Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studi...Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studies. It can disperse easily in epoxy resin to form exfoliated nanocomposites. The nanoscale silicate platelets dispersed in water can be metallized by silver deposition.展开更多
Rivanol(RVN) binds to the double helical DNA with a high affinity. Strong hypochromism and appreciable red shifts in the absorption spectra can be observed when RVN binds to CT DNA. The results of absorption spectra, ...Rivanol(RVN) binds to the double helical DNA with a high affinity. Strong hypochromism and appreciable red shifts in the absorption spectra can be observed when RVN binds to CT DNA. The results of absorption spectra, KI quenching studies, fluorescence polarization measurements, competitive binding studies. and thermal denaturation experiments suggested that the interaction between RVN and DNA be intercalative.展开更多
Population migration data derived from location-based services has often been used to delineate population flows between cities or construct intercity relationship networks to reveal and explore the complex interactio...Population migration data derived from location-based services has often been used to delineate population flows between cities or construct intercity relationship networks to reveal and explore the complex interaction patterns underlying human activities.Nevertheless,the inherent heterogeneity in multimodal migration big data has been ignored.This study conducts an in-depth comparison and quantitative analysis through a comprehensive lens of spatial association.Initially,the intercity interactive networks in China were constructed,utilizing migration data from Baidu and AutoNavi collected during the same time period.Subsequently,the characteristics and spatial structure similarities of the two types of intercity interactive networks were quantitatively assessed and analyzed from overall(network)and local(node)perspectives.Furthermore,the precision of these networks at the local scale is corroborated by constructing an intercity network from mobile phone(MP)data.Results indicate that the intercity interactive networks in China,as delineated by Baidu and AutoNavi migration flows,exhibit a high degree of structure equivalence.The correlation coefficient between these two networks is 0.874.Both networks exhibit a pronounced spatial polarization trend and hierarchical structure.This is evident in their distinct core and peripheral structures,as well as in the varying importance and influence of different nodes within the networks.Nevertheless,there are notable differences worthy of attention.Baidu intercity interactive network exhibits pronounced cross-regional effects,and its high-level interactions are characterized by a“rich-club”phenomenon.The AutoNavi intercity interactive network presents a more significant distance attenuation effect,and the high-level interactions display a gradient distribution pattern.Notably,there exists a substantial correlation between the AutoNavi and MP networks at the local scale,evidenced by a high correlation coefficient of 0.954.Furthermore,the“spatial dislocations”phenomenon was observed within the spatial structures at different levels,extracted from the Baidu and AutoNavi intercity networks.However,the measured results of network spatial structure similarity from three dimensions,namely,node location,node size,and local structure,indicate a relatively high similarity and consistency between the two networks.展开更多
With the development of urban infrastructure,it is inevitable that shield tunnels will undercross intercity railways.However,the safe operation of intercity railways requires strict subgrade deformation.On the basis o...With the development of urban infrastructure,it is inevitable that shield tunnels will undercross intercity railways.However,the safe operation of intercity railways requires strict subgrade deformation.On the basis of the engineering background of the Lianghu Tunnel in Wuhan,the three-dimensional centrifuge test and numerical back analysis were used to study the development of subgrade surface settlement during shield tunneling.A three-dimensional numerical model with the same size as the prototype was subsequently established to further study the settlement development and torsion behavior of the subgrade during tunnel excavation.The results show that the maximum settlement point of the transverse settlement trough gradually moves to the tunnel axis during tunnel excavation and that the entire subgrade experiences torsional deformation.Moreover,the effect of the intersection angle between the axes of the tunnel and the subgrade on the surface settlement of the subgrade was further studied.The results show that the intersection angle has no effect on the maximum settlement,but the width of the settlement trough increases gradually with increasing angle.Finally,on the basis of the soil arching effect caused by tunnel excavation,the subgrade settlement during tunnel excavation is reduced by reinforcing the soil in different zones of soil arching.The results show that the settlement of the subgrade caused by the shield tunnel can be effectively controlled by adding reinforcement directly to the top of the tunnel,and the maximum settlement of the subgrade surface is reduced from 24.41 mm to 9.47 mm,a reduction of approximately 61.2%.展开更多
Intercity mobility lays the foundation for capital flow,information flow,and knowledge flow,etc.,and is important for promoting regional integration.Although many scholars have studied intercity mobility in extensive ...Intercity mobility lays the foundation for capital flow,information flow,and knowledge flow,etc.,and is important for promoting regional integration.Although many scholars have studied intercity mobility in extensive well-developed urban agglomerations,few studies have examined the characteristics of intercity mobility at the county level and its impact on regionalization in western China.This study takes the Guanzhong Plain urban agglomeration(GPUA)as a case to study the geographical law of intercity mobility and then explore its impact on regionalization.The results obtained show that intercity mobility network exhibits a hub and spoke patterns focusing on major municipal districts at the county level.We also found a corridor effect that counties with higher travel volumes are mostly located along the trunk high speed railway(HSR)lines.Unlike previous studies,the distribution of intercity mobility is more concentrated than that of population and exhibits a super-linear behavior rule.There are the differences in gravity law for overall trips,weekday trips,weekend trips,and holiday trips.With the decrease of travel duration,the effect of attraction of destination is weakening,but the influence of distance decay is increasing.Finally,the spatial organization is still administrative-centric and is dominated by intraprefecture and intra-provincial development.Moreover,the coupled degree between network-based regionalization and attribute-based regionalization shows a decreasing trend from administrative via cultural to physical factors.These findings enrich the research on the intercity mobility and the regionalization in inland developing urban agglomerations.展开更多
The simulation of intercity population mobility helps to deepen the understanding of intercity population mobility and its underlying laws,which has great importance for epidemic prevention and control,social manageme...The simulation of intercity population mobility helps to deepen the understanding of intercity population mobility and its underlying laws,which has great importance for epidemic prevention and control,social management,and even urban planning.There are many factors that affect intercity population mobility,such as socioeconomic attributes,geographical distance,and industrial structure.The complexity of the coupling among these factors makes it difficult to simulate intercity population mobility.To address this issue,we propose a novel method named the quantum harmonic oscillator model for simulation of intercity population mobility(QHO-IPM).QHO-IPM describes the intercity population mobility as being affected by coupled driving factors that work as a multioscillator-coupled quantum harmonic oscillator system,which is further transformed by the oscillation process of an oscillator,namely,the breaking point of intercity population mobility.The intercity population mobility among seven cities in the Beijing-Tianjin-Hebei region and its surrounding region is taken as an example for verifying the QHO-IPM.The experimental results show that(1)compared with the reference methods(the autoregressive integrated moving average(ARIMA)and long and short-term memory(LSTM)models),the QHO-IPM achieves better simulation performance regarding intercity population mobility in terms of both overall trend and mutation.(2)The simulation error in the QHO-IPM for different-level intercity population mobility is small and stable,which illustrates the weak sensitivity of the QHO-IPM to intercity population mobility under different structures.(3)The discussion regarding the influence degree of different driving factors reveals the significant“one dominant and multiple auxiliary”factor pattern of driving factors on intercity population mobility in the study area.The proposed method has the potential to provide valuable support for understanding intercity population mobility laws and related decision-making on intercity population mobility control.展开更多
The interaction of ternary complexes [RE(phen)(cin)_3(H_2O)](RE= Nd (III),Ce(III),Eu(III))with calf thymus DNA was investigated by electronic absorption spectroscopy, ethidium bromide(EB)-DNA quenching fluorescent spe...The interaction of ternary complexes [RE(phen)(cin)_3(H_2O)](RE= Nd (III),Ce(III),Eu(III))with calf thymus DNA was investigated by electronic absorption spectroscopy, ethidium bromide(EB)-DNA quenching fluorescent spectra and resonance light scattering. All experimental results indicate that the three complexes bind to DNA by the electrostatic mode and the intercalative mode. It is predicted that these complexes show high anticancer activity or other biologic activity.展开更多
Na +-montmorillonite(Na +-MMT) was converted to organic montmorillonite(OMMT) using modifier which was synthesized at authors’ laboratory. PA6/OMMT nanocomposite was prepared via in situ intercalative polymerization....Na +-montmorillonite(Na +-MMT) was converted to organic montmorillonite(OMMT) using modifier which was synthesized at authors’ laboratory. PA6/OMMT nanocomposite was prepared via in situ intercalative polymerization. The limiting oxygen index (LOI), UL 94V flame retardancy and thermal stability of PA6/OMMT using thermal gravity analysis (TGA) were measured. The Fourier transform infrared (FTIR) technique was used to analyze the pyrolytic residuum and the cone calorimeter (CONE) was applied to determine a number of combustion parameters which were closely related to fire safety, including heat release rate, mass loss rate, effective combustion heat, total heat release, specific extinction area and the time of ignition. In addition, the elemental composition of the surface pyrolytic residuum and the corresponding X-ray photoelectron spectroscopy (XPS) data were obtained, and the morphology of the residuum from CONE measurement was examined by scanning electron microscope (SEM).展开更多
A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffrac...A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffraction.The complex crystallizes in the monoclinic space group P2 1 /c with a=11.218（3）,b=9.355（3）,c=13.449（4）,β=108.722（4）°,V=1336.8（6）3,Z=2,Dc=2.008 g/cm 3,μ（MoKα）=7.024 mm-1,F（000）=806,S=0.999,the final R=0.0342 and wR=0.0641for2611observed reflections （I〉2σ（I））.The central copper（Ⅱ） is four-coordinate and bonds to two nitrogen and two oxygen atoms from two Schiff base ligands.The complex is linked into a two-dimensional supramolecular structure by weak intermolecular interactions.In addition,DNA-binding properties of the metal complex were investigated using spectrometric titrations and viscosity measurements.The results show that the complex binds with calf-thymus DNA（CT-DNA）,presumably via a partial intercalative mode.The intrinsic binding constant of the Cu（Ⅱ） complex with DNA is 7.335×10 3 M-1.展开更多
Size distribution characteristics of intercity bus hubs in China from 1997 to 2（104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus h...Size distribution characteristics of intercity bus hubs in China from 1997 to 2（104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus hub sizes were exactly calculated by a novel model. Fractal dimensions of the 200 biggest intercity bus hubs from 2000 to 2004 were 1. 486 2 to 1. 511 8, and that is consistent with fractal dimensions of Chinese urban system sizes. It showed that the size distribution of intercity bus hubs had fractal structure. Fractal dimensions from 1997 to 2004 indicated that intercity bus hub size distribution grew from bi-fractal to single fractal. It is concluded that the intercity bus hub system is in evolutionary progress, and the Central Government should support large intercity bus hubs more to optimize system structure.展开更多
A new monometallic complex [Co(phen)_2tpphz]^(3+) (where tpphz is tetrapyrido [3,2-a:2′,3′-c:3″,2″-h:2′″,3′″-j] phenazine) was synthesized by the reaction of 5, 6-diamino-1,10-phenanthroline with [Co(phen)_2(p...A new monometallic complex [Co(phen)_2tpphz]^(3+) (where tpphz is tetrapyrido [3,2-a:2′,3′-c:3″,2″-h:2′″,3′″-j] phenazine) was synthesized by the reaction of 5, 6-diamino-1,10-phenanthroline with [Co(phen)_2(phendione)]^(3+). It was characterized by elemental analysis, molar conductivity, IR, ~1H NMR, ultraviolet and fluorescence spectroscopy. The interaction of the complex with DNA was also investigated. The complex shows the absorption hypochromicity, fluorescence enhancement, the specific viscosity increased when bound to calf thymus DNA. The cyclic voltammetry (CV) measurement showed a change in peak current with the addition of DNA. All the results provide the support for the intercalative binding mode of the mononuclear complex.展开更多
City networks have been a critical topic in the fields of urban geography and regional economics. Numerous studies have explored city networks, focusing mainly on infrastructure and industrial networks. Unlike traditi...City networks have been a critical topic in the fields of urban geography and regional economics. Numerous studies have explored city networks, focusing mainly on infrastructure and industrial networks. Unlike traditional urban network of which the major measuring indexes are population sizes and entity industries, online commodity service networks could reflect well the influencing of emerging economies, especially the Internet economy, on city networks. This study analyzes and reveals structural features of China's city networks through online commodity services, providing the internet economic approach on city networks. Results indicate that the core cities of online commodity service networks are mainly concentrated in eastern coastal areas. In addition, spatial polarization and layer structure of network connections are obvious, descending from the centers in eastern China to peripheral cities in central and western China. Online commodity services of different cities show apparent differences and uncertainties in terms of specialization rates of international connection, which presents a tendency toward diversification. Online commodity service networks are not only associated with goods production, supply, and consumption in physical space but also reflect virtual information, capital, and technology flows, thus providing a new empirical approach for understanding city networks in information and internet economic age.展开更多
Studies investigating innovation networks shaped by large innovative enterprises(LI-ENTs),which play a very important role in intercity diffusion of technology and knowledge,are rather thin on the ground.Using locatio...Studies investigating innovation networks shaped by large innovative enterprises(LI-ENTs),which play a very important role in intercity diffusion of technology and knowledge,are rather thin on the ground.Using location information of LI-ENTs in China,we performed a headquarter-branch analysis to generate intercity innovation linkages and analyzed the patterns and dynamics of the generated network of knowledge diffusion.Although the network covers 353 cities across China,its spatial distribution is extremely uneven,with a few cities and city-dyads dominating the structure of the network.Furthermore,intercity linkages of innovation within and of urban agglomerations,as well as their central cities,stand out.With regard to network dynamics,the economic development level,innovation ability,and administrative level of cities,as well as the geographical,institutional,and technological proximity between cities are all found to have a positive impact on intercity linkages of innovations,whilst the impact of FDI on the national distribution of Chinese innovative enterprises is negative.Most importantly,the status of cities within the urban agglomeration exerts a significant positive effect in relation to the innovative enterprises’expansions,which reflects that the top-down forces of government and the bottom-up forces of market function together.展开更多
Low-frequency carbody swaying phenomenon often occurs to railway vehicles due to hunting instability,which seriously deteriorates the ride comfort of passengers.This paper investigates low-frequency carbody swaying th...Low-frequency carbody swaying phenomenon often occurs to railway vehicles due to hunting instability,which seriously deteriorates the ride comfort of passengers.This paper investigates low-frequency carbody swaying through experimental analysis and numerical simulation.In the tests,the carbody acceleration,the wheel-rail profiles,and the dynamic characteristics of dampers were measured to understand the characteristics of the abnormal carbody vibration and to find out its primary contributor.Linear and nonlinear numerical simulations on the mechanism and optimization measures were carried out to solve this carbody swaying issue.The results showed that the carbody swaying is the manifest of carbody hunting instability.The low equivalent conicity and the decrease of dynamic damping of the yaw damper are probably the cause of this phenomenon.The optimization measures to increase the equivalent conicity and dynamic damping of the yaw damper were put forward and verified by on-track tests.The results of this study could enrich the knowledge of carbody hunting and provide a reference for solving abnormal carbody vibrations.展开更多
Beijing-Tianjin intercity railway is the first newly-built passenger dedicated line with operating speed of 350 km/h in our country. During design,new ideas of bridge construction were carried out to ensure the requir...Beijing-Tianjin intercity railway is the first newly-built passenger dedicated line with operating speed of 350 km/h in our country. During design,new ideas of bridge construction were carried out to ensure the requirements of safety,comfort and stability of the train under high-speed condition. At the same time,concepts of environmental adaptability,service to transportation and comprehensive benefits were observed. On the whole line,long-bridge schemes were adopted and the most advanced technologies of unballasted track were utilized on bridges,the length of which accounts for 87.7 % of the total line. The success of design and construction of the bridges on this rail has accumulated valuable experience for high-speed railway construction on a large scale in the future,and made it a marking,demonstrating,and model project to follow.展开更多
To analyze wheel wear discrepancy between motor car and trailer of an intercity train,a novel wheel wear rates calculation model was proposed,which was composed of the intercity train dynamics model,wheel-rail three-d...To analyze wheel wear discrepancy between motor car and trailer of an intercity train,a novel wheel wear rates calculation model was proposed,which was composed of the intercity train dynamics model,wheel-rail three-dimensional rolling contact FEM model and the wear model.The simulated results were contrasted with measured results in field test.The simulated results showed the motor car wheels had larger rotation rate and longitudinal creepage than the trailer wheels.Meanwhile,the motor car wheels encountered larger vertical forces and longitudinal forces from bogie because of the heavier car body and the impact of traction torque.The traction torque acting on motor car wheel could increase the slip rates in the rear part of wheel contact patch and weaken the spinning phenomenon of relative slip.Larger contact pressure and slip rates caused the higher wear rates of motor car wheel than those of trailer wheel.The overall trends of wheel wear depth in simulated and tested results were similar.And they both showed the motor car wheel encountered the more serious wear than the trailer wheel.These models can be used to study the effect of the traction characteristics curves on the wear of wheel.展开更多
The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adop...The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adoption of the operation frequency data of HSR from 12306 website,and based on the HSR connection strength model and social network analysis model,as well as according to the HSR connection strength,HSR network density,centrality,agglomeration subgroup,and other indicators,we analyzed the characteristics of HSR network structure in Northeast China.Results show that the number of HSR cities in Northeast China is small,cities in HSR network generally exhibit weak connectivity,and the existence of HSR network marginalizes cities such as Ulanhot,Baicheng,and Songyuan,which significantly reduce the overall network connectivity of Northeast China.The overall centrality of HSR network in Northeast China is characterized by“one axis,four edges”;specifically,the one axis is located in Harbin-Dalian transportation line and the four edges are located on both sides of the main axis of Harbin-Dalian transportation line.Eight agglomeration subgroups(four double city subgroups and four multi city subgroups)have formed in Northeast China.The core status of Shenyang in HSR network is improved significantly,and“one axis and two wings”HSR network in Liaoning Province is improved significantly.With the gradual expansion of Chaoyang-Fuxin,Dandong-Benxi,and Jilin-Yanji branch networks,the“point axis”HSR network mode in Northeast China has gradually developed and matured.In the future,it is recommended to rely on eight agglomerating subgroups to encrypt HSR network structure,create secondary node central cities,and gradually build a new pattern of opening up in Northeast China.展开更多
Estimating intercity vehicle emissions precisely would benefit collaborative control in multiple cities.Considering the variability of emissions caused by vehicles,roads,and traffic,the 24-hour change characteristics ...Estimating intercity vehicle emissions precisely would benefit collaborative control in multiple cities.Considering the variability of emissions caused by vehicles,roads,and traffic,the 24-hour change characteristics of air pollutants(CO,HC,NO_(X),PM_(2.5))on the intercity road network of Guangdong Province by vehicle categories and road links were revealed based on vehicle identity detection data in real-life traffic for each hour in July 2018.The results showed that the spatial diversity of emissions caused by the unbalanced economywas obvious.The vehicle emissions in the Pearl River Delta region(PRD)with a higher economic level were approximately 1–2 times those in the non-Pearl RiverDelta region(non-PRD).Provincial roads with high loads became potential sources of high emissions.Therefore,emission control policies must emphasize the PRD and key roads by travel guidance to achieve greater reduction.Gasoline passenger cars with a large proportion of traffic dominated morning and evening peaks in the 24-hour period and were the dominant contributors to CO and HC emissions,contributing more than 50%in the daytime(7:00–23:00)and higher than 26%at night(0:00–6:00).Diesel trucks made up 10%of traffic,but were the dominant player at night,contributed 50%–90%to NO_(X) and PM_(2.5) emissions,with amarked 24-hour change rule of more than 80%at night(23:00–5:00)and less than 60%during daytime.Therefore,targeted control measures by time-section should be set up on collaborative control.These findings provide time-varying decision support for variable vehicle emission control on a large scale.展开更多
Specific requirements and methods of settlement monitoring which were used in bridge of unballasted track passenger dedicated line or high-speed railway are introduced systematically,and mathematical model and determi...Specific requirements and methods of settlement monitoring which were used in bridge of unballasted track passenger dedicated line or high-speed railway are introduced systematically,and mathematical model and determinant conditions of settlement were proposed simultaneously,taking Beijing—Tianjin intercity railway as an example.展开更多
文摘Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studies. It can disperse easily in epoxy resin to form exfoliated nanocomposites. The nanoscale silicate platelets dispersed in water can be metallized by silver deposition.
文摘Rivanol(RVN) binds to the double helical DNA with a high affinity. Strong hypochromism and appreciable red shifts in the absorption spectra can be observed when RVN binds to CT DNA. The results of absorption spectra, KI quenching studies, fluorescence polarization measurements, competitive binding studies. and thermal denaturation experiments suggested that the interaction between RVN and DNA be intercalative.
基金National Natural Science Foundation of China,No.42361040。
文摘Population migration data derived from location-based services has often been used to delineate population flows between cities or construct intercity relationship networks to reveal and explore the complex interaction patterns underlying human activities.Nevertheless,the inherent heterogeneity in multimodal migration big data has been ignored.This study conducts an in-depth comparison and quantitative analysis through a comprehensive lens of spatial association.Initially,the intercity interactive networks in China were constructed,utilizing migration data from Baidu and AutoNavi collected during the same time period.Subsequently,the characteristics and spatial structure similarities of the two types of intercity interactive networks were quantitatively assessed and analyzed from overall(network)and local(node)perspectives.Furthermore,the precision of these networks at the local scale is corroborated by constructing an intercity network from mobile phone(MP)data.Results indicate that the intercity interactive networks in China,as delineated by Baidu and AutoNavi migration flows,exhibit a high degree of structure equivalence.The correlation coefficient between these two networks is 0.874.Both networks exhibit a pronounced spatial polarization trend and hierarchical structure.This is evident in their distinct core and peripheral structures,as well as in the varying importance and influence of different nodes within the networks.Nevertheless,there are notable differences worthy of attention.Baidu intercity interactive network exhibits pronounced cross-regional effects,and its high-level interactions are characterized by a“rich-club”phenomenon.The AutoNavi intercity interactive network presents a more significant distance attenuation effect,and the high-level interactions display a gradient distribution pattern.Notably,there exists a substantial correlation between the AutoNavi and MP networks at the local scale,evidenced by a high correlation coefficient of 0.954.Furthermore,the“spatial dislocations”phenomenon was observed within the spatial structures at different levels,extracted from the Baidu and AutoNavi intercity networks.However,the measured results of network spatial structure similarity from three dimensions,namely,node location,node size,and local structure,indicate a relatively high similarity and consistency between the two networks.
基金funding support from the National Natural Science Foundation of China(Grant Nos.52208355and 52378308)Shenzhen University's 2035 Program for Excellent Research(Grant No.00000219).
文摘With the development of urban infrastructure,it is inevitable that shield tunnels will undercross intercity railways.However,the safe operation of intercity railways requires strict subgrade deformation.On the basis of the engineering background of the Lianghu Tunnel in Wuhan,the three-dimensional centrifuge test and numerical back analysis were used to study the development of subgrade surface settlement during shield tunneling.A three-dimensional numerical model with the same size as the prototype was subsequently established to further study the settlement development and torsion behavior of the subgrade during tunnel excavation.The results show that the maximum settlement point of the transverse settlement trough gradually moves to the tunnel axis during tunnel excavation and that the entire subgrade experiences torsional deformation.Moreover,the effect of the intersection angle between the axes of the tunnel and the subgrade on the surface settlement of the subgrade was further studied.The results show that the intersection angle has no effect on the maximum settlement,but the width of the settlement trough increases gradually with increasing angle.Finally,on the basis of the soil arching effect caused by tunnel excavation,the subgrade settlement during tunnel excavation is reduced by reinforcing the soil in different zones of soil arching.The results show that the settlement of the subgrade caused by the shield tunnel can be effectively controlled by adding reinforcement directly to the top of the tunnel,and the maximum settlement of the subgrade surface is reduced from 24.41 mm to 9.47 mm,a reduction of approximately 61.2%.
基金Under the auspices of National Natural Science Foundation of China(No.42371189)Central University Basic Research Fund of China(No.24ZYYB017)。
文摘Intercity mobility lays the foundation for capital flow,information flow,and knowledge flow,etc.,and is important for promoting regional integration.Although many scholars have studied intercity mobility in extensive well-developed urban agglomerations,few studies have examined the characteristics of intercity mobility at the county level and its impact on regionalization in western China.This study takes the Guanzhong Plain urban agglomeration(GPUA)as a case to study the geographical law of intercity mobility and then explore its impact on regionalization.The results obtained show that intercity mobility network exhibits a hub and spoke patterns focusing on major municipal districts at the county level.We also found a corridor effect that counties with higher travel volumes are mostly located along the trunk high speed railway(HSR)lines.Unlike previous studies,the distribution of intercity mobility is more concentrated than that of population and exhibits a super-linear behavior rule.There are the differences in gravity law for overall trips,weekday trips,weekend trips,and holiday trips.With the decrease of travel duration,the effect of attraction of destination is weakening,but the influence of distance decay is increasing.Finally,the spatial organization is still administrative-centric and is dominated by intraprefecture and intra-provincial development.Moreover,the coupled degree between network-based regionalization and attribute-based regionalization shows a decreasing trend from administrative via cultural to physical factors.These findings enrich the research on the intercity mobility and the regionalization in inland developing urban agglomerations.
基金National Natural Science Foundation of China,No.42230406,No.42130103,No.41971404,No.42201504。
文摘The simulation of intercity population mobility helps to deepen the understanding of intercity population mobility and its underlying laws,which has great importance for epidemic prevention and control,social management,and even urban planning.There are many factors that affect intercity population mobility,such as socioeconomic attributes,geographical distance,and industrial structure.The complexity of the coupling among these factors makes it difficult to simulate intercity population mobility.To address this issue,we propose a novel method named the quantum harmonic oscillator model for simulation of intercity population mobility(QHO-IPM).QHO-IPM describes the intercity population mobility as being affected by coupled driving factors that work as a multioscillator-coupled quantum harmonic oscillator system,which is further transformed by the oscillation process of an oscillator,namely,the breaking point of intercity population mobility.The intercity population mobility among seven cities in the Beijing-Tianjin-Hebei region and its surrounding region is taken as an example for verifying the QHO-IPM.The experimental results show that(1)compared with the reference methods(the autoregressive integrated moving average(ARIMA)and long and short-term memory(LSTM)models),the QHO-IPM achieves better simulation performance regarding intercity population mobility in terms of both overall trend and mutation.(2)The simulation error in the QHO-IPM for different-level intercity population mobility is small and stable,which illustrates the weak sensitivity of the QHO-IPM to intercity population mobility under different structures.(3)The discussion regarding the influence degree of different driving factors reveals the significant“one dominant and multiple auxiliary”factor pattern of driving factors on intercity population mobility in the study area.The proposed method has the potential to provide valuable support for understanding intercity population mobility laws and related decision-making on intercity population mobility control.
文摘The interaction of ternary complexes [RE(phen)(cin)_3(H_2O)](RE= Nd (III),Ce(III),Eu(III))with calf thymus DNA was investigated by electronic absorption spectroscopy, ethidium bromide(EB)-DNA quenching fluorescent spectra and resonance light scattering. All experimental results indicate that the three complexes bind to DNA by the electrostatic mode and the intercalative mode. It is predicted that these complexes show high anticancer activity or other biologic activity.
文摘Na +-montmorillonite(Na +-MMT) was converted to organic montmorillonite(OMMT) using modifier which was synthesized at authors’ laboratory. PA6/OMMT nanocomposite was prepared via in situ intercalative polymerization. The limiting oxygen index (LOI), UL 94V flame retardancy and thermal stability of PA6/OMMT using thermal gravity analysis (TGA) were measured. The Fourier transform infrared (FTIR) technique was used to analyze the pyrolytic residuum and the cone calorimeter (CONE) was applied to determine a number of combustion parameters which were closely related to fire safety, including heat release rate, mass loss rate, effective combustion heat, total heat release, specific extinction area and the time of ignition. In addition, the elemental composition of the surface pyrolytic residuum and the corresponding X-ray photoelectron spectroscopy (XPS) data were obtained, and the morphology of the residuum from CONE measurement was examined by scanning electron microscope (SEM).
文摘A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffraction.The complex crystallizes in the monoclinic space group P2 1 /c with a=11.218（3）,b=9.355（3）,c=13.449（4）,β=108.722（4）°,V=1336.8（6）3,Z=2,Dc=2.008 g/cm 3,μ（MoKα）=7.024 mm-1,F（000）=806,S=0.999,the final R=0.0342 and wR=0.0641for2611observed reflections （I〉2σ（I））.The central copper（Ⅱ） is four-coordinate and bonds to two nitrogen and two oxygen atoms from two Schiff base ligands.The complex is linked into a two-dimensional supramolecular structure by weak intermolecular interactions.In addition,DNA-binding properties of the metal complex were investigated using spectrometric titrations and viscosity measurements.The results show that the complex binds with calf-thymus DNA（CT-DNA）,presumably via a partial intercalative mode.The intrinsic binding constant of the Cu（Ⅱ） complex with DNA is 7.335×10 3 M-1.
基金The Ph.D.Programs Foundation of Ministry of Edu-cation of China(No20050710006)
文摘Size distribution characteristics of intercity bus hubs in China from 1997 to 2（104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus hub sizes were exactly calculated by a novel model. Fractal dimensions of the 200 biggest intercity bus hubs from 2000 to 2004 were 1. 486 2 to 1. 511 8, and that is consistent with fractal dimensions of Chinese urban system sizes. It showed that the size distribution of intercity bus hubs had fractal structure. Fractal dimensions from 1997 to 2004 indicated that intercity bus hub size distribution grew from bi-fractal to single fractal. It is concluded that the intercity bus hub system is in evolutionary progress, and the Central Government should support large intercity bus hubs more to optimize system structure.
基金Supported by the National Natural Foundation of China and Shanxi Province.
文摘A new monometallic complex [Co(phen)_2tpphz]^(3+) (where tpphz is tetrapyrido [3,2-a:2′,3′-c:3″,2″-h:2′″,3′″-j] phenazine) was synthesized by the reaction of 5, 6-diamino-1,10-phenanthroline with [Co(phen)_2(phendione)]^(3+). It was characterized by elemental analysis, molar conductivity, IR, ~1H NMR, ultraviolet and fluorescence spectroscopy. The interaction of the complex with DNA was also investigated. The complex shows the absorption hypochromicity, fluorescence enhancement, the specific viscosity increased when bound to calf thymus DNA. The cyclic voltammetry (CV) measurement showed a change in peak current with the addition of DNA. All the results provide the support for the intercalative binding mode of the mononuclear complex.
基金Under the auspices of National Natural Science Foundation of China(No.41571146,41701178)China Postdoctoral Science Foundation(No.2016M600393)Natural Science Foundation of Jiangsu Province(No.BK20170639)
文摘City networks have been a critical topic in the fields of urban geography and regional economics. Numerous studies have explored city networks, focusing mainly on infrastructure and industrial networks. Unlike traditional urban network of which the major measuring indexes are population sizes and entity industries, online commodity service networks could reflect well the influencing of emerging economies, especially the Internet economy, on city networks. This study analyzes and reveals structural features of China's city networks through online commodity services, providing the internet economic approach on city networks. Results indicate that the core cities of online commodity service networks are mainly concentrated in eastern coastal areas. In addition, spatial polarization and layer structure of network connections are obvious, descending from the centers in eastern China to peripheral cities in central and western China. Online commodity services of different cities show apparent differences and uncertainties in terms of specialization rates of international connection, which presents a tendency toward diversification. Online commodity service networks are not only associated with goods production, supply, and consumption in physical space but also reflect virtual information, capital, and technology flows, thus providing a new empirical approach for understanding city networks in information and internet economic age.
基金The Third Xinjiang Scientific Expedition Program,No.2021xjkk0905National Natural Science Foundation of China,No.41971209,No.41571151,No.41901186。
文摘Studies investigating innovation networks shaped by large innovative enterprises(LI-ENTs),which play a very important role in intercity diffusion of technology and knowledge,are rather thin on the ground.Using location information of LI-ENTs in China,we performed a headquarter-branch analysis to generate intercity innovation linkages and analyzed the patterns and dynamics of the generated network of knowledge diffusion.Although the network covers 353 cities across China,its spatial distribution is extremely uneven,with a few cities and city-dyads dominating the structure of the network.Furthermore,intercity linkages of innovation within and of urban agglomerations,as well as their central cities,stand out.With regard to network dynamics,the economic development level,innovation ability,and administrative level of cities,as well as the geographical,institutional,and technological proximity between cities are all found to have a positive impact on intercity linkages of innovations,whilst the impact of FDI on the national distribution of Chinese innovative enterprises is negative.Most importantly,the status of cities within the urban agglomeration exerts a significant positive effect in relation to the innovative enterprises’expansions,which reflects that the top-down forces of government and the bottom-up forces of market function together.
基金supported by the National Key R&D Program of China under grant number 2018YFB1201701.
文摘Low-frequency carbody swaying phenomenon often occurs to railway vehicles due to hunting instability,which seriously deteriorates the ride comfort of passengers.This paper investigates low-frequency carbody swaying through experimental analysis and numerical simulation.In the tests,the carbody acceleration,the wheel-rail profiles,and the dynamic characteristics of dampers were measured to understand the characteristics of the abnormal carbody vibration and to find out its primary contributor.Linear and nonlinear numerical simulations on the mechanism and optimization measures were carried out to solve this carbody swaying issue.The results showed that the carbody swaying is the manifest of carbody hunting instability.The low equivalent conicity and the decrease of dynamic damping of the yaw damper are probably the cause of this phenomenon.The optimization measures to increase the equivalent conicity and dynamic damping of the yaw damper were put forward and verified by on-track tests.The results of this study could enrich the knowledge of carbody hunting and provide a reference for solving abnormal carbody vibrations.
文摘Beijing-Tianjin intercity railway is the first newly-built passenger dedicated line with operating speed of 350 km/h in our country. During design,new ideas of bridge construction were carried out to ensure the requirements of safety,comfort and stability of the train under high-speed condition. At the same time,concepts of environmental adaptability,service to transportation and comprehensive benefits were observed. On the whole line,long-bridge schemes were adopted and the most advanced technologies of unballasted track were utilized on bridges,the length of which accounts for 87.7 % of the total line. The success of design and construction of the bridges on this rail has accumulated valuable experience for high-speed railway construction on a large scale in the future,and made it a marking,demonstrating,and model project to follow.
基金Project(51805374)supported by the National Natural Science Foundation of ChinaProject(208YFB1201603-08)supported by the Key R&D Program of Ministry of Science and Technology,China。
文摘To analyze wheel wear discrepancy between motor car and trailer of an intercity train,a novel wheel wear rates calculation model was proposed,which was composed of the intercity train dynamics model,wheel-rail three-dimensional rolling contact FEM model and the wear model.The simulated results were contrasted with measured results in field test.The simulated results showed the motor car wheels had larger rotation rate and longitudinal creepage than the trailer wheels.Meanwhile,the motor car wheels encountered larger vertical forces and longitudinal forces from bogie because of the heavier car body and the impact of traction torque.The traction torque acting on motor car wheel could increase the slip rates in the rear part of wheel contact patch and weaken the spinning phenomenon of relative slip.Larger contact pressure and slip rates caused the higher wear rates of motor car wheel than those of trailer wheel.The overall trends of wheel wear depth in simulated and tested results were similar.And they both showed the motor car wheel encountered the more serious wear than the trailer wheel.These models can be used to study the effect of the traction characteristics curves on the wear of wheel.
基金the National Natural Science Foundation of China(41871151).
文摘The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adoption of the operation frequency data of HSR from 12306 website,and based on the HSR connection strength model and social network analysis model,as well as according to the HSR connection strength,HSR network density,centrality,agglomeration subgroup,and other indicators,we analyzed the characteristics of HSR network structure in Northeast China.Results show that the number of HSR cities in Northeast China is small,cities in HSR network generally exhibit weak connectivity,and the existence of HSR network marginalizes cities such as Ulanhot,Baicheng,and Songyuan,which significantly reduce the overall network connectivity of Northeast China.The overall centrality of HSR network in Northeast China is characterized by“one axis,four edges”;specifically,the one axis is located in Harbin-Dalian transportation line and the four edges are located on both sides of the main axis of Harbin-Dalian transportation line.Eight agglomeration subgroups(four double city subgroups and four multi city subgroups)have formed in Northeast China.The core status of Shenyang in HSR network is improved significantly,and“one axis and two wings”HSR network in Liaoning Province is improved significantly.With the gradual expansion of Chaoyang-Fuxin,Dandong-Benxi,and Jilin-Yanji branch networks,the“point axis”HSR network mode in Northeast China has gradually developed and matured.In the future,it is recommended to rely on eight agglomerating subgroups to encrypt HSR network structure,create secondary node central cities,and gradually build a new pattern of opening up in Northeast China.
基金supported by the Natural Science Foundation of China(No.U1811463,41975165)the National Key Research Program of China(No.2018YFB1601100)+1 种基金the Science Foundation Project of Guangdong(No.2019A1515010812)the Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications(No.NY221125).
文摘Estimating intercity vehicle emissions precisely would benefit collaborative control in multiple cities.Considering the variability of emissions caused by vehicles,roads,and traffic,the 24-hour change characteristics of air pollutants(CO,HC,NO_(X),PM_(2.5))on the intercity road network of Guangdong Province by vehicle categories and road links were revealed based on vehicle identity detection data in real-life traffic for each hour in July 2018.The results showed that the spatial diversity of emissions caused by the unbalanced economywas obvious.The vehicle emissions in the Pearl River Delta region(PRD)with a higher economic level were approximately 1–2 times those in the non-Pearl RiverDelta region(non-PRD).Provincial roads with high loads became potential sources of high emissions.Therefore,emission control policies must emphasize the PRD and key roads by travel guidance to achieve greater reduction.Gasoline passenger cars with a large proportion of traffic dominated morning and evening peaks in the 24-hour period and were the dominant contributors to CO and HC emissions,contributing more than 50%in the daytime(7:00–23:00)and higher than 26%at night(0:00–6:00).Diesel trucks made up 10%of traffic,but were the dominant player at night,contributed 50%–90%to NO_(X) and PM_(2.5) emissions,with amarked 24-hour change rule of more than 80%at night(23:00–5:00)and less than 60%during daytime.Therefore,targeted control measures by time-section should be set up on collaborative control.These findings provide time-varying decision support for variable vehicle emission control on a large scale.
文摘Specific requirements and methods of settlement monitoring which were used in bridge of unballasted track passenger dedicated line or high-speed railway are introduced systematically,and mathematical model and determinant conditions of settlement were proposed simultaneously,taking Beijing—Tianjin intercity railway as an example.
