Block copolymer(BCP) nanolithography offers potential beyond traditional photolithographic limits, yet reliably producing low-defect, perpendicular domains remains challenging. We introduce a microenvironmentdriven is...Block copolymer(BCP) nanolithography offers potential beyond traditional photolithographic limits, yet reliably producing low-defect, perpendicular domains remains challenging. We introduce a microenvironmentdriven isothermal annealing method for directed self-assembly of BCP thin films. By annealing films at stable temperature in a quasi-sealed, inert-gas chamber, our approach promotes highly uniform perpendicular lamellar nanopatterns over large areas, effectively mitigating environmental fluctuations and emulating solvent-vapor annealing without solvent exposure. Resulting BCP structures demonstrate enhanced spatial coherence and notably low defect density. Furthermore, we successfully transfer these nanopatterns into precise metal nano-line arrays,confirming the method's capability for high-fidelity pattern replication. This scalable, solvent-free technique provides a robust, reliable route for high-resolution nanopatterning in advanced semiconductor manufacturing.展开更多
The transformation mechanism of the inclusions and microstructure in 316L stainless steel after post-isothermal heat treatment(IHT)was revealed,along with the pitting behavior of the inclusions in a chloride environme...The transformation mechanism of the inclusions and microstructure in 316L stainless steel after post-isothermal heat treatment(IHT)was revealed,along with the pitting behavior of the inclusions in a chloride environment before and after the transformation.The effect of the inclusion transformation on the pitting corrosion behavior of 316L stainless steel and its intrinsic mechanism was also revealed.Results revealed a gradual transformation of MnO-SiO_(2)inclusions into MnO-Cr_(2)O_(3) within the temperature range of 1373 to 1573 K.MnO-Cr_(2)O_(3)inclusions exhibited minimal dissolution in chloride ion corrosion environments,while MnO-SiO_(2)oxides demonstrated higher electrochemical activity and were more prone to dissolve and form pits.Meanwhile,IHT significantly reduced the dislocation density of stainless steel,rendering it more stable in corrosive environments.X-ray photoelectron spectroscopy peak distributions of the passive films demonstrated that IHT increased the proportion of Cr and Fe oxides and hydroxides in the passive film which improved the stability and corrosion resistance of the steel.展开更多
Based on the entropy function, a two-dimensional phase field model of binary alloys was established. Meanwhile, an explicit difference method with uniform grid was adopted to solve the phase field and solute field con...Based on the entropy function, a two-dimensional phase field model of binary alloys was established. Meanwhile, an explicit difference method with uniform grid was adopted to solve the phase field and solute field controlled equations. And the alternating direction implicit(ADI) algorithm for solving temperature field controlled equation was also employed to avoid the restriction of time step. Some characteristics of the Ni-Cu alloy were captured in the process of non-isothermal solidification, and the comparative analysis of the isothermal and the non-isothermal solidification was investigated. The simulation results indicate that the non-isothermal model is favorable to simulate the real solidification process of binary alloys, and when the thermal diffusivity decreases, the non-isothermal phase-field model is gradually consistent with the isothermal phase-field model.展开更多
The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was appli...The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was applied to analyzing the kinetics behavior of Mg-Ni hydride. The calculation results show that the theoretical value and the experimental data can reach a good agreement, especially in the case of non-isothermal dehydriding. The rate-controlling step is the diffusion of hydrogen atoms in the solid solution. The sample prepared under magnetic field of 6 T under the isothermal condition can reach the best performance. The similar tendency was observed under the non-isothermal condition and the reason was discussed.展开更多
Semicrystalline polymers usually undergo multilevel microstructural evolutions with annealing and stretching processes,which is es-sential to tailor the physical properties of the polymer.Here,poly(butylene carbonate)...Semicrystalline polymers usually undergo multilevel microstructural evolutions with annealing and stretching processes,which is es-sential to tailor the physical properties of the polymer.Here,poly(butylene carbonate)(PBC)sheets were prepared via isothermal annealing and unidirectional pre-stretching processes,then the changes of PBC in crystallinity,mechanical properties,thermal properties and microscopic changes before and after annealing and stretching were measured,as well as the relationship between microstructure and macroscopic proper-ties before and after stretching.The strengthening mechanism of PBC was also described.It was demonstrated that shish-kabab structure emerged under the pre-stretching process.With the increase of the tensile ratio,the crystallinity,structure and mechanical properties are in-creased differently.Among them,the crystallinity and tensile strength after annealing-stretching treatment increased to 24.45%and 104.5 MPa,respectively,which were about 1.55 times and 3.4 times of those-without any treatment.展开更多
Silicomanganese dust contains large amounts of valuables,such as Si and Mn,which can be used as raw materials for the smelting of silicomanganese.However,the direct addition of dust to the submerged arc furnace can in...Silicomanganese dust contains large amounts of valuables,such as Si and Mn,which can be used as raw materials for the smelting of silicomanganese.However,the direct addition of dust to the submerged arc furnace can influence the permeability of burden due to the fine particle size of dust,which results in incomplete reduction reactions during the smelting process.In this paper,silicomanganese dust,graphite powder,and other additives were pressed to form carbon-containing dust briquettes,and the self-reduction process of the dust briquettes was investigated through the isothermal thermogravimetric method with different carbon–oxygen (C/O) molar ratios,contents of fluxing agents,and reduction temperatures.Various reduction kinetic models for dust briquettes at different temperatures were established.The results show that the reaction fraction of the dust briquettes was about 90%at a C/O molar ratio of 1.2 with optimal reduction efficiency.The addition of CaF_(2)contributed to the decrease in the melting point and viscosity of dust briquettes,which increased their reduction rate.As the reduction temperature increased,the reduction rate of dust briquettes increased.The reduction reaction rate of dust briquettes was controlled through gas-phase diffusion.Meanwhile,their reduction process was analyzed kinetically,with the reaction time of 5 min as the dividing line.The apparent activation energies for the two diffusion stages were 56.10 and 100.52 kJ/mol,respectively.The kinetic equations are expressed as[1-(1-f)^(1/3)]^(2)=0.69e^(-56100/(RT))t and [1-(1-f)^(1/3)]^(2)=2.06e^(-100520/(RT))t.展开更多
The factors affecting the oxidation degree of vanadium–titanium magnetite (VTM) pellets were analyzed via the isothermal oxidation experiment. Furthermore, the oxidation kinetics of VTM pellets were explored through ...The factors affecting the oxidation degree of vanadium–titanium magnetite (VTM) pellets were analyzed via the isothermal oxidation experiment. Furthermore, the oxidation kinetics of VTM pellets were explored through linear fitting to the kinetic equations based on the shrinking unreacted-core model. The results reveal that VTM pellets undergo oxidation in three distinct phases: pre-oxidation, mid-oxidation, and final stable phase. Notably, the mid-oxidation phase is absent in magnetite oxidation. The shrinking unreacted-core model has been proven to be suitable for modeling the process of oxidizing VTM pellets. In the pre-oxidation stage, the rate-controlling step is determined by both the oxidation temperature and the effective oxygen concentration. The influence of the effective oxygen concentration on the rate of oxidation is more pronounced at temperatures between 1073 and 1273 K, especially when the oxygen content falls below 15 vol.%. For the production of oxidized VTM pellets, it is necessary to maintain a preheating temperature above 1173 K (to accelerate the oxidation reaction) and below 1473 K (to prevent the swift formation of compact Fe2TiO5 at the shell of the pellet) in an oxygen-enriched atmosphere.展开更多
The isothermal oxidation kinetics of vanadium–titanium magnetite(VTM)pellets prepared with 3Co-binder(coal-based colloidal composite binder)and F-binder(pulverized Funa binder)are compared.The oxidation process was a...The isothermal oxidation kinetics of vanadium–titanium magnetite(VTM)pellets prepared with 3Co-binder(coal-based colloidal composite binder)and F-binder(pulverized Funa binder)are compared.The oxidation process was analyzed using the first-order irreversible reaction,following the shrinking unreacted nucleus model.The results demonstrate that VTM pellets prepared with 3Co-binder exhibit a faster oxidation rate than those with F-binder across the temperatures ranging from 1073 to 1473 K.In both cases,the oxidation process was controlled by an interfacial chemical reaction during the pre-oxidation stage and by internal diffusion during the mid-oxidation stage.The type of binder did not influence the primary oxidation control mechanism of the VTM pellets.However,the apparent rate constants in the pre-oxidation stage and the internal diffusion coefficients in the mid-oxidation stage were higher for pellets with 3Co-binder compared to those with F-binder.The apparent activation energies for the 3Co-binder pellets were similar to those of bentonite,indicating favorable kinetic conditions without negative impacts on the oxidation process.Nonetheless,it is important to note that pellets with F-binder required a longer oxidation time than those with 3Co-binder.展开更多
The microstructural evolution of AZ61 magnesium alloy predeformed by equal channel angular extrusion（ECAE） during semisolid isothermal treatment（SSIT） was investigated by means of optical metalloscopy and image an...The microstructural evolution of AZ61 magnesium alloy predeformed by equal channel angular extrusion（ECAE） during semisolid isothermal treatment（SSIT） was investigated by means of optical metalloscopy and image analysis equipment.The process involved application of ECAE to as-cast alloy at 310 ℃ to induce strain prior to heating in the semisolid region for different time lengths.The results show that extrusion pass,isothermal temperature and processing route have an influence on microstructural evolution of predeformed AZ61 magnesium alloy during SSIT.With the increase of extrusion pass,the solid particle size is reduced gradually.When isothermal temperature increases from 530 ℃ to 560 ℃,the average particle size increases from 22 μm to 35 μm.When isothermal temperature is 575 ℃,the average particle size decreases.The particle size of microstructure of AZ61 magnesium alloy predeformed by ECAE at BC during SSIT is the finest.展开更多
A Mg-8%Al-1%Si alloy with semisolid microstructure was fabricated by isothermal heat treatment process. The effects of isothermal process parameters such as holding temperature and holding time on the microstructure o...A Mg-8%Al-1%Si alloy with semisolid microstructure was fabricated by isothermal heat treatment process. The effects of isothermal process parameters such as holding temperature and holding time on the microstructure of Mg-8%Al-1%Si alloy were investigated. The results show that a non-dendritic microstructure could be obtained by isothermal heat treatment. With increasing holding temperature from 560 to 575 °C or holding time from 5 to 30 min, the liquid volume fraction increases, the average size of α-Mg grains grows larger and globular tendency becomes more obvious. In addition, the Mg2Si phase transforms from Chinese script shape to granule shape. The morphology modification mechanisium of Mg2Si phase in Mg-8%Al-1%Si alloy during the semisolid isothermal heat treatment was also studied.展开更多
The formation and evolution characteristics of bcc phase during the isothermal relaxation processes for supercooled-liquid and amorphous Pb were investigated by molecular dynamics simulation and cluster-type index met...The formation and evolution characteristics of bcc phase during the isothermal relaxation processes for supercooled-liquid and amorphous Pb were investigated by molecular dynamics simulation and cluster-type index method （CTIM）. It is found that during the relaxation process, the formation and evolution of bcc phase are closely dependent on the initial temperature and structure. During the simulation time scale, when the initial temperature is in the range of supercooled liquid region, the bcc phase can be formed and kept a long time; while it is in the range of glassy region, the bcc phase can be formed at first and then partially transformed into hcp phase; when it decreases to the lower one, the hcp and fcc phases can be directly transformed from the glassy structure without undergoing the metastable bcc phase. The Ostwald＇s ＂step rule＂ is impactful during the isothermal relaxation process of the supercooled and glassy Pb, and the metastable bcc phase plays an important role in the precursor of crystallization.展开更多
Using simple unequal-thickness billet combining isothermal local loading can control the metal flow and improve the cavity fill in manufacturing process of large-scale rib-web titanium alloy component with low cost an...Using simple unequal-thickness billet combining isothermal local loading can control the metal flow and improve the cavity fill in manufacturing process of large-scale rib-web titanium alloy component with low cost and short cycle. The beveling transition pattern is well used for variable-thickness region of billet （VTRB） due to its simple and ample range of transition condition. The transition condition development in the local loading process has a significant influence on dynamic boundary of unrestricted portion of VTRB. With the help of reasonable assumptions, a mathematical model of transition condition development was established by theoretical analysis. The predicted results for local loading process of rib-web component using the established model were compared with the numerical and experimental ones, and the results indicated that the model of transition condition development is reasonable. Using the established model could deal with the dynamic boundary of unrestricted portion of VTRB well, and the model is suitable for the analysis of metal flow and cavity fill in local loading process of multi-ribs component.展开更多
The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scann...The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). It is experimentally testified that theα-Mg solid solution is not in equilibrium with the Mg32(Al, Zn)49 (τ) ternary intermetallic compound orq quasicrystalline phase, but only in equilibrium with one ternary intermetallic compound Al5Mg11Zn4 (φ). The whole composition range of theφ phase was also obtained at 335 °C, i.e., 52.5%?56.4% Mg, 13.6%?24.0% Al, 19.6%?33.9% Zn (mole fraction). The solubility of Al in the MgZn phase is remarkably more than that in the Mg7Zn3 phase, and the maximum is about 8.6% Al. Aluminum and zinc are simultaneously soluble in theα-Mg solid solution.展开更多
This work was attempted to modify the current technology for thermal barrier coatings（TBCs） by adding an additional step of surface modification,namely,supersonic fine particles bombarding（SFPB） process,on bond co...This work was attempted to modify the current technology for thermal barrier coatings（TBCs） by adding an additional step of surface modification,namely,supersonic fine particles bombarding（SFPB） process,on bond coat before applying the topcoat.After isothermal oxidation at 1000 °C for different time,the surface state of the bond coat and its phase transformation were investigated using X-ray diffraction（XRD）,scanning electron microscopy（SEM） equipped with energy-dispersive X-ray spectrometry（EDS）,transmission electron microscopy（TEM） and Cr3＋ luminescence spectroscopy.The dislocation density significantly increases after SFPB process,which can generate a large number of diffusion channels in the area of the surface of the bond coat.At the initial stage of isothermal oxidation,the diffusion velocity of Al in the bond coat significantly increases,leading to the formation of a layer of stable α-Al2O3 phase.A great number of Cr3＋ positive ions can diffuse via diffusion channels during the transient state of isothermal oxidation,which can lead to the presence of（Al0.9Cr0.1）2O3 phase and accelerate the γ→θ→α phase transformation.Cr3＋ luminescence spectroscopy measurement shows that the residual stress increases at the initial stage of isothermal oxidation and then decreases.The residual stress after isothermal oxidation for 310 h reduces to 0.63 GPa compared with 0.93 GPa after isothermal oxidation for 26 h.In order to prolong the lifespan of TBCs,a layer of continuous,dense and pure α-Al2O3 with high oxidation resistance at the interface between topcoat and bond coat can be obtained due to additional SFPB process.展开更多
Nucleic acid(DNA and RNA)detection and quantification methods play vital roles in molecular biology.With the development of molecular biology,isothermal amplification of DNA/RNA,as a new molecular biology technology,c...Nucleic acid(DNA and RNA)detection and quantification methods play vital roles in molecular biology.With the development of molecular biology,isothermal amplification of DNA/RNA,as a new molecular biology technology,can be amplified under isothermal condition,it has the advantages of high sensitivity,high specificity,and high efficiency,and has been applied in various fields of biotechnology,including disease diagnosis,pathogen detection,food hygiene and safety detection and so on.This paper introduces the progress of isothermal amplification technology,including rolling circle amplification(RCA),nucleic acid sequence-dependent amplification(NASBA),strand displacement amplification(SDA),loop-mediated isothermal amplification(LAMP),helicase-dependent amplification(HDA),recombinase polymerase amplification(RPA),cross-priming amplification(CPA),and its principle,advantages and disadvantages,and application development are briefly summarized.展开更多
A reverse-transcription loop-mediated isothermal amplification （RT-LAMP） method was established for the detection of wheat streak mosaic virus （WSMV）. Ac-cording to the conservative regions of the genes that encod...A reverse-transcription loop-mediated isothermal amplification （RT-LAMP） method was established for the detection of wheat streak mosaic virus （WSMV）. Ac-cording to the conservative regions of the genes that encode the coat protein of WSMV, 2 pairs of primers were designed. Final y, the 1st pair of primers was select-ed through the specificity test. The sensitivity test showed the sensitivity of RT-LAMP method was 10 times higher than that of RT-PCR. In addition, the amplifica-tion of target gene could be judged visual y from the presence of fluorescence （cal-cein） in the final reaction system. The RT-LAMP method, established in this study, was rapid, easy, specific and sensitive. Moreover, it did not require sophisticated equip-ment. The RT-LAMP was suitable for the rapid detection of WSMV.展开更多
The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimet...The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 ℃. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminm metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30-330 ℃ at heating rates of 10,15 and 20 ℃·min^(-1).The TG/DTG data were used for determination of activation energy(E_a) of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall(OFW) and Kissinger-Akahira-Sunose(KAS) methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99-120 and 66-70 kJ mol^(-1)respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade.展开更多
An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and...An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and a continuous solid solution （Gd,Nd）Mg is also formed between MgGd and MgNd. Mg7Gd, Mg5Gd, Mg2Gd, Mg41Nd5, （Gd,Nd）3Mg and （Gd,Nd）Mg are found in the ternary system. In these intermetallic phases, Mg7Gd has been reported to be a metastable phase in previous literatures. The solubilities of Mg, Gd and Nd in all the phases were detected. Furthermore, four three-phase equilibria, α（Mg）＋Mg7Gd＋Mg41Nd5, Mg7Gd＋Mg5Gd＋Mg41Nd5, Mg5Gd＋Mg41Nd5＋（Gd,Nd）3Mg and （Gd,Nd）3Mg＋（Gd,Nd）Mg＋Mg2Gd, were identified in the isothermal section.展开更多
The kinetics of nonisothermal and isothermal crystallization of metallocene catalyzed and conventional polyethylenes has been studied by differential scanning calorimetry. Using Avrami equation, Ozawa theory and Mo Zh...The kinetics of nonisothermal and isothermal crystallization of metallocene catalyzed and conventional polyethylenes has been studied by differential scanning calorimetry. Using Avrami equation, Ozawa theory and Mo Zhishen method, the experimental data have been analyzed. It is shown that metallocene polyethylene possesses a higher rate of crystallization due to a higher stereoregularity of its molecular chains. Moreover, they have different nonisothermal crystallization mechanisms and identical isothermal crystallization mechanisms.展开更多
Effect of isothermal holding treatment in the solidification process on the microstructure of Ti-6Al-4V alloy was studied by temperature controlled induced melting apparatus. The result shows that with isothermal hold...Effect of isothermal holding treatment in the solidification process on the microstructure of Ti-6Al-4V alloy was studied by temperature controlled induced melting apparatus. The result shows that with isothermal holding treatment above the β transus temperature during solidification, the colony structure consisting of parallel lamellae was obtained. While the isothermal holding treatment was set at 960 °C, a unique bi-modal microstructure consisting of coarse primary α and fine secondary lamellar α was obtained. The primary lamellar α tended to break into several pieces, globularize and present equiaxed morphology. The formation mechanism of the equiaxed α can be explained with the atom immigration, high density dislocations, combined action with the interface tension of formed α phase during the isothermal holding treatment. After the isothermal holding, the retained β matrix transformed into fine lamellar α, thus, bi-modal microstructure was acquired. Compared with the lamellar structure, the grain boundary α presented discontinuously and cannot be distinguished from the primary α lamellae easily. The size of colonies α was greatly decreased. The microstructure tended to be much more homogeneous in the whole section of the samples.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.U20A20168 and 62404120)the National Key R&D Program (Grant No.2022YFB3204100)+2 种基金the Postdoctoral Fellowship Program of CPSF (Grant Nos.GZB20240335 and GZC20231216)the China Postdoctoral Science Foundation (Grant No.2025T180151)the Initiative Scientific Research Program of the School of Integrated Circuits,Tsinghua University。
文摘Block copolymer(BCP) nanolithography offers potential beyond traditional photolithographic limits, yet reliably producing low-defect, perpendicular domains remains challenging. We introduce a microenvironmentdriven isothermal annealing method for directed self-assembly of BCP thin films. By annealing films at stable temperature in a quasi-sealed, inert-gas chamber, our approach promotes highly uniform perpendicular lamellar nanopatterns over large areas, effectively mitigating environmental fluctuations and emulating solvent-vapor annealing without solvent exposure. Resulting BCP structures demonstrate enhanced spatial coherence and notably low defect density. Furthermore, we successfully transfer these nanopatterns into precise metal nano-line arrays,confirming the method's capability for high-fidelity pattern replication. This scalable, solvent-free technique provides a robust, reliable route for high-resolution nanopatterning in advanced semiconductor manufacturing.
基金the support from the National Natural Science Foundation of China(Grant Nos.52074198,52374342,and U21A20113)the Department of Science and Technology of Hubei Province(Grant Nos.2023AFB603 and 2023DJC140).
文摘The transformation mechanism of the inclusions and microstructure in 316L stainless steel after post-isothermal heat treatment(IHT)was revealed,along with the pitting behavior of the inclusions in a chloride environment before and after the transformation.The effect of the inclusion transformation on the pitting corrosion behavior of 316L stainless steel and its intrinsic mechanism was also revealed.Results revealed a gradual transformation of MnO-SiO_(2)inclusions into MnO-Cr_(2)O_(3) within the temperature range of 1373 to 1573 K.MnO-Cr_(2)O_(3)inclusions exhibited minimal dissolution in chloride ion corrosion environments,while MnO-SiO_(2)oxides demonstrated higher electrochemical activity and were more prone to dissolve and form pits.Meanwhile,IHT significantly reduced the dislocation density of stainless steel,rendering it more stable in corrosive environments.X-ray photoelectron spectroscopy peak distributions of the passive films demonstrated that IHT increased the proportion of Cr and Fe oxides and hydroxides in the passive film which improved the stability and corrosion resistance of the steel.
基金Projects(51161011,11364024)supported by the National Natural Science Foundation of China
文摘Based on the entropy function, a two-dimensional phase field model of binary alloys was established. Meanwhile, an explicit difference method with uniform grid was adopted to solve the phase field and solute field controlled equations. And the alternating direction implicit(ADI) algorithm for solving temperature field controlled equation was also employed to avoid the restriction of time step. Some characteristics of the Ni-Cu alloy were captured in the process of non-isothermal solidification, and the comparative analysis of the isothermal and the non-isothermal solidification was investigated. The simulation results indicate that the non-isothermal model is favorable to simulate the real solidification process of binary alloys, and when the thermal diffusivity decreases, the non-isothermal phase-field model is gradually consistent with the isothermal phase-field model.
基金Project(51464008) supported by the National Natural Science Foundation of ChinaProject(KY[2012]004) supported by the Key Laboratory Item of Education Office in Guizhou Province,China
文摘The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was applied to analyzing the kinetics behavior of Mg-Ni hydride. The calculation results show that the theoretical value and the experimental data can reach a good agreement, especially in the case of non-isothermal dehydriding. The rate-controlling step is the diffusion of hydrogen atoms in the solid solution. The sample prepared under magnetic field of 6 T under the isothermal condition can reach the best performance. The similar tendency was observed under the non-isothermal condition and the reason was discussed.
基金supported by the Sichuan Provincial Regional Innovation Cooperation Project(No.2024YFHZ0159).
文摘Semicrystalline polymers usually undergo multilevel microstructural evolutions with annealing and stretching processes,which is es-sential to tailor the physical properties of the polymer.Here,poly(butylene carbonate)(PBC)sheets were prepared via isothermal annealing and unidirectional pre-stretching processes,then the changes of PBC in crystallinity,mechanical properties,thermal properties and microscopic changes before and after annealing and stretching were measured,as well as the relationship between microstructure and macroscopic proper-ties before and after stretching.The strengthening mechanism of PBC was also described.It was demonstrated that shish-kabab structure emerged under the pre-stretching process.With the increase of the tensile ratio,the crystallinity,structure and mechanical properties are in-creased differently.Among them,the crystallinity and tensile strength after annealing-stretching treatment increased to 24.45%and 104.5 MPa,respectively,which were about 1.55 times and 3.4 times of those-without any treatment.
基金financially supported by the Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking (No. KF-20-3)Shandong Postdoctoral Science Foundation, China (No. SDCX-ZG-202301014)。
文摘Silicomanganese dust contains large amounts of valuables,such as Si and Mn,which can be used as raw materials for the smelting of silicomanganese.However,the direct addition of dust to the submerged arc furnace can influence the permeability of burden due to the fine particle size of dust,which results in incomplete reduction reactions during the smelting process.In this paper,silicomanganese dust,graphite powder,and other additives were pressed to form carbon-containing dust briquettes,and the self-reduction process of the dust briquettes was investigated through the isothermal thermogravimetric method with different carbon–oxygen (C/O) molar ratios,contents of fluxing agents,and reduction temperatures.Various reduction kinetic models for dust briquettes at different temperatures were established.The results show that the reaction fraction of the dust briquettes was about 90%at a C/O molar ratio of 1.2 with optimal reduction efficiency.The addition of CaF_(2)contributed to the decrease in the melting point and viscosity of dust briquettes,which increased their reduction rate.As the reduction temperature increased,the reduction rate of dust briquettes increased.The reduction reaction rate of dust briquettes was controlled through gas-phase diffusion.Meanwhile,their reduction process was analyzed kinetically,with the reaction time of 5 min as the dividing line.The apparent activation energies for the two diffusion stages were 56.10 and 100.52 kJ/mol,respectively.The kinetic equations are expressed as[1-(1-f)^(1/3)]^(2)=0.69e^(-56100/(RT))t and [1-(1-f)^(1/3)]^(2)=2.06e^(-100520/(RT))t.
基金supported by the National Natural Science Foundation of China(No.52204302)Young Elite Scientist Sponsorship Program by CAST(No.YESS20220533)+1 种基金Hunan Provincial Natural Science Foundation of China(No.2022JJ50274)China Baowu Low Carbon Metallurgy Innovation Foundation(No.BWLCF202103).
文摘The factors affecting the oxidation degree of vanadium–titanium magnetite (VTM) pellets were analyzed via the isothermal oxidation experiment. Furthermore, the oxidation kinetics of VTM pellets were explored through linear fitting to the kinetic equations based on the shrinking unreacted-core model. The results reveal that VTM pellets undergo oxidation in three distinct phases: pre-oxidation, mid-oxidation, and final stable phase. Notably, the mid-oxidation phase is absent in magnetite oxidation. The shrinking unreacted-core model has been proven to be suitable for modeling the process of oxidizing VTM pellets. In the pre-oxidation stage, the rate-controlling step is determined by both the oxidation temperature and the effective oxygen concentration. The influence of the effective oxygen concentration on the rate of oxidation is more pronounced at temperatures between 1073 and 1273 K, especially when the oxygen content falls below 15 vol.%. For the production of oxidized VTM pellets, it is necessary to maintain a preheating temperature above 1173 K (to accelerate the oxidation reaction) and below 1473 K (to prevent the swift formation of compact Fe2TiO5 at the shell of the pellet) in an oxygen-enriched atmosphere.
基金supported by National Natural Science Foundation of China(No.52204302)Young Elite Scientist Sponsorship Program by CAST(No.YESS20220533)Hunan Provincial Natural Science Foundation of China(No.2022JJ40625).
文摘The isothermal oxidation kinetics of vanadium–titanium magnetite(VTM)pellets prepared with 3Co-binder(coal-based colloidal composite binder)and F-binder(pulverized Funa binder)are compared.The oxidation process was analyzed using the first-order irreversible reaction,following the shrinking unreacted nucleus model.The results demonstrate that VTM pellets prepared with 3Co-binder exhibit a faster oxidation rate than those with F-binder across the temperatures ranging from 1073 to 1473 K.In both cases,the oxidation process was controlled by an interfacial chemical reaction during the pre-oxidation stage and by internal diffusion during the mid-oxidation stage.The type of binder did not influence the primary oxidation control mechanism of the VTM pellets.However,the apparent rate constants in the pre-oxidation stage and the internal diffusion coefficients in the mid-oxidation stage were higher for pellets with 3Co-binder compared to those with F-binder.The apparent activation energies for the 3Co-binder pellets were similar to those of bentonite,indicating favorable kinetic conditions without negative impacts on the oxidation process.Nonetheless,it is important to note that pellets with F-binder required a longer oxidation time than those with 3Co-binder.
基金Project(51075099) supported by the National Natural Science Foundation of ChinaProject(E201038) supported by Natural Science Foundation of the Heilongjiang Province,China+3 种基金Project(20090460884) supported by the China Postdoctoral Science Foundation Project(SKLSP201121) supported by the Fund of the State Key Laboratory of Solidification Processing in NWPU,ChinaProject (2011RFQXG010) supported by the Harbin City Young Scientists Foundation,ChinaProject(LBH-T1102) supported by the Specially Postdoctoral Science Foundation of Heilongjiang Province,China
文摘The microstructural evolution of AZ61 magnesium alloy predeformed by equal channel angular extrusion（ECAE） during semisolid isothermal treatment（SSIT） was investigated by means of optical metalloscopy and image analysis equipment.The process involved application of ECAE to as-cast alloy at 310 ℃ to induce strain prior to heating in the semisolid region for different time lengths.The results show that extrusion pass,isothermal temperature and processing route have an influence on microstructural evolution of predeformed AZ61 magnesium alloy during SSIT.With the increase of extrusion pass,the solid particle size is reduced gradually.When isothermal temperature increases from 530 ℃ to 560 ℃,the average particle size increases from 22 μm to 35 μm.When isothermal temperature is 575 ℃,the average particle size decreases.The particle size of microstructure of AZ61 magnesium alloy predeformed by ECAE at BC during SSIT is the finest.
基金Project(2009AA03Z423)supported by the High-tech Research and Development Program of ChinaProject(51071055)supported by the National Natural Science Foundation of ChinaProject(HEUFT05038)supported by the Basic Research Foundation of Harbin Engineering University,China
文摘A Mg-8%Al-1%Si alloy with semisolid microstructure was fabricated by isothermal heat treatment process. The effects of isothermal process parameters such as holding temperature and holding time on the microstructure of Mg-8%Al-1%Si alloy were investigated. The results show that a non-dendritic microstructure could be obtained by isothermal heat treatment. With increasing holding temperature from 560 to 575 °C or holding time from 5 to 30 min, the liquid volume fraction increases, the average size of α-Mg grains grows larger and globular tendency becomes more obvious. In addition, the Mg2Si phase transforms from Chinese script shape to granule shape. The morphology modification mechanisium of Mg2Si phase in Mg-8%Al-1%Si alloy during the semisolid isothermal heat treatment was also studied.
基金Projects (50831003, 50571037) supported by the National Natural Science Foundation of China
文摘The formation and evolution characteristics of bcc phase during the isothermal relaxation processes for supercooled-liquid and amorphous Pb were investigated by molecular dynamics simulation and cluster-type index method （CTIM）. It is found that during the relaxation process, the formation and evolution of bcc phase are closely dependent on the initial temperature and structure. During the simulation time scale, when the initial temperature is in the range of supercooled liquid region, the bcc phase can be formed and kept a long time; while it is in the range of glassy region, the bcc phase can be formed at first and then partially transformed into hcp phase; when it decreases to the lower one, the hcp and fcc phases can be directly transformed from the glassy structure without undergoing the metastable bcc phase. The Ostwald＇s ＂step rule＂ is impactful during the isothermal relaxation process of the supercooled and glassy Pb, and the metastable bcc phase plays an important role in the precursor of crystallization.
基金Project (50935007) supported by the National Natural Science Foundation of ChinaProject (2010CB731701) supported by the National Basic Research Program of China
文摘Using simple unequal-thickness billet combining isothermal local loading can control the metal flow and improve the cavity fill in manufacturing process of large-scale rib-web titanium alloy component with low cost and short cycle. The beveling transition pattern is well used for variable-thickness region of billet （VTRB） due to its simple and ample range of transition condition. The transition condition development in the local loading process has a significant influence on dynamic boundary of unrestricted portion of VTRB. With the help of reasonable assumptions, a mathematical model of transition condition development was established by theoretical analysis. The predicted results for local loading process of rib-web component using the established model were compared with the numerical and experimental ones, and the results indicated that the model of transition condition development is reasonable. Using the established model could deal with the dynamic boundary of unrestricted portion of VTRB well, and the model is suitable for the analysis of metal flow and cavity fill in local loading process of multi-ribs component.
基金Projects(50901017,51171043,51271053)supported by the National Natural Science Foundation of ChinaProject(20090042120008)supported by the Doctoral Program Foundation of Institutions of Higher Education of ChinaProject(2011BAE22B04-2)supported by National Key Technology R&D Program of China during the Twelfth Five-Year Plan Period
文摘The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). It is experimentally testified that theα-Mg solid solution is not in equilibrium with the Mg32(Al, Zn)49 (τ) ternary intermetallic compound orq quasicrystalline phase, but only in equilibrium with one ternary intermetallic compound Al5Mg11Zn4 (φ). The whole composition range of theφ phase was also obtained at 335 °C, i.e., 52.5%?56.4% Mg, 13.6%?24.0% Al, 19.6%?33.9% Zn (mole fraction). The solubility of Al in the MgZn phase is remarkably more than that in the Mg7Zn3 phase, and the maximum is about 8.6% Al. Aluminum and zinc are simultaneously soluble in theα-Mg solid solution.
基金Foundation item: Project (50575220) supported by the National Natural Science Foundation of ChinaProject supported by State Key Laboratory of Engines,China
文摘This work was attempted to modify the current technology for thermal barrier coatings（TBCs） by adding an additional step of surface modification,namely,supersonic fine particles bombarding（SFPB） process,on bond coat before applying the topcoat.After isothermal oxidation at 1000 °C for different time,the surface state of the bond coat and its phase transformation were investigated using X-ray diffraction（XRD）,scanning electron microscopy（SEM） equipped with energy-dispersive X-ray spectrometry（EDS）,transmission electron microscopy（TEM） and Cr3＋ luminescence spectroscopy.The dislocation density significantly increases after SFPB process,which can generate a large number of diffusion channels in the area of the surface of the bond coat.At the initial stage of isothermal oxidation,the diffusion velocity of Al in the bond coat significantly increases,leading to the formation of a layer of stable α-Al2O3 phase.A great number of Cr3＋ positive ions can diffuse via diffusion channels during the transient state of isothermal oxidation,which can lead to the presence of（Al0.9Cr0.1）2O3 phase and accelerate the γ→θ→α phase transformation.Cr3＋ luminescence spectroscopy measurement shows that the residual stress increases at the initial stage of isothermal oxidation and then decreases.The residual stress after isothermal oxidation for 310 h reduces to 0.63 GPa compared with 0.93 GPa after isothermal oxidation for 26 h.In order to prolong the lifespan of TBCs,a layer of continuous,dense and pure α-Al2O3 with high oxidation resistance at the interface between topcoat and bond coat can be obtained due to additional SFPB process.
基金supported by grants from Jiangsu Higher Education Institution Innovative Research Team for Science and Technology(2021),the Key Technology Program of Suzhou People’s Livelihood Technology Projects(Grant Nos.SKY2021029,SZS2020311)the Open Project of Jiangsu Biobank of Clinical Resources(TC2021B009)the Qing-Lan Project of Jiangsu Province in China(2021,2022).
文摘Nucleic acid(DNA and RNA)detection and quantification methods play vital roles in molecular biology.With the development of molecular biology,isothermal amplification of DNA/RNA,as a new molecular biology technology,can be amplified under isothermal condition,it has the advantages of high sensitivity,high specificity,and high efficiency,and has been applied in various fields of biotechnology,including disease diagnosis,pathogen detection,food hygiene and safety detection and so on.This paper introduces the progress of isothermal amplification technology,including rolling circle amplification(RCA),nucleic acid sequence-dependent amplification(NASBA),strand displacement amplification(SDA),loop-mediated isothermal amplification(LAMP),helicase-dependent amplification(HDA),recombinase polymerase amplification(RPA),cross-priming amplification(CPA),and its principle,advantages and disadvantages,and application development are briefly summarized.
文摘A reverse-transcription loop-mediated isothermal amplification （RT-LAMP） method was established for the detection of wheat streak mosaic virus （WSMV）. Ac-cording to the conservative regions of the genes that encode the coat protein of WSMV, 2 pairs of primers were designed. Final y, the 1st pair of primers was select-ed through the specificity test. The sensitivity test showed the sensitivity of RT-LAMP method was 10 times higher than that of RT-PCR. In addition, the amplifica-tion of target gene could be judged visual y from the presence of fluorescence （cal-cein） in the final reaction system. The RT-LAMP method, established in this study, was rapid, easy, specific and sensitive. Moreover, it did not require sophisticated equip-ment. The RT-LAMP was suitable for the rapid detection of WSMV.
基金the research committee of Malek-ashtar University of Technology(MUT)
文摘The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 ℃. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminm metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30-330 ℃ at heating rates of 10,15 and 20 ℃·min^(-1).The TG/DTG data were used for determination of activation energy(E_a) of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall(OFW) and Kissinger-Akahira-Sunose(KAS) methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99-120 and 66-70 kJ mol^(-1)respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade.
基金Projects(50731002,50971136)supported by the National Natural Science Foundation of China
文摘An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and a continuous solid solution （Gd,Nd）Mg is also formed between MgGd and MgNd. Mg7Gd, Mg5Gd, Mg2Gd, Mg41Nd5, （Gd,Nd）3Mg and （Gd,Nd）Mg are found in the ternary system. In these intermetallic phases, Mg7Gd has been reported to be a metastable phase in previous literatures. The solubilities of Mg, Gd and Nd in all the phases were detected. Furthermore, four three-phase equilibria, α（Mg）＋Mg7Gd＋Mg41Nd5, Mg7Gd＋Mg5Gd＋Mg41Nd5, Mg5Gd＋Mg41Nd5＋（Gd,Nd）3Mg and （Gd,Nd）3Mg＋（Gd,Nd）Mg＋Mg2Gd, were identified in the isothermal section.
文摘The kinetics of nonisothermal and isothermal crystallization of metallocene catalyzed and conventional polyethylenes has been studied by differential scanning calorimetry. Using Avrami equation, Ozawa theory and Mo Zhishen method, the experimental data have been analyzed. It is shown that metallocene polyethylene possesses a higher rate of crystallization due to a higher stereoregularity of its molecular chains. Moreover, they have different nonisothermal crystallization mechanisms and identical isothermal crystallization mechanisms.
基金Project(3102014JCQ01026)supported by the Fundamental Research Fund for the Central Universities,ChinaProject(B08040)supported by the Program of Introducing Talents of Discipline to Universities,China
文摘Effect of isothermal holding treatment in the solidification process on the microstructure of Ti-6Al-4V alloy was studied by temperature controlled induced melting apparatus. The result shows that with isothermal holding treatment above the β transus temperature during solidification, the colony structure consisting of parallel lamellae was obtained. While the isothermal holding treatment was set at 960 °C, a unique bi-modal microstructure consisting of coarse primary α and fine secondary lamellar α was obtained. The primary lamellar α tended to break into several pieces, globularize and present equiaxed morphology. The formation mechanism of the equiaxed α can be explained with the atom immigration, high density dislocations, combined action with the interface tension of formed α phase during the isothermal holding treatment. After the isothermal holding, the retained β matrix transformed into fine lamellar α, thus, bi-modal microstructure was acquired. Compared with the lamellar structure, the grain boundary α presented discontinuously and cannot be distinguished from the primary α lamellae easily. The size of colonies α was greatly decreased. The microstructure tended to be much more homogeneous in the whole section of the samples.
