The main ion-atomic collision treatment methods based on Monte-Carlo simulation are considered and discussed. We have proposed an efficient scheme for simulation of time between collisions taking into account cross-se...The main ion-atomic collision treatment methods based on Monte-Carlo simulation are considered and discussed. We have proposed an efficient scheme for simulation of time between collisions taking into account cross-section dependence on ion velocity and random generation of ion velocities and scattering angles after collisions. The developed algorithm of simulation of interval between collisions takes into account the change of relative velocity of ion-atom pair as well as the change of cross-section of collision and atomic concentration. At the same time, unlike the widely used “null-collision” method, both the probability of collision and change of particles’ state which determines this probability are taken into consideration for each particle independently in time. The simulation results according to the techniques proposed are found to be close to the theoretical values of ion drift velocities. It is revealed that the “null-collision” method results in exceeding of drift velocity in strong and intermediate fields. At the same time the proposed method of accumulation of probability under the same conditions gives values close to theoretical ones. In weak fields calculated values of drift velocity in both methods exceed theoretical values to some small extent.展开更多
X-ray emission from the collisions of 3 MeV Ar^(11+)ions with V,Fe,Co,Ni,Cu,and Zn is investigated.Both the x-rays of the target atom and projectile are observed simultaneously.The x-ray yield is extracted from the or...X-ray emission from the collisions of 3 MeV Ar^(11+)ions with V,Fe,Co,Ni,Cu,and Zn is investigated.Both the x-rays of the target atom and projectile are observed simultaneously.The x-ray yield is extracted from the original count.The inner-shell ionization cross section is estimated by the binary encounter approximation model and compared with the experimental result.The remarkable result is that the Ar K-shell x-ray yield is diminished with the target atomic number increasing,which is completely opposite to the theoretical calculation.That is interpreted by the competitive consumption of the energy loss for the ionization of inner-shell electrons between the projectile and target atom.展开更多
We have measured the cross-section ratios of helium induced by Cq＋ and Oq＋ （q = 1-4） in an energy range from 20 keV/amu to 500 keV/amu, and obtained the two-dimensional spectra by employing the coincidence method ...We have measured the cross-section ratios of helium induced by Cq＋ and Oq＋ （q = 1-4） in an energy range from 20 keV/amu to 500 keV/amu, and obtained the two-dimensional spectra by employing the coincidence method combined with the MPA-3 data acquisition system. Hence, we obtain the ratios of total single-ionization cross-sections （SI, SC, SLSI, and DLSI）, total double-ionization cross-sections （DI, DC, TI, SLDI, and DLDI） and cross-sections of every process （SI, SC, SLSI, DLSI, DI, DC, TI, SLDI, and DLDI）, which induce the single-ionization and double-ionization, to the total cross sections respectively. The competitive relations between the reaction-channels and the experimental data law of each reaction-channel are revealed explicitly, and the qualitative explanations involved in those results are also presented accordingly.展开更多
The K-shell x-rays of Ti, V, Fe, Co, Ni, Cu, and Zn induced by 424-MeV/u C^（6＋） ion impact are measured. It is found that the K x-ray shifts to the high energy side and the intensity ratio of Kβ/Kα is larger than...The K-shell x-rays of Ti, V, Fe, Co, Ni, Cu, and Zn induced by 424-MeV/u C^（6＋） ion impact are measured. It is found that the K x-ray shifts to the high energy side and the intensity ratio of Kβ/Kα is larger than the atomic data, owing to the L-shell multiple-ionization. The x-ray production cross sections are deduced from the experimental counts and compared with the binary encounter approximation（BEA）, plane wave approximation（PWBA） and energy-loss Coulomb-repulsion perturbed-stationary-state relativistic（ECPSSR） theoretical predictions. The BEA model with considering the multipleionization fluorescence yield is in better consistence with the experimental results. In addition, the cross section as a function of target atomic K-shell binding energy is presented.展开更多
In this paper a projectile ions recoil ions coincidence technique is employed to investigate the target ionization and projectile charge state changing processes in the collision of 0.22-6.35 MeV Cq^＋ （q = 1 - 4） i...In this paper a projectile ions recoil ions coincidence technique is employed to investigate the target ionization and projectile charge state changing processes in the collision of 0.22-6.35 MeV Cq^＋ （q = 1 - 4） ions with argon atoms. The partial cross section ratios of the double, triple, quadruplicate ionization to the single ionization （or the single capture） of argon associated with single electron loss （or single electron capture） by the projectile are measured and compared with the previous experimental results. In the present experiment, it is observed that the ratios of ionization cross sections R associated with single loss and single capture depend strongly on the projectile charge state and vary significantly with different reaction channels as impact energy increases. In addition, this paper gets empirical scaling laws for the ionization cross section ratios R corresponding to the projectile single loss and finds that the ratios of the double ionization to the single ionization associated with single electron capture remain constant in the present energy range.展开更多
The ratios of transfer ionization （TI） to single-electron capture （SC） cross sections have been measured for the collisions of partially stripped C^q＋ ions （q = 1-4） with He. The collision velocity ranges from ...The ratios of transfer ionization （TI） to single-electron capture （SC） cross sections have been measured for the collisions of partially stripped C^q＋ ions （q = 1-4） with He. The collision velocity ranges from 0.7 to 4.4 vo （vo is the Bohr velocity）. The projectile-ion and recoil-ion coincidence technique is used to separate the processes of TI and SC. The ratios reach the maximum when the velocity is about 3.7 vo. This can be explained qualitatively based on the two-step mechanism. The experimental results are also compared with the results calculated using the classical trajectory Monte Carlo （CTMC） method. The CTMC results are in agreement with the experimental data basically. The discrepancies in higher velocity region are interpreted by the effective charge effect.展开更多
The L-shell x-ray of Nd has been obtained for 300-600 keV He2+ions impacting,and compared with that produced by H+and H2+ions.The threshold of projectile kinetic energy for L-shell ionization of Nd is crudely verified...The L-shell x-ray of Nd has been obtained for 300-600 keV He2+ions impacting,and compared with that produced by H+and H2+ions.The threshold of projectile kinetic energy for L-shell ionization of Nd is crudely verified in the energy region of about 300-400 keV.It is found that the energy of the distinct L-subshell x-rays has a blue shift.The relative intensity ratios of Lβ_(1,3,4)and Lβ_(2,15)to Lα_(1,2)x-ray are enlarged compared to the atomic data,and they decrease with the increase of the incident energy,and increase with increasing the effective nuclear charge of the incident ions.That is interpreted by the multiple ionization of outer-shells induced by light ions.展开更多
Target ionization accompanied with projectile electron loss is investigated for 0.2-7 MeV C^q＋ （q = 1 - 4） with He and 0.25-5 MeV O^q＋ （q = 1 - 4） with He collisions. For projectile single-electron loss channel,...Target ionization accompanied with projectile electron loss is investigated for 0.2-7 MeV C^q＋ （q = 1 - 4） with He and 0.25-5 MeV O^q＋ （q = 1 - 4） with He collisions. For projectile single-electron loss channel, the He double-to-single ionization ratio R is nearly independent of projectile charge state but dependent on the nuclear charge of projectile Zp. The results are analysed with atomic structure qualitatively. So far there have not existed the experimental data comparable with our results, to our knowledge. The ratio R is interpreted in terms of the two-step mechanism. This analysis agrees well with similar experiments in the literature.展开更多
Electron-loss cross sections of 0q＋ （q = 1 -4） colliding with He, Ne and Ar atoms are measured in the intermediate velocity regime. The ratios of the cross sections of two-electron loss to that of one-electron loss...Electron-loss cross sections of 0q＋ （q = 1 -4） colliding with He, Ne and Ar atoms are measured in the intermediate velocity regime. The ratios of the cross sections of two-electron loss to that of one-electron loss R21 are presented. It is shown that single-channel analysis is not sufficient to explain the results, but that projectile electron loss, electron capture by the projectile and target ionization must be considered together to interpret the experimental data. The screening and antiscreening effects can account for the threshold velocity results, but cannot explain the dependence of the ratio R21 on velocity quantitatively. In general, the effective charge of the target atom increases with velocity increasing because the high-speed projectile ion can penetrate into the inner electronic shell of target atom. Ne and Ar atoms have similar effective charges in this velocity regime, but He atoms have smaller ones at the same velocities due to its smaller nuclear charge.展开更多
We investigate the single-electron loss processes of light charged ions （Li^1＋,2＋, C^2＋,3＋,5＋, and O^2＋,3＋） in collisions with helium. To better understand the experimental results, we propose a theoretical m...We investigate the single-electron loss processes of light charged ions （Li^1＋,2＋, C^2＋,3＋,5＋, and O^2＋,3＋） in collisions with helium. To better understand the experimental results, we propose a theoretical model to calculate the cross section of projectile electron loss. In this model, an ionization radius of the incident ion was defined under the classical over-barrier model, and we developed ＂strings＂ to explain the processes of projectile electron loss, which is similar with the molecular over-barrier model. Theoretical calculations are in good agreement with the experimental results for the cross section of single-electron loss and the ratio of double-to-single ionization of helium associated with one-electron loss.展开更多
In this paper, we studied the process of dissociation unimolecular of the evaporation of H+2n+1 hydrogen clusters according to size, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The rate constants k(E) were ...In this paper, we studied the process of dissociation unimolecular of the evaporation of H+2n+1 hydrogen clusters according to size, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The rate constants k(E) were determined with the use of statistical theory of unimolecular reactions using various approximations. In our work, we used the products frequencies instead of transitions frequencies in the calculation of unimolecular dissociation rates obtained by three models RRKM. The agreement between the experimental cross section ratio and calculated rate ratio with direct count approximation seems to be reasonable.展开更多
Multiple electron transfer processes are studied for Arq+ + Ne (q = 8, 9, 11, 12) collisions by using multi-parameter coincidence techniques. Various electron transfer processes are identified experimentally and the r...Multiple electron transfer processes are studied for Arq+ + Ne (q = 8, 9, 11, 12) collisions by using multi-parameter coincidence techniques. Various electron transfer processes are identified experimentally and the related cross-sections are measured. The dependence of transfer ionization cross-sections on the recoil charge states is compared with the results from the modified molecular classical overbarrier model. It is found that the modified model described the experimental results reasonably.展开更多
The ratios of the cross section of the transfer-ionization to the single-electron-capture of Argon induced by Cq+ (q=1,2,3) ions are measured by means of position sensitive and time-of-flight techniques. Our experimen...The ratios of the cross section of the transfer-ionization to the single-electron-capture of Argon induced by Cq+ (q=1,2,3) ions are measured by means of position sensitive and time-of-flight techniques. Our experimental results are compared with the data of Heq+ (q=1,2)-Ar of DuBois. A qualitative interpretation is presented based on the Classical-Over-Barrier Model of Bohr.展开更多
文摘The main ion-atomic collision treatment methods based on Monte-Carlo simulation are considered and discussed. We have proposed an efficient scheme for simulation of time between collisions taking into account cross-section dependence on ion velocity and random generation of ion velocities and scattering angles after collisions. The developed algorithm of simulation of interval between collisions takes into account the change of relative velocity of ion-atom pair as well as the change of cross-section of collision and atomic concentration. At the same time, unlike the widely used “null-collision” method, both the probability of collision and change of particles’ state which determines this probability are taken into consideration for each particle independently in time. The simulation results according to the techniques proposed are found to be close to the theoretical values of ion drift velocities. It is revealed that the “null-collision” method results in exceeding of drift velocity in strong and intermediate fields. At the same time the proposed method of accumulation of probability under the same conditions gives values close to theoretical ones. In weak fields calculated values of drift velocity in both methods exceed theoretical values to some small extent.
基金Project supported by the National Key R&D Program of China(Grant No.2017YFA0402300)the National Natural Science Foundation of China(Grant Nos.11505248,11775042,11875096,and 11605147)the Scientific Research Program Funded by Shaanxi Provincial Education Department,China(Grant No.20JK0975)+2 种基金the Scientific Research Plan of Science and Technology Department of Shaanxi Province,China(Grant Nos.2021JQ-812 and 2020JM-624)Open Funds of MOE Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions(Grant No.MPCEC201901)Xianyang Normal University Science Foundation(Grant Nos.XSYK20009 and XSYK20024).
文摘X-ray emission from the collisions of 3 MeV Ar^(11+)ions with V,Fe,Co,Ni,Cu,and Zn is investigated.Both the x-rays of the target atom and projectile are observed simultaneously.The x-ray yield is extracted from the original count.The inner-shell ionization cross section is estimated by the binary encounter approximation model and compared with the experimental result.The remarkable result is that the Ar K-shell x-ray yield is diminished with the target atomic number increasing,which is completely opposite to the theoretical calculation.That is interpreted by the competitive consumption of the energy loss for the ionization of inner-shell electrons between the projectile and target atom.
基金Project supported by the National Natural Science Foundation of China(Grant No.10775063)
文摘We have measured the cross-section ratios of helium induced by Cq＋ and Oq＋ （q = 1-4） in an energy range from 20 keV/amu to 500 keV/amu, and obtained the two-dimensional spectra by employing the coincidence method combined with the MPA-3 data acquisition system. Hence, we obtain the ratios of total single-ionization cross-sections （SI, SC, SLSI, and DLSI）, total double-ionization cross-sections （DI, DC, TI, SLDI, and DLDI） and cross-sections of every process （SI, SC, SLSI, DLSI, DI, DC, TI, SLDI, and DLDI）, which induce the single-ionization and double-ionization, to the total cross sections respectively. The competitive relations between the reaction-channels and the experimental data law of each reaction-channel are revealed explicitly, and the qualitative explanations involved in those results are also presented accordingly.
基金Project supported by the National Basic Research Program of China(Grant No.2010CB832902)the National Natural Science Foundation of China(Grant Nos.11505248,11375034,U1532263,11275241,11205225,11105192,and 11275238)the Scientific Research Program of Education Bureau of Shaanxi Province,China(Grant No.15JK1793)
文摘The K-shell x-rays of Ti, V, Fe, Co, Ni, Cu, and Zn induced by 424-MeV/u C^（6＋） ion impact are measured. It is found that the K x-ray shifts to the high energy side and the intensity ratio of Kβ/Kα is larger than the atomic data, owing to the L-shell multiple-ionization. The x-ray production cross sections are deduced from the experimental counts and compared with the binary encounter approximation（BEA）, plane wave approximation（PWBA） and energy-loss Coulomb-repulsion perturbed-stationary-state relativistic（ECPSSR） theoretical predictions. The BEA model with considering the multipleionization fluorescence yield is in better consistence with the experimental results. In addition, the cross section as a function of target atomic K-shell binding energy is presented.
文摘In this paper a projectile ions recoil ions coincidence technique is employed to investigate the target ionization and projectile charge state changing processes in the collision of 0.22-6.35 MeV Cq^＋ （q = 1 - 4） ions with argon atoms. The partial cross section ratios of the double, triple, quadruplicate ionization to the single ionization （or the single capture） of argon associated with single electron loss （or single electron capture） by the projectile are measured and compared with the previous experimental results. In the present experiment, it is observed that the ratios of ionization cross sections R associated with single loss and single capture depend strongly on the projectile charge state and vary significantly with different reaction channels as impact energy increases. In addition, this paper gets empirical scaling laws for the ionization cross section ratios R corresponding to the projectile single loss and finds that the ratios of the double ionization to the single ionization associated with single electron capture remain constant in the present energy range.
文摘The ratios of transfer ionization （TI） to single-electron capture （SC） cross sections have been measured for the collisions of partially stripped C^q＋ ions （q = 1-4） with He. The collision velocity ranges from 0.7 to 4.4 vo （vo is the Bohr velocity）. The projectile-ion and recoil-ion coincidence technique is used to separate the processes of TI and SC. The ratios reach the maximum when the velocity is about 3.7 vo. This can be explained qualitatively based on the two-step mechanism. The experimental results are also compared with the results calculated using the classical trajectory Monte Carlo （CTMC） method. The CTMC results are in agreement with the experimental data basically. The discrepancies in higher velocity region are interpreted by the effective charge effect.
基金supported by the National Key R&D Program of China(Grant No.2017YFA0402300)the National Natural Science Foundation of China(Grant Nos.11505248,11775042,11875096,and 11605147)+3 种基金the Scientific Research Program Funded by Shaanxi Provincial Education Department(Grant No.20JK0975)Scientific Research Plan of Science and Technology Department of Shaanxi Province,China(Grant No.2021JQ-812)Xianyang Normal University Science Foundation(Grant Nos.XSYK20024 and XSYK20009)the academic leader of Xianyang Normal University(Grant No.XSYXSDT202108)。
文摘The L-shell x-ray of Nd has been obtained for 300-600 keV He2+ions impacting,and compared with that produced by H+and H2+ions.The threshold of projectile kinetic energy for L-shell ionization of Nd is crudely verified in the energy region of about 300-400 keV.It is found that the energy of the distinct L-subshell x-rays has a blue shift.The relative intensity ratios of Lβ_(1,3,4)and Lβ_(2,15)to Lα_(1,2)x-ray are enlarged compared to the atomic data,and they decrease with the increase of the incident energy,and increase with increasing the effective nuclear charge of the incident ions.That is interpreted by the multiple ionization of outer-shells induced by light ions.
文摘Target ionization accompanied with projectile electron loss is investigated for 0.2-7 MeV C^q＋ （q = 1 - 4） with He and 0.25-5 MeV O^q＋ （q = 1 - 4） with He collisions. For projectile single-electron loss channel, the He double-to-single ionization ratio R is nearly independent of projectile charge state but dependent on the nuclear charge of projectile Zp. The results are analysed with atomic structure qualitatively. So far there have not existed the experimental data comparable with our results, to our knowledge. The ratio R is interpreted in terms of the two-step mechanism. This analysis agrees well with similar experiments in the literature.
基金supported by the Special Foundation for Key Programs of Basic Research at its earlier stage,Ministry of Science and Technology,China(Grant No. 2002CCA00900)the Foundation for the Doctors of University of South China (GrantNo. 5-2007-XQD-001)
文摘Electron-loss cross sections of 0q＋ （q = 1 -4） colliding with He, Ne and Ar atoms are measured in the intermediate velocity regime. The ratios of the cross sections of two-electron loss to that of one-electron loss R21 are presented. It is shown that single-channel analysis is not sufficient to explain the results, but that projectile electron loss, electron capture by the projectile and target ionization must be considered together to interpret the experimental data. The screening and antiscreening effects can account for the threshold velocity results, but cannot explain the dependence of the ratio R21 on velocity quantitatively. In general, the effective charge of the target atom increases with velocity increasing because the high-speed projectile ion can penetrate into the inner electronic shell of target atom. Ne and Ar atoms have similar effective charges in this velocity regime, but He atoms have smaller ones at the same velocities due to its smaller nuclear charge.
基金Project supported by the Special Program for Key Basic Research of the Ministry of Science and Technology,China(Grant No.2002CCA00900)the Fundamental Research Funds for the Central Universities of Ministry of Education of China(Grant No.lzujbky-2013-5)
文摘We investigate the single-electron loss processes of light charged ions （Li^1＋,2＋, C^2＋,3＋,5＋, and O^2＋,3＋） in collisions with helium. To better understand the experimental results, we propose a theoretical model to calculate the cross section of projectile electron loss. In this model, an ionization radius of the incident ion was defined under the classical over-barrier model, and we developed ＂strings＂ to explain the processes of projectile electron loss, which is similar with the molecular over-barrier model. Theoretical calculations are in good agreement with the experimental results for the cross section of single-electron loss and the ratio of double-to-single ionization of helium associated with one-electron loss.
文摘In this paper, we studied the process of dissociation unimolecular of the evaporation of H+2n+1 hydrogen clusters according to size, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The rate constants k(E) were determined with the use of statistical theory of unimolecular reactions using various approximations. In our work, we used the products frequencies instead of transitions frequencies in the calculation of unimolecular dissociation rates obtained by three models RRKM. The agreement between the experimental cross section ratio and calculated rate ratio with direct count approximation seems to be reasonable.
基金The authors would like to thank the ECR team for providing us with good beamThis work was supported by the National Natural Science Foundation of China (Grant No. 19704012)CAS-Bairen Plan.
文摘Multiple electron transfer processes are studied for Arq+ + Ne (q = 8, 9, 11, 12) collisions by using multi-parameter coincidence techniques. Various electron transfer processes are identified experimentally and the related cross-sections are measured. The dependence of transfer ionization cross-sections on the recoil charge states is compared with the results from the modified molecular classical overbarrier model. It is found that the modified model described the experimental results reasonably.
文摘The ratios of the cross section of the transfer-ionization to the single-electron-capture of Argon induced by Cq+ (q=1,2,3) ions are measured by means of position sensitive and time-of-flight techniques. Our experimental results are compared with the data of Heq+ (q=1,2)-Ar of DuBois. A qualitative interpretation is presented based on the Classical-Over-Barrier Model of Bohr.
