磷酸铁锂(LiFePO_(4),LFP)与镍钴锰酸锂(LiNi_(x)Co_(y)Mn_(2)O_(2),NCM)电池串联构建的混合动力电池系统,是突破传统单一化学体系瓶颈的关键技术。然而,混装电池包中LFP电池具有平坦的电压平台特性,导致全工作区间的荷电状态(state of ...磷酸铁锂(LiFePO_(4),LFP)与镍钴锰酸锂(LiNi_(x)Co_(y)Mn_(2)O_(2),NCM)电池串联构建的混合动力电池系统,是突破传统单一化学体系瓶颈的关键技术。然而,混装电池包中LFP电池具有平坦的电压平台特性,导致全工作区间的荷电状态(state of charge,SOC)估算精度受限,且在多算法切换时易出现SOC跳变现象。为此,本工作提出一种基于开路电压(open circuit voltage,OCV)曲线区间自适应划分的分段融合SOC估算方法。首先,考虑到LFP电池OCV斜率变化特征,设计了分段平滑策略,在高斜率区保持电压特征,在平台区增强平滑效果,并根据平滑OCV曲线的一阶差分斜率,设定自适应斜率阈值,将放电区间划分为前端高斜率区、中间平台区与后端高斜率区,为SOC算法选择提供明确依据;其次,构建分段估算框架:在高斜率区采用改进自适应扩展卡尔曼滤波进行SOC动态跟踪,在平台区则利用混合包中NCM电池的SOC进行映射估算。针对算法切换点SOC跳变问题,进一步提出梯度敏感的S型融合算法(gradient-sensitive adaptive blending,GSAB),该算法通过量化切换点邻域的SOC梯度差异,动态调整融合函数参数以生成平滑过渡权重,抑制切换点的SOC跳变。结果表明,改进自适应扩展卡尔曼滤波算法在NCM电池上的均方根误差相较于传统扩展卡尔曼滤波算法降低63.70%;GSAB策略有效消除了算法切换时的SOC突变,使过渡区波动降低72.42%。最终,在城市道路循环工况下,LFP电池全区间SOC估算的平均绝对误差与均方根误差分别降至1.08%和1.31%,验证了所提方法能有效提升LFP电池SOC全区间估算精度。展开更多
A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filte...A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp （A=116.5 nm）. The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized.展开更多
文摘A combination of high-field asymmetric waveform ion mobility spectrometry （FAIMS） with mass spectrometer （MS） was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp （A=116.5 nm）. The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized.
