This study employed integrated multi-omics approaches to elucidate,from the perspective of amino acid metabolism,the adaptive mechanism of Penicillium digitatum under modified atmosphere packaging(MAP)conditions.Compa...This study employed integrated multi-omics approaches to elucidate,from the perspective of amino acid metabolism,the adaptive mechanism of Penicillium digitatum under modified atmosphere packaging(MAP)conditions.Comparative analysis of natural air(Air),controlled atmosphere(CA),and MAP treatments revealed that MAP upregulated the expression of the hercynylcysteine S-oxide synthase(HCSOS),aldehyde dehydrogenase(ALDH),and monoamine oxidase(MAO)genes,thereby enhancing histidine-derived ergothioneine and methionine levels,and subsequently boosting glutathione-mediated redox homeostasis.Meanwhile,MAP induced the expression of the dihydroxyacid dehydratase(DHAD),saccharopine dehydrogenase(SDH),and arginosuccinate lyase(ASL)genes,redirecting valine,lysine,and arginine into the tricarboxylic acid(TCA)cycle to fuel ATP production.MAP also enhanced ASL-mediated arginine degradation and urea cycle activity,reducing arginine accumulation when compared to CA treatment.In contrast,while MAP induced upregulated expression of the pyrroline-5-carboxylate dehydrogenase(P5CDH)and D-amino acid oxidase(DAAO)genes,CA treatment promoted proline accumulation,reflecting stress-specific metabolic flexibility.Collectively,these findings demonstrate that MAP triggers transcriptional reprogramming of amino acid metabolism to coordinate oxidative defense,energy generation,and osmotic balance.By modulating these metabolic pathways and regulatory genes under MAP conditions,fungal adaptability can be disrupted.Hence,this study provides a promising strategy for suppressing green mold development,extending the postharvest shelf life,and improving the quality of fruits and vegetables.展开更多
The IUGG Associations for Atmosphere,Oceans and Cryosphere—IAMAS,IAPSO and IACS—held a Joint Scientific Assembly in Busan,South Korea,from 20 to 25 July 2025.This was the first joint assembly of all three associatio...The IUGG Associations for Atmosphere,Oceans and Cryosphere—IAMAS,IAPSO and IACS—held a Joint Scientific Assembly in Busan,South Korea,from 20 to 25 July 2025.This was the first joint assembly of all three associations since 2009,when they met in Montreal,Canada.It was the first time any of the associations had been hosted in Korea,and it had been two decades since any of them had met in Asia.The choice of Busan as the venue supported high levels of participation and smooth conference operations.The Local Organizing Committee,chaired by Prof.Kyung-Ja Ha of Pusan National University,oversaw the successful organization of the event.The assembly brought together 1725 participants in total,including 1282 researchers and 443 invited participants and individuals involved in side events,exhibitions,media coverage,and volunteer work.Participants came from 46 countries across Asia,Europe,North America,South America,Africa,and Oceania.IAMAS had 736 participants,IAPSO 321,and IACS 225.Survey data from 951 respondents revealed that Early Career Scientists,defined as those within 10 years of receiving their PhD,accounted for approximately 25%of participants.The demographic profile skewed young,with 66%of attendees in their 20s and 30s.The scientific program was organized by Prof.Seon-Ki Park(Chair),the Secretaries General from all three Associations,and the Local Organizing Committee.Reflecting the theme“Our Interconnected Earth,”the scientific program emphasized integrated approaches to climate systems,addressing climate change and environmental challenges through collaborative,transdisciplinary research.展开更多
To address the kinetic constraints inherent in the catalytic combustion of pulverized coal injection under low heating-rate conditions within conventional air atmospheres,a drop tube furnace was utilized to simulate t...To address the kinetic constraints inherent in the catalytic combustion of pulverized coal injection under low heating-rate conditions within conventional air atmospheres,a drop tube furnace was utilized to simulate the catalytic combustion of pulverized coal(PC).The effects of gas composition,oxygen concentration,the type,and the content of catalysts on the combustion reactivity were systematically analyzed.Furthermore,the structural changes of unburned pulverized coal were also examined.Experimental results indicate that as the oxygen concentration increased from 21%to 79%,compared with the O_(2)/N_(2)condition,the increment in the burnout rate of PC under the O_(2)/CO_(2)condition increased from 3%to 23%.After the addition of catalysts,including hematite,metallurgical oil sludge,and light-burnt dolomite(LBD),under the condition of 21%oxygen concentration,the effects of the three catalysts under the O_(2)/CO_(2)condition were superior to those under the O_(2)/N_(2)condition.This trend was reversed under the conditions of 38%and 79%oxygen concentrations.In all atmospheres,the three catalysts can enhance the burnout rate of PC.Among them,LBD exhibits the most favorable effect,and there exists an optimal dosage.Mechanistic analysis through scanning electron microscopy,X-ray diffraction,and N_(2)adsorption-desorption reveals that under 21%O_(2)/79%CO_(2)conditions,high-concentration CO_(2)leads to the formation of pores,and additives accelerate the oxidation of C and the gasification of CO_(2)through oxygen transfer,thereby enhancing the burnout rate of PC.展开更多
Ambient ozone(O_(3))is generated through the reactions of nitrogen oxides and volatile organic compounds(VOCs)in sunlight,and the primary sources of RO_(x)radicals play a very important role in O_(3)photochemistry.How...Ambient ozone(O_(3))is generated through the reactions of nitrogen oxides and volatile organic compounds(VOCs)in sunlight,and the primary sources of RO_(x)radicals play a very important role in O_(3)photochemistry.However,as major precursors of RO_(x)radicals,the systematical evaluation of ClNO_(2),HCHO,and HONO impacts on O_(3)photochemistry remains limited.Here,we utilized the observations of ClNO_(2),HCHO,and HONO conducted in a coastal city of Southeast China during a photochemical O_(3)pollution episode,combined with model simulations to elucidate their impacts on RO_(x)radicals and atmospheric oxidation capacity(AOC),as well as O_(3)formation.Decreased concentrations of ClNO_(2)and HONO were observed after sunrise,while HCHO concentrations peaked in the daytime.HCHO photolysis contributed the largest(∼25%)to RO_(x)radical production around noon,while HONO photolysis(∼47%)dominated RO_(x)radical production in the morning and late afternoon,and VOCs consumed by Cl radical released via ClNO_(2)photolysis was more important(∼10%)in the early morning,similar to their effects on the AOC levels.The results of model simulations indicated that HCHO photolysis greatly enhanced the photochemical formation of O_(3),followed by HONO and ClNO_(2)photolysis.Except for reducing VOCs due to a VOC-limited regime,the impacts of HCHO photolysis as primary RO_(x)sources should be valued to inhibit the intensification of O_(3)pollution.Our study stressed the importance of primary RO_(x)sources for O_(3)photochemistry in coastal regions,provided new insights into elucidating the self-purifying effect of the atmospheric environment.展开更多
The factors affecting the reflection and transmission coefficient of the ionosphere have been analyzed.These factors include wave frequency,incident angle,geomagnetic inclination,electron density and collision frequen...The factors affecting the reflection and transmission coefficient of the ionosphere have been analyzed.These factors include wave frequency,incident angle,geomagnetic inclination,electron density and collision frequency in the ionosphere.The ionosphere refractive index is also analyzed.The ionosphere above 70 km is considered to be homogeneous and anisotropic,and the reflection and transmission coefficient matrix is calculated using matrix method.Simultaneously the Booker quartic equation is solved to get the refractive index in the ionosphere.The results show that when the wave frequency is higher,it is easier to penetrate into the ionosphere from its bottom boundary and the propagation attenuation in the ionosphere is smaller.TE（traverse electric） wave and TM（traverse magnetic） wave can both penetrate into the ionosphere with a small incident angle,while TE wave can hardly transmit into the ionosphere when the incident angle is large.The transmission coefficient decreases as the geomagnetic inclination increases.TE and TM wave cannot penetrate into the ionosphere at magnetic equator.When the electron collision frequency is higher,it is easier for VLF wave to penetrate into the ionosphere and the attenuation of ordinary wave is weaker,which may be caused by the energy transportation between the waves and the particles.The ordinary（O） wave experiences severer attenuation than extraordinary（X） wave,and X wave is a penetration mode whereas O wave is a non-penetration mode in the ionosphere.All the results indicate that VLF wave with higher frequency is easier to penetrate into the ionosphere and to be recorded by the satellites at high latitude.It is hard for ULF and the lower frequency VLF wave to transmit into the ionosphere directly for the severe reflection and attenuation.It may transmit into the ionosphere with a small incident angle due to the nonlinear effect,for example,the interaction between the waves and the particles or cross modulation,and then propagate along the whistle duct with small attenuation.This work may be a preliminary theoretical exploration for the future calculation on the response of ground based VLF artificial transmitter in the ionosphere and further study on the seismic ionosphere coupling model.展开更多
The Si_(3)N_(4)-bonded silicon carbide(SiC)bricks in the sloped zone of dry quenching coke ovens support the weight of upper refractory materials and equipment.These bricks endure frequent temperature fluctuations and...The Si_(3)N_(4)-bonded silicon carbide(SiC)bricks in the sloped zone of dry quenching coke ovens support the weight of upper refractory materials and equipment.These bricks endure frequent temperature fluctuations and intense abrasion from coke dust,demanding extremely high performance.After three years of service,an analysis of the Si_(3)N_(4)-bonded SiC bricks revealed that oxidation,which reduces thermal shock resistance,is the primary cause of degradation.In the unused Si_(3)N_(4)-bonded SiC bricks,short columnar β-Si_(3)N_(4) forms an interwoven network around SiC particles and contains a small amount of plate-like Si_(2)N_(2)O.Under the complex N_(2)(84.42 vol.%)-CO_(2)(10.44 vol.%)-CO(4.43 vol.%)-H_(2)(0.56 vol.%)-O_(2)(0.15 vol.%)atmosphere in the dry quenching coke oven,O_(2)(0.15 vol.%)exhibits a stronger oxidizing effect than CO_(2)(10.44 vol.%)and CO(4.43 vol.%),making it the primary oxidizing agent.The short columnarβ-Si_(3)N_(4) is more susceptible to oxidation than the particulate SiC.Based on thermodynamic and kinetic analyses,the chemical stability of the phases in Si_(3)N_(4)-bonded SiC bricks ranks from strongest to weakest as follows:Si_(2)N_(2)O,SiC,Si_(3)N_(4).Future development of Si_(2)N_(2)O-bonded SiC bricks could improve the longevity of refractory materials in the sloped zone of dry quenching coke ovens.展开更多
The algebraic reconstruction technique(ART),multiplicative algebraic reconstruction technique(MART),and simultaneous iterative reconstruction technique(SIRT)are computational methodologies extensively utilized within ...The algebraic reconstruction technique(ART),multiplicative algebraic reconstruction technique(MART),and simultaneous iterative reconstruction technique(SIRT)are computational methodologies extensively utilized within the field of computerized ionospheric tomography(CIT)to facilitate three-dimensional reconstruction of the ionospheric morphology.However,reconstruction accuracy elicits recurrent disputes over its practical application,and people usually attribute this issue to incomplete and uneven coverage of the measurements.The Thermosphere Ionosphere Electrodynamics General Circulation Model(TIEGCM)offers a reasonable physics-based ionospheric background and is widely utilized in ionospheric research.We use the TIEGCM simulations as the targeted ionosphere because the current measurements are far from able to realistically reproduce the ionosphere in detail.Optimized designations of satellite measurements are conducted to investigate the limiting performance of CIT methods in ionospheric reconstruction.Similar to common practice,electron density distributions from outputs of the International Reference Ionosphere(IRI)model are used as the iterative initial value in CIT applications.The outcomes suggest that despite data coverage,iterative initial conditions also play an essential role in ionospheric reconstruction.In particular,in the longitudinal sectors where the iterative initial height of the F2-layer peak electron density(hmF2)differs substantially from the background densities,none of the three CIT methods can reproduce the exact background profile.When hmF2 is close but the ionospheric F2-layer peak density(NmF2)is different between the targeted background and initial conditions,the MART performs better than the ART and SIRT,as evidenced by the correlation coefficients of MART being above 0.97 and those of ART and SIRT being below 0.85.In summary,this investigation reveals the potential uncertainties in traditional CIT reconstruction,particularly when realistic hmF2 or NmF2 values differ substantially from the initial CIT conditions.展开更多
This paper is intended to summarize the research conducted during the first 2 years of the Dragon 5 project 59,332(geophysical and atmospheric retrieval from Synthetic Aperture Radar(SAR)data stacks over natural scena...This paper is intended to summarize the research conducted during the first 2 years of the Dragon 5 project 59,332(geophysical and atmospheric retrieval from Synthetic Aperture Radar(SAR)data stacks over natural scenarios).Monitoring atmospheric phenomena,encompassing both tropospheric and ionospheric conditions,holds pivotal significance for various scientific and practical applications.In this paper,we present an exploration of advanced techniques for estimating tropospheric and ionospheric phase screens using stacks of Synthetic Aperture Radar(SAR)images.Our study delves into the current state-of-the-art in atmospheric monitoring with a focus on spaceborne SAR systems,shedding light on their evolving capabilities.For tropospheric phase screen estimation,we propose a novel approach that jointly estimates the tropospheric component from all the images.We discuss the methodology in detail,highlighting its ability to recover accurate tropospheric maps.Through a series of quantitative case studies using real Sentinel-1 satellite data,we demonstrate the effectiveness of our technique in capturing tropospheric variability over different geographical regions.Concurrently,we delve into the estimation of ionospheric phase screens utilizing SAR image stacks.The intricacies of ionospheric disturbances pose unique challenges,necessitating specialized techniques.We dissect our approach,showcasing its capacity to mitigate ionospheric noise and recover precise phase information.Real data from the Sentinel-1 satellite are employed to showcase the efficacy of our method,unraveling ionospheric perturbations with improved accuracy.The integration of our techniques,though presented separately for clarity,collectively contributes to a comprehensive framework for atmospheric monitoring.Our findings emphasize the potential of SAR-based approaches in advancing our knowledge of atmospheric processes,thus fostering advancements in weather prediction,geophysics,and environmental management.展开更多
Ball milling is an environmentally friendly technology for the remediation of petroleumcontaminated soil(PCS),but the cleanup of organic pollutants requires a long time,and the post-remediation soil needs an economica...Ball milling is an environmentally friendly technology for the remediation of petroleumcontaminated soil(PCS),but the cleanup of organic pollutants requires a long time,and the post-remediation soil needs an economically viable disposal/reuse strategy due to its vast volume.The present paper develops a ball milling process under oxygen atmosphere to enhance PCS remediation and reuse the obtained carbonized soil(BCS-O)as wastewater treatment materials.The total petroleum hydrocarbon removal rates by ball milling under vacuum,air,and oxygen atmospheres are 39.83%,55.21%,and 93.84%,respectively.The Langmuir and pseudo second-order models satisfactorily describe the adsorption capacity and behavior of BCS-O for transition metals.The Cu^(2+),Ni^(2+),and Mn^(2+)adsorbed onto BCS-O were mainly bound to metal carbonates and metal oxides.Furthermore,BCS-O can effectively activate persulfate(PDS)oxidation to degrade aniline,while BCS-O loaded with transition metal(BCS-O-Me)shows better activation efficiency and reusability.BCS-O and BCS-O-Me activated PDS oxidation systems are dominated by^(1)O_(2)oxidation and electron transfer.The main active sites are oxygen-containing functional groups,vacancy defects,and graphitized carbon.The oxygen-containing functional groups and vacancy defects primarily activate PDS to generate^(1)O_(2)and attack aniline.Graphitized carbon promotes aniline degradation by accelerating electron transfer.The paper develops an innovative strategy to simultaneously realize efficient remediation of PCS and sequential reuse of the postremediation soil.展开更多
Due to the high elevation and cold climate of the Tibetan Plateau,the western region retains extensive snow cover during the summer,which can exhibit rapid variability over the course of just a few days.This study uti...Due to the high elevation and cold climate of the Tibetan Plateau,the western region retains extensive snow cover during the summer,which can exhibit rapid variability over the course of just a few days.This study utilizes numerical experiments to investigate the atmospheric response to extreme Tibetan Plateau snow cover(TPSC)events on a subseasonal timescale during summer.The results indicate that the subseasonal variations in TPSC exert limited impact on nonlocal atmospheric circulation and temperature during this period.Nevertheless,local surface energy and atmospheric temperature exhibit rapid cooling responses to increased snow cover.Specifically,an increase in snow cover over the western Tibetan Plateau leads to a sharp rise in surface albedo,resulting in a reduction in land surface energy and a negative response in the diabatic heating rate from the surface to 350 hPa locally.This negative diabatic heating response subsequently causes a decline in both surface and overlying atmospheric temperatures.The temperature response is confined to the western Tibetan Plateau and extends vertically from the surface to approximately 350 hPa.These extreme TPSC events and their associated atmospheric impacts occur within a two-week timescale.展开更多
The Sq(solar quiet)geomagnetic field is generated by the electric currents in the E-region of the ionosphere,driven by the atmospheric tides.It is a critical part of high-precision geomagnetic field modeling.Based on ...The Sq(solar quiet)geomagnetic field is generated by the electric currents in the E-region of the ionosphere,driven by the atmospheric tides.It is a critical part of high-precision geomagnetic field modeling.Based on the classic thermal tide theory and atmospheric electrodynamics,this research,for the first time,developed an Sq geomagnetic field model that is directly built on the physical mechanism of the ionospheric dynamo,which is responsible for daily variations of the geomagnetic field.The performance in Sq geomagnetic field modeling was investigated using the Macao Science Satellite-1(MSS-1)data.Our model can enhance the physics-based framework of comprehensive geomagnetic field modeling for the MSS-1 and ensuing missions.展开更多
The present study monitored bacterial succession,physicochemical properties,and volatile organic compounds(VOCs)changes in smoked chicken legs with modified atmosphere packaging(MAP,60% CO_(2) and 40%N_(2))during a 25...The present study monitored bacterial succession,physicochemical properties,and volatile organic compounds(VOCs)changes in smoked chicken legs with modified atmosphere packaging(MAP,60% CO_(2) and 40%N_(2))during a 25-day storage period at 4℃.After 15 days of storage,S erratia proteamaculans and Pseudomonas fragi became the predominant bacteria.Furthermore,physicochemical properties changed significantly,as evidenced by an increase in thiobarbituric acid reactive substances and b*(yellowness)value,and a decrease in hardness.A total of 65 VOCs were identified during storage.Correlation between bacterial succession and quality indicators(including VOCs and physicochemical properties)allowed the identification of 26 core dominant bacteria,including S.proteamaculans,Psychrobacter alimentarius,Pseudomonas putida,and Pseudomonas poae,which were positively related to spoilage VOCs(e.g.,1-octen-3-ol,1-pentanol,and 3-methyl-1-butanol)and could be defined as specific spoilage organisms(SSOs).The results of this study provide a systematic approach to predict SSOs in smoked chicken legs during storage,which can also provide a basis for product safety.展开更多
This work is an attempt to critically analyze the existing theoretical models of the impact of earthquake preparation processes on the state of the earth’s atmosphere and ionosphere in the zone of growing seismic act...This work is an attempt to critically analyze the existing theoretical models of the impact of earthquake preparation processes on the state of the earth’s atmosphere and ionosphere in the zone of growing seismic activity, as well as the mechanisms of formation and transfer of disturbances in various media over the earthquake center. The determining factor (criterion) of the analysis is the degree of compliance of the simulation results with experimental data obtained at various phases of earthquake development by direct and remote diagnostic methods using ground and aerospace technologies. The key role is played by the model’s compliance with the results of measuring electric fields and currents in the near-ground atmosphere and ionosphere, small-scale ionospheric inhomogeneities and correlated field-aligned currents and electromagnetic ULF/ELF emissions. A full-fledged model should also explain the origin of such seismic related phenomena as the generation in the troposphere and over-horizon propagation of pulsed VHF radiation, thermal effects and associated IR emissions as well as the modification of plasma distribution in the D, E and F layers of the ionosphere. The use of this criterion in the analysis allowed us to identify a theoretical model that most fully describes the totality of the above-mentioned experimental data within a single physical mechanism. This is an electrodynamic model based on the perturbation of the conductivity current in the global atmosphere—ionosphere electric circuit due to the injection of charged aerosols into the atmosphere during the preparation and development of an earthquake. The present paper describes this model and the formation mechanisms of related phenomena in the atmosphere and ionosphere, which can be considered as short-term precursors to earthquakes.展开更多
In this study, we present an innovative Mars Ionosphere-Thermosphere Model(MITM), which is a time-dependent, threedimensional(3-D) model that comprehensively represents the self-consistently coupled thermosphere and i...In this study, we present an innovative Mars Ionosphere-Thermosphere Model(MITM), which is a time-dependent, threedimensional(3-D) model that comprehensively represents the self-consistently coupled thermosphere and ionosphere of Mars within the altitude range of 70-300 km. The model incorporates an extensive range of parameters, including neutral number densities of CO_(2), CO,O, O_(2), N_(2), NO, N(^(2)D), N(^(4)S), Ar, and He;ion number densities of CO_(2)^(+), CO^(+), O^(+), O_(2)^(+), N_(2)^(+), NO^(+), N^(+) ions, and electrons;neutral temperature;and neutral wind fields. The MITM code employs a high-resolution grid system in a spherical geographical coordinate system, with a horizontal resolution of 5° latitude by 7.5° longitude. This altitude-resolved grid system enables accurate depiction of spatial variations in the Martian thermosphere and ionosphere. To showcase the capabilities of the MITM, we present two simulation cases: one during the equinox and another during the solstice. Both simulations reproduce key features of the Martian thermosphere and ionosphere including the characteristics of horizontal circulation, diurnal variations in chemical composition, and distribution of electron density. The MITM offers a robust framework for understanding the intricate interactions and processes that shape the Mars thermosphere and ionosphere,which are crucial for enhancing our understanding of Martian upper atmosphere and ionosphere.展开更多
Tweek atmospherics are extremely low frequency and very low frequency pulse signals with frequency dispersion characteristics that originate from lightning discharges and that propagate in the Earth–ionosphere wavegu...Tweek atmospherics are extremely low frequency and very low frequency pulse signals with frequency dispersion characteristics that originate from lightning discharges and that propagate in the Earth–ionosphere waveguide over long distances.In this study,we developed an automatic method to recognize tweek atmospherics and diagnose the lower ionosphere based on the machine learning method.The differences(automatic−manual)in each ionosphere parameter between the automatic method and the manual method were−0.07±2.73 km,0.03±0.92 cm^(−3),and 91±1,068 km for the ionospheric reflection height(h),equivalent electron densities at reflection heights(Ne),and propagation distance(d),respectively.Moreover,the automatic method is capable of recognizing higher harmonic tweek sferics.The evaluation results of the model suggest that the automatic method is a powerful tool for investigating the long-term variations in the lower ionosphere.展开更多
To explain the influence mechanism of MgO on the consolidation and reduction characteristics of roasted iron pellets,the properties and structure of pellets were investigated from multi-dimensions.It indicated that th...To explain the influence mechanism of MgO on the consolidation and reduction characteristics of roasted iron pellets,the properties and structure of pellets were investigated from multi-dimensions.It indicated that the MgO addition decreased the reduction swelling index(RSI)and reduction degree of pellets in both CO and H_(2)atmospheres.During the stepwise reduction process of Fe2O3→Fe3O4→FeO,the reduction behaviour of pellets in CO and H_(2)was similar,while the reduction rate of pellets in H_(2)atmosphere was almost twice as high as that in CO atmosphere.During the stepwise reduction process of FeO→Fe,the RSI of pellets showed a logarithmic increase in CO atmosphere and a linear decrease in H_(2)atmosphere.As investigated by first-principles calculations,C and Fe mainly formed chemical bonds,and the CO reduction process released energy,promoting the formation of iron whiskers.However,H and Fe produced weak physical adsorption,and the H_(2)reduction process was endothermic,inhibiting the generation of iron whiskers.With Mg2+doping in FexO,the nucleation region of iron whiskers expanded in CO reduction process,and the morphology of iron whiskers transformed from“slender”to“stocky,”reducing RSI of the pellets.展开更多
Cement production,while essential for global infrastructure,contributes significantly to carbon dioxide emissions,accounting for approximately 7%of total emissions.To mitigate these environmental impacts,flash calcina...Cement production,while essential for global infrastructure,contributes significantly to carbon dioxide emissions,accounting for approximately 7%of total emissions.To mitigate these environmental impacts,flash calcination of kaolinitic clays has been investigated as a sustainable alternative.This technique involves the rapid heating of clays,enabling their use as supplementary cementitious materials.The primary objective of this study was to modify the color of calcined clay in various atmospheres(oxidizing,inert,and reducing)to achieve a grayish tone similar to commercial cement while preserving its reactive properties.The experimental procedure employed a tubular reactor with precise control of gas flows(atmospheric air,nitrogen,and a carbon monoxide–nitrogen mixture).Physicochemical characterization of the raw clay was conducted before calcination,with analyses repeated on the calcined clays following experimentation.Results indicated that clay calcined in an oxidizing atmosphere acquired a reddish hue,attributed to the oxidation of iron in hematite.The Clay exhibited a pinkish tone in an inert atmosphere,while calcination in a reducing atmosphere yielded the desired grayish color.Regarding pozzolanic activity,clays calcined in oxidizing and inert atmospheres displayed robust strength,ranging from 82%to 87%.Calcination in a reducing atmosphere resulted in slightly lower strength,around 74%,likely due to the clay’s chemical composition and the calcination process,which affects compound formation and material reactivity.展开更多
Arsenic(As),classified as a Group I carcinogen by the International Agency for Research on Cancer(IARC),poses severe risks to ecosystems and human health through atmospheric exposure.This review synthesizes current kn...Arsenic(As),classified as a Group I carcinogen by the International Agency for Research on Cancer(IARC),poses severe risks to ecosystems and human health through atmospheric exposure.This review synthesizes current knowledge on the sources,health impacts,and control strategies of atmospheric arsenic,with an emphasis on its global transport and toxicity.Natural sources,such as volcanic eruptions and soil erosion,contribute approximately 2.1 Gg/year;however,anthropogenic activities,notably metal smelting and coal combustion,dominate emissions,with global anthropogenic releases reaching approximately 28.6 Gg/year.Atmospheric arsenic primarily exists in two forms:particulate matter(PM_(2.5)-bound As(Ⅴ)/As(Ⅲ)and methylated species)and gaseous forms(e.g.,AsH_(3),As_(2)O_(3)),facilitating long-range transport and cross-continental pollution,as evidenced by Asian emissions contributing 39% of Arctic deposition.Advanced techniques,such as inductively coupled plasma mass spectrometry(ICP-MS)and models like GEOS-Chem,enhance emission tracking;however,gaps persist in monitoring gaseous arsenic and refining emission inventories.Health risks include lung cancer,neurotoxicity,and cardiovascular diseases,exacerbated by inhalation and dietary exposure via contaminated crops.Control technologies,including calcium-and iron-based adsorbents and industrial scrubbers,show promise but face challenges related to efficiency and cost.Regional strategies,such as China’s tightened emission limits(0.5 mg/m^(3))and the EU’s Best Available Techniques(BAT),highlight progress,yet global cooperation remains vital for transboundary mitigation.Future research should prioritize low-cost sensors,elucidating speciation-toxicity relationships,and AI-driven emission management to address data gaps and optimize policies.Integrating multidisciplinary approaches—advanced science,stringent regulations,and international collaboration—is crucial to mitigate the environmental and public health impacts of arsenic amid growing industrialization and climate change.展开更多
The direct deoxygenative homo-coupling of benzyl alcohols holds great promise to build up bibenzyl motifs in organic synthesis,yet it remains a grand challenge in selectivity and activity control.Herein,we first disco...The direct deoxygenative homo-coupling of benzyl alcohols holds great promise to build up bibenzyl motifs in organic synthesis,yet it remains a grand challenge in selectivity and activity control.Herein,we first discovered that iron carbide catalysts displayed high efficiency and selectivity in the catalytic deoxygenative homo-coupling of benzyl alcohols into bibenzyls using H_(2)as the reductant.Ir-promoted Fe0@Fe_(5)C_(2)gave the best performance among the investigated catalysts,and a broad scope of substrates with diverse functional groups could be smoothly converted into bibenzyls,with the yield up to 85%.In addition,in the presence of alkenes,three-component coupling reactions between alcohols and alkenes were also for the first time achieved to construct more complex multi-ring molecules.The radical-trapping experiment and FTIR measurements revealed the radical nature of the reaction and the significantly promoted C–O bond activation after carbonization,respectively.This work will provide guidelines for the rational design of efficient and selective catalysts for the alcohol-involved carbon-carbon coupling reactions.展开更多
This study employs Principal Component Analysis(PCA)and 13 years of SD-WACCM-X model data(2007-2019)to investigate the characteristics and mechanisms of Inter-hemispheric Coupling(IHC)triggered by sudden stratospheric...This study employs Principal Component Analysis(PCA)and 13 years of SD-WACCM-X model data(2007-2019)to investigate the characteristics and mechanisms of Inter-hemispheric Coupling(IHC)triggered by sudden stratospheric warming(SSW)events.IHC in both hemispheres leads to a cold anomaly in the equatorial stratosphere,a warm anomaly in the equatorial mesosphere,and increased temperatures in the mesosphere and lower thermosphere(MLT)region of the summer hemisphere.However,the IHC features during boreal winter period are significantly weaker than during the austral winter period,primarily due to weaker stationary planetary wave activity in the Southern Hemisphere(SH).During the austral winter period,IHC results in a warm anomaly in the polar mesosphere of the SH,which does not occur in the NH during boreal winter period.This study also examines the possible influence of quasi-two-day waves(QTDWs)on IHC.We found that the largest temperature anomaly in the summer polar MLT region is associated with a large wind instability area,and a well-developed critical layer structure of QTDW in January.In contrast,during July,despite favorable conditions for QTDW propagation in the Northern Hemisphere,weaker IHC response is observed,suggesting that IHC features and the relationship with QTDWs during July would be more complex than during January.展开更多
文摘This study employed integrated multi-omics approaches to elucidate,from the perspective of amino acid metabolism,the adaptive mechanism of Penicillium digitatum under modified atmosphere packaging(MAP)conditions.Comparative analysis of natural air(Air),controlled atmosphere(CA),and MAP treatments revealed that MAP upregulated the expression of the hercynylcysteine S-oxide synthase(HCSOS),aldehyde dehydrogenase(ALDH),and monoamine oxidase(MAO)genes,thereby enhancing histidine-derived ergothioneine and methionine levels,and subsequently boosting glutathione-mediated redox homeostasis.Meanwhile,MAP induced the expression of the dihydroxyacid dehydratase(DHAD),saccharopine dehydrogenase(SDH),and arginosuccinate lyase(ASL)genes,redirecting valine,lysine,and arginine into the tricarboxylic acid(TCA)cycle to fuel ATP production.MAP also enhanced ASL-mediated arginine degradation and urea cycle activity,reducing arginine accumulation when compared to CA treatment.In contrast,while MAP induced upregulated expression of the pyrroline-5-carboxylate dehydrogenase(P5CDH)and D-amino acid oxidase(DAAO)genes,CA treatment promoted proline accumulation,reflecting stress-specific metabolic flexibility.Collectively,these findings demonstrate that MAP triggers transcriptional reprogramming of amino acid metabolism to coordinate oxidative defense,energy generation,and osmotic balance.By modulating these metabolic pathways and regulatory genes under MAP conditions,fungal adaptability can be disrupted.Hence,this study provides a promising strategy for suppressing green mold development,extending the postharvest shelf life,and improving the quality of fruits and vegetables.
基金support from USA NSF(Grant No.OPP2213875)NASA(Grant No.80NSSC22K1707).
文摘The IUGG Associations for Atmosphere,Oceans and Cryosphere—IAMAS,IAPSO and IACS—held a Joint Scientific Assembly in Busan,South Korea,from 20 to 25 July 2025.This was the first joint assembly of all three associations since 2009,when they met in Montreal,Canada.It was the first time any of the associations had been hosted in Korea,and it had been two decades since any of them had met in Asia.The choice of Busan as the venue supported high levels of participation and smooth conference operations.The Local Organizing Committee,chaired by Prof.Kyung-Ja Ha of Pusan National University,oversaw the successful organization of the event.The assembly brought together 1725 participants in total,including 1282 researchers and 443 invited participants and individuals involved in side events,exhibitions,media coverage,and volunteer work.Participants came from 46 countries across Asia,Europe,North America,South America,Africa,and Oceania.IAMAS had 736 participants,IAPSO 321,and IACS 225.Survey data from 951 respondents revealed that Early Career Scientists,defined as those within 10 years of receiving their PhD,accounted for approximately 25%of participants.The demographic profile skewed young,with 66%of attendees in their 20s and 30s.The scientific program was organized by Prof.Seon-Ki Park(Chair),the Secretaries General from all three Associations,and the Local Organizing Committee.Reflecting the theme“Our Interconnected Earth,”the scientific program emphasized integrated approaches to climate systems,addressing climate change and environmental challenges through collaborative,transdisciplinary research.
基金the National Natural Science Foundation of China(No.52374347)Yulin Science and Technology Program Project(No.2024-SF-227)Key Research and Development Program of Shaanxi(No.2021GY-128).
文摘To address the kinetic constraints inherent in the catalytic combustion of pulverized coal injection under low heating-rate conditions within conventional air atmospheres,a drop tube furnace was utilized to simulate the catalytic combustion of pulverized coal(PC).The effects of gas composition,oxygen concentration,the type,and the content of catalysts on the combustion reactivity were systematically analyzed.Furthermore,the structural changes of unburned pulverized coal were also examined.Experimental results indicate that as the oxygen concentration increased from 21%to 79%,compared with the O_(2)/N_(2)condition,the increment in the burnout rate of PC under the O_(2)/CO_(2)condition increased from 3%to 23%.After the addition of catalysts,including hematite,metallurgical oil sludge,and light-burnt dolomite(LBD),under the condition of 21%oxygen concentration,the effects of the three catalysts under the O_(2)/CO_(2)condition were superior to those under the O_(2)/N_(2)condition.This trend was reversed under the conditions of 38%and 79%oxygen concentrations.In all atmospheres,the three catalysts can enhance the burnout rate of PC.Among them,LBD exhibits the most favorable effect,and there exists an optimal dosage.Mechanistic analysis through scanning electron microscopy,X-ray diffraction,and N_(2)adsorption-desorption reveals that under 21%O_(2)/79%CO_(2)conditions,high-concentration CO_(2)leads to the formation of pores,and additives accelerate the oxidation of C and the gasification of CO_(2)through oxygen transfer,thereby enhancing the burnout rate of PC.
基金supported by the National Natural Science Foun-dation of China(No.U22A20578)the guiding project of seizing the commanding heights of“self-purifying city”(No.IUE-CERAE-202402)+3 种基金the Science and Technology Department of Fujian Province(No.2022L3025)the National Key Research and Development Program(No.2022YFC3700304)the STS Plan Supporting Project of the Chinese Academy of Sciences in Fujian Province(No.2023T3013)Xiamen Atmospheric Environment Observation and Research Station of Fujian Province.
文摘Ambient ozone(O_(3))is generated through the reactions of nitrogen oxides and volatile organic compounds(VOCs)in sunlight,and the primary sources of RO_(x)radicals play a very important role in O_(3)photochemistry.However,as major precursors of RO_(x)radicals,the systematical evaluation of ClNO_(2),HCHO,and HONO impacts on O_(3)photochemistry remains limited.Here,we utilized the observations of ClNO_(2),HCHO,and HONO conducted in a coastal city of Southeast China during a photochemical O_(3)pollution episode,combined with model simulations to elucidate their impacts on RO_(x)radicals and atmospheric oxidation capacity(AOC),as well as O_(3)formation.Decreased concentrations of ClNO_(2)and HONO were observed after sunrise,while HCHO concentrations peaked in the daytime.HCHO photolysis contributed the largest(∼25%)to RO_(x)radical production around noon,while HONO photolysis(∼47%)dominated RO_(x)radical production in the morning and late afternoon,and VOCs consumed by Cl radical released via ClNO_(2)photolysis was more important(∼10%)in the early morning,similar to their effects on the AOC levels.The results of model simulations indicated that HCHO photolysis greatly enhanced the photochemical formation of O_(3),followed by HONO and ClNO_(2)photolysis.Except for reducing VOCs due to a VOC-limited regime,the impacts of HCHO photolysis as primary RO_(x)sources should be valued to inhibit the intensification of O_(3)pollution.Our study stressed the importance of primary RO_(x)sources for O_(3)photochemistry in coastal regions,provided new insights into elucidating the self-purifying effect of the atmospheric environment.
基金supported by Chinese National Science and Technology Support Pro-gram (2008BAC35B01)Basic Research Project from Institute of Earthquake Science,China Earthquake Ad-ministration (02092408)
文摘The factors affecting the reflection and transmission coefficient of the ionosphere have been analyzed.These factors include wave frequency,incident angle,geomagnetic inclination,electron density and collision frequency in the ionosphere.The ionosphere refractive index is also analyzed.The ionosphere above 70 km is considered to be homogeneous and anisotropic,and the reflection and transmission coefficient matrix is calculated using matrix method.Simultaneously the Booker quartic equation is solved to get the refractive index in the ionosphere.The results show that when the wave frequency is higher,it is easier to penetrate into the ionosphere from its bottom boundary and the propagation attenuation in the ionosphere is smaller.TE（traverse electric） wave and TM（traverse magnetic） wave can both penetrate into the ionosphere with a small incident angle,while TE wave can hardly transmit into the ionosphere when the incident angle is large.The transmission coefficient decreases as the geomagnetic inclination increases.TE and TM wave cannot penetrate into the ionosphere at magnetic equator.When the electron collision frequency is higher,it is easier for VLF wave to penetrate into the ionosphere and the attenuation of ordinary wave is weaker,which may be caused by the energy transportation between the waves and the particles.The ordinary（O） wave experiences severer attenuation than extraordinary（X） wave,and X wave is a penetration mode whereas O wave is a non-penetration mode in the ionosphere.All the results indicate that VLF wave with higher frequency is easier to penetrate into the ionosphere and to be recorded by the satellites at high latitude.It is hard for ULF and the lower frequency VLF wave to transmit into the ionosphere directly for the severe reflection and attenuation.It may transmit into the ionosphere with a small incident angle due to the nonlinear effect,for example,the interaction between the waves and the particles or cross modulation,and then propagate along the whistle duct with small attenuation.This work may be a preliminary theoretical exploration for the future calculation on the response of ground based VLF artificial transmitter in the ionosphere and further study on the seismic ionosphere coupling model.
基金support from the National Natural Science Foundation of China(52172023 and 52302027).
文摘The Si_(3)N_(4)-bonded silicon carbide(SiC)bricks in the sloped zone of dry quenching coke ovens support the weight of upper refractory materials and equipment.These bricks endure frequent temperature fluctuations and intense abrasion from coke dust,demanding extremely high performance.After three years of service,an analysis of the Si_(3)N_(4)-bonded SiC bricks revealed that oxidation,which reduces thermal shock resistance,is the primary cause of degradation.In the unused Si_(3)N_(4)-bonded SiC bricks,short columnar β-Si_(3)N_(4) forms an interwoven network around SiC particles and contains a small amount of plate-like Si_(2)N_(2)O.Under the complex N_(2)(84.42 vol.%)-CO_(2)(10.44 vol.%)-CO(4.43 vol.%)-H_(2)(0.56 vol.%)-O_(2)(0.15 vol.%)atmosphere in the dry quenching coke oven,O_(2)(0.15 vol.%)exhibits a stronger oxidizing effect than CO_(2)(10.44 vol.%)and CO(4.43 vol.%),making it the primary oxidizing agent.The short columnarβ-Si_(3)N_(4) is more susceptible to oxidation than the particulate SiC.Based on thermodynamic and kinetic analyses,the chemical stability of the phases in Si_(3)N_(4)-bonded SiC bricks ranks from strongest to weakest as follows:Si_(2)N_(2)O,SiC,Si_(3)N_(4).Future development of Si_(2)N_(2)O-bonded SiC bricks could improve the longevity of refractory materials in the sloped zone of dry quenching coke ovens.
基金supported by the National Key R&D Program of China (Grant No. 2022YFF0503702)the National Natural Science Foundation of China (Grant No. 42074186)
文摘The algebraic reconstruction technique(ART),multiplicative algebraic reconstruction technique(MART),and simultaneous iterative reconstruction technique(SIRT)are computational methodologies extensively utilized within the field of computerized ionospheric tomography(CIT)to facilitate three-dimensional reconstruction of the ionospheric morphology.However,reconstruction accuracy elicits recurrent disputes over its practical application,and people usually attribute this issue to incomplete and uneven coverage of the measurements.The Thermosphere Ionosphere Electrodynamics General Circulation Model(TIEGCM)offers a reasonable physics-based ionospheric background and is widely utilized in ionospheric research.We use the TIEGCM simulations as the targeted ionosphere because the current measurements are far from able to realistically reproduce the ionosphere in detail.Optimized designations of satellite measurements are conducted to investigate the limiting performance of CIT methods in ionospheric reconstruction.Similar to common practice,electron density distributions from outputs of the International Reference Ionosphere(IRI)model are used as the iterative initial value in CIT applications.The outcomes suggest that despite data coverage,iterative initial conditions also play an essential role in ionospheric reconstruction.In particular,in the longitudinal sectors where the iterative initial height of the F2-layer peak electron density(hmF2)differs substantially from the background densities,none of the three CIT methods can reproduce the exact background profile.When hmF2 is close but the ionospheric F2-layer peak density(NmF2)is different between the targeted background and initial conditions,the MART performs better than the ART and SIRT,as evidenced by the correlation coefficients of MART being above 0.97 and those of ART and SIRT being below 0.85.In summary,this investigation reveals the potential uncertainties in traditional CIT reconstruction,particularly when realistic hmF2 or NmF2 values differ substantially from the initial CIT conditions.
基金prepared to summarize the research conducted during the first 2 years of research at the mid-term stage of the Dragon 5 project 59332(Geophysical and atmospheric retrieval from SAR data stacks over natural scenarios)funded by the European Space Agency under contract[4000136890/21/I-NB].
文摘This paper is intended to summarize the research conducted during the first 2 years of the Dragon 5 project 59,332(geophysical and atmospheric retrieval from Synthetic Aperture Radar(SAR)data stacks over natural scenarios).Monitoring atmospheric phenomena,encompassing both tropospheric and ionospheric conditions,holds pivotal significance for various scientific and practical applications.In this paper,we present an exploration of advanced techniques for estimating tropospheric and ionospheric phase screens using stacks of Synthetic Aperture Radar(SAR)images.Our study delves into the current state-of-the-art in atmospheric monitoring with a focus on spaceborne SAR systems,shedding light on their evolving capabilities.For tropospheric phase screen estimation,we propose a novel approach that jointly estimates the tropospheric component from all the images.We discuss the methodology in detail,highlighting its ability to recover accurate tropospheric maps.Through a series of quantitative case studies using real Sentinel-1 satellite data,we demonstrate the effectiveness of our technique in capturing tropospheric variability over different geographical regions.Concurrently,we delve into the estimation of ionospheric phase screens utilizing SAR image stacks.The intricacies of ionospheric disturbances pose unique challenges,necessitating specialized techniques.We dissect our approach,showcasing its capacity to mitigate ionospheric noise and recover precise phase information.Real data from the Sentinel-1 satellite are employed to showcase the efficacy of our method,unraveling ionospheric perturbations with improved accuracy.The integration of our techniques,though presented separately for clarity,collectively contributes to a comprehensive framework for atmospheric monitoring.Our findings emphasize the potential of SAR-based approaches in advancing our knowledge of atmospheric processes,thus fostering advancements in weather prediction,geophysics,and environmental management.
基金supported by the National Natural Science Foundation of China(No.41772240)the Key Research and Development program of Jiangsu Province(No.BE2021637).
文摘Ball milling is an environmentally friendly technology for the remediation of petroleumcontaminated soil(PCS),but the cleanup of organic pollutants requires a long time,and the post-remediation soil needs an economically viable disposal/reuse strategy due to its vast volume.The present paper develops a ball milling process under oxygen atmosphere to enhance PCS remediation and reuse the obtained carbonized soil(BCS-O)as wastewater treatment materials.The total petroleum hydrocarbon removal rates by ball milling under vacuum,air,and oxygen atmospheres are 39.83%,55.21%,and 93.84%,respectively.The Langmuir and pseudo second-order models satisfactorily describe the adsorption capacity and behavior of BCS-O for transition metals.The Cu^(2+),Ni^(2+),and Mn^(2+)adsorbed onto BCS-O were mainly bound to metal carbonates and metal oxides.Furthermore,BCS-O can effectively activate persulfate(PDS)oxidation to degrade aniline,while BCS-O loaded with transition metal(BCS-O-Me)shows better activation efficiency and reusability.BCS-O and BCS-O-Me activated PDS oxidation systems are dominated by^(1)O_(2)oxidation and electron transfer.The main active sites are oxygen-containing functional groups,vacancy defects,and graphitized carbon.The oxygen-containing functional groups and vacancy defects primarily activate PDS to generate^(1)O_(2)and attack aniline.Graphitized carbon promotes aniline degradation by accelerating electron transfer.The paper develops an innovative strategy to simultaneously realize efficient remediation of PCS and sequential reuse of the postremediation soil.
基金supported by the National Key R&D Program of China[grant number 2022YFF0801603]the Natural Science Foundation of China[grant number 41905074].
文摘Due to the high elevation and cold climate of the Tibetan Plateau,the western region retains extensive snow cover during the summer,which can exhibit rapid variability over the course of just a few days.This study utilizes numerical experiments to investigate the atmospheric response to extreme Tibetan Plateau snow cover(TPSC)events on a subseasonal timescale during summer.The results indicate that the subseasonal variations in TPSC exert limited impact on nonlocal atmospheric circulation and temperature during this period.Nevertheless,local surface energy and atmospheric temperature exhibit rapid cooling responses to increased snow cover.Specifically,an increase in snow cover over the western Tibetan Plateau leads to a sharp rise in surface albedo,resulting in a reduction in land surface energy and a negative response in the diabatic heating rate from the surface to 350 hPa locally.This negative diabatic heating response subsequently causes a decline in both surface and overlying atmospheric temperatures.The temperature response is confined to the western Tibetan Plateau and extends vertically from the surface to approximately 350 hPa.These extreme TPSC events and their associated atmospheric impacts occur within a two-week timescale.
基金supported by the National Natural Science Foundation of China(Grant Nos.12250013,12403070,12425306,42250101,12273092)the Macao Foundation,and Shanghai Post-doctoral Excellence Program(Grant No.2023000137)。
文摘The Sq(solar quiet)geomagnetic field is generated by the electric currents in the E-region of the ionosphere,driven by the atmospheric tides.It is a critical part of high-precision geomagnetic field modeling.Based on the classic thermal tide theory and atmospheric electrodynamics,this research,for the first time,developed an Sq geomagnetic field model that is directly built on the physical mechanism of the ionospheric dynamo,which is responsible for daily variations of the geomagnetic field.The performance in Sq geomagnetic field modeling was investigated using the Macao Science Satellite-1(MSS-1)data.Our model can enhance the physics-based framework of comprehensive geomagnetic field modeling for the MSS-1 and ensuing missions.
基金funded by the National Natural Science Foundation of China(U22A20547)the Major Science and Technology Projects of Heilongjiang Province(2021ZX12B05 and 2020ZX07B02)。
文摘The present study monitored bacterial succession,physicochemical properties,and volatile organic compounds(VOCs)changes in smoked chicken legs with modified atmosphere packaging(MAP,60% CO_(2) and 40%N_(2))during a 25-day storage period at 4℃.After 15 days of storage,S erratia proteamaculans and Pseudomonas fragi became the predominant bacteria.Furthermore,physicochemical properties changed significantly,as evidenced by an increase in thiobarbituric acid reactive substances and b*(yellowness)value,and a decrease in hardness.A total of 65 VOCs were identified during storage.Correlation between bacterial succession and quality indicators(including VOCs and physicochemical properties)allowed the identification of 26 core dominant bacteria,including S.proteamaculans,Psychrobacter alimentarius,Pseudomonas putida,and Pseudomonas poae,which were positively related to spoilage VOCs(e.g.,1-octen-3-ol,1-pentanol,and 3-methyl-1-butanol)and could be defined as specific spoilage organisms(SSOs).The results of this study provide a systematic approach to predict SSOs in smoked chicken legs during storage,which can also provide a basis for product safety.
文摘This work is an attempt to critically analyze the existing theoretical models of the impact of earthquake preparation processes on the state of the earth’s atmosphere and ionosphere in the zone of growing seismic activity, as well as the mechanisms of formation and transfer of disturbances in various media over the earthquake center. The determining factor (criterion) of the analysis is the degree of compliance of the simulation results with experimental data obtained at various phases of earthquake development by direct and remote diagnostic methods using ground and aerospace technologies. The key role is played by the model’s compliance with the results of measuring electric fields and currents in the near-ground atmosphere and ionosphere, small-scale ionospheric inhomogeneities and correlated field-aligned currents and electromagnetic ULF/ELF emissions. A full-fledged model should also explain the origin of such seismic related phenomena as the generation in the troposphere and over-horizon propagation of pulsed VHF radiation, thermal effects and associated IR emissions as well as the modification of plasma distribution in the D, E and F layers of the ionosphere. The use of this criterion in the analysis allowed us to identify a theoretical model that most fully describes the totality of the above-mentioned experimental data within a single physical mechanism. This is an electrodynamic model based on the perturbation of the conductivity current in the global atmosphere—ionosphere electric circuit due to the injection of charged aerosols into the atmosphere during the preparation and development of an earthquake. The present paper describes this model and the formation mechanisms of related phenomena in the atmosphere and ionosphere, which can be considered as short-term precursors to earthquakes.
基金This work is supported by the B-type Strategic Priority Program of the Chinese Academy of Sciences (Grant No. XDB4100000)the pre-research Project on Civil Aerospace Technologies No. D020105 funded by CNSAthe Strategic Priority Research Program of Chinese Academy of Sciences (Grant XDA17010404, XDA17010201)。
文摘In this study, we present an innovative Mars Ionosphere-Thermosphere Model(MITM), which is a time-dependent, threedimensional(3-D) model that comprehensively represents the self-consistently coupled thermosphere and ionosphere of Mars within the altitude range of 70-300 km. The model incorporates an extensive range of parameters, including neutral number densities of CO_(2), CO,O, O_(2), N_(2), NO, N(^(2)D), N(^(4)S), Ar, and He;ion number densities of CO_(2)^(+), CO^(+), O^(+), O_(2)^(+), N_(2)^(+), NO^(+), N^(+) ions, and electrons;neutral temperature;and neutral wind fields. The MITM code employs a high-resolution grid system in a spherical geographical coordinate system, with a horizontal resolution of 5° latitude by 7.5° longitude. This altitude-resolved grid system enables accurate depiction of spatial variations in the Martian thermosphere and ionosphere. To showcase the capabilities of the MITM, we present two simulation cases: one during the equinox and another during the solstice. Both simulations reproduce key features of the Martian thermosphere and ionosphere including the characteristics of horizontal circulation, diurnal variations in chemical composition, and distribution of electron density. The MITM offers a robust framework for understanding the intricate interactions and processes that shape the Mars thermosphere and ionosphere,which are crucial for enhancing our understanding of Martian upper atmosphere and ionosphere.
基金supported by the Chinese Academy of Sciences(CAS)Project of Stable Support for Youth Team in Basic Research Field(Grant No.YSRR-018)the National Key R&D Program of China(Grant No.2019YFC1510103)+1 种基金the National Natural Science Foundation of China(Grant Nos.41875006 and U1938115)the Chinese Meridian Project,and the International Partnership Program of CAS(Grant No.183311KYSB20200003).
文摘Tweek atmospherics are extremely low frequency and very low frequency pulse signals with frequency dispersion characteristics that originate from lightning discharges and that propagate in the Earth–ionosphere waveguide over long distances.In this study,we developed an automatic method to recognize tweek atmospherics and diagnose the lower ionosphere based on the machine learning method.The differences(automatic−manual)in each ionosphere parameter between the automatic method and the manual method were−0.07±2.73 km,0.03±0.92 cm^(−3),and 91±1,068 km for the ionospheric reflection height(h),equivalent electron densities at reflection heights(Ne),and propagation distance(d),respectively.Moreover,the automatic method is capable of recognizing higher harmonic tweek sferics.The evaluation results of the model suggest that the automatic method is a powerful tool for investigating the long-term variations in the lower ionosphere.
基金support from the National Natural Science Foundation of China(52174290).
文摘To explain the influence mechanism of MgO on the consolidation and reduction characteristics of roasted iron pellets,the properties and structure of pellets were investigated from multi-dimensions.It indicated that the MgO addition decreased the reduction swelling index(RSI)and reduction degree of pellets in both CO and H_(2)atmospheres.During the stepwise reduction process of Fe2O3→Fe3O4→FeO,the reduction behaviour of pellets in CO and H_(2)was similar,while the reduction rate of pellets in H_(2)atmosphere was almost twice as high as that in CO atmosphere.During the stepwise reduction process of FeO→Fe,the RSI of pellets showed a logarithmic increase in CO atmosphere and a linear decrease in H_(2)atmosphere.As investigated by first-principles calculations,C and Fe mainly formed chemical bonds,and the CO reduction process released energy,promoting the formation of iron whiskers.However,H and Fe produced weak physical adsorption,and the H_(2)reduction process was endothermic,inhibiting the generation of iron whiskers.With Mg2+doping in FexO,the nucleation region of iron whiskers expanded in CO reduction process,and the morphology of iron whiskers transformed from“slender”to“stocky,”reducing RSI of the pellets.
基金financial support for the research and for the publication costs of the articlesupported by Santa Catarina State Research Support Foundation(FAPESC)National Council for Scientific and Technological Development(CNPq no 302903/2023-2).
文摘Cement production,while essential for global infrastructure,contributes significantly to carbon dioxide emissions,accounting for approximately 7%of total emissions.To mitigate these environmental impacts,flash calcination of kaolinitic clays has been investigated as a sustainable alternative.This technique involves the rapid heating of clays,enabling their use as supplementary cementitious materials.The primary objective of this study was to modify the color of calcined clay in various atmospheres(oxidizing,inert,and reducing)to achieve a grayish tone similar to commercial cement while preserving its reactive properties.The experimental procedure employed a tubular reactor with precise control of gas flows(atmospheric air,nitrogen,and a carbon monoxide–nitrogen mixture).Physicochemical characterization of the raw clay was conducted before calcination,with analyses repeated on the calcined clays following experimentation.Results indicated that clay calcined in an oxidizing atmosphere acquired a reddish hue,attributed to the oxidation of iron in hematite.The Clay exhibited a pinkish tone in an inert atmosphere,while calcination in a reducing atmosphere yielded the desired grayish color.Regarding pozzolanic activity,clays calcined in oxidizing and inert atmospheres displayed robust strength,ranging from 82%to 87%.Calcination in a reducing atmosphere resulted in slightly lower strength,around 74%,likely due to the clay’s chemical composition and the calcination process,which affects compound formation and material reactivity.
文摘Arsenic(As),classified as a Group I carcinogen by the International Agency for Research on Cancer(IARC),poses severe risks to ecosystems and human health through atmospheric exposure.This review synthesizes current knowledge on the sources,health impacts,and control strategies of atmospheric arsenic,with an emphasis on its global transport and toxicity.Natural sources,such as volcanic eruptions and soil erosion,contribute approximately 2.1 Gg/year;however,anthropogenic activities,notably metal smelting and coal combustion,dominate emissions,with global anthropogenic releases reaching approximately 28.6 Gg/year.Atmospheric arsenic primarily exists in two forms:particulate matter(PM_(2.5)-bound As(Ⅴ)/As(Ⅲ)and methylated species)and gaseous forms(e.g.,AsH_(3),As_(2)O_(3)),facilitating long-range transport and cross-continental pollution,as evidenced by Asian emissions contributing 39% of Arctic deposition.Advanced techniques,such as inductively coupled plasma mass spectrometry(ICP-MS)and models like GEOS-Chem,enhance emission tracking;however,gaps persist in monitoring gaseous arsenic and refining emission inventories.Health risks include lung cancer,neurotoxicity,and cardiovascular diseases,exacerbated by inhalation and dietary exposure via contaminated crops.Control technologies,including calcium-and iron-based adsorbents and industrial scrubbers,show promise but face challenges related to efficiency and cost.Regional strategies,such as China’s tightened emission limits(0.5 mg/m^(3))and the EU’s Best Available Techniques(BAT),highlight progress,yet global cooperation remains vital for transboundary mitigation.Future research should prioritize low-cost sensors,elucidating speciation-toxicity relationships,and AI-driven emission management to address data gaps and optimize policies.Integrating multidisciplinary approaches—advanced science,stringent regulations,and international collaboration—is crucial to mitigate the environmental and public health impacts of arsenic amid growing industrialization and climate change.
文摘The direct deoxygenative homo-coupling of benzyl alcohols holds great promise to build up bibenzyl motifs in organic synthesis,yet it remains a grand challenge in selectivity and activity control.Herein,we first discovered that iron carbide catalysts displayed high efficiency and selectivity in the catalytic deoxygenative homo-coupling of benzyl alcohols into bibenzyls using H_(2)as the reductant.Ir-promoted Fe0@Fe_(5)C_(2)gave the best performance among the investigated catalysts,and a broad scope of substrates with diverse functional groups could be smoothly converted into bibenzyls,with the yield up to 85%.In addition,in the presence of alkenes,three-component coupling reactions between alcohols and alkenes were also for the first time achieved to construct more complex multi-ring molecules.The radical-trapping experiment and FTIR measurements revealed the radical nature of the reaction and the significantly promoted C–O bond activation after carbonization,respectively.This work will provide guidelines for the rational design of efficient and selective catalysts for the alcohol-involved carbon-carbon coupling reactions.
基金supported by the National Natural Science Foundation of China(Grant Numbers 42374195 and 42188101)the fellowship of China National Postdoctoral Program for Innovative Talents(Grant Number BX20230273)+1 种基金the Hubei Provincial Natural Science Foundation of China(Grant Number 2024AFB-097)the Postdoctor Project of Hubei Province(Grant Number 2024HBBHCXA054).
文摘This study employs Principal Component Analysis(PCA)and 13 years of SD-WACCM-X model data(2007-2019)to investigate the characteristics and mechanisms of Inter-hemispheric Coupling(IHC)triggered by sudden stratospheric warming(SSW)events.IHC in both hemispheres leads to a cold anomaly in the equatorial stratosphere,a warm anomaly in the equatorial mesosphere,and increased temperatures in the mesosphere and lower thermosphere(MLT)region of the summer hemisphere.However,the IHC features during boreal winter period are significantly weaker than during the austral winter period,primarily due to weaker stationary planetary wave activity in the Southern Hemisphere(SH).During the austral winter period,IHC results in a warm anomaly in the polar mesosphere of the SH,which does not occur in the NH during boreal winter period.This study also examines the possible influence of quasi-two-day waves(QTDWs)on IHC.We found that the largest temperature anomaly in the summer polar MLT region is associated with a large wind instability area,and a well-developed critical layer structure of QTDW in January.In contrast,during July,despite favorable conditions for QTDW propagation in the Northern Hemisphere,weaker IHC response is observed,suggesting that IHC features and the relationship with QTDWs during July would be more complex than during January.
