The current recovery technique of Sc was complicated and the chemical consumption was high,This was due to the low content of Sc in resources and the difficulty of stripping.In this research,the isooctanol was added i...The current recovery technique of Sc was complicated and the chemical consumption was high,This was due to the low content of Sc in resources and the difficulty of stripping.In this research,the isooctanol was added into the 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester(P507)extraction system to reduce the extraction and improve the stripping of Sc.The maximum stripping ratio of Sc from loaded organic phase by sulfuric acid can increase from 10%(without isooctanol)to 99%(with 15 vol%isooctanol).In the extraction test of the simulated red mud leaching liquor,the separation factors between Sc and Zr,Sc and Ti are 36 and 350,separately.At the same time,other metals are almost not extracted.The high selectivity and stripping of Sc suggest that the P507 with isooctanol extraction system can be applied in the practical Sc recovery process.展开更多
基金Project supported by the National Basic Research Program of China(2012CBA01202)the National Natural Science Foundation of China(51174184)
文摘The current recovery technique of Sc was complicated and the chemical consumption was high,This was due to the low content of Sc in resources and the difficulty of stripping.In this research,the isooctanol was added into the 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester(P507)extraction system to reduce the extraction and improve the stripping of Sc.The maximum stripping ratio of Sc from loaded organic phase by sulfuric acid can increase from 10%(without isooctanol)to 99%(with 15 vol%isooctanol).In the extraction test of the simulated red mud leaching liquor,the separation factors between Sc and Zr,Sc and Ti are 36 and 350,separately.At the same time,other metals are almost not extracted.The high selectivity and stripping of Sc suggest that the P507 with isooctanol extraction system can be applied in the practical Sc recovery process.
文摘采用P2O5为磷酸化试剂,研究了异辛醇聚氧乙烯醚[C8H17(EO)4OH]磷酸酯的合成工艺,取得了优化工艺条件:P2O5分批加料,加料温度≤40℃,原料配比n[C8H17(EO)4OH]n∶(P2O5)为2.61∶,70℃,酯化时间4h,水解温度80℃,水解时间2h.该产品性能:220g/L强烧碱溶液中不会产生漂油现象,渗透时间为4 s.
