[Objective]The aim was to discuss the actinomycete biodiversity of iron-mine tailings by phylogenetic analysis of 12 typical isolates. [Method]The genomic DNAs were extracted by phenol-chloroform method; phylogeny ana...[Objective]The aim was to discuss the actinomycete biodiversity of iron-mine tailings by phylogenetic analysis of 12 typical isolates. [Method]The genomic DNAs were extracted by phenol-chloroform method; phylogeny analysis was carried out based on 16S rDNA PCR amplification and sequencing. [Result]The results showed that all the 12 strains belong to the genus Streptomyces sharing 98.7%-99.9% similarities with their nearest known neighbors. [Conclusion]Streptomyces is the dominant culturable actinomycete group of iron mine tailings,in which there are many potential novel species.展开更多
The conversion of subtropical red soils into farmland involves complex transformations of iron oxides.Investigating iron mineralogy can enhance understanding of magnetic minerals in relation to soil formation on farml...The conversion of subtropical red soils into farmland involves complex transformations of iron oxides.Investigating iron mineralogy can enhance understanding of magnetic minerals in relation to soil formation on farmland in subtropical regions.In this study,we investigated the properties of iron oxide and its environmental implications in the farmland of Meizhou city,Guangdong province.The results showed that farmland soils had higher magnetism than the red soils developed from the same metamorphic rock.The red soils displayed significantly higher concentrations of goethite and hematite than the farmland soils.The dominant factor influencing the magnetic changes in farmland and red soils was the concentration of fine-grained ferromagnetic minerals.Red soil magnetism is an indicator of soil weathering intensity,whereas farmland soil magnetism is closely related to human cultivation activities.In contrast to the red soils,the farmland soils lacked the pronounced transformation of ferromagnetic minerals into hematite and goethite.A vigorous oxidation process catalyzes the transformation of strong magnetic minerals into significant amounts of hematite and goethite,which promotes the reduced magnetism of red soils.The conversion of red soils into farmland soils initially increased the accumulation of ferromagnetic materials due to cultivation processes.However,long-term cultivation led to the gradual loss of fine-grained ferromagnetic minerals,while goethite and lepidocrocite became the dominant magnetic mineral types.展开更多
The mineralogical characteristics of three kinds of gibbsitic high-iron bauxite and the effects of various digestion conditions on the enrichment and separation of iron minerals were investigated. The results show tha...The mineralogical characteristics of three kinds of gibbsitic high-iron bauxite and the effects of various digestion conditions on the enrichment and separation of iron minerals were investigated. The results show that adding an appropriate organic reductant such as glycerol can promote the digestion of concomitant diaspore, boehmite and alumogoethite as well as the conversion of goethite to hematite in the reductive Bayer digestion. Processing Bauxite A with A/S of 25.41 can directly produce qualified iron concentrates(TFe>56%) by the reductive Bayer digestion, and thus realize the zero red mud discharge. For Bauxite B and Bauxite C with A/S of 7.82 and 3.35, the iron recoveries of 65.13% and 79.13% can be achieved with the corresponding TFe of 52.05% and 50.16% in the iron concentrates by gravity separation, respectively, resulting in the red mud discharge reduction of ~50% or above.展开更多
In order to obtain the distribution rules of in situ stress and mining-induced stress of Beiminghe Iron Mine, the stress relief method by overcoring was used to measure the in situ stress, and the MC type bore-hole st...In order to obtain the distribution rules of in situ stress and mining-induced stress of Beiminghe Iron Mine, the stress relief method by overcoring was used to measure the in situ stress, and the MC type bore-hole stress gauge was adopted to measure the mining-induced stress. In the in situ stress measuring, the technique of improved hollow inclusion cells was adopted, which can realize complete temperature compensation. Based on the measuring results, the distribution model of in situ stress was established and analyzed. The in situ stress measuring result shows that the maximum horizontal stress is 1.75-2.45 times of vertical stress and almost 1.83 times of the minimum horizontal stress in this mineral field. And the mining-induced stress measuring result shows that, according to the magnitude of front abutment pressure the stress region can be separated into stress-relaxed area, stress- concentrated area and initial stress area. At the -50 m mining level of this mine, the range of stress-relaxed area is 0-3 m before mining face; the range of stress-concentrated area is 3-55 m before mining face, and the maximum mining-induced stress is 16.5-17.5 MPa, which is 15-20 m from the mining face. The coefficient of stress concentration is 1.85.展开更多
This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the...This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the hydrogeological parameters of the aquifer in the study area, the model was calibrated and validated using the observed heads through the integrated trial-and-error and automated techniques. Also, the sensitivity analysis of the model was performed to evaluate the uncertainty associated with the calibrated model. According to the mine construction plan at different mining levels of-500 m,-600 m, and-700 m, the calibrated model was then applied to predict the water yields dependent on the different mining levels. As indicated by the prediction results, the numerical simulation model can systematically describe the groundwater system in the mining area and determine the source of water inrush in this iron mine. In conclusion, numerical analyses carried out in this study can provide guidance to decision-makers in balancing the iron ore mining and mine dewatering in the future.展开更多
Mineral exploration is done by different methods. Geophysical and geochemical studies are two powerful tools in this field. In integrated studies, the results of each study are used to determine the location of the dr...Mineral exploration is done by different methods. Geophysical and geochemical studies are two powerful tools in this field. In integrated studies, the results of each study are used to determine the location of the drilling boreholes. The purpose of this study is to use field geophysics to calculate the depth of mineral reserve. The study area is located 38 km from Zarand city called Jalalabad iron mine. In this study, gravimetric data were measured and mineral depth was calculated using the Euler method. 1314 readings have been performed in this area. The rocks of the region include volcanic and sedimentary. The source of the mineralization in the area is hydrothermal processes. After gravity measuring in the region, the data were corrected, then various methods such as anomalous map remaining in levels one and two, upward expansion, first and second-degree vertical derivatives, analytical method, and analytical signal were drawn, and finally, the depth of the deposit was estimated by Euler method. As a result, the depth of the mineral deposit was calculated to be between 20 and 30 meters on average.展开更多
Dark formation of hydroxyl radical upon oxidation of reduced iron minerals plays an important role in the degradation and transformation of organic and inorganic pollutants.Herein,we compared the hydroxyl radical form...Dark formation of hydroxyl radical upon oxidation of reduced iron minerals plays an important role in the degradation and transformation of organic and inorganic pollutants.Herein,we compared the hydroxyl radical formation from various reduced iron minerals at different redox conditions.·OH production was generally observed from the oxidation of reduced iron minerals,following the order:mackinawite(FeS)>reduced nontronite(iron-bearing smectite clay)> pyrite(FeS2)> side rite(FeCO3).Structural Fe^2+ and dissolved O2 play critical roles in ·OH production from reduced iron minerals.·OH production increases with decreasing pH,and Cl^-has little effect on this process.More importantly,dissolved organic matter significantly enhances ·OH production,especially under O2 purging,highlighting the importance of this process in ambient environments.This sunlight-independent pathway in which ’OH forms during oxidation of reduced iron minerals is helpful for understanding the degradation and transformation of various inorganic and organic pollutants in the redox-fluctuation environments.展开更多
Selection of the crusher required a great deal of design regarding to the mine planning. Selection of suitable primary crusher from all of available primary crushers is a multi-criterion decision making(MCDM) problem....Selection of the crusher required a great deal of design regarding to the mine planning. Selection of suitable primary crusher from all of available primary crushers is a multi-criterion decision making(MCDM) problem. The present work explores the use of technique for order performance by similarity to ideal solution(TOPSIS) with fuzzy set theory to select best primary crusher for Golegohar Iron Mine in Iran. Gyratory, double toggle jaw, single toggle jaw, high speed roll crusher, low speed sizer, impact crusher, hammer mill and feeder breaker crushers have been considered as alternatives. Also, the capacity, feed size, product size, rock compressive strength, abrasion index and application of primary crusher for mobile plants were considered as criteria for solution of this MCDM problem. To determine the order of the alternatives, closeness coefficient is defined by calculating the distances to the fuzzy positive ideal solution(FPIS) and fuzzy negative ideal solution(FNIS). Results of our work based on fuzzy TOPSIS method show that the gyratory is the best primary crusher for the studied mine.展开更多
This paper compares analytical and numerical methods by taking the forecasting of water yield of deep-buried iron mine in Yanzhou, Shandong as an example. Regarding the analytical method, the equation of infinite and ...This paper compares analytical and numerical methods by taking the forecasting of water yield of deep-buried iron mine in Yanzhou, Shandong as an example. Regarding the analytical method, the equation of infinite and bilateral water inflow boundary is used to forecast the water yield, and in the case of numerical simulation, we employed the GMS software to establish a model and further to forecast the water yield. On the one hand, through applying the analytical method, the maximum water yield of mine 1 500 m deep below the surface was calculated to be 13 645.17 m3/d; on the other hand, through adopting the numerical method, we obtained the predicted result of 3 816.16 m3/d. Meanwhile, by using the boundary generalization in the above-mentioned two methods, and through a comparative analysis of the actual hydro-geological conditions in this deep-buried mine, which also concerns the advantages and disadvantages of the two methods respectively, this paper draws the conclusion that the analytical method is only applicable in ideal conditions, but numerical method is eligible to be used in complex hydro-geological conditions. Therefore, it is more applicable to employ the numerical method to forecast water yield of deep-buried iron mine in Yanzhou, Shandong.展开更多
Dissolved organic matter(DOM)and iron minerals widely existing in the natural aquatic environment can mediate the migration and transformation of organic pollutants.However,the mechanism of interaction between DOM and...Dissolved organic matter(DOM)and iron minerals widely existing in the natural aquatic environment can mediate the migration and transformation of organic pollutants.However,the mechanism of interaction between DOM and iron minerals in the microbial degradation of pollutants deserves further investigation.In this study,the mechanism of 17 alphaethinylestradiol(EE2)biodegradation mediated by humic acid(HA)and three kinds of iron minerals(goethite,magnetite,and pyrite)was investigated.The results found that HA and iron minerals significantly accelerated the biodegradation process of EE2,and the highest degradation efficiency of EE2(48%)was observed in the HA-mediated microbial system with pyrite under aerobic conditions.Furthermore,it had been demonstrated that hydroxyl radicals(HO·)was the main active substance responsible for the microbial degradation of EE2.HO·is primarily generated through the reaction between hydrogen peroxide secreted by microorganisms and Fe(II),with aerobic conditions being more conducive.The presence of iron minerals and HA could change the microbial communities in the EE2 biodegradation system.These findings provide new information for exploring the migration and transformation of pollutants by microorganisms in iron-rich environments.展开更多
An underground iron mine in China has been used as a case-study to research the subsidence due to ore extraction and backfilling during open stoping operations. A 3-D discontinuum numerical model was built incorporati...An underground iron mine in China has been used as a case-study to research the subsidence due to ore extraction and backfilling during open stoping operations. A 3-D discontinuum numerical model was built incorporating geologic complexities including faults and interfaces between different lithologies,and the stoping and backfilling sequence adopted from the mine plans. The stoping was carried out in two vertically stacked horizontal layers, with a total of 16 stopes. Large displacements of up to 50 cm were observed along the roof of the stopes, and a maximum surface subsidence of 22.5 cm was observed.Backfilling was found to eliminate subsequent displacements and subsidence. The extraction of the upper orebody was found to influence displacements in the lower orebody. Finally, a subsidence profile was constructed to show the subsidence at all locations along the length of the surface and region of influence on the surface.展开更多
Based on the analyses of the character of the exploitation of the iron ore resource and its destruction of eco-environment in Tangshan area,this paper puts forward the patterns of land reclamation which fits for this ...Based on the analyses of the character of the exploitation of the iron ore resource and its destruction of eco-environment in Tangshan area,this paper puts forward the patterns of land reclamation which fits for this area.The patterns include the reclamation of ecological agriculture,planting directly on the tailing bin without covering soil,reclamation of mine tailings in the pool,and improvement of the soil quality by using tailings etc.Now,over 700hm^2 land has been reclaimed by taking advantage of the pattern in Tangshan and eight typical reclamation districts have been built.The rates of reclamation exceed 80%and have reached the advanced level of the world.Practice has proved that the eco-environment of the ore area has been greatly improved and the remarkable economic and social benefits have been gained.展开更多
Malignant transformation of hamsterembryo cells was induced in vitro by rareearth iron mineral dusts(MP),naturalthorium(Th02) and MP plus Th02.Dusts of MP,MP plus Th02 or Th02 were added into themedium with the final ...Malignant transformation of hamsterembryo cells was induced in vitro by rareearth iron mineral dusts(MP),naturalthorium(Th02) and MP plus Th02.Dusts of MP,MP plus Th02 or Th02 were added into themedium with the final concentration of 17.0,展开更多
The micromorphology and physicochemical properties of hydrophobic blasting dust(HBD)from an iron mine were comprehensively analyzed by laser particle size analysis(LPSA),scanning electron microscopy(SEM),X-ray diffrac...The micromorphology and physicochemical properties of hydrophobic blasting dust(HBD)from an iron mine were comprehensively analyzed by laser particle size analysis(LPSA),scanning electron microscopy(SEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that the HBD particles can be classified into three types based on their particle size(PS):larger particles(PS>10μm),medium particles(1μm≤PS≤10μm),and nanoparticles(PS<1μm).The cumulative volume of respirable dust(PS≤10μm)was 84.45%.In addition,three shapes of HBD were observed by SEM:prism,flake,and bulk.In particular,the small particles were mostly flaky,with a greater possibility of being inhaled.Furthermore,the body and surface chemical compounds of HBD were determined by XRD and XPS,respectively.Ammonium adipate(C6H16N2O4)was the only organic compound in the body of HBD,but its mass fraction was only 13.4%.However,the content of organic C on the surface of HBD was 85.35%.This study demonstrated that the small-particle size and large amount of organic matter on the surface of HBD are the main reasons for its hydrophobicity,which can provide important guidance for controlling respirable dust in iron mines.展开更多
This study explores the key physicochemical factors affecting the hydrophilic characteristics of iron mine blasting dust(BD). The BD is separated into an unwetted part(UWBD, hydrophobic part) and a wetted part(WBD, hy...This study explores the key physicochemical factors affecting the hydrophilic characteristics of iron mine blasting dust(BD). The BD is separated into an unwetted part(UWBD, hydrophobic part) and a wetted part(WBD, hydrophilic part). Its particle size, true density(TD), pore parameters, mineral composition, and surface compounds are comprehensively characterized and compared. The results indicate that a smaller particle size and more developed pore parameters are two key factors responsible for the strong hydrophobicity of the BD. The mineral composition of the BD has no direct effect on its wetting properties;however, it indirectly influences the deposition characteristics of the BD in water by affecting its TD. Unlike coal dust, the surface organic composition of the BD does not affect its wettability and the peak area of C–C/C–H hydrophobic groups in the C 1s X-ray photoelectron spectrum of the UWBD(45.03%) is smaller than that in the C 1s spectrum of the WBD(68.30%). Thus, eleven co-influencing processes of physicochemical properties of the BD on its wettability are summarized. This research sheds light on the key factors affecting the wettability of the BD.展开更多
Microbially mediated bioreduction of iron oxyhydroxide plays an important role in the biogeochemical cycle of iron.Geobacter sulfurreducens is a representative dissimilatory ironreducing bacterium that assembles elect...Microbially mediated bioreduction of iron oxyhydroxide plays an important role in the biogeochemical cycle of iron.Geobacter sulfurreducens is a representative dissimilatory ironreducing bacterium that assembles electrically conductive pili and cytochromes.The impact of supplementation withγ-Fe_2O_3 nanoparticles(NPs)(0.2 and 0.6 g)on the G.sulfurreducens-mediated reduction of ferrihydrite was investigated.In the overall performance of microbial ferrihydrite reduction mediated byγ-Fe_2O_3 NPs,stronger reduction was observed in the presence of direct contact withγ-Fe_2O_3 NPs than with indirect contact.Compared to the production of Fe(Ⅱ)derived from biotic modification with ferrihydrite alone,increases greater than 1.6-and 1.4-fold in the production of Fe(Ⅱ)were detected in the biotic modifications in which direct contact with 0.2 g and 0.6 gγ-Fe_2O_3 NPs,respectively,occurred.X-ray diffraction analysis indicated that magnetite was a unique representative iron mineral in ferrihydrite when active G.sulfurreducens cells were in direct contact withγ-Fe_2O_3 NPs.Because of the sorption of biogenic Fe(Ⅱ)ontoγ-Fe_2O_3 NPs instead of ferrihydrite,the addition ofγ-Fe_2O_3 NPs could also contribute to increased duration of ferrihydrite reduction by preventing ferrihydrite surface passivation.Additionally,electron microscopy analysis confirmed that the direct addition ofγ-Fe_2O_3 NPs stimulated the electrically conductive pili and cytochromes to stretch,facilitating long-range electron transfer between the cells and ferrihydrite.The obtained findings provide a more comprehensive understanding of the effects of iron oxide NPs on soil biogeochemistry.展开更多
Numerous studies have demonstrated that Na2SO4 can significantly inhibit the reduction of iron oxide in the selective reduction process of laterite nickel ore. FeS generated in the process plays an important role in s...Numerous studies have demonstrated that Na2SO4 can significantly inhibit the reduction of iron oxide in the selective reduction process of laterite nickel ore. FeS generated in the process plays an important role in selective reduction, but the generation process of FeS and its inhibition mechanism on iron reduction are not clear. To figure this out, X-ray diffraction and scanning electron microscopy analyses were conducted to study the roasted ore. The results show that when Na2SO4 is added in the roasting, the FeO content in the roasted ore increases accompanied by the emergence of FeS phase. Further analysis indicates that NaeS formed by the reaction of Na2SO4 with CO reacts with SiO2 at the FeO surface to generate FeS and Na2Si2Os. As a result, a thin film forms on the surface of FeO, hindering the contact between reducing gas and FeO. Therefore, the reduction of iron is depressed, and the FeO content in the roasted ore increases.展开更多
The Alagxa Plateau, in the margin of the northeastern Tibetan Plateau, is one of the most important dust source areas in East Asia, and the widespread sandy desert in the area is important both as a reservoir and a so...The Alagxa Plateau, in the margin of the northeastern Tibetan Plateau, is one of the most important dust source areas in East Asia, and the widespread sandy desert in the area is important both as a reservoir and a source of eolian silty. The northeastern margin of the Tibetan Plateau is one of the most actively-growing mountain belt on earth, and has large amounts of debris, with masses of fine grained material, which were continuously mobilized and deposited in the Alagxa Plateau by rivers, forming broad alluvial fans. It is possible that the role of fluvial sediments as a source of silty dust in the Alagxa Plateau has been underestimated. In this study, we test this hypothesis by investigating the iron mineralogical and geochemical characteristics of the fluvial sediments and the surface material of the sandy desert in the Alagxa Plateau, and comparing them with paleo-eolian dust deposits(loess) in the adjacent Chinese Loess Plateau(CLP) to investigate the possible linkages among the fluvial sediments, sandy desert and the last glacial loess of the CLP. The results show that sandy desert typically have high contents of goethite, and high ratios of goethite to hematite, similar to the fluvial sediments in the Alagxa Plateau. Based on the major element characteristics, field investigations and the results of previous studies, we found a genetic link between the silt component of the fluvial sediments and the sandy desert in the Alagxa Plateau with high value of Gt(goethite) and similarity of the Gt/(Hm(hematite)+Gt) ratio. But the silt component of the sandy desert main come from the adjacent fluvial sediments. The iron mineralogical characteristics(χ(magnetic susceptibility), χARM(anhysteretic susceptibility), SIRM(saturation isothermal remanent magnetization) and SIRM_(AF100 mT)(SIRM demagnetized at 100 mT)) of the CLP samples overlap with those of the fluvial sediments in the Alagxa Plateau, but there is a mismatch with the sandy desert samples. This suggests that the fluvial sediments are the source of a large amount of silty material which could be transported to the CLP. Therefore, we conclude that the fluvial sediment in the Alagxa Plateau is an important source of eolian silt, which is deposited in downwind region, and that this source has been previously underestimated.展开更多
Iron mineralizations in the study area are found in amphibolites in the localities of Buyukoren,Uzunkuyu-Atkayasi,and Karabacak and they display a predominantly banded texture.Their paragenesis is dominated by magneti...Iron mineralizations in the study area are found in amphibolites in the localities of Buyukoren,Uzunkuyu-Atkayasi,and Karabacak and they display a predominantly banded texture.Their paragenesis is dominated by magnetite and hematite.In this study,iron mineralizations in Sarikaya were examined in terms of rare earth element(REE) contents and attempts were made to determine some physicochemical conditions that had an impact upon their formation.For this purpose,42 ore samples and 17 enriched magnetite samples...展开更多
A geophysical survey was conducted in the Kelle-Bidjocka village, Messondo subdivision, in the Centre Region, Cameroon. The data acquisition was made by combining Schlumberger profiling and electrical soundings along ...A geophysical survey was conducted in the Kelle-Bidjocka village, Messondo subdivision, in the Centre Region, Cameroon. The data acquisition was made by combining Schlumberger profiling and electrical soundings along six (06) profiles of 1500 m in length for a total of 64 geoelectrical stations’ survey conducted through a variable mesh 100 m × 200 m, or 100 m × 300 m. The equipment used is the DC resistivimeter Syscal Junior 48 (Iris Instrument). Processing and modelling of field data are made by using the Res2Dinv, Qwseln and Surfer software. The investigation methods used are electrical resistivity (DC) and induced polarization (IP) methods. The analyses and interpretations have helped to highlight areas of weakness or conductive discontinuities (fractures, faults, shear zones, etc.) in Precambrian gneiss formations, sometimes undergoing weathering processes. They identify the weathering or mineralogical accumulation horizons, the most promising is a mineralization channel identified in the NE-SW direction. The highlighted mineralization is characterized by strong gradients of chargeability or polarization. Samples and other geological evidences observed in the area are used to associate the most polarizable structures with ferriferous formations. Weakly polarizable and particularly conductive backgrounds identified by the inverse pseudo-sections are thought to be sulphate minerals or groundwater targets for future hydrogeological studies.展开更多
基金Supported by National Natural Science Foundation of China(30800003)Provincial Foundation Advanced Project of Hebei Uni-versity (2006Y09)~~
文摘[Objective]The aim was to discuss the actinomycete biodiversity of iron-mine tailings by phylogenetic analysis of 12 typical isolates. [Method]The genomic DNAs were extracted by phenol-chloroform method; phylogeny analysis was carried out based on 16S rDNA PCR amplification and sequencing. [Result]The results showed that all the 12 strains belong to the genus Streptomyces sharing 98.7%-99.9% similarities with their nearest known neighbors. [Conclusion]Streptomyces is the dominant culturable actinomycete group of iron mine tailings,in which there are many potential novel species.
基金Technology Program of Jiaying University,No.2024KJZ01Open Funding of Guangdong Provincial Key Laboratory of Conservation and Precision Utilization of Characteristic Agricultural Resources in Mountainous Areas,No.2023JYKF08National Natural Science Foundation of China,No.42277442。
文摘The conversion of subtropical red soils into farmland involves complex transformations of iron oxides.Investigating iron mineralogy can enhance understanding of magnetic minerals in relation to soil formation on farmland in subtropical regions.In this study,we investigated the properties of iron oxide and its environmental implications in the farmland of Meizhou city,Guangdong province.The results showed that farmland soils had higher magnetism than the red soils developed from the same metamorphic rock.The red soils displayed significantly higher concentrations of goethite and hematite than the farmland soils.The dominant factor influencing the magnetic changes in farmland and red soils was the concentration of fine-grained ferromagnetic minerals.Red soil magnetism is an indicator of soil weathering intensity,whereas farmland soil magnetism is closely related to human cultivation activities.In contrast to the red soils,the farmland soils lacked the pronounced transformation of ferromagnetic minerals into hematite and goethite.A vigorous oxidation process catalyzes the transformation of strong magnetic minerals into significant amounts of hematite and goethite,which promotes the reduced magnetism of red soils.The conversion of red soils into farmland soils initially increased the accumulation of ferromagnetic materials due to cultivation processes.However,long-term cultivation led to the gradual loss of fine-grained ferromagnetic minerals,while goethite and lepidocrocite became the dominant magnetic mineral types.
基金Project(2019M652799)supported by China Postdoctoral Science FoundationProject(51604309)supported by the National Natural Science Foundation of China。
文摘The mineralogical characteristics of three kinds of gibbsitic high-iron bauxite and the effects of various digestion conditions on the enrichment and separation of iron minerals were investigated. The results show that adding an appropriate organic reductant such as glycerol can promote the digestion of concomitant diaspore, boehmite and alumogoethite as well as the conversion of goethite to hematite in the reductive Bayer digestion. Processing Bauxite A with A/S of 25.41 can directly produce qualified iron concentrates(TFe>56%) by the reductive Bayer digestion, and thus realize the zero red mud discharge. For Bauxite B and Bauxite C with A/S of 7.82 and 3.35, the iron recoveries of 65.13% and 79.13% can be achieved with the corresponding TFe of 52.05% and 50.16% in the iron concentrates by gravity separation, respectively, resulting in the red mud discharge reduction of ~50% or above.
基金Projects(10702072, 10632100) supported by the National Nature Science Foundation of China
文摘In order to obtain the distribution rules of in situ stress and mining-induced stress of Beiminghe Iron Mine, the stress relief method by overcoring was used to measure the in situ stress, and the MC type bore-hole stress gauge was adopted to measure the mining-induced stress. In the in situ stress measuring, the technique of improved hollow inclusion cells was adopted, which can realize complete temperature compensation. Based on the measuring results, the distribution model of in situ stress was established and analyzed. The in situ stress measuring result shows that the maximum horizontal stress is 1.75-2.45 times of vertical stress and almost 1.83 times of the minimum horizontal stress in this mineral field. And the mining-induced stress measuring result shows that, according to the magnitude of front abutment pressure the stress region can be separated into stress-relaxed area, stress- concentrated area and initial stress area. At the -50 m mining level of this mine, the range of stress-relaxed area is 0-3 m before mining face; the range of stress-concentrated area is 3-55 m before mining face, and the maximum mining-induced stress is 16.5-17.5 MPa, which is 15-20 m from the mining face. The coefficient of stress concentration is 1.85.
基金financially supported by the National Natural Science Foundation of China(No.41402198 and 41372235)Jiangsu Natural Science Fund-Youth Fund(No.BK20131009)the Fundamental Research Funds for the Central Universities(No.2014B03614)
文摘This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the hydrogeological parameters of the aquifer in the study area, the model was calibrated and validated using the observed heads through the integrated trial-and-error and automated techniques. Also, the sensitivity analysis of the model was performed to evaluate the uncertainty associated with the calibrated model. According to the mine construction plan at different mining levels of-500 m,-600 m, and-700 m, the calibrated model was then applied to predict the water yields dependent on the different mining levels. As indicated by the prediction results, the numerical simulation model can systematically describe the groundwater system in the mining area and determine the source of water inrush in this iron mine. In conclusion, numerical analyses carried out in this study can provide guidance to decision-makers in balancing the iron ore mining and mine dewatering in the future.
文摘Mineral exploration is done by different methods. Geophysical and geochemical studies are two powerful tools in this field. In integrated studies, the results of each study are used to determine the location of the drilling boreholes. The purpose of this study is to use field geophysics to calculate the depth of mineral reserve. The study area is located 38 km from Zarand city called Jalalabad iron mine. In this study, gravimetric data were measured and mineral depth was calculated using the Euler method. 1314 readings have been performed in this area. The rocks of the region include volcanic and sedimentary. The source of the mineralization in the area is hydrothermal processes. After gravity measuring in the region, the data were corrected, then various methods such as anomalous map remaining in levels one and two, upward expansion, first and second-degree vertical derivatives, analytical method, and analytical signal were drawn, and finally, the depth of the deposit was estimated by Euler method. As a result, the depth of the mineral deposit was calculated to be between 20 and 30 meters on average.
基金financially supported by the National Natural Science Foundation of China (No.21777178)Key Projects for Frontier Sciences of the Chinese Academy of Sciences (No.QYZDBSSWDQC018)+2 种基金the CAS Interdisciplinary Innovation Team (No. JCTD-2018-04)supports from the National Young Top-Notch Talents (No.W03070030)Youth Innovation Promotion Association of the Chinese Academy of Sciences (No. 2016037)
文摘Dark formation of hydroxyl radical upon oxidation of reduced iron minerals plays an important role in the degradation and transformation of organic and inorganic pollutants.Herein,we compared the hydroxyl radical formation from various reduced iron minerals at different redox conditions.·OH production was generally observed from the oxidation of reduced iron minerals,following the order:mackinawite(FeS)>reduced nontronite(iron-bearing smectite clay)> pyrite(FeS2)> side rite(FeCO3).Structural Fe^2+ and dissolved O2 play critical roles in ·OH production from reduced iron minerals.·OH production increases with decreasing pH,and Cl^-has little effect on this process.More importantly,dissolved organic matter significantly enhances ·OH production,especially under O2 purging,highlighting the importance of this process in ambient environments.This sunlight-independent pathway in which ’OH forms during oxidation of reduced iron minerals is helpful for understanding the degradation and transformation of various inorganic and organic pollutants in the redox-fluctuation environments.
文摘Selection of the crusher required a great deal of design regarding to the mine planning. Selection of suitable primary crusher from all of available primary crushers is a multi-criterion decision making(MCDM) problem. The present work explores the use of technique for order performance by similarity to ideal solution(TOPSIS) with fuzzy set theory to select best primary crusher for Golegohar Iron Mine in Iran. Gyratory, double toggle jaw, single toggle jaw, high speed roll crusher, low speed sizer, impact crusher, hammer mill and feeder breaker crushers have been considered as alternatives. Also, the capacity, feed size, product size, rock compressive strength, abrasion index and application of primary crusher for mobile plants were considered as criteria for solution of this MCDM problem. To determine the order of the alternatives, closeness coefficient is defined by calculating the distances to the fuzzy positive ideal solution(FPIS) and fuzzy negative ideal solution(FNIS). Results of our work based on fuzzy TOPSIS method show that the gyratory is the best primary crusher for the studied mine.
文摘This paper compares analytical and numerical methods by taking the forecasting of water yield of deep-buried iron mine in Yanzhou, Shandong as an example. Regarding the analytical method, the equation of infinite and bilateral water inflow boundary is used to forecast the water yield, and in the case of numerical simulation, we employed the GMS software to establish a model and further to forecast the water yield. On the one hand, through applying the analytical method, the maximum water yield of mine 1 500 m deep below the surface was calculated to be 13 645.17 m3/d; on the other hand, through adopting the numerical method, we obtained the predicted result of 3 816.16 m3/d. Meanwhile, by using the boundary generalization in the above-mentioned two methods, and through a comparative analysis of the actual hydro-geological conditions in this deep-buried mine, which also concerns the advantages and disadvantages of the two methods respectively, this paper draws the conclusion that the analytical method is only applicable in ideal conditions, but numerical method is eligible to be used in complex hydro-geological conditions. Therefore, it is more applicable to employ the numerical method to forecast water yield of deep-buried iron mine in Yanzhou, Shandong.
基金supported by the National Natural Science Foundation of China(Nos.42207450,21866017,and 42067056)the Yunnan Fundamental Research Projects(No.202101BE070001-013)the Foundation for Distinguished Young Talents of Yunnan Province(No.202101AV070006)。
文摘Dissolved organic matter(DOM)and iron minerals widely existing in the natural aquatic environment can mediate the migration and transformation of organic pollutants.However,the mechanism of interaction between DOM and iron minerals in the microbial degradation of pollutants deserves further investigation.In this study,the mechanism of 17 alphaethinylestradiol(EE2)biodegradation mediated by humic acid(HA)and three kinds of iron minerals(goethite,magnetite,and pyrite)was investigated.The results found that HA and iron minerals significantly accelerated the biodegradation process of EE2,and the highest degradation efficiency of EE2(48%)was observed in the HA-mediated microbial system with pyrite under aerobic conditions.Furthermore,it had been demonstrated that hydroxyl radicals(HO·)was the main active substance responsible for the microbial degradation of EE2.HO·is primarily generated through the reaction between hydrogen peroxide secreted by microorganisms and Fe(II),with aerobic conditions being more conducive.The presence of iron minerals and HA could change the microbial communities in the EE2 biodegradation system.These findings provide new information for exploring the migration and transformation of pollutants by microorganisms in iron-rich environments.
基金the support from the National Natural Science Foundation of China (No. 51404024)partially funded by the NIOSH of the Centers for Disease Control and Prevention, USA through Contract No.200-201139886 given to the second author
文摘An underground iron mine in China has been used as a case-study to research the subsidence due to ore extraction and backfilling during open stoping operations. A 3-D discontinuum numerical model was built incorporating geologic complexities including faults and interfaces between different lithologies,and the stoping and backfilling sequence adopted from the mine plans. The stoping was carried out in two vertically stacked horizontal layers, with a total of 16 stopes. Large displacements of up to 50 cm were observed along the roof of the stopes, and a maximum surface subsidence of 22.5 cm was observed.Backfilling was found to eliminate subsequent displacements and subsidence. The extraction of the upper orebody was found to influence displacements in the lower orebody. Finally, a subsidence profile was constructed to show the subsidence at all locations along the length of the surface and region of influence on the surface.
基金Project supported by the Natural Science Foundation of Hebei Province,China
文摘Based on the analyses of the character of the exploitation of the iron ore resource and its destruction of eco-environment in Tangshan area,this paper puts forward the patterns of land reclamation which fits for this area.The patterns include the reclamation of ecological agriculture,planting directly on the tailing bin without covering soil,reclamation of mine tailings in the pool,and improvement of the soil quality by using tailings etc.Now,over 700hm^2 land has been reclaimed by taking advantage of the pattern in Tangshan and eight typical reclamation districts have been built.The rates of reclamation exceed 80%and have reached the advanced level of the world.Practice has proved that the eco-environment of the ore area has been greatly improved and the remarkable economic and social benefits have been gained.
文摘Malignant transformation of hamsterembryo cells was induced in vitro by rareearth iron mineral dusts(MP),naturalthorium(Th02) and MP plus Th02.Dusts of MP,MP plus Th02 or Th02 were added into themedium with the final concentration of 17.0,
基金financially supported by the National Key Research and Development Program of China(No.SQ2017YFSF060069)the National Natural Science Foundation of China(No.51574017)
文摘The micromorphology and physicochemical properties of hydrophobic blasting dust(HBD)from an iron mine were comprehensively analyzed by laser particle size analysis(LPSA),scanning electron microscopy(SEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that the HBD particles can be classified into three types based on their particle size(PS):larger particles(PS>10μm),medium particles(1μm≤PS≤10μm),and nanoparticles(PS<1μm).The cumulative volume of respirable dust(PS≤10μm)was 84.45%.In addition,three shapes of HBD were observed by SEM:prism,flake,and bulk.In particular,the small particles were mostly flaky,with a greater possibility of being inhaled.Furthermore,the body and surface chemical compounds of HBD were determined by XRD and XPS,respectively.Ammonium adipate(C6H16N2O4)was the only organic compound in the body of HBD,but its mass fraction was only 13.4%.However,the content of organic C on the surface of HBD was 85.35%.This study demonstrated that the small-particle size and large amount of organic matter on the surface of HBD are the main reasons for its hydrophobicity,which can provide important guidance for controlling respirable dust in iron mines.
基金financially supported by the National Key Research and Development Program of China (No. 2017YFC0805204)the National Natural Science Foundation of China (Nos. 51874015 and 51504017)
文摘This study explores the key physicochemical factors affecting the hydrophilic characteristics of iron mine blasting dust(BD). The BD is separated into an unwetted part(UWBD, hydrophobic part) and a wetted part(WBD, hydrophilic part). Its particle size, true density(TD), pore parameters, mineral composition, and surface compounds are comprehensively characterized and compared. The results indicate that a smaller particle size and more developed pore parameters are two key factors responsible for the strong hydrophobicity of the BD. The mineral composition of the BD has no direct effect on its wetting properties;however, it indirectly influences the deposition characteristics of the BD in water by affecting its TD. Unlike coal dust, the surface organic composition of the BD does not affect its wettability and the peak area of C–C/C–H hydrophobic groups in the C 1s X-ray photoelectron spectrum of the UWBD(45.03%) is smaller than that in the C 1s spectrum of the WBD(68.30%). Thus, eleven co-influencing processes of physicochemical properties of the BD on its wettability are summarized. This research sheds light on the key factors affecting the wettability of the BD.
基金supported by the National Natural Science Foundation of China (Nos. 41571449, 41271260, 41276101 and 41807035)the Fundamental Research Fund for the Central Universities of China (No. 20720160083)+2 种基金the Natural Science Foundation of Fujian Province of China (Nos. 2018J05073 and 2018Y0074)the Project of Educational Scientific Research of Fujian Province of China (Nos. JAT170831 and JA13344)the Open Fund of Key Laboratory of Measurement and Control System for Coastal Environment of China (No. S1-KF1701)
文摘Microbially mediated bioreduction of iron oxyhydroxide plays an important role in the biogeochemical cycle of iron.Geobacter sulfurreducens is a representative dissimilatory ironreducing bacterium that assembles electrically conductive pili and cytochromes.The impact of supplementation withγ-Fe_2O_3 nanoparticles(NPs)(0.2 and 0.6 g)on the G.sulfurreducens-mediated reduction of ferrihydrite was investigated.In the overall performance of microbial ferrihydrite reduction mediated byγ-Fe_2O_3 NPs,stronger reduction was observed in the presence of direct contact withγ-Fe_2O_3 NPs than with indirect contact.Compared to the production of Fe(Ⅱ)derived from biotic modification with ferrihydrite alone,increases greater than 1.6-and 1.4-fold in the production of Fe(Ⅱ)were detected in the biotic modifications in which direct contact with 0.2 g and 0.6 gγ-Fe_2O_3 NPs,respectively,occurred.X-ray diffraction analysis indicated that magnetite was a unique representative iron mineral in ferrihydrite when active G.sulfurreducens cells were in direct contact withγ-Fe_2O_3 NPs.Because of the sorption of biogenic Fe(Ⅱ)ontoγ-Fe_2O_3 NPs instead of ferrihydrite,the addition ofγ-Fe_2O_3 NPs could also contribute to increased duration of ferrihydrite reduction by preventing ferrihydrite surface passivation.Additionally,electron microscopy analysis confirmed that the direct addition ofγ-Fe_2O_3 NPs stimulated the electrically conductive pili and cytochromes to stretch,facilitating long-range electron transfer between the cells and ferrihydrite.The obtained findings provide a more comprehensive understanding of the effects of iron oxide NPs on soil biogeochemistry.
基金the Specialized Research Fund for the Doctoral Program of Higher Education of China (No.20130006110017) for the financial support for this research
文摘Numerous studies have demonstrated that Na2SO4 can significantly inhibit the reduction of iron oxide in the selective reduction process of laterite nickel ore. FeS generated in the process plays an important role in selective reduction, but the generation process of FeS and its inhibition mechanism on iron reduction are not clear. To figure this out, X-ray diffraction and scanning electron microscopy analyses were conducted to study the roasted ore. The results show that when Na2SO4 is added in the roasting, the FeO content in the roasted ore increases accompanied by the emergence of FeS phase. Further analysis indicates that NaeS formed by the reaction of Na2SO4 with CO reacts with SiO2 at the FeO surface to generate FeS and Na2Si2Os. As a result, a thin film forms on the surface of FeO, hindering the contact between reducing gas and FeO. Therefore, the reduction of iron is depressed, and the FeO content in the roasted ore increases.
基金supported by the National Natural Science Foundation of China (41401046)the Fundamental Research Funds for the Central Universities (lzujbky-2016-264, lzujbky-2016-bt01)
文摘The Alagxa Plateau, in the margin of the northeastern Tibetan Plateau, is one of the most important dust source areas in East Asia, and the widespread sandy desert in the area is important both as a reservoir and a source of eolian silty. The northeastern margin of the Tibetan Plateau is one of the most actively-growing mountain belt on earth, and has large amounts of debris, with masses of fine grained material, which were continuously mobilized and deposited in the Alagxa Plateau by rivers, forming broad alluvial fans. It is possible that the role of fluvial sediments as a source of silty dust in the Alagxa Plateau has been underestimated. In this study, we test this hypothesis by investigating the iron mineralogical and geochemical characteristics of the fluvial sediments and the surface material of the sandy desert in the Alagxa Plateau, and comparing them with paleo-eolian dust deposits(loess) in the adjacent Chinese Loess Plateau(CLP) to investigate the possible linkages among the fluvial sediments, sandy desert and the last glacial loess of the CLP. The results show that sandy desert typically have high contents of goethite, and high ratios of goethite to hematite, similar to the fluvial sediments in the Alagxa Plateau. Based on the major element characteristics, field investigations and the results of previous studies, we found a genetic link between the silt component of the fluvial sediments and the sandy desert in the Alagxa Plateau with high value of Gt(goethite) and similarity of the Gt/(Hm(hematite)+Gt) ratio. But the silt component of the sandy desert main come from the adjacent fluvial sediments. The iron mineralogical characteristics(χ(magnetic susceptibility), χARM(anhysteretic susceptibility), SIRM(saturation isothermal remanent magnetization) and SIRM_(AF100 mT)(SIRM demagnetized at 100 mT)) of the CLP samples overlap with those of the fluvial sediments in the Alagxa Plateau, but there is a mismatch with the sandy desert samples. This suggests that the fluvial sediments are the source of a large amount of silty material which could be transported to the CLP. Therefore, we conclude that the fluvial sediment in the Alagxa Plateau is an important source of eolian silt, which is deposited in downwind region, and that this source has been previously underestimated.
基金supported by Erciyes University,Directorate of Research Fund (FUBAP-FBT-04-36)
文摘Iron mineralizations in the study area are found in amphibolites in the localities of Buyukoren,Uzunkuyu-Atkayasi,and Karabacak and they display a predominantly banded texture.Their paragenesis is dominated by magnetite and hematite.In this study,iron mineralizations in Sarikaya were examined in terms of rare earth element(REE) contents and attempts were made to determine some physicochemical conditions that had an impact upon their formation.For this purpose,42 ore samples and 17 enriched magnetite samples...
文摘A geophysical survey was conducted in the Kelle-Bidjocka village, Messondo subdivision, in the Centre Region, Cameroon. The data acquisition was made by combining Schlumberger profiling and electrical soundings along six (06) profiles of 1500 m in length for a total of 64 geoelectrical stations’ survey conducted through a variable mesh 100 m × 200 m, or 100 m × 300 m. The equipment used is the DC resistivimeter Syscal Junior 48 (Iris Instrument). Processing and modelling of field data are made by using the Res2Dinv, Qwseln and Surfer software. The investigation methods used are electrical resistivity (DC) and induced polarization (IP) methods. The analyses and interpretations have helped to highlight areas of weakness or conductive discontinuities (fractures, faults, shear zones, etc.) in Precambrian gneiss formations, sometimes undergoing weathering processes. They identify the weathering or mineralogical accumulation horizons, the most promising is a mineralization channel identified in the NE-SW direction. The highlighted mineralization is characterized by strong gradients of chargeability or polarization. Samples and other geological evidences observed in the area are used to associate the most polarizable structures with ferriferous formations. Weakly polarizable and particularly conductive backgrounds identified by the inverse pseudo-sections are thought to be sulphate minerals or groundwater targets for future hydrogeological studies.
