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Preparation and electrochemical properties of LiFePO_4/C composite with network structure for lithium ion batteries 被引量:12
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作者 陈晗 于文志 +1 位作者 韩绍昌 徐仲榆 《中国有色金属学会会刊:英文版》 EI CSCD 2007年第5期951-956,共6页
The bare LiFePO4 and LiFePO4/C composites with network structure were prepared by solid-state reaction. The crystalline structures, morphologies and specific surface areas of the materials were investigated by X-ray d... The bare LiFePO4 and LiFePO4/C composites with network structure were prepared by solid-state reaction. The crystalline structures, morphologies and specific surface areas of the materials were investigated by X-ray diffractometry(XRD), scanning electron microscopy(SEM) and multi-point brunauer emmett and teller(BET) method. The results show that the LiFePO4/C composite with the best network structure is obtained by adding 10% phenolic resin carbon. Its electronic conductivity increases to 2.86×10-2 S/cm. It possesses the highest specific surface area of 115.65 m2/g, which exhibits the highest discharge specific capacity of 164.33 mA·h/g at C/10 rate and 149.12 mA·h/g at 1 C rate. The discharge capacity is completely recovered when C/10 rate is applied again. 展开更多
关键词 电化学 锂电池 LIFEPO4 网络结构 复合物
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Fast estimation of ion temperature from EAST charge exchange recombination spectroscopy using neural network
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作者 Baoyue CHAI Yingying LI +7 位作者 Ze CHEN Wei TAO Yixuan ZHOU Shifeng MAO Zhengping LUO Yi YU Bo LV Minyou YE 《Plasma Science and Technology》 SCIE EI CAS CSCD 2019年第10期28-32,共5页
Ion temperature, as one of the most critical plasma parameters, can be diagnosed by charge exchange recombination spectroscopy (CXRS). Iterative least-squares fitting is conventionally used to analyze CXRS spectra to ... Ion temperature, as one of the most critical plasma parameters, can be diagnosed by charge exchange recombination spectroscopy (CXRS). Iterative least-squares fitting is conventionally used to analyze CXRS spectra to identify the active charge exchange component, which is the result of local interaction between impurity ions with a neutral beam. Due to the limit of the time consumption of the conventional approach (~100 ms per frame), the Experimental Advanced Superconducting Tokamak CXRS data is now analyzed in-between shots. To explore the feasibility of real-time measurement, neural networks are introduced to perform fast estimation of ion temperature. Based on the same four-layer neural network architecture, two neural networks are trained for two central chords according to the ion temperature data acquired from the conventional method. Using the TensorFlow framework, the training procedures are performed by an error back-propagation algorithm with the regularization via the weight decay method. Good agreement in the deduced ion temperature is shown for the neural networks and the conventional approach, while the data processing time is reduced by 3 orders of magnitude (~0.1 ms per frame) by using the neural networks. 展开更多
关键词 CXRS NEURAL network ion TEMPERATURE EAST
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Effects of information transmission delay and channel blocking on synchronization in scale-free Hodgkin-Huxley neuronal networks
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作者 Qing-Yun Wang Yan-Hong Zheng 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第6期1052-1058,共7页
In this paper,we investigate the evolution of spatiotemporal patterns and synchronization transitions in dependence on the information transmission delay and ion channel blocking in scale-free neuronal networks.As the... In this paper,we investigate the evolution of spatiotemporal patterns and synchronization transitions in dependence on the information transmission delay and ion channel blocking in scale-free neuronal networks.As the underlying model of neuronal dynamics,we use the Hodgkin-Huxley equations incorporating channel blocking and intrinsic noise.It is shown that delays play a significant yet subtle role in shaping the dynamics of neuronal networks.In particular,regions of irregular and regular propagating excitatory fronts related to the synchronization transitions appear intermittently as the delay increases.Moreover,the fraction of working sodium and potassium ion channels can also have a significant impact on the spatiotemporal dynamics of neuronal networks.As the fraction of blocked sodium channels increases,the frequency of excitatory events decreases,which in turn manifests as an increase in the neuronal synchrony that,however,is dysfunctional due to the virtual absence of large-amplitude excitations.Expectedly,we also show that larger coupling strengths improve synchronization irrespective of the information transmission delay and channel blocking.The presented results are also robust against the variation of the network size,thus providing insights that could facilitate understanding of the joint impact of ion channel blocking and information transmission delay on the spatiotemporal dynamics of neuronal networks. 展开更多
关键词 Scale-free neuronal networks - Information transmission delay ion channel blocking SYNCHRONIZATion
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Large scale silver nanowires network fabricated by MeV hydrogen (H+) ion beam irradiation
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作者 Honey S Naseem S +3 位作者 Ishaq A Maaza M Bhatti M T Wan D 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第4期268-273,共6页
A random two-dimensional large scale nano-network of silver nanowires (Ag-NWs) is fabricated by MeV hydrogen (H+) ion beam irradiation. Ag-NWs are irradiated under H+ ion beam at different ion fluences at room t... A random two-dimensional large scale nano-network of silver nanowires (Ag-NWs) is fabricated by MeV hydrogen (H+) ion beam irradiation. Ag-NWs are irradiated under H+ ion beam at different ion fluences at room temperature. The Ag-NW network is fabricated by H+ ion beam-induced welding of Ag-NWs at intersecting positions. H+ ion beam induced welding is confirmed by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Moreover, the structure of Ag NWs remains stable under H+ ion beam, and networks are optically transparent. Morphology also remains stable under H+ ion beam irradiation. No slicings or cuttings of Ag-NWs are observed under MeV H+ ion beam irradiation. The results exhibit that the formation of Ag-NW network proceeds through three steps: ion beam induced thermal spikes lead to the local heating of Ag-NWs, the formation of simple junctions on small scale, and the formation of a large scale network. This observation is useful for using Ag-NWs based devices in upper space where protons are abandoned in an energy range from MeV to GeV. This high-quality Ag-NW network can also be used as a transparent electrode for optoelectronics devices. 展开更多
关键词 Ag nanowires H+ ion irradiation nanowelding large scale nano-network optical properties
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基于人工神经网络预测锂离子软包电池充放电行为研究
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作者 刘宁 孙海波 《微纳电子技术》 2026年第1期94-103,共10页
基于人工神经网络(ANN)技术对钴酸锂/镍钴酸锂软包电池不同循环次数下的充放电曲线进行了预测,研究了隐含层数量、隐含层神经元个数、传递函数类型及优化算法对充放电曲线预测精度的调控作用。结果表明,采用单隐含层的ANN模型可实现充... 基于人工神经网络(ANN)技术对钴酸锂/镍钴酸锂软包电池不同循环次数下的充放电曲线进行了预测,研究了隐含层数量、隐含层神经元个数、传递函数类型及优化算法对充放电曲线预测精度的调控作用。结果表明,采用单隐含层的ANN模型可实现充放电曲线的高精度预测。预测充电行为时,最优的网络结构为2-47-1,隐含层和输出层传递函数分别为logsig和purelin,优化算法选用trainbr,预测值与实验值的均方误差(MSE)最低为2.43×10-7;预测放电行为时,最优的网络结构为2-69-1,隐含层与输出层传递函数分别为tansig和purelin,优化算法仍为trainbr,MSE最低为1.41×10-6。基于电池1数据优化的模型可有效预测电池2的充放电行为,MSE稳定在10-5数量级;当循环次数增至7000次时,MSE升至10-2~10-3数量级,这是由于模型未能充分表征电池老化过程中的电化学特征。此外,该ANN模型在训练、验证和测试数据集上的回归系数(R2)均超过0.99,展现出优异的预测精度与泛化能力。 展开更多
关键词 锂离子电池 软包电池 充放电曲线 人工神经网络(ANN) 电化学行为预测
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PSO优化的BiLSTM-Attention网络的锂电池健康状态评估 被引量:9
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作者 张永 辛宇琪 +2 位作者 钱启政 解进 冉少林 《控制工程》 CSCD 北大核心 2022年第2期287-293,共7页
锂离子电池作为一种高效的储能元件,被广泛应用到生产生活的各个领域,其健康状态事关系统的安全性,受到越来越多的重视。基于粒子群优化算法,优化了具有注意力机制的双向长短期记忆网络,实现了锂离子电池的健康评估。首先,考虑到锂电池... 锂离子电池作为一种高效的储能元件,被广泛应用到生产生活的各个领域,其健康状态事关系统的安全性,受到越来越多的重视。基于粒子群优化算法,优化了具有注意力机制的双向长短期记忆网络,实现了锂离子电池的健康评估。首先,考虑到锂电池数据的时序特征,采取了一种双向长短期记忆网络提高预测效果,并且引入注意力机制解决信息过载问题,提高任务处理的效率和准确性。接着,利用粒子群优化算法优化网络模型结构的参数,获得高效的锂电池健康状态估计。最后,引入NASA锂离子电池数据集。实验结果验证了所提方法的有效性。 展开更多
关键词 锂离子电池 双向长短期记忆神经网络 注意力机制 健康状态
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基于ResNet-Bi-LSTM-Attention的锂离子电池剩余使用寿命预测 被引量:11
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作者 王朋凯 张新燕 张光昊 《储能科学与技术》 CAS CSCD 北大核心 2023年第4期1215-1222,共8页
锂离子电池剩余使用寿命(RUL)预测是锂离子电池研究的一个重要方向,通过对RUL的准确预测,可以降低锂离子电池出现事故的概率。针对锂离子电池RUL的准确预测,该研究提出一种综合残差神经网络(ResNet)和双向长短期记忆网络(Bi-LSTM)的优势... 锂离子电池剩余使用寿命(RUL)预测是锂离子电池研究的一个重要方向,通过对RUL的准确预测,可以降低锂离子电池出现事故的概率。针对锂离子电池RUL的准确预测,该研究提出一种综合残差神经网络(ResNet)和双向长短期记忆网络(Bi-LSTM)的优势,并且加入注意力机制(Attention)的锂离子电池RUL预测模型。首先选取能够表现电池寿命的特征参数作为输入量,利用ResNet提取输入数据的隐含特征信息,然后利用Bi-LSTM对时间序列信息进行预测,并且结合注意力机制对预测结果进行权重分配,得到最终的锂离子电池的RUL预测结果。通过美国马里兰大学(CALCE)提供的开源数据集进行锂离子电池RUL预测试验,并与现有的预测模型进行对比试验,对比模型的预测结果,试验结果表明提出的ResNet-Bi-LSTM-Attention模型能够准确地进行锂离子电池RUL预测,各项误差都比较低,具有较好的精度和准确性。最后使用美国航空航天局(NASA)提供的锂离子电池开源数据集进行泛化性实验,证明了ResNet-Bi-LSTM-Attention模型在不同电池RUL预测中具有良好的准确性,可以被广泛使用。 展开更多
关键词 锂离子电池 残差神经网络 双向长短期记忆网络 注意力机制 剩余使用寿命预测
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COORDINATION CROSSLINKING OF NITRILE RUBBER FILLED WITH COPPER SULFATE PARTICLES 被引量:4
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作者 吴驰飞 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2007年第5期447-459,共13页
By incorporating copper sulfate (CuSO4) particles into acrylonitrile butadiene rubber (NBR) followed by heat pressing, a novel vulcanization method is developed in rubber through the formation of coordination cros... By incorporating copper sulfate (CuSO4) particles into acrylonitrile butadiene rubber (NBR) followed by heat pressing, a novel vulcanization method is developed in rubber through the formation of coordination crosslinking. This method totally differs from traditional covalent or non-covalent vulcanization approaches of rubber. No other vulcanizing agent or additional additive is involved in this process. By analyzing the results of DMA, XPS and FT-IR, it is found that the crosslinking of CuSO4 particles filled NBR was induced by in situ coordination between nitrogen atoms of nitrile groups (-CN) and copper ions (Cu^2+) from CuSO4. SEM and EDX results revealed the generation of a core (CuSO4 solid particle)- shell (adherent NBR) structure, which leads to a result that the crosslinked rubber has excellent mechanical properties. Moreover, poly(vinyl chloride) (PVC) and liquid acrylonitrile-butadiene rubber (LNBR) were used as mobilizer to improve the coordination crosslinking of CuSO4/NBR. The addition of PVC or LNBR could lead to higher crosslink density and better mechanical properties of coordination vulcanization. In addition, crystal water in CuSO4 played a positive role to coordination crosslinking of rubber because it decreased the metal point of CuSO4 and promoted the metal ionization. 展开更多
关键词 COORDINATion Crosslink network Copper ions Nitrile rubber Vulcanization.
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Metal–Oleate Complex?Derived Bimetallic Oxides Nanoparticles Encapsulated in 3D Graphene Networks as Anodes for Efficient Lithium Storage with Pseudocapacitance 被引量:1
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作者 Yingying Cao Kaiming Geng +6 位作者 Hongbo Geng Huixiang Ang Jie Pei Yayuan Liu Xueqin Cao Junwei Zheng Hongwei Gu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2019年第1期250-263,共14页
In this manuscript, we have demonstrated the delicate design and synthesis of bimetallic oxides nanoparticles derived from metal–oleate complex embedded in 3D graphene networks(MnO/CoMn_2O_4  GN), as an anode mater... In this manuscript, we have demonstrated the delicate design and synthesis of bimetallic oxides nanoparticles derived from metal–oleate complex embedded in 3D graphene networks(MnO/CoMn_2O_4  GN), as an anode material for lithium ion batteries. The novel synthesis of the MnO/CoMn_2O_4  GN consists of thermal decomposition of metal–oleate complex containing cobalt and manganese metals and oleate ligand, forming bimetallic oxides nanoparticles, followed by a selfassembly route with reduced graphene oxides. The MnO/CoMn_2O_4  GN composite, with a unique architecture of bimetallic oxides nanoparticles encapsulated in 3D graphene networks, rationally integrates several benefits including shortening the di usion path of Li^+ ions, improving electrical conductivity and mitigating volume variation during cycling. Studies show that the electrochemical reaction processes of MnO/Co Mn_2O_4  GN electrodes are dominated by the pseudocapacitive behavior, leading to fast Li^+ charge/discharge reactions. As a result, the MnO/CoMn_2O_4  GN manifests high initial specific capacity, stable cycling performance, and excellent rate capability. 展开更多
关键词 Metal–oleate complex Bimetallic oxides NANOPARTICLES Porous architecture 3D GRAPHENE networkS Lithium ion batteries
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Quantum light storage in rare-earth-ion-doped solids 被引量:1
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作者 华怡林 周宗权 +1 位作者 李传锋 郭光灿 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第2期104-113,共10页
The reversible transfer of unknown quantum states between light and matter is essential for constructing large-scale quantum networks. Over the last decade, various physical systems have been proposed to realize such ... The reversible transfer of unknown quantum states between light and matter is essential for constructing large-scale quantum networks. Over the last decade, various physical systems have been proposed to realize such quantum memory for light. The solid-state quantum memory based on rare-earth-ion-doped solids has the advantages of a reduced setup complexity and high robustness for scalable application. We describe the methods used to spectrally prepare the quantum memory and release the photonic excitation on-demand. We will review the state of the art experiments and discuss the perspective applications of this particular system in both quantum information science and fundamental tests of quantum physics. 展开更多
关键词 quantum memory quantum physics quantum network rare-earth-ion-doped solids
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Coherence resonance in globally coupled neuronal networks with different neuron numbers
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作者 Ning Wei-Lian Zhang Zheng-Zhen +5 位作者 Zeng Shang-You Luo Xiao-Shu Hu Jin-Lin Zeng Shao-Wen Qiu Yi Wu Hui-Si 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第2期569-576,共8页
Because a brain consists of tremendous neuronal networks with different neuron numbers ranging from tens to tens of thousands, we study the coherence resonance due to ion channel noises in globally coupled neuronal ne... Because a brain consists of tremendous neuronal networks with different neuron numbers ranging from tens to tens of thousands, we study the coherence resonance due to ion channel noises in globally coupled neuronal networks with different neuron numbers. We confirm that for all neuronal networks with different neuron numbers there exist the array enhanced coherence resonance and the optimal synaptic conductance to cause the maximal spiking coherence. Furthermoremore, the enhancement effects of coupling on spiking coherence and on optimal synaptic conductance are almost the same, regardless of the neuron numbers in the neuronal networks. Therefore for all the neuronal networks with different neuron numbers in the brain, relative weak synaptic conductance (0.1 mS/cm2) is sufficient to induce the maximal spiking coherence and the best sub-threshold signal encoding. 展开更多
关键词 coherence resonance ion channel noise neuronal network
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Surface modification of polyolefin separators for lithium ion batteries to reduce thermal shrinkage without thickness increase 被引量:7
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作者 Peng Zhao Juping Yang +4 位作者 Yuming Shang Li Wang Mou Fang Jianlong Wang Xiangming He 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2015年第2期138-144,共7页
Surface chemical modification of polyolefin separators for lithium ion batteries is attempted to reduce the thermal shrinkage, which is im- portant for the battery energy density. In this study, we grafted organic/ino... Surface chemical modification of polyolefin separators for lithium ion batteries is attempted to reduce the thermal shrinkage, which is im- portant for the battery energy density. In this study, we grafted organic/inorganic hybrid crosslinked networks on the separators, simply by grafting polymerization and condensation reaction. The considerable silicon-oxygen crosslinked heat-resistance networks are responsible for the reduced thermal shrinkage. The strong chemical bonds between networks and separators promise enough mechanical support even at high temperature. The shrinkage at 150 ℃ for 30 min in the mechanical direction was 38.6% and 4.6% for the pristine and present graft-modified separators, respectively. Meanwhile, the grafting organic-inorganic hybrid crosslink networks mainly occupied part of void in the internal pores of the separators, so the thicknesses of the graft-modified separators were similar with the pristine one. The half cells prepared with the modified separators exhibited almost identical electrochemical properties to those with the commercial separators, thus proving that, in order to enhance the thermal stability of lithium ion battery, this kind of grafting-modified separators may be a better alternative to conventional silica nanoparticle layers-coated polyolefin separators. 展开更多
关键词 thermal shrinkage organic/inorganic hybrid crosslinked network chemical grafting SEPARATOR lithium ion battery
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基于短时随机充电数据和优化卷积神经网络的锂电池健康状态估计 被引量:2
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作者 申江卫 折亦鑫 +4 位作者 舒星 刘永刚 魏福星 夏雪磊 陈峥 《储能科学与技术》 北大核心 2025年第4期1585-1595,共11页
用户充电过程较强的随机性,导致很难获得完整且固定的充电段用于精确表征电池健康状态的变化。针对充电行为的无序性,提出了一种基于随机健康指标和卷积神经网络的电池健康状态估计方法。对锂电池的原始充电电压时序数据进行分割作为随... 用户充电过程较强的随机性,导致很难获得完整且固定的充电段用于精确表征电池健康状态的变化。针对充电行为的无序性,提出了一种基于随机健康指标和卷积神经网络的电池健康状态估计方法。对锂电池的原始充电电压时序数据进行分割作为随机充电数据,使用单一卷积神经网络架构从中自适应提取老化特征,并采用蜣螂优化算法对其参数寻优,建立了多阶段模型。仅使用短时随机原始充电电压数据即可实现电池健康状态估计,且有效适用于不同充电模式和充电速率。实验测试验证结果表明,使用连续5 s(100个数据点)的原始电压时序数据,在恒流-恒压充电模式下,锂电池健康状态估计结果平均绝对误差小于2.07%,在多阶段恒流充电模式下,锂电池健康状态估计结果平均绝对误差小于1.22%。 展开更多
关键词 健康状态 随机充电 数据分割 卷积神经网络 锂离子电池
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Spherical FeF3·0.33H2O/MWCNTs nanocomposite with mesoporous structure as cathode material of sodium ion battery 被引量:2
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作者 Shuangying Wei Xianyou Wang +3 位作者 Min Liu Rui Zhang Gang Wang Hai Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2018年第2期573-581,共9页
FeF3·0.33H2O crystallizes in hexagonal tungsten bronze structure with more opened hexagonal cavities are considered as next generation electrode materials of both lithium ion battery and sodium ion battery.In thi... FeF3·0.33H2O crystallizes in hexagonal tungsten bronze structure with more opened hexagonal cavities are considered as next generation electrode materials of both lithium ion battery and sodium ion battery.In this paper the mesoporous spherical FeF3·0.33H2O/MWCNTs nanocomposite was successfully synthesized via a one-step solvothermal approach. Galvanostatic measurement showed that the performances of sodium ion batteries(SIBs) using FeF3·0.33H2O/MWCNTs as cathode material were highly dependent on the morphology and size of the as-prepared materials. Benefitting from the special mesoporous structure features, FeF3·0.33H2O/MWCNTs nanocomposite exhibits much better electrochemical performances in terms of initial discharge capacity(350.4 mAh g-1) and cycle performance(123.5 mAh g-1 after 50 cycles at 0.1 C range from 1.0 V to 4.0 V) as well as rate capacity(123.8 mAh g-1 after 25 cycles back to 0.1 C). The excellent electrochemical performance enhancement can be attributed to the synergistic effect of the mesoporous structure and the MWCNTs conductive network, which can effectively increase the contact area between the active materials and the electrolyte, shorten the Na+ diffusion pathway,buffer the volume change during cycling/discharge process and improve the structure stability of the FeF3·0.33H2O/MWCNTs nanocomposite. 展开更多
关键词 Sodium ion batteries Cathode material Spherical nanoparticles Mesoporous structure Conductive network
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基于GRU的地层液离子浓度趋势预测方法研究
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作者 张岩 张可佳 刘涛 《微型电脑应用》 2025年第11期6-11,共6页
地层液离子浓度的变化趋势是进行采油井结垢预测的重要依据。由于离子浓度数据具有类型复杂、维度高、规律性弱的特点,导致传统预测方法预测效果较差、精度较低。为此,结合深度学习理论,提出一种基于循环神经网络的地层液离子浓度预测... 地层液离子浓度的变化趋势是进行采油井结垢预测的重要依据。由于离子浓度数据具有类型复杂、维度高、规律性弱的特点,导致传统预测方法预测效果较差、精度较低。为此,结合深度学习理论,提出一种基于循环神经网络的地层液离子浓度预测方法。在深入分析离子浓度数据类型和特点的基础上应用数据分解方法,合理增加样本数量;设计门控循环单元(GRU)网络模型学习离子浓度数据的变化规律,得到离子浓度预测值;在真实场景下,设计比较实验进行方法的预测精度和稳定性测验。实验结果表明,所提出的方法具有较高的预测精度和较好的稳定性。 展开更多
关键词 采油井结垢 深度学习 循环神经网络 离子浓度趋势预测
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离子交联纳米复合高强度水凝胶的制备与性能 被引量:1
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作者 游曼可 周卿云 +3 位作者 柴子铧 王大威 吴江渝 曾小平 《复合材料学报》 北大核心 2025年第6期3439-3448,共10页
通过自由基聚合法和盐溶液浸泡法相结合,制备了一种综合性能良好的离子交联纳米复合水凝胶。首先用水溶性短链壳聚糖(CS)改性埃洛石纳米管(HNTs),再与丙烯酰胺(AM)、丙烯酸(AA)等经过热引发自由基聚合得到纳米复合水凝胶基体,随后浸泡Fe... 通过自由基聚合法和盐溶液浸泡法相结合,制备了一种综合性能良好的离子交联纳米复合水凝胶。首先用水溶性短链壳聚糖(CS)改性埃洛石纳米管(HNTs),再与丙烯酰胺(AM)、丙烯酸(AA)等经过热引发自由基聚合得到纳米复合水凝胶基体,随后浸泡Fe(NO_(3))_(3)溶液、Na_(2)SO_(4)溶液,得到力学性能优异、具有独特抗溶胀性且抗冻的离子交联纳米复合水凝胶。FTIR及TEM结果证实形成了CS修饰HNTs的结构,复合水凝胶的SEM结果显示浸泡离子后结构变得更加紧密、孔洞尺寸明显减少。考察了不同含量的AA、HNTs对复合水凝胶力学性能的影响。结果表明:当CS为2wt%,AA占单体总量的12mol%、AM占88mol%,HNTs为3.5wt%且浸泡了Fe^(3+)和SO_(4)^(2-)离子溶液时,水凝胶的综合力学性能最佳,拉伸强度与断裂伸长率分别达到3.96 MPa与553%,85%应变下的抗压强度为13.4 MPa,且经过去离子水浸泡48 h后,拉伸强度增长到5.64MPa,模量高达15 MPa,为设计和开发强韧水凝胶提供了新策略。 展开更多
关键词 埃洛石纳米管 复合水凝胶 离子交联 双网络 高强度
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共建“一带一路”国家锂离子电池贸易网络结构动态演变及驱动因素研究
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作者 程云洁 李沛阳 《新疆财经》 2025年第1期70-80,共11页
文章选取2012—2022年共建“一带一路”国家锂离子电池贸易额数据,采用社会网络分析法构建共建“一带一路”国家锂离子电池贸易网络并分析其结构动态演变的驱动因素。研究发现:共建“一带一路”国家锂离子电池贸易网络的空间关联性、稳... 文章选取2012—2022年共建“一带一路”国家锂离子电池贸易额数据,采用社会网络分析法构建共建“一带一路”国家锂离子电池贸易网络并分析其结构动态演变的驱动因素。研究发现:共建“一带一路”国家锂离子电池贸易网络的空间关联性、稳定性和连通性逐步增强,并呈现明显的“小世界”特征;共建“一带一路”国家锂离子电池贸易网络社团逐步聚拢,中国、新加坡、捷克和波兰在贸易网络中处于核心地位;国内生产总值、石油出口量、研发支出占GDP比重、地理距离、接壤国家和“双碳”目标是共建“一带一路”国家锂离子电池贸易网络结构动态演变的主要驱动因素。今后,中国应进一步提升创新能力,加快电子商务服务平台、跨境物流通道建设,推进“一带一路”互联互通建设,推进共建“一带一路”绿色发展。 展开更多
关键词 “一带一路” 锂离子电池贸易 社会网络分析法 QAP模型
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创新的三个空间维度:理论辨析与实证检验
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作者 李刚 王世福 袁奇峰 《城市规划》 北大核心 2025年第8期27-39,共13页
从创新何以成为城市规划学研究的对象引出思考,核心是辨析创新具有的空间维度。首先,从梳理创新研究脉络切入,厘清从1970年代开始创新研究产生3个空间转向派别,包括创新经济地理、创新城市地理、创新空间建设的研究。其次,从中辨析出创... 从创新何以成为城市规划学研究的对象引出思考,核心是辨析创新具有的空间维度。首先,从梳理创新研究脉络切入,厘清从1970年代开始创新研究产生3个空间转向派别,包括创新经济地理、创新城市地理、创新空间建设的研究。其次,从中辨析出创新活动具有3个空间维度——空间集聚维度,归因于地理空间邻近效应;空间网络维度,归因于创新具有开放性;空间培育维度,归因于政府以空间培育创新。第三,以广州实证检验展示了创新的3个空间维度,广州是珠三角区域创新中的高等级城市、网络中心城市,广州的创新活动集聚形成53个“创新空间单元”,构成“三级九类”创新空间体系,并形成“三心”协同的“核心—边缘”创新空间网络结构,其中广州科学城是政府以空间培育创新的成功案例,展现了空间规划可干预创新。 展开更多
关键词 创新空间 创新地理 创新网络 规划干预 广州
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双网络As(Ⅴ)离子印迹水凝胶的制备及其吸附性能
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作者 莫叶伶 周典礼 +7 位作者 朱俊杰 李高阳 高佳丽 徐斐 曹慧 袁敏 叶泰 阴凤琴 《分析试验室》 北大核心 2025年第2期167-173,共7页
以As(Ⅴ)阴离子为模板,N,N,N-三甲基-3-(2-甲基烯丙酰氨基)-1-氯化丙铵和丙烯酰胺为功能单体,N,N,N,N-四甲基乙二胺(TEMED)为促进剂,过硫酸铵(APS)为引发剂,N,N-亚甲基双丙烯酰胺(MBA)为交联剂,合成了双网络As(Ⅴ)离子印迹冷冻凝胶(DIIC... 以As(Ⅴ)阴离子为模板,N,N,N-三甲基-3-(2-甲基烯丙酰氨基)-1-氯化丙铵和丙烯酰胺为功能单体,N,N,N,N-四甲基乙二胺(TEMED)为促进剂,过硫酸铵(APS)为引发剂,N,N-亚甲基双丙烯酰胺(MBA)为交联剂,合成了双网络As(Ⅴ)离子印迹冷冻凝胶(DIIC)。采用扫描电镜(SEM)、傅立叶变换红外光谱(FT-IR)和X射线光电子能谱(XPS)对DIIC进行表征,并对吸附条件进行了优化。在pH 9、环境温度25℃、As(Ⅴ)溶液浓度300mg/L、吸附时间5min时,DIIC的最佳吸附量为48.47mg/g,非离子印迹水凝胶(DNIC)的饱和吸附量为24.05 mg/g,印迹因子为2.02。吸附动力学和等温吸附模型表明,DNIC和DIIC对As(Ⅴ)的吸附属于单分子层化学吸附,检测限为0.32μg/L;在加标样品中的回收率在80%以上,有望用于痕量As(Ⅴ)的快速检测。 展开更多
关键词 双网络离子印迹水凝胶 As(Ⅴ) 吸附 检测
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Evaluation Strategies for Coupled GC-IMS Measurement including the Systematic Use of Parametrized ANN
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作者 Artur Scheinemann Stefanie Sielemann +1 位作者 Jorg Walter Theodor Doll 《Open Journal of Applied Sciences》 2012年第4期257-266,共10页
Data evaluation strategies for the novel coupled MCC-IMS sensory system are developed. Mayor attention to the plausibility of applied procedures and the feasibility of automation was paid. Three stages of extraction l... Data evaluation strategies for the novel coupled MCC-IMS sensory system are developed. Mayor attention to the plausibility of applied procedures and the feasibility of automation was paid. Three stages of extraction levels with increasing data reduction are presented for several fields of application. According to suitable extraction levels, real data were tested on various structures of artificial neural networks (ANN) with the result, that the computational levels must still be chosen by expertise, but subsequent processing and training can be fully automated. For the training of larger net- works a method of automated generation of secondary training data is presented which exceeds the quality of previous noise models by far. It is concluded that the combination of MCC-IMS as measuring instrument and ANNs as evalua- tion technique have high potential for industrial use in process monitoring. 展开更多
关键词 Gas CHROMATOGRAPHY ion Mobility SPECTROMETRY GC-IMS MCC-IMS Artificial Neural network MEASUREMENT EVALUATion
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