Using land-use types derived from satellite remote sensing data collected by the EOS Moderate Resolution Imaging Spectroradiometer （EOS/MODIS）, the mesoscale and turbulent fluxes generated by inhomogeneities of the ...Using land-use types derived from satellite remote sensing data collected by the EOS Moderate Resolution Imaging Spectroradiometer （EOS/MODIS）, the mesoscale and turbulent fluxes generated by inhomogeneities of the underlying surface over the Jinta Oasis, northwestern China, were simulated using the Regional Atmospheric Modeling System （RAMS4.4）. The results indicate that mesoscale circulation generated by land-surface inhomogeneities over the Jinta Oasis is more important than turbulence. Vertical heat fluxes and water vapor are transported to higher levels by mesoscale circulation. Mesoscale circulation also produces mesoscale synoptic systems and prevents water vapor over the oasis from running off. Mesoscale circulation transports moisture to higher atmospheric levels as the land-surface moisture over the oasis increases, favoring the formation of clouds, which sometimes leads to rainfall. Large-scale wind speed has a significant impact on mesoscale heat fluxes. During the active phase of mesoscale circulation, the stronger large-scale winds are associated with small mesoscale fluxes; however, background wind seems to intensify the turbulent sensible heat flux and turbulent latent heat flux. If the area of oasis is enlarged properly, mesoscale circulation will be able to transport moisture to higher levels, favoring the formation of rainfall in the oasis and protecting its ＂cold island＂ effect. The impact of irrigation on rainfall is important, and increasing irrigation across the oasis is necessary to protect the oasis.展开更多
With the Riemann solver to the scalar hyperbolic conservation law with a spatially varying flux, a δ-mapping algorithm was proposed. The algorithm and its prospective application in traffic flow problems were briefed...With the Riemann solver to the scalar hyperbolic conservation law with a spatially varying flux, a δ-mapping algorithm was proposed. The algorithm and its prospective application in traffic flow problems were briefed in the paper.展开更多
Numerous articles have examined archival weather observations and attributed climate changes on time scales ranging from centuries to decades and in one case even days to human activity. This article gives examples sh...Numerous articles have examined archival weather observations and attributed climate changes on time scales ranging from centuries to decades and in one case even days to human activity. This article gives examples showing how climate variability and sudden changes in instruments affect trend determination. In particular, surface temperature and water vapor pressure trends in North America during 1948-2010 are discussed. Over 1/4 billion hourly observations taken at 309 stations, were first carefully examined for inhomogeneities. Positive and negative steps, for both temperature and water vapor pressure were found to not be evenly distributed in time. Inclusion of such data in a trend analysis would overstate decadal changes in temperature and water vapor. Time series free of such discontinuities show a statistically significant warming has primarily affected the western Arctic, Canadian prairies and the Midwestern U.S. during winter. Increases in water vapor pressure are most pronounced in summer in the eastern U.S. The decadal water vapor pressure trends are somewhat smaller than found in other studies that examined data for far shorter time periods. The claim of a change in the DTR （diurnal temperature range） during the 3 day flight ban following Sept. 11, 2011, is not substantiated. The observed change in the DTR was likely caused by a reduction in cloudiness during the flight ban.展开更多
In this work we have realized a simplified model to analyze compositional inhomogeneities in commercial hydrogen storage alloys. We have used it to evaluate the effect of the thermal annealing, together with calorimet...In this work we have realized a simplified model to analyze compositional inhomogeneities in commercial hydrogen storage alloys. We have used it to evaluate the effect of the thermal annealing, together with calorimetric, PCIs and XRD measurement. We have compared results with composition distribution histograms based on Rietveld refinement of XRD patterns. Finally we studied the variation of α and β phases crystallographic parameters with H2 pressure.展开更多
Multi-principal element solid solutions are prone to develop local chemical inhomogeneities,i.e.,chemi-cal order/clustering and/or compositional undulation.However,these structural details from short-range(first coupl...Multi-principal element solid solutions are prone to develop local chemical inhomogeneities,i.e.,chemi-cal order/clustering and/or compositional undulation.However,these structural details from short-range(first couple of nearest-neighbor atomic shells)to nanometer length scale are very challenging to re-solve in both experimental characterization and computer simulations.For instance,Monte Carlo model-ing based on density-functional-theory calculations is severely limited by the sample size and the sim-ulation steps practical in the simulations.Adopting the cluster expansion approach,here we systemati-cally reveal the local chemical inhomogeneity,including chemical order and compositional fluctuation,in three representative equiatomic TiZrNb-based body-centered cubic refractory high-entropy alloys(HEAs):TiZrNb,TiZrHfNb and TiZrHfNbTa.Ti-Zr pairs are found to exhibit the highest degree of chemical pref-erence among all atomic pairs.Such chemical short-range order(CSRO)induces an accompanying com-positional undulation,both extending to characteristic dimensions of the order of one nanometer.The chemical inhomogeneity trend uncovered for this series of TiZrNb-based HEAs is expected to impact their mechanical properties;e.g.,incorporating the CSRO effects in a current model significantly improves its agreement with experimental measured yield strength.展开更多
This paper discusses use of approximations and the Integral Mean Value Theorem to show that 6 coefficients approximately describe the distortions of near surface inhomogeneities on the MT field of a horizontally layer...This paper discusses use of approximations and the Integral Mean Value Theorem to show that 6 coefficients approximately describe the distortions of near surface inhomogeneities on the MT field of a horizontally layered earth model. When these 6 coefficients are considered together with those of the magnetic field of a horizontally layered earth model,the analytic and approximate wave impedance equations can be derived for the MT response of a horizontally layered earth model with near-surface 2-D and 3-D inhomogeneities. These approximate wave impedance equations are used with inverted MT data for 2-D and 3-D forward modelling. Although these 6 coefficients cannot be determined before inversion,initial estimates can be used. The 6 coefficients and the asistivity and thickness of each layer of a horizontally layered earth can be obtained by using published inversion methods. The 6 coefficients give important informaion (depths and resistivities) on the near-surface inhomogenelties.The authors inverted 2-D and 3-D theoretical models for Fast Approximate Inversion of Magnetotelluric (FAIMT) data for a horizontally layered earth with near-surface inhomogeneities compares favorably with traditional invrsion methods, especially for inverting regional or basin structures. This method simplifies computation and gives a reasonable 1 -D geological model with fewer nonuniquenas problems.展开更多
A commercially available laser marking system based on diode-pumped Nd:YVO<sub>4</sub> laser was used for creating grid patterns for forming strain analysis of a dual-phase steel. The aim was to determine ...A commercially available laser marking system based on diode-pumped Nd:YVO<sub>4</sub> laser was used for creating grid patterns for forming strain analysis of a dual-phase steel. The aim was to determine and analyze the influence of laser working parameters on the formability of sheet material by means of an in-depth characterization of this induced microstructural and geometric inhomogeneity. The electrochemical etching served as the reference method without the negative effect of generating inhomogeneity. The formability was evaluated using the cupping test according to Erichsen. While the quantification of geometric inhomogeneity was based on the determination of the notch factor, light microscopy and microhardness measurement were used for the evaluation of microstructural inhomogeneity. Furthermore, on the basis of the results an empirical regression model was established which described in terms of quantity the relationship between the examined factors such as laser power, pulse frequency and scanning speed as well as the command variable and the mark depth. The results showed that microstructural inhomogeneity in the used marking parameters due to their locally very limited formation did not have an appreciable influence on the mechanical properties. In contrast to this, the induced geometric inhomogeneity had a marked influence on the material formability.展开更多
In recent years, the research advancements have high-lighted the critical role of the A-site cation in determining the optoelectronic and physicochemical properties of organicinorganic lead halide perovskites. Mixed-c...In recent years, the research advancements have high-lighted the critical role of the A-site cation in determining the optoelectronic and physicochemical properties of organicinorganic lead halide perovskites. Mixed-cation perovskites(MCPs) have been extensively used as absorber thin films in perovskite solar cells(PSCs), achieving high power conversion efficiencies(PCE) over 26%^([1, 2]).展开更多
Asymptotic expansions of the voltage potential in terms of the "radius" of a diametrically small(or several diametrically small) material inhomogeneity(ies) are by now quite well-known. Such asymptotic expan...Asymptotic expansions of the voltage potential in terms of the "radius" of a diametrically small(or several diametrically small) material inhomogeneity(ies) are by now quite well-known. Such asymptotic expansions for diametrically small inhomogeneities are uniform with respect to the conductivity of the inhomogeneities.In contrast, thin inhomogeneities, whose limit set is a smooth, codimension 1 manifold,σ, are examples of inhomogeneities for which the convergence to the background potential,or the standard expansion cannot be valid uniformly with respect to the conductivity, a, of the inhomogeneity. Indeed, by taking a close to 0 or to infinity, one obtains either a nearly homogeneous Neumann condition or nearly constant Dirichlet condition at the boundary of the inhomogeneity, and this difference in boundary condition is retained in the limit.The purpose of this paper is to find a "simple" replacement for the background potential, with the following properties:(1) This replacement may be(simply) calculated from the limiting domain Ω\σ, the boundary data on the boundary of Ω, and the right-hand side.(2) This replacement depends on the thickness of the inhomogeneity and the conductivity,a, through its boundary conditions on σ.(3) The difference between this replacement and the true voltage potential converges to 0 uniformly in a, as the inhomogeneity thickness tends to 0.展开更多
This study aims to investigate the effects of heat treatment on the corrosion resistance and antimicrobial activity of Mg-Zn-Ag-xCa alloys under simulated physiological conditions.The focus of this research is to unde...This study aims to investigate the effects of heat treatment on the corrosion resistance and antimicrobial activity of Mg-Zn-Ag-xCa alloys under simulated physiological conditions.The focus of this research is to understand how to optimize the biomedical performance of the alloy by adjusting its composition,particularly its stability in simulated body fluids and its ability to counteract microbes.The corrosion behavior and antibacterial properties of silver-containing magnesium alloys with different calcium contents after solution treatment were studied.The results show that the addition of calcium affects the microstructure of the alloy,including grain refinement and the distribution of the second phase.It acts as a barrier at the microscopic scale,which helps to prevent the invasion of the corrosive agent,thereby improving the overall corrosion resistance of the material.The gradual increase in calcium initially has a positive effect on the properties of the alloy,especially in terms of corrosion resistance.However,when the calcium content increases to 1.5Ca,although the initial corrosion potential of the alloy increases,excessive calcium may lead to excessive accumulation of the second phase in the microstructure,which will have a negative impact on the long-term stability and corrosion resistance of the material.After corrosion,when the calcium content is 1.0 wt%,the surface roughness of the sample is 1.65μm,with the surface being the smoothest,and the corrosion rate is 0.25 mm·year-1.However,when the calcium content increases to 1.5 wt%,the sample exhibits the fastest corrosion rate at 0.45 mm·year-1.The antibacterial properties of magnesium alloy were optimized by adding silver.展开更多
The gas explosion in residential building has always been a highly concerned problem.Explosions in homogeneous mixtures have been extensively studied.However,mixtures are often inhomogeneous in the practical scenarios...The gas explosion in residential building has always been a highly concerned problem.Explosions in homogeneous mixtures have been extensively studied.However,mixtures are often inhomogeneous in the practical scenarios due to the differences in the densities of methane and air.In order to investigate the effects of gas explosions in inhomogeneous mixtures,experimental studies involving gas leakage and explosion are conducted in a full-scale residential building to reproduce the process of gas explosion.By fitting the dimensionless buoyancy as a function of dimensionless height and dimensionless time,a distribution model of gas in large-scale spaces is established,and the mechanism of inhomogeneous distribution of methane is also be revealed.Furthermore,the stratified reconstruction method(SRM)is introduced for efficiently setting up inhomogeneous concentration fields in FLACS.The simulation results highlight that for the internal overpressure,the distribution of methane has no effect on the first overpressure peak(ΔP1),while it significantly influences the subsequent overpressure peak(ΔP2),and the maximum difference between the overpressure of homogeneous and inhomogeneous distribution is174.3%.Moreover,the initial concentration distribution also has a certain impact on the external overpressure.展开更多
The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to si...The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to simulate the IFW process of a Ni-based superalloy and reveal the omnidirectional thermo-mechanical coupling mechanism of the friction interface.The numerical model successfully simulated the deceleration,deformation processes,and peak torsional moments in IFW and captured the evolution of temperature,contact pressure,and stress.The simulated results were validated through measured thermal history,optical macrography,and axial shortening.The results indicated that interfacial friction heat was the primary heat source,and plastic deformation energy only accounted for 4%of the total.The increase in initial rotational speed and friction pressure elevated the peak temperature,reaching a maximum of 1525.5K at an initial rotational speed of 2000 r/min and friction pressure of 400 MPa.The interface heat generation could form an axial temperature gradient exceeding 320K/mm.The radial inhomogeneities of heat generation and temperature were manifested in a concentric ring distribution with maximum heat flux and temperature ranging from 2/5 to 2/3 radius.The radial inhomogeneities were caused by increasing linear velocity along the radius and an opposite distribution of contact pressure,which could reach 1.7 times the set pressure at the center.The circumferential inhomogeneity of thermomechanical distribution during rotary friction welding was revealed for the first time,benefiting from the 3D model.The deflection and transformation of distribution in contact pressure and Mises stress were indicators of plastic deformation and transition of quasi-steady state welding.The critical Mises stress was 0.5 times the friction pressure in this study.The presented modeling provides a reliable insight into the thermo-mechanical coupling mechanism of IFW and lays a solid foundation for predicting the microstructures and mechanical properties of inertia friction welded joints.展开更多
The high-pressure mercury intrusion (HPMI) experiment is widely used to assess the pore architecture oftight sandstone reservoirs. However, the conventional analysis of the high- pressure mercury intrusionhas always f...The high-pressure mercury intrusion (HPMI) experiment is widely used to assess the pore architecture oftight sandstone reservoirs. However, the conventional analysis of the high- pressure mercury intrusionhas always focused on the mercury injection curves themselves, neglecting the important geologicalinformation conveyed by the mercury ejection curves. This paper quantitatively describes the fractalcharacteristics of ejection curves by using four fractal models, i.e.,. Menger model, Thermodynamicmodel, Sierpinski model, and multi- fractal model. In comparison with mercury injection curves, weexplore the fractal significance of mercury ejection curves and define the applicability of different fractalmodels in characterizing pore architectures. Investigated tight sandstone samples can be divided intofour types (Types A, B, C and D) based on porosity, permeability, and mercury removal efficiency. Type Dsamples are unique in that they have higher permeability (>0.6 mD) but lower mercury removal effi-ciency (<35%). Fractal studies of the mercury injection curve show that it mainly reflects the pore throatcharacteristics, while the mercury ejection curve serves to reveal the pore features, and porosity andpermeability correlate well with the fractal dimension of the injection curve, while mercury removalefficiency correlates only with the Ds' value of the ejection curve. The studies on the mercury ejectioncurves also reveal that the small pores and micropores of the Type C and Type D samples are moredeveloped, with varying pore architecture. The fractal dimension Ds' value of Type D samples is greaterthan that of Type C samples, and the dissolution of Type D samples is more intense than that of Type Csamples, which further indicates that the Type D samples are smaller in pore size, rougher in surface, andwith greater difficulty for the hydrocarbon to enter, resulting in their reservoir capacity probably lessthan that of Type C samples. In this regard, the important information characterized by the mercuryejection curve should be considered in evaluating the tight sandstone reservoirs. Finally, the Menger andThermodynamic models prove to be more suitable for describing the total pore architecture, while theSierpinski model is better for characterizing the variability of the interconnected pores.展开更多
this paper,we study the exponential non-uniform Berry-Esseen bound for the maximum likelihood estimator of some time inhomogeneous diffusion process.As applications,the optimal uniform Berry-Esseen bound and optimal C...this paper,we study the exponential non-uniform Berry-Esseen bound for the maximum likelihood estimator of some time inhomogeneous diffusion process.As applications,the optimal uniform Berry-Esseen bound and optimal Cramer-type moderate deviations of the Ornstein-Uhlenbeck process andα-Brownian bridge can be obtained.The main methods are the change of measure method and asymptotic analysis technique.展开更多
Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show t...Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show that the scattering angle of SRS in a longitudinally inhomogeneous plasma can be significantly affected by transverse density modulation.Under transverse density modulation conditions,the laser focuses into underdense regions,owing to the transversely modulated refractive index.The angle of LA-SRS,neither a purely 90° angle side scattering nor purely backscattering,is almost consistent with the specific angle at which the density inhomogeneity vanishes.In modulated plasmas,the nonuniform distribution of laser intensity shifts the regions of scattering and gain compared with those in uniform plasmas,ultimately affecting the laser transmission.SRS is suppressed in weakly modulated regimes,whereas it is enhanced under strong modulation conditions,and a theoretical criterion distinguishing between strong and weak modulation is established.展开更多
1.Introduction Multi-principal element alloys(MPEAs),with compositions in the central region of the multicomponent phase diagram,have been dubbed"high-entropy alloys"(HEAs)in recent years[1-11].A more genera...1.Introduction Multi-principal element alloys(MPEAs),with compositions in the central region of the multicomponent phase diagram,have been dubbed"high-entropy alloys"(HEAs)in recent years[1-11].A more general term currently accepted by the community for these MPEAs is complex concentrated alloys or compositionally complex alloys(CCAs)[12].These alloys are usually based on single-phase multi-principal element solid solutions,with no need or possibility to distinguish which species constitutes the solvent and which ones are solutes.This Viewpoint and Perspective article focuses on a salient feature in the internal structure of MPEAs,different from traditional metals and solvent-(dilute)solute solutions.Specifically,the unusual trait to be highlighted for these heavily concentrated solutions is their inherent chemical inhomogeneity on the nanoscale,in terms of the high propensity for compositional fluctuation and local chemical order.展开更多
With a three-dimensional semiclassical ensemble method, we theoretically investigated the nonsequential double ionization of Ar driven by the spatially inhomogeneous few-cycle negatively chirped laser pulses. Our resu...With a three-dimensional semiclassical ensemble method, we theoretically investigated the nonsequential double ionization of Ar driven by the spatially inhomogeneous few-cycle negatively chirped laser pulses. Our results show that the recollision time window can be precisely controlled within an isolated time interval of several hundred attoseconds, which is useful for understanding the subcycle correlated electron dynamics. More interestingly, the correlated electron momentum distribution (CEMD) exhibits a strong dependence on laser intensity. That is, at lower laser intensity, CEMD is located in the first quadrant. As the laser intensity increases,CEMD shifts almost completely to the second and fourth quadrants, and then gradually to the third quadrant.The underlying physics governing the CEMD's dependence on laser intensity is explained.展开更多
This paper presented a numerical approach to solving the problem of a flat-ended punch in contact with a half-space matrix embedded with multiple three dimensional arbitrary-shaped inhomogeneities.Based on the semi-an...This paper presented a numerical approach to solving the problem of a flat-ended punch in contact with a half-space matrix embedded with multiple three dimensional arbitrary-shaped inhomogeneities.Based on the semi-analytical method(SAM)and the equivalent inclusion method,numerical procedures were developed and the effects of inclusion shape and distribution were analyzed.Fast Fourier transform technique was implemented to accelerate the calculation of surface deformation and subsurface stress.Interactions of inter-inclusions and inclusion-matrix were taken into account.Numerical results showed the presence of inhomogeneities(i.e.,microstructures in solids)indeed had a great effect on local contact pressure and a strong disturbance to the subsurface stress field in the vicinity of inclusions.The effects were dependent on the shape and distribution of inclusions and inter-inclusion interactions.The physical significance of this study is to provide an insight into the relation between the material microstructure and its response to the external load,and the solution approach and procedures may find useful applications,for example,the analysis of fatigue and crack propagation for composite materials,prediction of stress field in solids containing material defects,and study of the mechanism of chemical-mechanical polish(CMP)for inhomogeneous materials,etc.展开更多
We investigate the use of graded inhomogeneities in order to enhance the focusing and collimation performance of structure-embedded acoustic metamaterial lenses.The type of inhomogeneity exploited in this study consis...We investigate the use of graded inhomogeneities in order to enhance the focusing and collimation performance of structure-embedded acoustic metamaterial lenses.The type of inhomogeneity exploited in this study consists in axial symmetric exponential-like gradients of either material or geometric properties that create gradient-index inclusions able to bend and redirect propagating waves.In particular,we exploit the concept of gradient index inclusions to achieve focusing and collimation of ultrasonic beams created by embedded drop-channel lenses in both bulk and thin-walled structures.In the latter,the implementation is possible thanks to geometric exponential tapers known as Acoustic Black Holes(ABH).ABH tapers allow accurate control of the characteristics of the acoustic beam emanating from the lens channel which in the conventional design is severely affected by diffraction.The concept of beam control via graded inclusions is numerically illustrated and validated by using a combination of methodologies including geometric acoustics,finite difference time domain,and finite element methods.展开更多
The conversion of intermittent renewable electrical energy to chemical energy is of great importance which can not only mitigate current energy and environmental crisis but also contribute to the ongoing carbon neutra...The conversion of intermittent renewable electrical energy to chemical energy is of great importance which can not only mitigate current energy and environmental crisis but also contribute to the ongoing carbon neutrality national strategy.Electrocatalysis is serving as a low-carbon conversion technology that enables green and efficient energy conversion mainly through hydrogen evolution reaction(HER),carbon dioxide reduction reaction(CO_(2)RR),and nitrogen reduction reaction(NRR).The core of electrocatalysis is the design and construction of low-cost high-activity and high-stability electrocatalyst to drive reaction thermodynamics and kinetics.The employment of polyoxometalates(POMs)as platforms or precursors to construct different types of electrocatalysts has been widely reported.Herein,we systematically summarized the recent advances in POM-derived nanostructures for electrocatalysis application.The strategies for precursor design and electrocatalyst synthesis were briefly introduced.The morphology control,phase control,composite modulation,and heterostructure engineering in POM-derived nanostructures were presented in detail.The structure–activity relationship of POM-derived nanostructures is fully discussed for HER CO_(2)RR,and NRR applications.Finally,the current challenges and future outlooks of POM-derived nanostructures are summarized to provide insights toward high-efficiency electrocatalysts for energy conversion technologies.展开更多
基金supported by the National Basic Research Program (also called 973 Program) (Grant No. 2009CB421402)Chinese National Science Foundation Program (Grant No. 40975007),Chinese National Science Foundation Program (Grant No. 40633014)+1 种基金China Postdoctoral Science Foundation (Grant No. 119100581F)Important Program of State Key Laboratory of Severe Weather Chinese Academy of Meteorological Sciences (Grant No. 2010LASW-A02)
文摘Using land-use types derived from satellite remote sensing data collected by the EOS Moderate Resolution Imaging Spectroradiometer （EOS/MODIS）, the mesoscale and turbulent fluxes generated by inhomogeneities of the underlying surface over the Jinta Oasis, northwestern China, were simulated using the Regional Atmospheric Modeling System （RAMS4.4）. The results indicate that mesoscale circulation generated by land-surface inhomogeneities over the Jinta Oasis is more important than turbulence. Vertical heat fluxes and water vapor are transported to higher levels by mesoscale circulation. Mesoscale circulation also produces mesoscale synoptic systems and prevents water vapor over the oasis from running off. Mesoscale circulation transports moisture to higher atmospheric levels as the land-surface moisture over the oasis increases, favoring the formation of clouds, which sometimes leads to rainfall. Large-scale wind speed has a significant impact on mesoscale heat fluxes. During the active phase of mesoscale circulation, the stronger large-scale winds are associated with small mesoscale fluxes; however, background wind seems to intensify the turbulent sensible heat flux and turbulent latent heat flux. If the area of oasis is enlarged properly, mesoscale circulation will be able to transport moisture to higher levels, favoring the formation of rainfall in the oasis and protecting its ＂cold island＂ effect. The impact of irrigation on rainfall is important, and increasing irrigation across the oasis is necessary to protect the oasis.
文摘With the Riemann solver to the scalar hyperbolic conservation law with a spatially varying flux, a δ-mapping algorithm was proposed. The algorithm and its prospective application in traffic flow problems were briefed in the paper.
文摘Numerous articles have examined archival weather observations and attributed climate changes on time scales ranging from centuries to decades and in one case even days to human activity. This article gives examples showing how climate variability and sudden changes in instruments affect trend determination. In particular, surface temperature and water vapor pressure trends in North America during 1948-2010 are discussed. Over 1/4 billion hourly observations taken at 309 stations, were first carefully examined for inhomogeneities. Positive and negative steps, for both temperature and water vapor pressure were found to not be evenly distributed in time. Inclusion of such data in a trend analysis would overstate decadal changes in temperature and water vapor. Time series free of such discontinuities show a statistically significant warming has primarily affected the western Arctic, Canadian prairies and the Midwestern U.S. during winter. Increases in water vapor pressure are most pronounced in summer in the eastern U.S. The decadal water vapor pressure trends are somewhat smaller than found in other studies that examined data for far shorter time periods. The claim of a change in the DTR （diurnal temperature range） during the 3 day flight ban following Sept. 11, 2011, is not substantiated. The observed change in the DTR was likely caused by a reduction in cloudiness during the flight ban.
文摘In this work we have realized a simplified model to analyze compositional inhomogeneities in commercial hydrogen storage alloys. We have used it to evaluate the effect of the thermal annealing, together with calorimetric, PCIs and XRD measurement. We have compared results with composition distribution histograms based on Rietveld refinement of XRD patterns. Finally we studied the variation of α and β phases crystallographic parameters with H2 pressure.
基金J.D.and E.M.acknowledge XJTU for hosting their research at the Center for Alloy Innovation and Design(CAID).This work was funded by the Natural Science Foundation of China(No.12004294)National Youth Talents Program and the HPC platform of Xi’an Jiaotong University。
文摘Multi-principal element solid solutions are prone to develop local chemical inhomogeneities,i.e.,chemi-cal order/clustering and/or compositional undulation.However,these structural details from short-range(first couple of nearest-neighbor atomic shells)to nanometer length scale are very challenging to re-solve in both experimental characterization and computer simulations.For instance,Monte Carlo model-ing based on density-functional-theory calculations is severely limited by the sample size and the sim-ulation steps practical in the simulations.Adopting the cluster expansion approach,here we systemati-cally reveal the local chemical inhomogeneity,including chemical order and compositional fluctuation,in three representative equiatomic TiZrNb-based body-centered cubic refractory high-entropy alloys(HEAs):TiZrNb,TiZrHfNb and TiZrHfNbTa.Ti-Zr pairs are found to exhibit the highest degree of chemical pref-erence among all atomic pairs.Such chemical short-range order(CSRO)induces an accompanying com-positional undulation,both extending to characteristic dimensions of the order of one nanometer.The chemical inhomogeneity trend uncovered for this series of TiZrNb-based HEAs is expected to impact their mechanical properties;e.g.,incorporating the CSRO effects in a current model significantly improves its agreement with experimental measured yield strength.
文摘This paper discusses use of approximations and the Integral Mean Value Theorem to show that 6 coefficients approximately describe the distortions of near surface inhomogeneities on the MT field of a horizontally layered earth model. When these 6 coefficients are considered together with those of the magnetic field of a horizontally layered earth model,the analytic and approximate wave impedance equations can be derived for the MT response of a horizontally layered earth model with near-surface 2-D and 3-D inhomogeneities. These approximate wave impedance equations are used with inverted MT data for 2-D and 3-D forward modelling. Although these 6 coefficients cannot be determined before inversion,initial estimates can be used. The 6 coefficients and the asistivity and thickness of each layer of a horizontally layered earth can be obtained by using published inversion methods. The 6 coefficients give important informaion (depths and resistivities) on the near-surface inhomogenelties.The authors inverted 2-D and 3-D theoretical models for Fast Approximate Inversion of Magnetotelluric (FAIMT) data for a horizontally layered earth with near-surface inhomogeneities compares favorably with traditional invrsion methods, especially for inverting regional or basin structures. This method simplifies computation and gives a reasonable 1 -D geological model with fewer nonuniquenas problems.
文摘A commercially available laser marking system based on diode-pumped Nd:YVO<sub>4</sub> laser was used for creating grid patterns for forming strain analysis of a dual-phase steel. The aim was to determine and analyze the influence of laser working parameters on the formability of sheet material by means of an in-depth characterization of this induced microstructural and geometric inhomogeneity. The electrochemical etching served as the reference method without the negative effect of generating inhomogeneity. The formability was evaluated using the cupping test according to Erichsen. While the quantification of geometric inhomogeneity was based on the determination of the notch factor, light microscopy and microhardness measurement were used for the evaluation of microstructural inhomogeneity. Furthermore, on the basis of the results an empirical regression model was established which described in terms of quantity the relationship between the examined factors such as laser power, pulse frequency and scanning speed as well as the command variable and the mark depth. The results showed that microstructural inhomogeneity in the used marking parameters due to their locally very limited formation did not have an appreciable influence on the mechanical properties. In contrast to this, the induced geometric inhomogeneity had a marked influence on the material formability.
基金financially supported by the National Natural Science Foundation of China (52462032, 62274018, 52462031)Natural Science Foundation of Yunnan Province (202501AT070353, 202101BE070001-049)+2 种基金the Xinjiang Construction Corps Key Areas of Science and Technology Research Project (2023AB029)the Tianchi Talent Program of Xinjiang Uygur Autonomous Region (2024, Jiangzhao Chen)the Key Project of Chongqing Overseas Students Returning to China Entrepreneurship and Innovation Support Plan (cx2023006)。
文摘In recent years, the research advancements have high-lighted the critical role of the A-site cation in determining the optoelectronic and physicochemical properties of organicinorganic lead halide perovskites. Mixed-cation perovskites(MCPs) have been extensively used as absorber thin films in perovskite solar cells(PSCs), achieving high power conversion efficiencies(PCE) over 26%^([1, 2]).
基金partially supported by NSF grant DMS-12-11330 while CD was a postdoctoral visitor at Rutgers University and by the NSF IR/D program while MSV served at the National Science Foundation
文摘Asymptotic expansions of the voltage potential in terms of the "radius" of a diametrically small(or several diametrically small) material inhomogeneity(ies) are by now quite well-known. Such asymptotic expansions for diametrically small inhomogeneities are uniform with respect to the conductivity of the inhomogeneities.In contrast, thin inhomogeneities, whose limit set is a smooth, codimension 1 manifold,σ, are examples of inhomogeneities for which the convergence to the background potential,or the standard expansion cannot be valid uniformly with respect to the conductivity, a, of the inhomogeneity. Indeed, by taking a close to 0 or to infinity, one obtains either a nearly homogeneous Neumann condition or nearly constant Dirichlet condition at the boundary of the inhomogeneity, and this difference in boundary condition is retained in the limit.The purpose of this paper is to find a "simple" replacement for the background potential, with the following properties:(1) This replacement may be(simply) calculated from the limiting domain Ω\σ, the boundary data on the boundary of Ω, and the right-hand side.(2) This replacement depends on the thickness of the inhomogeneity and the conductivity,a, through its boundary conditions on σ.(3) The difference between this replacement and the true voltage potential converges to 0 uniformly in a, as the inhomogeneity thickness tends to 0.
基金supported by Wenhai Program of the S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology(No.2021WHZZB2301)Hainan Provincial Joint Project of Sanya Yazhou Bay Science and Technology City(No.2021CXLH0005)Overseas Science and Education Centers of Bureau of International Cooperation Chinese Academy of Sciences(No.121311KYSB20210005-2).
文摘This study aims to investigate the effects of heat treatment on the corrosion resistance and antimicrobial activity of Mg-Zn-Ag-xCa alloys under simulated physiological conditions.The focus of this research is to understand how to optimize the biomedical performance of the alloy by adjusting its composition,particularly its stability in simulated body fluids and its ability to counteract microbes.The corrosion behavior and antibacterial properties of silver-containing magnesium alloys with different calcium contents after solution treatment were studied.The results show that the addition of calcium affects the microstructure of the alloy,including grain refinement and the distribution of the second phase.It acts as a barrier at the microscopic scale,which helps to prevent the invasion of the corrosive agent,thereby improving the overall corrosion resistance of the material.The gradual increase in calcium initially has a positive effect on the properties of the alloy,especially in terms of corrosion resistance.However,when the calcium content increases to 1.5Ca,although the initial corrosion potential of the alloy increases,excessive calcium may lead to excessive accumulation of the second phase in the microstructure,which will have a negative impact on the long-term stability and corrosion resistance of the material.After corrosion,when the calcium content is 1.0 wt%,the surface roughness of the sample is 1.65μm,with the surface being the smoothest,and the corrosion rate is 0.25 mm·year-1.However,when the calcium content increases to 1.5 wt%,the sample exhibits the fastest corrosion rate at 0.45 mm·year-1.The antibacterial properties of magnesium alloy were optimized by adding silver.
基金the financial support from National Natural Science Foundation of China(Grant No.52378488)Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX22_0222)。
文摘The gas explosion in residential building has always been a highly concerned problem.Explosions in homogeneous mixtures have been extensively studied.However,mixtures are often inhomogeneous in the practical scenarios due to the differences in the densities of methane and air.In order to investigate the effects of gas explosions in inhomogeneous mixtures,experimental studies involving gas leakage and explosion are conducted in a full-scale residential building to reproduce the process of gas explosion.By fitting the dimensionless buoyancy as a function of dimensionless height and dimensionless time,a distribution model of gas in large-scale spaces is established,and the mechanism of inhomogeneous distribution of methane is also be revealed.Furthermore,the stratified reconstruction method(SRM)is introduced for efficiently setting up inhomogeneous concentration fields in FLACS.The simulation results highlight that for the internal overpressure,the distribution of methane has no effect on the first overpressure peak(ΔP1),while it significantly influences the subsequent overpressure peak(ΔP2),and the maximum difference between the overpressure of homogeneous and inhomogeneous distribution is174.3%.Moreover,the initial concentration distribution also has a certain impact on the external overpressure.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFB3404904)。
文摘The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to simulate the IFW process of a Ni-based superalloy and reveal the omnidirectional thermo-mechanical coupling mechanism of the friction interface.The numerical model successfully simulated the deceleration,deformation processes,and peak torsional moments in IFW and captured the evolution of temperature,contact pressure,and stress.The simulated results were validated through measured thermal history,optical macrography,and axial shortening.The results indicated that interfacial friction heat was the primary heat source,and plastic deformation energy only accounted for 4%of the total.The increase in initial rotational speed and friction pressure elevated the peak temperature,reaching a maximum of 1525.5K at an initial rotational speed of 2000 r/min and friction pressure of 400 MPa.The interface heat generation could form an axial temperature gradient exceeding 320K/mm.The radial inhomogeneities of heat generation and temperature were manifested in a concentric ring distribution with maximum heat flux and temperature ranging from 2/5 to 2/3 radius.The radial inhomogeneities were caused by increasing linear velocity along the radius and an opposite distribution of contact pressure,which could reach 1.7 times the set pressure at the center.The circumferential inhomogeneity of thermomechanical distribution during rotary friction welding was revealed for the first time,benefiting from the 3D model.The deflection and transformation of distribution in contact pressure and Mises stress were indicators of plastic deformation and transition of quasi-steady state welding.The critical Mises stress was 0.5 times the friction pressure in this study.The presented modeling provides a reliable insight into the thermo-mechanical coupling mechanism of IFW and lays a solid foundation for predicting the microstructures and mechanical properties of inertia friction welded joints.
基金The research project was co-funded by the National Natural Science Foundation of China(No.42072172,No.41772120)Shandong Province Natural Science Fund for Distinguished Young Scholars(No.JQ201311)the Graduate Scientific and Technological Innovation Project Financially Supported by Shandong University of Science and Technology(No.SDKDYC190313).
文摘The high-pressure mercury intrusion (HPMI) experiment is widely used to assess the pore architecture oftight sandstone reservoirs. However, the conventional analysis of the high- pressure mercury intrusionhas always focused on the mercury injection curves themselves, neglecting the important geologicalinformation conveyed by the mercury ejection curves. This paper quantitatively describes the fractalcharacteristics of ejection curves by using four fractal models, i.e.,. Menger model, Thermodynamicmodel, Sierpinski model, and multi- fractal model. In comparison with mercury injection curves, weexplore the fractal significance of mercury ejection curves and define the applicability of different fractalmodels in characterizing pore architectures. Investigated tight sandstone samples can be divided intofour types (Types A, B, C and D) based on porosity, permeability, and mercury removal efficiency. Type Dsamples are unique in that they have higher permeability (>0.6 mD) but lower mercury removal effi-ciency (<35%). Fractal studies of the mercury injection curve show that it mainly reflects the pore throatcharacteristics, while the mercury ejection curve serves to reveal the pore features, and porosity andpermeability correlate well with the fractal dimension of the injection curve, while mercury removalefficiency correlates only with the Ds' value of the ejection curve. The studies on the mercury ejectioncurves also reveal that the small pores and micropores of the Type C and Type D samples are moredeveloped, with varying pore architecture. The fractal dimension Ds' value of Type D samples is greaterthan that of Type C samples, and the dissolution of Type D samples is more intense than that of Type Csamples, which further indicates that the Type D samples are smaller in pore size, rougher in surface, andwith greater difficulty for the hydrocarbon to enter, resulting in their reservoir capacity probably lessthan that of Type C samples. In this regard, the important information characterized by the mercuryejection curve should be considered in evaluating the tight sandstone reservoirs. Finally, the Menger andThermodynamic models prove to be more suitable for describing the total pore architecture, while theSierpinski model is better for characterizing the variability of the interconnected pores.
基金supported by the NSFC(12101358,12471095)the Natural Science Foundation of Hubei Province in China(2024AFC020)the Fundamental Research Funds for the Central Universities,South-Central MinZu University(CZY23010)。
文摘this paper,we study the exponential non-uniform Berry-Esseen bound for the maximum likelihood estimator of some time inhomogeneous diffusion process.As applications,the optimal uniform Berry-Esseen bound and optimal Cramer-type moderate deviations of the Ornstein-Uhlenbeck process andα-Brownian bridge can be obtained.The main methods are the change of measure method and asymptotic analysis technique.
基金supported by the National Natural Science Foundation of China under Grant Nos.U2430207,12035002,and 12305258by the CAEP Foundation under Grant No.YZJJZQ2023020.
文摘Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show that the scattering angle of SRS in a longitudinally inhomogeneous plasma can be significantly affected by transverse density modulation.Under transverse density modulation conditions,the laser focuses into underdense regions,owing to the transversely modulated refractive index.The angle of LA-SRS,neither a purely 90° angle side scattering nor purely backscattering,is almost consistent with the specific angle at which the density inhomogeneity vanishes.In modulated plasmas,the nonuniform distribution of laser intensity shifts the regions of scattering and gain compared with those in uniform plasmas,ultimately affecting the laser transmission.SRS is suppressed in weakly modulated regimes,whereas it is enhanced under strong modulation conditions,and a theoretical criterion distinguishing between strong and weak modulation is established.
基金supported by the National Natural Science Foundation of China(Grant No.52231001)Evan Ma and Jun Ding also acknowledge XJTU for hosting their research at the Center for Alloy Innovation and Design(CAID).
文摘1.Introduction Multi-principal element alloys(MPEAs),with compositions in the central region of the multicomponent phase diagram,have been dubbed"high-entropy alloys"(HEAs)in recent years[1-11].A more general term currently accepted by the community for these MPEAs is complex concentrated alloys or compositionally complex alloys(CCAs)[12].These alloys are usually based on single-phase multi-principal element solid solutions,with no need or possibility to distinguish which species constitutes the solvent and which ones are solutes.This Viewpoint and Perspective article focuses on a salient feature in the internal structure of MPEAs,different from traditional metals and solvent-(dilute)solute solutions.Specifically,the unusual trait to be highlighted for these heavily concentrated solutions is their inherent chemical inhomogeneity on the nanoscale,in terms of the high propensity for compositional fluctuation and local chemical order.
基金supported by the National Natural Science Foundation of China (Grant No. 12074329)Nanhu Scholars Program for Young Scholars of Xinyang Normal University。
文摘With a three-dimensional semiclassical ensemble method, we theoretically investigated the nonsequential double ionization of Ar driven by the spatially inhomogeneous few-cycle negatively chirped laser pulses. Our results show that the recollision time window can be precisely controlled within an isolated time interval of several hundred attoseconds, which is useful for understanding the subcycle correlated electron dynamics. More interestingly, the correlated electron momentum distribution (CEMD) exhibits a strong dependence on laser intensity. That is, at lower laser intensity, CEMD is located in the first quadrant. As the laser intensity increases,CEMD shifts almost completely to the second and fourth quadrants, and then gradually to the third quadrant.The underlying physics governing the CEMD's dependence on laser intensity is explained.
基金supported by the National Basic Research Program of China(Grant Nos.2009CB724200,2011CB013404 and 2011CB706602)
文摘This paper presented a numerical approach to solving the problem of a flat-ended punch in contact with a half-space matrix embedded with multiple three dimensional arbitrary-shaped inhomogeneities.Based on the semi-analytical method(SAM)and the equivalent inclusion method,numerical procedures were developed and the effects of inclusion shape and distribution were analyzed.Fast Fourier transform technique was implemented to accelerate the calculation of surface deformation and subsurface stress.Interactions of inter-inclusions and inclusion-matrix were taken into account.Numerical results showed the presence of inhomogeneities(i.e.,microstructures in solids)indeed had a great effect on local contact pressure and a strong disturbance to the subsurface stress field in the vicinity of inclusions.The effects were dependent on the shape and distribution of inclusions and inter-inclusion interactions.The physical significance of this study is to provide an insight into the relation between the material microstructure and its response to the external load,and the solution approach and procedures may find useful applications,for example,the analysis of fatigue and crack propagation for composite materials,prediction of stress field in solids containing material defects,and study of the mechanism of chemical-mechanical polish(CMP)for inhomogeneous materials,etc.
文摘We investigate the use of graded inhomogeneities in order to enhance the focusing and collimation performance of structure-embedded acoustic metamaterial lenses.The type of inhomogeneity exploited in this study consists in axial symmetric exponential-like gradients of either material or geometric properties that create gradient-index inclusions able to bend and redirect propagating waves.In particular,we exploit the concept of gradient index inclusions to achieve focusing and collimation of ultrasonic beams created by embedded drop-channel lenses in both bulk and thin-walled structures.In the latter,the implementation is possible thanks to geometric exponential tapers known as Acoustic Black Holes(ABH).ABH tapers allow accurate control of the characteristics of the acoustic beam emanating from the lens channel which in the conventional design is severely affected by diffraction.The concept of beam control via graded inclusions is numerically illustrated and validated by using a combination of methodologies including geometric acoustics,finite difference time domain,and finite element methods.
基金financially supported by Shandong Provincial Natural Science Foundation(No.ZR2019BB025)。
文摘The conversion of intermittent renewable electrical energy to chemical energy is of great importance which can not only mitigate current energy and environmental crisis but also contribute to the ongoing carbon neutrality national strategy.Electrocatalysis is serving as a low-carbon conversion technology that enables green and efficient energy conversion mainly through hydrogen evolution reaction(HER),carbon dioxide reduction reaction(CO_(2)RR),and nitrogen reduction reaction(NRR).The core of electrocatalysis is the design and construction of low-cost high-activity and high-stability electrocatalyst to drive reaction thermodynamics and kinetics.The employment of polyoxometalates(POMs)as platforms or precursors to construct different types of electrocatalysts has been widely reported.Herein,we systematically summarized the recent advances in POM-derived nanostructures for electrocatalysis application.The strategies for precursor design and electrocatalyst synthesis were briefly introduced.The morphology control,phase control,composite modulation,and heterostructure engineering in POM-derived nanostructures were presented in detail.The structure–activity relationship of POM-derived nanostructures is fully discussed for HER CO_(2)RR,and NRR applications.Finally,the current challenges and future outlooks of POM-derived nanostructures are summarized to provide insights toward high-efficiency electrocatalysts for energy conversion technologies.
