胶结充填体作为人工矿柱常受到邻近矿房开采的爆破扰动,严重影响其稳定性。基于KCC(Karagozian and Case Concrete)本构模型和ALE(Arbitrary Lagrangian-Eulerian)流固耦合算法,采用LS-DYNA软件开展胶结充填体受邻近矿房爆破扰动的数值...胶结充填体作为人工矿柱常受到邻近矿房开采的爆破扰动,严重影响其稳定性。基于KCC(Karagozian and Case Concrete)本构模型和ALE(Arbitrary Lagrangian-Eulerian)流固耦合算法,采用LS-DYNA软件开展胶结充填体受邻近矿房爆破扰动的数值模拟研究,考虑不同边孔间距(0.6、1.2、1.8、2.4 m)及养护龄期(14、21、28 d)影响,揭示充填体中爆破波传播规律,探究爆破扰动对胶结充填体的动力响应及其失稳破坏情况。结果表明:邻近采场爆破对胶结充填体的破坏损伤主要集中在边界处,为提高矿石回收率并保证充填体安全,建议采用边孔间距1.2 m方案;矿山爆破开采中充填体至少需要养护21 d;低龄期充填体矿柱顶底部区域是整个矿柱中的薄弱部分,易发生失稳,应予以重点监测。展开更多
The mechanical behaviour of a quasi-brittle material,i.e.Pietra Serena sandstone,was investigated both numerically and experimentally in order to build a reliable numerical modelling system applicable to more complex ...The mechanical behaviour of a quasi-brittle material,i.e.Pietra Serena sandstone,was investigated both numerically and experimentally in order to build a reliable numerical modelling system applicable to more complex cases.The Karagozian and Case concrete(KCC)model was exploited as the material constitutive law and a new method to utilise this model for efficient and accurate simulation of quasibrittle materials is discussed.The capability of this model is evaluated by comparing the results of the numerical simulations with the corresponding experimental results,and the method itself is critically assessed.展开更多
Uniform Pd nanoparticles immobilized on N-(3-trimethoxysilylpropyl)diethylenetriamine (PDETA)-functionalized fibrous silica KCC-1 (Pd/KCC-1-PDETA) were prepared with a mean Pd particle size of 2.8 nm. After characteri...Uniform Pd nanoparticles immobilized on N-(3-trimethoxysilylpropyl)diethylenetriamine (PDETA)-functionalized fibrous silica KCC-1 (Pd/KCC-1-PDETA) were prepared with a mean Pd particle size of 2.8 nm. After characterization using powder X-ray diffraction, X-ray photoelectron spectroscopy, and N2 adsorption-desorption isotherms, Pd/KCC-1-PDETA was used as catalyst for additive-free dehydrogenation of formic acid to produce H2. Pd nanoparticle catalysts supported on two other mesoporous silica materials (MSF and KIT-6) were also synthesized to examine how the support affects the reaction. Among the three catalysts, Pd/KCC-1-PDETA exhibited significant catalytic activity (a turnover frequency of 332 h?1 at 323 K and 100% selectivity towards hydrogen), owing to the unique fibrous morphology of KCC-1 and the presence of amine groups that reduced the Pd particle size and improved the access of reactant to the catalytically active Pd sites. The influence of Pd loading (2–10 wt.%), reaction temperature, and reaction time was also examined for the dehydrogenation reaction. Pd/KCC-1-PDETA was recovered easily after the reaction and showed good reusability up to five times without any significant loss in catalytic performance.展开更多
文摘胶结充填体作为人工矿柱常受到邻近矿房开采的爆破扰动,严重影响其稳定性。基于KCC(Karagozian and Case Concrete)本构模型和ALE(Arbitrary Lagrangian-Eulerian)流固耦合算法,采用LS-DYNA软件开展胶结充填体受邻近矿房爆破扰动的数值模拟研究,考虑不同边孔间距(0.6、1.2、1.8、2.4 m)及养护龄期(14、21、28 d)影响,揭示充填体中爆破波传播规律,探究爆破扰动对胶结充填体的动力响应及其失稳破坏情况。结果表明:邻近采场爆破对胶结充填体的破坏损伤主要集中在边界处,为提高矿石回收率并保证充填体安全,建议采用边孔间距1.2 m方案;矿山爆破开采中充填体至少需要养护21 d;低龄期充填体矿柱顶底部区域是整个矿柱中的薄弱部分,易发生失稳,应予以重点监测。
基金supported by the National Natural Science Foundation of China (220925310, U1162102)the Specialized Research Fund for the Doc-toral of Higher Education (2012007613000)+1 种基金the National Basic Research Program of China (973 Program, 2012BAE05B02)the Shanghai Lead-ing Academic Discipline Project (B409)~~
文摘The mechanical behaviour of a quasi-brittle material,i.e.Pietra Serena sandstone,was investigated both numerically and experimentally in order to build a reliable numerical modelling system applicable to more complex cases.The Karagozian and Case concrete(KCC)model was exploited as the material constitutive law and a new method to utilise this model for efficient and accurate simulation of quasibrittle materials is discussed.The capability of this model is evaluated by comparing the results of the numerical simulations with the corresponding experimental results,and the method itself is critically assessed.
基金supported by C1 Gas Refinery Program(2015M3D3A1A01064899)by the Ministry of Science,ICT&Future PlanningBasic Science Research Program through the National Research Foundation of Korea funded by the Ministry of Education(Grant No.:NRF-2015R1A4A1042434)
文摘Uniform Pd nanoparticles immobilized on N-(3-trimethoxysilylpropyl)diethylenetriamine (PDETA)-functionalized fibrous silica KCC-1 (Pd/KCC-1-PDETA) were prepared with a mean Pd particle size of 2.8 nm. After characterization using powder X-ray diffraction, X-ray photoelectron spectroscopy, and N2 adsorption-desorption isotherms, Pd/KCC-1-PDETA was used as catalyst for additive-free dehydrogenation of formic acid to produce H2. Pd nanoparticle catalysts supported on two other mesoporous silica materials (MSF and KIT-6) were also synthesized to examine how the support affects the reaction. Among the three catalysts, Pd/KCC-1-PDETA exhibited significant catalytic activity (a turnover frequency of 332 h?1 at 323 K and 100% selectivity towards hydrogen), owing to the unique fibrous morphology of KCC-1 and the presence of amine groups that reduced the Pd particle size and improved the access of reactant to the catalytically active Pd sites. The influence of Pd loading (2–10 wt.%), reaction temperature, and reaction time was also examined for the dehydrogenation reaction. Pd/KCC-1-PDETA was recovered easily after the reaction and showed good reusability up to five times without any significant loss in catalytic performance.
