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ASEAN Countries' Perceptions and Responses to US Construction of “Indo–Pacific” Minilateral Framework
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作者 Liu Yanfeng 《Contemporary International Relations》 2024年第5期66-85,共20页
ASEAN countries are important targets for the United States to promote the “Indo–Pacific” minilateral framework. Their official, think tank, and media opinions regard this as an important opportunity to enhance the... ASEAN countries are important targets for the United States to promote the “Indo–Pacific” minilateral framework. Their official, think tank, and media opinions regard this as an important opportunity to enhance their national status and promote their national interests, which will be beneficial to peace and stability in the “Indo–Pacific” region. However, they are worried that it will damage the “ASEAN centrality.” ASEAN has responded positively and is committed to reshaping its “central position” and regional leadership and improving regional governance capabilities, but there are differences in the responses of various countries. In the future, ASEAN countries will seek to achieve direct and practical interests through the US “Indo–Pacific” minilateral framework, but they are more wor ried that the “central position of ASEAN” will be replaced and its “neutral and balanced” position will be threatened. 展开更多
关键词 ASEAN centrality ASEAN countries indo–Pacific” minilateral framework
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2-(4,5-二硫甲基-1,3-二硫环戊烯基)-3,4-富勒吡咯烷的合成表征及电子光谱的INDO/S研究 被引量:13
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作者 朱玉兰 尹起范 +3 位作者 曹丽 杨彦杰 阚玉和 苏忠民 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2004年第2期126-130,共5页
通过亚胺叶立德与C60 发生 1,3 偶极环加成反应的方法 ,合成了一种新的具有分子内给 受体系的C60吡咯烷衍生物 2 (4 ,5 二硫甲基 1,3 二硫环戊烯基 ) 3,4 富勒吡咯烷 (C66H9NS4) ,以红外、元素分析、核磁共振氢谱、紫外进行了表征 ... 通过亚胺叶立德与C60 发生 1,3 偶极环加成反应的方法 ,合成了一种新的具有分子内给 受体系的C60吡咯烷衍生物 2 (4 ,5 二硫甲基 1,3 二硫环戊烯基 ) 3,4 富勒吡咯烷 (C66H9NS4) ,以红外、元素分析、核磁共振氢谱、紫外进行了表征 .运用Gaussian98量子化学程序包 ,利用密度泛函的方法对分子的几何构型进行了优化 ,在优化的基础上 ,应用INDO/S的方法计算了化合物的电子光谱 ,计算结果表明 ,C66H9NS4的光谱吸收在 4 38.9nm ,与实验值 4 31. 展开更多
关键词 C60 电子光谱 B3LYP indo/S
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巴比妥酸苯胺取代衍生物二阶非线性光学性质和电子光谱的INDO/CI研究 被引量:11
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作者 赵亮 苏忠民 +3 位作者 阚玉和 朱玉兰 任爱民 封继康 《化学学报》 SCIE CAS CSCD 北大核心 2003年第8期1197-1201,共5页
利用量子化学密度泛函理论 (DFT)B3LYP方法 ,在 6 3 1G 基组下对巴比妥酸苯胺取代衍生物体系BA1~BA5进行几何结构优化 .以优化后的构型为基础 ,应用INDO/CI方法进行电子光谱计算 ,并结合实验数据进行了分析 .同时应用完全态求和 (SOS)... 利用量子化学密度泛函理论 (DFT)B3LYP方法 ,在 6 3 1G 基组下对巴比妥酸苯胺取代衍生物体系BA1~BA5进行几何结构优化 .以优化后的构型为基础 ,应用INDO/CI方法进行电子光谱计算 ,并结合实验数据进行了分析 .同时应用完全态求和 (SOS)公式计算二阶非线性光学 (NLO)系数 βμ.设计的系列体系中 βμ 最大值可达到 65 .47× 10 -3 0 esu .进一步探讨了体系的共轭性和烷基取代基链的长度对二者的影响 ,结果表明 ,体系的共轭程度越高 ,烷基取代基的链长度越长 ,体系 βμ值越大 。 展开更多
关键词 巴比妥酸苯胺取代衍生物 二阶非线性光学性质 电子光谱 indo/CI DFT 自组装 几何构型
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牛血清白蛋白与Indo-1相互作用的荧光光谱法研究 被引量:34
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作者 白海鑫 杨成 杨秀荣 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2007年第2期227-233,共7页
以牛血清白蛋白(Bovine serum album in,BSA)与荧光探针Indo-1为蛋白质和配体模型,基于Indo-1的荧光强度与BSA的分析浓度间的关系,建立了计算二者相互作用位点数的方法,并利用荧光共振能量转移及各种荧光技术对Indo-1和BSA的相互作用进... 以牛血清白蛋白(Bovine serum album in,BSA)与荧光探针Indo-1为蛋白质和配体模型,基于Indo-1的荧光强度与BSA的分析浓度间的关系,建立了计算二者相互作用位点数的方法,并利用荧光共振能量转移及各种荧光技术对Indo-1和BSA的相互作用进行了研究.结果表明,Indo-1在BSA中有3个作用位点,这3个作用位点与BSA中的212位色氨酸(Trp 212)间的距离分别为2.93,2.57和2.40 nm;Indo-1通过疏水性作用进入到BSA的3个疏水性空腔.在荧光猝灭实验中,通过M icrolab 500系列进样器和PTI荧光仪的联用实现了荧光强度的自动和实时记录. 展开更多
关键词 牛血清白蛋白 荧光探针indo-1 结合位点数 相互作用 荧光光谱法
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牛血清白蛋白与Indo-1相互作用时构象变化的荧光光谱法分析 被引量:1
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作者 白海鑫 李聪 +1 位作者 刘小花 袁超 《河南农业大学学报》 CAS CSCD 北大核心 2008年第5期570-574,共5页
系用荧光光谱及吸收光谱法证明了牛血清白蛋白(bovine serum albumin,BSA)与荧光探针Indo-1共存时二者能够发生相互作用,并用同步扫描荧光光谱法研究了BSA与Indo-1相互作用时构象变化的情况,考察了溶液的酸度对二者相互作用的影响.结果... 系用荧光光谱及吸收光谱法证明了牛血清白蛋白(bovine serum albumin,BSA)与荧光探针Indo-1共存时二者能够发生相互作用,并用同步扫描荧光光谱法研究了BSA与Indo-1相互作用时构象变化的情况,考察了溶液的酸度对二者相互作用的影响.结果表明,荧光探针Indo-1在与BSA相互作用时未引起该蛋白质构象的变化,认为Indo-1可作为荧光探针用于诸如BSA这样的蛋白质与其它配体相互作用的荧光光谱法研究. 展开更多
关键词 牛血清白蛋白 荧光探针分子 indo-1 相互作用 构象变化
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某些镧系化合物化学键特性的INDO研究 被引量:1
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作者 李振祥 兰桂刚 孟庆波 《化学学报》 SCIE CAS CSCD 北大核心 1992年第3期244-248,共5页
本文用INDO方法研究了不同价态镧系化合物的成键性质和4f轨道在成键中的作用,结果表明,镧系化合物的成键受许多因素,如价态、半径、配体、配位数、空间构型等影响。不同配体与镧系元素成键的强度差别较大;高价态的共价性大于低价态的;... 本文用INDO方法研究了不同价态镧系化合物的成键性质和4f轨道在成键中的作用,结果表明,镧系化合物的成键受许多因素,如价态、半径、配体、配位数、空间构型等影响。不同配体与镧系元素成键的强度差别较大;高价态的共价性大于低价态的;配位数低的大于配位数高的。某些特殊构型的镧系化合物除σ键外,还形成重叠较好的π配键,使Ln—L键共价性大大增强。4f轨道在成键中的作用比5d的少得多,三价(二价态)的4f轨道基本定域(<0.1%),四价态的4f轨道对成键的贡献明显增大,可接近1%。 展开更多
关键词 镧系化合物 化学键 indo
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二氰基三维苯多烯共轭化合物电子光谱及非线性光学性质的INDO/SOS研究 被引量:1
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作者 阚玉和 《东北师大学报(自然科学版)》 CAS CSCD 北大核心 2004年第3期61-65,共5页
 以量子化学半经验AM1方法优化几何构型为基础,应用INDO/CI方法对几种D-π-A型二氰基三维苯多烯及其脂环化合物的垂直跃迁能进行了计算,同时应用完全态求和(SOS)公式计算了二阶非线性光学(NLO)系数β.讨论了体系的共轭性、烯链链长变...  以量子化学半经验AM1方法优化几何构型为基础,应用INDO/CI方法对几种D-π-A型二氰基三维苯多烯及其脂环化合物的垂直跃迁能进行了计算,同时应用完全态求和(SOS)公式计算了二阶非线性光学(NLO)系数β.讨论了体系的共轭性、烯链链长变化及烯链脂环化对共轭体系结构和电子光谱的影响.结果表明:随着共轭链长度增加共轭程度增大,体系β值增大,λmax红移;烯链的脂环化使β值变小,而λmax蓝移. 展开更多
关键词 苯多烯 indo CI indo SOS 电子光谱 二阶NLO性质
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Fe(Ⅱ)、Co(Ⅲ)卟吩复合物电子结构的INDO研究
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作者 傅强 陈彬 +3 位作者 张红革 杜锡光 邵允 赵成大 《东北师大学报(自然科学版)》 CAS CSCD 1993年第4期141-143,共3页
本文用量子化学的半经验的INDO法对卟吩及其二价铁和三价钴的复合物进行了计算,得到了它们的电子结构。通过计算结果分析,为研究金属卟啉类化合物的催化机制提供了参考依据。
关键词 indo 卟吩 电子结构 铁卟吩 钴卟吩
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INDO基组中包括f轨道时单中心双电子积分的旋转不变性
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作者 任镜清 徐光宪 《高等学校化学学报》 SCIE EI CAS 1988年第4期363-368,共6页
在包括f轨道的INDO方法中,为保证单中心双电子积分的旋转不变性。提出了两种方法,一种是将单中心双电子积分(μμ|νν)、(μν|μν)和(μμ|μμ)分别用它们的权重平均值Jμμ′、Kμμ′和J′μμ=Jμμ′+2Kμμ′,来代替;第二种方... 在包括f轨道的INDO方法中,为保证单中心双电子积分的旋转不变性。提出了两种方法,一种是将单中心双电子积分(μμ|νν)、(μν|μν)和(μμ|μμ)分别用它们的权重平均值Jμμ′、Kμμ′和J′μμ=Jμμ′+2Kμμ′,来代替;第二种方法除了Coulomb积分和交换积分外,还保留全部单中心双电子杂化积分。为此,导出了690个非零的杂化积分的Slater-Condon参数表达式。 展开更多
关键词 indo f轨道 双电子积分 旋转不变性
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荧光试剂Indo-1的合成
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作者 徐若千 郭媛 +2 位作者 宋丹梅 贺怀贞 陈康裕 《合成化学》 CAS CSCD 2008年第5期503-507,共5页
以邻硝基酚为原料,经10步反应合成了测定细胞游离钙离子浓度的强荧光试剂——Indo-1,其结构经1H NMR,IR和MS表征。
关键词 荧光试剂 indo-1 合成
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INDO级别上的最大重迭对称性分子轨道
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作者 叶世勇 湛昌国 《华中师范大学学报(自然科学版)》 CAS CSCD 北大核心 1997年第3期320-327,共8页
提出了INDO级别上的最大重迭对称性分子轨道计算方案,并采用通常的半经验分子轨道方法INDO中完全相同的参数进行了计算,以上计算所得结果与通常的INDOLCAO-MO结果相一致,由此,我们得出结论,提出的计算方案是可... 提出了INDO级别上的最大重迭对称性分子轨道计算方案,并采用通常的半经验分子轨道方法INDO中完全相同的参数进行了计算,以上计算所得结果与通常的INDOLCAO-MO结果相一致,由此,我们得出结论,提出的计算方案是可行的,同时,由于计算过程简单,从而更适用于大分子体系。 展开更多
关键词 对称性分子轨道 indo近似 半经验分子轨道
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LOCALIZED INDO STUDY OF THE ELECTRONIC STRUCTURE OF Sc(Sc_6Cl_(12)Co)
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作者 Song GAO Le Min LI Guang Xian XU (Research Center of Rare Earth Chemistry,Peking University,Beijing 100871,P.R.China) 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第2期171-174,共4页
Spin-unrestricted localized INDO method was used to calculate the electronic structure of rare earth cluster Sc(Sc_6Cl_(12)Co).Based on the analysis of the composition of the molecular orbitals and bond orders,it was ... Spin-unrestricted localized INDO method was used to calculate the electronic structure of rare earth cluster Sc(Sc_6Cl_(12)Co).Based on the analysis of the composition of the molecular orbitals and bond orders,it was pointed out that the interstitial transition metal atom Co in the octahedral Sc skeleton forms strong covalent bond with six Sc atoms and the bonding of Sc- Cl is mainly ionic in character.There are nine valence molecular orbitals in the cluster. 展开更多
关键词 indo LOCALIZED indo STUDY OF THE ELECTRONIC STRUCTURE OF Sc CO Cl
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稀土卟啉配合物电子结构和光谱的INDO/CI研究 被引量:2
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作者 李丽 郑世钧 孟令鹏 《中国稀土学报》 CAS CSCD 北大核心 1999年第3期198-202,共5页
利用INDO/CI方法研究镧系金属卟啉配合物中稀土离子的络合高度及溶剂配位, 发现稀土卟啉配合物的优化分子构型和络合高度随稀土离子半径减小而降低。对系列稀土卟啉配合物的电子光谱主要吸收带进行了指认, 计算结果与实验值能... 利用INDO/CI方法研究镧系金属卟啉配合物中稀土离子的络合高度及溶剂配位, 发现稀土卟啉配合物的优化分子构型和络合高度随稀土离子半径减小而降低。对系列稀土卟啉配合物的电子光谱主要吸收带进行了指认, 计算结果与实验值能较好地吻合。讨论了稀土卟啉化合物的电子结构及能级变化规律, 并分析了它们的特征电子光谱。 展开更多
关键词 稀土 卟啉配合物 indo CI计算 电子结构 光谱
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INDO级别上的最大重迭对称性分子轨道III C—N核自旋偶合常数的计算
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作者 叶世勇 沫小龙 《淮北煤师院学报(自然科学版)》 2000年第4期34-37,共4页
采用已建立的 INDO级别上的最大重迭对称性分子轨道方法计算得到的密度矩阵和分子中各原子净电荷,求得分子的最大键级杂化轨道,进而研究了 C— N核自旋偶合常数,所得计算结果与实验数据一致,结果表明我们建立的理论方法是可行的。
关键词 自旋偶合常数 最大重迭对称性分子轨道 indo级别 C-N核 密度矩阵 原子净电荷 键级杂化轨道
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Mechanism of Thermal Features over the Indo-China Peninsula and Possible Effects on the Onset of the South China Sea Monsoon 被引量:18
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作者 张耀存 钱永甫 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2002年第5期885-900,共16页
The thermal characteristics during the South China Sea (SCS) summer monsoon onset period near the Indo-China Peninsula are analyzed by using the South China Sea Monsoon Experiment (SCSMEX) reanalysis data from 1 May t... The thermal characteristics during the South China Sea (SCS) summer monsoon onset period near the Indo-China Peninsula are analyzed by using the South China Sea Monsoon Experiment (SCSMEX) reanalysis data from 1 May to 31 August 1998 and the NCEP/ NCAR pentad-mean reanalysis data from January 1980 to December 1995. The possible relationships between the anomaly of thermal features near the Indo-China Peninsula and the SCS monsoon onset are investigated, and the mechanism causing the SCS summer monsoon onset is also discussed. Results from the 1998 SCSMEX reanalysis data show that there exists a strong persistent surface sensible heating near the Indo-China Peninsula prior to the SCS monsoon onset, which has apparent low frequency oscillation features. This sensible healing leads lo a warmer center in the lower atmosphere near the Indo-China Peninsula and strong local horizontal temperature and geopotential height gradients which are favorable to strengthening the southwest wind over the Indo-China Peninsula. It is also found that stronger convergent winds at lower levels and stronger divergent winds at high levels appear, which provide a favorable configuration for the development of vertical motion, enhancement of precipitation, and onset of the SCS monsoon. These results can be verified by analysis of the multi-year mean data. Additionally, it is found that the temperature at 850 hPa increases more rapidly over the Indo-China Peninsula than the South China Sea prior to the SCS monsoon onset, which leads to a strengthening of the temperature difference between the Indo-China Peninsula and the South China Sea. Moreover, results from the analysis of the longitudinal temperature and geopotential height differences show that the eastern retreat of the subtropical high over the Indo-China Peninsula during the period of SCS monsoon onset is associated with the temperature increase over the Indo-China Peninsula and the eastern extension of low trough over the Bay of Bengal. 展开更多
关键词 indo-China Peninsula thermal feature mechanism of SCS monsoon onset
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Variation of Indo-Pacific upper ocean heat content during 2001–2012 revealed by Argo 被引量:6
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作者 WU Xiaofen LIU Zenghong +1 位作者 LIAO Guanghong WU Lingjuan 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2015年第5期29-38,共10页
Understanding of the temporal variation of oceanic heat content (OHC) is of fundamental importance to the prediction of climate change and associated global meteorological phenomena. However, OHC characteristics in ... Understanding of the temporal variation of oceanic heat content (OHC) is of fundamental importance to the prediction of climate change and associated global meteorological phenomena. However, OHC characteristics in the Pacific and Indian oceans are not well understood. Based on in situ ocean temperature and salinity profiles mainly from the Argo program, we estimated the upper layer (0-750 m) OHC in the Indo-Pacific Ocean (40°S-40°N, 30°E-80°W). Spatial and temporal variability of OHC and its likely physical mechanisms are also analyzed. Climatic distributions of upper-layer OHC in the Indian and Pacific oceans have a similar saddle pattern in the subtropics, and the highest OHC value was in the northern Arabian Sea. However, OHC variabilities in the two oceans were different. OHC in the Pacific has an east-west see-saw pattern, which does not appear in the Indian Ocean. In the Indian Ocean, the largest change was around 10°S. The most interesting phenomenon is that, there was a long-term shift of OHC in the Indo-Pacific Ocean during 2001-2012. Such variation coincided with modulation of subsurface temperature/salinity. During 2001-2007, there was subsurface cooling (freshening) nearly the entire upper 400 m layer in the western Pacific and warming (salting) in the eastern Pacific. During 2008-2012, the thermocline deepened in the western Pacific but shoaled in the east. In the Indian Ocean, there was only cooling (upper 150 m only) and freshening (almost the entire upper 400 m) during 2001-2007. The thermocline deepened during 2008-2012 in the Indian Ocean. Such change appeared from the equator to off the equator and even to the subtropics (about 20°N/S) in the two oceans. This long-term change of subsurface temperature/salinity may have been caused by change of the wind field over the two oceans during 2001-2012, in turn modifying OHC. 展开更多
关键词 ocean heat content temperature and salinity profiles wind forcing ARGO indo-Pacific Ocean
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Establishment of the South Asian High over the Indo-China Peninsula During Late Spring to Summer 被引量:4
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作者 Lijuan WANG Aiguo DAI +1 位作者 Shuaihong GUO Jing GE 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2017年第2期169-180,共12页
The establishment of the upper-level South Asian high (SAH) over the Indo-China Peninsula (ICP) during late boreal spring and its possible causes are investigated using long-term NCEP-NCAR and ERA-40 reanalysis an... The establishment of the upper-level South Asian high (SAH) over the Indo-China Peninsula (ICP) during late boreal spring and its possible causes are investigated using long-term NCEP-NCAR and ERA-40 reanalysis and satellite-observed OLR data. Results show that, from early March to mid-April, deep convection stays south of -6°N over the northern Sumatran islands. As the maximum solar radiation moves over the latitudes of the ICP (10-20°N) in late April, the air over the ICP becomes unstable. It ascends over the ICP and descends over the adjacent waters to the east and west. This triggers deep convection over the ICP that induces large latent heating and strong updrafts and upper-level divergence, leading to the formation of an upper-level anticyclonic circulation and the SAH over the ICE During early to mid-May, deep convection over the ICP intensifies and extends northwards to the adjacent waters. Strong latent heating from deep convection enhances and maintains the strong updrafts and upper-level divergence, and the SAH is fully established by mid-May. Thus, the seasonal maximum solar heating and the land-sea contrast around the ICP provide the basic conditions for deep convection to occur preferentially over the ICP, which leads to the formation of the SAH over the ICP from late April to mid-May. Simulations using RegCM4 also indicate that the diabatic heating over the ICP is conducive to the generation and development of upper-level anticyclonic circulation, which leads to an earlier establishment of the SAH. 展开更多
关键词 South Asian high indo-China Peninsula diabatic heating deep convection
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荧光钙敏试剂Indo-1AM的合成 被引量:1
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作者 杨琍苹 张熊德 +3 位作者 游福有 屠惠萍 沈茂星 朱培闳 《合成化学》 CAS CSCD 1993年第4期341-347,共7页
Indo-1AM 是一种新的测定细胞内自由钙离子浓度的强荧光试剂。本文详细报导了从邻硝基酚及α-溴甲基苯甲酸酯出发经十—步反应的合成方法及其荧光性能,并提出了由 Indo-1酸o‖引入CH_3—C—OCH_2—(AM)基团的简易方法。
关键词 荧光试剂 钙离子 细胞钙离子
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Impact of Drought on Agriculture in the Indo-Gangetic Plain,India 被引量:2
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作者 Reshmita NATH Debashis NATH +2 位作者 Qian LI Wen CHEN Xuefeng CUI 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2017年第3期335-346,共12页
In this study, we investigate the spatiotemporal characteristics of drought in India and its impact on agriculture during the summer season (April-September). In the analysis, we use Standardized Precipitation Evapo... In this study, we investigate the spatiotemporal characteristics of drought in India and its impact on agriculture during the summer season (April-September). In the analysis, we use Standardized Precipitation Evapotranspiration Index (SPEI) datasets between 1982 and 2012 at the six-monthly timescale. Based on the criterion SPEI 〈 -1, we obtain a map of the number of occurrences of drought and find that the humid subtropical Upper Middle Gangetic Plain (UMGP) region is highly drought-prone, with an occurrence frequency of 40%-45%. This UMGP region contributes at least 18%-20% of India's annual cereal production. Not only the probability of drought, but the UMGP region has become increasingly drought-prone in recent decades. Moreover, cereal production in the UMGP region has experienced a gradual declining trend from 2000 onwards, which is consistent with the increase in drought-affected areas from 20%-25% to 50%-60%, before and after 2000, respectively. A higher correlation coefficient (-0.69) between the cereal production changes and drought-affected areas confirms that at least 50% of the agricultural (cereal) losses are associated with drought. While analyzing the individual impact of precipitation and surface temperature on SPEI at 6 month timescale [SPEI (6)] we find that, in the UMGP region, surface temperature plays the primary role in the lowering of the SPEI. The linkage is further confirmed by correlation analysis between SPEI (6) and surface temperature, which exhibits strong negative values in the UMGP region. Higher temperatures may have caused more evaporation and drying, which therefore increased the area affected by drought in recent decades. 展开更多
关键词 DROUGHT AGRICULTURE SPEI indo-Gangetic Plain temperature PRECIPITATION potential evapotranspiration
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INDO近似下包含d、f轨道的定域化分子轨道方法
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作者 黎健 任镜清 +1 位作者 陈敏伯 徐光宪 《北京大学学报(自然科学版)》 CAS CSCD 北大核心 1989年第2期129-137,共9页
研究了当基组包括d、f原子轨道时,保证INDO方法具有旋转不变性的两种方法——估算全部杂化积分和权重平均库仑交换积分。导出了INDO近似下Edmiston-Rue-denberg能量定域化方法的LCAO计算公式,建立了相应的计算程序并对程序的使用进行了... 研究了当基组包括d、f原子轨道时,保证INDO方法具有旋转不变性的两种方法——估算全部杂化积分和权重平均库仑交换积分。导出了INDO近似下Edmiston-Rue-denberg能量定域化方法的LCAO计算公式,建立了相应的计算程序并对程序的使用进行了考验和说明。 展开更多
关键词 定域化 分子轨道 indo f轨道
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