An intense Asian dust storm invadedQinhuangdao,a coastal city ofNorth China on April 11-14,2023.We analyzed the bulk water-soluble inorganic ions(WSII)of PM_(10)and PM_(2.5)using an Ion Chromatograph and investigated ...An intense Asian dust storm invadedQinhuangdao,a coastal city ofNorth China on April 11-14,2023.We analyzed the bulk water-soluble inorganic ions(WSII)of PM_(10)and PM_(2.5)using an Ion Chromatograph and investigated individual particlemorphology and elemental composition using a scanning electron microscope coupled with energy dispersive X-ray.The results showed when the dust was directly transported to the sampling site from northwestern China(direct transport stages),the PM_(10)mass concentrations were high(675.0μg/m^(3))but the relative humidity(RH)was low.Total WSII were 19.54μg/m^(3)and 11.17μg/m^(3),accounting for 2.90%and 7.25%of the PM_(10)and PM_(2.5),respectively.In addition,the proportion of S-containing individual mineral dust was low(28.7%-35.3%).The results suggested there were limited secondary inorganic aerosol formation.However,when the dust was transported back to the sampling site across the Bohai Sea in the following days(reverse transport stages),both the PM_(10)mass concentrations(462.3μg/m^(3))and RH were high.Total WSII were 43.75μg/m^(3)and 18.71μg/m^(3),accounting for 9.62%and 14.45%of the total PM_(10)and PM_(2.5),respectively.The proportion of S-containing particles was 51.5%-72.5%.In addition,the concentration of NO_(3)^(−)was much higher than that of SO_(4)^(2−).The results suggested both the sulfate and nitrate formation occurred on coarse mineral dust but the nitrate formation exceeded sulfate formation.Interestingly,mostmineral dust,including Sirich particles contained Cl when they passed through the marine atmosphere.The results highlighted the heterogeneous reactions of dust varied in different transport stages.展开更多
Recent observations of Asian dust storms show an eastern expansion of the source area to degraded lands, where dust emissions have been little studied. The dust concentrations over the saline land of the western Songn...Recent observations of Asian dust storms show an eastern expansion of the source area to degraded lands, where dust emissions have been little studied. The dust concentrations over the saline land of the western Songnen Plain （SSL）, Northeastern China, are circumstantially higher than those from the northwestern Chinese deserts. These concentrations are sensitive to the surface soil conditions and wind velocity on the ground. The dust samples collected during dust storm events on the SSL contain abundant Na, Mg, A1, K, Ca, Fe and Ti, as well as toxic elements such as Cu, V, Zn and Ba. Individual particle analysis reveals that fine saline particles （〈 10 μm in diameter） on the saline land, consisting largely of carbonate, halite and sulfate together with lithogenic minerals such as SiO2 and aluminosilicate, are eventually uplifted during the interval from spring to autuum. The predominantly fine saline particles uplifted from the SSL are likely transported eastward by the winter monsoon circulation and westerlies. Recent degradation of saline lands in Northeastern China would not only increase the frequency of dust storm events in the downwind area, but also might change the chemical composition of the Asian dust emissions.展开更多
In order to further understand the sources of PM2.5 in Shanghai air, the synchrotron X-ray fluores- cence microprobe at the BL-4A Beamline of Photon Factory of High Energy Accelerator Research Organization, Japan, was...In order to further understand the sources of PM2.5 in Shanghai air, the synchrotron X-ray fluores- cence microprobe at the BL-4A Beamline of Photon Factory of High Energy Accelerator Research Organization, Japan, was applied to analyze the individual PM2.5 particles collected from Shanghai air in the winter of 2007. Eight categories of emission sources were recognized in these individual particles. The source identification shows that most of the analyzed PM2.5 particles are derived from vehicle exhaust and metallurgical emissions. This suggests that the important emission sources of PM2.5 in Shanghai air would be vehicle exhaust and metallurgical activities.展开更多
基金supported by the Natural Science Foundation of Hebei Province(Nos.B2022407001 and D2021501004)the National Natural Science Foundation of China(No.42075107)the Fundamental Research Funds for the Central Universities(No.N2223011).
文摘An intense Asian dust storm invadedQinhuangdao,a coastal city ofNorth China on April 11-14,2023.We analyzed the bulk water-soluble inorganic ions(WSII)of PM_(10)and PM_(2.5)using an Ion Chromatograph and investigated individual particlemorphology and elemental composition using a scanning electron microscope coupled with energy dispersive X-ray.The results showed when the dust was directly transported to the sampling site from northwestern China(direct transport stages),the PM_(10)mass concentrations were high(675.0μg/m^(3))but the relative humidity(RH)was low.Total WSII were 19.54μg/m^(3)and 11.17μg/m^(3),accounting for 2.90%and 7.25%of the PM_(10)and PM_(2.5),respectively.In addition,the proportion of S-containing individual mineral dust was low(28.7%-35.3%).The results suggested there were limited secondary inorganic aerosol formation.However,when the dust was transported back to the sampling site across the Bohai Sea in the following days(reverse transport stages),both the PM_(10)mass concentrations(462.3μg/m^(3))and RH were high.Total WSII were 43.75μg/m^(3)and 18.71μg/m^(3),accounting for 9.62%and 14.45%of the total PM_(10)and PM_(2.5),respectively.The proportion of S-containing particles was 51.5%-72.5%.In addition,the concentration of NO_(3)^(−)was much higher than that of SO_(4)^(2−).The results suggested both the sulfate and nitrate formation occurred on coarse mineral dust but the nitrate formation exceeded sulfate formation.Interestingly,mostmineral dust,including Sirich particles contained Cl when they passed through the marine atmosphere.The results highlighted the heterogeneous reactions of dust varied in different transport stages.
基金supported in a part by Chinese National Key Project of Basic Research (No G2000048703)the Grant-in-Aid for Scientific Research (No 16310008,18403002) from the Ministry of Education, Culture,Sports, Science and Technology, Japan
文摘Recent observations of Asian dust storms show an eastern expansion of the source area to degraded lands, where dust emissions have been little studied. The dust concentrations over the saline land of the western Songnen Plain （SSL）, Northeastern China, are circumstantially higher than those from the northwestern Chinese deserts. These concentrations are sensitive to the surface soil conditions and wind velocity on the ground. The dust samples collected during dust storm events on the SSL contain abundant Na, Mg, A1, K, Ca, Fe and Ti, as well as toxic elements such as Cu, V, Zn and Ba. Individual particle analysis reveals that fine saline particles （〈 10 μm in diameter） on the saline land, consisting largely of carbonate, halite and sulfate together with lithogenic minerals such as SiO2 and aluminosilicate, are eventually uplifted during the interval from spring to autuum. The predominantly fine saline particles uplifted from the SSL are likely transported eastward by the winter monsoon circulation and westerlies. Recent degradation of saline lands in Northeastern China would not only increase the frequency of dust storm events in the downwind area, but also might change the chemical composition of the Asian dust emissions.
基金Supported by Knowledge Innovation Project of Chinese Academy of Sciences (KJCX3.SYW.N3) National Natural Science Foundation of China (10775172, 10675159)performance under approval of Photon Factory (PF) Program Advisory Committee(Proposal No.2007G502)
文摘In order to further understand the sources of PM2.5 in Shanghai air, the synchrotron X-ray fluores- cence microprobe at the BL-4A Beamline of Photon Factory of High Energy Accelerator Research Organization, Japan, was applied to analyze the individual PM2.5 particles collected from Shanghai air in the winter of 2007. Eight categories of emission sources were recognized in these individual particles. The source identification shows that most of the analyzed PM2.5 particles are derived from vehicle exhaust and metallurgical emissions. This suggests that the important emission sources of PM2.5 in Shanghai air would be vehicle exhaust and metallurgical activities.
