Population growth, urbanization, water resources pollution, environmental awareness, uneven distribution of water resources and water scarcity have necessitated water reuse especially in arid and semi-arid countries. ...Population growth, urbanization, water resources pollution, environmental awareness, uneven distribution of water resources and water scarcity have necessitated water reuse especially in arid and semi-arid countries. Influent and effluent data of chemical and biological analyses from four wastewater treatment plants (WWTPs) in the Sedibeng district municipality (SDM) were used to assess the viability of water reuse. Available worldwide water reuse criteria of Water Reclamation Plants (WRPs) for different reuse options were used to characterize the SDM’s four WWTPs for potable water, power and steel industrial water reuse. Only WWTP4 does not meet the influent design criteria of the New Goreangab WRP in Windhoek, Namibia of 43 mg/l and the DWAF general limit of discharge of 75 mg/l used by Beaufort West WRP in South Africa for COD. WWTP2 and 4 do not meet the DWAF general limit of 25 mg/l for suspended solids. Some of the water quality parameters of the effluents from these plants were non-compliant to the requirements for reuse in power generation and steel manufacturing. However, the implementation of advance treatment technologies such as membrane or advanced oxidation processes (AOPs) as part of the treatment train in a potential WRP would address the water quality issues. Water reclamation of SDM effluent either through direct (DPR) or indirect potable (IPR) water reuse, power generation and steel manufacturing industry has the potential of reuse in the Southern Gauteng region. The success of the selected option would be depended on cost effectiveness, stakeholder commitment and public acceptance of the reuse strategy.展开更多
Hydrophobic acid organic matter （HpoA） extracted from treated effluent has been known to improve the rejection of steroid hormone estrone by reverse osmosis （RO） and nanofiltration （NF） membranes. In this study,...Hydrophobic acid organic matter （HpoA） extracted from treated effluent has been known to improve the rejection of steroid hormone estrone by reverse osmosis （RO） and nanofiltration （NF） membranes. In this study, the effects of solution chemistry （solution pH and ionic strength） on the estrone rejection by NF membrane with the presence of HpoA were systematically investigated. Crossflow nanofiltration experiments show that the presence of HpoA significantly improved estrone rejection at all pH and ionic strength levels investigated. It is consistently shown that the ＂enhancement effect＂ of HpoA on estrone rejection at neutral and alkaline pH is attributed to the binding of estrone by HpoA macromolecules via hydrogen bonding between phenolic functional groups in feed solutions, which leads to an increase in molecular weight and appearance of negative charge. The membrane exhibited the best performance in terms ofestrone rejection at pH 10.4 （compared to pH 4 and pH 7） as a result of strengthening the electrostatic repulsion between estrone and membrane with the presence of HpoA. At neutral pH level, the ability of HpoA macromolecules to promote estrone rejection became stronger with increasing ionic strength due to their more extended conformation, which created more chances for the association between estrone and HpoA. The important conclusion of this study is that increasing solution pH and salinity can greatly intensify the ＂enhancement effect＂ of HpoA. These results can be important for NF application in direct/indirect potable water reuse.展开更多
文摘Population growth, urbanization, water resources pollution, environmental awareness, uneven distribution of water resources and water scarcity have necessitated water reuse especially in arid and semi-arid countries. Influent and effluent data of chemical and biological analyses from four wastewater treatment plants (WWTPs) in the Sedibeng district municipality (SDM) were used to assess the viability of water reuse. Available worldwide water reuse criteria of Water Reclamation Plants (WRPs) for different reuse options were used to characterize the SDM’s four WWTPs for potable water, power and steel industrial water reuse. Only WWTP4 does not meet the influent design criteria of the New Goreangab WRP in Windhoek, Namibia of 43 mg/l and the DWAF general limit of discharge of 75 mg/l used by Beaufort West WRP in South Africa for COD. WWTP2 and 4 do not meet the DWAF general limit of 25 mg/l for suspended solids. Some of the water quality parameters of the effluents from these plants were non-compliant to the requirements for reuse in power generation and steel manufacturing. However, the implementation of advance treatment technologies such as membrane or advanced oxidation processes (AOPs) as part of the treatment train in a potential WRP would address the water quality issues. Water reclamation of SDM effluent either through direct (DPR) or indirect potable (IPR) water reuse, power generation and steel manufacturing industry has the potential of reuse in the Southern Gauteng region. The success of the selected option would be depended on cost effectiveness, stakeholder commitment and public acceptance of the reuse strategy.
文摘Hydrophobic acid organic matter （HpoA） extracted from treated effluent has been known to improve the rejection of steroid hormone estrone by reverse osmosis （RO） and nanofiltration （NF） membranes. In this study, the effects of solution chemistry （solution pH and ionic strength） on the estrone rejection by NF membrane with the presence of HpoA were systematically investigated. Crossflow nanofiltration experiments show that the presence of HpoA significantly improved estrone rejection at all pH and ionic strength levels investigated. It is consistently shown that the ＂enhancement effect＂ of HpoA on estrone rejection at neutral and alkaline pH is attributed to the binding of estrone by HpoA macromolecules via hydrogen bonding between phenolic functional groups in feed solutions, which leads to an increase in molecular weight and appearance of negative charge. The membrane exhibited the best performance in terms ofestrone rejection at pH 10.4 （compared to pH 4 and pH 7） as a result of strengthening the electrostatic repulsion between estrone and membrane with the presence of HpoA. At neutral pH level, the ability of HpoA macromolecules to promote estrone rejection became stronger with increasing ionic strength due to their more extended conformation, which created more chances for the association between estrone and HpoA. The important conclusion of this study is that increasing solution pH and salinity can greatly intensify the ＂enhancement effect＂ of HpoA. These results can be important for NF application in direct/indirect potable water reuse.
