In the present work,by virtue of the synergistic and independent effects of Janus structure,an asymmetric nickel-chain/multiwall carbon nanotube/polyimide(Ni/MWCNTs/PI)composite foam with absorption-dominated electrom...In the present work,by virtue of the synergistic and independent effects of Janus structure,an asymmetric nickel-chain/multiwall carbon nanotube/polyimide(Ni/MWCNTs/PI)composite foam with absorption-dominated electromagnetic interference(EMI)shielding and thermal insulation performances was successfully fabricated through an ordered casting and directional freeze-drying strategy.Water-soluble polyamic acid(PAA)was chosen to match the oriented freeze-drying method to acquire oriented pores,and the thermal imidization process from PAA to PI exactly eliminated the interface of the multilayered structure.By controlling the electro-magnetic gradient and propagation path of the incident microwaves in the MWCNT/PI and Ni/PI layers,the PI composite foam exhibited an efficient EMI SE of 55.8 dB in the X-band with extremely low reflection characteristics(R=0.22).The asymmetric conductive net-work also greatly preserved the thermal insulation properties of PI.The thermal conductivity(TC)of the Ni/MWCNT/PI composite foam was as low as 0.032 W/(m K).In addition,owing to the elimination of MWCNT/PI and Ni/PI interfaces during the thermal imidization process,the composite foam showed satisfactory compressive strength.The fabricated PI composite foam could provide reliable electromagnetic protection in complex applications and withstand high temperatures,which has great potential in cuttingedge applications such as advanced aircraft.展开更多
MXene-based composite films are regarded as up-and-coming multifunctional electromagnetic interference(EMI)shielding materials.However,the conflict between strong mechanical properties and high electrical conductivity...MXene-based composite films are regarded as up-and-coming multifunctional electromagnetic interference(EMI)shielding materials.However,the conflict between strong mechanical properties and high electrical conductivity hinders their application in modern integrated electronics.Herein,in virtue of density-induced sedimentation,robust and multifunctional liquid metals-reinforced cellulose nanofibers(CNF)/MXene(LMs-CNF/MXene)composite films with Janus structure are fabricated by one-step vacuum-assisted filtration method.Not only does the nacre-like structure of the CNF/MXene layer not destroy,but the deposited liquid metals(LMs)layer can serve as conductive potentiation.Due to the special Janus structure,an“absorption-reflection-reabsorption”shielding process is created in LMs-CNF/MXene composite film to strengthen EMI shielding performance.Its shielding effectiveness can reach 51.9 dB at -27μm,and the reflection coefficient falls to 0.89,below those of reported MXene-based shielding films.Meanwhile,the CNF/MXene layer can endow composite films with excellent mechanical properties with a super tensile strength of 110.3 MPa.Notably,the LMs-CNF/MXene EMI shielding composite films also integrate outstanding photo-/electrothermal conversion performances,which can effectively deice outdoors.The robust LMs-CNF/MXene EMI shielding composite films with satisfying photo-/electrothermal performances have extensive application prospects,such as aerospace,wearable electronics,and portable electronics.展开更多
Hierarchically three-dimensional(3D)materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects.In this work,α-Fe_(2)O_(3)@ZrO_(2)with core-shell structu...Hierarchically three-dimensional(3D)materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects.In this work,α-Fe_(2)O_(3)@ZrO_(2)with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method.Following calcination,3D ZrO_(2)/Fe_(3)O_(4)/C nanocomposites with Janus structure have been successfully synthesized.By controlling the lattice match and mismatch in both processes,a core-shell structure ofα-Fe_(2)O_(3)@ZrO_(2)and Janus structure of ZrO_(2)/Fe_(3)O_(4)have been well-define performed.The composite material ZrO_(2)/Fe_(3)O_(4)/C-700 has a minimum reflection loss(RLmin)of−67.4 dB at a thickness of 2.0 mm.The effective absorption bandwidth(EAB)at a thickness of 2.4 mm is 6.0 GHz(11.0-17.0 GHz).This study provides a novel strategy for fabricating high-efficiency electromagnetic wave absorption materials with dual synergistic effects in nanosized scale.展开更多
The accurate delivery of nanoparticles and organic small molecule drugs remains a serious challenge in nanoparticle-based tumor therapy.Dual-targeted therapy combining tumor cell targeting and organelle targeting is a...The accurate delivery of nanoparticles and organic small molecule drugs remains a serious challenge in nanoparticle-based tumor therapy.Dual-targeted therapy combining tumor cell targeting and organelle targeting is an effective solution.Here,an anticancer nanoformulation accurate delivery system was prepared using hyaluronic acid (HA) targeting CD44 receptors on the surface of tumor cells and IR780iodine (IR780) targeting mitochondrial for delivery.The system is based on an ultra-small Janus structured inorganic sensitizer TiO_(2-x)@NaGdF_(4) nanoparticles (TN NPs) prepared by one-step pyrolysis,further loaded with organic small molecule acoustic sensitizer IR780 and mitochondrial hexokinase Ⅱ inhibitor lonidamine (LND),followed by encapsulation of HA.Ultra-small size nanoparticles exhibit strong tissue penetration,tumor inhibition and in vivo metabolism.Under ultrasound radiation,TN NPs and IR780could produce a synergistic effect,effectively increased the efficiency of reactive oxygen species (ROS)production.Meanwhile,the released IR780 could smoothly target the mitochondria,and the ROS produced by IR780 can destroy the mitochondrial structure and disrupt the mitochondrial respiration.LND could inhibit the energy metabolism of tumor cells by reducing the activity of hexokinase Ⅱ (HK Ⅱ),which further accelerates the process of apoptosis.Furthermore,since the Janus structure allows the integration of multifunctional components into a single system,TN NPs can not only serve as an acoustic sensitizer to generate ROS,but the Gd element contained can also act as the nuclear magnetic resonance (MR)imaging contrast agent,suggesting that the nanoformulation can enable imaging-guided diagnosis and therapy.In conclusion,a new scheme to enhance sonodynamic therapy (SDT) and chemotherapy synergistically is proposed here based on ultra-small dual-targeted nanoformulation with Janus structure in the ultrasound radiation environment.展开更多
Photoelectrochemical water splitting using solar energy,generating oxygen and hydrogen is one of the clean fuel production processes.Inspired by surface-dependent characteristics of Janus structures,a newly designed J...Photoelectrochemical water splitting using solar energy,generating oxygen and hydrogen is one of the clean fuel production processes.Inspired by surface-dependent characteristics of Janus structures,a newly designed Janus monolayer Silicon Phosphorous Arsenide(SiPAs)was analyzed with Density Functional Theory(DFT)methods.Hybrid exchange-correlation functional(HSE06)combined with Wannier90-based analysis for electronic and optical properties of SiPAs reveals that it can act as a photocatalyst.SiPAs show an indirect bandgap of 1.88 eV,absorbing visible light range is 350 to 500 nm.The phonon spectrum confirms dynamic stability.The exciton binding energy is computed with GW/BSE methods.The electronic band edge positions are at-5.75 and-4.43 eV,perfectly straddling the water redox potentials.Interestingly the strain application modifies the bandgap and also non-homogenously widens the absorption band.A novel range of photocatalyst designs with Group IV-V elements with great promise for water-splitting,photovoltaic,and narrow bandgap semiconductor(optoelectronics)applications may be feasible.展开更多
This study presents the synthesis of a ternary CeO_(2)-AuNR-Cu_(2)O Janus structure with dual Schottky junctions,achieved by sequential growth of CeO_(2) and Cu_(2)O crystal domains on AuNR seeds.The dual Schottky jun...This study presents the synthesis of a ternary CeO_(2)-AuNR-Cu_(2)O Janus structure with dual Schottky junctions,achieved by sequential growth of CeO_(2) and Cu_(2)O crystal domains on AuNR seeds.The dual Schottky junctions and the Janus-type CeO_(2)-Cu_(2)O P-N heterostructure led to significant enhancement in charge separation and suppress of the electron-hole recombination.The localized surface plasmon resonance(LSPR)effect of AuNR and the Z-scheme electron transfer pathway further boost the photocatalytic performance.This enhancement was demonstrated through the model photocatalytic degradation of methylene blue(MB)in aqueous solution.The proposed strategy not only improves photocatalytic efficiency but also provides insights into electron migration mechanisms,offering new opportunities for advanced nanostructure development in various applications.展开更多
Flexible multifunctional polymer-based electromagnetic interference(EMI)shielding composite films have important application values in the fields of 5G communication technology,wearable electronic devices and artifici...Flexible multifunctional polymer-based electromagnetic interference(EMI)shielding composite films have important application values in the fields of 5G communication technology,wearable electronic devices and artificial intelligence.In this work,Fe_(3)O_(4)/polyamic acid(PAA)nanofiber films are prepared by in-situ polymerization and electrospinning technology,and Ti_(3)C_(2)T_(x)nanosheets are deposited on the surface of the Fe_(3)O_(4)/PAA nanofiber films via vacuum-assisted filtration.Then,Janus Ti_(3)C_(2)T_(x)-(Fe_(3)O_(4)/polyimide(PI))composite films are obtained by thermal imidization.The two sides of the Janus films exhibit completely different properties.The Fe_(3)O_(4)/PI side has excellent hydrophobicity and insulation property,and the Ti_(3)C_(2)T_(x)side has hydrophilicity and terrific conductivity.When the mass fraction of Ti_(3)C_(2)T_(x)is 80 wt.%,the Janus Ti_(3)C_(2)T_(x)-(Fe_(3)O_(4)/PI)composite film has excellent EMI shielding performances and mechanical properties,with EMI shielding effectiveness,tensile strength and Young’s modulus reaching 66 dB,114.5 MPa and 5.8 GPa,respectively.At the same time,electromagnetic waves show different absorption shielding effectiveness(SEA)when incident from two sides of the Janus films.When the electromagnetic waves are incident from the Fe_(3)O_(4)/PI side,the SEA of the Janus film is 58 dB,much higher than that when the electromagnetic waves are incident from the Ti_(3)C_(2)T_(x)side(39 dB).In addition,the Ti_(3)C_(2)T_(x)side of the Janus Ti_(3)C_(2)T_(x)-(Fe_(3)O_(4)/PI)composite films also has excellent electrothermal and photothermal conversion performances.When the applied voltage is 4 V,the stable surface temperature reaches 108°C;when it is irradiated by simulated sunlight with power density of 200 mW/cm2,the stable surface temperature reaches 95℃.展开更多
Flexible multifunctional polymer-based electromagnetic interference(EMI)shielding composite films play a pivotal role in 5 G communication technology,smart wearables,automotive electronics,and aerospace.In this work,(...Flexible multifunctional polymer-based electromagnetic interference(EMI)shielding composite films play a pivotal role in 5 G communication technology,smart wearables,automotive electronics,and aerospace.In this work,(Ti_(3)C_(2)T_(x) MXene/cellulose nanofibers(CNF)-(hydroxy‑functionalized BNNS(BNNS-OH)/CNF)composite films(TBCF)with Janus structure are prepared via vacuum-assisted filtration of BNNS-OH/CNF and Ti_(3)C_(2)T_(x)/CNF suspension by one after another.Then ionic bonding-strengthened TBCF(ITBCF)is obtained by Ca^(2+)ion infiltration and cold-pressing technique.The Janus structure endows ITBCF with the unique“conductive on one side and insulating on the other”property.When the mass ratio of Ti_(3)C_(2)T_(x) and BNNS is 1:1 and the total mass fraction is 70 wt.%,the electrical conductivity(σ)of the Ti_(3)C_(2)T_(x)/CNF side of ITBCF reaches 166.7 S/cm,while the surface resistivity of the BNNS-OH/CNF side is as high as 304 MΩ.After Ca^(2+)ion infiltration,the mechanical properties of ITBCF are significantly enhanced.The tensile strength and modulus of ITBCF are 73.5 MPa and 15.6 GPa,which are increased by 75.9%and 46.2%compared with those of TBCF,respectively.Moreover,ITBCF exhibits outstanding EMI shielding effectiveness(SE)of 57 dB and thermal conductivity(λ)of 9.49 W/(m K).In addition,ITBCF also presents excellent photothermal and photoelectric energy conversion performance.Under simulated solar irradiation with a power density of 120 mW/cm^(2),the surface stabilization temperature reaches up to 65.3°C and the maximum steady state voltage reaches up to 58.2 mV.展开更多
Quasi-solid electrolytes(QSEs)based on nanoporous materials are promising candidates to construct high-performance Limetal batteries(LMBs).However,simultaneously boosting the ionic conductivity(σ)and lithium-ion tran...Quasi-solid electrolytes(QSEs)based on nanoporous materials are promising candidates to construct high-performance Limetal batteries(LMBs).However,simultaneously boosting the ionic conductivity(σ)and lithium-ion transference number(t^(+)) of liquid electrolyte confined in porous matrix remains challenging.Herein,we report a novel Janus MOFLi/MSLi QSEs with asymmetric porous structure to inherit the benefits of both mesoporous and microporous hosts.This Janus QSE composed of mesoporous silica and microporous MOF exhibits a neat Li^(+) conductivity of 1.5.10^(–4)S cm^(−1) with t^(+) of 0.71.A partially de-solvated structure and preference distribution of Li^(+)near the Lewis base O atoms were depicted by MD simulations.Meanwhile,the nanoporous structure enabled efficient ion flux regulation,promoting the homogenous deposition of Li^(+).When incorporated in Li||Cu cells,the MOFLi/MSLi QSEs demonstrated a high Coulombic efficiency of 98.1%,surpassing that of liquid electrolytes(96.3%).Additionally,NCM 622||Li batteries equipped with MOFLi/MSLi QSEs exhibited promising rate performance and could operate stably for over 200 cycles at 1 C.These results highlight the potential of Janus MOFLi/MSLi QSEs as promising candidates for next-generation LMBs.展开更多
Several natural organism can change shape under external stimuli. These natural phenomena have inspired a vast amount of research on exploration and implementation of reconfigurable shape transformation. The Janus str...Several natural organism can change shape under external stimuli. These natural phenomena have inspired a vast amount of research on exploration and implementation of reconfigurable shape transformation. The Janus structure is a promising approach to achieve shape transformation based on its heterogeneous chemical or physical properties on opposite sides.However, the heterogeneity is generally realized by multi-step processing, different materials,and/or different processing parameters. Here, we present a simple and flexible method of producing p H-sensitive Janus microactuators from a single material, using the same laser printing parameters. These microactuators exhibit reversible structural deformations with large bending angles of ~31°and fast response(~0.2 s) by changing the p H value of the aqueous environment. Benefited from the high flexibility of the laser printing technique and the spatial arrangements, pillar heights, and bending directions of microactuators are readily controlled,enabling a variety of switchable ordered patterns and complex petal-like structures on flat surfaces and inside microchannels. Finally, we explore the potential applications of this method in information encryption/decryption and microtarget capturing.展开更多
The Janus MoSSe and alloy MoS_(x)Se_((1-x)),belonging to the family of two-dimensional(2D)transition metal dichalcogenides(TMDs),have gained significant attention for their potential applications in nanotechnology.The...The Janus MoSSe and alloy MoS_(x)Se_((1-x)),belonging to the family of two-dimensional(2D)transition metal dichalcogenides(TMDs),have gained significant attention for their potential applications in nanotechnology.The unique asymmetric structure of Janus MoSSe provides intriguing possibilities for tailored applications.The alloy MoS_(x)Se_((1-x))offers a tunable composition,allowing for the fine-tuning of the properties to meet specific requirements.These materials exhibit remarkable mechanical,electrical,and optical properties,including a tunable band gap,high absorption coefficient,and photoconductivity.The vibrational and magnetic properties also make it a promising candidate for nanoscale sensing and magnetic storage applications.Properties of these materials can be precisely controlled through different approaches such as size-dependent properties,phase engineering,doping,alloying,defect and vacancy engineering,intercalation,morphology,and heterojunction or hybridisation.Various synthesis methods for 2D Janus MoSSe and alloy MoS_(x)Se_((1-x))are discussed,including hydro/solvothermal,chemical vapour transport,chemical vapour deposition,physical vapour depositio,and other approaches.The review also presents the latest advancements in Janus and alloy MoSSe-based applications,such as chemical and gas sensors,surface-enhanced Raman spectroscopy,field emission,and energy storage.Moreover,the review highlights the challenges and future directions in the research of these materials,including the need for improved synthesis methods,understanding of their stability,and exploration of new applications.Despite the early stages of research,both the MoSSe-based materials have shown significant potential in various fields,and this review provides valuable insights for researchers and engineers interested in exploring its potential.展开更多
Background:Excessive exudate secreted from chronic wounds often leads to overhydration and infection.Although a variety of dressings are currently available in clinical applications,they frequently fail to provide mul...Background:Excessive exudate secreted from chronic wounds often leads to overhydration and infection.Although a variety of dressings are currently available in clinical applications,they frequently fail to provide multifunction to promote chronic wound healing.The dressings with a Janus structure,featuring distinct properties on each side,are potential to improve wound healing.Methods:Composite dressings with a Janus structure were fabricated,comprising freeze-dried polycaprolactone(PCL)electrospun membrane and alginate-based hydrogel.The PCL fibrous membrane provided air permeability,while the hydrogel loaded with Deferoxamine,composed of alginate and poly(N-isopropylacrylamide)(PNIPAM),exhibited hygroscopic properties.The inclusion of PNIPAM imparted thermo-responsivity.Results:The hydrogel(thickness of 2.778±0.082 mm)exhibited a robust adhesion to the fiber membrane(thickness of 0.261±0.041 mm).For ANDC(Alginate-PNIPAM hydrogel with Deferoxamine/PCL membrane)samples,the water vapor transmission rate(WVTR)was measured to be 3364.80±23.23 g∙m−2∙day−1 and the swelling ratio at 2 h was determined to be 1179±125%.The thermo-responsivity of ANDC samples manifested in an increased swelling rate,escalating from 797±189%at 37°C to 1132±147%at 4°C.The elastic modulus was assessed for lyophilized and rehydrated ANDC sample.When theωof the rheometer rotor was decreased from 10 rad/s to 0.1 rad/s,the lyophilized dressing exhibited a decrease from 2.65±0.01 MPa to 1.80±0.90 MPa,while the rehydrated dressing demonstrated an increase from 133.65±55.68 Pa to 264.23±141.71 Pa.The pro-healing properties of the dressings were evaluated using full-thickness skin defect model on SD rats,and a circular wound of diameter 10 mm healed completely by day 12.Conclusion:The dressings not only protected the wound and absorbed excess exudate,but also demonstrated nondestructive peelability upon cooling,providing a novel approach for accelerating wound healing and management.展开更多
The detection and removal of volatile organic compounds(VOCs) are of great importance to reduce the risk of indoor air quality concerns. This study reports the rational synthesis of a dual-functional Janus nanostructu...The detection and removal of volatile organic compounds(VOCs) are of great importance to reduce the risk of indoor air quality concerns. This study reports the rational synthesis of a dual-functional Janus nanostructure and its feasibility for simultaneous detection and removal of VOCs.The Janus nanostructure was synthesized via an anisotropic growth method, composed of plasmonic nanoparticles,semiconductors, and metal organic frameworks(e.g.,Au@ZnO@ZIF-8). It exhibits excellent selective detection to formaldehyde(HCHO, as a representative VOC) at room temperature over a wide range of concentrations(from 0.25 to100 ppm), even in the presence of water and toluene molecules as interferences. In addition, HCHO was also found to be partially oxidized into non-toxic formic acid simultaneously with detection. The mechanism underlying this technology was unraveled by both experimental measurements and theoretical calculations: ZnO maintains the conductivity, while ZIF-8 improves the selective gas adsorption; the plasmonic effect of Au nanorods enhances the visible-light-driven photocatalysis of ZnO at room temperature.展开更多
The development of excellent catalyst to achieve photocatalytic syngas production from CO_(2) and H_(2)O is a prospective and sustainable strategy to alleviate environment and energy crisis. In this study, a unique Ja...The development of excellent catalyst to achieve photocatalytic syngas production from CO_(2) and H_(2)O is a prospective and sustainable strategy to alleviate environment and energy crisis. In this study, a unique Janus PdZn-Co catalyst is prepared by annealed the Pd/IRMOF-3(Co, Zn) precursor. Due to the strong interaction, the electron transfers from PdZn terminal to Co terminal in the Janus structure. The electron-received Co terminal facilitates Co sites coordinate with the electrophilic C atom of CO_(2) and the electron-donated PdZn center is easier to coordinate with nucleophilic O atoms of H_(2)O or C=O bonds.The charge redistribution enhances the absorption of CO_(2) and H2O, which promotes H_(2) evolution and CO production. In addition, the carbon shell effectively suppresses the metal core agglomeration and facilitates the electron transmission from photosensitizer to metallic active sites. Meanwhile, the ratio of CO/H_(2) can be regulated(~3:1 to 2:1) by adjusting the proportion of Co and PdZn. The Janus structure and graphite carbon synergistically play a profound impact on improving the photocatalytic performance.The optimized PdZn-Co catalyst exhibits a superior photocatalytic CO production rate(20.03 μmol/h) and the H_(2) generation rate(9.90 μmol/h) with a ratio of CO/H_(2)= 2.02.展开更多
Currently,the develop-ment of low-reflection electromagnetic interference(EMI)shielding composite materials for mitigating secondary electromagnetic wave pollution has become a major research focus.However,achieving t...Currently,the develop-ment of low-reflection electromagnetic interference(EMI)shielding composite materials for mitigating secondary electromagnetic wave pollution has become a major research focus.However,achieving thinness,high toughness,low reflectivity,and multi-functionality in flexible EMI shielding films remains a challenge.To address this issue,this study introduces a“magnetic-electric”Janus structure EMI shielding composite film composed of MXene nanosheets,carbonized ZIF-67(CZIF67)nanop-articles and aramid nanofibers(ANF),balancing thinness,high toughness,low reflectivity,and multifunctionality.As a result,the MXene/ANF-CZIF67/ANF-4(MACA-4)sample exhibits high tensile strength(110.0±7.0 MPa),large strain tolerance(21%),and superior toughness(14.9±0.9 MJ·m^(-3)),reflecting the stress dispersion effect of the three-dimensional(3D)network structure of ANF and the strengthening effect of hydrogen bonding.The sample exhibits excellent flexibility,resistance to rubbing and folding.Even with a thickness of only 80μm,the MACA-4 film exhibits a reflection performance(SER)as low as 4.3 to 4.5 dB in the 8.2 to 9.6 GHz band and the SE_(T)in the X-band reaches 44.8 dB.In addition,the superior conductivity of the MXene/ANF layer and the localized surface plasmon resonance effect give the MACA composite films excellent electrothermal conversion capabilities.Surprisingly,the sample also exhibited excellent infrared stealth and fire alarm properties.This work offers valuable guidance on the fabrication of ultra-thin flexible EMI shielding composites and provides an important scientific basis for the design and application of efficient EMI shielding materials.展开更多
Owing to the unpredictable size of wounds and irregular edges formed by trauma,nanofibers’highly customizable and adherent in situ deposition can contribute to intervention in the healing process.However,electrospinn...Owing to the unpredictable size of wounds and irregular edges formed by trauma,nanofibers’highly customizable and adherent in situ deposition can contribute to intervention in the healing process.However,electrospinning is limited by the constraints of conventional polymeric materials despite its potential for anti-inflammatory and antimicrobial properties.Here,inspired by the Janus structure and biochemistry of nanometal ions,we developed an in situ sprayed electrospinning method to overcome bacterial infections and immune imbalances during wound healing.The bilayer fiber scaffold has a hydrophobic outer layer composed of polycaprolactone(PCL)and a hydrophilic inner layer composed of gelatin,poly(L-lactic acid)(PLLA),and magnesium oxide nanoparticles,constituting the PCL/PLLA-gelatin-MgO(PPGM)electrospun scaffold.This electrospun scaffold blocked the colonization and growth of bacteria and remained stable on the wound for continuous anti-inflammatory properties to promote wound healing.Furthermore,PPGM electrospinning modulated collagen deposition and the inflammatory microenvironment in the full-thickness skin model,significantly accelerating vascularization and epithelialization progression.This personalized Janus electrospun scaffold has excellent potential as a new type of wound dressing for first aid and wound healthcare.展开更多
Moist-electric power generation is an emerging energy technology that collects energy from the environment and converts it into electrical energy through the interaction of moisture with materials.Although most of the...Moist-electric power generation is an emerging energy technology that collects energy from the environment and converts it into electrical energy through the interaction of moisture with materials.Although most of the moist-electric generators(MEGs)have achieved continuous breakthroughs in open-circuit voltage(V_(OC))and duration at present,it has been proven to be a challenge to maintain a continuous relatively high short-circuit current(ISC).Herein,electrospun nanofiber-based Janus heterogeneous film with both moisture absorption and moisture evaporation characteristics is prepared,and excellent power output performance MEGs have been fabricated by setting perforated electrode at each side respectively.Results have demonstrated the Janus nanofiber moist-electric generator(JFMEG)can generate a V_(OC)of 0.6 V with a continuous power generation time of up to 30 d and a maximum I_(SC)of about 44µA cm^(−2)at 95%relative humidity.In addition,the I_(SC)maintenance time above 10µA cm^(−2)is close to 40 h The integrated device can power commercial equipment and can be used for self-powered breath detection.Additionally,the self-powered field-effect transistor by JFMEG has been fabricated,demonstrating excellent output characteristics.The detailed working mechanism of JFMEG and the influencing factors of power generation performance are systematically analyzed,which can provide reference for the performance improvement of similar moist-electric devices.展开更多
Precise structural control had attracted tremendous interest in nanosynthesis due to its great importance in tailoring the physical properties of nanomaterials.Here we report the synthesis of highly ordered Cd S-Au-Ti...Precise structural control had attracted tremendous interest in nanosynthesis due to its great importance in tailoring the physical properties of nanomaterials.Here we report the synthesis of highly ordered Cd S-Au-TiO_(2) ternary Janus structure via templateprotected sequential growth and conversion method.Arising from the integration of the rectification effect of Au-CdS and AuTiO_(2) Schottky barriers,the Janus configuration of the Cd S-TiO_(2) domains,the plasmonic effect of Au nanosphere,and the Zscheme charge transportation,the Cd S-Au-TiO_(2) Janus structure showed high efficiency in the model photocatalytic degradation of methyl orange(MO)dye.Importantly,the well-defined structural order allowed the identification of the correlation between the structure and the catalytic performance.We believe that the synthetic control and the mechanism insights would help the design and synthesis of sophisticated nanostructures,and would eventually promote their applications in photocatalysis fields.展开更多
The properties of nanocrystals are highly dependent on their morphology, composition and structure. To obtain full control over their properties, the behavior of nanocrystals under external stimuli, such as heat treat...The properties of nanocrystals are highly dependent on their morphology, composition and structure. To obtain full control over their properties, the behavior of nanocrystals under external stimuli, such as heat treatment, needs to be understood. Herein, to in situ observe their microstructure and morphology changes, Fe3O4–Ag heterodimers were selected as a model system. Their structural changes after heat treatment were investigated by in situ transmission electron microscopy. A combination of real-time imaging with elemental analysis enabled observation of the transformation of Fe3O4–Ag heterodimers having a loose interface configuration to those with a Janus structure at the atomic scale after heating from room temperature to 600 °C. After incubation at 600 °C for 32 min, two kinds of Janus structures could be seen, including a clear linear interface in the Fe3O4–Ag heterodimers and a semi-crescent-shaped interface between the Ag and Fe3O4 nanoparticles(NPs). These dynamic observations provide unique insights into NP growth mechanisms, which are essential for understanding and controlling the structure and morphology of nanoparticles.展开更多
Solar vapor generation is a promising sustainable technology that uses solar distillation to produce fresh water from seawater and wastewater,helping relieve global water resource shortage.Here,inspired by naturally g...Solar vapor generation is a promising sustainable technology that uses solar distillation to produce fresh water from seawater and wastewater,helping relieve global water resource shortage.Here,inspired by naturally grown integrally molded mulberry leaves with a Janus hydrophilic and hydrophobic structure,a novel,simple,and efficient integrated molding method is proposed to break through the limitations of the traditional split manufacturing strategy and realizes the integrated formation of Janus evaporator.Based on the spontaneous sedimentation characteristics of MXene in silk fibroin solution and its regulation of mesoscopic structure and hydrophilicity of silk fibroin,layered structures with different compositions and hydrophilicities were obtained in one step.Meanwhile,ethanol and glutaraldehyde were added to construct a physical crystallization-chemical crosslinking dual stabilization structure in silk fibroin.Our evaporator has the evaporation rate of 3.07 kg·m^(-2)·h^(-1) and the efficiency of 86.8%under 1 sun and maintains high evaporation performance under various extreme test conditions including vigorous washing,repeated compression,and high-intensity ultraviolet(UV)irradiation.Additionally,the evaporator performs well in practical application scenarios,its evaporation rate in the simulated Dead Sea seawater exceeds 2.13 kg·m^(-2)·h^(-1),and more than 99.9%of the salt,heavy metal ions,oil pollution,and dyes are purified.展开更多
基金supported by the Natural Science Foundation of Shanxi Province(Nos.20210302123015 and 20210302123035)the Opening Project of State Key Laboratory of Polymer Materials Engineering(Sichuan University)(No.sklpme2022-4-06)the Open Foundation of China-Belarus Belt and Road Joint Laboratory on Electromagnetic Environment Effect(No.ZBKF2022030301).
文摘In the present work,by virtue of the synergistic and independent effects of Janus structure,an asymmetric nickel-chain/multiwall carbon nanotube/polyimide(Ni/MWCNTs/PI)composite foam with absorption-dominated electromagnetic interference(EMI)shielding and thermal insulation performances was successfully fabricated through an ordered casting and directional freeze-drying strategy.Water-soluble polyamic acid(PAA)was chosen to match the oriented freeze-drying method to acquire oriented pores,and the thermal imidization process from PAA to PI exactly eliminated the interface of the multilayered structure.By controlling the electro-magnetic gradient and propagation path of the incident microwaves in the MWCNT/PI and Ni/PI layers,the PI composite foam exhibited an efficient EMI SE of 55.8 dB in the X-band with extremely low reflection characteristics(R=0.22).The asymmetric conductive net-work also greatly preserved the thermal insulation properties of PI.The thermal conductivity(TC)of the Ni/MWCNT/PI composite foam was as low as 0.032 W/(m K).In addition,owing to the elimination of MWCNT/PI and Ni/PI interfaces during the thermal imidization process,the composite foam showed satisfactory compressive strength.The fabricated PI composite foam could provide reliable electromagnetic protection in complex applications and withstand high temperatures,which has great potential in cuttingedge applications such as advanced aircraft.
基金the support and funding from the National Natural Science Foundation of China(Nos.52203145,12204383)the Young Talent Fund of Association for Science and Technology in Shaanxi China(No.20230428)+1 种基金the Qinchuangyuan Citing High-level Innovation and Entrepreneurship Talent Projects(No.QCYRCXM-2022-190)the Key Research and Development Program of Shaanxi Province(No.2021SF-296).
文摘MXene-based composite films are regarded as up-and-coming multifunctional electromagnetic interference(EMI)shielding materials.However,the conflict between strong mechanical properties and high electrical conductivity hinders their application in modern integrated electronics.Herein,in virtue of density-induced sedimentation,robust and multifunctional liquid metals-reinforced cellulose nanofibers(CNF)/MXene(LMs-CNF/MXene)composite films with Janus structure are fabricated by one-step vacuum-assisted filtration method.Not only does the nacre-like structure of the CNF/MXene layer not destroy,but the deposited liquid metals(LMs)layer can serve as conductive potentiation.Due to the special Janus structure,an“absorption-reflection-reabsorption”shielding process is created in LMs-CNF/MXene composite film to strengthen EMI shielding performance.Its shielding effectiveness can reach 51.9 dB at -27μm,and the reflection coefficient falls to 0.89,below those of reported MXene-based shielding films.Meanwhile,the CNF/MXene layer can endow composite films with excellent mechanical properties with a super tensile strength of 110.3 MPa.Notably,the LMs-CNF/MXene EMI shielding composite films also integrate outstanding photo-/electrothermal conversion performances,which can effectively deice outdoors.The robust LMs-CNF/MXene EMI shielding composite films with satisfying photo-/electrothermal performances have extensive application prospects,such as aerospace,wearable electronics,and portable electronics.
基金supported by the National Natural Science Foundation of China(No.51873004)。
文摘Hierarchically three-dimensional(3D)materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects.In this work,α-Fe_(2)O_(3)@ZrO_(2)with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method.Following calcination,3D ZrO_(2)/Fe_(3)O_(4)/C nanocomposites with Janus structure have been successfully synthesized.By controlling the lattice match and mismatch in both processes,a core-shell structure ofα-Fe_(2)O_(3)@ZrO_(2)and Janus structure of ZrO_(2)/Fe_(3)O_(4)have been well-define performed.The composite material ZrO_(2)/Fe_(3)O_(4)/C-700 has a minimum reflection loss(RLmin)of−67.4 dB at a thickness of 2.0 mm.The effective absorption bandwidth(EAB)at a thickness of 2.4 mm is 6.0 GHz(11.0-17.0 GHz).This study provides a novel strategy for fabricating high-efficiency electromagnetic wave absorption materials with dual synergistic effects in nanosized scale.
基金financially supported by the National Natural Science Foundation of China (Nos. 52250077, 52272156, 51872263 and 52202175)Taishan Scholars Project (No. ts20190911)+1 种基金Shandong Natural Science Foundation (No. ZR2020ZD36)Guangdong Basic and Applied Basic Research Foundation (No. 2022A1515010461)。
文摘The accurate delivery of nanoparticles and organic small molecule drugs remains a serious challenge in nanoparticle-based tumor therapy.Dual-targeted therapy combining tumor cell targeting and organelle targeting is an effective solution.Here,an anticancer nanoformulation accurate delivery system was prepared using hyaluronic acid (HA) targeting CD44 receptors on the surface of tumor cells and IR780iodine (IR780) targeting mitochondrial for delivery.The system is based on an ultra-small Janus structured inorganic sensitizer TiO_(2-x)@NaGdF_(4) nanoparticles (TN NPs) prepared by one-step pyrolysis,further loaded with organic small molecule acoustic sensitizer IR780 and mitochondrial hexokinase Ⅱ inhibitor lonidamine (LND),followed by encapsulation of HA.Ultra-small size nanoparticles exhibit strong tissue penetration,tumor inhibition and in vivo metabolism.Under ultrasound radiation,TN NPs and IR780could produce a synergistic effect,effectively increased the efficiency of reactive oxygen species (ROS)production.Meanwhile,the released IR780 could smoothly target the mitochondria,and the ROS produced by IR780 can destroy the mitochondrial structure and disrupt the mitochondrial respiration.LND could inhibit the energy metabolism of tumor cells by reducing the activity of hexokinase Ⅱ (HK Ⅱ),which further accelerates the process of apoptosis.Furthermore,since the Janus structure allows the integration of multifunctional components into a single system,TN NPs can not only serve as an acoustic sensitizer to generate ROS,but the Gd element contained can also act as the nuclear magnetic resonance (MR)imaging contrast agent,suggesting that the nanoformulation can enable imaging-guided diagnosis and therapy.In conclusion,a new scheme to enhance sonodynamic therapy (SDT) and chemotherapy synergistically is proposed here based on ultra-small dual-targeted nanoformulation with Janus structure in the ultrasound radiation environment.
基金the financial support for conducting part of the computational work,by the Australian Government through the Australian Research Council(ARC)under the centre of Excellence scheme(Project No.CE170100026)National Computational Infrastructure(NCI),a National Facility for computing resources.S K M also acknowledges the computing system resources’support from the University of Tsukuba,Japan through the International Postdoctoral Fellowship of Japan Society for the Promotion of Science(JSPS)’s KAKENHI(Grant No.JP22F32733)+1 种基金during the computational work and finalization of this studyS K M also acknowledges the support of Mr Matta Sai Aneesh,University of Queensland,Australia while preparing the graphical abstract.
文摘Photoelectrochemical water splitting using solar energy,generating oxygen and hydrogen is one of the clean fuel production processes.Inspired by surface-dependent characteristics of Janus structures,a newly designed Janus monolayer Silicon Phosphorous Arsenide(SiPAs)was analyzed with Density Functional Theory(DFT)methods.Hybrid exchange-correlation functional(HSE06)combined with Wannier90-based analysis for electronic and optical properties of SiPAs reveals that it can act as a photocatalyst.SiPAs show an indirect bandgap of 1.88 eV,absorbing visible light range is 350 to 500 nm.The phonon spectrum confirms dynamic stability.The exciton binding energy is computed with GW/BSE methods.The electronic band edge positions are at-5.75 and-4.43 eV,perfectly straddling the water redox potentials.Interestingly the strain application modifies the bandgap and also non-homogenously widens the absorption band.A novel range of photocatalyst designs with Group IV-V elements with great promise for water-splitting,photovoltaic,and narrow bandgap semiconductor(optoelectronics)applications may be feasible.
基金financially supported by Jiangsu Science and Technology Plan(BK20211258)Nanjing Tech University(39837140)+1 种基金Jiangsu Second Normal University(928201/084)Jiangsu Funding Program for Excellent Postdoctoral Talent(2022ZB372)。
文摘This study presents the synthesis of a ternary CeO_(2)-AuNR-Cu_(2)O Janus structure with dual Schottky junctions,achieved by sequential growth of CeO_(2) and Cu_(2)O crystal domains on AuNR seeds.The dual Schottky junctions and the Janus-type CeO_(2)-Cu_(2)O P-N heterostructure led to significant enhancement in charge separation and suppress of the electron-hole recombination.The localized surface plasmon resonance(LSPR)effect of AuNR and the Z-scheme electron transfer pathway further boost the photocatalytic performance.This enhancement was demonstrated through the model photocatalytic degradation of methylene blue(MB)in aqueous solution.The proposed strategy not only improves photocatalytic efficiency but also provides insights into electron migration mechanisms,offering new opportunities for advanced nanostructure development in various applications.
基金supports from the National Natural Science Foundation of China(Nos.U21A2093 and 51903145)Fundamental Research Funds for the Central Universities(No.D5000210627)+1 种基金Y.L.Z.would like to thank the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(No.CX2021107)This work is also financially supported by Polymer Electromagnetic Functional Materials Innovation Team of Shaanxi Sanqin Scholars.
文摘Flexible multifunctional polymer-based electromagnetic interference(EMI)shielding composite films have important application values in the fields of 5G communication technology,wearable electronic devices and artificial intelligence.In this work,Fe_(3)O_(4)/polyamic acid(PAA)nanofiber films are prepared by in-situ polymerization and electrospinning technology,and Ti_(3)C_(2)T_(x)nanosheets are deposited on the surface of the Fe_(3)O_(4)/PAA nanofiber films via vacuum-assisted filtration.Then,Janus Ti_(3)C_(2)T_(x)-(Fe_(3)O_(4)/polyimide(PI))composite films are obtained by thermal imidization.The two sides of the Janus films exhibit completely different properties.The Fe_(3)O_(4)/PI side has excellent hydrophobicity and insulation property,and the Ti_(3)C_(2)T_(x)side has hydrophilicity and terrific conductivity.When the mass fraction of Ti_(3)C_(2)T_(x)is 80 wt.%,the Janus Ti_(3)C_(2)T_(x)-(Fe_(3)O_(4)/PI)composite film has excellent EMI shielding performances and mechanical properties,with EMI shielding effectiveness,tensile strength and Young’s modulus reaching 66 dB,114.5 MPa and 5.8 GPa,respectively.At the same time,electromagnetic waves show different absorption shielding effectiveness(SEA)when incident from two sides of the Janus films.When the electromagnetic waves are incident from the Fe_(3)O_(4)/PI side,the SEA of the Janus film is 58 dB,much higher than that when the electromagnetic waves are incident from the Ti_(3)C_(2)T_(x)side(39 dB).In addition,the Ti_(3)C_(2)T_(x)side of the Janus Ti_(3)C_(2)T_(x)-(Fe_(3)O_(4)/PI)composite films also has excellent electrothermal and photothermal conversion performances.When the applied voltage is 4 V,the stable surface temperature reaches 108°C;when it is irradiated by simulated sunlight with power density of 200 mW/cm2,the stable surface temperature reaches 95℃.
基金financially supported by the National Natural Science Foundation of China(Nos.52303090,52403132,52403112,52473083)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2023-JC-QN-0168,2024JC-TBZC-04)+6 种基金the Innovation Capability Support Plan of Shaanxi Province(No.2024ZC-KJXX-022)the Shaanxi Province Key Research and Development Plan Project(No.2023-YBGY-461)the Innovation Capability Support Program of Shaanxi(No.2024RS-CXTD-57)the Natural Science Foundation of Chongqing,China(No.2023NSCQ-MSX2547)the Youth Talent Promotion Project of Shaanxi Science and Technology Association(No.20240426)The Special Scientific Research Plan of Education Department of Shaanxi Province(No.23JK0376)the authors would also like to thank Shiyaniia lab for the sup-port of SEM and XPS tests.
文摘Flexible multifunctional polymer-based electromagnetic interference(EMI)shielding composite films play a pivotal role in 5 G communication technology,smart wearables,automotive electronics,and aerospace.In this work,(Ti_(3)C_(2)T_(x) MXene/cellulose nanofibers(CNF)-(hydroxy‑functionalized BNNS(BNNS-OH)/CNF)composite films(TBCF)with Janus structure are prepared via vacuum-assisted filtration of BNNS-OH/CNF and Ti_(3)C_(2)T_(x)/CNF suspension by one after another.Then ionic bonding-strengthened TBCF(ITBCF)is obtained by Ca^(2+)ion infiltration and cold-pressing technique.The Janus structure endows ITBCF with the unique“conductive on one side and insulating on the other”property.When the mass ratio of Ti_(3)C_(2)T_(x) and BNNS is 1:1 and the total mass fraction is 70 wt.%,the electrical conductivity(σ)of the Ti_(3)C_(2)T_(x)/CNF side of ITBCF reaches 166.7 S/cm,while the surface resistivity of the BNNS-OH/CNF side is as high as 304 MΩ.After Ca^(2+)ion infiltration,the mechanical properties of ITBCF are significantly enhanced.The tensile strength and modulus of ITBCF are 73.5 MPa and 15.6 GPa,which are increased by 75.9%and 46.2%compared with those of TBCF,respectively.Moreover,ITBCF exhibits outstanding EMI shielding effectiveness(SE)of 57 dB and thermal conductivity(λ)of 9.49 W/(m K).In addition,ITBCF also presents excellent photothermal and photoelectric energy conversion performance.Under simulated solar irradiation with a power density of 120 mW/cm^(2),the surface stabilization temperature reaches up to 65.3°C and the maximum steady state voltage reaches up to 58.2 mV.
基金supported by National Natural Science Foundation of China(Grant No.22005266)Zhejiang Provincial Natural Science Foundation(Grant No.LR21E020003)“the Fundamental Research Funds for the Central Universities”(2021FZZX001-09).
文摘Quasi-solid electrolytes(QSEs)based on nanoporous materials are promising candidates to construct high-performance Limetal batteries(LMBs).However,simultaneously boosting the ionic conductivity(σ)and lithium-ion transference number(t^(+)) of liquid electrolyte confined in porous matrix remains challenging.Herein,we report a novel Janus MOFLi/MSLi QSEs with asymmetric porous structure to inherit the benefits of both mesoporous and microporous hosts.This Janus QSE composed of mesoporous silica and microporous MOF exhibits a neat Li^(+) conductivity of 1.5.10^(–4)S cm^(−1) with t^(+) of 0.71.A partially de-solvated structure and preference distribution of Li^(+)near the Lewis base O atoms were depicted by MD simulations.Meanwhile,the nanoporous structure enabled efficient ion flux regulation,promoting the homogenous deposition of Li^(+).When incorporated in Li||Cu cells,the MOFLi/MSLi QSEs demonstrated a high Coulombic efficiency of 98.1%,surpassing that of liquid electrolytes(96.3%).Additionally,NCM 622||Li batteries equipped with MOFLi/MSLi QSEs exhibited promising rate performance and could operate stably for over 200 cycles at 1 C.These results highlight the potential of Janus MOFLi/MSLi QSEs as promising candidates for next-generation LMBs.
基金the Hong Kong Scholar Program (XJ2018035) for their financial supportsupported by Research Grants Council of Hong Kong (No. JLFS/E-402/18)National Natural Science Foundation of China (No. 51805509)。
文摘Several natural organism can change shape under external stimuli. These natural phenomena have inspired a vast amount of research on exploration and implementation of reconfigurable shape transformation. The Janus structure is a promising approach to achieve shape transformation based on its heterogeneous chemical or physical properties on opposite sides.However, the heterogeneity is generally realized by multi-step processing, different materials,and/or different processing parameters. Here, we present a simple and flexible method of producing p H-sensitive Janus microactuators from a single material, using the same laser printing parameters. These microactuators exhibit reversible structural deformations with large bending angles of ~31°and fast response(~0.2 s) by changing the p H value of the aqueous environment. Benefited from the high flexibility of the laser printing technique and the spatial arrangements, pillar heights, and bending directions of microactuators are readily controlled,enabling a variety of switchable ordered patterns and complex petal-like structures on flat surfaces and inside microchannels. Finally, we explore the potential applications of this method in information encryption/decryption and microtarget capturing.
基金financial assistance from the SERB Core Research Grant(Grant No.CRG/2022/000897)Department of Science and Technology(DST/NM/NT/2019/205(G))+1 种基金Minor Research Project Grant,Jain University(JU/MRP/CNMS/29/2023)CSR acknowledges National Research Foundation of Korea for the Brain Pool program funded by the Ministry of Science and ICT,South Korea(Grant No.RS-2023-00222186).
文摘The Janus MoSSe and alloy MoS_(x)Se_((1-x)),belonging to the family of two-dimensional(2D)transition metal dichalcogenides(TMDs),have gained significant attention for their potential applications in nanotechnology.The unique asymmetric structure of Janus MoSSe provides intriguing possibilities for tailored applications.The alloy MoS_(x)Se_((1-x))offers a tunable composition,allowing for the fine-tuning of the properties to meet specific requirements.These materials exhibit remarkable mechanical,electrical,and optical properties,including a tunable band gap,high absorption coefficient,and photoconductivity.The vibrational and magnetic properties also make it a promising candidate for nanoscale sensing and magnetic storage applications.Properties of these materials can be precisely controlled through different approaches such as size-dependent properties,phase engineering,doping,alloying,defect and vacancy engineering,intercalation,morphology,and heterojunction or hybridisation.Various synthesis methods for 2D Janus MoSSe and alloy MoS_(x)Se_((1-x))are discussed,including hydro/solvothermal,chemical vapour transport,chemical vapour deposition,physical vapour depositio,and other approaches.The review also presents the latest advancements in Janus and alloy MoSSe-based applications,such as chemical and gas sensors,surface-enhanced Raman spectroscopy,field emission,and energy storage.Moreover,the review highlights the challenges and future directions in the research of these materials,including the need for improved synthesis methods,understanding of their stability,and exploration of new applications.Despite the early stages of research,both the MoSSe-based materials have shown significant potential in various fields,and this review provides valuable insights for researchers and engineers interested in exploring its potential.
基金supported by the Shenzhen Basic Research Project,No.JCYJ20190807155805818the Foundation of Guangdong Provincial Key Laboratory of Sensor Technology and Biomedical Instrument,No.2020B1212060077the Sun Yat-sen University Training Program of Research for Undergraduates,No.76190-51200001.
文摘Background:Excessive exudate secreted from chronic wounds often leads to overhydration and infection.Although a variety of dressings are currently available in clinical applications,they frequently fail to provide multifunction to promote chronic wound healing.The dressings with a Janus structure,featuring distinct properties on each side,are potential to improve wound healing.Methods:Composite dressings with a Janus structure were fabricated,comprising freeze-dried polycaprolactone(PCL)electrospun membrane and alginate-based hydrogel.The PCL fibrous membrane provided air permeability,while the hydrogel loaded with Deferoxamine,composed of alginate and poly(N-isopropylacrylamide)(PNIPAM),exhibited hygroscopic properties.The inclusion of PNIPAM imparted thermo-responsivity.Results:The hydrogel(thickness of 2.778±0.082 mm)exhibited a robust adhesion to the fiber membrane(thickness of 0.261±0.041 mm).For ANDC(Alginate-PNIPAM hydrogel with Deferoxamine/PCL membrane)samples,the water vapor transmission rate(WVTR)was measured to be 3364.80±23.23 g∙m−2∙day−1 and the swelling ratio at 2 h was determined to be 1179±125%.The thermo-responsivity of ANDC samples manifested in an increased swelling rate,escalating from 797±189%at 37°C to 1132±147%at 4°C.The elastic modulus was assessed for lyophilized and rehydrated ANDC sample.When theωof the rheometer rotor was decreased from 10 rad/s to 0.1 rad/s,the lyophilized dressing exhibited a decrease from 2.65±0.01 MPa to 1.80±0.90 MPa,while the rehydrated dressing demonstrated an increase from 133.65±55.68 Pa to 264.23±141.71 Pa.The pro-healing properties of the dressings were evaluated using full-thickness skin defect model on SD rats,and a circular wound of diameter 10 mm healed completely by day 12.Conclusion:The dressings not only protected the wound and absorbed excess exudate,but also demonstrated nondestructive peelability upon cooling,providing a novel approach for accelerating wound healing and management.
基金the supports from the American Chemical Society Petroleum Research Fund(57072-DNI10)the National Science Foundation(CMMI-1727553)+2 种基金Partial support from the Virginia Commonwealth University Presidential Research Quest Fundsupports by the US Department of Energy under Awards No.DE-FG02-96ER45579and No.DE-AC02-05CH11231BET measurements(NSF I/UCR Center Grant,IIP 1464595)
文摘The detection and removal of volatile organic compounds(VOCs) are of great importance to reduce the risk of indoor air quality concerns. This study reports the rational synthesis of a dual-functional Janus nanostructure and its feasibility for simultaneous detection and removal of VOCs.The Janus nanostructure was synthesized via an anisotropic growth method, composed of plasmonic nanoparticles,semiconductors, and metal organic frameworks(e.g.,Au@ZnO@ZIF-8). It exhibits excellent selective detection to formaldehyde(HCHO, as a representative VOC) at room temperature over a wide range of concentrations(from 0.25 to100 ppm), even in the presence of water and toluene molecules as interferences. In addition, HCHO was also found to be partially oxidized into non-toxic formic acid simultaneously with detection. The mechanism underlying this technology was unraveled by both experimental measurements and theoretical calculations: ZnO maintains the conductivity, while ZIF-8 improves the selective gas adsorption; the plasmonic effect of Au nanorods enhances the visible-light-driven photocatalysis of ZnO at room temperature.
基金supported by the National Natural Science Foundation of China (No. 51872025)the National Key R&D Program of China (No. 2021YFB3802200)+4 种基金Natural Science Foundation of Guangdong Province (No. 2220XCC061)the National Defense Basic Scientific Research (No. JCKY2021110B206)Scientific and Technological Innovation Foundation of Foshan (No. BK21BE008)Zibo Key Research and Development Program (No. 2020XCCG0036)supported by USTB MatCom of Beijing Advanced Innovation Center for Materials Genome Engineering。
文摘The development of excellent catalyst to achieve photocatalytic syngas production from CO_(2) and H_(2)O is a prospective and sustainable strategy to alleviate environment and energy crisis. In this study, a unique Janus PdZn-Co catalyst is prepared by annealed the Pd/IRMOF-3(Co, Zn) precursor. Due to the strong interaction, the electron transfers from PdZn terminal to Co terminal in the Janus structure. The electron-received Co terminal facilitates Co sites coordinate with the electrophilic C atom of CO_(2) and the electron-donated PdZn center is easier to coordinate with nucleophilic O atoms of H_(2)O or C=O bonds.The charge redistribution enhances the absorption of CO_(2) and H2O, which promotes H_(2) evolution and CO production. In addition, the carbon shell effectively suppresses the metal core agglomeration and facilitates the electron transmission from photosensitizer to metallic active sites. Meanwhile, the ratio of CO/H_(2) can be regulated(~3:1 to 2:1) by adjusting the proportion of Co and PdZn. The Janus structure and graphite carbon synergistically play a profound impact on improving the photocatalytic performance.The optimized PdZn-Co catalyst exhibits a superior photocatalytic CO production rate(20.03 μmol/h) and the H_(2) generation rate(9.90 μmol/h) with a ratio of CO/H_(2)= 2.02.
基金supported by the Talent Fund of Beijing Jiaotong University(No.2023XKRC015)the National Natural Science Foundation of China(No.52172081)+2 种基金the Key R&D and Promotion Special Projects(Science and Technology)of Henan Province(No.232102240068)the Henan Provincial Department of Education(No.22B150010)Henan Province Key Research and Development Project(No.251111321500).
文摘Currently,the develop-ment of low-reflection electromagnetic interference(EMI)shielding composite materials for mitigating secondary electromagnetic wave pollution has become a major research focus.However,achieving thinness,high toughness,low reflectivity,and multi-functionality in flexible EMI shielding films remains a challenge.To address this issue,this study introduces a“magnetic-electric”Janus structure EMI shielding composite film composed of MXene nanosheets,carbonized ZIF-67(CZIF67)nanop-articles and aramid nanofibers(ANF),balancing thinness,high toughness,low reflectivity,and multifunctionality.As a result,the MXene/ANF-CZIF67/ANF-4(MACA-4)sample exhibits high tensile strength(110.0±7.0 MPa),large strain tolerance(21%),and superior toughness(14.9±0.9 MJ·m^(-3)),reflecting the stress dispersion effect of the three-dimensional(3D)network structure of ANF and the strengthening effect of hydrogen bonding.The sample exhibits excellent flexibility,resistance to rubbing and folding.Even with a thickness of only 80μm,the MACA-4 film exhibits a reflection performance(SER)as low as 4.3 to 4.5 dB in the 8.2 to 9.6 GHz band and the SE_(T)in the X-band reaches 44.8 dB.In addition,the superior conductivity of the MXene/ANF layer and the localized surface plasmon resonance effect give the MACA composite films excellent electrothermal conversion capabilities.Surprisingly,the sample also exhibited excellent infrared stealth and fire alarm properties.This work offers valuable guidance on the fabrication of ultra-thin flexible EMI shielding composites and provides an important scientific basis for the design and application of efficient EMI shielding materials.
基金supported by grants from the 512 Talents Development Project of Bengbu Medical University(by51202302)the Domestic Visiting and Training Program for Outstanding Young Backbone Teachers in High Schools(gxgnfx2022036)+1 种基金the Anhui Provincial Natural Science Foundation(2308085MH262)the Natural Science Research Project of the Anhui Educational Committee(2023AH051939).
文摘Owing to the unpredictable size of wounds and irregular edges formed by trauma,nanofibers’highly customizable and adherent in situ deposition can contribute to intervention in the healing process.However,electrospinning is limited by the constraints of conventional polymeric materials despite its potential for anti-inflammatory and antimicrobial properties.Here,inspired by the Janus structure and biochemistry of nanometal ions,we developed an in situ sprayed electrospinning method to overcome bacterial infections and immune imbalances during wound healing.The bilayer fiber scaffold has a hydrophobic outer layer composed of polycaprolactone(PCL)and a hydrophilic inner layer composed of gelatin,poly(L-lactic acid)(PLLA),and magnesium oxide nanoparticles,constituting the PCL/PLLA-gelatin-MgO(PPGM)electrospun scaffold.This electrospun scaffold blocked the colonization and growth of bacteria and remained stable on the wound for continuous anti-inflammatory properties to promote wound healing.Furthermore,PPGM electrospinning modulated collagen deposition and the inflammatory microenvironment in the full-thickness skin model,significantly accelerating vascularization and epithelialization progression.This personalized Janus electrospun scaffold has excellent potential as a new type of wound dressing for first aid and wound healthcare.
基金financially supported by the National Natural Science Foundation of China(Nos.11774001 and 52202156)the Scientific Research Project of Colleges and Universities in Anhui Province(No.2022AH050113)+2 种基金the University Synergy Innovation Program of Anhui Province(No.GXXT-2022-012)the China Postdoctoral Science Foundation(No.2024M760010)the Postdoctoral Daily Public Start-up Funds of Anhui University(No.S202418001/069).
文摘Moist-electric power generation is an emerging energy technology that collects energy from the environment and converts it into electrical energy through the interaction of moisture with materials.Although most of the moist-electric generators(MEGs)have achieved continuous breakthroughs in open-circuit voltage(V_(OC))and duration at present,it has been proven to be a challenge to maintain a continuous relatively high short-circuit current(ISC).Herein,electrospun nanofiber-based Janus heterogeneous film with both moisture absorption and moisture evaporation characteristics is prepared,and excellent power output performance MEGs have been fabricated by setting perforated electrode at each side respectively.Results have demonstrated the Janus nanofiber moist-electric generator(JFMEG)can generate a V_(OC)of 0.6 V with a continuous power generation time of up to 30 d and a maximum I_(SC)of about 44µA cm^(−2)at 95%relative humidity.In addition,the I_(SC)maintenance time above 10µA cm^(−2)is close to 40 h The integrated device can power commercial equipment and can be used for self-powered breath detection.Additionally,the self-powered field-effect transistor by JFMEG has been fabricated,demonstrating excellent output characteristics.The detailed working mechanism of JFMEG and the influencing factors of power generation performance are systematically analyzed,which can provide reference for the performance improvement of similar moist-electric devices.
基金supported by Jiangsu Science and Technology Plan(BK20211258)Nanjing Tech University(39837140)Jiangsu Funding Program for Excellent Postdoctoral Talents。
文摘Precise structural control had attracted tremendous interest in nanosynthesis due to its great importance in tailoring the physical properties of nanomaterials.Here we report the synthesis of highly ordered Cd S-Au-TiO_(2) ternary Janus structure via templateprotected sequential growth and conversion method.Arising from the integration of the rectification effect of Au-CdS and AuTiO_(2) Schottky barriers,the Janus configuration of the Cd S-TiO_(2) domains,the plasmonic effect of Au nanosphere,and the Zscheme charge transportation,the Cd S-Au-TiO_(2) Janus structure showed high efficiency in the model photocatalytic degradation of methyl orange(MO)dye.Importantly,the well-defined structural order allowed the identification of the correlation between the structure and the catalytic performance.We believe that the synthetic control and the mechanism insights would help the design and synthesis of sophisticated nanostructures,and would eventually promote their applications in photocatalysis fields.
基金the Zhejiang Provincial Natural Science Foundation of China(No.LD19E010001)the National Natural Science Foundation of China(Nos.51771219,51771095 and 51771220)。
文摘The properties of nanocrystals are highly dependent on their morphology, composition and structure. To obtain full control over their properties, the behavior of nanocrystals under external stimuli, such as heat treatment, needs to be understood. Herein, to in situ observe their microstructure and morphology changes, Fe3O4–Ag heterodimers were selected as a model system. Their structural changes after heat treatment were investigated by in situ transmission electron microscopy. A combination of real-time imaging with elemental analysis enabled observation of the transformation of Fe3O4–Ag heterodimers having a loose interface configuration to those with a Janus structure at the atomic scale after heating from room temperature to 600 °C. After incubation at 600 °C for 32 min, two kinds of Janus structures could be seen, including a clear linear interface in the Fe3O4–Ag heterodimers and a semi-crescent-shaped interface between the Ag and Fe3O4 nanoparticles(NPs). These dynamic observations provide unique insights into NP growth mechanisms, which are essential for understanding and controlling the structure and morphology of nanoparticles.
基金supported by the National Natural Science Foundation of China(Nos.51773171 and 12074322)Science and Technology Project of Xiamen City(No.3502Z20183012)+1 种基金Science and Technology Planning Project of Guangdong Province(No.2018B030331001)Shenzhen Science and Technology Plan Project(No.JCYJ20180504170208402).
文摘Solar vapor generation is a promising sustainable technology that uses solar distillation to produce fresh water from seawater and wastewater,helping relieve global water resource shortage.Here,inspired by naturally grown integrally molded mulberry leaves with a Janus hydrophilic and hydrophobic structure,a novel,simple,and efficient integrated molding method is proposed to break through the limitations of the traditional split manufacturing strategy and realizes the integrated formation of Janus evaporator.Based on the spontaneous sedimentation characteristics of MXene in silk fibroin solution and its regulation of mesoscopic structure and hydrophilicity of silk fibroin,layered structures with different compositions and hydrophilicities were obtained in one step.Meanwhile,ethanol and glutaraldehyde were added to construct a physical crystallization-chemical crosslinking dual stabilization structure in silk fibroin.Our evaporator has the evaporation rate of 3.07 kg·m^(-2)·h^(-1) and the efficiency of 86.8%under 1 sun and maintains high evaporation performance under various extreme test conditions including vigorous washing,repeated compression,and high-intensity ultraviolet(UV)irradiation.Additionally,the evaporator performs well in practical application scenarios,its evaporation rate in the simulated Dead Sea seawater exceeds 2.13 kg·m^(-2)·h^(-1),and more than 99.9%of the salt,heavy metal ions,oil pollution,and dyes are purified.
