金Beijing Academy of Science and Technology (BJAST) supported this worksupported by the Financial Program of BJAST (Nos. 24CE-BGS-02, 24CA010-01, and 23CB106)
文摘Cells live in a multiphysics-coupled microenvironment in vivo,in which electric fields(EFs)and mechanical cues are the most essential induction signals.The regulatory effects of EFs and stiffness on cells have been independently demonstrated.However,how cells respond to electromechanical coupling cues remains mysterious.In this study,an electro-stiffness-coupled chip system was designed and fabricated,freely integrating and precisely controlling EF strength and the mechanical stiffness applied to cells across the physiological spectrum.Utilizing the innovative bioreactor,it was observed that electromechanical coupling stimulations can shape cancer cell morphology and cytoskeleton into a unique anteroposterior polarization state and orient cancer cell migration in a voltage-dependent manner through cytoskeleton-associated mechanisms.Moreover,the mechanical stiffness regulated cancer cell susceptibility to EFs,and the orientation effect of EFs on cells required a stiffness threshold.Furthermore,transforming growth factor-β1 suppressed the orientation of cancer cells induced by electromechanical coupling signals and showed a splitting effect on the directionality and velocity of cancer cell migration,indicating a comprehensive cross-talk of biochemical–electromechanical signals.Together with the dual-physical bioreactor we designed,these findings provide a robust and convenient platform for exploring cellular responses to electro-stiffness coupling signals,reveal the biophysical mechanisms of cell polarization and migration from the perspective of electromechanical coupling,and lay a promising foundation for biophysical-based cell manipulation and therapeutic interventions.
文摘In this paper,we develop the teleportation scheme in[Zheng in Phys Rev A 69,064302,2004],in the sense that,we work in the strong atom-field coupling regime wherein the rotating wave approximation(RWA)is no longer valid.To achieve the purpose,a scheme consisting of a qubit interacting with a single-mode quantized field is described via the Rabi model(counter rotation terms are taken into account).Our first aim is to teleport an unknown atomic state of a qubit(which interacts with the quantized field in a cavity)to a second qubit(exists in another distant cavity field),beyond the RWA and without the Bell-state measurement method.In the continuation,in a similar way,we teleport an unknown state of a single-mode field too.In fact,it is shown that,in this regime,after applying some particular conditions,containing the interaction time of atom-field in the cavities,adjusting the involved frequencies,as well as the atom-field coupling in the model,if a proper measurement is performed on the state of the first qubit(the related field in the cavity),the unknown states of the qubit(field)can be teleported from the first qubit(cavity field)to the second qubit(cavity field),appropriately.We show that in both considered cases,the teleportation protocol is successfully performed with the maximum possible fidelity,1,and the acceptable success probability,0.25.
基金Project supported by the Research work of Liaoning Provincial Development of Education, China (Grant No 2008670)
文摘A hierarchy of non-isospectral Ablowitz-Kaup-Newell-Segur （AKNS） equations with self-consistent sources is derived. As a general reduction case, a hierarchy of non-isospectral nonlinear SchrSdinger equations （NLSE） with selfconsistent sources is obtained. Moreover, a new non-isospectral integrable coupling of the AKNS soliton hierarchy with self-consistent sources is constructed by using the Kronecker product.
基金the National Natural Science Foundation of China(No.20462002)Natural Science Foundation of Jiangxi Province(No.0420015)for financial support.
文摘（E）-α-Iodovinyl sulfones 1 underwent the Sonogashira coupling reactions with terminal alkynes 2 in piperidine at room temperature in the presence of 5 mol% of Pd（PPh3）4 and 10 mol% of CuI to stereospecifically afford the corresponding （Z）-2-sulfonyl-substituted 1,3-enynes 3 in high yields.
