Hole transport material free carbon-based all-inorganic CsPbBr_(3)perovskite solar cells(PSCs)are promising for commercialization due to its low-cost,high open-circuit voltage(V_(oc))and superior stability.Due to the ...Hole transport material free carbon-based all-inorganic CsPbBr_(3)perovskite solar cells(PSCs)are promising for commercialization due to its low-cost,high open-circuit voltage(V_(oc))and superior stability.Due to the different solubility of PbBr_(2)and CsBr in conventional solvents,CsPbBr_(3)films are mainly obtained by multi-step spin-coating through the phase evolution from PbBr_(2)to CsPb_(2)Br_(5)and then to CsPbBr_(3).The scalable fabrication of high-quality CsPbBr_(3)films has been rarely studied.Herein,an inkjet-printing method is developed to prepare high-quality CsPbBr_(3)films.The formation of long-range crystalline CsPb_(2)Br_(5)phase can effectively improve phase purity and promote regular crystal stacking of CsPbBr_(3).Consequently,the inkjet-printed CsPbBr_(3)C-PSCs realized PCEs up to 9.09%,8.59%and 7.81%with active areas of 0.09,0.25,and 1 cm^(2),respectively,demonstrating the upscaling potential of our fabrication method and devices.This high performance is mainly ascribed to the high purity,strong crystal orientation,reduced surface roughness and lower trap states density of the as-printed CsPbBr_(3)films.This work provides insights into the relationship between the phase evolution mechanisms and crystal growth dynamics of cesium lead bromide halide films.展开更多
Radio frequency identification (RFID) provides great potential for different Internet of Things (IOT) applications. In the future, material choices in these IOT devices will have a huge effect on the environment and t...Radio frequency identification (RFID) provides great potential for different Internet of Things (IOT) applications. In the future, material choices in these IOT devices will have a huge effect on the environment and thus use of renewable materials is a growing trend. In this paper, passive ultra high frequency (UHF) RFID tags were inkjet-printed directly on wood, paper, and cardboard substrates, and their performance was evaluated by measuring two key properties: threshold power and theoretical read range. According to our measurements, the tags on wood showed read ranges of 7 - 8 meters, the tags on cardboard exhibited read ranges of 4 - 7 meters, and the tags printed on paper showed read ranges of 2 - 7 meters through the global UHF RFID band. According to these results, the performance of these inkjet-printed UHF RFID tags is sufficient for many IOT devices and potential applications e.g. in construction and packaging industry.展开更多
基金supported by the National Key Research and Development Program of China(Grant Nos.2021YFB3800100 and 2021YFB3800101)the National Natural Science Foundation of China(62004089,U2001217,and U19A2089)+6 种基金the Guangdong Basic and Applied Basic Research Foundation(2019A1515110439,2019B1515120083,and2022A1515011218)the Shenzhen Science and Technology Program(JCYJ20190809150811504 and KQTD2015033110182370)the HKRGC General Research Funds(16312216)the Shenzhen&Hong Kong Joint Research Program(SGLH20180622092406130)the Shenzhen Engineering Research and Development Center for Flexible Solar Cel s Project funding from Shenzhen Development and Reform Committee(2019-126)the Key Fundamental Research Project funding from the Shenzhen Science and Technology Innovation Committee(JCYJ20200109141014474)the Guangdong-Hong Kong-Macao Joint Laboratory(2019B121205001)
文摘Hole transport material free carbon-based all-inorganic CsPbBr_(3)perovskite solar cells(PSCs)are promising for commercialization due to its low-cost,high open-circuit voltage(V_(oc))and superior stability.Due to the different solubility of PbBr_(2)and CsBr in conventional solvents,CsPbBr_(3)films are mainly obtained by multi-step spin-coating through the phase evolution from PbBr_(2)to CsPb_(2)Br_(5)and then to CsPbBr_(3).The scalable fabrication of high-quality CsPbBr_(3)films has been rarely studied.Herein,an inkjet-printing method is developed to prepare high-quality CsPbBr_(3)films.The formation of long-range crystalline CsPb_(2)Br_(5)phase can effectively improve phase purity and promote regular crystal stacking of CsPbBr_(3).Consequently,the inkjet-printed CsPbBr_(3)C-PSCs realized PCEs up to 9.09%,8.59%and 7.81%with active areas of 0.09,0.25,and 1 cm^(2),respectively,demonstrating the upscaling potential of our fabrication method and devices.This high performance is mainly ascribed to the high purity,strong crystal orientation,reduced surface roughness and lower trap states density of the as-printed CsPbBr_(3)films.This work provides insights into the relationship between the phase evolution mechanisms and crystal growth dynamics of cesium lead bromide halide films.
基金funded by Finnish Funding Agency for Technology and Innovation(TEKES),Academy of Finland,Centennial Foundation of Finnish Technology Industries,and Finnish Forest Foundation.
文摘Radio frequency identification (RFID) provides great potential for different Internet of Things (IOT) applications. In the future, material choices in these IOT devices will have a huge effect on the environment and thus use of renewable materials is a growing trend. In this paper, passive ultra high frequency (UHF) RFID tags were inkjet-printed directly on wood, paper, and cardboard substrates, and their performance was evaluated by measuring two key properties: threshold power and theoretical read range. According to our measurements, the tags on wood showed read ranges of 7 - 8 meters, the tags on cardboard exhibited read ranges of 4 - 7 meters, and the tags printed on paper showed read ranges of 2 - 7 meters through the global UHF RFID band. According to these results, the performance of these inkjet-printed UHF RFID tags is sufficient for many IOT devices and potential applications e.g. in construction and packaging industry.
